ZA200304976B - Liquid fuel compositions for electrochemical fuel cells. - Google Patents
Liquid fuel compositions for electrochemical fuel cells. Download PDFInfo
- Publication number
- ZA200304976B ZA200304976B ZA200304976A ZA200304976A ZA200304976B ZA 200304976 B ZA200304976 B ZA 200304976B ZA 200304976 A ZA200304976 A ZA 200304976A ZA 200304976 A ZA200304976 A ZA 200304976A ZA 200304976 B ZA200304976 B ZA 200304976B
- Authority
- ZA
- South Africa
- Prior art keywords
- fuel
- compound
- fuel composition
- anode
- hydrogen
- Prior art date
Links
- 239000000446 fuel Substances 0.000 title claims description 176
- 239000000203 mixture Substances 0.000 title claims description 63
- 239000007788 liquid Substances 0.000 title description 14
- 239000001257 hydrogen Substances 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- 150000001875 compounds Chemical class 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
- 239000003792 electrolyte Substances 0.000 claims description 16
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 14
- 150000002484 inorganic compounds Chemical class 0.000 claims description 14
- 229910010272 inorganic material Inorganic materials 0.000 claims description 14
- 230000005611 electricity Effects 0.000 claims description 13
- 230000009467 reduction Effects 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 229910052987 metal hydride Inorganic materials 0.000 claims description 7
- 150000004681 metal hydrides Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 7
- 150000002429 hydrazines Chemical class 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 229910010082 LiAlH Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 229910020828 NaAlH4 Inorganic materials 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 93
- 230000003197 catalytic effect Effects 0.000 description 28
- 230000003647 oxidation Effects 0.000 description 14
- 238000007254 oxidation reaction Methods 0.000 description 14
- 239000012528 membrane Substances 0.000 description 11
- 230000001590 oxidative effect Effects 0.000 description 11
- 239000007800 oxidant agent Substances 0.000 description 10
- 239000000243 solution Substances 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910002091 carbon monoxide Inorganic materials 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- -1 hydrogen ions Chemical class 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000012453 solvate Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003637 basic solution Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011244 liquid electrolyte Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000005518 polymer electrolyte Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000007784 solid electrolyte Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- 229920000557 Nafion® Polymers 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 229910000929 Ru alloy Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
- H01M8/083—Alkaline fuel cells
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/08—Fuel cells with aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Fuel Cell (AREA)
- Inert Electrodes (AREA)
- Liquid Carbonaceous Fuels (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/752,551 US6554877B2 (en) | 2001-01-03 | 2001-01-03 | Liquid fuel compositions for electrochemical fuel cells |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200304976B true ZA200304976B (en) | 2003-10-29 |
Family
ID=25026764
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200304976A ZA200304976B (en) | 2001-01-03 | 2003-09-26 | Liquid fuel compositions for electrochemical fuel cells. |
Country Status (18)
Country | Link |
---|---|
US (5) | US6554877B2 (pl) |
EP (1) | EP1348014A4 (pl) |
JP (1) | JP3883509B2 (pl) |
KR (1) | KR20030072587A (pl) |
CN (1) | CN1253956C (pl) |
AU (1) | AU2002241813B2 (pl) |
BR (1) | BR0206263A (pl) |
CA (1) | CA2433401A1 (pl) |
EC (1) | ECSP034681A (pl) |
HK (1) | HK1061308A1 (pl) |
IL (2) | IL156624A0 (pl) |
MX (1) | MXPA03005826A (pl) |
NO (1) | NO20032961L (pl) |
NZ (1) | NZ526661A (pl) |
PL (1) | PL363315A1 (pl) |
RU (1) | RU2265643C2 (pl) |
WO (1) | WO2002054506A2 (pl) |
ZA (1) | ZA200304976B (pl) |
Families Citing this family (84)
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US6758871B2 (en) * | 2002-11-20 | 2004-07-06 | More Energy Ltd. | Liquid fuel compositions for electrochemical fuel cells |
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2001
- 2001-01-03 US US09/752,551 patent/US6554877B2/en not_active Expired - Fee Related
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2002
- 2002-01-03 BR BR0206263-1A patent/BR0206263A/pt not_active IP Right Cessation
- 2002-01-03 NZ NZ526661A patent/NZ526661A/xx unknown
- 2002-01-03 JP JP2002554894A patent/JP3883509B2/ja not_active Expired - Fee Related
- 2002-01-03 AU AU2002241813A patent/AU2002241813B2/en not_active Ceased
- 2002-01-03 PL PL02363315A patent/PL363315A1/pl not_active Application Discontinuation
- 2002-01-03 RU RU2003124056/09A patent/RU2265643C2/ru not_active IP Right Cessation
- 2002-01-03 MX MXPA03005826A patent/MXPA03005826A/es active IP Right Grant
- 2002-01-03 KR KR10-2003-7008956A patent/KR20030072587A/ko not_active Application Discontinuation
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- 2002-01-03 WO PCT/US2002/000140 patent/WO2002054506A2/en active IP Right Grant
- 2002-01-03 CA CA002433401A patent/CA2433401A1/en not_active Abandoned
- 2002-01-03 EP EP02707399A patent/EP1348014A4/en not_active Withdrawn
- 2002-01-25 US US10/054,865 patent/US6562497B2/en not_active Expired - Fee Related
- 2002-06-06 US US10/162,564 patent/US20020142196A1/en not_active Abandoned
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- 2003-06-30 EC EC2003004681A patent/ECSP034681A/es unknown
- 2003-09-26 ZA ZA200304976A patent/ZA200304976B/en unknown
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Also Published As
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HK1061308A1 (en) | 2004-09-10 |
NO20032961D0 (no) | 2003-06-27 |
PL363315A1 (pl) | 2004-11-15 |
US20020094459A1 (en) | 2002-07-18 |
NO20032961L (no) | 2003-09-03 |
CN1253956C (zh) | 2006-04-26 |
EP1348014A4 (en) | 2005-02-23 |
CN1484685A (zh) | 2004-03-24 |
CA2433401A1 (en) | 2002-07-11 |
US6554877B2 (en) | 2003-04-29 |
AU2002241813B2 (en) | 2007-05-24 |
RU2265643C2 (ru) | 2005-12-10 |
WO2002054506A3 (en) | 2002-10-03 |
KR20030072587A (ko) | 2003-09-15 |
IL156624A (en) | 2007-07-24 |
US6562497B2 (en) | 2003-05-13 |
MXPA03005826A (es) | 2005-02-14 |
BR0206263A (pt) | 2004-07-27 |
NZ526661A (en) | 2004-12-24 |
EP1348014A2 (en) | 2003-10-01 |
US20020142196A1 (en) | 2002-10-03 |
US20030207157A1 (en) | 2003-11-06 |
US20020083640A1 (en) | 2002-07-04 |
JP3883509B2 (ja) | 2007-02-21 |
ECSP034681A (es) | 2003-10-28 |
JP2004517176A (ja) | 2004-06-10 |
IL156624A0 (en) | 2004-01-04 |
US20060183008A1 (en) | 2006-08-17 |
WO2002054506A2 (en) | 2002-07-11 |
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