WO2024087545A1 - Device and method for producing carbon-nitrogen synergistic ultrahigh-nitrogen steel by means of multi-furnace pressure casting - Google Patents

Device and method for producing carbon-nitrogen synergistic ultrahigh-nitrogen steel by means of multi-furnace pressure casting Download PDF

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WO2024087545A1
WO2024087545A1 PCT/CN2023/089784 CN2023089784W WO2024087545A1 WO 2024087545 A1 WO2024087545 A1 WO 2024087545A1 CN 2023089784 W CN2023089784 W CN 2023089784W WO 2024087545 A1 WO2024087545 A1 WO 2024087545A1
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nitrogen
casting
pressure
furnace
steel
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PCT/CN2023/089784
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French (fr)
Chinese (zh)
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刘吉猛
王书桓
赵定国
宋琼
张福成
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华北理工大学
燕山大学
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Publication of WO2024087545A1 publication Critical patent/WO2024087545A1/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D18/00Pressure casting; Vacuum casting
    • B22D18/06Vacuum casting, i.e. making use of vacuum to fill the mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D1/00Treatment of fused masses in the ladle or the supply runners before casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/14Closures
    • B22D41/16Closures stopper-rod type, i.e. a stopper-rod being positioned downwardly through the vessel and the metal therein, for selective registry with the pouring opening
    • B22D41/20Stopper-rod operating equipment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D41/00Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
    • B22D41/14Closures
    • B22D41/22Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/38Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • the invention belongs to the technical field of ultra-high nitrogen steel casting, and relates to a device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting.
  • ultra-high nitrogen steel has become more and more extensive, especially in wear-resistant steel, steel for train tracks and steel for marine engineering.
  • Ultra-high nitrogen steel is divided into high nitrogen high manganese steel and high nitrogen marine engineering steel according to its different uses.
  • Ordinary high manganese steel contains higher carbon, which enhances wear resistance, but has poor corrosion resistance. Reducing the carbon element in high manganese steel, adding nitrogen, and utilizing the carbon-nitrogen synergistic enhancement mechanism can not only improve the wear resistance of the material, but also make it have good corrosion resistance.
  • Marine engineering steel generally uses non-corrosion-resistant ordinary carbon steel, which has a short service life and high replacement cost. Although stainless steel is partially used, the mechanical properties of conventional stainless steel are low and cannot meet the requirements of the complex marine environment.
  • the industrial production generally contains nitrogen-containing high manganese steel with a nitrogen content of less than 0.2% and nitrogen-containing marine engineering steel with a nitrogen content of less than 0.4%.
  • the effect of nitrogen on improving material performance is not obvious.
  • the main reason is that under normal conditions, nitrogen has to pass through a ⁇ -Fe zone with a particularly low nitrogen solubility during the solidification of molten steel, resulting in low nitrogen content in this type of steel during solidification and prone to defects such as solidification porosity.
  • the main ways to increase the solidification rate of molten steel are to add cold steel to the molten steel, use directional solidification or increase the heat exchange between the molten steel and the mold.
  • high nitrogen steel generally has a relatively high manganese content
  • the molten steel shrinks greatly during solidification, and has poor heat dissipation. Excessively high cooling rates can easily lead to increased internal stress in the material and even internal cracks.
  • the main purpose of pressure casting is to provide a suitable environmental pressure during the solidification process of molten steel so that nitrogen can be better dissolved in the steel to increase the nitrogen solubility in high-nitrogen steel; and pressure casting can not only increase the nitrogen content, but also reduce the segregation of nitrogen components, improve the uniformity of material organization, and greatly improve the performance and application range of the material.
  • the present invention provides a device and method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting, which can not only effectively utilize the carbon-nitrogen synergistic mechanism to reduce the carbon in the steel, increase and stabilize the nitrogen content in the steel, and reduce component segregation, but also realize the casting and solidification of ultra-high nitrogen steel with different casting molds in multiple furnaces under pressurized conditions, which is suitable for the industrial production of various castings and improves product performance.
  • the present invention provides the following technical solutions:
  • a multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel comprising a ladle, a casting chamber located at the bottom of the ladle, and a casting mold arranged inside the casting chamber;
  • the top of the ladle is provided with a furnace cover, a stopper rod control mechanism is provided inside and a three-layer sliding gate is opened at the bottom of the steel outlet; the upper slide plate of the three-layer sliding gate is connected to the gate at the bottom of the ladle, and the lower slide plate is connected to a high-pressure resistant pipe;
  • the top of the casting chamber is provided with a furnace cover 2, and the furnace cover 2 is provided with a three-layer sliding water gate 2;
  • the upper slide plate of the three-layer sliding nozzle 2 is connected to the high-pressure resistant pipe 2, and the lower slide plate is connected to the pressure-resistant casting long nozzle;
  • the casting mold is a cavity structure formed by upper and lower double molds.
  • the top of the casting mold is provided with a plurality of risers and a pouring port, and the pouring port is located below the pressure-resistant casting long nozzle.
  • a furnace cover hanging ring is provided in the center of the furnace cover 1, and a nitrogen pressurizing hole, a pressure relief valve and a pressure gauge are provided on the furnace cover 1.
  • the stopper rod control mechanism can control the lifting and lowering of the stopper rod; and the stopper rod control mechanism includes a base fixedly connected to the inside of the furnace cover, a bracket parallel to the stopper rod Y direction, and a clamp that can be electrically controlled to move in the bracket Y direction.
  • stopper rod control mechanism is easy to implement in the field of mechanical control, that is, a linear displacement device in the Y direction.
  • the stopper rod only needs to move up and down, and the displacement is very small to control the flow of molten steel.
  • a bottom blowing hole is provided at the bottom of the ladle, and the ladle and the furnace cover are surrounded by sealing bolts to form a closed furnace chamber.
  • the ladle is supported by a hollow support platform, and the casting chamber is located at the bottom of the hollow support platform.
  • the furnace cover 2 is provided with a pressure gauge and a pressure relief valve, and the side wall of the casting chamber is provided with pressurized vacuum inlet and outlet holes; and the furnace cover 2 and the casting chamber are surrounded by sealing bolts to form a closed furnace cavity.
  • the high-pressure resistant pipeline 1 is connected to the high-pressure resistant pipeline 2 via a multi-furnace conversion joint.
  • the present invention also claims a method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting, which is a method for producing carbon-nitrogen synergistic ultra-high nitrogen steel using the above-mentioned device, specifically comprising the following steps:
  • the stopper rod is controlled to descend to seal the water inlet of the ladle, the middle slide plates of the three-layer sliding water inlet 1 and the three-layer sliding water inlet 2 are closed respectively, the multi-furnace conversion joint is opened, the pressure in the casting chamber is always paid attention to so as to perform appropriate pressure replenishment operation, and the ladle is hoisted above another casting chamber for casting of the next casting mold;
  • pressurization can increase the dissolved nitrogen content during the casting process, and vacuuming and furnace cleaning can improve the purity of the material.
