WO2023281726A1 - 浸漬ノズル - Google Patents
浸漬ノズル Download PDFInfo
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- WO2023281726A1 WO2023281726A1 PCT/JP2021/025890 JP2021025890W WO2023281726A1 WO 2023281726 A1 WO2023281726 A1 WO 2023281726A1 JP 2021025890 W JP2021025890 W JP 2021025890W WO 2023281726 A1 WO2023281726 A1 WO 2023281726A1
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- opening
- channel
- openings
- cross
- flow
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- 238000007654 immersion Methods 0.000 title claims description 10
- 229910000831 Steel Inorganic materials 0.000 description 26
- 239000010959 steel Substances 0.000 description 26
- 230000005499 meniscus Effects 0.000 description 16
- 238000005266 casting Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000009749 continuous casting Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 229910002804 graphite Inorganic materials 0.000 description 5
- 239000010439 graphite Substances 0.000 description 5
- 239000011819 refractory material Substances 0.000 description 5
- 238000011144 upstream manufacturing Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
Definitions
- the present invention relates to an immersion nozzle used for continuous casting of thin slabs.
- Direct connection between continuous casting and the hot rolling of the resulting slab is attracting attention for its effect of omitting the slab heating process and saving energy. is oriented.
- the mold When casting a thin slab (for example, 200 mm or less in thickness), the mold must be flattened, and therefore the submerged nozzle must also be flattened (for example, Patent Document 1).
- Skinning is particularly prone to problems when casting thin slabs. This is because thin slabs have a large aspect ratio of the surface area of the molten steel, so the surface temperature is more likely to drop than in ordinary slabs. is likely to decrease.
- the immersion nozzle described in Patent Document 1 it is possible to prevent the base metal attachment that occurs between the immersion nozzle and the mold wall and the skinning of the molten metal surface that occurs near the short side of the wide mold. It is possible to prevent the occurrence of the suction phenomenon of the solidified shell and the remelting of the solidified shell.
- the submerged nozzle described in Patent Literature 1 cannot be said to be sufficient in suppressing skinning at the meniscus portion.
- a submerged nozzle according to the present invention is a submerged nozzle that includes a flow path and an opening, and is provided with a first portion, a connecting portion, and a second portion in order from a base end side, wherein the first portion includes the
- the cross-sectional shape of the channel is circular
- the cross-sectional shape of the channel is rectangular in the second portion
- the shape of the channel in the connection portion is the same as the channel in the first portion.
- the second portion has a shape that continuously connects with the flow path, and in the second portion, the ratio a/b of the length a of the long side and the length b of the short side of the rectangle is 3 or more.
- the cross-sectional area S2 of the channel in the second part is greater than the cross - sectional area S1 of the channel in the first part
- the openings comprise two first openings and two and a second opening, wherein the first opening is open to two side surfaces respectively corresponding to the two short sides of the second portion, and the two second openings are One is open over one of the two side surfaces and the bottom surface that is the tip surface of the second portion, and the other of the two second openings is one of the two side surfaces. It is characterized by opening over the other side surface and the bottom surface.
- the opening area S 3 on the side surface of the first opening, the opening area S 4 on the side surface of the second opening, and the opening area S 5 on the bottom surface are , preferably satisfies the following equations (1) and (2).
- the discharge flow discharged from the nozzle hits the short side of the mold and separates into an upward flow and a downward flow.
- the upward flow is excessively strong, powder is likely to be caught, and if the downward flow is excessively strong, it is difficult for inclusions and air bubbles to surface.
- the balance between the upward flow and the downward flow can be optimized, and excessive meniscus flow can be suppressed.
- the opening area S3 on the side surface of the first opening is smaller than the opening area S6 on the flow path side.
- the submerged nozzle according to the present invention preferably has a maximum width of 300 mm or less.
