ZA984690B - Zeolite itq 3 - Google Patents

Zeolite itq 3

Info

Publication number
ZA984690B
ZA984690B ZA984690A ZA984690A ZA984690B ZA 984690 B ZA984690 B ZA 984690B ZA 984690 A ZA984690 A ZA 984690A ZA 984690 A ZA984690 A ZA 984690A ZA 984690 B ZA984690 B ZA 984690B
Authority
ZA
South Africa
Prior art keywords
microporous
zero
preparation
equal
value lower
Prior art date
Application number
ZA984690A
Other languages
English (en)
Inventor
Avelino Corma Canos
Miguel Angel Camblor Fernandez
Luis Angel Villaescusa Alonso
Original Assignee
Consejo Superior Investigacion
Universidad Politecnica De Valencia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior Investigacion, Universidad Politecnica De Valencia filed Critical Consejo Superior Investigacion
Publication of ZA984690B publication Critical patent/ZA984690B/xx

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • B01J20/18Synthetic zeolitic molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/005Silicates, i.e. so-called metallosilicalites or metallozeosilites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/04Thermal processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00Purification; Separation; Use of additives
    • C07C7/12Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
    • C07C7/13Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/02Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
    • C10G25/03Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00Reforming naphtha
    • C10G35/04Catalytic reforming
    • C10G35/06Catalytic reforming characterised by the catalyst used
    • C10G35/095Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Saccharide Compounds (AREA)
ZA984690A 1997-05-31 1998-06-01 Zeolite itq 3 ZA984690B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES009701229A ES2135329B1 (es) 1997-05-31 1997-05-31 Zeolita itq-3.

Publications (1)

Publication Number Publication Date
ZA984690B true ZA984690B (en) 1998-12-21

Family

ID=8299583

Family Applications (1)

Application Number Title Priority Date Filing Date
ZA984690A ZA984690B (en) 1997-05-31 1998-06-01 Zeolite itq 3

Country Status (9)

Country Link
US (1) US6500404B1 (xx)
EP (1) EP1016626B1 (xx)
JP (1) JP2002511046A (xx)
AT (1) ATE206689T1 (xx)
DE (1) DE69802001T2 (xx)
DK (1) DK1016626T3 (xx)
ES (2) ES2135329B1 (xx)
WO (1) WO1998054091A1 (xx)
ZA (1) ZA984690B (xx)

