YU45839B - Sestavina katalizatorja in katalizatorja za polimerizacijo etilena ali kopolimerizacijo etilena z alfa-olefinom ter postopek za pripravo te sestavine - Google Patents

Sestavina katalizatorja in katalizatorja za polimerizacijo etilena ali kopolimerizacijo etilena z alfa-olefinom ter postopek za pripravo te sestavine

Info

Publication number
YU45839B
YU45839B YU21988A YU21988A YU45839B YU 45839 B YU45839 B YU 45839B YU 21988 A YU21988 A YU 21988A YU 21988 A YU21988 A YU 21988A YU 45839 B YU45839 B YU 45839B
Authority
YU
Yugoslavia
Prior art keywords
titanium
catalyst
catalyst component
ratio
trivalent
Prior art date
Application number
YU21988A
Other languages
English (en)
Other versions
YU21988A (en
Inventor
R. Invernizzi
F. Masi
A. Moalli
Original Assignee
Enichem Anic S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Enichem Anic S.P.A. filed Critical Enichem Anic S.P.A.
Publication of YU21988A publication Critical patent/YU21988A/xx
Publication of YU45839B publication Critical patent/YU45839B/sh
Priority to HRP-219/88A priority Critical patent/HRP930611B1/xx
Priority to BA970162A priority patent/BA97162B1/bs

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

SESTAVINA KATALIZATORJA IN KATALIZATORJA ZA POLIMERIZACIJO ETILENA ALI KOPOLIMERIZACIJO ETILENA Z ALFA-OLEFINOM TER POSTOPEK ZA PRIPRAVO TE SESTAVINE, oznacen s tem, da je v obliki trdnih kroglastih zrn z najmanj okoli 80% zrn z velikostjo od 30 do 40 um, s specificno povrsino od 15 do 30 m2/g in s poroznostjo od 40 do 80 vol. %, in da jo lahko definiramo s formulo (v atomskih razmerjih): Til Mg0,3-3,1 Al0,4-0, 65Cl3,2-8,2 (Et + OEt + OR')1,9-3 kjer Et pomeni etilno skupino, OEt pomeni etoksi skupino in OR' pomeni alkoksi skupino z 1 do 9 atomi ogljika v nerazvejenem ali razvejenem alkilnem delu, in v kateri je razmerje med titanom v trivalentnem stanju in vsoto titana v trivalentnem in tetravalentnem stanju v obmocju od 0,8/1 do 1/1. Postopek za pripravo sestavine katalizatorja po zahtevkih 1 do 3, oz nacen s tem, da razprisilno posusimo etanolno raztopino magnezijevega klorida, da nastane trden, zrnat, kroglast in sipek nosilec, ki vsebuje od 18 do 25 mas.% alkoholnih hidroksilov, izrazenih kot etanol, ta nosilec suspendiramo v inertni tekocini, kot n-dekanu, in ga spravimo v stik in najprej presnovimo s titanovim tetraalkoksidom Ti(OR')4, kjer R' predstavlja nerazvejeno ali razvejeno alkilno skupino, ki vsebuje od 1 do 8 atomov ogljika, pri cemer delamo pri temperaturi med sobno temperaturo in 90 C z atomskim razmerjem med magnezijem v magnezijevem kloridu in titanom v titanovem tetralkoksidu od 0,5/1 do 3/1, in nato z dietil aluminijevim kloridom ali etil aluminijevim seskvikloridom, pri cemer delamo pri temperaturi med sobno temperaturo in 80 C z razmerjem med atomi klora v dietil aluminijevem kloridu ali etil aluminijevem seskvikloridu in alkoksi skupinami, ki izvirajo iz titanovega tetraalkoksida in iz etanola, v obmocju od 0,5/1 do 1,5, da dobimo trdno sestavino katalizatorja, v kateri je razmerje med titanom v trivalentnem stanju in vsoto titana v trivalentnem in tetravalentnem stanju v obmocju od 0,8/1 do 1/1 in iz ustrezne suspenzije pridobimo trdno sestavino katalizatorja. Prijava sadrzi se 9 patentnih zahtevkov.
YU21988A 1987-02-06 1988-02-04 Sestavina katalizatorja in katalizatorja za polimerizacijo etilena ali kopolimerizacijo etilena z alfa-olefinom ter postopek za pripravo te sestavine YU45839B (sh)