- FIG. 2 is a side cross-sectional view (a cross-sectional view taken along the line II-II in FIG. 1) of the nozzle according to the embodiment;
- FIG. 2 is a cross-sectional view (cross-sectional view taken along line III-III in FIG. 1) of the first portion of the nozzle according to the embodiment;
- FIG. 2 is a cross-sectional view (cross-sectional view taken along line IV-IV of FIG. 1) of the second portion of the nozzle according to the embodiment;
- FIG. 4 is a side view of a second portion of an embodiment nozzle;
- FIG. 4B is a bottom view of the second portion of the nozzle according to the embodiment;
- the nozzle 1 is a tubular member made of a refractory material. A flow path for circulating molten steel is formed inside, and an opening 5 is provided at the tip.
- the nozzle 1 is provided with a first portion 2, a connecting portion 3, and a second portion 4 in order from the base end side, and each portion has a different shape (FIGS. 1 and 2).
- the nozzle 1 is joined at the first portion 2 to equipment on the upstream side (stopper, sliding nozzle, etc., not shown), and molten steel flowing from the equipment on the upstream side flows through the channel.
- the second portion 4 is provided with openings 5 (a first opening 51 and a second opening 52), and molten steel flows out from the openings 5 to a mold (not shown).
- the type of refractory material that constitutes the nozzle 1 is not particularly limited, and any refractory material conventionally used in this field can be used.
- Such refractory materials include alumina-graphite, magnesia-graphite, spinel-graphite, zirconia-graphite, calcium zirconate-graphite, high alumina, alumina-siliceous, siliceous, zirconium, and spinel. etc. are exemplified. Also, zone lining may be applied as appropriate.
- Fig. 1 When referring to directions in the following description, the arrangement shown in Fig. 1 is used as a reference. That is, when referring to the vertical direction, the base end side (first portion 2 side) is referred to as top (upper, upper, upper, upstream, etc.), and the distal end side (second portion 4 side) is referred to as lower (lower, lower, lower, upper, etc.). lower, downstream, etc.).
- the cross section of the flow channel in the direction perpendicular to the vertical direction defined above (the direction perpendicular to the paper surface of FIG. 1) is referred to as the cross section.
- the cross section defined above is also a section in the flow direction of the molten steel.
- the first portion 2 is the main portion on the proximal side of the nozzle 1 .
- the cross-sectional shape of the channel 21 is circular (FIGS. 1-3).
- the circular shape referred to here is not limited to a circular shape in a mathematical sense, and may be a shape that can be treated as a substantially circular shape. Therefore, there may be deviations (tolerances, etc.) from the mathematical circularity that may occur in achieving circularity as an industrial product.
- the cross - sectional area S1 of the channel 21 is 6000 mm2 .
- the second portion 4 is the main portion on the tip side of the nozzle 1 .
- the cross-sectional shape of the channel 41 is rectangular (FIGS. 1, 2 and 4).
- the rectangle referred to here is not limited to a rectangle (rectangle) in a mathematical sense, and can be a shape that can be substantially treated as a rectangle. Therefore, it may have deformations (such as chamfers) that are normally applied when realizing a rectangle as an industrial product, or it may have deviations (tolerances, etc.) from a mathematical rectangle.
- the cross - sectional area S2 of the channel 41 is 10000 mm2 . Therefore, cross-sectional area S 2 of channel 41 is greater than cross-sectional area S 1 of channel 21 .
- the length a of the long side 42 of the rectangle is 200 mm, and the length b of the short side 43 is 50 mm (Fig. 4). Therefore, the ratio a/b between the two is 4.0.
- the shape of the rectangle is not limited to the above numerical values, and may be changed within the range where the ratio a/b is 3 or more and 7 or less.
- both the length a of the long side 42 and the length of the short side 43 of the rectangle can be changed, but the length b of the short side 43 is regulated by the length of the short side of the mold. Therefore, the length a of the long side 42 generally has a higher degree of freedom.
- the ratio a/b is 3 or more and 7 or less, the molten steel flow is less likely to separate from the wall surface of the flow path 41, and an appropriate flow can be obtained.
