WO2023219104A1 - Soil conditioner and method for producing same, and method for improving soil using same - Google Patents

Soil conditioner and method for producing same, and method for improving soil using same Download PDF

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Publication number
WO2023219104A1
WO2023219104A1 PCT/JP2023/017571 JP2023017571W WO2023219104A1 WO 2023219104 A1 WO2023219104 A1 WO 2023219104A1 JP 2023017571 W JP2023017571 W JP 2023017571W WO 2023219104 A1 WO2023219104 A1 WO 2023219104A1
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Prior art keywords
soil
biodegradable
product
mass
products
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PCT/JP2023/017571
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French (fr)
Japanese (ja)
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皓志 園部
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クレサヴァ株式会社
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Publication of WO2023219104A1 publication Critical patent/WO2023219104A1/en

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/20Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material
    • A01G24/22Growth substrates; Culture media; Apparatus or methods therefor based on or containing natural organic material containing plant material
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/30Growth substrates; Culture media; Apparatus or methods therefor based on or containing synthetic organic compounds
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F9/00Fertilisers from household or town refuse
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/10Solid or semi-solid fertilisers, e.g. powders
    • C05G5/14Tablets, spikes, rods, blocks or balls
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/14Soil-conditioning materials or soil-stabilising materials containing organic compounds only
    • C09K17/18Prepolymers; Macromolecular compounds
    • C09K17/32Prepolymers; Macromolecular compounds of natural origin, e.g. cellulosic materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses

Definitions

  • the present invention relates to a soil reforming material, a method for producing the same, and a method for improving soil using the same.
  • SDGs Sustainable Development Goals
  • Patent Document 1 discloses a technique for molding, burning, etc. organic waste and using it as a soil improvement material. Discloses textile recycling technology.
  • Patent Document 2 discloses a technique for reusing so-called paper cups as pulp soil.
  • An object of the present invention is to provide a soil reforming material, a method for producing the same, and a method for improving soil using the same, which can constitute a recycling-oriented society.
  • ⁇ Aspect 1 ⁇ A method for producing a soil reforming material, comprising the step of pelletizing a crushed biodegradable product, the biodegradable product being a hydrophilic biodegradable industrial product.
  • ⁇ Aspect 2 ⁇ A method according to aspect 1, wherein the biodegradable product is clothing.
  • ⁇ Aspect 3 ⁇ The method according to aspect 2, wherein the garment contains 30% by mass or more of biodegradable fibers.
  • ⁇ Aspect 4 ⁇ The method according to aspect 3, wherein the biodegradable fiber is Japanese paper.
  • ⁇ Aspect 5 ⁇ A method according to any one of aspects 1 to 4, further comprising the step of mixing the biodegradable product with an enzyme.
  • ⁇ Aspect 6 ⁇ The method according to any one of aspects 1 to 5, further comprising the step of mixing the biodegradable product with manure and composting the manure.
  • ⁇ Aspect 7 ⁇ A method for producing a soil improvement material, including a step of fermenting a mixture of a textile product and a fermentable organic substance to obtain a fermented mixture.
  • ⁇ Aspect 11 ⁇ 11 A method according to aspect 10, wherein the fabric is derived from a garment.
  • ⁇ Aspect 12 ⁇ 8 The method according to aspect 7, wherein the textile product comprises a synthetic fiber.
  • ⁇ Aspect 13 ⁇ The method according to aspect 7, wherein the fermentable organic substance is a food-derived raw material.
  • ⁇ Aspect 14 ⁇ The method according to aspect 13, wherein the food-derived raw material is rice bran, okara, molasses, rice hulls, fishmeal, rice straw, wheat straw, and combinations thereof.
  • ⁇ Aspect 15 ⁇ The method according to aspect 7, wherein the textile product contains a chemical fiber and the fermentable organic substance is a food-derived raw material.
  • ⁇ Aspect 16 ⁇ A method for producing agricultural products, the method comprising the steps of disposing or mixing a soil reforming material produced by the method according to any one of aspects 1 to 15 in soil, and producing agricultural products using the soil.
  • ⁇ Aspect 17 ⁇ A method for activating soil, comprising a step of placing or mixing in soil a soil reforming material produced by the method according to any one of Aspects 1 to 15.
  • industrial products can be converted into soil reforming materials, and soil can be modified with this soil modifying material to produce vegetables and the like.
  • the method of the present invention is very useful because it is possible to construct a recycling-oriented society.
  • the manufactured soil reforming material can greatly activate soil. Furthermore, the soil reforming material produced according to the present invention can be made from industrial products, and can be used to improve soil and produce vegetables and the like. As a result, the method of the present invention is very useful because it is possible to construct a recycling-oriented society.
  • FIG. 1 is an actual photograph of the soil amendment material of the first embodiment manufactured in the example.
  • FIG. 2 shows the fibers in a coarsely pulverized state according to the second embodiment.
  • FIG. 3 shows the fibers in a finely pulverized state according to the second embodiment.
  • FIG. 4 shows the fermentable mixture immediately after obtaining it and the fermented mixture after fermentation for 3 weeks regarding the second embodiment.
  • FIG. 5(a) shows a state where the fermented mixture is being put into a pelletizer
  • FIG. 5(b) shows the pellets obtained thereby.
  • the method for producing a soil reforming material of the present invention includes a step of pelletizing a crushed biodegradable product.
  • the biodegradable product is a hydrophilic biodegradable industrial product.
  • the soil reforming material produced in this manner When the soil reforming material produced in this manner is placed or mixed in soil, it is decomposed and returned to the soil after a certain period of time. Therefore, even if the industrial products used by the method of the present invention are produced in large quantities, they will not become waste because they will be decomposed in the soil.
  • the industrial products used in the present invention are hydrophilic and can contain water, when placed in or mixed with soil, they can improve and/or maintain the moisture content of the soil, and produce vegetables. It can be used effectively to Moreover, the soil reforming material obtained by the method of the present invention is pelletized, so that it can be sprayed on farmland in large quantities by a tractor. According to studies conducted by the present inventors, it was possible to decompose one ton of biodegradable products per one farmland (approximately 1000 m 2 ) in one to two months.
  • the biodegradable product used in the present invention is a hydrophilic biodegradable industrial product.
  • a hydrophilic biodegradable industrial product is an industrial product that is substantially composed only of hydrophilic biodegradable materials, but if it does not adversely affect the growth of agricultural products such as vegetables, a portion of the product may be does not need to be hydrophilic or a biodegradable material.
  • Hydrophilic fiber products can also make the final soil improvement material hydrophilic. Therefore, when this is placed or mixed in soil, the moisture content of the soil can be improved and/or maintained, and it can be effectively used for producing vegetables.
  • a biodegradable product is preferably composed only of biodegradable materials, but it is sufficient if most of the product is composed of biodegradable materials.
  • a biodegradable product may contain 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, or 85% by mass of the above-mentioned biodegradable materials.
  • the above content is preferably 90% by mass or more, 95% by mass or more, 98% by mass or more, or 99% by mass or more.
  • the portion of the biodegradable product that is not a biodegradable material is preferably a material that does not adversely affect the soil in which agricultural crops are grown.
  • Industrial products include all products that can be manufactured industrially using hydrophilic and biodegradable materials, such as clothing, textile products such as sheets and futons, tableware, containers, furniture, building materials, toys, Books, etc. can be mentioned.
  • biodegradable material is not particularly limited as long as it is a material that can be decomposed by soil microorganisms in the natural environment.
  • biodegradable materials can include both synthetic and natural biodegradable polymers.
  • hydrophilicity refers to the ability of a product to store water, and refers not only to cases where the material itself is water-absorbing, but also when the material is water-repellent but is porous and water-absorbing. including cases where it is possible to retain
  • hydrophilicity may be a property that, when mixed with soil, allows the product to maintain the moisture content of the soil for as long as possible compared to the soil without the product mixed therein.
  • the biodegradable product is water absorbent rather than water repellent.
  • the biodegradable product used in the method of the invention is clothing.
  • Consumers who take fashion trends into account generally purchase new clothing according to trends and dispose of clothing that is no longer fashionable.
  • the method of the present invention allows consumers to protect the global environment even if they continue to purchase new clothes in a short period of time, and is also beneficial for the fashion industry as it allows consumers to purchase new clothes in a short period of time. Become.
  • biodegradable material is not particularly limited as long as it is a material that can be decomposed by soil microorganisms in the natural environment.
  • biodegradable materials can include both synthetic and natural biodegradable polymers.
  • Synthetic biodegradable polymers include polylactic acid, polycaprolactone, polybutylene succinate, polyethylene succinate, polyvinyl alcohol, polyglycolic acid, poly(caprolactone/butylene succinate), poly(butylene succinate/adipate), and poly(butylene succinate/adipate). (ethylene terephthalate/succinate), poly(tetramethylene adipate/terephthalate), and the like.
  • natural biodegradable polymers include carbohydrate-based compounds such as cellulose-based materials and starch-based materials, and amino acid-based compounds such as polypeptides and proteins.
  • biodegradable materials mention may be made in particular of natural fibers, such as cotton, linen, silk, wool, or materials derived therefrom.
  • natural fibers such as cotton, linen, silk, wool, or materials derived therefrom.
  • the present inventor has found that among these, cotton and hemp, especially fibers used for Japanese paper, are especially suitable for use because they have excellent biodegradability in soil and very high water absorption.
  • washi refers to paper made by making washi raw materials made from fibers obtained from raw material plants suitable for washi, such as kozo, mitsumata, hemp, coniferous trees, and bamboo.
  • raw material plants suitable for washi such as kozo, mitsumata, hemp, coniferous trees, and bamboo.
  • the biodegradable product is clothing
  • Japanese paper made from Manila hemp has recently been known for use in clothing, and is suitable because it has very high biodegradability and water absorption.
  • the method of the invention can include the step of crushing the biodegradable product to be pelletized.
  • the crushing step may be simply cutting or pulverizing into particles.
  • the crushing step is a step of cutting into small pieces and then pulverizing them into particles.
  • "crushing" includes not only physical processing as described above, but also chemical processing to make biodegradable products more easily decomposed.
  • the machine used for crushing can be changed depending on the product to be crushed.
  • a cutting machine such as a shredder, a rotary cutter, or a slitter cutter can be used, and an impact crusher such as a cutter mill, hammer mill, or pin mill can be used.
  • an impact crusher such as a cutter mill, hammer mill, or pin mill can be used.
  • a single-screw type or two-screw type shear type crusher can be used in the crushing step.
  • a secondary fine crushing process can be performed.
  • a media type crusher may be used as the crusher.
  • Media type crushers include container driven type crushers and media agitation type crushers.
  • container-driven crushers include rolling mills, vibration mills, planetary mills, centrifugal fluid mills, etc.
  • media agitation type crushers include tower-type crushers such as tower mills; attritors, aquamizers, Examples include stirring tank type pulverizers such as sand grinders; flow tank type pulverizers such as Visco Mill and Pearl Mill; flow tube type pulverizers; annular type pulverizers such as Coball Mill; and continuous dynamic type pulverizers.
  • the final particle size can be selected as appropriate depending on the workability, etc., when the crushed fiber products are later pelletized or placed or mixed in the soil as they are. For example, after being crushed into a size of about 15 mm to 300 mm or 20 mm to 50 mm in a primary crushing process, it may be crushed to a size of about 2 to 20 mm or 3 to 10 mm in a secondary crushing process.
  • the method of the invention can include the step of pelletizing the crushed biodegradable product as described above.
  • the process of placing or mixing it into the soil can be carried out very efficiently and mechanically on a large scale.
  • pelletized biodegradable products can be placed or mixed into the soil in uniform amounts and in large quantities, it is very difficult to perform the pelleting process to retain moisture in the soil. It is valid.
  • Pelletization can be performed by melt-kneading the crushed biodegradable product and then pelletizing it. Further, the pelletizer may be integrated with a crusher used in the crushing process.
  • melt-kneading device examples include a single-screw extruder, a twin-screw extruder, a kneader, and a Banbury mixer. Further, when the biodegradable product contains volatile components such as water, it is preferable to attach a devolatilization device to the melt-kneading device.
  • the temperature during melt-kneading is appropriately set depending on the melting temperature of the biodegradable product, and can be, for example, within the range of 90 to 300°C.
  • the biodegradable product is cut into granular pellets with a diameter of 1 mm to 30 mm or 5 mm to 20 mm using various pelletizers.
  • the pelletizer is not particularly limited, and any known method can be applied. Specifically, there are underwater pelletizers, in which strands are extruded directly into water from the die of the kneading device and then cut, strand pelletizers, in which rod-shaped strands are extruded from the die, cooled with water or air cooling to a temperature at which they do not stick to each other, and then cut with a rotating blade, and from the die. Any pelletizer such as a hot-cut pelletizer that cuts immediately after extrusion into the air can be suitably used. Depending on the format of the pelletizer, the pellets can take various shapes such as cylindrical, lenticular, and spherical, and any of them can be suitably used.
