WO2023176847A1 - 電子機器、ベッドセンサー、及び棚用センサー - Google Patents

電子機器、ベッドセンサー、及び棚用センサー Download PDF

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WO2023176847A1
WO2023176847A1 PCT/JP2023/009915 JP2023009915W WO2023176847A1 WO 2023176847 A1 WO2023176847 A1 WO 2023176847A1 JP 2023009915 W JP2023009915 W JP 2023009915W WO 2023176847 A1 WO2023176847 A1 WO 2023176847A1
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sensor
detection circuit
piezo element
circuit
element type
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French (fr)
Japanese (ja)
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至 渡邉
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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Priority to JP2024508193A priority Critical patent/JPWO2023176847A1/ja
Priority to CN202380027042.1A priority patent/CN118871758A/zh
Priority to EP23770801.1A priority patent/EP4495564A4/en
Priority to KR1020247030074A priority patent/KR20240160111A/ko
Publication of WO2023176847A1 publication Critical patent/WO2023176847A1/ja
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    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00—Measuring force or stress, in general
    • G01L1/16—Measuring force or stress, in general using properties of piezoelectric devices
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/02—Detecting, measuring or recording for evaluating the cardiovascular system, e.g. pulse, heart rate, blood pressure or blood flow
    • A61B5/024—Measuring pulse rate or heart rate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/103—Measuring devices for testing the shape, pattern, colour, size or movement of the body or parts thereof, for diagnostic purposes
    • A61B5/1036—Measuring load distribution, e.g. podologic studies
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/68—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient
    • A61B5/6887—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient mounted on external non-worn devices, e.g. non-medical devices
    • A61B5/6891—Furniture
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01L—MEASURING FORCE, STRESS, TORQUE, WORK, MECHANICAL POWER, MECHANICAL EFFICIENCY, OR FLUID PRESSURE
    • G01L1/00—Measuring force or stress, in general
    • G01L1/18—Measuring force or stress, in general using properties of piezo-resistive materials, i.e. materials of which the ohmic resistance varies according to changes in magnitude or direction of force applied to the material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B2562/00—Details of sensors; Constructional details of sensor housings or probes; Accessories for sensors
    • A61B2562/02—Details of sensors specially adapted for in-vivo measurements
    • A61B2562/0247—Pressure sensors
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B2562/00—Details of sensors; Constructional details of sensor housings or probes; Accessories for sensors
    • A61B2562/02—Details of sensors specially adapted for in-vivo measurements
    • A61B2562/0252—Load cells
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B2562/00—Details of sensors; Constructional details of sensor housings or probes; Accessories for sensors
    • A61B2562/12—Manufacturing methods specially adapted for producing sensors for in-vivo measurements
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/02—Detecting, measuring or recording for evaluating the cardiovascular system, e.g. pulse, heart rate, blood pressure or blood flow
    • A61B5/024—Measuring pulse rate or heart rate
    • A61B5/02444—Details of sensor
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/103—Measuring devices for testing the shape, pattern, colour, size or movement of the body or parts thereof, for diagnostic purposes
    • A61B5/11—Measuring movement of the entire body or parts thereof, e.g. head or hand tremor or mobility of a limb
    • A61B5/113—Measuring movement of the entire body or parts thereof, e.g. head or hand tremor or mobility of a limb occurring during breathing
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B5/00—Measuring for diagnostic purposes; Identification of persons
    • A61B5/68—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient
    • A61B5/6887—Arrangements of detecting, measuring or recording means, e.g. sensors, in relation to patient mounted on external non-worn devices, e.g. non-medical devices
    • A61B5/6892—Mats

Definitions

  • the present invention relates to electronic equipment, bed sensors, and shelf sensors. This application claims priority based on Japanese Patent Application No. 2022-044701 filed in Japan on March 18, 2022, the contents of which are incorporated herein.
  • Patent Documents 1 to 3 propose techniques for detecting respiration, pulse, body movement, etc. using piezoelectric films such as PVDF films and porous polypropylene electret films.
  • a sensor using a piezoelectric film such as a PVDF film or a porous polypropylene electret film is also called a piezo element type sensor, and detects a voltage generated by pressure applied to the sensor.