- the ratio a/b is less than 3, the length a of the long side 42 becomes too small, making it difficult to secure the inner pipe cross-sectional area necessary for casting.
- the ratio a/b exceeds 7, the length a of the long side 42 becomes excessively large, and the weight of the nozzle 1 tends to increase, which can increase the load on the operator and the device handling the nozzle 1 .
- the ratio a/b exceeds 7, the deformation of the channel 31 in the long side direction at the connecting portion 3 becomes steep, which may induce separation of the molten steel flow from the channel wall surface.
- the cross-sectional shape of the substantial portion (refractory material portion) of the second portion 4 is also rectangular, and therefore the second portion 4 is formed in the shape of a bottomed prism. It is
- the width W of the surface corresponding to the long side 42 of the rectangle is 270 mm, which is the maximum width of the nozzle 1 .
- the maximum width W of the nozzle 1 is less than 300 mm, because the workability of exchanging the nozzle 1 using the quick exchanging device is improved. This is because, when the maximum width W of the nozzle 1 is less than 300 mm, it is easy to secure a space inside the mold for replacing the nozzle 1 due to the relationship between the dimensions of the nozzle 1 and the mold.
- a first opening 51 opens in a side surface 44 corresponding to the short side 43 of the rectangle (Figs. 1 and 5).
- Two first openings 51 are provided, and the two first openings 51 (51A, 51B) have two side surfaces 44 (44A, 44B) respectively corresponding to the two short sides 43 (43A, 43B). It is open one by one. Since the first opening 51 is open on the side surface 44, the molten steel flow can be discharged toward the short side of the mold. This can generate an upward flow in the mold to facilitate heat supply to the meniscus.
- two second openings 52 are opened across the side surface 44 and the bottom surface 45 that is the surface of the tip of the second portion 4 in the longitudinal direction (Figs. 1, 5, and 6).
- one second opening 52A is open over the side surface 44A (one side surface) and the bottom surface 45
- the other second opening portion 52B is open to the side surface 44B (the other side surface). It is open over the bottom surface 45 . Since the second opening 52 is opened in the manner described above, the molten steel flow can be discharged downward from the mold, and the molten steel flow within the mold can be appropriately distributed.
- the opening area S 3 (the area of the first opening 51 shown in FIG. 5) at the side surface 44 of the first opening 51 is 2700 mm 2 .
- the opening area S 4 at the side surface 44 of the second opening 52 (the area of the second opening 52 shown in FIG. 5) is 2000 mm 2
- the opening area S 5 at the bottom surface 45 (shown in FIG. 6).
- the area of the second opening 52) is 5000 mm 2 . From the above opening areas, the following formulas (1) and (2) are established. S 4 ⁇ S 5 (1) (S 4 +S 5 )/S 3 ⁇ 1.5 (2)
- the opening area S3 of the first opening 51 and the opening areas S4 and S5 of the second opening 52 are not limited to the above values, and can be changed as long as the formulas ( 1 ) and (2) are satisfied. It is possible.
- the opening area S6 of the first opening 51 on the channel 41 side is 4000 mm 2 . Therefore, the opening area S3 on the side surface 44 of the first opening 51 is smaller than the opening area S6 on the channel 41 side.
- the opening area S6 of the first opening 51 on the flow path 41 side is larger than or equal to the opening area S3 on the side surface 44, so that the cross-sectional area of the flow path toward the exit in the flow direction of molten steel gradually decreases, the molten steel flow is rectified. As a result, the generation of a suction flow in the upper portion of the first opening 51 is suppressed, and the molten steel is easily discharged from the entire first opening 51 smoothly.
- connection portion 3 is a portion that continuously connects the first portion 2 and the second portion 4 (FIGS. 1 and 2).
- a channel 31 is provided that continuously connects the channel 21 of the first portion 2 having a circular cross-sectional shape and the channel 41 of the second portion 4 having a rectangular cross-sectional shape.