  • composition of the carbon-nitrogen synergistic ultra-high nitrogen steel mainly produced using the above-mentioned casting device is: C 0 ⁇ 0.8%, Si 0 ⁇ 0.5%, Cr 4 ⁇ 20%, Mn 11 ⁇ 20%, N 0.3 ⁇ 1.4%, S 0 ⁇ 0.02%, P 0 ⁇ 0.02%, and the rest is iron.
  • the device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting provided by the present invention has the following excellent effects:
  • the present invention mainly comprises a pressurized ladle, a multi-furnace pressurized casting chamber, a conversion and connection device between the multiple furnaces, and a cast carbon-nitrogen synergistic ultra-high nitrogen steel special steel.
  • a pressurized ladle bottom blowing nitrogen stirring and nitrogen pressure are adopted to realize high nitrogen alloy homogenization of molten steel.
  • Pressurized solidification is carried out in the casting chamber to inhibit nitrogen escape, improve element segregation, and greatly enhance the wear resistance and corrosion resistance of the special steel with reduced carbon and increased nitrogen.
  • the present invention designs the pressurized ladle and the pressurized casting chamber separately. Through multiple pressurized casting chambers and conversion and connection devices, pressurized casting of different casting materials in multiple furnaces can be realized, thereby greatly improving the production efficiency of the special steel.
  • the ultra-high nitrogen steel cast by the present invention has a high nitrogen content and a uniform composition, and can meet the corrosion-resistant use requirements in special environments such as train tracks, frogs, and marine engineering.
  • FIG1 is a schematic diagram of the structure of a multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel.
  • FIG. 2 is a microstructural morphology of nitrogen-containing or high-nitrogen high-manganese steel with a nitrogen content of 0.18% (a) at normal pressure solidification and a nitrogen content of 0.54% (b) at pressurized solidification.
  • the embodiment of the present invention discloses a device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting.
  • the carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
  • the carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
  • the carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
  • control the stopper rod to descend to seal the ladle water inlet, close the middle slide of the three-layer sliding water inlet one, close the middle slide of the three-layer sliding water inlet two, open the multi-furnace conversion joint between the two high-pressure resistant pipes, always pay attention to the pressure in the casting chamber, perform appropriate pressure replenishment operations, and hoist the ladle to the top of another casting chamber for casting of the next mold.
  • FIG2a the microstructure morphology of the atmospheric solidified high manganese steel with a nitrogen content of 0.18% is shown in FIG2a
  • FIG2b the microstructure of the pressurized solidified high manganese steel with a nitrogen content of 0.54% is shown in FIG2b.
  • the tensile properties are shown in Table 2.
  • the nitrogen content of the high manganese steel is generally less than 0.18%, and the nitrogen content of the marine steel is generally less than 0.4%. It can be seen from Table 1 that the nitrogen content of the ultra-high nitrogen steel produced by casting with the pressurized device is very high. Under the conditions of pressure casting and pressurized solidification, the nitrogen content reaches 0.38%, 0.54% and 1.1% respectively. Increasing the nitrogen content in the steel can not only improve the corrosion resistance of the material, but also improve its mechanical properties.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)

Abstract

A device for producing a carbon-nitrogen synergistic ultrahigh-nitrogen steel by means of multi-furnace pressure casting. The device comprises a pressurizable steel ladle (22), a pressurizable casting chamber (13) located at the bottom of the steel ladle, and a casting mold (14) provided inside the casting chamber. A tap hole at the bottom of the steel ladle is provided with a three-layer slide gate I (9), and a furnace lid II (18) at the top of the casting chamber is provided with a three-layer slide gate II (11); a high-pressure-resistant pipeline I (20) is connected to a lower sliding plate of the three-layer slide gate I, and a high-pressure-resistant pipeline II (19) is connected to an upper sliding plate of the three-layer slide gate II; and the high-pressure-resistant pipeline I and the high-pressure-resistant pipeline II are connected by means of a multi-furnace conversion joint (10). Further provided is a method for producing a carbon-nitrogen synergistic ultrahigh-nitrogen steel by means of multi-furnace pressure casting. By using the device, high-nitrogen alloy homogenization of molten steel is achieved in the pressurizable steel ladle by performing bottom-blowing nitrogen stirring and increasing the nitrogen pressure; and pressurizing solidification is performed in the casting chamber, and the escaping of nitrogen is inhibited. The pressurizable steel ladle and the pressurizable casting chamber are separately designed, and pressurizing casting of different casting materials in multiple furnaces can be achieved by means of multiple pressurizable casting chambers and multi-furnace conversion joints, thereby improving the production efficiency of a special steel type. The cast ultrahigh-nitrogen steel has a high nitrogen content and uniform components, and can satisfy the corrosion-resistant usage requirements in special environments such as train rails, railroad frogs and ocean engineering.

Description

一种多炉加压浇铸生产碳氮协同超高氮钢装置及方法A device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting 技术领域Technical Field
本发明属于超高氮钢浇铸技术领域,涉及一种多炉加压浇铸生产碳氮协同超高氮钢装置及方法。The invention belongs to the technical field of ultra-high nitrogen steel casting, and relates to a device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting.
背景技术Background technique
超高氮钢的应用领域已越来越广泛,特别是在耐磨钢、列车轨道用钢及海洋工程用钢方面,但随着工业发展及工作环境的需要,对材料提出更加苛刻的要求。超高氮钢按其用途不同又分为高氮高锰钢和高氮海工钢,普通高锰钢中含有较高碳,增强了耐磨性能,但耐腐蚀性能较差,降低高锰钢中碳元素,添加氮元素,利用碳氮协同增强机制,不仅可以提高材料耐磨性能,还使其具有很好的耐腐蚀性能。海洋工程用钢一般采用不耐腐蚀的普碳钢,使用年限短,更换成本高,不锈钢虽有部分使用,但常规不锈钢的力学性能低,不能满足海洋复杂环境的要求。The application field of ultra-high nitrogen steel has become more and more extensive, especially in wear-resistant steel, steel for train tracks and steel for marine engineering. However, with the development of industry and the needs of the working environment, more stringent requirements are placed on materials. Ultra-high nitrogen steel is divided into high nitrogen high manganese steel and high nitrogen marine engineering steel according to its different uses. Ordinary high manganese steel contains higher carbon, which enhances wear resistance, but has poor corrosion resistance. Reducing the carbon element in high manganese steel, adding nitrogen, and utilizing the carbon-nitrogen synergistic enhancement mechanism can not only improve the wear resistance of the material, but also make it have good corrosion resistance. Marine engineering steel generally uses non-corrosion-resistant ordinary carbon steel, which has a short service life and high replacement cost. Although stainless steel is partially used, the mechanical properties of conventional stainless steel are low and cannot meet the requirements of the complex marine environment.
