ZA200105123B - Nonaqueous sizing system for glass fibers and injection moldable polymers. - Google Patents
Nonaqueous sizing system for glass fibers and injection moldable polymers. Download PDFInfo
- Publication number
- ZA200105123B ZA200105123B ZA200105123A ZA200105123A ZA200105123B ZA 200105123 B ZA200105123 B ZA 200105123B ZA 200105123 A ZA200105123 A ZA 200105123A ZA 200105123 A ZA200105123 A ZA 200105123A ZA 200105123 B ZA200105123 B ZA 200105123B
- Authority
- ZA
- South Africa
- Prior art keywords
- sizing composition
- molecular weight
- glass
- composition
- nonaqueous
- Prior art date
Links
- 238000004513 sizing Methods 0.000 title claims description 100
- 239000003365 glass fiber Substances 0.000 title claims description 57
- 229920000642 polymer Polymers 0.000 title claims description 17
- 238000002347 injection Methods 0.000 title description 5
- 239000007924 injection Substances 0.000 title description 5
- 239000000203 mixture Substances 0.000 claims description 77
- 239000000843 powder Substances 0.000 claims description 36
- 239000011521 glass Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 30
- 239000007822 coupling agent Substances 0.000 claims description 19
- 239000004677 Nylon Substances 0.000 claims description 11
- 229920001778 nylon Polymers 0.000 claims description 11
- 239000004743 Polypropylene Substances 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 229920001610 polycaprolactone Polymers 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 5
- 229920002647 polyamide Polymers 0.000 claims description 5
- 229920000180 alkyd Polymers 0.000 claims description 4
- 230000003014 reinforcing effect Effects 0.000 claims description 4
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 3
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 claims description 2
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical class [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims 2
- 239000013032 Hydrocarbon resin Substances 0.000 claims 1
- 229920002292 Nylon 6 Polymers 0.000 claims 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims 1
- 229920001903 high density polyethylene Polymers 0.000 claims 1
- 239000004700 high-density polyethylene Substances 0.000 claims 1
- 229920006270 hydrocarbon resin Polymers 0.000 claims 1
- 229920000515 polycarbonate Polymers 0.000 claims 1
- 239000004417 polycarbonate Substances 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 239000012783 reinforcing fiber Substances 0.000 claims 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 claims 1
- 229920006305 unsaturated polyester Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 47
- 239000008188 pellet Substances 0.000 description 33
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000002131 composite material Substances 0.000 description 9
- 238000009472 formulation Methods 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 230000002787 reinforcement Effects 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920001169 thermoplastic Polymers 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229910000077 silane Inorganic materials 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000012855 volatile organic compound Substances 0.000 description 5
- 229920000049 Carbon (fiber) Polymers 0.000 description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 239000004917 carbon fiber Substances 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- 239000006060 molten glass Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 150000004756 silanes Chemical class 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000009977 dual effect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000004632 polycaprolactone Substances 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 108020005224 Arylamine N-acetyltransferase Proteins 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 2
- 229920007814 Orgasol® 2001 UD NAT 2 Polymers 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002238 attenuated effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229940095674 pellet product Drugs 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004412 Bulk moulding compound Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920009686 Orgasol® 2001 EXD NAT 1 Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000003677 Sheet moulding compound Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000006265 aqueous foam Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
- C08J5/08—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/323—Polyesters, e.g. alkyd resins
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/255—Oils, waxes, fats or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
- C03C25/47—Coatings containing composite materials containing particles, fibres or flakes, e.g. in a continuous phase
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/24994—Fiber embedded in or on the surface of a polymeric matrix
- Y10T428/249942—Fibers are aligned substantially parallel
- Y10T428/249946—Glass fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2907—Staple length fiber with coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2938—Coating on discrete and individual rods, strands or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/220,221 US6399198B1 (en) | 1998-12-23 | 1998-12-23 | Nonaqueous sizing system for glass fibers and injection moldable polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200105123B true ZA200105123B (en) | 2002-06-21 |