  • a binder may be added to the biodegradable product during or after pelletizing. Depending on the type of biodegradable product, it may be difficult to form pellets even when heated and pelletized, or the pellets may lose their shape during dispersion, making it difficult to spray large quantities by machine. These problems can be solved by using agents.
  • the binder is preferably biodegradable or volatile, and may be water, oil such as vegetable oil or animal oil, gelatin, or the like.
  • the method of the invention can include the step of incorporating an enzyme into the biodegradable product.
  • This allows biodegradable products that are placed or mixed into the soil to provide very high effects on crop growth, and the degradability of biodegradable products is also high, so biodegradable products can be used for a short period of time. It was found that it can be consumed in the soil.
  • these enzymes activate the function of soil microorganisms, increase the number of useful bacteria, suppress the proliferation of harmful bacteria, and maintain the balance of soil microorganisms, thereby preventing the generation of harmful gases and revitalizing the soil. be able to.
  • the enzyme mixing step can typically be performed by immersing the biodegradable product in an enzyme-containing solution, particularly an enzyme-containing aqueous solution.
  • the enzyme mixing step may be performed at any stage before the placement or mixing step, but for example, the biodegradable product may be immersed in the enzyme-containing liquid as it is before the crushing step, or the biodegradable product may be immersed in the enzyme-containing liquid as it is, or the After that, the crushed biodegradable product may be immersed in an enzyme-containing solution.
  • the biodegradable product can be crushed while wet with the liquid, and the heat during crushing can dry the biodegradable product.
  • the heat during crushing can dry the biodegradable product.
  • the drying step can be substantially omitted.
  • a drying step may be performed to dry the water content of the enzyme-containing aqueous solution.
  • the enzyme used is not particularly limited as long as it is suitable for growing agricultural crops, but agricultural enzymes are preferred. Agricultural enzymes are thought to be able to improve the yield and quality of agricultural crops by rendering soil treated with pesticides, herbicides, chemical fertilizers, etc. harmless.
  • microorganisms used to make agricultural enzymes can be grown in sealed tanks containing nutrients such as sugar, starch, soybeans, and corn, making them safer than chemical fertilizers because they are bio-based. Since it is considered to have high properties, it can be said that it has high affinity with the method of the present invention.
  • enzymes used include phosphatase, dehydrogenase, sulfatase, protease, etc., and enzymes obtained from liquid extracted from bamboo or by fermenting various agricultural products, such as Manda Koso. (trademark), Oishi Kozo (trademark), etc. may be used. These enzymes are commercially available, and those skilled in the art can appropriately select an enzyme depending on the intended use.
  • liquid fertilizers for growing crops may be mixed into biodegradable products.
  • Liquid fertilizer is an aqueous solution containing nutrients, and serves to supply nutrients to agricultural crops.
  • the liquid fertilizer does not need to be particularly limited as long as it fulfills this role, and liquid fertilizers containing various nutritional components can be used. Examples of such nutrients include nitrogen, potassium, and phosphorus.
  • the method of the invention may further include the step of mixing the crushed biodegradable product, particularly the crushed and pelletized biodegradable product, with manure to compost the manure.
  • the biodegradable product used in the present invention is hydrophilic, so it can be well mixed with manure, and the biodegradable product obtained by turning the manure into compost retains moisture in the soil. It can be used as an organic fertilizer.
  • the process of composting the manure by mixing it with manure involves, for example, using the crushed biodegradable product as bedding for several days to several weeks in a livestock building such as a cow shed, a pigsty, or a stable, and then collecting it. This can be done by providing an additional ripening period for compost, if necessary.
  • bedding mixes with filth such as animal excrement and urine, so by replacing it at predetermined intervals, it is possible to obtain a biodegradable product mixed with compost.
  • the step of composting the manure by mixing it with animal manure can be carried out by simply mixing it with animal manure and leaving it for several days to several weeks.
  • the method for producing a soil reforming material of the present invention includes a step of fermenting a mixture of a textile product and a fermentable organic substance to obtain a fermented mixture.
  • the method for producing a soil improvement material of the present invention includes a step of crushing a textile product, a step of mixing the crushed textile product with a fermentable organic substance to obtain a fermentable mixture, and a step of fermenting the fermentable mixture to ferment the fermentable mixture. and pelletizing the fermented mixture.
  • the soil amendment material manufactured by the present invention can function as a soil activator that greatly activates the soil when placed or mixed with the soil. Therefore, it can be effectively used for producing agricultural products such as vegetables.
  • the effect of soil activation was evaluated using the quantitative evaluation method adopted by the present inventor. It was found that this can be obtained even when synthetic fibers, which are usually considered to have no or low biodegradability, are used as textile products.
  • the soil reforming material obtained in this way is very advantageous because it can be used not only as a soil reforming material by itself, but also as a fertilizer.
  • the soil improvement material produced by the method of the present invention can be made of any kind of fiber products used as raw materials, there is no need to separate the fibers, and all textile products can be used. It is also very advantageous to be able to
  • the soil reforming material obtained by the method of the present invention is pelletized, it can be spread on farmland in large quantities using a tractor. According to studies conducted by the present inventors, it was possible to decompose one ton of biodegradable products per one plot (approximately 1000 m 2 ) of farmland, for example, in one to two months.
  • the textile product used in the present invention is not particularly limited in type as long as it can bring about the advantageous effects of the present invention and contains fibers.
  • the fibers may be natural fibers or synthetic fibers, as detailed below.
  • Textile products may be industrial products, and industrial products may include all products that can be manufactured industrially, such as clothing, tableware, containers, furniture, building materials, toys, books, etc. Can be done.
  • a textile product is typically a fabric containing fibers, but is not limited thereto.
  • the fabric is typically a fabric derived from clothing, but fabrics derived from textile products for furniture such as sheets and futons are also useful.
  • the textile products used in the method of the present invention are clothing. Consumers who take fashion trends into account generally purchase new clothing according to trends and dispose of clothing that is no longer fashionable. However, it also goes against the intentions of the fashion industry for such consumers to continue wearing out-of-fashion clothing in consideration of the environment.
  • the method of the present invention allows consumers to protect the global environment even if they continue to purchase new clothes in a short period of time, and is also beneficial for the fashion industry as it allows consumers to purchase new clothes in a short period of time. Become.
  • the textile product used in the present invention may be a hydrophilic biodegradable industrial product containing fibers. It has been found that soil activation can be promoted when biodegradable products such as natural fibers are used as the fiber products used in the present invention.
  • the hydrophilic biodegradable industrial product may be the same as described in relation to the first embodiment.
  • textile products mention may be made in particular of products containing natural fibers, such as cotton, linen, silk, wool, or materials derived therefrom.
  • natural fibers such as cotton, linen, silk, wool, or materials derived therefrom.
  • the present inventor has found that among these, cotton and hemp, especially fibers used for Japanese paper, are especially suitable for use because they have excellent biodegradability in soil and very high water absorption.
  • the textile products used in the present invention may be products made of chemically based synthetic fibers that are generally not considered biodegradable.
  • the degree of soil activation is not as high as when using natural fibers, but the point is that even these fibers can be used as raw materials for soil improvement materials. was unexpected.
  • chemical fibers that are normally considered to have no or low biodegradability can be used as soil improvement materials. It was found that it can be used as a raw material for
  • such chemical fibers include polyester fibers, nylon fibers, polyurethane fibers, acrylic fibers, and fibers that are combinations of these fibers.
  • the textile products used in the present invention contain 20% by mass or more, 25% by mass or more, 30% by mass or more, 50% by mass or more, 70% by mass or more, 80% by mass or more of the above-mentioned chemical-based synthetic fibers, or The content may be 90% by mass or more, 100% by mass or less, 90% by mass or less, 80% by mass or less, 60% by mass or less, or 50% by mass or less.
  • the process of crushing the textile product may be the same as the process of pre-treating the biodegradable product described in the first embodiment.
  • the process of crushing textile products may be a process of crushing only textile products, but it may also be a process of crushing not only textile products but also a mixture of fermentable organic matter and textile products as described below.
  • it may be a step of fermenting a mixture of a textile product and a fermentable organic substance and crushing the fermented mixture. That is, the order of the step of crushing the textile product, the step of obtaining the fermentable mixture, and the step of obtaining the fermented mixture is not limited.
  • the final particle size can be selected as appropriate depending on the workability, etc., when the crushed fiber products are later pelletized or placed or mixed in the soil as they are. For example, after being crushed into a size of about 15 mm to 300 mm or 20 mm to 50 mm in a primary crushing process, it may be crushed to a size of about 2 to 20 mm or 3 to 10 mm in a secondary crushing process.
  • the process of obtaining a fermentable mixture is a process of mixing a textile product and a fermentable organic substance, and the mixing method is not particularly limited.
  • Fermentable organic substances are not particularly limited as long as they can be fermented by microorganisms, and may be organic substances that are food-derived raw materials, such as rice bran, okara, molasses, rice husks, fish meal, rice straw, or wheat straw; Examples include animal manure that can be fermented and composted, such as cow manure and chicken manure.
  • the mass ratio when mixing textile products and fermentable organic matter depends on the type of textile product used, but the fermentable organic matter is at least 20% by mass and 30% by mass based on the total of textile products and fermentable organic matter. % or more, or 40% by mass or more, and may be 80% by mass or less, 70% by mass or less, 60% by mass or less, 50% by mass or less, or 40% by mass or less.
  • the mass of the fermentable organic matter relative to the total of the textile product and the fermentable organic matter is 20% by mass or more and 80% by mass or less, and when the textile product is a highly biodegradable fiber, such as a natural fiber, the textile product
  • the mass of the total of the and the fermentable organic matter can be 20% by mass or more and 50% by mass or less or 30% by mass or more and 40% by mass or less, and when the textile product is a fiber with low biodegradability, for example, a synthetic fiber.
  • the mass of the textile product and the fermentable organic matter relative to the total may be 30% by mass or more and 70% by mass or less, or 40% by mass or more and 60% by mass or less.
  • the fermentable mixture can further contain water to make conditions suitable for fermentation, for example, the water content in the mixture is 10% by mass or more, 20% by mass or more, 30% by mass or more, or 40% by mass. or more, and may be 60% by mass or less, 50% by mass or less, 40% by mass or less, or 30% by mass or less.
  • the water content of the fermentable mixture may be 10% by mass or more and 60% by mass or less, or 20% by mass or more and 40% by mass or less.
  • the step of obtaining the fermented mixture is a step of fermenting the above-mentioned fermentable mixture, and the conditions are not particularly limited as long as the fermentation can be carried out.
  • the fermentation step can be carried out at a temperature of 25°C or higher, 30°C or higher, 35°C or higher, or 40°C or higher, and 60°C or lower, 55°C or lower, 50°C or lower, or 45°C or lower.
  • the fermentation process is performed at a relative humidity of 50% or more, 55% or more, 60% or more, or 65% or more and 90% or less, 85% or less, 80% or less, 75% or less, or 70% or less. Can be done with humidity.
  • the period for fermentation can be 1 week or more, 2 weeks or more, 3 weeks or more, or 8 weeks or less, 6 weeks or less, or 4 weeks or less.
  • the fermentation process can be carried out at a temperature of 35° C. or more and 45° C. or less, and a relative humidity of 50% or more and 75% or less, for a period of 2 weeks or more and 6 weeks or less.
  • the fermentation process can be carried out with ventilation and water added to the fermentable mixture as needed.
  • this step may be a step of composting the fermentable mixture, and this step can be performed by allowing the fermentable mixture containing animal excrement to stand for several days to several weeks.
  • the method of the invention can include pelletizing the fermented mixture.
  • pelletizing the fermented mixture By pelletizing the fermented mixture, the process of placing or mixing into the soil can be carried out very efficiently and mechanically on a large scale. Further, the pelletizing process is very effective because pellets can be placed or mixed in the soil in a uniform amount and in large quantities.
  • the pelletizer that can be used in the pelletizing step the same pelletizer as described in the first embodiment can be used.
  • the moisture content of the fermented mixture can be 30% by mass or less, 20% by mass or less, or 15% by mass or less, and 1% by mass or more, 5% by mass or more, or 10% by mass or more. .
  • Hard pellets are advantageous when the process of placing or mixing into the soil is performed mechanically on a large scale.
  • the fermented mixture can be dried to lower the moisture content before pelletizing.
  • the drying temperature can be 5°C or higher, 10°C or higher, 20°C or higher, or 30°C or higher, and 50°C or lower, 45°C or lower, 40°C or lower, or 35°C or lower.
  • pelletization can be carried out at a temperature of 10°C or more and 40°C or less, which allows pellets to be obtained without adversely affecting the microorganisms present in the fermented mixture, and can be used as a soil improvement material. Become useful.
  • the method of the present invention further relates to a method of producing agricultural crops using soil in which the above-mentioned soil amendment material is arranged or mixed.
  • the soil improved as described above has a high water retention property, and it is easy to produce agricultural products in such soil.
  • Agricultural crops include, but are not limited to, grains such as rice and wheat, vegetables, fruits, and flowers. From the viewpoint of consuming a large amount of biodegradable products or textile products, agricultural crops may be annual plants.