目前工业生产的一般为氮含量低于0.2%的含氮高锰钢和氮含量低于0.4%的含氮海工钢,氮元素对材料性能提升的作用不太明显。主要原因是在常规条件下,氮在钢液凝固过程中要经过一个氮溶解度特别低的δ-Fe区,导致该钢种凝固时氮含量不高并容易产生凝固疏松等缺陷。At present, the industrial production generally contains nitrogen-containing high manganese steel with a nitrogen content of less than 0.2% and nitrogen-containing marine engineering steel with a nitrogen content of less than 0.4%. The effect of nitrogen on improving material performance is not obvious. The main reason is that under normal conditions, nitrogen has to pass through a δ-Fe zone with a particularly low nitrogen solubility during the solidification of molten steel, resulting in low nitrogen content in this type of steel during solidification and prone to defects such as solidification porosity.
目前提高高氮钢中氮含量的方法主要有两种,一种是提高钢水凝固速率,缩短凝固过程中δ铁素体形成区间的凝固时间,减少氮元素的逸出;另一种是提高钢水凝固过程中周围大气压力,形成高压凝固氛围,高压可以缩小凝固过程中的δ铁素体形成区域,甚至使δ铁素体区消失。 At present, there are two main methods to increase the nitrogen content in high nitrogen steel. One is to increase the solidification rate of molten steel, shorten the solidification time of the delta ferrite formation zone during the solidification process, and reduce the escape of nitrogen; the other is to increase the surrounding atmospheric pressure during the solidification of molten steel to form a high-pressure solidification atmosphere. High pressure can reduce the delta ferrite formation area during the solidification process, and even make the delta ferrite area disappear.
其中,提高钢水凝固速率的主要方式为向钢液中加入冷钢、采用定向凝固或增加钢液与铸模的热交换,但高氮钢一般锰含量均比较高,钢水凝固收缩大,散热性差,过高的冷却速率易导致材料内部应力增大甚至产生内裂纹。Among them, the main ways to increase the solidification rate of molten steel are to add cold steel to the molten steel, use directional solidification or increase the heat exchange between the molten steel and the mold. However, high nitrogen steel generally has a relatively high manganese content, the molten steel shrinks greatly during solidification, and has poor heat dissipation. Excessively high cooling rates can easily lead to increased internal stress in the material and even internal cracks.
然而,加压浇铸主要目的是在钢水凝固过程中,提供一个合适的环境压力,使氮可以更好的固溶在钢中,以提高高氮钢中的氮溶解度;且加压浇铸不仅可以提高氮含量,还可以降低氮元素成分偏析,提高材料组织均匀性,大大提高材料的性能及使用范围。However, the main purpose of pressure casting is to provide a suitable environmental pressure during the solidification process of molten steel so that nitrogen can be better dissolved in the steel to increase the nitrogen solubility in high-nitrogen steel; and pressure casting can not only increase the nitrogen content, but also reduce the segregation of nitrogen components, improve the uniformity of material organization, and greatly improve the performance and application range of the material.
因此,如何提供一种既能提高高氮钢中氮含量又能改善材料性能的多炉加压浇铸生产碳氮协同超高氮钢装置及方法是本领域技术人员亟需解决的技术问题。Therefore, how to provide a device and method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting that can both increase the nitrogen content in high nitrogen steel and improve material properties is a technical problem that technical personnel in this field urgently need to solve.
发明内容Summary of the invention
有鉴于此,本发明提供了一种多炉加压浇铸生产碳氮协同超高氮钢装置及方法,不仅能够有效利用碳氮协同机制降低钢中的碳,提高和稳定钢中氮含量,减轻成分偏析,还能实现多炉不同铸型超高氮钢在加压条件下浇铸、凝固,适合工业化各种铸件的生产,提高产品性能。In view of this, the present invention provides a device and method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting, which can not only effectively utilize the carbon-nitrogen synergistic mechanism to reduce the carbon in the steel, increase and stabilize the nitrogen content in the steel, and reduce component segregation, but also realize the casting and solidification of ultra-high nitrogen steel with different casting molds in multiple furnaces under pressurized conditions, which is suitable for the industrial production of various castings and improves product performance.
为了实现上述目的,本发明提供如下技术方案:In order to achieve the above object, the present invention provides the following technical solutions:
一种多炉加压浇铸生产碳氮协同超高氮钢装置,所述装置包括钢包,位于所述钢包底部的铸造室及设置在所述铸造室内部的铸模;其中,A multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel, the device comprising a ladle, a casting chamber located at the bottom of the ladle, and a casting mold arranged inside the casting chamber; wherein:
所述钢包的顶部设有炉盖一,内部设有塞棒控制机构及底部出钢口处开设有三层式滑动水口一;所述三层式滑动水口一的上滑板与所述钢包底部的水口连接,下滑板与耐高压管道一连接;The top of the ladle is provided with a furnace cover, a stopper rod control mechanism is provided inside and a three-layer sliding gate is opened at the bottom of the steel outlet; the upper slide plate of the three-layer sliding gate is connected to the gate at the bottom of the ladle, and the lower slide plate is connected to a high-pressure resistant pipe;
所述铸造室的顶部设有炉盖二,所述炉盖二上设有三层式滑动水口二;所 述三层式滑动水口二的上滑板与耐高压管道二连接,下滑板与耐压浇铸长水口连接;The top of the casting chamber is provided with a furnace cover 2, and the furnace cover 2 is provided with a three-layer sliding water gate 2; The upper slide plate of the three-layer sliding nozzle 2 is connected to the high-pressure resistant pipe 2, and the lower slide plate is connected to the pressure-resistant casting long nozzle;
所述铸模是由上下双开模形成的空腔结构,所述铸模的顶部设有多个冒口和一个浇注口,且所述浇铸口位于所述耐压浇铸长水口的下方。The casting mold is a cavity structure formed by upper and lower double molds. The top of the casting mold is provided with a plurality of risers and a pouring port, and the pouring port is located below the pressure-resistant casting long nozzle.
可选地,所述炉盖一的中央设有炉盖吊环,且所述炉盖一上设置有氮气加压孔、泄压阀和压力表。Optionally, a furnace cover hanging ring is provided in the center of the furnace cover 1, and a nitrogen pressurizing hole, a pressure relief valve and a pressure gauge are provided on the furnace cover 1.
