CN105017984A - Polymer self-adhesive tape, production method and application thereof - Google Patents
Polymer self-adhesive tape, production method and application thereof Download PDFInfo
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- CN105017984A CN105017984A CN201510431562.6A CN201510431562A CN105017984A CN 105017984 A CN105017984 A CN 105017984A CN 201510431562 A CN201510431562 A CN 201510431562A CN 105017984 A CN105017984 A CN 105017984A
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- adhesive tape
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J193/00—Adhesives based on natural resins; Adhesives based on derivatives thereof
- C09J193/04—Rosin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J145/00—Adhesives based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J153/02—Vinyl aromatic monomers and conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J157/00—Adhesives based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09J157/02—Copolymers of mineral oil hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a polymer self-adhesive tape, a production method and application thereof, the polymer self-adhesive tape comprises the following raw materials in parts by weight: 25 to 50 parts of a styrene - isoprene -styrene block copolymer, 10 to 30 parts of a plasticizer; 30 to 60 parts of first tackifying resin; 3 to 10 parts of nanofiller; 10 to 20 parts of second tackifying resin; 0.02 to 0.05 parts of an ultraviolet absorber; and 0.02 to 0.05 part of an antioxidant; the first tackifying resin is one or a mixture of two of C5 hydrogenated petroleum resin and terpene resin, and the second tackifying resin is one or a mixture of more than one of petroleum resin, terpene resin and rosin resin. By addition of the first tackifying resin, the second tackifying resin, the plasticizer, the nanofiller and other components into the styrene - isoprene -styrene block copolymer, the obtained self-adhesive tape has excellent adhesion performance with concrete, aluminum alloy and plastic steel and other materials, and has the very soft feature, node special-shaped parts are easy to fit and compact, and the obtained self-adhesive tape can be adapted to a variety of structural deformation.
Description
Technical field
The invention belongs to polymeric material field, relate to a kind of single-coated foam, be specifically related to a kind of adhesive polymer adhesive tape, making method and application thereof.
Background technology
Leakage of building is complain one of maximum problem in construction work, roof leakage, seepage in toilet, kitchen, exterior wall leakage, basement leakage always, is regarded as building " cancer ".Just there is the situation of serious leakage then in many completion of works newly built up.Cause one of leakage of building major reason: position of joints is depended merely on the sealing of common waterproof paint and certainly existed waterproof defect! Expand with heat and contract with cold because the position of joints such as negative and positive angle, Guan Gen, bearing exists, waterproof paint that non-uniform settling, various combination material cause unit elongation poor because of the equal objective factor of linear expansion coefficient is by drawing crack seepage.
If produce a kind of adhesive polymer adhesive tape, it can have excellent adhesive property (just glue, hold sticky and low temperature bonding) with the material such as concrete, aluminium alloy and plastic-steel, also there is very soft feature, easily realize at node special-shaped part docile and closely knit.Various structural deformation can be adapted at this adhesive polymer adhesive tapes of position of joints paving such as negative and positive angle, Guan Gen, bearings like this, thus avoid leakage of building.
Summary of the invention
The present invention seeks to provide a kind of adhesive polymer adhesive tape to overcome the deficiencies in the prior art.
For achieving the above object, the technical solution used in the present invention is: a kind of adhesive polymer adhesive tape, and with parts by weight, its composition of raw materials is as follows:
Styrene isoprene styrene block copolymer (SIS) 25 ~ 50 parts;
10 ~ 30 parts, softening agent;
First tackifying resin 30 ~ 60 parts;
Nano filling 3 ~ 10 parts;
Second tackifying resin 10 ~ 20 parts;
Uv-absorbing agent 0.02 ~ 0.05 part;
0.02 ~ 0.05 part, oxidation inhibitor;
Described first tackifying resin is mixtures of one or both compositions in C 5 hydrogenated petroleum resin and terpine resin; Described second tackifying resin is the mixture of one or more compositions in petroleum resin, terpine resin and Gum Rosin.
Optimally, the density of described styrene isoprene styrene block copolymer (SIS) is 0.9 ~ 0.92g/cm
3, melt flow rate (MFR) is 8.5 ~ 9.5g/10min, and cinnamic mass content is 13 ~ 18%.
Further, the volume coefficient of described styrene isoprene styrene block copolymer (SIS) is 0.32 ~ 0.38, and tensile stress is 0.8 ~ 1.0Mpa, and stretching yield stress is 25 ~ 30 Mpa, and elongation at break is 1000 ~ 1500%, and apparent viscosity is 1 ~ 1.5Pas.