  • Piezo element sensors generally output pulse-like signals at the timing when pressure changes occur, so they can obtain information about stimuli that change the pressure or load (hereinafter also referred to as "dynamic information"); It has been thought that it is difficult to obtain information regarding stimuli that continue to be subjected to pressure or load (hereinafter also referred to as "static information").
  • Patent Document 4 proposes a technique for measuring body posture using a static acceleration sensor, and exemplifies a piezoresistive sensor as the static acceleration sensor.
  • Piezoresistive sensors detect changes in resistance inside the sensor due to pressure, and can acquire static information to quantify pressure and load, but they can also acquire dynamic information and quantify pressure and load. It was difficult to accurately respond to changes in pressure or load.
  • Patent Document 5 proposes a technique for detecting changes in the load applied to the bed using a load cell.
  • sensors for the healthcare field may require both dynamic information and static information.
  • sensors for the healthcare field are required to acquire both dynamic information such as breathing, pulse, and body movements, as well as static information such as sleeping posture and sleeping position.
  • an object of the present invention is to provide an electronic device that can also acquire static information with a single piezo element sensor that is cheaper than a load cell, and a bed sensor and a shelf sensor equipped with the electronic device.
  • the present inventors discovered that static information can be obtained using a piezo element sensor by devising a detection circuit that detects the output voltage of the piezo element sensor. That is, the gist of the present invention is as follows.
  • a first aspect of the present invention includes a piezo element type sensor that outputs a voltage according to applied pressure, and a continuous pressure applied to the piezo element type sensor from the output voltage of the piezo element type sensor.
  • an electronic device the first detection circuit having a capacitor connected in parallel to the piezo element type sensor, and a high input impedance circuit connected in series to the piezo element type sensor. It is.
  • a second aspect of the present invention is that in the first aspect, the input impedance of the high input impedance circuit is 0.1 T ⁇ or more and 10 T ⁇ or less.
  • the voltage is applied to the piezo element type sensor by being connected in series with the first detection circuit and differentiating the detection result of the first detection circuit. It further includes a differential circuit that detects changes in pressure.
  • a fourth aspect of the present invention in the first or second aspect, further includes a second detection circuit that detects a change in pressure applied to the piezo element type sensor from the output voltage of the piezo element type sensor.
  • the input impedance of the high input impedance circuit included in the first detection circuit is higher than the input impedance of the second detection circuit.
  • the input impedance of the high input impedance circuit included in the first detection circuit is 10 4 times or more and 10 8 times or less of the input impedance of the second detection circuit.
  • the input impedance of the second detection circuit is 0.1 M ⁇ or more and 10 M ⁇ or less.
  • any one of the fourth to seventh aspects it is determined whether the first detection circuit or the second detection circuit is connected to the piezo element type sensor. It has a switching circuit for switching.
  • the capacitance of the capacitor is 100 pF or more and 5000 pF or less.
  • the piezo element type sensor includes an electret film.
  • An eleventh aspect of the present invention is that in the tenth aspect, the electret film contains a polyolefin resin.
  • a twelfth aspect of the present invention is a bed sensor comprising the electronic device according to any one of the first to eleventh aspects.
  • a thirteenth aspect of the present invention is a shelf sensor comprising the electronic device according to any one of the first to eleventh aspects.
  • static information can also be acquired with a single piezo element sensor that is cheaper than a load cell, making it possible to reduce the cost and space of the sensor.
  • FIG. 1 is a block diagram showing a main part configuration of an electronic device according to a first embodiment of the present invention.
  • FIG. 1 is an exploded perspective view showing the basic configuration of a sensor used in a first embodiment of the present invention.
  • FIG. 2 is a block diagram showing the configuration of main parts of an electronic device according to a second embodiment of the present invention.
  • FIG. 3 is a block diagram showing the configuration of main parts of an electronic device according to a third embodiment of the present invention.
  • FIG. 3 is a block diagram showing the configuration of main parts of an electronic device according to a fourth embodiment of the present invention.
  • 7 is a diagram showing the waveform of the output voltage obtained by the second detection circuit when the sensor of Example 1 is used.
  • FIG. 7 is a diagram showing the waveform of the output voltage acquired by the first detection circuit when the sensor of Example 1 is used.