  • the soil activation method of the present invention includes a step of disposing or mixing a soil reforming material in soil.
  • soil refers to soil that can grow agricultural products and microorganisms, and such soil can decompose biodegradable products or textile products such as those described above by microorganisms.
  • the step of placing or mixing the soil amendment material in the soil may be simply placing the soil amendment material on the surface of the soil, or may be simply burying the soil amendment material in the soil. However, it is preferable to actively mix it with the soil. Mixing may be performed manually or mechanically.
  • the soil reforming material used in the method of the present invention is pelletized, it can be mechanically sprayed onto the soil in large quantities.
  • a tractor with a fertilizer spreader can spread a large amount of soil amendment material.
  • the present invention also relates to a soil amendment material or artificial soil that can be used in the method described above.
  • a soil amendment material or artificial soil that can be used in the method described above.
  • the soil reforming material or artificial soil of the present invention contains 80% by mass or more of hydrophilic biodegradable fibers and is in the form of pellets.
  • This pelleted soil amendment material or artificial soil may also contain agricultural enzymes such as those mentioned above, and such soil amendment material or artificial soil may contain hydrophilic biodegradable materials such as cotton, hemp, and Japanese paper. It can be obtained by immersing clothing made from synthetic fibers in an enzyme-containing solution, cutting it, crushing it, and pelletizing it with a pelletizer.
  • the soil reforming material or artificial soil of the present invention contains fibers and a fermented product of fermentable organic matter, and is in the form of pellets.
  • the fermentable organic substance is preferably a food-derived raw material, such as rice bran, okara, molasses, rice hulls, fish meal, rice straw, wheat straw, and combinations thereof.
  • a soil conditioner or artificial soil can be used by being mixed or placed in soil, but it can also be used as it is instead of soil for potted plants, etc., without being mixed with soil. In veranda vegetable gardens, it is sometimes a problem to dispose of the soil after cultivation, but this soil conditioner or artificial soil is very easy to dispose of because it can be disposed of as combustible garbage.
  • the clothes taken out of the enzyme-containing solution were dehydrated, coarsely ground to about 100 mm to 10 mm using a crusher, and further finely crushed using a crusher (DASE series, Seiho Engineering Co., Ltd.). As a result, biodegradable fibers crushed into pieces of 10 mm or less were obtained.
  • the biodegradable fibers were pelletized using a pelletizer to obtain a pelleted soil reforming material containing Japanese paper and enzymes. The photograph is shown in Figure 1.
  • the soil reforming material thus obtained was spread on the soil in an amount of about 1 ton/tan (approximately 1000 m 2 ) using a tractor equipped with a fertilizer spreader to produce vegetables such as eggplants, radishes, and Chinese cabbage.
  • vegetables such as eggplants, radishes, and Chinese cabbage.
  • the above-mentioned soil reforming material disappeared in 1.5 to 2 months.
  • pelletized soil reforming material was used as bedding material in livestock barns for one month, and then collected and mixed with soil.
  • ⁇ Second embodiment> ⁇ Manufacturing ⁇ Clothes containing the fibers listed in Table 1 were coarsely crushed to about 100 mm to 30 mm using a crusher, and then finely crushed using a crusher (DASE series, Seiho Engineering Co., Ltd.). As a result, fibers pulverized to about 6 to 9 mm were obtained.
  • FIG. 2 shows the fibers after being coarsely pulverized
  • FIG. 3 shows the fibers after being finely pulverized.
  • the crushed fibers were mixed with rice bran.
  • the fibers and rice bran were mixed at a ratio of 2:1, and in the case of synthetic fibers, they were mixed at a ratio of 1:1. Thereafter, water was added to adjust the water content to 20 to 35% by mass.
  • FIG. 4 shows the state of the fermentable mixture immediately after it was obtained and the fermented mixture after 3 weeks of fermentation.
  • FIG. 5(a) shows the fermented mixture being put into a pelletizer
  • FIG. 5(b) shows the pellets obtained thereby.
  • the soil evaluation was outsourced to DGC Technology Co., Ltd. Here, for each sample, soil was collected at three or more locations and the average value was evaluated.
  • the degree of crop growth in the soil was evaluated by the method described in Japanese Patent No. 5807956. This involves placing a diluted sample of soil in a test plate containing 95 different types of organic matter, and using a special robot to continuously measure the soil at a constant temperature at 15-minute intervals for 48 hours. Examine the rate at which each organic substance is decomposed by the living microorganisms.
  • the types of organic matter that can be decomposed by microorganisms differ, so the fact that many kinds of organic matter can be decomposed means that there are many kinds of microorganisms, and the fact that the rate of decomposition of organic matter is fast means that This means that microorganisms are actively working.
  • the results of measuring both microbial diversity and activity are quantified and evaluated as a soil microbial diversity/activity value (BIOTREX (trademark)).
  • soil microbial diversity and activity values are 500,000 to 700,000 for average soil, 700,000 to 1,000,000 for soil that is relatively well prepared, and 1,000,000 to 1,300,000 for soil that is rich and disease-free. Soil is said to be difficult to grow and yield delicious agricultural products, 1.3 million to 1.5 million is considered to be very rich soil, and 1.5 million to 2 million is extremely rich soil.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
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  • Pest Control & Pesticides (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
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Abstract

The present invention provides: a method for producing a new soil conditioner that can create a sound material-cycle society; and a soil activation method using the same. The present invention pertains to a method that is for producing a soil conditioner, and that comprises a step for forming, into pellets, crushed biodegradable products. The biodegradable products are hydrophilic biodegradable industrial products. The present invention also pertains to a soil conditioner containing 30 mass% or more of hydrophilic biodegradable fibers. Furthermore, the method for producing a soil conditioner according to the present invention comprises: a step for obtaining a fermentable mixture by mixing fiber products and fermentable organic matter; and a step for obtaining a fermented mixture by fermenting the fermentable mixture. Further, a method for activating soil according to the present invention comprises a step for mixing with soil, or placing on soil, a soil conditioner produced by such a soil conditioner production method.

Description

土壌改質材及びその製造方法、並びにそれを用いた土壌の改良方法Soil reforming material, its manufacturing method, and soil improvement method using the same
 本発明は、土壌改質材及びその製造方法、並びにそれを用いた土壌の改良方法に関する。 The present invention relates to a soil reforming material, a method for producing the same, and a method for improving soil using the same.
 持続可能な開発目標(Sustainable Development Goals : SDGs)の1つとして、「つくる責任つかう責任(Responsible Consumption and Production)」が掲げられており、大量消費社会のあり方が見直されている。 One of the Sustainable Development Goals (SDGs) is “Responsible Consumption and Production,” and the state of mass consumption society is being reconsidered.
 それに対して、例えばファッション業界では、トレンドを先読みし、売れるとわかったものしか作らないマーチャンダイズプランを掲げており、これにより、ひたすらサンプルを作り続け、トレンドが過ぎたものは棄てるといった、大量生産・大量消費・大量廃棄が発生している。 On the other hand, in the fashion industry, for example, there is a merchandising plan in which trends are predicted and only products that are known to sell are produced. Mass consumption and mass disposal are occurring.
 実際に、日本における衣服の廃棄量は年間100万トンを超えるとされており、世界で見ると年間1億トンに近い衣服が廃棄されている。その約7割は生産する企業側が生み出しており、トレンドに応じた売れる衣服を大量生産するために作られる多くのサンプル及び過剰な在庫品が廃棄されている。製造された衣服は、大量に消費者の元へ届き、消費されるものの、不要となる衣服は大量に生まれ、結果として廃棄物となっている。 In fact, the amount of clothing discarded in Japan is estimated to exceed 1 million tons per year, and worldwide, nearly 100 million tons of clothing are discarded annually. Approximately 70% of this is generated by manufacturing companies, and many samples and excess inventory that are made to mass produce clothes that sell according to trends are discarded. Although manufactured clothing is delivered to consumers in large quantities and consumed, a large amount of unnecessary clothing is produced, resulting in waste.
 このような状況の下、様々な製品のリサイクル技術が開発されている。例えば、特許文献1は、有機廃棄物を成型、焼成等を行って土壌改良材として利用する技術を開示している。繊維のリサイクル技術を開示している。 Under these circumstances, various product recycling technologies are being developed. For example, Patent Document 1 discloses a technique for molding, burning, etc. organic waste and using it as a soil improvement material. Discloses textile recycling technology.
 特許文献2は、いわゆる紙コップをパルプ土壌として再利用する技術を開示している。 Patent Document 2 discloses a technique for reusing so-called paper cups as pulp soil.
特開2002-248442号公報Japanese Patent Application Publication No. 2002-248442 特開2016-93772号公報Japanese Patent Application Publication No. 2016-93772
 本発明は、循環型社会を構成することができる、土壌改質材及びその製造方法、並びにそれを用いた土壌の改良方法を提供することを目的とする。 An object of the present invention is to provide a soil reforming material, a method for producing the same, and a method for improving soil using the same, which can constitute a recycling-oriented society.
 本発明者らは、以下の態様を有する本発明により、上記課題を解決できることを見出した。
《態様1》
 破砕した生分解性製品をペレット化する工程を含み、前記生分解性製品が、親水性の生分解性工業製品である、土壌改質材の製造方法。
《態様2》
 前記生分解性製品が、衣服である、態様1に記載の方法。
《態様3》
 前記衣服が、生分解性繊維を30質量%以上で含む、態様2に記載の方法。
《態様4》
 前記生分解性繊維が、和紙である、態様3に記載の方法。
《態様5》
 前記生分解性製品を酵素と混合する工程をさらに含む、態様1~4のいずれか一項に記載の方法。
《態様6》
 前記生分解性製品を糞尿と混合して前記糞尿を堆肥化する工程をさらに含む、態様1~5のいずれか一項に記載の方法。
《態様7》
 繊維製品と発酵性有機物との混合物を発酵させて発酵した混合物を得る工程を含む、土壌改質材の製造方法。
《態様8》
 前記繊維製品が破砕されている、態様7に記載の方法。
《態様9》
 前記発酵した混合物を得る工程の後に、前記発酵した混合物をペレット化する工程を含む、態様7に記載の方法。
《態様10》
 前記繊維製品が、布地を含む、態様7に記載の方法。
《態様11》
 前記布地が、衣服に由来している、態様10に記載の方法。
《態様12》
 前記繊維製品が、化学繊維を含む、態様7に記載の方法。
《態様13》
 前記発酵性有機物が、食品由来原料である、態様7に記載の方法。
《態様14》
 前記食品由来原料が、米ぬか、おから、糖蜜、もみがら、魚粉、稲わら、麦わら及びこれらの組み合わせである、態様13に記載の方法。
《態様15》
 前記繊維製品が、化学繊維を含み、かつ前記発酵性有機物が、食品由来原料である、態様7に記載の方法。
《態様16》
 態様1~15のいずれか一項に記載の方法によって製造された土壌改質材を土壌に配置又は混合する工程、及び前記土壌で農作物を生産する工程を含む、農作物の生産方法。
《態様17》
 態様1~15のいずれか一項に記載の方法によって製造された土壌改質材を、土壌に配置又は混合する工程を含む、土壌の活性化方法。
The present inventors have discovered that the above problems can be solved by the present invention having the following aspects.
《Aspect 1》
A method for producing a soil reforming material, comprising the step of pelletizing a crushed biodegradable product, the biodegradable product being a hydrophilic biodegradable industrial product.
《Aspect 2》
A method according to aspect 1, wherein the biodegradable product is clothing.
《Aspect 3》
The method according to aspect 2, wherein the garment contains 30% by mass or more of biodegradable fibers.
《Aspect 4》
The method according to aspect 3, wherein the biodegradable fiber is Japanese paper.
《Aspect 5》
A method according to any one of aspects 1 to 4, further comprising the step of mixing the biodegradable product with an enzyme.
《Aspect 6》
The method according to any one of aspects 1 to 5, further comprising the step of mixing the biodegradable product with manure and composting the manure.
《Aspect 7》
A method for producing a soil improvement material, including a step of fermenting a mixture of a textile product and a fermentable organic substance to obtain a fermented mixture.
《Aspect 8》
8. The method according to aspect 7, wherein the textile product is crushed.
《Aspect 9》
8. The method according to aspect 7, comprising the step of pelletizing the fermented mixture after the step of obtaining the fermented mixture.
《Aspect 10》
8. The method of embodiment 7, wherein the textile product comprises a fabric.
《Aspect 11》
11. A method according to aspect 10, wherein the fabric is derived from a garment.
《Aspect 12》
8. The method according to aspect 7, wherein the textile product comprises a synthetic fiber.
《Aspect 13》
The method according to aspect 7, wherein the fermentable organic substance is a food-derived raw material.
《Aspect 14》
The method according to aspect 13, wherein the food-derived raw material is rice bran, okara, molasses, rice hulls, fishmeal, rice straw, wheat straw, and combinations thereof.
《Aspect 15》
The method according to aspect 7, wherein the textile product contains a chemical fiber and the fermentable organic substance is a food-derived raw material.