Optimally, described softening agent is the mixture of one or more compositions in white oil, vegetables oil, naphthenic oil, dioctyl phthalate (DOP) and Octyl adipate.
Optimally, described Nano filling is nano-calcium carbonate.
Optimally, the ash oontent≤0.1vol% of described Gum Rosin, softening temperature is 85 ~ 90 DEG C, and acid number is 7.5 ~ 8mgKOH/g.
Optimally, the softening temperature of described terpine resin is 100 ~ 130 DEG C, acid number≤5mgKOH/g, toluene insolubles content≤0.05vol%, and iodine number is 10 ~ 15, saponification value≤1.5mgKOH/g.
Optimally, the softening temperature of described C 5 hydrogenated petroleum resin and described petroleum resin is 95 ~ 105 DEG C, ash oontent≤0.02 vol%.
Another object of the present invention is the making method providing a kind of above-mentioned adhesive polymer adhesive tape, and it comprises the following steps:
A the mixing of the raw material of formula ratio is placed on and stores in glue groove by (), heating maintenance stores that glue groove temperature is 145 ~ 150 DEG C, glue spreader temperature is 130 ~ 135 DEG C makes raw materials melt, stirs subsequently;
B raw material after stirring on facing material, is cooled rear coated insulation film, then carries out cutting packing by ().
Another object of the present invention is the application providing a kind of above-mentioned adhesive polymer adhesive tape, and it comprises the following steps:
A () be adhesive polymer adhesive tape described in the paving of building node position;
B () be brushing waterproof paint on described adhesive polymer adhesive tape.
Because technique scheme is used, the present invention compared with prior art has following advantages: adhesive polymer adhesive tape of the present invention, by adding the compositions such as the first tackifying resin, the second tackifying resin, softening agent and Nano filling in styrene isoprene styrene block copolymer (SIS), the materials such as adhesive tape obtained like this and concrete, aluminium alloy and plastic-steel have excellent adhesive property, be no matter just glue, hold glue and low temperature bonding performance all better; But also there is very soft feature, easily realize at node special-shaped part docile and closely knit, various structural deformation can be adapted to.
Embodiment
Adhesive polymer adhesive tape of the present invention, with parts by weight, its composition of raw materials is as follows: styrene isoprene styrene block copolymer (SIS) (SIS rubber) 25 ~ 50 parts; 10 ~ 30 parts, softening agent; First tackifying resin 30 ~ 60 parts; Nano filling 3 ~ 10 parts; Second tackifying resin 10 ~ 20 parts; Uv-absorbing agent 0.02 ~ 0.05 part; 0.02 ~ 0.05 part, oxidation inhibitor; Described first tackifying resin is mixtures of one or both compositions in C 5 hydrogenated petroleum resin and terpine resin; Described second tackifying resin is the mixture of one or more compositions in petroleum resin, terpine resin and Gum Rosin.By adding the compositions such as the first tackifying resin, the second tackifying resin, softening agent and Nano filling in SIS rubber, and accurately can control the parts by weight of each component, like this material such as the adhesive tape and concrete, aluminium alloy and the plastic-steel that are formed of configuration have excellent adhesive property (be no matter just glue, hold glue and low temperature bonding performance all better); But also there is very soft feature, easily realize at node special-shaped part docile and closely knit, various structural deformation can be adapted to.
In the present embodiment, the density of SIS rubber is 0.9 ~ 0.92g/cm
3melt flow rate (MFR) is 8.5 ~ 9.5g/10min, and cinnamic mass content is 13 ~ 18%, and now corresponding SIS rubber has applicable molecular weight, can carry out fully miscible with other composition such as softening agent well, guarantee the stable of the homogeneous of tape compositions and quality.The further preferred volume coefficient of SIS rubber is 0.32 ~ 0.38, tensile stress is 0.8 ~ 1.0Mpa, stretching yield stress is 25 ~ 30 Mpa, elongation at break is 1000 ~ 1500%, apparent viscosity is 1 ~ 1.5Pas, thus ensures the flexible wires of adhesive tape further.Softening agent is the mixture of one or more compositions in white oil, vegetables oil, naphthenic oil, dioctyl phthalate (DOP) and Octyl adipate.Nano filling is nano-calcium carbonate, and such adhesive tape and concrete have better adhesive property.The character of above-mentioned Gum Rosin is: ash oontent≤0.1vol%(volume content), softening temperature is 85 ~ 90 DEG C, and acid number is 7.5 ~ 8mgKOH/g; The character of terpine resin is: softening temperature is 100 ~ 130 DEG C, acid number≤5mgKOH/g, toluene insolubles content≤0.05vol%, and iodine number is 10 ~ 15, saponification value≤1.5mgKOH/g; The softening temperature of C 5 hydrogenated petroleum resin and petroleum resin is 95 ~ 105 DEG C, ash oontent≤0.02 vol%, and the tape performance that these three kinds of resin-made obtain is optimum.Uv-absorbing agent can select salicylate class, benzophenone class, benzotriazole category, group-substituted acrylonitrile, triazines and hindered amines etc., and concrete model is UV-P, UV531, UV-327 etc.Oxidation inhibitor is aromatic amine, Hinered phenols etc., as 1010,168, BHT, 1076 etc.
