ZA200405830B - Production of olefins. - Google Patents
Production of olefins. Download PDFInfo
- Publication number
- ZA200405830B ZA200405830B ZA200405830A ZA200405830A ZA200405830B ZA 200405830 B ZA200405830 B ZA 200405830B ZA 200405830 A ZA200405830 A ZA 200405830A ZA 200405830 A ZA200405830 A ZA 200405830A ZA 200405830 B ZA200405830 B ZA 200405830B
- Authority
- ZA
- South Africa
- Prior art keywords
- process according
- energy
- anyone
- gas
- hydrocarbon feed
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 150000001336 alkenes Chemical class 0.000 title description 11
- 238000000034 method Methods 0.000 claims description 59
- 239000007789 gas Substances 0.000 claims description 46
- 239000003054 catalyst Substances 0.000 claims description 33
- 229930195733 hydrocarbon Natural products 0.000 claims description 30
- 150000002430 hydrocarbons Chemical class 0.000 claims description 30
- 239000000446 fuel Substances 0.000 claims description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 19
- 238000000926 separation method Methods 0.000 claims description 19
- 238000002485 combustion reaction Methods 0.000 claims description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 14
- 239000001301 oxygen Substances 0.000 claims description 14
- 229910052760 oxygen Inorganic materials 0.000 claims description 14
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 7
- 229910001882 dioxygen Inorganic materials 0.000 claims description 7
- 230000005611 electricity Effects 0.000 claims description 7
- 238000007906 compression Methods 0.000 claims description 6
- 230000006835 compression Effects 0.000 claims description 6
- 239000012188 paraffin wax Substances 0.000 claims description 6
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 150000005673 monoalkenes Chemical class 0.000 claims description 4
- 239000002737 fuel gas Substances 0.000 claims description 3
- 239000001273 butane Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000001294 propane Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 description 29
- 239000002184 metal Substances 0.000 description 29
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 28
- 238000005336 cracking Methods 0.000 description 27
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 22
- 239000000047 product Substances 0.000 description 17
- 229910052697 platinum Inorganic materials 0.000 description 16
- 229910052763 palladium Inorganic materials 0.000 description 12
- 229910052723 transition metal Inorganic materials 0.000 description 12
- 150000003624 transition metals Chemical class 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 10
- 238000004230 steam cracking Methods 0.000 description 10
- 239000010949 copper Substances 0.000 description 9
- 229910052703 rhodium Inorganic materials 0.000 description 9
- 239000010948 rhodium Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 239000000919 ceramic Substances 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 239000005431 greenhouse gas Substances 0.000 description 6
- 238000010791 quenching Methods 0.000 description 6
- 229910052718 tin Inorganic materials 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 4
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- -1 ethylene, propylene Chemical group 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 229910052733 gallium Inorganic materials 0.000 description 3
- 229910052732 germanium Inorganic materials 0.000 description 3
- 238000005470 impregnation Methods 0.000 description 3
- 229910052741 iridium Inorganic materials 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
