ZA200507892B - Configurations and methods of carbon capture - Google Patents
Configurations and methods of carbon capture Download PDFInfo
- Publication number
- ZA200507892B ZA200507892B ZA200507892A ZA200507892A ZA200507892B ZA 200507892 B ZA200507892 B ZA 200507892B ZA 200507892 A ZA200507892 A ZA 200507892A ZA 200507892 A ZA200507892 A ZA 200507892A ZA 200507892 B ZA200507892 B ZA 200507892B
- Authority
- ZA
- South Africa
- Prior art keywords
- carbon dioxide
- plant
- hydrogen
- gas
- unit
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 43
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title description 5
- 229910052799 carbon Inorganic materials 0.000 title description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 176
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 claims description 104
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 88
- 239000001569 carbon dioxide Substances 0.000 claims description 81
- 239000007789 gas Substances 0.000 claims description 72
- 239000001257 hydrogen Substances 0.000 claims description 44
- 229910052739 hydrogen Inorganic materials 0.000 claims description 44
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 41
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 32
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 29
- 239000006096 absorbing agent Substances 0.000 claims description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 21
- 238000002485 combustion reaction Methods 0.000 claims description 21
- 229910052717 sulfur Inorganic materials 0.000 claims description 21
- 239000011593 sulfur Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 16
- 239000012528 membrane Substances 0.000 claims description 13
- 239000002274 desiccant Substances 0.000 claims description 11
- 238000001179 sorption measurement Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910001868 water Inorganic materials 0.000 claims description 9
- 238000011144 upstream manufacturing Methods 0.000 claims description 4
- 238000012545 processing Methods 0.000 claims description 3
- 241000196324 Embryophyta Species 0.000 description 19
- 238000011084 recovery Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 9
- 238000005262 decarbonization Methods 0.000 description 9
- 239000003546 flue gas Substances 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 7
- 239000012466 permeate Substances 0.000 description 7
- 238000002309 gasification Methods 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- 239000007790 solid phase Substances 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 description 2
- 150000001412 amines Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- PVXVWWANJIWJOO-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-N-ethylpropan-2-amine Chemical compound CCNC(C)CC1=CC=C2OCOC2=C1 PVXVWWANJIWJOO-UHFFFAOYSA-N 0.000 description 1
- 235000009027 Amelanchier alnifolia Nutrition 0.000 description 1
- 244000068687 Amelanchier alnifolia Species 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 1
- QMMZSJPSPRTHGB-UHFFFAOYSA-N MDEA Natural products CC(C)CCCCC=CCC=CC(O)=O QMMZSJPSPRTHGB-UHFFFAOYSA-N 0.000 description 1
- 241000282485 Vulpes vulpes Species 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 239000005417 food ingredient Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/06—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation
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- F25J3/067—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by partial condensation characterised by the separated product stream separation of carbon dioxide
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- B01D53/002—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by condensation
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- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
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- B01D53/526—Mixtures of hydrogen sulfide and carbon dioxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8612—Hydrogen sulfide
- B01D53/8615—Mixtures of hydrogen sulfide and sulfur oxides
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- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
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- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
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EP2023066A1 (en) * | 2007-07-25 | 2009-02-11 | BP Alternative Energy Holdings Limited | Separation of carbon dioxide and hydrogen |
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JP5473934B2 (ja) | 2007-11-27 | 2014-04-16 | アルストム テクノロジー リミテッド | 水素を多く含む第二の燃料を用いてガスタービン設備を動作させる装置及び方法 |
US8980211B2 (en) | 2008-03-01 | 2015-03-17 | Bryan Christopher Timmins | Method for the capture and disposal of carbon dioxide in an energy conversion process |
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EP2149769A1 (en) * | 2008-07-31 | 2010-02-03 | BP Alternative Energy International Limited | Separation of carbon dioxide and hydrogen |
WO2010043859A1 (en) * | 2008-10-14 | 2010-04-22 | Cyril Timmins | High pressure physical absorption process for use in carbon capture in energy production processes |
EP2196251A1 (de) * | 2008-12-04 | 2010-06-16 | Siemens Aktiengesellschaft | Kohlendioxid-Abtrennanlage und Verfahren zum Betrieb einer solchen Anlage |
CN102422108A (zh) * | 2009-03-09 | 2012-04-18 | 英国备选能源国际有限公司 | 二氧化碳与氢气的分离 |
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US20110020188A1 (en) * | 2009-07-24 | 2011-01-27 | General Electric Company | Igcc with constant pressure sulfur removal system for carbon capture with co2 selective membranes |
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WO2011018620A2 (en) * | 2009-08-12 | 2011-02-17 | Bp Alternative Energy International Limited | Separation of carbon dioxide from a mixture of gases |
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US9851143B2 (en) * | 2010-07-02 | 2017-12-26 | Union Engineering A/S | High pressure recovery of carbon dioxide from a fermentation process |
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US8268044B2 (en) | 2010-07-13 | 2012-09-18 | Air Products And Chemicals, Inc. | Separation of a sour syngas stream |
US8535638B2 (en) | 2010-11-11 | 2013-09-17 | Air Liquide Large Industries U.S. | Process for recovering hydrogen and carbon dioxide |
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US20120292574A1 (en) * | 2011-05-18 | 2012-11-22 | Air Liquide Large Industries U.S. Lp | Process For The Production Of Hydrogen And Carbon Dioxide |
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-
2004
- 2004-04-02 US US10/550,054 patent/US20060260189A1/en not_active Abandoned
- 2004-04-02 EP EP04749689.8A patent/EP1608445B1/en not_active Expired - Lifetime
- 2004-04-02 JP JP2006509645A patent/JP4317213B2/ja not_active Expired - Fee Related
- 2004-04-02 ES ES04749689T patent/ES2433717T3/es not_active Expired - Lifetime
- 2004-04-02 DK DK04749689.8T patent/DK1608445T3/da active
- 2004-04-02 CA CA002521010A patent/CA2521010C/en not_active Expired - Fee Related
- 2004-04-02 PL PL04749689T patent/PL1608445T3/pl unknown
- 2004-04-02 WO PCT/US2004/010248 patent/WO2004089499A2/en active IP Right Grant
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2005
- 2005-09-28 NO NO20054492A patent/NO338729B1/no not_active IP Right Cessation
- 2005-09-29 ZA ZA200507892A patent/ZA200507892B/en unknown
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2010
- 2010-11-05 US US12/940,305 patent/US8557024B2/en not_active Expired - Fee Related
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CA2521010C (en) | 2010-01-19 |
WO2004089499A3 (en) | 2006-02-09 |
NO20054492D0 (no) | 2005-09-28 |
US20110271714A1 (en) | 2011-11-10 |
US8557024B2 (en) | 2013-10-15 |
ES2433717T3 (es) | 2013-12-12 |
AU2004228010B2 (en) | 2007-03-29 |
PL1608445T3 (pl) | 2014-02-28 |
JP2006522004A (ja) | 2006-09-28 |
EP1608445A2 (en) | 2005-12-28 |
US20060260189A1 (en) | 2006-11-23 |
NO20054492L (no) | 2005-11-01 |
NO338729B1 (no) | 2016-10-10 |
EP1608445A4 (en) | 2009-06-10 |
WO2004089499A2 (en) | 2004-10-21 |
JP4317213B2 (ja) | 2009-08-19 |
EP1608445B1 (en) | 2013-07-03 |
CA2521010A1 (en) | 2004-10-21 |
DK1608445T3 (da) | 2013-09-30 |
AU2004228010A1 (en) | 2004-10-21 |
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