To be described in detail to the preferred embodiment of the invention below:
Embodiment 1
The invention provides a kind of adhesive polymer adhesive tape, with parts by weight, its composition of raw materials is as follows:
(density is 0.9g/cm to SIS rubber 25 parts
3, melt flow rate (MFR) is 8.5g/10min, and cinnamic content is 13wt%, and volume coefficient is 0.32, and tensile stress is 0.8Mpa, and stretching yield stress is 25Mpa, and elongation at break is 1000%, and apparent viscosity is 1Pas); White oil 10 parts; First tackifying resin 30 parts; Nano-calcium carbonate (median size 500nm) 3 parts; Second tackifying resin 10 parts; Uv-absorbing agent UV-P 0.02 part; Antioxidant 1010 0.02 part; First tackifying resin is the mixture in C 5 hydrogenated petroleum resin and terpine resin; The softening temperature of terpine resin is 100 DEG C, and acid number is 5mgKOH/g, and toluene insolubles content is 0.05vol%, and iodine number is 10, and saponification value is 1.5mgKOH/g; The softening temperature of C 5 hydrogenated petroleum resin is 95 DEG C, and ash oontent is 0.02 vol%.Second tackifying resin is the mixture of petroleum resin, terpine resin and Gum Rosin composition, and the softening temperature of petroleum resin is 95 DEG C, and ash oontent is 0.02 vol%; The softening temperature of terpine resin is 100 DEG C, and acid number is 5mgKOH/g, and toluene insolubles content is 0.05vol%, and iodine number is 10, and saponification value is 1.5mgKOH/g; The ash oontent of Gum Rosin is 0.1vol%, and softening temperature is 85 DEG C, and acid number is 7.5KOH/g.
Preparation method is:
A the mixing of the raw material of formula ratio is placed on and stores in glue groove by (), heating maintenance stores that glue groove temperature is 145 DEG C, glue spreader temperature is 130 DEG C makes raw materials melt, subsequently with convention stir speed stirring and evenly mixing (stir and do not have much affect to the character of colloid);
B raw material after stirring (needs to check that facing material is with or without breakage by () on facing material, such as cavity, scuffing etc., prevent subsequent handling from interrupting tire, affect production efficiency), just having started gluing hourly velocity can not too soon (at about 1cm/s), Deng gluing honest and kind stable after, progressively improve speed to 2 ~ about 5cm/s; Coated insulation film after cooling, then carry out cutting packing.
Using method for: (a) be adhesive polymer adhesive tape described in the paving of building node position;
B () be brushing waterproof paint on described adhesive polymer adhesive tape.
Embodiment 2
The invention provides a kind of adhesive polymer adhesive tape, with parts by weight, its composition of raw materials is as follows:
(density is 0.9g/cm to SIS rubber 50 parts
3, melt flow rate (MFR) is 8.5g/10min, and cinnamic content is 13wt%, and volume coefficient is 0.38, and tensile stress is 1.0Mpa, and stretching yield stress is 30Mpa, and elongation at break is 1500%, and apparent viscosity is 1.5Pas); Vegetables oil and naphthenic oil totally 30 parts (vegetables oil 15 parts, naphthenic oil 15 parts); First tackifying resin 60 parts; Nano-calcium carbonate 10 parts; Second tackifying resin 20 parts; Uv-absorbing agent UV531 0.05 part; Irgasfos 168 0.05 part; First tackifying resin is C 5 hydrogenated petroleum resin; The softening temperature of C 5 hydrogenated petroleum resin is 105 DEG C, and ash oontent is 0.01 vol%.Second tackifying resin is the mixture of terpine resin and Gum Rosin composition, and the softening temperature of terpine resin is 130 DEG C, and acid number is 4mgKOH/g, and toluene insolubles content is 0.03vol%, and iodine number is 15, and saponification value is 1mgKOH/g; The ash oontent of Gum Rosin is 0.05vol%, and softening temperature is 90 DEG C, and acid number is 8KOH/g.