  • FIG. 3 is a diagram showing the relationship between the magnitude of the load applied to the sensor of Example 1 and the magnitude of the output voltage of the first detection circuit.
  • FIG. 7 is a diagram showing the waveform of the output voltage acquired by the first detection circuit when the sensor of Example 2 is used.
  • FIG. 1 is a block diagram showing the main configuration of an electronic device according to a first embodiment of the present invention.
  • the electronic device 1 of this embodiment includes a sensor 10 and a first detection circuit 20, and detects static information applied to the sensor 10.
  • the static information is information regarding stimulation to which a constant pressure or load continues to be applied.
  • This static information can also be referred to as a continuous pressure applied to the sensor 10.
  • continuous pressure can also be said to be pressure or load that does not change over time, or pressure or load that changes minutely over time. In other words, it can be said that the rate of change with respect to time is zero, or a pressure or load that can be considered zero.
  • the sensor 10 is a sensor that outputs a voltage according to the applied pressure.
  • This sensor 10 is a piezo element type sensor, and outputs a pulse-like signal at the timing when a pressure change occurs.
  • the sensor 10 includes two output ends T11 and T12.
  • the output terminal T11 is connected to the first detection circuit 20, and the output terminal T12 is grounded.
  • the sensor 10 outputs the above pulsed signal from the output end T11 when pressure is applied. Note that the details of the sensor 10 will be described later.
  • the first detection circuit 20 includes a capacitor 21 and a high input impedance circuit 22, and detects static information applied to the sensor 10 from the output voltage of the sensor 10.
  • the first detection circuit 20 may be an analog circuit or a digital circuit.
  • Capacitor 21 is connected in parallel to sensor 10 . Specifically, one electrode of the capacitor 21 is connected to the output terminal T11 of the sensor 10, and the other electrode is grounded.
  • the capacitor 21 is provided to control the waveform of a pulse-like signal output from the output terminal T11 of the sensor 10 by charging and discharging the charge generated in the sensor 10.
  • the capacitance of the capacitor 21 is, for example, 100 pF or more and 5000 pF or less, preferably 200 pF or more and 3000 pF or less, and more preferably 500 pF or more and 2000 pF or less.
  • the high input impedance circuit 22 is a circuit that includes an operational amplifier 22a and is connected in series to the sensor 10.
  • This high input impedance circuit 22 is a circuit (so-called voltage follower circuit (buffer circuit)) in which the inverting input terminal and the output terminal of the operational amplifier 22a are connected, and the non-inverting input terminal of the operational amplifier 22a is connected to the output terminal T11 of the sensor 10. It is connected to the.
  • the high input impedance circuit 22 is provided to prevent the charge generated in the sensor 10 from flowing out.
  • the input impedance of the high input impedance circuit 22 is, for example, 0.1 T ⁇ or more and 10 T ⁇ or less, preferably 0.2 T ⁇ or more and 8 T ⁇ or less, and more preferably 0.5 T ⁇ or more and 5 T ⁇ or less.
  • the output end of the high input impedance circuit 22 (the output end of the operational amplifier 22a) is connected to the output end T20 of the first detection circuit 20.
  • a signal indicating static information applied to the sensor 10 is output from the output terminal T20 of the first detection circuit 20.
  • a circuit such as an amplifier circuit that amplifies the signal output from the high input impedance circuit 22 may be provided between the high input impedance circuit 22 and the output terminal T20 of the first detection circuit 20. .
  • the sensor 10 is a piezo element type sensor.
  • This piezo element type sensor is not particularly limited as long as it is a sensor that can detect a voltage generated by pressure applied to the sensor, and examples thereof include a sensor containing a ceramic-based or organic polymer-based piezoelectric material.
  • ceramic-based piezoelectric materials include lead zirconate titanate (PZT), barium strontium titanate (BST), and the like.
  • Organic polymer-based piezoelectric materials include PVDF (polyvinylidene fluoride), vinylidene fluoride and ethylene trifluoride copolymer (P(VDF-TrFE)), vinylidene fluoride and ethylene tetrafluoride copolymer (P( Examples include electret films made of charged films made of permanent dipole materials such as VDF-TFE), polylactic acid (PLA), and polyolefin resins. Among these, from the viewpoint of piezoelectric properties and sensor flexibility, organic polymer-based piezoelectric materials are preferred, and electret films are more preferred.
