CN106753235A - A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof - Google Patents
A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106753235A CN106753235A CN201611179062.9A CN201611179062A CN106753235A CN 106753235 A CN106753235 A CN 106753235A CN 201611179062 A CN201611179062 A CN 201611179062A CN 106753235 A CN106753235 A CN 106753235A
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- China
- Prior art keywords
- parts
- sensitive adhesive
- pressure sensitive
- melt pressure
- polyisobutene
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof, it is made up of following mass fraction formula components：20 40 parts of thermoplastic elastomer (TPE), 24 parts of halogen-free flame retardants, 12 parts of antioxidant, 5 10 parts of amorphous polyolefin, 20 30 parts of vistanex, 46 parts of polyisobutene, 12 parts of plasticizer, 13 parts of biological emulsifier, 50 60 parts of tackifying resin, 35 parts of ultra-violet absorber, the present invention has excellent ultraviolet aging resistance, heat-resistant aging, low temperature resistant bending property is good, with suitable cohesive force, peeling force, initial bonding strength, and with anti-flammability, perfect can solve the defect that traditional pre- laying water-proof coiled material can only construct more than 0 DEG C.
Description
Technical field
The present invention relates to adhesive field, in particular to a kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof.
Background technology
With the acceleration of urbanization process, limited land resource has been difficult to accommodate more populations and has built, develops and live
It is dynamic.Then, development and utilization Underground Space Resource turns into the inevitable choice of numerous urban developments at present and in the future.Current underground is empty
Between using having been directed to：Underground commerce facility, underground parking station, groundwater reservoir, subway, pipe gallery etc..But, underground is prevented
Channeling water seepage and settlement influence in Hydraulic Projects are still to perplex a great problem of waterproof expert and user.It how to be structure coagulation
It is extremely challenging that soil provides directly completely viscous waterproofing protection.
The content of the invention
The invention provides a kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof, the present invention has excellent ultraviolet aging resistance
Property, heat-resistant aging, low temperature resistant bending is good, with suitable cohesive force, peeling force, initial bonding strength, and with anti-flammability, can
Perfection solves the defect that traditional pre- laying water-proof coiled material can only construct more than 0 DEG C.
To achieve the above object, the present invention provides following technical scheme：
A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof, is made up of following mass fraction formula components：Thermoplastic elastic
Body 20-40 parts, halogen-free flame retardants 2-4 parts, antioxidant 1-2 parts, amorphous polyolefin 5-10 parts, vistanex 20-30 parts, it is poly-
Isobutene 4-6 parts, plasticizer 1-2 parts, biological emulsifier 1-3 parts, tackifying resin 50-60 parts, ultra-violet absorber 3-5 parts.
Further：It is made up of following mass fraction formula components：20 parts of thermoplastic elastomer (TPE), 2 parts of halogen-free flame retardants, antioxygen
1 part of agent, 5 parts of amorphous polyolefin, 20 parts of vistanex, 4 parts of polyisobutene, 1 part of plasticizer, 1 part of biological emulsifier, thickening
50 parts of resin, 3 parts of ultra-violet absorber.
Further：It is made up of following mass fraction formula components：30 parts of thermoplastic elastomer (TPE), 3 parts of halogen-free flame retardants, antioxygen
1.5 parts of agent, 7.5 parts of amorphous polyolefin, 25 parts of vistanex, 5 parts of polyisobutene, 1.5 parts of plasticizer, biological emulsifier 2
Part, 55 parts of tackifying resin, 4 parts of ultra-violet absorber.
Further：It is made up of following mass fraction formula components：40 parts of thermoplastic elastomer (TPE), 4 parts of halogen-free flame retardants, antioxygen
2 parts of agent, 10 parts of amorphous polyolefin, 30 parts of vistanex, 6 parts of polyisobutene, 2 parts of plasticizer, 3 parts of biological emulsifier, increasing
60 parts of viscosity resin, 5 parts of ultra-violet absorber.