Preparation method is:
A the mixing of the raw material of formula ratio is placed on and stores in glue groove by (), heating maintenance stores that glue groove temperature is 150 DEG C, glue spreader temperature is 135 DEG C makes raw materials melt, subsequently with convention stir speed stirring and evenly mixing (stir and do not have much affect to the character of colloid);
B raw material after stirring (needs to check that facing material is with or without breakage by () on facing material, such as cavity, scuffing etc., prevent subsequent handling from interrupting tire, affect production efficiency), just having started gluing hourly velocity can not too soon (at about 1cm/s), Deng gluing honest and kind stable after, progressively improve speed; Coated insulation film after cooling, then carry out cutting packing.
Embodiment 3
The invention provides a kind of adhesive polymer adhesive tape, with parts by weight, its composition of raw materials is as follows:
(density is 0.91g/cm to SIS rubber 40 parts
3, melt flow rate (MFR) is 9g/10min, and cinnamic content is 15wt%, and volume coefficient is 0.35, and tensile stress is 0.9Mpa, and stretching yield stress is 28Mpa, and elongation at break is 1300%, and apparent viscosity is 1.2Pas); Dioctyl phthalate (DOP) and Octyl adipate totally 20 parts (dioctyl phthalate (DOP) 5 parts, Octyl adipate 15 parts); First tackifying resin 50 parts; Nano-calcium carbonate 5 parts; Second tackifying resin 15 parts; Uv-absorbing agent UV-327 0.05 part; Antioxidant BHT and antioxidant 1076 (their weight is identical) totally 0.05 part; First tackifying resin is terpine resin, and its softening temperature is 120 DEG C, and acid number is 4.5mgKOH/g, and toluene insolubles content is 0.04vol%, and iodine number is 12, and saponification value is 1.2mgKOH/g.Second tackifying resin is the mixture of terpine resin and Gum Rosin composition, and the softening temperature of terpine resin is 120 DEG C, and acid number is 4.5mgKOH/g, and toluene insolubles content is 0.04vol%, and iodine number is 12, and saponification value is 1.2mgKOH/g; The ash oontent of Gum Rosin is 0.08vol%, and softening temperature is 89 DEG C, and acid number is 7.8KOH/g.
Preparation method is:
A the mixing of the raw material of formula ratio is placed on and stores in glue groove by (), heating maintenance stores that glue groove temperature is 148 DEG C, glue spreader temperature is 132 DEG C makes raw materials melt, subsequently with convention stir speed stirring and evenly mixing (stir and do not have much affect to the character of colloid);
B raw material after stirring (needs to check that facing material is with or without breakage by () on facing material, such as cavity, scuffing etc., prevent subsequent handling from interrupting tire, affect production efficiency), just having started gluing hourly velocity can not too soon (at about 1cm/s), Deng gluing honest and kind stable after, progressively improve speed; Coated insulation film after cooling, then carry out cutting packing.
Above-described embodiment is only for illustrating technical conceive of the present invention and feature; its object is to person skilled in the art can be understood content of the present invention and implement according to this; can not limit the scope of the invention with this; all equivalences done according to spirit of the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (10)
1. an adhesive polymer adhesive tape, is characterized in that, with parts by weight, its composition of raw materials is as follows:
Styrene isoprene styrene block copolymer (SIS) 25 ~ 50 parts;
10 ~ 30 parts, softening agent;
First tackifying resin 30 ~ 60 parts;
Nano filling 3 ~ 10 parts;
Second tackifying resin 10 ~ 20 parts;
Uv-absorbing agent 0.02 ~ 0.05 part;
0.02 ~ 0.05 part, oxidation inhibitor;
Described first tackifying resin is mixtures of one or both compositions in C 5 hydrogenated petroleum resin and terpine resin; Described second tackifying resin is the mixture of one or more compositions in petroleum resin, terpine resin and Gum Rosin.
2. adhesive polymer adhesive tape according to claim 1, is characterized in that: the density of described styrene isoprene styrene block copolymer (SIS) is 0.9 ~ 0.92g/cm
3, melt flow rate (MFR) is 8.5 ~ 9.5g/10min, and cinnamic mass content is 13 ~ 18%.
3. adhesive polymer adhesive tape according to claim 2, it is characterized in that: the volume coefficient of described styrene isoprene styrene block copolymer (SIS) is 0.32 ~ 0.38, tensile stress is 0.8 ~ 1.0Mpa, stretching yield stress is 25 ~ 30 Mpa, elongation at break is 1000 ~ 1500%, and apparent viscosity is 1 ~ 1.5Pas.