- the cross-sectional shape of the channel 31 is circular at the upper end 32 and rectangular at the lower end 33 .
- the opening areas S 3 , S 4 , S 5 , and S 6 of the openings 5 are obtained by formulas (1) and (2).
- S 3 is less than S 6 has been described as an example.
- the submerged nozzle according to the present invention may not satisfy one or both of equations ( 1 ) and ( 2 ), and S3 may be greater than S6.
- the configuration in which the maximum width W of the nozzle 1 is 270 mm and less than 300 mm has been described as an example.
- the maximum width of the submerged nozzle according to the invention may be 300 mm or more.
- meniscus flow velocity was identified based on the output flow velocity contour diagram. Evaluation was made in three grades from A to C according to the value of the meniscus flow velocity.
- Table 1 shows the dimensional conditions and evaluation results of each example of Examples and Comparative Examples.
- S 2 was greater than S 1
- the meniscus flow velocity was within the proper range (evaluation A or B).
- Comparative Example 2 in which S2 was smaller than S1, the meniscus flow velocity was not within the preferable range (evaluation C ).
- Examples 3 to 6 where S 3 , S 4 and S 5 satisfy formula (2) the meniscus flow velocity was in a more suitable range than Examples 1 and 2 which did not satisfy formula (2).
- Examples 5 and 6, in which S 3 is smaller than S 6 , compared to Example 1, in which S 3 is equal to S 6 , and Examples 2 to 4, in which S 3 is larger than S 6 have a higher suction of the first opening. showed more favorable results with respect to flow.
- the present invention can be used, for example, as an immersion nozzle for continuous casting of thin slabs.
Abstract
Description
S4<S5 (1)
(S4+S5)/S3≧1.5 (2)
ノズル1は、耐火材料によって形成された筒状の部材である。内部には溶鋼を流通させるための流路が形成されており、先端部分には開口部5が設けられている。ノズル1には、基端側から順に第一部分2、接続部分3、および第二部分4が設けられており、各部分の形状が異なる(図1、図2)。ノズル1は、第一部分2において、上流側の設備(ストッパー、スライディングノズルなど。不図示。)と接合されており、上流側の設備から流入した溶鋼が流路を流通する。また、第二部分4には開口部5(第一開口部51および第二開口部52)が設けられており、開口部5からモールド(不図示)に溶鋼が流出する。
第一部分2は、ノズル1の基端側における主たる部分である。第一部分2において、流路21の横断面形状は円形である(図1~図3)。なお、ここで言う円形とは、数学的な意味における円形に限定されず、実質的に円形として取り扱いうる形状でありうる。したがって、工業製品として円形を実現する際に生じうる数学的な円形からの逸脱(公差など)があってもよい。本実施形態では、流路21の断面積S1は、6000mm2である。