可选地,所述塞棒控制机构能控制塞棒的升降;且所述塞棒控制机构包括与所述炉盖内部固定连接的基座、与所述塞棒Y方向平行的支架及可电动控制在所述支架Y方向移动的夹具。Optionally, the stopper rod control mechanism can control the lifting and lowering of the stopper rod; and the stopper rod control mechanism includes a base fixedly connected to the inside of the furnace cover, a bracket parallel to the stopper rod Y direction, and a clamp that can be electrically controlled to move in the bracket Y direction.
需要说明的是,塞棒控制机构在机械控制领域很容易实现,即Y方向线性位移器。所述塞棒只需上下移动,且移动位移很小就可以控制钢水的流动。It should be noted that the stopper rod control mechanism is easy to implement in the field of mechanical control, that is, a linear displacement device in the Y direction. The stopper rod only needs to move up and down, and the displacement is very small to control the flow of molten steel.
可选地,所述钢包的底部设有底吹孔,且所述钢包与所述炉盖一通过密封螺栓围成封闭的炉腔。Optionally, a bottom blowing hole is provided at the bottom of the ladle, and the ladle and the furnace cover are surrounded by sealing bolts to form a closed furnace chamber.
进一步地,所述钢包由中空式支撑平台支撑,及所述铸造室位于所述中空式支撑平台的底部。Furthermore, the ladle is supported by a hollow support platform, and the casting chamber is located at the bottom of the hollow support platform.
可选地,所述炉盖二上设有压力表和泄压阀,所述铸造室的侧壁开设有加压抽真空进出气孔;且所述炉盖二与所述铸造室通过密封螺栓围成封闭的炉腔。Optionally, the furnace cover 2 is provided with a pressure gauge and a pressure relief valve, and the side wall of the casting chamber is provided with pressurized vacuum inlet and outlet holes; and the furnace cover 2 and the casting chamber are surrounded by sealing bolts to form a closed furnace cavity.
可选地,所述耐高压管道一与所述耐高压管道二通过多炉转换接头连接。Optionally, the high-pressure resistant pipeline 1 is connected to the high-pressure resistant pipeline 2 via a multi-furnace conversion joint.
此外,本发明还请求保护一种多炉加压浇铸生产碳氮协同超高氮钢的方法,其是采用上述装置生产碳氮协同超高氮钢的方法,具体包括如下步骤:In addition, the present invention also claims a method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting, which is a method for producing carbon-nitrogen synergistic ultra-high nitrogen steel using the above-mentioned device, specifically comprising the following steps:
1)将冶炼出的含有过饱和氮的钢水加入所述钢包中,对所述钢包加炉盖一密封处理后,经钢包底吹孔进行底吹氮气搅拌和氮气加压孔进行加压操作, 压力控制在0-6MPa范围内;1) adding the molten steel containing supersaturated nitrogen into the ladle, sealing the ladle with a furnace cover, stirring with bottom blowing nitrogen through the ladle bottom blowing hole and pressurizing with nitrogen through the nitrogen pressurizing hole, The pressure is controlled within the range of 0-6MPa;
2)将所述铸模放入所述铸造室的内部,对所述铸造室通过加压抽真空进出气孔进行先抽真空至10Pa以下,再氮气洗炉一次,随后抽真空后采用氮气加压操作,直至达到指定压力;2) placing the casting mold into the casting chamber, evacuating the casting chamber to below 10 Pa by pressurizing the vacuum inlet and outlet holes, washing the furnace with nitrogen once, and then vacuumizing and pressurizing with nitrogen until the specified pressure is reached;
3)将所述钢包吊至所述铸造室上方的中空式支撑平台上,并将所述耐高压管道一与所述耐高压管道二通过多炉转换接头连接;3) hoisting the ladle onto the hollow support platform above the casting chamber, and connecting the high-pressure resistant pipe 1 and the high-pressure resistant pipe 2 through a multi-furnace conversion joint;
4)打开所述三层式滑动水口二的中间滑板,使耐高压管道内压力与所述铸造室内相同;4) opening the middle slide plate of the three-layer sliding gate 2 to make the pressure in the high-pressure resistant pipeline the same as that in the casting chamber;
5)打开三层式滑动水口一的中间滑板并控制塞棒上升,进行浇铸;5) Open the middle slide of the three-layer sliding gate and control the stopper rod to rise for casting;
6)待浇铸完成后,控制塞棒下降以封住所述钢包的水口,分别关闭三层式滑动水口一和所述三层式滑动水口二的中间滑板,打开所述多炉转换接头,时刻关注所述铸造室内的压力情况,以进行适当补压操作,并将所述钢包吊至另一个铸造室上方进行下一个铸型的浇铸;6) After the casting is completed, the stopper rod is controlled to descend to seal the water inlet of the ladle, the middle slide plates of the three-layer sliding water inlet 1 and the three-layer sliding water inlet 2 are closed respectively, the multi-furnace conversion joint is opened, the pressure in the casting chamber is always paid attention to so as to perform appropriate pressure replenishment operation, and the ladle is hoisted above another casting chamber for casting of the next casting mold;
7)保持所述铸造室内压力恒定直至钢液完全凝固完成,打开泄压阀放气至常压后打开所述铸造室的上盖,吊出所述铸模并打开,即得到碳氮协同超高氮钢。7) Maintaining a constant pressure in the casting chamber until the molten steel is completely solidified, opening the pressure relief valve to release air to normal pressure, and then opening the upper cover of the casting chamber, lifting out the casting mold and opening it, thereby obtaining carbon-nitrogen synergistic ultra-high nitrogen steel.
需要说明的是,加压可以提高铸造过程中氮的溶解含量,抽真空及洗炉可以提高材料的纯净度。It should be noted that pressurization can increase the dissolved nitrogen content during the casting process, and vacuuming and furnace cleaning can improve the purity of the material.
进一步地,使用上述浇铸装置主要生产碳氮协同超高氮钢的成分为:C 0~0.8%,Si 0~0.5%,Cr 4~20%,Mn 11~20%,N 0.3~1.4%,S 0~0.02%,P 0~0.02%,其余为铁。Furthermore, the composition of the carbon-nitrogen synergistic ultra-high nitrogen steel mainly produced using the above-mentioned casting device is: C 0~0.8%, Si 0~0.5%, Cr 4~20%, Mn 11~20%, N 0.3~1.4%, S 0~0.02%, P 0~0.02%, and the rest is iron.
