ZA200610495B - Oligomerisation of olefinic compounds in an aliphatic medium - Google Patents
Oligomerisation of olefinic compounds in an aliphatic mediumInfo
- Publication number
- ZA200610495B ZA200610495B ZA200610495A ZA200610495A ZA200610495B ZA 200610495 B ZA200610495 B ZA 200610495B ZA 200610495 A ZA200610495 A ZA 200610495A ZA 200610495 A ZA200610495 A ZA 200610495A ZA 200610495 B ZA200610495 B ZA 200610495B
- Authority
- ZA
- South Africa
- Prior art keywords
- oligomerisation
- olefinic compounds
- aliphatic medium
- aliphatic
- medium
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
- B01J31/188—Amide derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
- B01J2531/62—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/24—Phosphines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200610495A ZA200610495B (en) | 2004-06-18 | 2006-12-14 | Oligomerisation of olefinic compounds in an aliphatic medium |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ZA200404841 | 2004-06-18 | ||
| ZA200610495A ZA200610495B (en) | 2004-06-18 | 2006-12-14 | Oligomerisation of olefinic compounds in an aliphatic medium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200610495B true ZA200610495B (en) | 2008-08-27 |
Family
ID=35241333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200610495A ZA200610495B (en) | 2004-06-18 | 2006-12-14 | Oligomerisation of olefinic compounds in an aliphatic medium |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7964763B2 (xx) |
| EP (1) | EP1756024B1 (xx) |
| CN (1) | CN101052605B (xx) |
| BR (1) | BRPI0511007B1 (xx) |
| CA (1) | CA2570054C (xx) |
| ES (1) | ES2695001T3 (xx) |
| MY (1) | MY145458A (xx) |
| WO (1) | WO2005123633A1 (xx) |
| ZA (1) | ZA200610495B (xx) |
Families Citing this family (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7273959B2 (en) | 2003-10-10 | 2007-09-25 | Shell Oil Company | Catalytic trimerization of olefinic monomers |
| US7259123B2 (en) | 2005-04-08 | 2007-08-21 | Shell Oil Company | Catalytic trimerization and tetramerization of olefinic monomers |
| CA2612214C (en) | 2005-07-12 | 2013-04-16 | Sasol Technology (Pty) Limited | Oligomerisation of olefinic compounds in the presence of a diluted metal containing activator |
| WO2008004986A1 (en) * | 2006-07-05 | 2008-01-10 | National University Of Singapore | Catalyst system for oligomerization of olefins |
| US7378537B2 (en) * | 2006-07-25 | 2008-05-27 | Chevron Phillips Chemical Company Lp | Olefin oligomerization catalysts and methods of using same |
| KR101074202B1 (ko) * | 2007-01-18 | 2011-10-14 | 에스케이종합화학 주식회사 | 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법 |
| KR101057576B1 (ko) * | 2007-08-16 | 2011-08-17 | 에스케이종합화학 주식회사 | 선택적 에틸렌 올리머고화 촉매계 |
| CN102307662B (zh) | 2009-02-16 | 2016-03-02 | Sasol技术股份有限公司 | 在活化的低聚催化剂存在下烯属化合物的低聚 |
| KR101809226B1 (ko) | 2009-10-16 | 2017-12-14 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 에틸렌을 포함하는 다성분 탄화수소 스트림으로부터 성분들의 분리 |
| KR101641545B1 (ko) | 2009-10-19 | 2016-07-21 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 폴리머 형성이 감소된 올레핀 화합물의 올리고머화 |
| US8680003B2 (en) | 2009-12-31 | 2014-03-25 | Chevron Phillips Chemical Company Lp | Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
| CA2737713C (en) * | 2011-04-20 | 2018-10-30 | Nova Chemicals Corporation | Activation for oligomerization |