  • the type of electret film is not particularly limited as long as it has piezoelectric properties, but a porous electret film is preferred from the viewpoint of further enhancing piezoelectric properties. Moreover, it is more preferable to use the electret film by charging the porous film.
  • the method for making the film porous is not particularly limited, and examples thereof include chemical or physical foaming and stretching. Among these, forming pores by stretching is preferred because a dense porous structure can be obtained and the shape of the pores can be easily controlled.
  • Materials for electret film include polyolefin resins, fluororesins, vinyl chloride resins, polystyrene resins, butadiene resins, polyester resins, and acrylic resins, which are said to have a low environmental impact and are easy to charge.
  • polyolefin resins are preferably used.
  • the electret film in this embodiment preferably contains a polyolefin resin as a main component, and particularly preferably contains a polypropylene resin as a main component.
  • the term "main component" means that the content in the electret film is 50% by mass or more, preferably 70% by mass or more, more preferably 80% by mass or more, even more preferably 90% by mass or more. .
  • the upper limit of the content is not particularly limited, and may be 100% by mass or less.
  • polypropylene resins examples include homopolypropylene (propylene homopolymer), or ⁇ -based resins such as propylene and ethylene, 1-butene, 1-pentene, 1-hexene, 1-heptene, 1-octene, 1-nonene, or 1-decene. -Random copolymers or block copolymers with olefins, etc. Among these, homopolypropylene is more preferably used from the viewpoint of mechanical strength.
  • the isotactic pentad fraction exhibiting stereoregularity of the polypropylene resin is preferably 80% or more, more preferably 83% or more, still more preferably 85% or more, and more preferably 99% or less. is 98% or less, more preferably 97% or less. If the isotactic pentad fraction is 80% or more, mechanical strength is good.
  • the upper limit of the isotactic pentad fraction is specified by the upper limit that can be obtained industrially at present, but this may not apply if a resin with even higher regularity is developed at an industrial level in the future. isn't it.
  • Isotactic pentad fraction is a three-dimensional structure in which five methyl groups, which are side chains, are located in the same direction with respect to the main chain formed by carbon-carbon bonds composed of five consecutive propylene units. Or it means the percentage. Attribution of signals in the methyl group region is as follows: A. Zambelli et al. (Macromol. 8, 687 (1975)).
  • the polypropylene resin has Mw/Mn, which is a parameter indicating molecular weight distribution, preferably 1.5 or more, more preferably 2.0 or more, and preferably 10.0 or less, more preferably 8.0 or less, More preferably, it is 6.0 or less.
  • Mw/Mn is a parameter indicating molecular weight distribution, preferably 1.5 or more, more preferably 2.0 or more, and preferably 10.0 or less, more preferably 8.0 or less, More preferably, it is 6.0 or less.
  • Mw/Mn means a narrower molecular weight distribution, but by setting Mw/Mn to 1.5 or more, sufficient extrusion moldability can be obtained and industrial mass production is possible. On the other hand, by setting Mw/Mn to 10.0 or less, sufficient mechanical strength can be ensured.
  • Mw/Mn is measured as a polystyrene equivalent value by GPC (gel per emission chromatography) method.
  • the melt flow rate (MFR) of the polypropylene resin is not particularly limited, but is preferably 0.5 g/10 minutes or more, more preferably 1.0 g/10 minutes or more, and preferably 15 g/10 minutes. minutes or less, more preferably 10 g/10 minutes or less.
  • MFR melt flow rate
  • the method for producing the polypropylene resin is not particularly limited, and may be any known polymerization method using a known polymerization catalyst, such as a multisite catalyst such as a Ziegler-Natta catalyst or a single site catalyst such as a metallocene catalyst. Examples include polymerization methods using catalysts.
  • polypropylene resins examples include the product names “Novatec PP”, “WINTEC”, “WAYMAX” (manufactured by Nippon Polypropylene Co., Ltd.), “Versify”, “Notio”, “Tafmer XR” (Mitsui Chemicals) (manufactured by Sumitomo Chemical), “Xelas”, “Thermolan” (manufactured by Mitsubishi Chemical), “Sumitomo Noblen”, “Toughselen” (manufactured by Sumitomo Chemical), “Prime Polypro”, “Prime TPO” (manufactured by Prime Polymer), “Adflex”, “ Commercially available products include “Adsyl”, “HMS-PP (PF814)” (manufactured by Sun Allomer), and “Inspire” (Dow Chemical).