经由上述的技术方案可知,与现有技术相比,本发明提供的一种多炉加压浇铸生产碳氮协同超高氮钢装置及方法,具有如下优异效果: It can be seen from the above technical solutions that, compared with the prior art, the device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting provided by the present invention has the following excellent effects:
本发明主要包括加压钢包、多炉加压铸造室、多炉间的转换连接装置以及浇铸的碳氮协同超高氮钢特殊钢种,在加压钢包中采用底吹氮气搅拌和加氮气压力下实现钢液的高氮合金均匀化,铸造室内加压凝固,抑制氮的逸出,改善元素偏析,较大提升降碳增氮的特殊钢种耐磨、耐蚀性;且本发明将加压钢包与加压铸造室分开设计,通过多个加压铸造室及转换连接装置可以实现多炉不同铸型材料的加压浇铸,大大提高该特殊钢种的生产效率。The present invention mainly comprises a pressurized ladle, a multi-furnace pressurized casting chamber, a conversion and connection device between the multiple furnaces, and a cast carbon-nitrogen synergistic ultra-high nitrogen steel special steel. In the pressurized ladle, bottom blowing nitrogen stirring and nitrogen pressure are adopted to realize high nitrogen alloy homogenization of molten steel. Pressurized solidification is carried out in the casting chamber to inhibit nitrogen escape, improve element segregation, and greatly enhance the wear resistance and corrosion resistance of the special steel with reduced carbon and increased nitrogen. In addition, the present invention designs the pressurized ladle and the pressurized casting chamber separately. Through multiple pressurized casting chambers and conversion and connection devices, pressurized casting of different casting materials in multiple furnaces can be realized, thereby greatly improving the production efficiency of the special steel.
通过采用本发明浇铸的超高氮钢的氮含量高,成分均匀,可以满足列车轨道、辙叉、海洋工程等特殊环境下的耐腐蚀使用要求。The ultra-high nitrogen steel cast by the present invention has a high nitrogen content and a uniform composition, and can meet the corrosion-resistant use requirements in special environments such as train tracks, frogs, and marine engineering.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
为了更清楚地说明本发明实施例或现有技术中的技术方案,下面将对实施例或现有技术描述中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本发明的实施例,对于本领域普通技术人员来讲,在不付出创造性劳动的前提下,还可以根据提供的附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required for use in the embodiments or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are only embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on the provided drawings without paying creative work.
图1为多炉加压浇铸生产碳氮协同超高氮钢装置的结构示意图。FIG1 is a schematic diagram of the structure of a multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel.
图2为常压凝固氮含量0.18%(a)和加压凝固氮含量0.54%(b)含氮或高氮高锰钢的显微组织形貌图。FIG. 2 is a microstructural morphology of nitrogen-containing or high-nitrogen high-manganese steel with a nitrogen content of 0.18% (a) at normal pressure solidification and a nitrogen content of 0.54% (b) at pressurized solidification.
其中,图1中:Among them, in Figure 1:
1-炉盖一;2-氮气加压孔;3-泄压阀;4-炉盖吊环;5-压力表;6-塞棒控制机构;7-密封螺栓;8-塞棒;9-三层式滑动水口一;10-多炉转换接头;11-三层式滑动水口一;12-中空式支撑平台;13-铸造室;14-铸模;15-浇铸口;16-冒口;17-加压抽真空进出气孔;18-炉盖二;19-耐高压管道二;20-耐高压管道一;21-钢包底吹孔;22-钢包。1-furnace cover one; 2-nitrogen pressurizing hole; 3-pressure relief valve; 4-furnace cover lifting ring; 5-pressure gauge; 6-stopper rod control mechanism; 7-sealing bolt; 8-stopper rod; 9-three-layer sliding gate one; 10-multi-furnace conversion joint; 11-three-layer sliding gate one; 12-hollow support platform; 13-casting chamber; 14-casting mold; 15-casting mouth; 16-riser; 17-pressurized vacuum inlet and outlet holes; 18-furnace cover two; 19-high-pressure resistant pipeline two; 20-high-pressure resistant pipeline one; 21-bottom blowing hole of ladle; 22-ladle.
具体实施方式Detailed ways
下面将结合本发明实施例及说明书附图,对本发明实施例中的技术方案进 行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention will be described below in combination with the embodiments of the present invention and the accompanying drawings. The present invention is clearly and completely described. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
本发明实施例公开了一种多炉加压浇铸生产碳氮协同超高氮钢装置及方法。The embodiment of the present invention discloses a device and method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting.
为更好地理解本发明,下面通过以下实施例对本发明作进一步具体的阐述,但不可理解为对本发明的限定,对于本领域的技术人员根据上述发明内容所作的一些非本质的改进与调整,也视为落在本发明的保护范围内。In order to better understand the present invention, the present invention is further specifically described below through the following examples, but it should not be understood as a limitation of the present invention. Some non-essential improvements and adjustments made by technicians in this field based on the above invention content are also considered to fall within the protection scope of the present invention.
下面,将结合具体实施例,对本发明的技术方案作进一步的说明。The technical solution of the present invention will be further described below in conjunction with specific embodiments.
实施例1Example 1
使用本发明的碳氮协同超高氮钢浇铸装置进行超高氮钢浇铸,浇铸生产方法如下:The carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
1、将冶炼出的含有过饱和氮的钢水加入钢包中,对钢包加盖密封处理后进行底吹氮气搅拌和氮气加压至0.6MPa并保持压力恒定。1. Add the molten steel containing supersaturated nitrogen into the ladle, cover and seal the ladle, then stir with bottom-blown nitrogen and pressurize the nitrogen to 0.6 MPa and keep the pressure constant.
2、将铸模放入铸造室内,对铸造室进行先抽真空至10Pa以下,停止抽真空,充氮气至常压,再次开始抽真空至10Pa以下,停止抽真空,对铸造室充氮气加压操作,直到压力达到1.2MPa。2. Place the mold into the casting chamber, evacuate the casting chamber to below 10Pa, stop evacuating, fill with nitrogen to normal pressure, evacuate the casting chamber to below 10Pa again, stop evacuating, and pressurize the casting chamber with nitrogen until the pressure reaches 1.2MPa.
3、将钢包吊至铸造室上方支撑架上,将两耐高压管道采用多炉转换接头链接。3. Hang the ladle onto the support frame above the casting chamber and connect the two high-pressure resistant pipes with a multi-furnace conversion joint.
4、打开三层式滑动水口二的中间滑板,使耐高压管道内压力与铸造室内相同。4. Open the middle slide of the three-layer sliding gate 2 to make the pressure inside the high-pressure resistant pipe the same as that in the casting chamber.
5、打开三层式滑动水口一的中间滑板并控制塞棒上升,进行浇铸作业。5. Open the middle slide of the three-layer sliding gate and control the stopper rod to rise to carry out casting operations.
6、浇铸完成后,控制塞棒下降封住钢包水口,关闭三层式滑动水口一的 中间滑板,关闭三层式滑动水口二的中间滑板,打开两耐高压管道之间的多炉转换接头,时刻关注铸造室内压力情况,进行适当补压操作,并将钢包吊至另一个铸造室上方进行下一个铸型的浇铸。6. After casting is completed, control the stopper rod to descend to seal the ladle water inlet and close the three-layer sliding water inlet. Middle slide, close the middle slide of the three-layer sliding gate 2, open the multi-furnace conversion joint between the two high-pressure resistant pipes, always pay attention to the pressure situation in the casting chamber, perform appropriate pressure replenishment operations, and hoist the ladle to the top of another casting chamber for casting of the next mold.