第二部分4は、ノズル1の先端側における主たる部分である。第二部分4において、流路41の横断面形状は矩形である(図1、図2、および図4)。なお、ここで言う矩形とは、数学的な意味における矩形(長方形)に限定されず、実質的に矩形として取り扱いうる形状でありうる。したがって、工業製品として矩形を実現する際に通常適用される変形(面取りなど)が施されていてもよいし、数学的な矩形からの逸脱(公差など)があってもよい。
第二部分4において、矩形の短辺43に対応する側面44には、第一開口部51が開口している(図1、図5)。第一開口部51は二つ設けられており、二つの第一開口部51(51A、51B)は、二つの短辺43(43A、43B)にそれぞれ対応する二つの側面44(44A、44B)に一つずつ開口している。第一開口部51が側面44に開口していることによって、溶鋼流をモールドの短辺側に向けて吐出できる。これによって、モールド内に上昇流を発生させて、メニスカスへの熱供給を促進しうる。
S4<S5 (1)
(S4+S5)/S3≧1.5 (2)
接続部分3は、第一部分2と第二部分4とを連続的に接続する部分である(図1、図2)。接続部分3では、断面形状が円形である第一部分2の流路21と、断面形状が矩形である第二部分4の流路41とを連続的に接続する形状の流路31が設けられている。したがって、流路31の断面形状は、上端32において円形であり、下端33において矩形である。
最後に、本発明に係る浸漬ノズルのその他の実施形態について説明する。なお、以下のそれぞれの実施形態で開示される構成は、矛盾が生じない限り、他の実施形態で開示される構成と組み合わせて適用することも可能である。
種々の寸法条件のノズルを設計し、CHAM-japan社製の流体解析ソフトウェア「PHOENICS」を使用して、吐出される溶鋼流の態様についての数値流体力学計算を行なった。実施例および比較例の各例の寸法条件は、後掲の表1~3に記載されているとおりである。計算結果に基づいて、流速コンター図を出力した。なお、計算にあたって以下の各パラメータを適用した。
・計算セル数: 約50万(モデルにより変動)
・流体: 溶鋼(1560℃、密度7.08g/cm3)
・鋳造速度: 毎分4t
・モールドサイズ: 1200mm×150mm
実施例および比較例の各例について、出力された流速コンター図に基づいてメニスカス流速を特定した。メニスカス流速の値に応じて、A~Cの三段階で評価した。
A:メニスカス流速が10cm/秒以上25cm/秒以下である。
B:メニスカス流速が25cm/秒を超え35cm/秒以下である。
C:メニスカス流速が10cm/秒未満または35cm/秒を超える。
実施例および比較例の各例について、出力された流速コンター図を目視で確認して、第二部分4における溶鋼流の剥離の有無を特定し、良否(AまたはC)を判断した。
A:第二部分4の全域において壁面に沿う溶鋼流が形成されている。
C:第二部分4において溶鋼流の剥離が見られる。
実施例および比較例の各例について、出力された流速コンター図を目視で確認して、第一開口部51における吸込み流の有無および程度を特定した。観察された状態に応じて、A~Cの三段階で評価した。
A:第一開口部51から溶鋼流が淀みなく吐出されている。
B:第一開口部51の付近に溶鋼流の停滞が認められる。
C:第一開口部51に流入する吸込み流が認められる。
実施例および比較例の各例の寸法条件および評価結果を表1に示す。比a/bが3以上7以下の範囲にある実施例1~6は、溶鋼流の剥離の評価がAだった。一方、比a/bが8.0である比較例1は、溶鋼流の剥離の評価がCだった。また、S2がS1より大きい実施例1~6では、メニスカス流速が適正範囲(評価AまたはB)だった。一方、S2がS1より小さい比較例2では、メニスカス流速が好ましい範囲になかった(評価C)。
2 :第一部分
21 :流路
3 :接続部分
31 :流路
32 :接続部分の上端
33 :接続部分の下端
4 :第二部分
41 :流路
42 :長辺
43 :短辺
44 :側面
45 :底面
5 :開口部
51 :第一開口部
52 :第二開口部
Claims (4)
- 流路と開口部とを備え、基端側から順に、第一部分、接続部分、および第二部分が設けられている浸漬ノズルであって、
前記第一部分において、前記流路の横断面形状は円形であり、
前記第二部分において、前記流路の横断面形状は矩形であり、
前記接続部分において、前記流路の形状は、前記第一部分の前記流路と前記第二部分の前記流路とを連続的に接続する形状であり、
前記第二部分において、前記矩形の長辺の長さaと短辺の長さbとの比a/bは、3以上7以下であり、
前記第二部分における前記流路の断面積S2は、前記第一部分における前記流路の断面積S1より大きく、
前記開口部は、二つの第一開口部と、二つの第二開口部と、を含み、
前記第一開口部は、前記第二部分の二つの前記短辺にそれぞれ対応する二つの側面に一つずつ開口しており、
二つの前記第二開口部の一方は、二つの前記側面のうちの一方の側面と、前記第二部分の先端の面である底面と、にわたって開口しており、
二つの前記第二開口部の他方は、二つの前記側面のうちの他方の側面と、前記底面と、にわたって開口している浸漬ノズル。 - 前記第一開口部の前記側面における開口面積S3、ならびに、前記第二開口部の前記側面における開口面積S4および前記底面における開口面積S5は、以下の式(1)および式(2)を満たす請求項1に記載の浸漬ノズル。
S4<S5 (1)
(S4+S5)/S3≧1.5 (2) - 前記第一開口部の前記側面における開口面積S3は、前記流路側における開口面積S6より小さい請求項1または2に記載の浸漬ノズル。