  • the electret film in this embodiment contains a polypropylene resin as a main component
  • the electret film may be made of a resin composition containing a polypropylene resin as a main component containing a large amount of ⁇ crystals, which is one of the crystal forms.
  • a non-porous film made of a resin composition whose main component is a polypropylene resin containing a large amount of ⁇ -crystals exhibits excellent piezoelectricity after charging treatment, but it can also be stretched to create a porous structure, resulting in even better piezoelectricity. You can get sex.
  • a film made porous using ⁇ -crystals has a dense porous structure and a large surface area of pores, making it easier for more charges to be trapped during the charging process.
  • a porous electret film exhibits piezoelectricity due to the charges trapped at the interface between the pores and the matrix, so if the porous structure of the film is dense, the piezoelectric properties tend to be good. Furthermore, when the porous structure is dense, the distance between the pores becomes very short, and the trapped charges are likely to be fixed by mutual Coulomb force. This makes it difficult for the trapped charges to be discharged, and the characteristics as an electret film also become difficult to deteriorate.
  • the ⁇ -crystal activity of the electret film in this embodiment can be regarded as an indicator indicating that the polypropylene resin has generated ⁇ -crystals in the non-porous membrane material before stretching. If the polypropylene resin in the non-porous membrane material before stretching produces ⁇ crystals, many fine and uniform pores will be formed by subsequent stretching, resulting in excellent mechanical properties and fine and uniform pores. Excellent voltage resistance can be obtained by forming pores.
  • the presence or absence of ⁇ -crystal activity in the electret film in this embodiment is determined by performing differential thermal analysis of the electret film using a differential scanning calorimeter (DSC), and detecting the crystal melting peak temperature derived from the ⁇ -crystals of the polypropylene resin. It will be judged whether or not it will be done. Specifically, the laminated porous film was heated from 40°C to 200°C using a differential scanning calorimeter at a heating rate of 10°C/min, then held for 1 minute, and then cooled from 200°C to 40°C at a cooling rate of 10°C/min.
  • DSC differential scanning calorimeter
  • the crystal melting peak temperature (Tm ⁇ ) is detected, it is determined that the substance has ⁇ -crystal activity.
  • the presence or absence of the ⁇ -crystal activity can also be determined from the diffraction profile obtained by X-ray diffraction measurement of an electret film subjected to a specific heat treatment.
  • Methods for obtaining the ⁇ -crystal activity of the polypropylene resin described above include methods that do not add substances that promote the formation of ⁇ -crystals in the polypropylene resin, and methods that generate peroxide radicals as described in Japanese Patent No. 3739481.
  • Examples include a method of adding a polypropylene resin that has been treated with a polypropylene resin, and a method of adding a ⁇ -crystal nucleating agent. preferable.
  • a ⁇ -crystal nucleating agent By adding a ⁇ -crystal nucleating agent, the formation of ⁇ -crystals in the polypropylene resin can be promoted more uniformly and efficiently, and an electret film having ⁇ -crystal activity can be obtained.
  • the degree of the ⁇ -crystal activity can be quantified by measuring the ability to generate ⁇ -crystals.
  • the ⁇ -crystal forming ability of the polypropylene resin contained in the electret film is preferably 80% or more, more preferably 85% or more, and still more preferably 90% or more.
  • suitable piezoelectricity can be exhibited.
  • the upper limit There is no particular restriction on the upper limit, but it is usually 100% or less. Note that the ⁇ -crystal production ability is calculated by the method described below.
  • the electret film in this embodiment contains a polypropylene resin as a main component
  • the electret film contains a ⁇ -crystal nucleating agent in order to obtain excellent piezoelectricity. It is preferable that the By containing a ⁇ -crystal nucleating agent in the electret film, ⁇ -crystal activity can be obtained.
  • the ⁇ -crystal nucleating agent used in this embodiment include the ⁇ -crystal nucleating agents shown below.