Further：Preparation method comprises the following steps：
Step one, by above-mentioned material according to mass fraction match after it is standby；
Step 2, kneader are warming up to 90 DEG C of thermoplastic elastomer (TPE)s, 20 parts of brombutyl, amorphous polyolefin 10
Part, 30 parts of vistanex, polyisobutene, tackifying resin, temperature keeps 130 DEG C of kneading 2h after the completion of addition；
Step 3, will step 2 gained add halogen-free flame retardants, antioxidant, plasticizer, biological emulsifier, ultraviolet radiation absorption
Agent, finished product is both obtained after being cooled to room temperature.
The beneficial effects of the invention are as follows：
1st, the present invention has excellent ultraviolet aging resistance, and heat-resistant aging, low temperature resistant bending is good；
2nd, with suitable cohesive force, peeling force, initial bonding strength, and with anti-flammability, perfect can solve the pre- laying of tradition
The defect that waterproof roll can only construct more than 0 DEG C.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment one：
A kind of flame-retardant hot-melt pressure sensitive adhesive is made up of following mass fraction formula components：Thermoplastic elastomer (TPE) 20-40 parts, Halogen
Fire retardant 2-4 parts, antioxidant 1-2 parts, amorphous polyolefin 5-10 parts, vistanex 20-30 parts, polyisobutene 4-6 parts, increasing
1-2 parts, biological emulsifier 1-3 parts, tackifying resin 50-60 parts, ultra-violet absorber 3-5 parts of agent of modeling.
Embodiment two：
A kind of flame-retardant hot-melt pressure sensitive adhesive is made up of following mass fraction formula components：20 parts of thermoplastic elastomer (TPE), Halogen resistance
2 parts of agent of combustion, 1 part of antioxidant, 5 parts of amorphous polyolefin, 20 parts of vistanex, 4 parts of polyisobutene, 1 part of plasticizer, biological cream
1 part of agent, 50 parts of tackifying resin, 3 parts of ultra-violet absorber.
Embodiment three：
A kind of flame-retardant hot-melt pressure sensitive adhesive is made up of following mass fraction formula components：30 parts of thermoplastic elastomer (TPE), Halogen resistance
Combustion 3 parts of agent, 1.5 parts of antioxidant, 7.5 parts of amorphous polyolefin, 25 parts of vistanex, 5 parts of polyisobutene, 1.5 parts of plasticizer,
2 parts of biological emulsifier, 55 parts of tackifying resin, 4 parts of ultra-violet absorber.
Example IV：
A kind of flame-retardant hot-melt pressure sensitive adhesive is made up of following mass fraction formula components：40 parts of thermoplastic elastomer (TPE), Halogen resistance
4 parts of agent of combustion, 2 parts of antioxidant, 10 parts of amorphous polyolefin, 30 parts of vistanex, 6 parts of polyisobutene, 2 parts of plasticizer, biology
3 parts of emulsifying agent, 60 parts of tackifying resin, 5 parts of ultra-violet absorber.
Embodiment five：
A kind of preparation method of flame-retardant hot-melt pressure sensitive adhesive comprises the following steps：
Step one, by above-mentioned material according to mass fraction match after it is standby；
Step 2, kneader are warming up to 90 DEG C of thermoplastic elastomer (TPE)s, 20 parts of brombutyl, amorphous polyolefin 10
Part, 30 parts of vistanex, polyisobutene, tackifying resin, temperature keeps 130 DEG C of kneading 2h after the completion of addition；
Step 3, will step 2 gained add halogen-free flame retardants, antioxidant, plasticizer, biological emulsifier, ultraviolet radiation absorption
Agent, finished product is both obtained after being cooled to room temperature.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.
Claims (5)
1. a kind of flame-retardant hot-melt pressure sensitive adhesive, it is characterised in that：It is made up of following mass fraction formula components：
Thermoplastic elastomer (TPE) 20-40 parts, halogen-free flame retardants 2-4 parts, antioxidant 1-2 parts, amorphous polyolefin 5-10 parts, polyolefin
Resin 20-30 parts, polyisobutene 4-6 parts, plasticizer 1-2 parts, biological emulsifier 1-3 parts, tackifying resin 50-60 parts, ultraviolet
Absorbent 3-5 parts.