| CA2747501C (en) * | 2011-07-26 | 2018-01-23 | Nova Chemicals Corporation | "bulk" ethylene oligomerization |
| KR102074753B1 (ko) | 2012-05-09 | 2020-02-07 | 사솔 테크날러지 (프로프라이어터리) 리미티드 | 적어도 하나의 공단량체 생성물을 형성하기 위한 탄화수소 올리고머화 방법 |
| SG11201407140SA (en) | 2012-05-09 | 2014-11-27 | Sasol Tech Pty Ltd | Oligomerisation of olefinic compounds with reduced polymer formation |
| ES2607135T3 (es) | 2012-05-09 | 2017-03-29 | Sasol Technology (Proprietary) Limited | Separación de componentes de una corriente de hidrocarburo multi-componente |
| US8865610B2 (en) | 2012-06-06 | 2014-10-21 | Chevron Phillips Chemical Company Lp | Phosphinyl guanidine compounds, metal salt complexes, catalyst systems, and their use to oligomerize or polymerize olefins |
| EP3013474A1 (fr) * | 2013-06-28 | 2016-05-04 | IFP Énergies nouvelles | Nouvelle composition catalytique à base de nickel et son utilisation dans un procede d'oligomerisation des olefines |
| KR101638980B1 (ko) * | 2013-09-30 | 2016-07-12 | 주식회사 엘지화학 | 리간드 화합물, 유기크롬 화합물, 에틸렌 올리고머화용 촉매 시스템, 및 이를 이용한 에틸렌 올리고머화 방법 |
| KR20150058034A (ko) | 2013-11-18 | 2015-05-28 | 주식회사 엘지화학 | 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 |
| CA2837590C (en) | 2013-12-23 | 2020-12-15 | Nova Chemicals Corporation | Continuous ethylene oligomerization with in-situ catalyst preparation |
| US9175109B1 (en) | 2014-05-20 | 2015-11-03 | Chevron Phillips Chemical Company Lp | Oligomerization processes and polymer compositions produced therefrom |
| EP3101039B1 (en) | 2014-06-18 | 2019-07-31 | LG Chem, Ltd. | Ligand compound, organic chrome compound, catalyst system for olefin oligomerization, and method for oligomerizing olefin using same |
| KR101757369B1 (ko) | 2014-12-11 | 2017-07-12 | 주식회사 엘지화학 | 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
| DE102015200702A1 (de) | 2015-01-19 | 2016-07-21 | Evonik Degussa Gmbh | Herstellung von Butadien aus Ethen |
| MX369759B (es) | 2015-01-19 | 2019-11-20 | Evonik Operations Gmbh | Preparación combinada de buteno y octeno a partir de eteno. |
| ES2660618T3 (es) | 2015-01-19 | 2018-03-23 | Evonik Degussa Gmbh | Preparación combinada de al menos buteno y octeno a partir de eteno |
| US9505675B2 (en) | 2015-02-09 | 2016-11-29 | Chevron Phillips Chemical Company Lp | Deactivation of a process by-product |
| BR112017019416B1 (pt) | 2015-03-13 | 2023-05-02 | Dow Global Technologies Llc | Composição e processo para preparar uma composição |
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| KR101757370B1 (ko) | 2015-06-01 | 2017-07-12 | 주식회사 엘지화학 | 1-옥텐 조성물 |
| KR101757835B1 (ko) * | 2015-06-12 | 2017-07-13 | 주식회사 엘지화학 | 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
| EP3310476B1 (en) | 2015-06-19 | 2019-09-18 | Saudi Arabian Oil Company | Antifouling oligomerization catalyst systems |
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| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
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| US10519077B2 (en) | 2015-09-18 | 2019-12-31 | Chevron Phillips Chemical Company Lp | Ethylene oligomerization/trimerization/tetramerization reactor |
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| KR101761830B1 (ko) | 2015-10-21 | 2017-07-26 | 주식회사 엘지화학 | 리간드 화합물, 올레핀 올리고머화용 촉매계, 및 이를 이용한 올레핀 올리고머화 방법 |