7、保持铸造室内压力恒定在1.2MPa直至钢液完全凝固,打开泄压阀放气至常压后打开铸造室上盖,吊出铸模,打开铸模即可得到超高氮钢,测量该超高氮钢的氮含量为0.38%。7. Maintain the pressure in the casting chamber at a constant 1.2 MPa until the molten steel is completely solidified. Open the pressure relief valve to release the air to normal pressure, then open the upper cover of the casting chamber, lift out the casting mold, and open the casting mold to obtain ultra-high nitrogen steel. The nitrogen content of the ultra-high nitrogen steel is measured to be 0.38%.
实施例2Example 2
使用本发明的碳氮协同超高氮钢浇铸装置进行超高氮钢浇铸,浇铸生产方法如下:The carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
1、将冶炼出的含有过饱和氮的钢水加入钢包中,对钢包加盖密封处理后进行底吹氮气搅拌和氮气加压至0.7MPa并保持压力恒定。1. Add the molten steel containing supersaturated nitrogen into the ladle, cover and seal the ladle, stir with bottom nitrogen, pressurize the nitrogen to 0.7MPa and keep the pressure constant.
2、将铸模放入铸造室内,对铸造室进行先抽真空至10Pa以下,停止抽真空,充氮气至常压,再次开始抽真空至10Pa以下,停止抽真空,对铸造室充氮气加压操作,直到压力达到1.5MPa。2. Place the mold into the casting chamber, evacuate the casting chamber to below 10Pa, stop evacuating, fill with nitrogen to normal pressure, evacuate the casting chamber to below 10Pa again, stop evacuating, and pressurize the casting chamber with nitrogen until the pressure reaches 1.5MPa.
3、将钢包吊至铸造室上方支撑架上,将两耐高压管道采用多炉转换接头链接。3. Hang the ladle onto the support frame above the casting chamber and connect the two high-pressure resistant pipes with a multi-furnace conversion joint.
4、打开三层式滑动水口二的中间滑板,使耐高压管道内压力与铸造室内相同。4. Open the middle slide of the three-layer sliding gate 2 to make the pressure inside the high-pressure resistant pipe the same as that in the casting chamber.
5、打开三层式滑动水口一的中间滑板并控制塞棒上升,进行浇铸作业。5. Open the middle slide of the three-layer sliding gate and control the stopper rod to rise to carry out casting operations.
6、浇铸完成后,控制塞棒下降封住钢包水口,关闭三层式滑动水口一的中间滑板,关闭三层式滑动水口二的中间滑板,打开两耐高压管道之间的多炉转换接头,时刻关注铸造室内压力情况,进行适当补压操作,并将钢包吊至另 一个铸造室上方进行下一个铸型的浇铸。6. After the casting is completed, control the stopper rod to descend to seal the ladle water inlet, close the middle slide of the three-layer sliding water inlet 1, close the middle slide of the three-layer sliding water inlet 2, open the multi-furnace conversion joint between the two high-pressure resistant pipes, always pay attention to the pressure in the casting room, perform appropriate pressure replenishment operations, and hoist the ladle to another The next mold is poured above one casting chamber.
7、保持铸造室内压力恒定在1.5MPa直至钢液完全凝固,打开泄压阀放气至常压后打开铸造室上盖,吊出铸模,打开铸模即可得到超高氮钢,测量该超高氮钢的氮含量为0.54%。7. Maintain the pressure in the casting chamber at a constant 1.5 MPa until the molten steel is completely solidified. Open the pressure relief valve to release the air to normal pressure, then open the upper cover of the casting chamber, lift out the casting mold, and open the casting mold to obtain ultra-high nitrogen steel. The nitrogen content of the ultra-high nitrogen steel is measured to be 0.54%.
实施例3Example 3
使用本发明的碳氮协同超高氮钢浇铸装置进行超高氮钢浇铸,浇铸生产方法如下:The carbon-nitrogen coordinated ultra-high nitrogen steel casting device of the present invention is used to cast ultra-high nitrogen steel, and the casting production method is as follows:
1、将冶炼出的含有过饱和氮的钢水加入钢包中,对钢包加盖密封处理后进行底吹氮气搅拌和氮气加压至0.7MPa并保持压力恒定。1. Add the molten steel containing supersaturated nitrogen into the ladle, cover and seal the ladle, stir with bottom nitrogen, pressurize the nitrogen to 0.7MPa and keep the pressure constant.
2、将铸模放入铸造室内,对铸造室进行先抽真空至10Pa以下,停止抽真空,充氮气至常压,再次开始抽真空至10Pa以下,停止抽真空,对铸造室充氮气加压操作,直到压力达到1.3MPa。2. Place the mold into the casting chamber, evacuate the casting chamber to below 10Pa, stop evacuating, fill with nitrogen to normal pressure, evacuate the casting chamber to below 10Pa again, stop evacuating, and pressurize the casting chamber with nitrogen until the pressure reaches 1.3MPa.
3、将钢包吊至铸造室上方支撑架上,将两耐高压管道采用多炉转换接头链接。3. Hang the ladle onto the support frame above the casting chamber and connect the two high-pressure resistant pipes with a multi-furnace conversion joint.
4、打开三层式滑动水口二的中间滑板,使耐高压管道内压力与铸造室内相同。4. Open the middle slide of the three-layer sliding gate 2 to make the pressure inside the high-pressure resistant pipe the same as that in the casting chamber.
5、打开三层式滑动水口一的中间滑板并控制塞棒上升,进行浇铸作业。5. Open the middle slide of the three-layer sliding gate and control the stopper rod to rise to carry out casting operations.
6、浇铸完成后,控制塞棒下降封住钢包水口,关闭三层式滑动水口一的中间滑板,关闭三层式滑动水口二的中间滑板,打开两耐高压管道之间的多炉转换接头,时刻关注铸造室内压力情况,进行适当补压操作,并将钢包吊至另一个铸造室上方进行下一个铸型的浇铸。6. After the casting is completed, control the stopper rod to descend to seal the ladle water inlet, close the middle slide of the three-layer sliding water inlet one, close the middle slide of the three-layer sliding water inlet two, open the multi-furnace conversion joint between the two high-pressure resistant pipes, always pay attention to the pressure in the casting chamber, perform appropriate pressure replenishment operations, and hoist the ladle to the top of another casting chamber for casting of the next mold.