4. adhesive polymer adhesive tape according to claim 1, is characterized in that: described softening agent is the mixture of one or more compositions in white oil, vegetables oil, naphthenic oil, dioctyl phthalate (DOP) and Octyl adipate.
5. adhesive polymer adhesive tape according to claim 1, is characterized in that: described Nano filling is nano-calcium carbonate.
6. adhesive polymer adhesive tape according to claim 1, is characterized in that: the ash oontent≤0.1vol% of described Gum Rosin, and softening temperature is 85 ~ 90 DEG C, and acid number is 7.5 ~ 8mgKOH/g.
7. adhesive polymer adhesive tape according to claim 1, is characterized in that: the softening temperature of described terpine resin is 100 ~ 130 DEG C, acid number≤5mgKOH/g, toluene insolubles content≤0.05vol%, and iodine number is 10 ~ 15, saponification value≤1.5mgKOH/g.
8. adhesive polymer adhesive tape according to claim 1, is characterized in that: the softening temperature of described C 5 hydrogenated petroleum resin and described petroleum resin is 95 ~ 105 DEG C, ash oontent≤0.02 vol%.
9. the making method of arbitrary described adhesive polymer adhesive tape in claim 1 to 8, it is characterized in that, it comprises the following steps:
A the mixing of the raw material of formula ratio is placed on and stores in glue groove by (), heating maintenance stores that glue groove temperature is 145 ~ 150 DEG C, glue spreader temperature is 130 ~ 135 DEG C makes raw materials melt, stirs subsequently;
B raw material after stirring on facing material, is cooled rear coated insulation film, then carries out cutting packing by ().
10. the application of arbitrary described adhesive polymer adhesive tape in claim 1 to 8, it is characterized in that, it comprises the following steps:
A () be adhesive polymer adhesive tape described in the paving of building node position;
B () be brushing waterproof paint on described adhesive polymer adhesive tape.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510431562.6A CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
| PCT/CN2015/097289 WO2017012256A1 (en) | 2015-07-22 | 2015-12-14 | High polymer self-adhesive tape, manufacturing method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510431562.6A CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
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| Publication Number | Publication Date |
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| CN105017984A true CN105017984A (en) | 2015-11-04 |
| CN105017984B CN105017984B (en) | 2018-08-17 |
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| CN201510431562.6A Active CN105017984B (en) | 2015-07-22 | 2015-07-22 | A kind of adhesive polymer adhesive tape, production method and its application |
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| WO (1) | WO2017012256A1 (en) |
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| CN105505096A (en) * | 2016-01-20 | 2016-04-20 | 河北豫源防水材料有限公司 | Environment-friendly non-curing water-resistant paint and preparation method thereof |
| CN106221629A (en) * | 2016-08-15 | 2016-12-14 | 江苏凯伦建材股份有限公司 | A kind of flame-retardant hot-melt pressure sensitive adhesive, its preparation method and application |
| CN106281211A (en) * | 2016-08-22 | 2017-01-04 | 重庆中防德邦防水技术有限公司 | A kind of creep reactive polymer rubber adhesive waterproof coil and preparation method |
| CN106318292A (en) * | 2016-08-31 | 2017-01-11 | 河北方大包装股份有限公司 | Removable hot-melt pressure-sensitive adhesive and preparation method |
| WO2017012256A1 (en) * | 2015-07-22 | 2017-01-26 | 江苏凯伦建材股份有限公司 | High polymer self-adhesive tape, manufacturing method and application thereof |
| CN110408341A (en) * | 2019-08-05 | 2019-11-05 | 江苏凯伦建材股份有限公司 | Macromolecule overlays waterproof roll with applying adhesive tape and its construction application |
| CN110696255A (en) * | 2019-08-22 | 2020-01-17 | 湖北三江航天红林探控有限公司 | Silicon rubber rapid pouring method for miniature fuze borderless special-shaped control plate |
| CN110761663A (en) * | 2019-09-27 | 2020-02-07 | 江苏凯伦建材股份有限公司 | Anti-leakage method for window frame |
| WO2022143062A1 (en) * | 2021-01-04 | 2022-07-07 | 江苏凯伦建材股份有限公司 | Waterproof treatment method for root of pipeline through wall or floor |
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| CN112175541B (en) * | 2020-09-16 | 2022-07-19 | 广州慧谷功能材料有限公司 | Adhesive tape capable of being removed at 90 degrees, preparation method thereof and electronic product |
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