《Aspect 16》
A method for producing agricultural products, the method comprising the steps of disposing or mixing a soil reforming material produced by the method according to any one of aspects 1 to 15 in soil, and producing agricultural products using the soil.
《Aspect 17》
A method for activating soil, comprising a step of placing or mixing in soil a soil reforming material produced by the method according to any one of Aspects 1 to 15.
 第1の実施形態によれば、工業製品を土壌改質材に転換することができ、この土壌改質材で土壌の改質をして野菜等を生産することができる。これにより、循環型社会を構成することができるため本発明の方法は、非常に有益である。 According to the first embodiment, industrial products can be converted into soil reforming materials, and soil can be modified with this soil modifying material to produce vegetables and the like. As a result, the method of the present invention is very useful because it is possible to construct a recycling-oriented society.
 第2の実施形態によれば、製造された土壌改質材は、土壌を大いに活性化することができる。また、本発明によって製造される土壌改質材は、工業製品を原料することができ、この土壌改質材で土壌の改質をして野菜等を生産することができる。これにより、循環型社会を構成することができるため本発明の方法は、非常に有益である。 According to the second embodiment, the manufactured soil reforming material can greatly activate soil. Furthermore, the soil reforming material produced according to the present invention can be made from industrial products, and can be used to improve soil and produce vegetables and the like. As a result, the method of the present invention is very useful because it is possible to construct a recycling-oriented society.
図1は、実施例において製造された第1の実施形態の土壌改質材の実際の写真である。FIG. 1 is an actual photograph of the soil amendment material of the first embodiment manufactured in the example. 図2は、第2の実施形態に関して、粗粉砕を行った状態の繊維を示している。FIG. 2 shows the fibers in a coarsely pulverized state according to the second embodiment. 図3は、第2の実施形態に関して、微粉砕を行った状態の繊維を示している。FIG. 3 shows the fibers in a finely pulverized state according to the second embodiment. 図4は、第2の実施形態に関して、発酵性混合物を得た直後の状態と、3週間発酵させた後の発酵した混合物とを示している。FIG. 4 shows the fermentable mixture immediately after obtaining it and the fermented mixture after fermentation for 3 weeks regarding the second embodiment. 図5(a)は、第2の実施形態に関して、発酵した混合物をペレタイザーに投入している状態を示しており、図5(b)は、それにより得られたペレットを示している。Regarding the second embodiment, FIG. 5(a) shows a state where the fermented mixture is being put into a pelletizer, and FIG. 5(b) shows the pellets obtained thereby.
 本明細書において、その発明の課題を解決することができる限り、1つの実施形態の発明の構成は、本明細書において開示されている他の実施形態の発明の構成と、相互に交換可能である。 In this specification, the configuration of the invention of one embodiment is interchangeable with the configuration of the invention of other embodiments disclosed in this specification, as long as the problem of the invention can be solved. be.
《第1の実施形態》
 第1の実施形態において、本発明の土壌改質材の製造方法は、破砕した生分解性製品をペレット化する工程を含む。ここで、生分解性製品とは、親水性の生分解性工業製品である。
《First embodiment》
In a first embodiment, the method for producing a soil reforming material of the present invention includes a step of pelletizing a crushed biodegradable product. Here, the biodegradable product is a hydrophilic biodegradable industrial product.
 このようにして製造された土壌改質材を土壌に配置又は混合すると、一定期間後に分解されて土壌に還る。したがって、本発明の方法によって用いられる工業製品は、大量に生産されたとしても、土壌で分解されるため廃棄物とはならない。ここで、本発明で用いられる工業製品は親水性で水を含むことができるため、土壌に配置又は混合された場合には、土壌の含水率を向上及び又は維持することができ、野菜の生産をするために有効に利用することができる。また、本発明の方法によって得られた土壌改質材は、ペレット化されていることで、トラクターによって大量に農地に散布することができる。本発明者らの検討によれば、1反(約1000m)の農地当たり、1~2ヶ月で、1トンもの生分解性製品を分解させることができた。 When the soil reforming material produced in this manner is placed or mixed in soil, it is decomposed and returned to the soil after a certain period of time. Therefore, even if the industrial products used by the method of the present invention are produced in large quantities, they will not become waste because they will be decomposed in the soil. Here, since the industrial products used in the present invention are hydrophilic and can contain water, when placed in or mixed with soil, they can improve and/or maintain the moisture content of the soil, and produce vegetables. It can be used effectively to Moreover, the soil reforming material obtained by the method of the present invention is pelletized, so that it can be sprayed on farmland in large quantities by a tractor. According to studies conducted by the present inventors, it was possible to decompose one ton of biodegradable products per one farmland (approximately 1000 m 2 ) in one to two months.
〈生分解性製品〉
 本発明で用いられる生分解性製品は、親水性の生分解性工業製品である。親水性の生分解性工業製品とは、親水性の生分解性材料のみで実質的に構成された工業製品をいうが、野菜等の農作物の生育に悪影響を与えないのであれば、その一部が親水性である必要はなく、また生分解性材料でなくてもよい。親水性の繊維製品は、最終的に得られる土壌改質材も親水性にすることができる。したがって、これを土壌に配置又は混合した場合には、土壌の含水率を向上及び又は維持することができ、野菜の生産をするために有効に利用することができる。
<Biodegradable products>
The biodegradable product used in the present invention is a hydrophilic biodegradable industrial product. A hydrophilic biodegradable industrial product is an industrial product that is substantially composed only of hydrophilic biodegradable materials, but if it does not adversely affect the growth of agricultural products such as vegetables, a portion of the product may be does not need to be hydrophilic or a biodegradable material. Hydrophilic fiber products can also make the final soil improvement material hydrophilic. Therefore, when this is placed or mixed in soil, the moisture content of the soil can be improved and/or maintained, and it can be effectively used for producing vegetables.
 例えば、生分解性製品は、生分解性材料のみから構成されていることが好ましいが、その大部分が生分解性材料で構成されていればよい。例えば、生分解性製品は、上記のような生分解性材料を30質量%以上、40質量%以上、50質量%以上、60質量%以上、70質量%以上、80質量%以上、85質量%以上、90質量%以上、95質量%以上、98質量%以上、又は99質量%以上含むことが好ましい。生分解性製品のうち、生分解性材料ではない部分については、農作物を栽培する土壌に悪影響を与えない材料であることが好ましい。 For example, a biodegradable product is preferably composed only of biodegradable materials, but it is sufficient if most of the product is composed of biodegradable materials. For example, a biodegradable product may contain 30% by mass or more, 40% by mass or more, 50% by mass or more, 60% by mass or more, 70% by mass or more, 80% by mass or more, or 85% by mass of the above-mentioned biodegradable materials. The above content is preferably 90% by mass or more, 95% by mass or more, 98% by mass or more, or 99% by mass or more. The portion of the biodegradable product that is not a biodegradable material is preferably a material that does not adversely affect the soil in which agricultural crops are grown.
 工業製品としては、親水性の生分解性の材料で工業的に製造されうる全ての製品であってよく、例えば、衣服、シーツ、布団等の繊維製品、食器、容器、家具、建材、玩具、本等を挙げることができる。 Industrial products include all products that can be manufactured industrially using hydrophilic and biodegradable materials, such as clothing, textile products such as sheets and futons, tableware, containers, furniture, building materials, toys, Books, etc. can be mentioned.
 生分解性材料としては、自然環境下で土壌の微生物によって分解される材料であれば特に限定されない。例えば、生分解性材料としては、合成系生分解性ポリマー及び天然系生分解性ポリマーの両方を挙げることができる。 The biodegradable material is not particularly limited as long as it is a material that can be decomposed by soil microorganisms in the natural environment. For example, biodegradable materials can include both synthetic and natural biodegradable polymers.
 本明細書において、親水性とは、その製品が水を蓄えることができる性質をいい、材質自体が吸水性である場合だけではなく、材質が撥水性であってもその材質が多孔質で水を保持できる場合を含む。例えば、親水性とは、土壌に混合された際に、その製品が混合されていない状態の土壌と比較して、土壌の含水率を少しでも長く維持できる性質であってもよい。ただし、生分解性製品は、撥水性ではなく、吸水性であることが好ましい。 In this specification, hydrophilicity refers to the ability of a product to store water, and refers not only to cases where the material itself is water-absorbing, but also when the material is water-repellent but is porous and water-absorbing. including cases where it is possible to retain For example, hydrophilicity may be a property that, when mixed with soil, allows the product to maintain the moisture content of the soil for as long as possible compared to the soil without the product mixed therein. However, it is preferable that the biodegradable product is water absorbent rather than water repellent.
 特に、本発明の方法で用いられる生分解性製品は、衣服である。流行のファッション性を考慮する消費者は、流行に応じて新しい衣服を購入して、流行が過ぎた衣服を処分することが一般的である。しかしながら、このような消費者が、環境面を考慮して、流行遅れの衣服を着用し続けることもファッション業界の意図と反してしまう。それに対して、本発明の方法は、消費者が短期間に新しい衣服を購入し続けても、地球環境保護をすることができ、短期間で新しい衣服を購入してもらえるファッション業界としても有益となる。 In particular, the biodegradable product used in the method of the invention is clothing. Consumers who take fashion trends into account generally purchase new clothing according to trends and dispose of clothing that is no longer fashionable. However, it also goes against the intentions of the fashion industry for such consumers to continue wearing out-of-fashion clothing in consideration of the environment. On the other hand, the method of the present invention allows consumers to protect the global environment even if they continue to purchase new clothes in a short period of time, and is also beneficial for the fashion industry as it allows consumers to purchase new clothes in a short period of time. Become.
 生分解性材料としては、自然環境下で土壌の微生物によって分解される材料であれば特に限定されない。例えば、生分解性材料としては、合成系生分解性ポリマー及び天然系生分解性ポリマーの両方を挙げることができる。 The biodegradable material is not particularly limited as long as it is a material that can be decomposed by soil microorganisms in the natural environment. For example, biodegradable materials can include both synthetic and natural biodegradable polymers.
 合成系生分解性ポリマーとしては、ポリ乳酸、ポリカプロラクトン、ポリブチレンサクシネート、ポリエチレンサクシネート、ポリビニルアルコール、ポリグリコール酸、ポリ(カプロラクトン/ブチレンサクシネート)、ポリ(ブチレンサクシネート/アジペート)、ポリ(エチレンテレフタレート/サクシネート)、ポリ(テトラメチレンアジペート/テレフタレート)等を挙げることができる。 Synthetic biodegradable polymers include polylactic acid, polycaprolactone, polybutylene succinate, polyethylene succinate, polyvinyl alcohol, polyglycolic acid, poly(caprolactone/butylene succinate), poly(butylene succinate/adipate), and poly(butylene succinate/adipate). (ethylene terephthalate/succinate), poly(tetramethylene adipate/terephthalate), and the like.
 天然系生分解性ポリマーとしては、セルロース系材料、澱粉系材料等の炭水化物系化合物、ポリペプチド、タンパク質等のアミノ酸系化合物を挙げることができる。 Examples of natural biodegradable polymers include carbohydrate-based compounds such as cellulose-based materials and starch-based materials, and amino acid-based compounds such as polypeptides and proteins.
 生分解性材料としては、特に天然繊維を挙げることができ、例えば綿、麻、絹、ウール、又はこれらに由来する材料を挙げることができる。本発明者は、これらの中でも特に綿及び麻、特に和紙として用いられる繊維が特に土壌における生分解性に優れており、かつ非常に吸水性が高いため、特に好適に用いられることを見出した。 As biodegradable materials, mention may be made in particular of natural fibers, such as cotton, linen, silk, wool, or materials derived therefrom. The present inventor has found that among these, cotton and hemp, especially fibers used for Japanese paper, are especially suitable for use because they have excellent biodegradability in soil and very high water absorption.
 ここで、和紙とは、こうぞ、みつまた、麻類、針葉樹、笹等の和紙に適した原料植物から得られる繊維からなる和紙原料を漉いて作られる紙をいう。特に、生分解性製品が衣服である場合、近年、マニラ麻を原料とした和紙が衣服用として知られており、この生分解性及び吸水性は非常に高いため好適である。 Here, washi refers to paper made by making washi raw materials made from fibers obtained from raw material plants suitable for washi, such as kozo, mitsumata, hemp, coniferous trees, and bamboo. In particular, when the biodegradable product is clothing, Japanese paper made from Manila hemp has recently been known for use in clothing, and is suitable because it has very high biodegradability and water absorption.
〈破砕工程〉
 本発明の方法は、ペレット化する生分解性製品を破砕する工程を含むことができる。破砕工程は、単に切断するだけであってもよく、又は粒状に粉砕する工程であってもよい。好ましくは、破砕工程は、小さく切断した後に、粒状に粉砕する工程である。本明細書において、「破砕」とは、上記のような物理的処理によるものだけではなく、化学的処理によって生分解性製品をより分解しやすくする処理も含む。
<Crushing process>
The method of the invention can include the step of crushing the biodegradable product to be pelletized. The crushing step may be simply cutting or pulverizing into particles. Preferably, the crushing step is a step of cutting into small pieces and then pulverizing them into particles. In this specification, "crushing" includes not only physical processing as described above, but also chemical processing to make biodegradable products more easily decomposed.
