ZA200507926B - Process for the preparation of a hydrogen-rich stream - Google Patents
Process for the preparation of a hydrogen-rich stream Download PDFInfo
- Publication number
- ZA200507926B ZA200507926B ZA200507926A ZA200507926A ZA200507926B ZA 200507926 B ZA200507926 B ZA 200507926B ZA 200507926 A ZA200507926 A ZA 200507926A ZA 200507926 A ZA200507926 A ZA 200507926A ZA 200507926 B ZA200507926 B ZA 200507926B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- shift
- hydrogen
- dimethyl ether
- methanol
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 42
- 230000008569 process Effects 0.000 title claims description 40
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 29
- 239000001257 hydrogen Substances 0.000 title claims description 29
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 26
- 238000002360 preparation method Methods 0.000 title claims description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 98
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims description 65
- 239000003054 catalyst Substances 0.000 claims description 54
- 239000007789 gas Substances 0.000 claims description 34
- 238000006703 hydration reaction Methods 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 230000036571 hydration Effects 0.000 claims description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 8
- 238000000354 decomposition reaction Methods 0.000 claims description 8
- 238000002407 reforming Methods 0.000 claims description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 239000011973 solid acid Substances 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 206010037660 Pyrexia Diseases 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 229940105305 carbon monoxide Drugs 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 25
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 10
- 238000003786 synthesis reaction Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000629 steam reforming Methods 0.000 description 7
- 239000000446 fuel Substances 0.000 description 6
- 229940108928 copper Drugs 0.000 description 5
- 239000003345 natural gas Substances 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 235000012721 chromium Nutrition 0.000 description 3
- 229940107218 chromium Drugs 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 239000010457 zeolite Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011949 solid catalyst Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- QUQFTIVBFKLPCL-UHFFFAOYSA-L copper;2-amino-3-[(2-amino-2-carboxylatoethyl)disulfanyl]propanoate Chemical compound [Cu+2].[O-]C(=O)C(N)CSSCC(N)C([O-])=O QUQFTIVBFKLPCL-UHFFFAOYSA-L 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000004449 solid propellant Substances 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 238000011144 upstream manufacturing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
- C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
- C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
- C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
- C01B2203/143—Three or more reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DKPA200300499 | 2003-04-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200507926B true ZA200507926B (en) | 2006-12-27 |
Family
ID=33104008
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200507925A ZA200507925B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
| ZA200507926A ZA200507926B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200507925A ZA200507925B (en) | 2003-04-01 | 2004-03-25 | Process for the preparation of a hydrogen-rich stream |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US7527781B2 (fr) |
| EP (1) | EP1613553A1 (fr) |
| JP (1) | JP2006521989A (fr) |
| KR (1) | KR20060002903A (fr) |
| CN (2) | CN1331731C (fr) |
| AU (1) | AU2004226236A1 (fr) |
| CA (1) | CA2520988A1 (fr) |
| MX (1) | MXPA05010538A (fr) |
| RU (1) | RU2005133161A (fr) |
| WO (1) | WO2004087567A1 (fr) |
| ZA (2) | ZA200507925B (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0406779B1 (pt) * | 2003-11-17 | 2013-05-28 | processo para a preparaÇço de urÉia. | |
| CA2496839A1 (fr) | 2004-07-19 | 2006-01-19 | Woodland Chemical Systems Inc. | Methode de production d'ethanol a partir de gaz de synthese a teneur elevee en monoxyde de carbone |
| US7947251B2 (en) * | 2005-06-15 | 2011-05-24 | The Ohio State University Research Foundation | Catalyst for hydrogen production from water gas shift reaction |
