ZA200404715B - Regeneration of catalysts for carbon monoxide hydrogention. - Google Patents
Regeneration of catalysts for carbon monoxide hydrogention. Download PDFInfo
- Publication number
- ZA200404715B ZA200404715B ZA200404715A ZA200404715A ZA200404715B ZA 200404715 B ZA200404715 B ZA 200404715B ZA 200404715 A ZA200404715 A ZA 200404715A ZA 200404715 A ZA200404715 A ZA 200404715A ZA 200404715 B ZA200404715 B ZA 200404715B
- Authority
- ZA
- South Africa
- Prior art keywords
- catalyst
- hydrogen
- metal
- gas
- containing gas
- Prior art date
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- 239000003054 catalyst Substances 0.000 title claims description 204
- 229910002091 carbon monoxide Inorganic materials 0.000 title claims description 26
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims description 25
- 238000011069 regeneration method Methods 0.000 title description 16
- 230000008929 regeneration Effects 0.000 title description 14
- 229910052751 metal Inorganic materials 0.000 claims description 71
- 239000002184 metal Substances 0.000 claims description 70
- 238000000034 method Methods 0.000 claims description 69
- 239000007789 gas Substances 0.000 claims description 61
- 230000008569 process Effects 0.000 claims description 45
- 229930195733 hydrocarbon Natural products 0.000 claims description 44
- 150000002430 hydrocarbons Chemical class 0.000 claims description 44
- 229910052739 hydrogen Inorganic materials 0.000 claims description 36
- 239000001257 hydrogen Substances 0.000 claims description 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 34
- 239000004215 Carbon black (E152) Substances 0.000 claims description 23
- 239000002904 solvent Substances 0.000 claims description 20
- 238000001354 calcination Methods 0.000 claims description 19
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- 239000007800 oxidant agent Substances 0.000 claims description 15
- 239000012298 atmosphere Substances 0.000 claims description 13
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
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- XILIYVSXLSWUAI-UHFFFAOYSA-N 2-(diethylamino)ethyl n'-phenylcarbamimidothioate;dihydrobromide Chemical compound Br.Br.CCN(CC)CCSC(N)=NC1=CC=CC=C1 XILIYVSXLSWUAI-UHFFFAOYSA-N 0.000 claims 1
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
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- B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
- C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
- C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
- C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J2038/005—Regeneration or reactivation of catalysts, in general involving supercritical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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| US10/059,926 US6800579B2 (en) | 2002-01-29 | 2002-01-29 | Catalyst regeneration |
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| ZA200404715B true ZA200404715B (en) | 2006-02-22 |
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| ZA200404715A ZA200404715B (en) | 2002-01-29 | 2004-06-14 | Regeneration of catalysts for carbon monoxide hydrogention. |
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| Country | Link |
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| US (1) | US6800579B2 (zh) |
| EP (1) | EP1472001B1 (zh) |
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| DE (1) | DE60330752D1 (zh) |
| TW (1) | TWI266649B (zh) |
| WO (1) | WO2003064034A2 (zh) |
| ZA (1) | ZA200404715B (zh) |
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| US7256149B2 (en) * | 2004-02-24 | 2007-08-14 | Lyondell Chemical Technology, L.P. | Catalyst regeneration process |
| US7524787B2 (en) * | 2005-01-11 | 2009-04-28 | Sasol Technology (Proprietary Limited) | Producing supported cobalt catalysts for the Fisher-Tropsch synthesis |
| US8648006B2 (en) * | 2005-10-13 | 2014-02-11 | Velocys, Inc. | Electroless plating in microchannels |
| US7378452B2 (en) * | 2005-12-28 | 2008-05-27 | Exxonmobil Research And Engineering Company | Filtration system for slurry hydrocarbon synthesis process using both small and large pore filter elements |
| US7825055B2 (en) * | 2006-04-21 | 2010-11-02 | Chevron U.S.A. Inc. | Regeneration of ionic liquid catalyst using a regeneration metal in the presence of added hydrogen |