7、保持铸造室内压力恒定在1.3MPa直至钢液完全凝固,打开泄压阀放气 至常压后打开铸造室上盖,吊出铸模,打开铸模即可得到海工钢,测量该海工钢氮含量为1.1%。7. Keep the pressure in the casting chamber constant at 1.3MPa until the molten steel is completely solidified, and open the pressure relief valve to release air. After reaching normal pressure, the upper cover of the casting chamber is opened, the casting mold is lifted out, and the marine steel can be obtained by opening the casting mold. The nitrogen content of the marine steel is measured to be 1.1%.
其中,采用上述装置及方法浇铸出的碳氮协同超高氮钢成分如下表1所示:Among them, the composition of the carbon-nitrogen synergistic ultra-high nitrogen steel cast by the above-mentioned device and method is shown in Table 1 below:
表1
Table 1
且,常压凝固高锰钢氮含量为0.18%时显微组织形貌如图2a所示,加压凝固高锰钢氮含量为0.54%时显微组织如图2b所示,拉伸性能如表2所示。Moreover, the microstructure morphology of the atmospheric solidified high manganese steel with a nitrogen content of 0.18% is shown in FIG2a, and the microstructure of the pressurized solidified high manganese steel with a nitrogen content of 0.54% is shown in FIG2b. The tensile properties are shown in Table 2.
表2
Table 2
常压条件下,该高锰钢的氮含量一般小于0.18%,该海工钢的氮含量一般小于0.4%,由表1可知,经过本加压装置浇铸生产的超高氮钢氮含量均非常高,在加压浇铸加压凝固条件下,氮含量分别达到了0.38%,0.54%和1.1%,提高钢中氮含量不仅可以提高材料的耐腐蚀性能,还可以提高其力学性能。Under normal pressure conditions, the nitrogen content of the high manganese steel is generally less than 0.18%, and the nitrogen content of the marine steel is generally less than 0.4%. It can be seen from Table 1 that the nitrogen content of the ultra-high nitrogen steel produced by casting with the pressurized device is very high. Under the conditions of pressure casting and pressurized solidification, the nitrogen content reaches 0.38%, 0.54% and 1.1% respectively. Increasing the nitrogen content in the steel can not only improve the corrosion resistance of the material, but also improve its mechanical properties.
并由图2a和b可知,提高钢中氮含量可以细化铸态组织晶粒,且由表2可知,含氮0.54%高锰钢与普通含氮0.18%高锰钢相比,屈服强度提高16.02%,抗拉强度提高6.00%,断后伸长率提高14.63%,断后收缩率提高16.87%,实现了力学性能的全面提升。It can be seen from Figures 2a and 2b that increasing the nitrogen content in the steel can refine the cast grains. And from Table 2, compared with ordinary high manganese steel containing 0.18% nitrogen, the yield strength of high manganese steel containing 0.54% nitrogen is increased by 16.02%, the tensile strength is increased by 6.00%, the elongation after fracture is increased by 14.63%, and the shrinkage after fracture is increased by 16.87%, achieving a comprehensive improvement in mechanical properties.
对所公开的实施例的上述说明,使本领域专业技术人员能够实现或使用本发明。对这些实施例的多种修改对本领域的专业技术人员来说将是显而易见的,本文中所定义的一般原理可以在不脱离本发明的精神或范围的情况下,在其它实施例中实现。因此,本发明将不会被限制于本文所示的这些实施例,而 是要符合与本文所公开的原理和新颖特点相一致的最宽的范围。 The above description of the disclosed embodiments enables one skilled in the art to implement or use the present invention. Various modifications to these embodiments will be apparent to one skilled in the art, and the general principles defined herein may be implemented in other embodiments without departing from the spirit or scope of the present invention. Therefore, the present invention is not limited to the embodiments shown herein, but It is to be consistent with the widest scope consistent with the principles and novel features disclosed herein.

Claims (9)

  1. 一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述装置包括钢包(22),位于所述钢包(22)底部的铸造室(13)及设置在所述铸造室(13)内部的铸模(14);其中,A multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel, characterized in that the device comprises a ladle (22), a casting chamber (13) located at the bottom of the ladle (22), and a casting mold (14) arranged inside the casting chamber (13); wherein:
    所述钢包(22)的顶部设有炉盖一(1),内部设有塞棒控制机构(6)及底部出钢口处开设有三层式滑动水口一(9);所述三层式滑动水口一(9)的上滑板与所述钢包(22)底部的水口连接,下滑板与耐高压管道一(20)连接;The top of the ladle (22) is provided with a furnace cover (1), a stopper rod control mechanism (6) is provided inside, and a three-layer sliding gate (9) is opened at the bottom of the steel outlet; the upper slide plate of the three-layer sliding gate (9) is connected to the gate at the bottom of the ladle (22), and the lower slide plate is connected to a high-pressure resistant pipe (20);
    所述铸造室(13)的顶部设有炉盖二(18),所述炉盖二(18)上设有三层式滑动水口二(11);所述三层式滑动水口二(11)的上滑板与耐高压管道二(19)连接,下滑板与耐压浇铸长水口连接;A furnace cover 2 (18) is provided on the top of the casting chamber (13), and a three-layer sliding gate 2 (11) is provided on the furnace cover 2 (18); the upper slide plate of the three-layer sliding gate 2 (11) is connected to the high-pressure resistant pipe 2 (19), and the lower slide plate is connected to the long pressure-resistant casting gate;
    所述铸模(14)是由上下双开模形成的空腔结构,所述铸模(14)的顶部设有多个冒口(16)和一个浇注口(15),且所述浇铸口(15)位于所述耐压浇铸长水口的下方。The casting mold (14) is a cavity structure formed by upper and lower double molds. The top of the casting mold (14) is provided with a plurality of risers (16) and a pouring port (15), and the pouring port (15) is located below the pressure-resistant casting long nozzle.
  2. 根据权利要求1所述的一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述炉盖一(1)的中央设有炉盖吊环(4),且所述炉盖一(1)上设置有氮气加压孔(2)、泄压阀(3)和压力表(5)。According to the multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel as described in claim 1, it is characterized in that a furnace cover hanging ring (4) is provided in the center of the furnace cover (1), and a nitrogen pressurizing hole (2), a pressure relief valve (3) and a pressure gauge (5) are provided on the furnace cover (1).
  3. 根据权利要求1所述的一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述塞棒控制机构(6)能控制塞棒(8)的升降;且所述塞棒控制机构(6)包括与所述炉盖(1)内部固定连接的基座、与所述塞棒(8)Y方向平行的支架及可电动控制在所述支架Y方向移动的夹具。According to the multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel according to claim 1, it is characterized in that the stopper rod control mechanism (6) can control the lifting and lowering of the stopper rod (8); and the stopper rod control mechanism (6) includes a base fixedly connected to the inside of the furnace cover (1), a bracket parallel to the Y direction of the stopper rod (8), and a clamp that can be electrically controlled to move in the Y direction of the bracket.
