ZA200006426B - Method of making washable, dryable elastic articles. - Google Patents
Method of making washable, dryable elastic articles. Download PDFInfo
- Publication number
- ZA200006426B ZA200006426B ZA200006426A ZA200006426A ZA200006426B ZA 200006426 B ZA200006426 B ZA 200006426B ZA 200006426 A ZA200006426 A ZA 200006426A ZA 200006426 A ZA200006426 A ZA 200006426A ZA 200006426 B ZA200006426 B ZA 200006426B
- Authority
- ZA
- South Africa
- Prior art keywords
- interpolymer
- ethylene
- polymer
- percent
- elastic
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 36
- 229920000573 polyethylene Polymers 0.000 claims description 114
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 111
- 239000005977 Ethylene Substances 0.000 claims description 111
- 239000000835 fiber Substances 0.000 claims description 110
- 229920000642 polymer Polymers 0.000 claims description 103
- 238000000034 method Methods 0.000 claims description 77
- 239000003381 stabilizer Substances 0.000 claims description 62
- -1 polyethylene Polymers 0.000 claims description 53
- 238000002844 melting Methods 0.000 claims description 30
- 230000008018 melting Effects 0.000 claims description 30
- 238000001125 extrusion Methods 0.000 claims description 27
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 25
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 23
- 229910000077 silane Inorganic materials 0.000 claims description 22
- 239000004971 Cross linker Substances 0.000 claims description 20
- 238000010894 electron beam technology Methods 0.000 claims description 20
- 230000005855 radiation Effects 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 19
- 239000000654 additive Substances 0.000 claims description 16
- 229910052799 carbon Inorganic materials 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 238000009826 distribution Methods 0.000 claims description 14
- 239000000523 sample Substances 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 13
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- 239000003999 initiator Substances 0.000 claims description 11
- 238000000576 coating method Methods 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 10
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 10
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000007493 shaping process Methods 0.000 claims description 10
- 238000005227 gel permeation chromatography Methods 0.000 claims description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 8
- 238000005481 NMR spectroscopy Methods 0.000 claims description 7
- 239000004745 nonwoven fabric Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 6
- 230000005865 ionizing radiation Effects 0.000 claims description 6
- 150000003053 piperidines Chemical class 0.000 claims description 6
- 238000000518 rheometry Methods 0.000 claims description 6
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- 238000004458 analytical method Methods 0.000 claims description 5
- 238000001746 injection moulding Methods 0.000 claims description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 5
- 229920001059 synthetic polymer Polymers 0.000 claims description 5
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- 238000002360 preparation method Methods 0.000 claims description 4
- 150000003254 radicals Chemical class 0.000 claims description 4
- 238000003856 thermoforming Methods 0.000 claims description 4
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 claims description 3
- BXOUVIIITJXIKB-UHFFFAOYSA-N ethene;styrene Chemical group C=C.C=CC1=CC=CC=C1 BXOUVIIITJXIKB-UHFFFAOYSA-N 0.000 claims description 3
- 238000002074 melt spinning Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- NQRYJNQNLNOLGT-UHFFFAOYSA-N tetrahydropyridine hydrochloride Natural products C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 claims description 3
- 238000003490 calendering Methods 0.000 claims description 2
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- 208000015181 infectious disease Diseases 0.000 claims description 2
- 238000001175 rotational moulding Methods 0.000 claims description 2
- 239000002759 woven fabric Substances 0.000 claims description 2
- 229920005615 natural polymer Polymers 0.000 claims 4
- QPFMBZIOSGYJDE-MICDWDOJSA-N 1,1,2,2-tetrachloro-1-deuterioethane Chemical compound [2H]C(Cl)(Cl)C(Cl)Cl QPFMBZIOSGYJDE-MICDWDOJSA-N 0.000 claims 1
- 238000000071 blow moulding Methods 0.000 claims 1
- 239000006185 dispersion Substances 0.000 claims 1
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- 230000035882 stress Effects 0.000 description 38
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- 239000000126 substance Substances 0.000 description 16
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 14
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- 239000002131 composite material Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 230000001976 improved effect Effects 0.000 description 10
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- 238000012545 processing Methods 0.000 description 9
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- 239000004759 spandex Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 7