 破砕に使用する機械は、破砕する製品に応じて変更することができる。例えば、破砕工程は、シュレッダー、ロータリーカッター、又はスリッターカッター等の裁断機を使用することができ、またカッターミル、ハンマーミル、ピンミル等の衝撃式粉砕機を使用することができる。また、破砕工程は、一軸式又は二軸式のせん断式粉砕機を用いることができる。また、破砕工程は、一次的な粗破砕工程を上記のように行った後に、二次的な微破砕工程を行うことができる。 The machine used for crushing can be changed depending on the product to be crushed. For example, in the crushing step, a cutting machine such as a shredder, a rotary cutter, or a slitter cutter can be used, and an impact crusher such as a cutter mill, hammer mill, or pin mill can be used. Moreover, a single-screw type or two-screw type shear type crusher can be used in the crushing step. Further, in the crushing process, after performing the primary coarse crushing process as described above, a secondary fine crushing process can be performed.
 特に、破砕する生分解性製品が比較的硬質である場合には、破砕機として、媒体式粉砕機を用いてもよい。媒体式粉砕機には容器駆動式粉砕機と媒体攪拌式粉砕機とがある。容器駆動式粉砕機としては、転動ミル、振動ミル、遊星ミル、遠心流動ミル等を挙げることができ、媒体攪拌式粉砕機としては、タワーミル等の塔型粉砕機;アトライター、アクアマイザー、サンドグラインダー等の攪拌槽型粉砕機;ビスコミル、パールミル等の流通槽型粉砕機;流通管型粉砕機;コボールミル等のアニュラー型粉砕機;連続式のダイナミック型粉砕機等を挙げることができる。 In particular, when the biodegradable product to be crushed is relatively hard, a media type crusher may be used as the crusher. Media type crushers include container driven type crushers and media agitation type crushers. Examples of container-driven crushers include rolling mills, vibration mills, planetary mills, centrifugal fluid mills, etc., and examples of media agitation type crushers include tower-type crushers such as tower mills; attritors, aquamizers, Examples include stirring tank type pulverizers such as sand grinders; flow tank type pulverizers such as Visco Mill and Pearl Mill; flow tube type pulverizers; annular type pulverizers such as Coball Mill; and continuous dynamic type pulverizers.
 破砕工程は、後に破砕した繊維製品をペレット化する場合、そのまま土壌に配置又は混合する場合の作業性等に応じて、適宜、最終的に得られる粒径を選択することができる。例えば、一次的な破砕工程によって、15mm~300mm程度又は20mm~50mm程度の大きさに破砕した後に、二次的な破砕工程によって2~20mm程度又は3~10mmの大きさにしてもよい。 In the crushing step, the final particle size can be selected as appropriate depending on the workability, etc., when the crushed fiber products are later pelletized or placed or mixed in the soil as they are. For example, after being crushed into a size of about 15 mm to 300 mm or 20 mm to 50 mm in a primary crushing process, it may be crushed to a size of about 2 to 20 mm or 3 to 10 mm in a secondary crushing process.
〈ペレット化工程〉
 本発明の方法は、上記のように破砕した生分解性製品をペレット化する工程を含むことができる。破砕した生分解性製品をペレット化することによって、土壌に配置又は混合する工程を非常に効率的かつ機械的に大規模に行うことができる。また、ペレット化された生分解性製品は、均一な量で、かつ大量に、土壌に配置又は混合させることができるため、土壌の水分保持をするために、ペレット化工程を行うことは非常に有効である。
<Pelletization process>
The method of the invention can include the step of pelletizing the crushed biodegradable product as described above. By pelletizing the crushed biodegradable product, the process of placing or mixing it into the soil can be carried out very efficiently and mechanically on a large scale. Also, since pelletized biodegradable products can be placed or mixed into the soil in uniform amounts and in large quantities, it is very difficult to perform the pelleting process to retain moisture in the soil. It is valid.
 ペレット化は、破砕した生分解性製品を溶融混練した後にペレット化することができる。また、ペレタイザーは、破砕工程で用いられる破砕機と一体型となっていてもよい。 Pelletization can be performed by melt-kneading the crushed biodegradable product and then pelletizing it. Further, the pelletizer may be integrated with a crusher used in the crushing process.
 溶融混練装置としては、単軸押出機、二軸押出機、ニーダー、バンバリーミキサーなどが挙げられる。また、生分解性製品が水分等の揮発成分を含む場合には、溶融混練装置に脱揮装置を取り付けることが好ましい。 Examples of the melt-kneading device include a single-screw extruder, a twin-screw extruder, a kneader, and a Banbury mixer. Further, when the biodegradable product contains volatile components such as water, it is preferable to attach a devolatilization device to the melt-kneading device.
 溶融混練時の温度は、生分解性製品の溶融温度に応じて適宜設定され、例えば、90~300℃の範囲内でとすることができる。 The temperature during melt-kneading is appropriately set depending on the melting temperature of the biodegradable product, and can be, for example, within the range of 90 to 300°C.
 生分解性製品は、各種のペレタイザーにて直径1mm~30mm又は5mm~20mmの粒状のペレットに裁断される。ペレタイザーとしては特に限定されず、公知の方法が適用できる。具体的には混練装置のダイスから直接水中に押出してカットするアンダーウォーターペレタイザー、ダイスから棒状のストランドとして押出し、互着しない温度まで水冷または空冷で冷却した後に回転刃でカットするストランドペレタイザー、ダイスから空気中に押出しすぐカットするホットカットペレタイザー等のペレタイザーをいずれも好適に用いることができる。ペレタイザーの形式によりペレットは円柱状、レンズ状、球状など各種の形状を取るが、いずれも好適に用いることができる。 The biodegradable product is cut into granular pellets with a diameter of 1 mm to 30 mm or 5 mm to 20 mm using various pelletizers. The pelletizer is not particularly limited, and any known method can be applied. Specifically, there are underwater pelletizers, in which strands are extruded directly into water from the die of the kneading device and then cut, strand pelletizers, in which rod-shaped strands are extruded from the die, cooled with water or air cooling to a temperature at which they do not stick to each other, and then cut with a rotating blade, and from the die. Any pelletizer such as a hot-cut pelletizer that cuts immediately after extrusion into the air can be suitably used. Depending on the format of the pelletizer, the pellets can take various shapes such as cylindrical, lenticular, and spherical, and any of them can be suitably used.
 ペレット化をする際に又はペレット化した後に、生分解性製品に結着剤を添加してもよい。生分解性製品の種類によっては、加熱してペレット化してもペレットの形成が難しい場合があり又は散布の際にペレットの形が崩れ、機械による大量の散布が難しくなる場合があるが、結着剤を用いることによってこのような課題を解決することができる。結着剤としては、生分解性又は揮発性であることが好ましく、例えば水、植物性油脂又は動物性油脂等の油脂、ゼラチン等であってもよい。 A binder may be added to the biodegradable product during or after pelletizing. Depending on the type of biodegradable product, it may be difficult to form pellets even when heated and pelletized, or the pellets may lose their shape during dispersion, making it difficult to spray large quantities by machine. These problems can be solved by using agents. The binder is preferably biodegradable or volatile, and may be water, oil such as vegetable oil or animal oil, gelatin, or the like.
〈酵素混合工程〉
 本発明の方法は、生分解性製品に酵素を含有させる工程を含むことができる。これにより、土壌に配置又は混合される生分解性製品は、農作物の生育に非常に高い効果を提供できることができ、かつ生分解性製品の分解性も高くなるため、生分解性製品を短期間に土壌で消費できることがわかった。また、このような酵素は、土壌微生物の働きを活性化させ、有用菌を増やし、有害菌の繁殖を抑えて土壌微生物のバランスを保ち、それにより有害ガスの発生を防ぎ、土壌に活力を与えることができる。
<Enzyme mixing process>
The method of the invention can include the step of incorporating an enzyme into the biodegradable product. This allows biodegradable products that are placed or mixed into the soil to provide very high effects on crop growth, and the degradability of biodegradable products is also high, so biodegradable products can be used for a short period of time. It was found that it can be consumed in the soil. In addition, these enzymes activate the function of soil microorganisms, increase the number of useful bacteria, suppress the proliferation of harmful bacteria, and maintain the balance of soil microorganisms, thereby preventing the generation of harmful gases and revitalizing the soil. be able to.
 酵素混合工程は、典型的には、生分解性製品を酵素含有液、特に酵素含有水溶液に浸漬することによって行うことができる。 The enzyme mixing step can typically be performed by immersing the biodegradable product in an enzyme-containing solution, particularly an enzyme-containing aqueous solution.
 酵素混合工程は、配置又は混合工程の前であれば、どの段階で行ってもよいが、例えば破砕工程の前に、生分解性製品をそのまま酵素含有液に浸漬させてもよく、又は破砕工程の後に、破砕された生分解性製品を酵素含有液に浸漬させてもよい。 The enzyme mixing step may be performed at any stage before the placement or mixing step, but for example, the biodegradable product may be immersed in the enzyme-containing liquid as it is before the crushing step, or the biodegradable product may be immersed in the enzyme-containing liquid as it is, or the After that, the crushed biodegradable product may be immersed in an enzyme-containing solution.
 破砕工程の前に生分解性製品を酵素含有液に浸漬する場合、生分解製品を液に濡らした状態で破砕することができ、破砕時の熱で生分解性製品を乾燥させることができる。例えば、衣服を酵素含有液に浸漬して裁断機等で一次的に粗粉砕した後、カッターミル等で二次的に微粉砕する場合、一次的破砕時には、液が60質量%程度喪失しており、二次破砕時には、液が80質量%以上喪失させることができる。これにより、乾燥工程を実質的に省略させることができる。一方で、必要に応じて、乾燥工程を行って、酵素含有水溶液の水分を乾燥させてもよい。 If the biodegradable product is immersed in an enzyme-containing liquid before the crushing process, the biodegradable product can be crushed while wet with the liquid, and the heat during crushing can dry the biodegradable product. For example, when clothing is immersed in an enzyme-containing liquid and first coarsely pulverized using a cutter or the like, and then secondarily finely pulverized using a cutter mill or the like, approximately 60% by mass of the liquid is lost during the primary pulverization. During secondary crushing, more than 80% by mass of liquid can be lost. Thereby, the drying step can be substantially omitted. On the other hand, if necessary, a drying step may be performed to dry the water content of the enzyme-containing aqueous solution.
 用いられる酵素としては、農作物を生育するのに適した酵素であれば特に限定されないが、農業用酵素であることが好ましい。農業用酵素は、農薬、除草剤、化学肥料等で処理された土壌を無害化することで、農作物の収穫量と品質を向上できると考えられている。 The enzyme used is not particularly limited as long as it is suitable for growing agricultural crops, but agricultural enzymes are preferred. Agricultural enzymes are thought to be able to improve the yield and quality of agricultural crops by rendering soil treated with pesticides, herbicides, chemical fertilizers, etc. harmless.
 農業用酵素の製造に使用される微生物は、砂糖、デンプン、大豆、トウモロコシなどの栄養分を含む密閉されたタンク中で成長させることができ、バイオベースの薬品であることから、化学肥料よりも安全性が高いと考えられているため、本発明の方法とも親和性が高いといえる。 The microorganisms used to make agricultural enzymes can be grown in sealed tanks containing nutrients such as sugar, starch, soybeans, and corn, making them safer than chemical fertilizers because they are bio-based. Since it is considered to have high properties, it can be said that it has high affinity with the method of the present invention.
 用いられる酵素としては、酵素としては、ホスファターゼ、デヒドロゲナーゼ、スルファターゼ、プロテアーゼ等を挙げることができるが、竹から抽出された液、あるいは各種の農作物に発酵作用を加えて得られたもの、たとえば万田酵素(商標)、大石酵素(商標)等であってもよい。これらの酵素は市販されており、当業者は、適宜、用途に応じて酵素を選択することができる。 Examples of enzymes used include phosphatase, dehydrogenase, sulfatase, protease, etc., and enzymes obtained from liquid extracted from bamboo or by fermenting various agricultural products, such as Manda Koso. (trademark), Oishi Kozo (trademark), etc. may be used. These enzymes are commercially available, and those skilled in the art can appropriately select an enzyme depending on the intended use.
 同様にして、酵素に加えて又は酵素に替えて、農作物生育用の液体肥料を生分解性製品に混合してもよい。液体肥料は、栄養成分を含む水溶液であり、農作物に栄養成分を供給する役割を果たす。液体肥料は、かかる役割を果たす限り特に限定する必要はなく、種々の栄養成分を含んだ液肥を用いることができる。このような栄養素として、例えば、窒素、カリウム、リンなどが挙げられる。 Similarly, in addition to or in place of enzymes, liquid fertilizers for growing crops may be mixed into biodegradable products. Liquid fertilizer is an aqueous solution containing nutrients, and serves to supply nutrients to agricultural crops. The liquid fertilizer does not need to be particularly limited as long as it fulfills this role, and liquid fertilizers containing various nutritional components can be used. Examples of such nutrients include nitrogen, potassium, and phosphorus.
