ZA200104962B - Fungicidal mixtures. - Google Patents
Fungicidal mixtures. Download PDFInfo
- Publication number
- ZA200104962B ZA200104962B ZA200104962A ZA200104962A ZA200104962B ZA 200104962 B ZA200104962 B ZA 200104962B ZA 200104962 A ZA200104962 A ZA 200104962A ZA 200104962 A ZA200104962 A ZA 200104962A ZA 200104962 B ZA200104962 B ZA 200104962B
- Authority
- ZA
- South Africa
- Prior art keywords
- compound
- copper
- mixture
- composition
- formula
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 54
- 230000000855 fungicidal effect Effects 0.000 title claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 59
- 241000233866 Fungi Species 0.000 claims description 17
- -1 areas Substances 0.000 claims description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 239000010949 copper Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 6
- 230000002195 synergetic effect Effects 0.000 claims description 6
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 2
- 239000005751 Copper oxide Substances 0.000 claims description 2
- YXLXNENXOJSQEI-UHFFFAOYSA-L Oxine-copper Chemical compound [Cu+2].C1=CN=C2C([O-])=CC=CC2=C1.C1=CN=C2C([O-])=CC=CC2=C1 YXLXNENXOJSQEI-UHFFFAOYSA-L 0.000 claims description 2
- RJNIPHBKXIABMZ-UHFFFAOYSA-N [Cu].[NH3+]N.[NH3+]N.[O-]S(=O)(=O)OS([O-])(=O)=O Chemical compound [Cu].[NH3+]N.[NH3+]N.[O-]S(=O)(=O)OS([O-])(=O)=O RJNIPHBKXIABMZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910000431 copper oxide Inorganic materials 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- UXCKXHXXSNDUMI-UHFFFAOYSA-L copper;2-carboxy-6-phenylphenolate Chemical compound [Cu+2].OC1=C(C([O-])=O)C=CC=C1C1=CC=CC=C1.OC1=C(C([O-])=O)C=CC=C1C1=CC=CC=C1 UXCKXHXXSNDUMI-UHFFFAOYSA-L 0.000 claims description 2
- WNMPGCKOSIFMAE-UHFFFAOYSA-L copper;chloro hypochlorite;sulfate Chemical compound [Cu+2].ClOCl.[O-]S([O-])(=O)=O WNMPGCKOSIFMAE-UHFFFAOYSA-L 0.000 claims description 2
- SKQUUKNCBWILCD-UHFFFAOYSA-J dicopper;chloride;trihydroxide Chemical compound [OH-].[OH-].[OH-].[Cl-].[Cu+2].[Cu+2] SKQUUKNCBWILCD-UHFFFAOYSA-J 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
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- 239000007788 liquid Substances 0.000 claims 2
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 claims 1
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- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 235000016213 coffee Nutrition 0.000 description 1
- 235000013353 coffee beverage Nutrition 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 244000038559 crop plants Species 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- AEUGJWFECANMJW-UHFFFAOYSA-N dimethylcarbamodithioic acid dihydrochloride Chemical compound Cl.Cl.CN(C)C(S)=S AEUGJWFECANMJW-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 125000005624 silicic acid group Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
- A01N59/20—Copper
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19853503 | 1998-11-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
ZA200104962B true ZA200104962B (en) | 2002-06-18 |
Family
ID=7888405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ZA200104962A ZA200104962B (en) | 1998-11-19 | 2001-06-18 | Fungicidal mixtures. |
Country Status (26)
Country | Link |
---|---|
US (1) | US6503936B1 (pt) |
EP (1) | EP1130967B1 (pt) |
JP (1) | JP2002530303A (pt) |
KR (1) | KR100689931B1 (pt) |
CN (1) | CN100518510C (pt) |
AR (1) | AR021345A1 (pt) |
AT (1) | ATE245354T1 (pt) |
AU (1) | AU767577B2 (pt) |
BG (1) | BG65003B1 (pt) |
BR (1) | BR9915503B1 (pt) |
CA (1) | CA2351819C (pt) |
CO (1) | CO5210926A1 (pt) |
CZ (1) | CZ293437B6 (pt) |
DE (1) | DE59906388D1 (pt) |
DK (1) | DK1130967T3 (pt) |
ES (1) | ES2204196T3 (pt) |
HU (1) | HU228597B1 (pt) |
IL (1) | IL143101A (pt) |
NZ (1) | NZ512191A (pt) |
PT (1) | PT1130967E (pt) |
RO (1) | RO122006B1 (pt) |
RU (1) | RU2244420C2 (pt) |
SK (1) | SK284747B6 (pt) |
UA (1) | UA70345C2 (pt) |
WO (1) | WO2000030450A1 (pt) |