- 229910052707 ruthenium Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000502 Li-aluminosilicate Inorganic materials 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 229910052762 osmium Inorganic materials 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005235 decoking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002534 ethynyl group Chemical class [H]C#C* 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 238000005839 oxidative dehydrogenation reaction Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/20—C2-C4 olefins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0204140.8A GB0204140D0 (en) | 2002-02-22 | 2002-02-22 | Production of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200405830B true ZA200405830B (en) | 2005-09-27 |
Family
ID=9931529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200405830A ZA200405830B (en) | 2002-02-22 | 2004-07-21 | Production of olefins. |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7244872B2 (fr) |
| EP (1) | EP1476410A1 (fr) |
| JP (1) | JP2005517729A (fr) |
| KR (1) | KR20040095224A (fr) |
| CN (1) | CN1315762C (fr) |
| AR (1) | AR038589A1 (fr) |
| AU (1) | AU2003246826B2 (fr) |
| BR (1) | BR0307867A (fr) |
| CA (1) | CA2474656A1 (fr) |
| CO (1) | CO5611193A2 (fr) |
| EA (1) | EA006723B1 (fr) |
| EG (1) | EG23393A (fr) |
| GB (1) | GB0204140D0 (fr) |
| MX (1) | MXPA04007780A (fr) |
| NO (1) | NO20043948L (fr) |
| TW (1) | TW200403218A (fr) |
| WO (1) | WO2003070672A1 (fr) |
| ZA (1) | ZA200405830B (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004059355A1 (de) * | 2004-12-09 | 2006-06-14 | Basf Ag | Verfahren zur Herstellung von Propan zu Propen |
| WO2006061552A1 (fr) * | 2004-12-11 | 2006-06-15 | Ineos Europe Limited | Procede pour la coproduction d'olefines et de produits gtl |
| CA2616176A1 (fr) * | 2005-07-28 | 2007-02-15 | Ineos Usa Llc | Processus de recuperation d'ethylene a partir d'un effluent de reacteur a craquage autothermique |
| GB2432164A (en) * | 2007-03-17 | 2007-05-16 | Ineos Usa Llc | Production of linear alpha olefins |
| WO2012039890A1 (fr) * | 2010-09-20 | 2012-03-29 | Exxonmobil Chemical Patents Inc. | Procédé et appareil pour la coproduction d'oléfines et d'énergie électrique |
| CA2867731C (fr) * | 2014-10-15 | 2022-08-30 | Nova Chemicals Corporation | Procede de deshydrogenation oxydative a selectivite et conversion elevees |
| KR102079768B1 (ko) * | 2018-05-08 | 2020-02-20 | 에스케이가스 주식회사 | 올레핀 제조 공정 중에 발생하는 배가스 내 이산화질소를 저감하는 방법 |
| US11926582B2 (en) | 2020-04-09 | 2024-03-12 | Technip Energies France | Ultra-low emission ethylene plant |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3329605A (en) * | 1963-07-23 | 1967-07-04 | Michikazu Takeyoshi | Gaseous phase cracking reaction methods |
| US3661799A (en) | 1970-01-26 | 1972-05-09 | Standard Oil Co | Oxidative fluidized regeneration of petroleum conversion catalyst in separate dilute and dense phase zones |
| JPS5024918A (fr) | 1973-06-15 | 1975-03-17 | ||
| JPS5113122A (en) | 1974-07-22 | 1976-02-02 | Kunimasa Ooide | Tenjoban kabeitanadono haritsukesekohoho |
| US4143521A (en) * | 1977-02-08 | 1979-03-13 | Stone & Webster Engineering Corporation | Process for the production of ethylene |
| GB2027739B (en) | 1978-08-07 | 1982-12-22 | Ici Ltd | Hydrocarbon conversion |
| JPS57165325A (en) | 1981-04-03 | 1982-10-12 | Mitsui Eng & Shipbuild Co Ltd | Preparation of hydrocarbon decomposition gas |
| DE3314132A1 (de) * | 1983-04-19 | 1984-10-25 | Linde Ag, 6200 Wiesbaden | Verfahren zum betreiben einer anlage fuer die spaltung von kohlenwasserstoffen |