  4. 根据权利要求1所述的一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述钢包(22)的底部设有底吹孔(21),且所述钢包(22)与所述炉盖一(1)通过密封螺栓(7)围成封闭的炉腔。According to the multi-furnace pressure casting device for producing carbon-nitrogen synergistic ultra-high nitrogen steel as described in claim 1, it is characterized in that a bottom blowing hole (21) is provided at the bottom of the ladle (22), and the ladle (22) and the furnace cover (1) are surrounded by sealing bolts (7) to form a closed furnace chamber.
  5. 根据权利要求1或4所述的一种多炉加压浇铸生产碳氮协同超高氮钢 装置,其特征在于,所述钢包(22)由中空式支撑平台(12)支撑,及所述铸造室(13)位于所述中空式支撑平台(12)的底部。A method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting according to claim 1 or 4 The device is characterized in that the ladle (22) is supported by a hollow support platform (12), and the casting chamber (13) is located at the bottom of the hollow support platform (12).
  6. 根据权利要求1所述的一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述炉盖二(18)上设有压力表和泄压阀,所述铸造室(13)的侧壁开设有加压抽真空进出气孔(17);且所述炉盖二(18)与所述铸造室(13)通过密封螺栓围成封闭的炉腔。According to the multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel as described in claim 1, it is characterized in that a pressure gauge and a pressure relief valve are provided on the second furnace cover (18), and a pressurized vacuum inlet and outlet hole (17) is opened on the side wall of the casting chamber (13); and the second furnace cover (18) and the casting chamber (13) are surrounded by sealing bolts to form a closed furnace cavity.
  7. 根据权利要求1所述的一种多炉加压浇铸生产碳氮协同超高氮钢装置,其特征在于,所述耐高压管道一(20)与所述耐高压管道二(19)通过多炉转换接头(10)连接。According to the multi-furnace pressure casting device for producing carbon-nitrogen coordinated ultra-high nitrogen steel as described in claim 1, it is characterized in that the high-pressure resistant pipeline one (20) is connected to the high-pressure resistant pipeline two (19) through a multi-furnace conversion joint (10).
  8. 一种多炉加压浇铸生产碳氮协同超高氮钢的方法,其特征在于,采用如权利要求1所述装置生产超高氮钢的方法具体包括如下步骤:A method for producing carbon-nitrogen coordinated ultra-high nitrogen steel by multi-furnace pressure casting, characterized in that the method for producing ultra-high nitrogen steel using the device as claimed in claim 1 specifically comprises the following steps:
    1)将冶炼出的含有过饱和氮的钢水加入所述钢包(22)中,对所述钢包(22)加炉盖一(1)密封处理后,经钢包底吹孔(21)进行底吹氮气搅拌和氮气加压孔(2)进行加压操作,压力控制在0-6MPa范围内;1) adding the molten steel containing supersaturated nitrogen into the ladle (22), sealing the ladle (22) with a furnace cover (1), blowing nitrogen through the ladle bottom blowing hole (21) for stirring, and pressurizing through the nitrogen pressurizing hole (2), wherein the pressure is controlled within the range of 0-6 MPa;
    2)将所述铸模(14)放入所述铸造室(13)的内部,对所述铸造室(13)通过加压抽真空进出气孔(17)进行先抽真空至10Pa以下,再氮气洗炉一次,随后抽真空后采用氮气加压操作,直至达到指定压力;2) placing the casting mold (14) into the casting chamber (13), evacuating the casting chamber (13) to below 10 Pa through the pressurized vacuum inlet and outlet holes (17), then flushing the furnace with nitrogen once, and then applying nitrogen pressure after evacuation until a specified pressure is reached;
    3)将所述钢包(22)吊至所述铸造室(13)上方的中空式支撑平台(12)上,并将所述耐高压管道一(20)与所述耐高压管道二(19)通过多炉转换接头(10)连接;3) hoisting the ladle (22) onto the hollow support platform (12) above the casting chamber (13), and connecting the high-pressure resistant pipe 1 (20) and the high-pressure resistant pipe 2 (19) via a multi-furnace conversion joint (10);
    4)打开所述三层式滑动水口二(11)的中间滑板,使耐高压管道内压力与所述铸造室(13)内相同;4) opening the middle slide plate of the three-layer sliding gate second (11) to make the pressure in the high-pressure resistant pipeline the same as that in the casting chamber (13);
    5)打开三层式滑动水口一(9)的中间滑板并控制塞棒(8)上升,进行 浇铸;5) Open the middle slide of the three-layer sliding gate (9) and control the stopper rod (8) to rise. casting;
    6)待浇铸完成后,控制塞棒(8)下降以封住所述钢包(22)的水口,分别关闭三层式滑动水口一(9)和所述三层式滑动水口二(11)的中间滑板,打开所述多炉转换接头(10),时刻关注所述铸造室(13)内的压力情况,以进行适当补压操作,并将所述钢包(22)吊至另一个铸造室上方进行下一个铸型的浇铸;6) After the casting is completed, the stopper rod (8) is controlled to descend to seal the water inlet of the ladle (22), the middle slide plates of the three-layer sliding water inlet 1 (9) and the three-layer sliding water inlet 2 (11) are closed respectively, the multi-furnace conversion joint (10) is opened, and the pressure in the casting chamber (13) is always paid attention to so as to perform appropriate pressure replenishment operations, and the ladle (22) is hoisted above another casting chamber for casting of the next casting mold;
    7)保持所述铸造室(13)内压力恒定直至钢液完全凝固完成,打开泄压阀放气至常压后打开所述铸造室(13)的上盖,吊出所述铸模(14)并打开,即得到碳氮协同超高氮钢。7) Maintaining a constant pressure in the casting chamber (13) until the molten steel is completely solidified, opening the pressure relief valve to release air to normal pressure, and then opening the upper cover of the casting chamber (13), lifting out the casting mold (14) and opening it, thereby obtaining carbon-nitrogen synergistic ultra-high nitrogen steel.
  9. 根据权利要求8所述的一种多炉加压浇铸生产碳氮协同超高氮钢的方法,其特征在于,生产的碳氮协同超高氮钢成分以质量百分比计,如下:The method for producing carbon-nitrogen synergistic ultra-high nitrogen steel by multi-furnace pressure casting according to claim 8 is characterized in that the components of the produced carbon-nitrogen synergistic ultra-high nitrogen steel are as follows in terms of mass percentage:
    C 0~0.8%,Si 0~0.5%,Cr 4~20%,Mn 11~20%,N 0.3~1.4%,S 0~0.02%,P 0~0.02%,其余为铁。 C 0~0.8%, Si 0~0.5%, Cr 4~20%, Mn 11~20%, N 0.3~1.4%, S 0~0.02%, P 0~0.02%, and the rest is iron.
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