| KR101982789B1 (ko) | 2015-12-04 | 2019-05-27 | 주식회사 엘지화학 | 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법 |
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| US10294171B2 (en) | 2017-09-22 | 2019-05-21 | Chevron Phillips Chemical Company Lp | Carbonyl-containing perfluorohydrocarbyl-N2-phosphinyl amidine compounds, chromium salt complexes and their use to oligomerize ethylene |
| US10464862B2 (en) | 2017-09-28 | 2019-11-05 | Chevron Phillips Chemical Company Lp | Oligomerization reactions using aluminoxanes |
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| WO2022115749A1 (en) | 2020-11-30 | 2022-06-02 | Saudi Arabian Oil Company | Catalyst systems |
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|---|---|---|---|---|
| US3635937A (en) | 1969-11-05 | 1972-01-18 | Shell Oil Co | Ethylene polymerization |
| US3676523A (en) | 1971-07-16 | 1972-07-11 | Shell Oil Co | Alpha-olefin production |
| US3906053A (en) | 1971-08-10 | 1975-09-16 | Ethyl Corp | Process for the production of olefins |
| DE3480845D1 (de) * | 1983-04-06 | 1990-02-01 | Shell Int Research | Verfahren zur herstellung von polyketonen. |
| US6096676A (en) * | 1997-07-02 | 2000-08-01 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6184428B1 (en) | 1998-04-22 | 2001-02-06 | Saudi Basic Industries Corporation | Catalyst and process for ethylene oligomerization |
| US6137012A (en) * | 1998-10-13 | 2000-10-24 | E. I. Du Pont De Nemours And Company | Phosphole and diphosphole ligands for catalysis |
| GB0016895D0 (en) * | 2000-07-11 | 2000-08-30 | Bp Chem Int Ltd | Olefin oligomerisation |
| US7223893B2 (en) | 2000-09-12 | 2007-05-29 | Chevron Phillips Chemical Company Lp | Linear alpha-olefin dimers possessing substantial linearity |
| WO2003053891A1 (en) * | 2001-12-20 | 2003-07-03 | Sasol Technology (Pty) Ltd. | Trimerisation and oligomerisation of olefins using a chromium based catalyst |
| US7300904B2 (en) * | 2001-12-20 | 2007-11-27 | Sasol Technology (Pty) Ltd. | Trimerisation and oligomerisation of olefins using a chromium based catalyst |
| BR0317510A (pt) | 2002-12-20 | 2005-11-16 | Sasol Tech Pty Ltd | Tetramerização de olefinas |
-
2005
- 2005-06-13 BR BRPI0511007-6A patent/BRPI0511007B1/pt active IP Right Grant
- 2005-06-13 CN CN2005800259458A patent/CN101052605B/zh active Active
- 2005-06-13 CA CA2570054A patent/CA2570054C/en active Active
- 2005-06-13 ES ES05746315.0T patent/ES2695001T3/es active Active
- 2005-06-13 EP EP05746315.0A patent/EP1756024B1/en active Active
- 2005-06-13 US US11/629,533 patent/US7964763B2/en active Active
- 2005-06-13 WO PCT/IB2005/051940 patent/WO2005123633A1/en active Application Filing
- 2005-06-16 MY MYPI20052754A patent/MY145458A/en unknown
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2006
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| Publication number | Publication date |
|---|---|
| WO2005123633A1 (en) | 2005-12-29 |
| CN101052605A (zh) | 2007-10-10 |
| US20110086991A1 (en) | 2011-04-14 |
| MY145458A (en) | 2012-02-15 |
| US7964763B2 (en) | 2011-06-21 |
| CA2570054A1 (en) | 2005-12-29 |
| CA2570054C (en) | 2012-10-02 |
| BRPI0511007B1 (pt) | 2021-03-16 |
| ES2695001T3 (es) | 2018-12-28 |
| EP1756024B1 (en) | 2018-08-15 |
| CN101052605B (zh) | 2011-12-21 |
| EP1756024A1 (en) | 2007-02-28 |
| BRPI0511007A (pt) | 2007-11-27 |
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