ZA201305726B - Z-selective olefin metathesis catalysts and their synthetic procedure - Google Patents
Z-selective olefin metathesis catalysts and their synthetic procedureInfo
- Publication number
- ZA201305726B ZA201305726B ZA2013/05726A ZA201305726A ZA201305726B ZA 201305726 B ZA201305726 B ZA 201305726B ZA 2013/05726 A ZA2013/05726 A ZA 2013/05726A ZA 201305726 A ZA201305726 A ZA 201305726A ZA 201305726 B ZA201305726 B ZA 201305726B
- Authority
- ZA
- South Africa
- Prior art keywords
- synthetic procedure
- olefin metathesis
- metathesis catalysts
- selective olefin
- selective
- Prior art date
Links
- 238000005865 alkene metathesis reaction Methods 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2269—Heterocyclic carbenes
- B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2265—Carbenes or carbynes, i.e.(image)
- B01J31/2278—Complexes comprising two carbene ligands differing from each other, e.g. Grubbs second generation catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
- C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
- B01J2231/54—Metathesis reactions, e.g. olefin metathesis
- B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161432849P | 2011-01-14 | 2011-01-14 | |
| US201161433949P | 2011-01-18 | 2011-01-18 | |
| US201161515262P | 2011-08-04 | 2011-08-04 | |
| PCT/US2012/021609 WO2012097379A2 (en) | 2011-01-14 | 2012-01-17 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA201305726B true ZA201305726B (en) | 2018-12-19 |
Family
ID=46507707
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA2013/05726A ZA201305726B (en) | 2011-01-14 | 2013-07-29 | Z-selective olefin metathesis catalysts and their synthetic procedure |
| ZA2014/08071A ZA201408071B (en) | 2011-01-14 | 2014-11-04 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA2014/08071A ZA201408071B (en) | 2011-01-14 | 2014-11-04 | Z-selective olefin metathesis catalysts and their synthetic procedure |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9597674B2 (https=) |
| EP (1) | EP2663398B1 (https=) |
| JP (1) | JP5893646B2 (https=) |
| KR (1) | KR101835170B1 (https=) |
| CN (1) | CN103402628B (https=) |
| AU (1) | AU2012206966B2 (https=) |
| BR (1) | BR112013017938B1 (https=) |
| CA (1) | CA2824518C (https=) |
| IL (1) | IL227432A (https=) |
| PL (1) | PL2663398T3 (https=) |
| SG (1) | SG191980A1 (https=) |
| WO (1) | WO2012097379A2 (https=) |
| ZA (2) | ZA201305726B (https=) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013134192A1 (en) | 2012-03-05 | 2013-09-12 | California Institute Of Technology | Syntheses of z-olefin-containing lepidopteran insect pheromones |
| SG11201408648YA (en) | 2012-06-29 | 2015-01-29 | Apeiron Synthesis Sa | Metal complexes, their application and methods of carrying out of metathesis reaction |
| US9234985B2 (en) | 2012-08-01 | 2016-01-12 | California Institute Of Technology | Birefringent polymer brush structures formed by surface initiated ring-opening metathesis polymerization |
| WO2014022482A1 (en) | 2012-08-01 | 2014-02-06 | California Institute Of Technology | Solvent-free enyne metathesis polymerization |
| US9586981B2 (en) | 2012-12-12 | 2017-03-07 | California Institute Of Technology | Z-selective metathesis catalysts |
| US9663440B2 (en) | 2013-04-09 | 2017-05-30 | Materia, Inc. | Cross metathesis of poly-branched poly-olefins |
| US9758445B2 (en) | 2013-04-09 | 2017-09-12 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
| CA2908383A1 (en) | 2013-04-09 | 2014-10-16 | Materia, Inc. | Preparation of surfactants via cross-metathesis |
| US20160101414A1 (en) * | 2013-05-15 | 2016-04-14 | California Institute Of Technology | Highly z-selective and enantioselective ring opening/cross metathesis catalyzed by a resolved stereogenic-at-ru complex |
| PL3008078T3 (pl) | 2013-06-12 | 2019-06-28 | Trustees Of Boston College | Katalizatory do wydajnej, Z-selektywnej metatezy |
| WO2016014954A1 (en) * | 2014-07-25 | 2016-01-28 | California Institute Of Technology | Tandem z-selective metathesis / dihydroxylation |
| PL3353187T3 (pl) * | 2015-09-24 | 2021-11-22 | Umicore Ag & Co. Kg | Katalizatory metatezy olefin na bazie karbenu metalu |
| CN108368001B (zh) | 2015-12-10 | 2021-07-23 | 优美科股份公司及两合公司 | 烯烃复分解催化剂 |
| EP3528942B1 (en) * | 2016-10-19 | 2021-04-28 | Umicore Ag & Co. Kg | Synthesis and characterization of ru alkylidene complexes |
| US10320390B1 (en) | 2016-11-17 | 2019-06-11 | X Development Llc | Field programmable gate array including coupled lookup tables |
| EP3630741A1 (en) | 2017-05-30 | 2020-04-08 | Verbio Vereinigte Bioenergie AG | Methods of making olefinic e- and z-isomers |