| AU2007235322A1 (en) * | 2006-04-05 | 2007-10-18 | Woodland Biofuels Inc. | System and method for converting biomass to ethanol via syngas |
| CN101177240B (zh) * | 2007-11-09 | 2010-04-07 | 清华大学 | 一种集成式二甲醚水蒸气重整制氢装置及方法 |
| JP2011507666A (ja) * | 2007-12-26 | 2011-03-10 | ネルコー ピューリタン ベネット エルエルシー | 生理学的パラメーターに対する履歴傾向アイコン |
| GB0914500D0 (en) * | 2009-08-19 | 2009-09-30 | Johnson Matthey Plc | Process |
| DE102013104893A1 (de) * | 2013-05-13 | 2014-11-13 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur Inbetriebnahme einer Vorreformierungsstufe |
| EP3647264B1 (fr) * | 2018-10-31 | 2023-10-11 | L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude | Procédé et installation de production d'un gaz de synthèse épuré et converti |
| CN112960645B (zh) * | 2019-12-14 | 2022-08-05 | 中国科学院大连化学物理研究所 | 一种自热重整制氢反应用水汽变换反应器及提高水汽变换反应co转化率的方法 |
| CN110980642B (zh) * | 2019-12-30 | 2021-12-24 | 北京蓝玖新能源科技有限公司 | 一种制氢设备及其工艺和应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4091086A (en) * | 1976-12-20 | 1978-05-23 | Engelhard Minerals & Chemicals Corporation | Process for production of hydrogen |
| DK147705C (da) * | 1982-09-07 | 1985-05-13 | Haldor Topsoe As | Fremgangsmaade til fremstilling af carbonhydrider ud fra syntesegas |
| JPS59203702A (ja) * | 1983-05-04 | 1984-11-17 | Mitsubishi Heavy Ind Ltd | 水素の製造法 |
| JP3020984B2 (ja) * | 1990-03-02 | 2000-03-15 | 株式会社東芝 | 燃料電池発電装置 |
| JP2755804B2 (ja) * | 1990-08-27 | 1998-05-25 | 株式会社東芝 | 水素製造方法 |
| US5830425A (en) * | 1993-02-09 | 1998-11-03 | Sud-Chemie Ag | Chromium-free catalyst based on iron oxide for conversion of carbon monoxide |
| US5498370A (en) * | 1994-12-15 | 1996-03-12 | Amoco Corporation | Process for hydroshifting dimethyl ether |
| US5990040A (en) * | 1995-01-11 | 1999-11-23 | United Catalysts Inc. | Promoted and stabilized copper oxide and zinc oxide catalyst and preparation |
| DK173416B1 (da) * | 1995-07-21 | 2000-10-02 | Topsoe Haldor As | Fremgangsmåde til fremstilling af hydrogenrig gas |
| GB9820608D0 (en) * | 1998-09-23 | 1998-11-11 | Ici Plc | Hydrogen |
| JP2000143209A (ja) * | 1998-11-05 | 2000-05-23 | Idemitsu Kosan Co Ltd | 一酸化炭素の転化方法および触媒 |
| DE10010069A1 (de) * | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Verfahren zum Betreiben einer Gaserzeugungsvorrichtung bzw. eines Brennstoffzellensystems, Gaserzeugungsvorrichtung und Brennstoffzellensystem |
| DE10010070A1 (de) * | 2000-03-02 | 2001-09-20 | Xcellsis Gmbh | Gaserzeugungsvorrichtung |
| JP3496051B2 (ja) * | 2000-06-07 | 2004-02-09 | 独立行政法人産業技術総合研究所 | メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法 |
| DE10059674A1 (de) * | 2000-12-01 | 2002-06-20 | Xcellsis Gmbh | Brennstoffzellensystem |
| DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
| DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
| JP2003010685A (ja) * | 2001-06-27 | 2003-01-14 | Nkk Corp | 水素製造触媒およびその製造方法ならびに水素を製造する方法 |
| JP4175452B2 (ja) * | 2001-08-07 | 2008-11-05 | 三菱重工業株式会社 | ジメチルエーテル改質触媒およびジメチルエーテル改質方法 |
-
2004
- 2004-03-25 CN CNB2004800088271A patent/CN1331731C/zh not_active Expired - Fee Related
- 2004-03-25 ZA ZA200507925A patent/ZA200507925B/en unknown
- 2004-03-25 WO PCT/EP2004/003159 patent/WO2004087567A1/fr not_active Application Discontinuation
- 2004-03-25 AU AU2004226236A patent/AU2004226236A1/en not_active Abandoned
- 2004-03-25 ZA ZA200507926A patent/ZA200507926B/en unknown
- 2004-03-25 US US10/548,802 patent/US7527781B2/en active Active
- 2004-03-25 RU RU2005133161/15A patent/RU2005133161A/ru not_active Application Discontinuation
- 2004-03-25 EP EP04723209A patent/EP1613553A1/fr not_active Withdrawn
- 2004-03-25 KR KR1020057018604A patent/KR20060002903A/ko not_active Application Discontinuation
- 2004-03-25 CN CNA2004800090248A patent/CN1856441A/zh active Pending
- 2004-03-25 CA CA002520988A patent/CA2520988A1/fr not_active Abandoned
- 2004-03-25 MX MXPA05010538A patent/MXPA05010538A/es active IP Right Grant
- 2004-03-25 JP JP2006504860A patent/JP2006521989A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200507925B (en) | 2006-12-27 |
| KR20060002903A (ko) | 2006-01-09 |
| EP1613553A1 (fr) | 2006-01-11 |
| US7527781B2 (en) | 2009-05-05 |
| MXPA05010538A (es) | 2005-11-23 |
| JP2006521989A (ja) | 2006-09-28 |
| CN1331731C (zh) | 2007-08-15 |
| CA2520988A1 (fr) | 2004-10-14 |
| CN1768004A (zh) | 2006-05-03 |
| WO2004087567A1 (fr) | 2004-10-14 |
| AU2004226236A1 (en) | 2004-10-14 |
| US20060165589A1 (en) | 2006-07-27 |
| CN1856441A (zh) | 2006-11-01 |
| RU2005133161A (ru) | 2006-04-27 |
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