〈堆肥化する工程〉
 本発明の方法は、破砕した生分解性製品、特に破砕してペレット化した生分解性製品を糞尿と混合して糞尿を堆肥化する工程をさらに含むことができる。本発明で用いられる生分解性製品は、親水性であるため糞尿とよく馴染ませることができ、その後、糞尿が堆肥となって得られた生分解性製品は、土壌の水分を好適に保持することができる有機肥料として用いることができる。
<Composting process>
The method of the invention may further include the step of mixing the crushed biodegradable product, particularly the crushed and pelletized biodegradable product, with manure to compost the manure. The biodegradable product used in the present invention is hydrophilic, so it can be well mixed with manure, and the biodegradable product obtained by turning the manure into compost retains moisture in the soil. It can be used as an organic fertilizer.
 糞尿と混合して糞尿を堆肥化する工程は、例えば、牛舎、豚舎、厩舎等の畜舎において、破砕した生分解性製品を数日~数週の間、敷料として用いて、これを回収し、必要に応じてさらに堆肥のための熟成期間を設けることによって行うことができる。畜舎等では、敷料が、動物の糞尿などの汚物と混合するため、所定の期間ごとにこれを交換して、堆肥と混合した生分解性製品を得ることができる。また、糞尿と混合して糞尿を堆肥化する工程は、動物の糞尿と単に混合して、それを数日~数週の間、放置することでこの工程を行うことができる。 The process of composting the manure by mixing it with manure involves, for example, using the crushed biodegradable product as bedding for several days to several weeks in a livestock building such as a cow shed, a pigsty, or a stable, and then collecting it. This can be done by providing an additional ripening period for compost, if necessary. In livestock barns and the like, bedding mixes with filth such as animal excrement and urine, so by replacing it at predetermined intervals, it is possible to obtain a biodegradable product mixed with compost. Further, the step of composting the manure by mixing it with animal manure can be carried out by simply mixing it with animal manure and leaving it for several days to several weeks.
《第2の実施形態》
 第2の実施形態において、本発明の土壌改質材の製造方法は、繊維製品と発酵性有機物との混合物を発酵させて発酵した混合物を得る工程を含む。例えば、本発明の土壌改質材の製造方法は、繊維製品を破砕する工程、前記破砕した繊維製品を発酵性有機物と混合して発酵性混合物を得る工程、前記発酵性混合物を発酵させて発酵した混合物を得る工程、及び前記発酵した混合物をペレット化する工程を含む。
《Second embodiment》
In a second embodiment, the method for producing a soil reforming material of the present invention includes a step of fermenting a mixture of a textile product and a fermentable organic substance to obtain a fermented mixture. For example, the method for producing a soil improvement material of the present invention includes a step of crushing a textile product, a step of mixing the crushed textile product with a fermentable organic substance to obtain a fermentable mixture, and a step of fermenting the fermentable mixture to ferment the fermentable mixture. and pelletizing the fermented mixture.
 このようにして製造された土壌改質材を土壌に配置又は混合すると、一定期間後に分解されて土壌に還る。したがって、本発明の方法によって、原料として用いられる繊維製品は、大量に生産されたとしても、土壌で分解されるため廃棄物とはならない。ここで、本発明者の検討によれば、本発明で製造された土壌改質材は、土壌に配置又は混合された場合に、土壌を大いに活性化する土壌活性化剤として機能することができるため、野菜等の農作物の生産をするために有効に利用することができる。驚くべきことに、本発明においては、繊維製品と発酵性有機物とを混合して発酵させていることによって、本発明者が採用した定量的な評価方法によって評価したところ、この土壌活性化の効果は、通常は生分解性がない又は低いとされるような化学繊維を繊維製品として用いた場合であっても得られることがわかった。 When the soil reforming material produced in this way is placed or mixed into soil, it will be decomposed and returned to the soil after a certain period of time. Therefore, even if the textile products used as raw materials are produced in large quantities by the method of the present invention, they will not become waste because they will be decomposed in the soil. Here, according to the inventor's study, the soil amendment material manufactured by the present invention can function as a soil activator that greatly activates the soil when placed or mixed with the soil. Therefore, it can be effectively used for producing agricultural products such as vegetables. Surprisingly, in the present invention, by mixing and fermenting textile products and fermentable organic matter, the effect of soil activation was evaluated using the quantitative evaluation method adopted by the present inventor. It was found that this can be obtained even when synthetic fibers, which are usually considered to have no or low biodegradability, are used as textile products.
 このようにして得られた土壌改質材は、それ単独で、土壌改質材として用いられるだけではなく、肥料として使用することができるため、非常に有利である。また、本発明の方法によって製造される土壌改良化材は、原料として用いられる繊維製品がどのような繊維であってもよいために、繊維の分別等を行う必要なく、全ての布製品を用いることができることも非常に有利である。 The soil reforming material obtained in this way is very advantageous because it can be used not only as a soil reforming material by itself, but also as a fertilizer. In addition, since the soil improvement material produced by the method of the present invention can be made of any kind of fiber products used as raw materials, there is no need to separate the fibers, and all textile products can be used. It is also very advantageous to be able to
 さらに、本発明の方法によって得られた土壌改質材は、ペレット化されていることで、トラクターによって大量に農地に散布することができる。本発明者らの検討によれば、1反(約1000m)の農地当たり、例えば1~2ヶ月で、1トンもの生分解性製品を分解させることができた。 Furthermore, since the soil reforming material obtained by the method of the present invention is pelletized, it can be spread on farmland in large quantities using a tractor. According to studies conducted by the present inventors, it was possible to decompose one ton of biodegradable products per one plot (approximately 1000 m 2 ) of farmland, for example, in one to two months.
〈繊維製品〉
 本発明で用いられる繊維製品とは、本発明の有利な効果をもたらすことができ、かつ繊維を含む製品であれば、特にその種類を限定されない。ここで、繊維とは、以下に詳述するとおり、天然繊維であってもよく、合成繊維であってもよい。
<Fiber products>
The textile product used in the present invention is not particularly limited in type as long as it can bring about the advantageous effects of the present invention and contains fibers. Here, the fibers may be natural fibers or synthetic fibers, as detailed below.
 繊維製品は、工業製品であってもよく、工業製品としては、工業的に製造されうる全ての製品であってよく、例えば、衣服、食器、容器、家具、建材、玩具、本等を挙げることができる。 Textile products may be industrial products, and industrial products may include all products that can be manufactured industrially, such as clothing, tableware, containers, furniture, building materials, toys, books, etc. Can be done.
 繊維製品は、典型的には、繊維を含む布地であるが、これに限定されない。ここで、布地は、典型的には衣服に由来する布地であるが、例えばシーツ、布団等の家具用の繊維製品に由来する布地も有用である。 A textile product is typically a fabric containing fibers, but is not limited thereto. Here, the fabric is typically a fabric derived from clothing, but fabrics derived from textile products for furniture such as sheets and futons are also useful.
 特に、本発明の方法で用いられる繊維製品は、衣服である。流行のファッション性を考慮する消費者は、流行に応じて新しい衣服を購入して、流行が過ぎた衣服を処分することが一般的である。しかしながら、このような消費者が、環境面を考慮して、流行遅れの衣服を着用し続けることもファッション業界の意図と反してしまう。それに対して、本発明の方法は、消費者が短期間に新しい衣服を購入し続けても、地球環境保護をすることができ、短期間で新しい衣服を購入してもらえるファッション業界としても有益となる。 In particular, the textile products used in the method of the present invention are clothing. Consumers who take fashion trends into account generally purchase new clothing according to trends and dispose of clothing that is no longer fashionable. However, it also goes against the intentions of the fashion industry for such consumers to continue wearing out-of-fashion clothing in consideration of the environment. On the other hand, the method of the present invention allows consumers to protect the global environment even if they continue to purchase new clothes in a short period of time, and is also beneficial for the fashion industry as it allows consumers to purchase new clothes in a short period of time. Become.
 例えば、本発明で用いられる繊維製品は、繊維を含む親水性の生分解性工業製品であってもよい。本発明で用いられる繊維製品として、生分解性製品、例えば天然繊維を用いた場合には、土壌の活性化が促進できることが分かった。 For example, the textile product used in the present invention may be a hydrophilic biodegradable industrial product containing fibers. It has been found that soil activation can be promoted when biodegradable products such as natural fibers are used as the fiber products used in the present invention.
 親水性の生分解性工業製品とは、第1の実施形態に関して述べたものと同一であってよい。 The hydrophilic biodegradable industrial product may be the same as described in relation to the first embodiment.
 繊維製品としては、特に天然繊維を含む製品を挙げることができ、天然繊維としては、例えば綿、麻、絹、ウール、又はこれらに由来する材料を挙げることができる。本発明者は、これらの中でも特に綿及び麻、特に和紙として用いられる繊維が特に土壌における生分解性に優れており、かつ非常に吸水性が高いため、特に好適に用いられることを見出した。 As textile products, mention may be made in particular of products containing natural fibers, such as cotton, linen, silk, wool, or materials derived therefrom. The present inventor has found that among these, cotton and hemp, especially fibers used for Japanese paper, are especially suitable for use because they have excellent biodegradability in soil and very high water absorption.
 一方、本発明で用いられる繊維製品は、一般的には生分解性とはされない化学系の合成繊維による製品であってもよい。このような繊維を用いた場合には、土壌の活性化度合いについては天然繊維を用いた場合と比較して高くはないが、これらの繊維であっても土壌改良材の原料として使用できるという点は、予想外であった。具体的には、本発明においては、繊維製品と発酵性有機物とを混合して発酵させていることによって、通常は生分解性がない又は低いとされるような化学繊維を、土壌改質材の原料として使用できることが分かった。 On the other hand, the textile products used in the present invention may be products made of chemically based synthetic fibers that are generally not considered biodegradable. When using such fibers, the degree of soil activation is not as high as when using natural fibers, but the point is that even these fibers can be used as raw materials for soil improvement materials. was unexpected. Specifically, in the present invention, by mixing and fermenting textile products and fermentable organic matter, chemical fibers that are normally considered to have no or low biodegradability can be used as soil improvement materials. It was found that it can be used as a raw material for
 例えば、そのような化学繊維としては、ポリエステル繊維、ナイロン繊維、ポリウレタン繊維、アクリル繊維、及びこれらを組み合わせた繊維等を挙げることができる。 For example, such chemical fibers include polyester fibers, nylon fibers, polyurethane fibers, acrylic fibers, and fibers that are combinations of these fibers.
 本発明で用いられる繊維製品は、上記のような化学系の合成繊維を20質量%以上、25質量%以上、30質量%以上、50質量%以上、70質量%以上、80質量%以上、又は90質量%以上含んでいてもよく、100質量%以下、90質量%以下、80質量%以下、60質量%以下、又は50質量%以下で含んでいてもよい。 The textile products used in the present invention contain 20% by mass or more, 25% by mass or more, 30% by mass or more, 50% by mass or more, 70% by mass or more, 80% by mass or more of the above-mentioned chemical-based synthetic fibers, or The content may be 90% by mass or more, 100% by mass or less, 90% by mass or less, 80% by mass or less, 60% by mass or less, or 50% by mass or less.
〈破砕工程〉
 繊維製品を破砕する工程は、第1の実施形態において述べた生分解性製品を前処理する工程と同じであってよい。
<Crushing process>
The process of crushing the textile product may be the same as the process of pre-treating the biodegradable product described in the first embodiment.
 なお、繊維製品を破砕する工程は、繊維製品のみを破砕する工程であってもよいが、繊維製品だけではなく、下記の発酵性有機物と繊維製品との混合物を破砕する工程であってもよく、また繊維製品と発酵性有機物との混合物を発酵させた、発酵した混合物を破砕する工程であってもよい。すなわち、繊維製品を破砕する工程と、発酵性混合物を得る工程及び発酵した混合物を得る工程との順番は限定されない。一方で、発酵性混合物を得る工程等での取扱い性を踏まえれば、繊維製品を破砕する工程の後に、発酵性混合物を得る工程及び発酵した混合物を得る工程を行うことが好ましい。 Note that the process of crushing textile products may be a process of crushing only textile products, but it may also be a process of crushing not only textile products but also a mixture of fermentable organic matter and textile products as described below. Alternatively, it may be a step of fermenting a mixture of a textile product and a fermentable organic substance and crushing the fermented mixture. That is, the order of the step of crushing the textile product, the step of obtaining the fermentable mixture, and the step of obtaining the fermented mixture is not limited. On the other hand, considering the ease of handling in the step of obtaining the fermentable mixture, etc., it is preferable to perform the step of obtaining the fermentable mixture and the step of obtaining the fermented mixture after the step of crushing the textile product.