Priority Applications (2)

Application Number Priority Date Filing Date Title
HRP-219/88A HRP930611B1 (en) 1987-02-06 1993-03-30 Catalyser system and a catalyser for the polymerization or copolymerization of ethylene with alpha olefine
BA970162A BA97162B1 (bs) 1987-02-06 1997-04-24 Sastojak katalizatora i katalizator za polimerizaciju etilena ili kopolimerizaciju etilena sa alfa-olefinom te postupak za dobijanje ovog sastojka

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT19276/87A IT1203330B (it) 1987-02-06 1987-02-06 Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine

Publications (2)

Publication Number Publication Date
YU21988A YU21988A (en) 1989-10-31
YU45839B true YU45839B (sh) 1992-07-20

Family

ID=11156327

Family Applications (2)

Application Number Title Priority Date Filing Date
YU21988A YU45839B (sh) 1987-02-06 1988-02-04 Sestavina katalizatorja in katalizatorja za polimerizacijo etilena ali kopolimerizacijo etilena z alfa-olefinom ter postopek za pripravo te sestavine
YU107389A YU46934B (sh) 1987-02-06 1989-05-24 Postupak za polimerizaciju etilena ili kopolimerizaciju etilena sa alfa-olefinom

Family Applications After (1)

Application Number Title Priority Date Filing Date
YU107389A YU46934B (sh) 1987-02-06 1989-05-24 Postupak za polimerizaciju etilena ili kopolimerizaciju etilena sa alfa-olefinom

Country Status (16)

Country Link
US (1) US4843049A (sh)
EP (1) EP0281524B1 (sh)
JP (1) JP2622393B2 (sh)
AR (1) AR244256A1 (sh)
AT (1) ATE54318T1 (sh)
BR (1) BR8800484A (sh)
CA (1) CA1318909C (sh)
DE (1) DE3860281D1 (sh)
ES (1) ES2017012B3 (sh)
FI (1) FI91768C (sh)
GR (1) GR3000891T3 (sh)
HR (1) HRP930610B1 (sh)
IT (1) IT1203330B (sh)
NO (1) NO170637C (sh)
PT (1) PT86705B (sh)
YU (2) YU45839B (sh)

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KR100351386B1 (ko) 2000-04-24 2002-09-05 삼성종합화학주식회사 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법
KR100353960B1 (ko) 2000-05-31 2002-09-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체의 제조방법
KR100359932B1 (ko) 2000-06-15 2002-11-07 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매
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KR100389476B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100389475B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100389962B1 (ko) * 2000-11-10 2003-07-02 삼성종합화학주식회사 에틸렌 중합 또는 공중합용 촉매의 제조 방법
KR100421551B1 (ko) * 2000-12-16 2004-03-09 삼성아토피나주식회사 올레핀 전중합 촉매 및 이를 이용한 올레핀 중합방법
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Also Published As

Publication number Publication date
IT8719276A0 (it) 1987-02-06
EP0281524A2 (en) 1988-09-07
IT1203330B (it) 1989-02-15
FI91768B (fi) 1994-04-29
NO170637C (no) 1992-11-11
AR244256A1 (es) 1993-10-29
YU21988A (en) 1989-10-31
DE3860281D1 (de) 1990-08-09
YU107389A (en) 1990-04-30
JPS63289005A (ja) 1988-11-25
HRP930610B1 (en) 1998-08-31
JP2622393B2 (ja) 1997-06-18
ATE54318T1 (de) 1990-07-15
FI880547A (fi) 1988-08-07
GR3000891T3 (en) 1991-11-15
FI91768C (fi) 1994-08-10
PT86705A (pt) 1988-03-01
PT86705B (pt) 1992-04-30
US4843049A (en) 1989-06-27
EP0281524B1 (en) 1990-07-04
EP0281524A3 (en) 1988-09-14
BR8800484A (pt) 1988-09-27
ES2017012B3 (es) 1990-12-16
NO170637B (no) 1992-08-03
HRP930610A2 (en) 1996-04-30
NO880456L (no) 1988-08-08
NO880456D0 (no) 1988-02-02
CA1318909C (en) 1993-06-08
FI880547A0 (fi) 1988-02-05
YU46934B (sh) 1994-06-24

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