Family
ID=22822610
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200105123A ZA200105123B (en) | 1998-12-23 | 2001-06-21 | Nonaqueous sizing system for glass fibers and injection moldable polymers. |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6399198B1 (ko) |
| EP (1) | EP1152991B1 (ko) |
| JP (1) | JP4739528B2 (ko) |
| KR (1) | KR20010099938A (ko) |
| CN (1) | CN1333734A (ko) |
| AT (1) | ATE248784T1 (ko) |
| AU (1) | AU2177600A (ko) |
| BR (1) | BR9916487B1 (ko) |
| CA (1) | CA2354127C (ko) |
| CZ (1) | CZ299979B6 (ko) |
| DE (1) | DE69911068T2 (ko) |
| ES (1) | ES2207331T3 (ko) |
| HU (1) | HUP0202933A2 (ko) |
| NO (1) | NO332885B1 (ko) |
| NZ (1) | NZ512538A (ko) |
| WO (1) | WO2000039042A1 (ko) |
| ZA (1) | ZA200105123B (ko) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6562257B1 (en) * | 2000-04-25 | 2003-05-13 | Owens Corning Fiberglas Technology, Inc. | Loose-fill insulation with improved recoverability |
| US6607186B2 (en) * | 2000-05-01 | 2003-08-19 | Bret Voelkel | Shock absorber |
| FR2826359B1 (fr) * | 2001-06-21 | 2004-05-07 | Saint Gobain Vetrotex | Fils de verre ensimes, composition d'ensimage et composites comprenant lesdits fils |
| US6844374B2 (en) | 2001-10-03 | 2005-01-18 | Lord Corporation | Enhanced scratch resistant coatings using inorganic fillers |
| US7414780B2 (en) * | 2003-06-30 | 2008-08-19 | Imra America, Inc. | All-fiber chirped pulse amplification systems |
| FR2864073B1 (fr) * | 2003-12-17 | 2006-03-31 | Saint Gobain Vetrotex | Fils de verre ensimes a impregnation rapide pour le renforcement de matieres polymeres |
| US20060177657A1 (en) * | 2005-02-08 | 2006-08-10 | Keith Weller | Sizing compositions for fibers utilizing low VOC silanes |
| MX2010006974A (es) * | 2007-12-21 | 2010-08-11 | Saudi Basic Ind Corp | Procedimiento para producir composiciones termoplasticas reforzadas con fibra de vidrio larga. |
| US20140228486A1 (en) * | 2011-08-01 | 2014-08-14 | Ocv Intellectual Capital, Llc | Sizing compositions and methods of their use |
| US20130143025A1 (en) * | 2011-12-06 | 2013-06-06 | Makoto Kibayashi | Thermoplastic resin impregnated tape |
| US9718956B2 (en) | 2014-01-14 | 2017-08-01 | Sabic Global Technologies B.V. | Interior aircraft components and methods of manufacture |
| US9365720B2 (en) * | 2014-01-14 | 2016-06-14 | Sabic Global Technologies B.V. | Interior train components having low smoke and low heat release, and methods of their manufacture |
| CN104045244B (zh) * | 2014-05-29 | 2017-02-01 | 巨石集团有限公司 | 连续纤维增强聚烯烃用无碱直接纱浸润剂 |
| TWI719982B (zh) | 2015-05-15 | 2021-03-01 | 美商西凱渥資訊處理科技公司 | 半導體裝置中之空腔形成 |
| CN105568694B (zh) * | 2016-03-09 | 2017-10-27 | 广东工业大学 | 一种热塑性上浆剂及其制备方法与应用 |
| KR101999900B1 (ko) * | 2017-10-24 | 2019-07-12 | 주식회사 케이씨씨 | 사이징 조성물 및 이를 이용한 유리섬유 |
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| US3676287A (en) * | 1970-09-08 | 1972-07-11 | Owens Corning Fiberglass Corp | Glass fiber-reinforced elastomers |
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-
1998
- 1998-12-23 US US09/220,221 patent/US6399198B1/en not_active Expired - Lifetime
-
1999
- 1999-12-13 WO PCT/US1999/029494 patent/WO2000039042A1/en active IP Right Grant
- 1999-12-13 CN CN99815688A patent/CN1333734A/zh active Pending
- 1999-12-13 CA CA002354127A patent/CA2354127C/en not_active Expired - Lifetime
- 1999-12-13 AT AT99966167T patent/ATE248784T1/de not_active IP Right Cessation
- 1999-12-13 NZ NZ512538A patent/NZ512538A/xx not_active IP Right Cessation
- 1999-12-13 EP EP99966167A patent/EP1152991B1/en not_active Expired - Lifetime
- 1999-12-13 DE DE69911068T patent/DE69911068T2/de not_active Expired - Lifetime
- 1999-12-13 HU HU0202933A patent/HUP0202933A2/hu unknown
- 1999-12-13 KR KR1020017008092A patent/KR20010099938A/ko active IP Right Grant
- 1999-12-13 JP JP2000590958A patent/JP4739528B2/ja not_active Expired - Lifetime
- 1999-12-13 AU AU21776/00A patent/AU2177600A/en not_active Abandoned
- 1999-12-13 CZ CZ20012347A patent/CZ299979B6/cs not_active IP Right Cessation
- 1999-12-13 BR BRPI9916487-6A patent/BR9916487B1/pt not_active IP Right Cessation
- 1999-12-13 ES ES99966167T patent/ES2207331T3/es not_active Expired - Lifetime
-
2001
- 2001-06-21 ZA ZA200105123A patent/ZA200105123B/en unknown
- 2001-06-22 NO NO20013137A patent/NO332885B1/no not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NZ512538A (en) | 2003-03-28 |
| NO20013137L (no) | 2001-06-22 |
| EP1152991A1 (en) | 2001-11-14 |
| WO2000039042A1 (en) | 2000-07-06 |
| JP4739528B2 (ja) | 2011-08-03 |
| EP1152991B1 (en) | 2003-09-03 |
| CZ299979B6 (cs) | 2009-01-14 |
| DE69911068T2 (de) | 2004-07-15 |
| AU2177600A (en) | 2000-07-31 |
| CZ20012347A3 (cs) | 2004-03-17 |
| BR9916487A (pt) | 2001-12-11 |
| NO332885B1 (no) | 2013-01-28 |
| DE69911068D1 (de) | 2003-10-09 |
| US20020054985A1 (en) | 2002-05-09 |
| ES2207331T3 (es) | 2004-05-16 |
| CA2354127C (en) | 2008-08-12 |
| CA2354127A1 (en) | 2000-07-06 |
| HUP0202933A2 (en) | 2002-12-28 |
| ATE248784T1 (de) | 2003-09-15 |
| US6399198B1 (en) | 2002-06-04 |
| CN1333734A (zh) | 2002-01-30 |
| JP2002533296A (ja) | 2002-10-08 |
| KR20010099938A (ko) | 2001-11-09 |
| NO20013137D0 (no) | 2001-06-22 |
| BR9916487B1 (pt) | 2009-08-11 |
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