| DE3433088A1 (de) | 1984-09-08 | 1985-10-03 | Wilhelm 7464 Schömberg Wissing | Verfahren zur selektiven energiegewinnung aus festen brennstoffen, unter abtrennung von fluechtigen bestandteilen, schwefel und aschen und verwertung der anfallenden anorgan. bestandteile etc. |
| JPS62146990A (ja) | 1985-12-19 | 1987-06-30 | Idemitsu Petrochem Co Ltd | 炭化水素の熱分解装置 |
| US4617109A (en) * | 1985-12-23 | 1986-10-14 | The M. W. Kellogg Company | Combustion air preheating |
| GB8805447D0 (en) | 1988-03-08 | 1988-04-07 | British Petroleum Co Plc | Chemical process |
| GB9117216D0 (en) * | 1991-08-09 | 1991-09-25 | British Petroleum Co Plc | Process for the production of mono-olefins |
| GB9217685D0 (en) * | 1992-08-20 | 1992-09-30 | British Petroleum Co Plc | Process for the production of mono-olefins |
| DE4241464A1 (de) | 1992-08-28 | 1994-03-03 | Linde Ag | Verfahren zur Beschickung von Öfen mit sauerstoffhaltigem Verbrennungsgas in Industrieanlagen mit einer Gasturbine |
| GB9421734D0 (en) | 1994-10-28 | 1994-12-14 | Bp Chem Int Ltd | Hydrocarbon conversion process |
| EP1114013B1 (fr) | 1998-09-03 | 2002-11-27 | The Dow Chemical Company | Synthese en ligne et regeneration d'un catalyseur utilise dans une oxydation autothermique |
| GB9819645D0 (en) * | 1998-09-10 | 1998-11-04 | Bp Chem Int Ltd | Process |
| FR2796078B1 (fr) * | 1999-07-07 | 2002-06-14 | Bp Chemicals Snc | Procede et dispositif de vapocraquage d'hydrocarbures |
-
2002
- 2002-02-22 GB GBGB0204140.8A patent/GB0204140D0/en not_active Ceased
-
2003
- 2003-02-13 EP EP03742599A patent/EP1476410A1/fr not_active Withdrawn
- 2003-02-13 EA EA200401076A patent/EA006723B1/ru not_active IP Right Cessation
- 2003-02-13 JP JP2003569582A patent/JP2005517729A/ja not_active Withdrawn
- 2003-02-13 CN CNB038043297A patent/CN1315762C/zh not_active Expired - Fee Related
- 2003-02-13 AU AU2003246826A patent/AU2003246826B2/en not_active Ceased
- 2003-02-13 KR KR10-2004-7012944A patent/KR20040095224A/ko not_active Application Discontinuation
- 2003-02-13 US US10/502,545 patent/US7244872B2/en not_active Expired - Fee Related
- 2003-02-13 BR BR0307867-1A patent/BR0307867A/pt not_active IP Right Cessation
- 2003-02-13 MX MXPA04007780A patent/MXPA04007780A/es active IP Right Grant
- 2003-02-13 CA CA002474656A patent/CA2474656A1/fr not_active Abandoned
- 2003-02-13 WO PCT/GB2003/000637 patent/WO2003070672A1/fr active Application Filing
- 2003-02-19 EG EG2003020173A patent/EG23393A/xx active
- 2003-02-20 TW TW092103541A patent/TW200403218A/zh unknown
- 2003-02-21 AR ARP030100580A patent/AR038589A1/es active IP Right Grant
-
2004
- 2004-07-21 ZA ZA200405830A patent/ZA200405830B/en unknown
- 2004-07-30 CO CO04073965A patent/CO5611193A2/es not_active Application Discontinuation
- 2004-09-21 NO NO20043948A patent/NO20043948L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1315762C (zh) | 2007-05-16 |
| EA200401076A1 (ru) | 2005-04-28 |
| US7244872B2 (en) | 2007-07-17 |
| CO5611193A2 (es) | 2006-02-28 |
| GB0204140D0 (en) | 2002-04-10 |
| EG23393A (en) | 2005-04-27 |
| CN1635986A (zh) | 2005-07-06 |
| EA006723B1 (ru) | 2006-04-28 |
| MXPA04007780A (es) | 2004-10-15 |
| KR20040095224A (ko) | 2004-11-12 |
| EP1476410A1 (fr) | 2004-11-17 |
| NO20043948L (no) | 2004-11-11 |
| WO2003070672A1 (fr) | 2003-08-28 |
| AU2003246826B2 (en) | 2008-05-01 |
| CA2474656A1 (fr) | 2003-08-28 |
| US20050089299A1 (en) | 2005-04-28 |
| AU2003246826A1 (en) | 2003-09-09 |
| BR0307867A (pt) | 2004-12-07 |
| AR038589A1 (es) | 2005-01-19 |
| JP2005517729A (ja) | 2005-06-16 |
| TW200403218A (en) | 2004-03-01 |
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