ZA (1) | ZA200104962B (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITMI20012430A1 (it) * | 2001-11-19 | 2003-05-19 | Isagro Spa | Composizioni a base di sali rameici sali rameici e loro utilizzo per il controllo di fitopatogeni |
BRPI0415365A (pt) * | 2003-10-17 | 2006-12-12 | Basf Ag | uso de aminoácidos básicos, composição fungicida, processos para a preparação de uma formulação fungicida, e para o combate de fungos fitopatogênicos, semente, e, material |
CN103478142B (zh) * | 2003-10-31 | 2016-03-30 | 石原产业株式会社 | 杀菌剂组合物和植物病害的防除方法 |
US20050112393A1 (en) * | 2003-11-20 | 2005-05-26 | Fliermans Carl B. | Antifungal preservative composition for an environmentally friendly process |
US7198663B2 (en) * | 2004-07-14 | 2007-04-03 | Sommerville Acquisitions Co., Inc. | Wood preservative composition |
WO2006108834A1 (de) * | 2005-04-15 | 2006-10-19 | Basf Aktiengesellschaft | Verwendung von basischen aminosäuren in kupferhaltigen bioziden formulierungen |
WO2006108835A2 (de) * | 2005-04-15 | 2006-10-19 | Basf Aktiengesellschaft | Verwendung von polylysin in kupferhaltigen bioziden formulierungen |
CN102217621A (zh) * | 2011-07-18 | 2011-10-19 | 青岛瀚生生物科技股份有限公司 | 含有吡唑醚菌酯和松脂酸铜杀菌剂复配组合物 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU1120495A (en) * | 1993-12-02 | 1995-06-19 | Sumitomo Chemical Company, Limited | Bactericidal composition |
DE4423612A1 (de) * | 1994-07-06 | 1996-01-11 | Basf Ag | 2-[(Dihydro)pyrazolyl-3'-oxymethylen]-anilide, Verfahren zu ihrer Herstelung und ihre Verwendung |
DE4423613A1 (de) * | 1994-07-06 | 1996-01-11 | Basf Ag | 2-[1',2',4'-Triazol-3'yloxymethylen]-anilide, Verfahren zu ihrer Herstellung und ihre Verwendung |
CA2195577A1 (en) * | 1994-07-21 | 1996-02-08 | Harald Kohle | Method of combating harmful fungi |
WO1997015189A1 (de) | 1995-10-25 | 1997-05-01 | Basf Aktiengesellschaft | Fungizide mischungen von oximethercarbonsäureestern mit kupferhaltigen fungiziden |
DE19710760A1 (de) * | 1997-03-14 | 1998-09-17 | Basf Ag | Fungizide Mischung |
AU7913298A (en) | 1997-05-30 | 1998-12-30 | Basf Aktiengesellschaft | Fungicidal Mixtures |
-
1999
- 1999-06-11 UA UA2001064274A patent/UA70345C2/uk unknown
- 1999-11-06 JP JP2000583348A patent/JP2002530303A/ja active Pending
- 1999-11-06 BR BRPI9915503-6A patent/BR9915503B1/pt not_active IP Right Cessation
- 1999-11-06 DE DE59906388T patent/DE59906388D1/de not_active Expired - Lifetime
- 1999-11-06 SK SK678-2001A patent/SK284747B6/sk not_active IP Right Cessation
- 1999-11-06 IL IL14310199A patent/IL143101A/en not_active IP Right Cessation
- 1999-11-06 EP EP99972495A patent/EP1130967B1/de not_active Expired - Lifetime
- 1999-11-06 NZ NZ512191A patent/NZ512191A/en not_active IP Right Cessation
- 1999-11-06 AU AU11609/00A patent/AU767577B2/en not_active Ceased
- 1999-11-06 CZ CZ20011737A patent/CZ293437B6/cs not_active IP Right Cessation
- 1999-11-06 KR KR1020017006273A patent/KR100689931B1/ko not_active IP Right Cessation
- 1999-11-06 RO ROA200100535A patent/RO122006B1/ro unknown
- 1999-11-06 DK DK99972495T patent/DK1130967T3/da active
- 1999-11-06 CN CNB99814746XA patent/CN100518510C/zh not_active Expired - Lifetime
- 1999-11-06 RU RU2001116595/04A patent/RU2244420C2/ru not_active IP Right Cessation
- 1999-11-06 AT AT99972495T patent/ATE245354T1/de active
- 1999-11-06 CA CA002351819A patent/CA2351819C/en not_active Expired - Fee Related
- 1999-11-06 US US09/856,034 patent/US6503936B1/en not_active Expired - Lifetime
- 1999-11-06 WO PCT/EP1999/008512 patent/WO2000030450A1/de active IP Right Grant
- 1999-11-06 HU HU0104414A patent/HU228597B1/hu not_active IP Right Cessation
- 1999-11-06 PT PT99972495T patent/PT1130967E/pt unknown
- 1999-11-06 ES ES99972495T patent/ES2204196T3/es not_active Expired - Lifetime
- 1999-11-19 CO CO99073049A patent/CO5210926A1/es not_active Application Discontinuation
- 1999-11-19 AR ARP990105912A patent/AR021345A1/es active IP Right Grant
-
2001
- 2001-05-22 BG BG105537A patent/BG65003B1/bg unknown
- 2001-06-18 ZA ZA200104962A patent/ZA200104962B/en unknown
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