- 最大幅は300mm以下である請求項1~3のいずれか一項に記載の浸漬ノズル。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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JP2023533008A JP7427138B2 (ja) | 2021-07-09 | 2021-07-09 | 浸漬ノズル |
CN202180100225.2A CN117580657A (zh) | 2021-07-09 | 2021-07-09 | 浸渍喷嘴 |
PCT/JP2021/025890 WO2023281726A1 (ja) | 2021-07-09 | 2021-07-09 | 浸漬ノズル |
KR1020247000401A KR20240034747A (ko) | 2021-07-09 | 2021-07-09 | 침지 노즐 |
CA3223418A CA3223418A1 (en) | 2021-07-09 | 2021-07-09 | Immersion nozzle |
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PCT/JP2021/025890 WO2023281726A1 (ja) | 2021-07-09 | 2021-07-09 | 浸漬ノズル |
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KR (1) | KR20240034747A (ja) |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH0839208A (ja) | 1994-07-26 | 1996-02-13 | Sumitomo Metal Ind Ltd | 広幅薄スラブ鋳造用浸漬ノズル |
JP2000233262A (ja) * | 1999-02-09 | 2000-08-29 | Toshiba Ceramics Co Ltd | 薄スラブ鋳造用扁平ノズル |
JP2004001057A (ja) * | 2002-04-26 | 2004-01-08 | Toshiba Ceramics Co Ltd | 薄スラブ連続鋳造用浸漬ノズル |
JP2009233717A (ja) * | 2008-03-27 | 2009-10-15 | Kurosaki Harima Corp | 連続鋳造用浸漬ノズル |
JP2012213785A (ja) * | 2011-03-31 | 2012-11-08 | Kurosaki Harima Corp | 連続鋳造用浸漬ノズル |
-
2021
- 2021-07-09 CN CN202180100225.2A patent/CN117580657A/zh active Pending
- 2021-07-09 JP JP2023533008A patent/JP7427138B2/ja active Active
- 2021-07-09 KR KR1020247000401A patent/KR20240034747A/ko unknown
- 2021-07-09 CA CA3223418A patent/CA3223418A1/en active Pending
- 2021-07-09 WO PCT/JP2021/025890 patent/WO2023281726A1/ja active Application Filing
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0839208A (ja) | 1994-07-26 | 1996-02-13 | Sumitomo Metal Ind Ltd | 広幅薄スラブ鋳造用浸漬ノズル |
JP2000233262A (ja) * | 1999-02-09 | 2000-08-29 | Toshiba Ceramics Co Ltd | 薄スラブ鋳造用扁平ノズル |
JP2004001057A (ja) * | 2002-04-26 | 2004-01-08 | Toshiba Ceramics Co Ltd | 薄スラブ連続鋳造用浸漬ノズル |
JP2009233717A (ja) * | 2008-03-27 | 2009-10-15 | Kurosaki Harima Corp | 連続鋳造用浸漬ノズル |
JP2012213785A (ja) * | 2011-03-31 | 2012-11-08 | Kurosaki Harima Corp | 連続鋳造用浸漬ノズル |
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CA3223418A1 (en) | 2023-01-12 |
JPWO2023281726A1 (ja) | 2023-01-12 |
CN117580657A (zh) | 2024-02-20 |
KR20240034747A (ko) | 2024-03-14 |
JP7427138B2 (ja) | 2024-02-02 |
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