 破砕工程は、後に破砕した繊維製品をペレット化する場合、そのまま土壌に配置又は混合する場合の作業性等に応じて、適宜、最終的に得られる粒径を選択することができる。例えば、一次的な破砕工程によって、15mm~300mm程度又は20mm~50mm程度の大きさに破砕した後に、二次的な破砕工程によって2~20mm程度又は3~10mmの大きさにしてもよい。 In the crushing step, the final particle size can be selected as appropriate depending on the workability, etc., when the crushed fiber products are later pelletized or placed or mixed in the soil as they are. For example, after being crushed into a size of about 15 mm to 300 mm or 20 mm to 50 mm in a primary crushing process, it may be crushed to a size of about 2 to 20 mm or 3 to 10 mm in a secondary crushing process.
〈発酵性混合物を得る工程〉
 発酵性混合物を得る工程は、繊維製品と発酵性有機物とを混合する工程であり、その混合方法は特に限定されない。
<Process of obtaining fermentable mixture>
The process of obtaining a fermentable mixture is a process of mixing a textile product and a fermentable organic substance, and the mixing method is not particularly limited.
 発酵性有機物としては、微生物によって発酵させることができれば特に限定されず、食品由来原料の有機物、例えば、米ぬか、おから、糖蜜、もみがら、魚粉、稲わら、麦わら等であってもよく、又は発酵させて堆肥化可能な動物の糞尿、例えば牛糞、鶏糞等を挙げることができる。 Fermentable organic substances are not particularly limited as long as they can be fermented by microorganisms, and may be organic substances that are food-derived raw materials, such as rice bran, okara, molasses, rice husks, fish meal, rice straw, or wheat straw; Examples include animal manure that can be fermented and composted, such as cow manure and chicken manure.
 繊維製品と発酵性有機物とを混合する際の質量比は、用いる繊維製品の種類にもよるが、繊維製品と発酵性有機物との合計に対して発酵性有機物が、20質量%以上、30質量%以上、又は40質量%以上であってもよく、80質量%以下、70質量%以下、60質量%以下、50質量%以下、又は40質量%以下であってもよい。例えば、繊維製品と発酵性有機物との合計に対する発酵性有機物の質量は、20質量%以上80質量%以下であり、繊維製品が生分解性の高い繊維、例えば天然繊維の場合には、繊維製品と発酵性有機物との合計に対する質量は、20質量%以上50質量%以下又は30質量%以上40質量%以下とすることができ、繊維製品が生分解性の低い繊維、例えば合成繊維の場合には、繊維製品と発酵性有機物との合計に対する質量は、30質量%以上70質量%以下又は40質量%以上60質量%以下であってもよい。 The mass ratio when mixing textile products and fermentable organic matter depends on the type of textile product used, but the fermentable organic matter is at least 20% by mass and 30% by mass based on the total of textile products and fermentable organic matter. % or more, or 40% by mass or more, and may be 80% by mass or less, 70% by mass or less, 60% by mass or less, 50% by mass or less, or 40% by mass or less. For example, the mass of the fermentable organic matter relative to the total of the textile product and the fermentable organic matter is 20% by mass or more and 80% by mass or less, and when the textile product is a highly biodegradable fiber, such as a natural fiber, the textile product The mass of the total of the and the fermentable organic matter can be 20% by mass or more and 50% by mass or less or 30% by mass or more and 40% by mass or less, and when the textile product is a fiber with low biodegradability, for example, a synthetic fiber. The mass of the textile product and the fermentable organic matter relative to the total may be 30% by mass or more and 70% by mass or less, or 40% by mass or more and 60% by mass or less.
 発酵性混合物は、発酵に適した条件とするためにさらに水を含有させることができ、例えば混合物中の含水率は、10質量%以上、20質量%以上、30質量%以上、又は40質量%以上であってもよく、60質量%以下、50質量%以下、40質量%以下、又は30質量%以下であってもよい。例えば発酵性混合物の含水率は、10質量%以上60質量%以下又は20質量%以上40質量%以下であってもよい。 The fermentable mixture can further contain water to make conditions suitable for fermentation, for example, the water content in the mixture is 10% by mass or more, 20% by mass or more, 30% by mass or more, or 40% by mass. or more, and may be 60% by mass or less, 50% by mass or less, 40% by mass or less, or 30% by mass or less. For example, the water content of the fermentable mixture may be 10% by mass or more and 60% by mass or less, or 20% by mass or more and 40% by mass or less.
〈発酵した混合物を得る工程〉
 発酵した混合物を得る工程は、上記の発酵性混合物を発酵させる工程であり、発酵させることができればその条件は、特に限定されない。
<Process of obtaining fermented mixture>
The step of obtaining the fermented mixture is a step of fermenting the above-mentioned fermentable mixture, and the conditions are not particularly limited as long as the fermentation can be carried out.
 発酵工程は、25℃以上、30℃以上、35℃以上、又は40℃以上で、かつ60℃以下、55℃以下、50℃以下、又は45℃以下の温度で行うことができる。また、発酵工程は、相対湿度で、50%以上、55%以上、60%以上、又は65%以上で、かつ90%以下、85%以下、80%以下、75%以下、又は70%以下の湿度で行うことができる。発酵のための期間は、1週間以上、2週間以上、3週間以上、又は8週間以下、6週間以下、又は4週間以下で行うことができる。例えば、発酵工程は、35℃以上45℃以下の温度で、50%以上75%以下の相対湿度で、2週間以上6週間以下の期間で行うことができる。 The fermentation step can be carried out at a temperature of 25°C or higher, 30°C or higher, 35°C or higher, or 40°C or higher, and 60°C or lower, 55°C or lower, 50°C or lower, or 45°C or lower. In addition, the fermentation process is performed at a relative humidity of 50% or more, 55% or more, 60% or more, or 65% or more and 90% or less, 85% or less, 80% or less, 75% or less, or 70% or less. Can be done with humidity. The period for fermentation can be 1 week or more, 2 weeks or more, 3 weeks or more, or 8 weeks or less, 6 weeks or less, or 4 weeks or less. For example, the fermentation process can be carried out at a temperature of 35° C. or more and 45° C. or less, and a relative humidity of 50% or more and 75% or less, for a period of 2 weeks or more and 6 weeks or less.
 発酵工程は、換気を行いながら必要に応じて水を発酵性混合物に追加しながら行うことができる。 The fermentation process can be carried out with ventilation and water added to the fermentable mixture as needed.
 例えば、この工程は、発酵性混合物を堆肥化する工程であってもよく、動物の糞尿を含む発酵性混合物を数日~数週の間、放置することでこの工程を行うことができる。 For example, this step may be a step of composting the fermentable mixture, and this step can be performed by allowing the fermentable mixture containing animal excrement to stand for several days to several weeks.
〈ペレット化工程〉
 本発明の方法は、発酵した混合物をペレット化する工程を含むことができる。発酵した混合物をペレット化することによって、土壌に配置又は混合する工程を非常に効率的かつ機械的に大規模に行うことができる。また、ペレットは、均一な量で、かつ大量に、土壌に配置又は混合させることができるため、ペレット化工程を行うことは非常に有効である。ペレット化工程で用いることができるペレタイザーは、第1の実施形態において述べたものと同じものを使用することができる。
<Pelletization process>
The method of the invention can include pelletizing the fermented mixture. By pelletizing the fermented mixture, the process of placing or mixing into the soil can be carried out very efficiently and mechanically on a large scale. Further, the pelletizing process is very effective because pellets can be placed or mixed in the soil in a uniform amount and in large quantities. As the pelletizer that can be used in the pelletizing step, the same pelletizer as described in the first embodiment can be used.
 ペレット化する際には、発酵した混合物の含水率を30質量%以下、20質量%以下、又は15質量%以下で、1質量%以上、5質量%以上又は10質量%以上とすることができる。これによって、硬質なペレットを製造することができる。硬質なペレットは、土壌に配置又は混合する工程を機械的に大規模に行う際に有利である。 When pelletizing, the moisture content of the fermented mixture can be 30% by mass or less, 20% by mass or less, or 15% by mass or less, and 1% by mass or more, 5% by mass or more, or 10% by mass or more. . This allows production of hard pellets. Hard pellets are advantageous when the process of placing or mixing into the soil is performed mechanically on a large scale.
 また、ペレット化する前に、含水率を低くするために発酵した混合物を乾燥させることができる。その乾燥温度は、5℃以上、10℃以上、20℃以上、又は30℃以上で、かつ50℃以下、45℃以下、40℃以下、又は35℃以下の温度で行うことができる。例えば、ペレット化の際の温度は、10℃以上40℃以下で行うことができ、これにより、発酵した混合物に存在する微生物に悪影響を与えずにペレットを得ることができ、土壌改質材として有用となる。 Also, the fermented mixture can be dried to lower the moisture content before pelletizing. The drying temperature can be 5°C or higher, 10°C or higher, 20°C or higher, or 30°C or higher, and 50°C or lower, 45°C or lower, 40°C or lower, or 35°C or lower. For example, pelletization can be carried out at a temperature of 10°C or more and 40°C or less, which allows pellets to be obtained without adversely affecting the microorganisms present in the fermented mixture, and can be used as a soil improvement material. Become useful.
《農作物の生産方法》
 本発明の方法は、さらに、上記のような土壌改質材を配置又は混合した土壌で農作物を生産する方法に関する。上記のようにして改良された土壌は、水分保持性が高く、このような土壌では、農作物の生産が容易となる。
《Agricultural crop production method》
The method of the present invention further relates to a method of producing agricultural crops using soil in which the above-mentioned soil amendment material is arranged or mixed. The soil improved as described above has a high water retention property, and it is easy to produce agricultural products in such soil.
 農作物としては、米、小麦等の穀物、野菜、果物、花等を挙げることができるが、これらに限定されない。生分解性製品又は繊維製品を多く消費させる観点からは、農作物は、1年草であってもよい。 Agricultural crops include, but are not limited to, grains such as rice and wheat, vegetables, fruits, and flowers. From the viewpoint of consuming a large amount of biodegradable products or textile products, agricultural crops may be annual plants.
《土壌の活性化方法》
 本発明の土壌の活性化方法は、土壌改質材を、土壌に配置又は混合する工程を含む。本明細書において、土壌とは、農作物及び微生物を生育できる土をいい、このような土は、微生物によって上記のような生分解性製品又は繊維製品を分解することができる。
《Soil activation method》
The soil activation method of the present invention includes a step of disposing or mixing a soil reforming material in soil. As used herein, soil refers to soil that can grow agricultural products and microorganisms, and such soil can decompose biodegradable products or textile products such as those described above by microorganisms.
〈配置又は混合工程〉
 本発明の方法において、土壌改質材を土壌に配置又は混合する工程は、単に土壌の表面上に土壌改質材を配置するだけであってもよく、土壌に土壌改質材を埋めるだけであってもよいが、土壌と積極的に混合する工程であることが好ましい。混合は、人力で行ってもよく、機械的に行うこともできる。
<Arrangement or mixing process>
In the method of the present invention, the step of placing or mixing the soil amendment material in the soil may be simply placing the soil amendment material on the surface of the soil, or may be simply burying the soil amendment material in the soil. However, it is preferable to actively mix it with the soil. Mixing may be performed manually or mechanically.
 本発明の方法で用いられる土壌改質材は、ペレット化されていることによって、機械的に大量に土壌に散布できる。例えば、肥料散布機付きのトラクターによって、土壌改質材を大量に散布させることができる。 Since the soil reforming material used in the method of the present invention is pelletized, it can be mechanically sprayed onto the soil in large quantities. For example, a tractor with a fertilizer spreader can spread a large amount of soil amendment material.
《土壌改質材又は人工土壌》
 本発明は、上記のような方法で用いることができる土壌改質材又は人工土壌にも関する。本発明の土壌改質材又は人工土壌の構成は、上記の方法に関して述べた土壌改質材についての記載を参照することができる。
《Soil reforming material or artificial soil》
The present invention also relates to a soil amendment material or artificial soil that can be used in the method described above. For the structure of the soil reforming material or artificial soil of the present invention, reference can be made to the description of the soil reforming material described in relation to the above method.
 例えば、第1の実施形態において、本発明の土壌改質材又は人工土壌は、親水性の生分解性繊維を80質量%以上含み、ペレット状である。このペレット状の土壌改質材又は人工土壌は、上記のような農業用酵素も含むことができ、このような土壌改質材又は人工土壌は、綿、麻、和紙等の親水性の生分解性繊維から製造された衣服を酵素含有液に浸漬した後、裁断して粉砕し、ペレタイザーによってペレット化することによって得ることができる。 For example, in the first embodiment, the soil reforming material or artificial soil of the present invention contains 80% by mass or more of hydrophilic biodegradable fibers and is in the form of pellets. This pelleted soil amendment material or artificial soil may also contain agricultural enzymes such as those mentioned above, and such soil amendment material or artificial soil may contain hydrophilic biodegradable materials such as cotton, hemp, and Japanese paper. It can be obtained by immersing clothing made from synthetic fibers in an enzyme-containing solution, cutting it, crushing it, and pelletizing it with a pelletizer.