| EP3762143A1 (en) * | 2018-03-09 | 2021-01-13 | PPG Industries Ohio Inc. | Compounds for coordinating with a metal, compositions containing such compounds, and methods of catalyzing reactions |
| JP7368381B2 (ja) | 2018-05-15 | 2023-10-24 | カリフォルニア・インスティテュート・オブ・テクノロジー | 立体保持メタセシスによるプロスタグランジンｊ天然物の全合成 |
| US11939410B2 (en) * | 2018-06-29 | 2024-03-26 | Apeiron Synthesis S.A. | Organoruthenium complexes as precatalysts for olefin metathesis |
| US20250269361A1 (en) * | 2019-07-17 | 2025-08-28 | Umicore Ag & Co. Kg | New syntheses of z-selective olefin metathesis catalysts |
| IL294790A (en) * | 2020-03-05 | 2022-09-01 | Firmenich & Cie | A process for preparing an intermediate for perfumery |
| JP2023518157A (ja) * | 2020-03-13 | 2023-04-28 | ザ ボード オブ トラスティーズ オブ ザ ユニヴァーシティー オブ イリノイ | 触媒的ヒドロシリル化のための方法 |
| CN114478166B (zh) * | 2020-10-26 | 2024-09-27 | 中国石油天然气股份有限公司 | 一种制备端烯烃的方法 |
| CN118056617A (zh) * | 2022-11-15 | 2024-05-21 | 中国石油天然气股份有限公司 | 一种用于1-己烯自歧化的负载型催化剂及其制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5312940A (en) | 1992-04-03 | 1994-05-17 | California Institute Of Technology | Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization |
| US6284852B1 (en) * | 1997-10-30 | 2001-09-04 | California Institute Of Technology | Acid activation of ruthenium metathesis catalysts and living ROMP metathesis polymerization in water |
| EP1313559B2 (en) | 2000-08-10 | 2012-10-24 | Trustees of Boston College | Recyclable metathesis catalysts |
| WO2003044060A2 (en) | 2001-11-15 | 2003-05-30 | Materia, Inc. | Chelating carbene ligand precursors and their use in the synthesis of metathesis catalysts |
| US7598330B2 (en) * | 2002-04-05 | 2009-10-06 | California Institute Of Technology | Cross-metathesis of olefins directly substituted with an electron-withdrawing group using transition metal carbene catalysts |
| EP1765839B1 (en) * | 2004-06-09 | 2017-01-25 | UTI Limited Partnership | Transition metal carbene complexes containing a cationic substituent as catalysts of olefin metathesis reactions |
| FR2878246B1 (fr) | 2004-11-23 | 2007-03-30 | Inst Francais Du Petrole | Procede de co-production d'olefines et d'esters par ethenolyse de corps gras insatures dans des liquides ioniques non-aqueux |
| RU2435778C2 (ru) | 2005-07-04 | 2011-12-10 | Заннан Сайтех Ко., Лтд. | Лиганд комплекса рутения, комплекс рутения, катализатор комплекса рутения и способы его получения и применения |
| JP5619724B2 (ja) * | 2008-04-09 | 2014-11-05 | マテリア， インコーポレイテッド | 置換された骨格を有するｎ−ヘテロ環状カルベンリガンドを有するルテニウムオレフィン複分解触媒 |
| EP2255877B1 (en) | 2009-05-07 | 2014-09-24 | Umicore AG & Co. KG | Method for preparation of ruthenium-based metathesis catalysts with chelating alkylidene ligands |
-
2012
- 2012-01-17 AU AU2012206966A patent/AU2012206966B2/en not_active Ceased
- 2012-01-17 CA CA2824518A patent/CA2824518C/en not_active Expired - Fee Related
- 2012-01-17 CN CN201280010878.2A patent/CN103402628B/zh active Active
- 2012-01-17 US US13/978,940 patent/US9597674B2/en active Active
- 2012-01-17 PL PL12734668T patent/PL2663398T3/pl unknown
- 2012-01-17 BR BR112013017938-4A patent/BR112013017938B1/pt active IP Right Grant
- 2012-01-17 JP JP2013549616A patent/JP5893646B2/ja not_active Expired - Fee Related
- 2012-01-17 EP EP12734668.2A patent/EP2663398B1/en active Active
- 2012-01-17 WO PCT/US2012/021609 patent/WO2012097379A2/en not_active Ceased
- 2012-01-17 SG SG2013054085A patent/SG191980A1/en unknown
- 2012-01-17 KR KR1020137021063A patent/KR101835170B1/ko not_active Expired - Fee Related
-
2013
- 2013-07-11 IL IL227432A patent/IL227432A/en active IP Right Grant
- 2013-07-29 ZA ZA2013/05726A patent/ZA201305726B/en unknown
-
2014
- 2014-11-04 ZA ZA2014/08071A patent/ZA201408071B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| SG191980A1 (en) | 2013-08-30 |
| BR112013017938B1 (pt) | 2019-10-15 |
| CN103402628A (zh) | 2013-11-20 |
| WO2012097379A3 (en) | 2012-10-11 |
| EP2663398A4 (en) | 2014-07-23 |
| CA2824518A1 (en) | 2012-07-19 |
| JP2014503356A (ja) | 2014-02-13 |
| CN103402628B (zh) | 2015-12-23 |
| IL227432A (en) | 2017-12-31 |
| AU2012206966B2 (en) | 2016-11-17 |
| CA2824518C (en) | 2019-03-26 |
| EP2663398B1 (en) | 2018-07-18 |
| WO2012097379A2 (en) | 2012-07-19 |
| BR112013017938A2 (pt) | 2018-11-27 |
| KR101835170B1 (ko) | 2018-03-06 |
| JP5893646B2 (ja) | 2016-03-23 |
| KR20140021995A (ko) | 2014-02-21 |
| US9597674B2 (en) | 2017-03-21 |
| IL227432A0 (en) | 2013-09-30 |
| US20140106960A1 (en) | 2014-04-17 |
| PL2663398T3 (pl) | 2019-01-31 |
| EP2663398A2 (en) | 2013-11-20 |
| ZA201408071B (en) | 2019-06-26 |
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