- 238000001723 curing Methods 0.000 description 7
- 238000011084 recovery Methods 0.000 description 7
- 150000004756 silanes Chemical class 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 229910002091 carbon monoxide Inorganic materials 0.000 description 6
- 238000010828 elution Methods 0.000 description 6
- 238000004900 laundering Methods 0.000 description 6
- 229920000092 linear low density polyethylene Polymers 0.000 description 6
- 239000004707 linear low-density polyethylene Substances 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 5
- 239000005041 Mylar™ Substances 0.000 description 5
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 5
- 238000005194 fractionation Methods 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 5
- LIKMAJRDDDTEIG-UHFFFAOYSA-N n-hexene Natural products CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- 230000006641 stabilisation Effects 0.000 description 5
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
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- UJAWGGOCYUPCPS-UHFFFAOYSA-N 4-(2-phenylpropan-2-yl)-n-[4-(2-phenylpropan-2-yl)phenyl]aniline Chemical compound C=1C=C(NC=2C=CC(=CC=2)C(C)(C)C=2C=CC=CC=2)C=CC=1C(C)(C)C1=CC=CC=C1 UJAWGGOCYUPCPS-UHFFFAOYSA-N 0.000 description 3
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- 206010021639 Incontinence Diseases 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
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- ORECYURYFJYPKY-UHFFFAOYSA-N n,n'-bis(2,2,6,6-tetramethylpiperidin-4-yl)hexane-1,6-diamine;2,4,6-trichloro-1,3,5-triazine;2,4,4-trimethylpentan-2-amine Chemical compound CC(C)(C)CC(C)(C)N.ClC1=NC(Cl)=NC(Cl)=N1.C1C(C)(C)NC(C)(C)CC1NCCCCCCNC1CC(C)(C)NC(C)(C)C1 ORECYURYFJYPKY-UHFFFAOYSA-N 0.000 description 2
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Classifications
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US8753698P | 1998-06-01 | 1998-06-01 |
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Publication number | Priority date | Publication date | Assignee | Title |
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US6709742B2 (en) * | 1998-05-18 | 2004-03-23 | Dow Global Technologies Inc. | Crosslinked elastic fibers |
AR018359A1 (es) * | 1998-05-18 | 2001-11-14 | Dow Global Technologies Inc | Articulo resistente al calor , configurado, irradiado y reticulado, libre de un agente de reticulacion de silano |
WO2001085843A1 (en) * | 2000-05-11 | 2001-11-15 | The Dow Chemical Company | Method of making elastic articles having improved heat-resistance |
WO2003078723A1 (en) * | 2002-03-11 | 2003-09-25 | Dow Global Technologies Inc. | Stretch fabric with improved chemical resistance and durability |
US20060011863A1 (en) * | 2001-06-28 | 2006-01-19 | E-Beam & Light, Inc. | Electron beam method and apparatus for improved melt point temperatures and optical clarity of halogenated optical materials |
US6951685B1 (en) * | 2001-11-27 | 2005-10-04 | Integrated Textile Systems, Inc. | Ultra high molecular weight polyethylene fibers |
EP1860214B1 (en) | 2002-03-11 | 2009-04-29 | Dow Global Technologies Inc. | Reversible, heat-set, elastic fibers, and method of making and articles made from same |
DE60313305T2 (de) | 2002-03-11 | 2007-12-27 | Dow Global Technologies, Inc., Midland | Reversible, thermofixierte, elastische fasern, herstellungsverfahren und daraus hergestellte artikel |
JP3877064B2 (ja) | 2002-07-18 | 2007-02-07 | 東洋紡績株式会社 | 弾性布帛及びその製造方法 |
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1999
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- 1999-05-27 EP EP99939815A patent/EP1086188B1/en not_active Expired - Lifetime
- 1999-05-27 IL IL13958199A patent/IL139581A0/xx not_active IP Right Cessation
- 1999-05-27 CA CA002332558A patent/CA2332558A1/en not_active Abandoned
- 1999-05-27 ID IDW20002468A patent/ID27047A/id unknown
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- 1999-05-27 CN CNB998069523A patent/CN1174042C/zh not_active Expired - Lifetime
- 1999-05-27 AU AU43166/99A patent/AU759029B2/en not_active Ceased
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US20020049269A1 (en) | 2002-04-25 |
KR100608402B1 (ko) | 2006-08-02 |
DE69933214D1 (de) | 2006-10-26 |
DE69933214T2 (de) | 2006-12-28 |
RU2226200C2 (ru) | 2004-03-27 |
IL139581A (en) | 2006-04-10 |
ATE339482T1 (de) | 2006-10-15 |
IL139581A0 (en) | 2002-02-10 |
WO1999063021A1 (en) | 1999-12-09 |
CN1304436A (zh) | 2001-07-18 |
US6559208B2 (en) | 2003-05-06 |
MY122449A (en) | 2006-04-29 |
AU759029B2 (en) | 2003-04-03 |
BR9911213B1 (pt) | 2010-11-16 |
EP1086188A1 (en) | 2001-03-28 |
ES2268877T3 (es) | 2007-03-16 |
ID27047A (id) | 2001-02-22 |
TW510904B (en) | 2002-11-21 |
AR019148A1 (es) | 2001-12-26 |
TR200003556T2 (tr) | 2001-04-20 |
EP1086188B1 (en) | 2006-09-13 |
JP2002517545A (ja) | 2002-06-18 |
AU4316699A (en) | 1999-12-20 |
KR20010052504A (ko) | 2001-06-25 |
CA2332558A1 (en) | 1999-12-09 |
BR9911213A (pt) | 2001-02-13 |
HK1035550A1 (en) | 2001-11-30 |
CN1174042C (zh) | 2004-11-03 |
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