 例えば、第2の実施形態において、本発明の土壌改質材又は人工土壌は、繊維及び発酵性有機物の発酵物を含み、ペレット状である。ここで、発酵性有機物は、食品由来原料であることが好ましく、例えば米ぬか、おから、糖蜜、もみがら、魚粉、稲わら、麦わら及びこれらの組み合わせである。 For example, in the second embodiment, the soil reforming material or artificial soil of the present invention contains fibers and a fermented product of fermentable organic matter, and is in the form of pellets. Here, the fermentable organic substance is preferably a food-derived raw material, such as rice bran, okara, molasses, rice hulls, fish meal, rice straw, wheat straw, and combinations thereof.
 土壌改質剤又は人工土壌は、土壌に混合又は配置されて用いることができるが、土壌に混合せずに、鉢植え等の土の代わりにそのまま使用することができる。ベランダ菜園では、栽培後の土の処理に悩まされることがあるが、この土壌改質剤又は人工土壌は、燃えるゴミとして捨てることができるため、非常に処理が容易である。 A soil conditioner or artificial soil can be used by being mixed or placed in soil, but it can also be used as it is instead of soil for potted plants, etc., without being mixed with soil. In veranda vegetable gardens, it is sometimes a problem to dispose of the soil after cultivation, but this soil conditioner or artificial soil is very easy to dispose of because it can be disposed of as combustible garbage.
 本発明を以下の実施例でさらに具体的に説明をするが、本発明はこれによって限定されるものではない。 The present invention will be explained in more detail with reference to the following examples, but the present invention is not limited thereto.
〈第1の実施形態〉
 マニラ麻を原料とした和紙100質量%で構成された衣服を、農業用酵素(万田アミノアルファ、万田発酵株式会社)を含む酵素含有液に数時間浸漬した。
<First embodiment>
Clothes made of 100% by mass Japanese paper made from Manila hemp were immersed for several hours in an enzyme-containing solution containing agricultural enzymes (Manda Amino Alpha, Manda Hakko Co., Ltd.).
 酵素含有液から取り出した衣服を脱水して、破砕機によって100mm~10mm程度に粗粉砕をして、さらに粉砕機(DASEシリーズ、西邦エンジニアリング株式会社)によって微粉砕した。これにより、10mm以下に破砕された生分解性繊維を得た。 The clothes taken out of the enzyme-containing solution were dehydrated, coarsely ground to about 100 mm to 10 mm using a crusher, and further finely crushed using a crusher (DASE series, Seiho Engineering Co., Ltd.). As a result, biodegradable fibers crushed into pieces of 10 mm or less were obtained.
 その生分解性繊維を、ペレタイザーによってペレット化して、和紙と酵素を含む、ペレット状の土壌改質材を得た。その写真を図1に示す。 The biodegradable fibers were pelletized using a pelletizer to obtain a pelleted soil reforming material containing Japanese paper and enzymes. The photograph is shown in Figure 1.
 このようにして得られた土壌改質材を、肥料散布機付きのトラクターで1トン/反(約1000m)程度の量で土壌に散布して、ナス、大根、白菜等の野菜を製造したところ、いずれも非常に美味しい野菜が収穫できた。また、上記の土壌改質材は、1.5ヶ月~2ヶ月で消失した。なお、綿100%で構成された衣服によって同様にして製造した土壌改質材は、2~4ヶ月で消失した。 The soil reforming material thus obtained was spread on the soil in an amount of about 1 ton/tan (approximately 1000 m 2 ) using a tractor equipped with a fertilizer spreader to produce vegetables such as eggplants, radishes, and Chinese cabbage. However, we were able to harvest some very delicious vegetables. In addition, the above-mentioned soil reforming material disappeared in 1.5 to 2 months. Note that the soil improvement material produced in the same manner using clothing made of 100% cotton disappeared within 2 to 4 months.
 また、上記のペレット状の土壌改質材を畜舎に1ヶ月間敷料として用いて、これを回収して、土壌に混合した。 In addition, the above pelletized soil reforming material was used as bedding material in livestock barns for one month, and then collected and mixed with soil.
〈第2の実施形態〉
《製造》
 表1に記載の繊維を含む衣服を、破砕機によって100mm~30mm程度に粗粉砕をして、さらに粉砕機(DASEシリーズ、西邦エンジニアリング株式会社)によって微粉砕した。これにより、6~9mm程度に粉砕された繊維を得た。図2は、粗粉砕を行った状態の繊維を示しており、図3は、微粉砕を行った状態の繊維を示す。
<Second embodiment>
《Manufacturing》
Clothes containing the fibers listed in Table 1 were coarsely crushed to about 100 mm to 30 mm using a crusher, and then finely crushed using a crusher (DASE series, Seiho Engineering Co., Ltd.). As a result, fibers pulverized to about 6 to 9 mm were obtained. FIG. 2 shows the fibers after being coarsely pulverized, and FIG. 3 shows the fibers after being finely pulverized.
 その破砕された繊維を、米ぬかと混ぜ合わせた。ここで、天然繊維の場合には、繊維と米ぬかとを2:1で混ぜ合わせ、化学繊維の場合には、1:1で混ぜ合わせた。その後、水を加えて、含水率を20~35質量%とした。 The crushed fibers were mixed with rice bran. Here, in the case of natural fibers, the fibers and rice bran were mixed at a ratio of 2:1, and in the case of synthetic fibers, they were mixed at a ratio of 1:1. Thereafter, water was added to adjust the water content to 20 to 35% by mass.
 その後、空調の効いた施設内で、温度42℃かつ相対湿度65%の条件で、5日に一回水を加えながら、その混合物を3~4週間程度発酵させた。図4は、発酵性混合物を得た直後の状態と、3週間発酵させた後の発酵した混合物とを示している。 Thereafter, the mixture was fermented for about 3 to 4 weeks in an air-conditioned facility at a temperature of 42°C and relative humidity of 65%, while adding water once every 5 days. FIG. 4 shows the state of the fermentable mixture immediately after it was obtained and the fermented mixture after 3 weeks of fermentation.
 その後、発酵した混合物の含水率が20質量%以下になるまで乾燥させて、ペレタイザーによってペレット化して、土壌改質材を得た。乾燥させる際には、温度を40℃以下に保つことによって、土壌活性化剤中の微生物に悪影響を及ぼさないようにした。図5(a)は、発酵した混合物をペレタイザーに投入している状態を示しており、図5(b)は、それにより得られたペレットを示している。 Thereafter, the fermented mixture was dried until the moisture content became 20% by mass or less, and pelletized using a pelletizer to obtain a soil reforming material. During drying, the temperature was maintained at 40° C. or lower to avoid adverse effects on the microorganisms in the soil activator. FIG. 5(a) shows the fermented mixture being put into a pelletizer, and FIG. 5(b) shows the pellets obtained thereby.
《評価》
 得られたペレットを、京都府南丹市美山町原古ミノ越15の畑で、2022年6月に散布を行い、1ヶ月後に土壌の評価を行った。
"evaluation"
The obtained pellets were sprayed in a field at 15 Harako Minokoshi, Miyama-cho, Nantan City, Kyoto Prefecture in June 2022, and the soil was evaluated one month later.
 土壌の評価は、株式会社DGCテクノロジーに委託をして行った。ここで、各サンプルについて、3箇所以上で土壌を採取してその平均値を評価した。 The soil evaluation was outsourced to DGC Technology Co., Ltd. Here, for each sample, soil was collected at three or more locations and the average value was evaluated.
 具体的には、特許第5807956号公報に記載の方法によって、土壌の作物育成度を評価した。これは、95種類の異なった有機物が入った試験用プレートに、サンプル土壌を薄めたものを入れて、専用のロボットを用いて一定温度で15分間隔で48時間連続的に測定し、サンプルに生息する微生物によって各有機物が分解される速度を調べる。微生物によって分解できる有機物の種類は異なっているため、たくさんの種類の有機物が分解できたということは、たくさんの種類の微生物がいるということになり、また有機物の分解速度が速いということは、それだけ微生物が活発に働いているということになる。こうして、微生物の多様性と活性との両方を合わせて計測した結果を定量化して、土壌微生物多様性・活性値(BIOTREX(商標))として評価する。 Specifically, the degree of crop growth in the soil was evaluated by the method described in Japanese Patent No. 5807956. This involves placing a diluted sample of soil in a test plate containing 95 different types of organic matter, and using a special robot to continuously measure the soil at a constant temperature at 15-minute intervals for 48 hours. Examine the rate at which each organic substance is decomposed by the living microorganisms. The types of organic matter that can be decomposed by microorganisms differ, so the fact that many kinds of organic matter can be decomposed means that there are many kinds of microorganisms, and the fact that the rate of decomposition of organic matter is fast means that This means that microorganisms are actively working. In this way, the results of measuring both microbial diversity and activity are quantified and evaluated as a soil microbial diversity/activity value (BIOTREX (trademark)).
《結果》
 以下にその結果を示す。
"result"
The results are shown below.
Figure JPOXMLDOC01-appb-I000001
Figure JPOXMLDOC01-appb-I000001
 なお、土壌微生物多様性・活性値は、50万~70万が平均的な土壌、70万~100万が土作りが比較的うまくいっている土壌、100万~130万が豊かな土壌で、病気が発生しにくく美味しい農作物が得られる土壌、130万~150万が大変豊かな土壌、150万~200万が極めて豊かな土壌であるとされている。 In addition, soil microbial diversity and activity values are 500,000 to 700,000 for average soil, 700,000 to 1,000,000 for soil that is relatively well prepared, and 1,000,000 to 1,300,000 for soil that is rich and disease-free. Soil is said to be difficult to grow and yield delicious agricultural products, 1.3 million to 1.5 million is considered to be very rich soil, and 1.5 million to 2 million is extremely rich soil.
 上記結果を見れば明らかなように、すべての実施例で、土壌改良化材としての効果が得られることがわかった。また、すべての実施例で、2~3ヶ月後には、完全に土壌に分解されて消費されることが分かった。
 
As is clear from the above results, it was found that the effect as a soil improvement agent was obtained in all Examples. Furthermore, in all Examples, it was found that the product was completely decomposed into the soil and consumed after 2 to 3 months.

Claims (13)

  1.  繊維製品と発酵性有機物との混合物を発酵させて発酵した混合物を得る工程を含む、土壌改質材の製造方法。 A method for producing a soil improvement material, which includes a step of fermenting a mixture of textile products and fermentable organic matter to obtain a fermented mixture.
  2.  前記繊維製品が破砕されている、請求項1に記載の方法。 The method according to claim 1, wherein the textile product is crushed.
  3.  前記発酵した混合物を得る工程の後に、前記発酵した混合物をペレット化する工程を含む、請求項1に記載の方法。 2. The method of claim 1, further comprising the step of pelletizing the fermented mixture after the step of obtaining the fermented mixture.
  4.  前記繊維製品が、衣服に由来している、請求項1に記載の方法。 The method according to claim 1, wherein the textile product is derived from clothing.
  5.  前記繊維製品が、化学繊維を含む、請求項1に記載の方法。 The method according to claim 1, wherein the textile product includes synthetic fibers.
  6.  前記発酵性有機物が、食品由来原料である、請求項1に記載の方法。 The method according to claim 1, wherein the fermentable organic substance is a food-derived raw material.
  7.  前記食品由来原料が、米ぬか、おから、糖蜜、もみがら、魚粉、稲わら、麦わら及びこれらの組み合わせである、請求項6に記載の方法。 The method according to claim 6, wherein the food-derived raw material is rice bran, okara, molasses, rice hulls, fishmeal, rice straw, wheat straw, or a combination thereof.
  8.  破砕した生分解性製品をペレット化する工程を含み、前記生分解性製品が、親水性の生分解性工業製品である、土壌改質材の製造方法。 A method for producing a soil reforming material, which includes a step of pelletizing a crushed biodegradable product, and the biodegradable product is a hydrophilic biodegradable industrial product.
  9.  前記生分解性製品が、生分解性繊維を30質量%以上で含む、請求項8に記載の方法。 The method according to claim 8, wherein the biodegradable product contains 30% by mass or more of biodegradable fibers.
  10.  前記生分解性製品を酵素と混合する工程をさらに含む、請求項8に記載の方法。 9. The method of claim 8, further comprising mixing the biodegradable product with an enzyme.
  11.  前記生分解性製品を糞尿と混合して前記糞尿を堆肥化する工程をさらに含む、請求項8に記載の方法。 9. The method of claim 8, further comprising the step of mixing the biodegradable product with manure and composting the manure.
  12.  請求項1~11のいずれか一項に記載の方法によって製造された土壌改質材を土壌に配置又は混合する工程、及び前記土壌で農作物を生産する工程を含む、農作物の生産方法。 A method for producing agricultural products, comprising a step of disposing or mixing a soil reforming material produced by the method according to any one of claims 1 to 11 in soil, and a step of producing agricultural products with the soil.
  13.  請求項1~11のいずれか一項に記載の方法によって製造された土壌改質材を、土壌に配置又は混合する工程を含む、土壌の活性化方法。
     
    A method for activating soil, comprising the step of disposing or mixing in soil a soil reforming material produced by the method according to any one of claims 1 to 11.
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