| JP4650354B2 (ja) * | 2006-06-28 | 2011-03-16 | 住友化学株式会社 | 不飽和アルデヒド及び／又は不飽和カルボン酸製造用触媒の再生方法、並びに不飽和アルデヒド及び／又は不飽和カルボン酸の製造方法 |
| WO2008139407A2 (en) * | 2007-05-11 | 2008-11-20 | Sasol Technology (Proprietary) Limited | Catalysts |
| JP5169047B2 (ja) | 2007-07-23 | 2013-03-27 | 住友化学株式会社 | 塩素の製造方法 |
| US8614158B2 (en) * | 2008-02-29 | 2013-12-24 | Schlumberger Technology Corporation | Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process |
| FR2930733B1 (fr) * | 2008-04-30 | 2014-04-11 | Inst Francais Du Petrole | Masse active d'oxydo-reduction et procede de combustion en boucle chimique. |
| US8293805B2 (en) * | 2008-05-29 | 2012-10-23 | Schlumberger Technology Corporation | Tracking feedstock production with micro scale gas-to-liquid units |
| JP2012512735A (ja) * | 2008-12-18 | 2012-06-07 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 酸化し、炭酸アンモニウム、水酸化アンモニウムおよび水の混合物を用いて処理することによるフィッシャー・トロプシュ触媒の再生 |
| BRPI0923470A8 (pt) * | 2008-12-23 | 2017-10-10 | Rentech Inc | Método e sistema para ativar um catalisador de fischer-tropsch |
| RU2554866C2 (ru) * | 2009-12-16 | 2015-06-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ регенерирования катализатора |
| CN101797501A (zh) * | 2010-04-26 | 2010-08-11 | 哈尔滨工业大学 | 聚锰硅盐及其制备方法和其在水处理中的应用 |
| CN101791535B (zh) * | 2010-04-28 | 2012-03-21 | 哈尔滨工业大学 | 聚硅酸锰盐掺杂二氧化锰吸附剂的制备方法 |
| CN102309966B (zh) * | 2010-07-07 | 2013-06-19 | 中国石油化工股份有限公司 | 一种钴基费托合成催化剂的制备方法 |
| FR2970187B1 (fr) * | 2011-01-11 | 2013-02-08 | Eurecat Sa | Procede de regeneration hors site de catalyseurs solides. |
| CA2830504C (en) * | 2011-03-19 | 2021-05-04 | Quanta Technologies, Llc | Process to improve formulations of hydrocarbon conversion catalysts through removal and modification of detrimental particles and reuse of modified fractions |
| JP5635445B2 (ja) * | 2011-04-08 | 2014-12-03 | 三井化学株式会社 | 開環メタセシス重合体水素添加物の製造方法 |
| MX346507B (es) * | 2011-10-14 | 2017-03-23 | Honeywell Int Inc | Proceso para producir 2,3,3,3,-tetrafluoropropeno. |
| CN103182329B (zh) * | 2011-12-29 | 2016-03-23 | 神华集团有限责任公司 | 一种煤液化油加氢失活催化剂的再生和复活方法 |
| US20140371501A1 (en) | 2012-02-20 | 2014-12-18 | Dow Global Technologies Llc | Reconstituted dehydrogenation catalyst showing slowed activity loss when compared with fresh catalyst |
| CN103816923B (zh) * | 2012-11-16 | 2016-01-20 | 万华化学集团股份有限公司 | 一种钌加氢催化剂再生的方法 |
| CN103599796B (zh) * | 2013-11-06 | 2016-10-05 | 太仓市方亮精细合金厂 | 一种合金粉催化剂的再生方法 |
| US10190057B2 (en) | 2014-11-20 | 2019-01-29 | Sasol Technology Proprietary Limited | Fischer-tropsch synthesis |
| CN105214740A (zh) * | 2015-09-30 | 2016-01-06 | 广西大学 | 内部汽化膨胀法再生改性fcc废触媒及其应用 |
| EP3239282B1 (en) * | 2016-04-27 | 2018-08-29 | The Procter and Gamble Company | Method of manual dishwashing |
| CN106866429B (zh) * | 2017-04-10 | 2019-03-15 | 上海迅凯新材料科技有限公司 | 连续化催化氢化生产及催化剂再生装置及方法 |
| US10434506B1 (en) | 2018-12-18 | 2019-10-08 | Emerging Fuels Technology, Inc. | Method for activation or regeneration of a catalyst |
| CN111378510B (zh) * | 2018-12-28 | 2021-05-04 | 中国石油化工股份有限公司 | 一种利用生物质制备合成气的方法和系统 |
| CN112563526A (zh) * | 2019-09-26 | 2021-03-26 | 荆门市格林美新材料有限公司 | 一种氢氧燃料电池阳极催化剂的再生方法 |
| CN110841647B (zh) * | 2019-12-04 | 2021-05-14 | 大连理工大学 | 一种回收利用废旧骨架镍催化剂的方法 |
| CN111686824A (zh) * | 2020-06-11 | 2020-09-22 | 中科合成油内蒙古有限公司 | 一种固定床费托合成钌基催化剂的原位再生方法 |
| CN113634290A (zh) * | 2021-08-11 | 2021-11-12 | 兖矿榆林精细化工有限公司 | 一种煤液化催化剂的再生方法 |
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| IT1301801B1 (it) * | 1998-06-25 | 2000-07-07 | Agip Petroli | Procedimento per la preparazione di idrocarburi da gas di sintesi |
| FR2782280B1 (fr) | 1998-08-12 | 2000-09-22 | Inst Francais Du Petrole | Catalyseurs supportes utilisables dans des reactions de transformation de composes organiques |
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|---|---|
| ATE453449T1 (de) | 2010-01-15 |
| WO2003064034A2 (en) | 2003-08-07 |
| CN1750876B (zh) | 2011-05-04 |
| AR038135A1 (es) | 2004-12-29 |
| US20030144366A1 (en) | 2003-07-31 |
| CA2470945A1 (en) | 2003-08-07 |
| CA2470945C (en) | 2011-03-15 |
| AU2003202874B2 (en) | 2010-07-15 |
| JP2005516055A (ja) | 2005-06-02 |
| EP1472001A2 (en) | 2004-11-03 |
| CN1750876A (zh) | 2006-03-22 |
| WO2003064034A3 (en) | 2003-11-27 |
| EP1472001B1 (en) | 2009-12-30 |
| DE60330752D1 (de) | 2010-02-11 |
| TWI266649B (en) | 2006-11-21 |
| TW200302132A (en) | 2003-08-01 |
| US6800579B2 (en) | 2004-10-05 |
| JP4660093B2 (ja) | 2011-03-30 |
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