2. a kind of flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
20 parts of thermoplastic elastomer (TPE), 2 parts of halogen-free flame retardants, 1 part of antioxidant, 5 parts of amorphous polyolefin, 20 parts of vistanex,
4 parts of polyisobutene, 1 part of plasticizer, 1 part of biological emulsifier, 50 parts of tackifying resin, 3 parts of ultra-violet absorber.
3. a kind of flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
30 parts of thermoplastic elastomer (TPE), 3 parts of halogen-free flame retardants, 1.5 parts of antioxidant, 7.5 parts of amorphous polyolefin, vistanex 25
Part, 5 parts of polyisobutene, 1.5 parts of plasticizer, 2 parts of biological emulsifier, 55 parts of tackifying resin, 4 parts of ultra-violet absorber.
4. a kind of flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：By following mass fraction formula components
Composition：
40 parts of thermoplastic elastomer (TPE), 4 parts of halogen-free flame retardants, 2 parts of antioxidant, 10 parts of amorphous polyolefin, 30 parts of vistanex,
6 parts of polyisobutene, 2 parts of plasticizer, 3 parts of biological emulsifier, 60 parts of tackifying resin, 5 parts of ultra-violet absorber.
5. a kind of a kind of preparation method of flame-retardant hot-melt pressure sensitive adhesive according to claim 1, it is characterised in that：Including as follows
Step：
Step one, by above-mentioned material according to mass fraction match after it is standby；
Step 2, kneader are warming up to 90 DEG C of thermoplastic elastomer (TPE)s, 20 parts of brombutyl, 10 parts of amorphous polyolefin, poly-
30 parts of olefin resin, polyisobutene, tackifying resin, temperature keeps 130 DEG C of kneading 2h after the completion of addition；
Step 3, will step 2 gained add halogen-free flame retardants, antioxidant, plasticizer, biological emulsifier, ultra-violet absorber,
Finished product is both obtained after being cooled to room temperature.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179062.9A CN106753235A (en) | 2016-12-19 | 2016-12-19 | A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611179062.9A CN106753235A (en) | 2016-12-19 | 2016-12-19 | A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106753235A true CN106753235A (en) | 2017-05-31 |
Family
ID=58890398
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611179062.9A Pending CN106753235A (en) | 2016-12-19 | 2016-12-19 | A kind of flame-retardant hot-melt pressure sensitive adhesive and preparation method thereof |
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| Country | Link |
|---|---|
| CN (1) | CN106753235A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108865059A (en) * | 2018-06-26 | 2018-11-23 | 广东能辉新材料科技有限公司 | Not inharmonious thermotropic pressure sensitive glue of ultraviolet ray ageing and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1754932A (en) * | 2004-09-30 | 2006-04-05 | 赵璐 | Polymer adhesive resin for corrosion-prevention of steel pipe and preparation process thereof |
| CN104059553A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of high-polymer self-adhesive waterproof roll |
| CN106221629A (en) * | 2016-08-15 | 2016-12-14 | 江苏凯伦建材股份有限公司 | A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application |
-
2016
- 2016-12-19 CN CN201611179062.9A patent/CN106753235A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1754932A (en) * | 2004-09-30 | 2006-04-05 | 赵璐 | Polymer adhesive resin for corrosion-prevention of steel pipe and preparation process thereof |
| CN104059553A (en) * | 2014-06-11 | 2014-09-24 | 胜利油田大明新型建筑防水材料有限责任公司 | Preparation method of high-polymer self-adhesive waterproof roll |
| CN106221629A (en) * | 2016-08-15 | 2016-12-14 | 江苏凯伦建材股份有限公司 | A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108865059A (en) * | 2018-06-26 | 2018-11-23 | 广东能辉新材料科技有限公司 | Not inharmonious thermotropic pressure sensitive glue of ultraviolet ray ageing and preparation method thereof |
| CN108865059B (en) * | 2018-06-26 | 2020-06-19 | 广东能辉新材料科技有限公司 | Ultraviolet aging non-sticking hot melt pressure-sensitive adhesive and preparation method thereof |
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Application publication date: 20170531 |