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ES2156827B1 (es) * 1999-07-15 2002-03-01 Univ Valencia Politecnica Oxido acido microporoso con propiedades cataliticas. itq-18.
ES2155797B1 (es) * 1999-07-29 2001-12-01 Univ Valencia Politecnica Zeolita itq-10
KR20020055450A (ko) * 1999-12-15 2002-07-08 알. 더블류. 윌리암스 제올라이트 ssz-50
US6488741B2 (en) 2001-01-23 2002-12-03 The Trustess Of The University Of Pennsylvania Light hydrocarbon separation using 8-member ring zeolites
US6554023B2 (en) 2001-06-13 2003-04-29 Baxter International Inc. Vacuum demand flow valve
US6863261B2 (en) 2002-03-12 2005-03-08 Baxter International Inc. Valve stop
US7122500B2 (en) 2003-09-22 2006-10-17 Exxonmobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
EP1843847B1 (en) 2005-01-31 2018-06-13 ExxonMobil Chemical Patents Inc. Molecular sieve catalyst composition, its making and use in conversion processes
ES2263369B1 (es) * 2005-02-02 2007-12-16 Universidad Politecnica De Valencia Material cristalino microporoso de naturaleza zeolitica, zeolita itq-32, procedimiento de preparacion y uso.
ES2284379B1 (es) * 2006-02-28 2008-11-01 Universidad Politecnica De Valencia Un material cristalino microporoso, zeolita itq-37, procedimiento de preparacion y uso.
CA2584876A1 (en) * 2007-02-02 2008-08-02 Albemarle Netherlands Bv A crystalline microporous material of zeolitic nature
US8906138B2 (en) 2007-11-12 2014-12-09 Exxonmobil Upstream Research Company Methods of generating and utilizing utility gas
EA022697B1 (ru) 2008-04-30 2016-02-29 Эксонмобил Апстрим Рисерч Компани Способ и система избирательного удаления масла из потока газа, содержащего метан
AU2011258795B2 (en) 2010-05-28 2014-06-26 Exxonmobil Upstream Research Company Integrated adsorber head and valve design and swing adsorption methods related thereto
TWI495501B (zh) 2010-11-15 2015-08-11 Exxonmobil Upstream Res Co 動力分餾器及用於氣體混合物之分餾的循環法
EP2680954B1 (en) 2011-03-01 2018-09-12 Exxonmobil Upstream Research Company Methods of removing contaminants from a hydrocarbon stream by pressure swing adsorption and related apparatus and systems
WO2012118755A1 (en) 2011-03-01 2012-09-07 Exxonmobil Upstream Research Company Apparatus and systems having an encased adsorbent contractor and swing adsorption processes related thereto
AU2012223486A1 (en) 2011-03-01 2013-08-15 Exxonmobil Upstream Research Company Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto
EP2680947A4 (en) 2011-03-01 2015-04-29 Exxonmobil Upstream Res Co APPARATUS AND SYSTEMS HAVING MULTI-MODULATED ADSORPTION BEDS WITH COMPACT CONFIGURATION AND RELATED METHODS
US9017457B2 (en) 2011-03-01 2015-04-28 Exxonmobil Upstream Research Company Apparatus and systems having a reciprocating valve head assembly and swing adsorption processes related thereto
EA201501140A1 (ru) 2011-03-01 2016-04-29 Эксонмобил Апстрим Рисерч Компани Способы удаления загрязняющих примесей из потока углеводородов в циклическом адсорбционном процессе и связанные с этим устройства и системы
CA2842928A1 (en) 2011-03-01 2012-11-29 Exxonmobil Upstream Research Company Apparatus and systems having a rotary valve assembly and swing adsorption processes related thereto
US9034078B2 (en) 2012-09-05 2015-05-19 Exxonmobil Upstream Research Company Apparatus and systems having an adsorbent contactor and swing adsorption processes related thereto
US9675925B2 (en) 2014-07-25 2017-06-13 Exxonmobil Upstream Research Company Apparatus and system having a valve assembly and swing adsorption processes related thereto
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CN107635644A (zh) 2014-12-23 2018-01-26 埃克森美孚上游研究公司 结构化吸附床,其生产方法及其用途
WO2016186725A1 (en) 2015-05-15 2016-11-24 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes related thereto comprising mid-bed purge systems
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AU2016344415B2 (en) 2015-10-27 2019-08-22 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes related thereto having a plurality of valves
KR20180083911A (ko) 2015-11-16 2018-07-23 엑손모빌 업스트림 리서치 캄파니 흡착재 및 이산화탄소의 흡착 방법
CA3017612C (en) 2016-03-18 2021-06-22 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes related thereto
AU2017274289B2 (en) 2016-05-31 2020-02-27 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes
RU2702545C1 (ru) 2016-05-31 2019-10-08 Эксонмобил Апстрим Рисерч Компани Устройство и система для осуществления процессов циклической адсорбции
US10434458B2 (en) 2016-08-31 2019-10-08 Exxonmobil Upstream Research Company Apparatus and system for swing adsorption processes related thereto
CN109922872A (zh) 2016-09-01 2019-06-21 埃克森美孚上游研究公司 使用3a沸石结构移除水的变化吸附处理
US10328382B2 (en) 2016-09-29 2019-06-25 Exxonmobil Upstream Research Company Apparatus and system for testing swing adsorption processes
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US10597299B2 (en) 2018-06-07 2020-03-24 Chevron U.S.A. Inc. Synthesis of ITE framework type molecular sieves
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US11376545B2 (en) 2019-04-30 2022-07-05 Exxonmobil Upstream Research Company Rapid cycle adsorbent bed
KR20220042386A (ko) 2019-07-29 2022-04-05 셰브런 유.에스.에이.인크. 분자체 ssz-118, 이의 합성 및 용도
US11655910B2 (en) 2019-10-07 2023-05-23 ExxonMobil Technology and Engineering Company Adsorption processes and systems utilizing step lift control of hydraulically actuated poppet valves
EP4045173A1 (en) 2019-10-16 2022-08-24 Exxonmobil Upstream Research Company (EMHC-N1-4A-607) Dehydration processes utilizing cationic zeolite rho

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US5939044A (en) * 1996-12-31 1999-08-17 Chevron U.S.A. Inc. Zeolite SSZ-36

Also Published As

Publication number Publication date
ES2165678T3 (es) 2002-03-16
WO1998054091A1 (es) 1998-12-03
ES2135329B1 (es) 2000-05-16
DK1016626T3 (da) 2002-01-28
US6500404B1 (en) 2002-12-31
EP1016626A1 (en) 2000-07-05
JP2002511046A (ja) 2002-04-09
DE69802001D1 (de) 2001-11-15
ATE206689T1 (de) 2001-10-15
ES2135329A1 (es) 1999-10-16
DE69802001T2 (de) 2002-06-13
EP1016626B1 (en) 2001-10-10

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