  • the ⁇ -crystal nucleating agent may be used alone or in combination of two or more in any combination and ratio.
  • ⁇ -crystal nucleating agents examples include amide compounds; tetraoxaspiro compounds; quinacridones; iron oxides having nanoscale sizes; potassium 1,2-hydroxystearate, magnesium benzoate, magnesium succinate, magnesium phthalate, etc.
  • amide compounds are preferred. Piezoelectric properties can be enhanced by using amide compounds in electret films.
  • the amide compound include N,N'-dicyclohexyl-2,6-naphthalenedicarboxyamide, N,N'-dicyclohexyl terephthalamide, N,N'-diphenylhexanediamide, etc. Among them, N,N'-dicyclohexyl -2,6-naphthalene dicarboxamide is preferred. Since amide compounds have highly polar amide groups, charges can be localized in the crystal structure and are thought to have high piezoelectric properties.
  • a specific example of a commercially available ⁇ -crystal nucleating agent is "N Jester NU-100", a ⁇ -crystal nucleating agent manufactured by Shin Nihon Rika Co., Ltd., and a specific example of a propylene-based resin to which a ⁇ -crystal nucleating agent is added is manufactured by Aristech Co., Ltd. polypropylene "Bepol B-022SP” manufactured by Borealis, "Beta ( ⁇ )-PP BE60-7032” manufactured by Borealis, and polypropylene "BNX BETAPP-LN” manufactured by Mayzo.
  • the content of the ⁇ -crystal nucleating agent in the electret film in the present embodiment can be adjusted as appropriate depending on the type of ⁇ -crystal nucleating agent or the composition of the polypropylene resin, but preferably based on 100 parts by mass of the polypropylene resin. 0.0001 parts by mass or more, more preferably 0.001 parts by mass or more, even more preferably 0.01 parts by mass or more, and preferably 5.0 parts by mass or less, more preferably 3.0 parts by mass or less, even more preferably is 1.0 part by mass or less.
  • the content of the ⁇ -crystal nucleating agent is 0.0001 parts by mass or more based on 100 parts by mass of the polypropylene resin, the ⁇ -crystals of the polypropylene resin will be sufficiently generated and grown during manufacturing, and sufficient ⁇ -crystal activity will be ensured. Therefore, sufficient ⁇ -crystal activity can be ensured even when it is made into a porous film. Therefore, by charging the porous film, a porous electret film having desired piezoelectricity can be obtained.
  • the content of the ⁇ -crystal nucleating agent is 5.0 parts by mass or less per 100 parts by mass of the polypropylene resin, it will not only be economically advantageous but also prevent the ⁇ -crystal nucleating agent from bleeding onto the film surface. Very preferable.
  • the electret film of the present invention is a porous film, it may contain a blowing agent, filler, etc. instead of or in addition to the ⁇ -crystal nucleating agent. You can stay there.
  • a film made porous by chemical or physical foaming as the electret film of the present invention, chemical foaming agents, physical foaming agents, supercritical fluids, thermal expansion It is preferable to add sterile microcapsules and the like. These may be used alone or in combination of two or more.
  • a resin or an inorganic filler that is incompatible with the resin serving as the main component.
  • the inorganic filler include calcium carbonate, calcium sulfate, barium carbonate, barium sulfate, titanium oxide, talc, clay, kaolinite, montmorillonite, and the like.
  • the electret film in this embodiment contains additives such as heat stabilizers, antioxidants, ultraviolet absorbers, light stabilizers, crystal nucleating agents, colorants, antistatic agents, and hydrolyzable agents to the extent that their properties are not impaired.
  • additives such as heat stabilizers, antioxidants, ultraviolet absorbers, light stabilizers, crystal nucleating agents, colorants, antistatic agents, and hydrolyzable agents to the extent that their properties are not impaired.
  • additives such as inhibitors, lubricants, flame retardants, conductive agents, and elastomers may be included as appropriate.
  • the porosity of the electret film in this embodiment is usually 0% or more, preferably 5% or more, more preferably 10% or more, and preferably 70% or less, more preferably 50% or less, and still more preferably 40%. It is more preferably 30% or less.
  • the porosity of the electret film is less than or equal to the above upper limit, the pores are less likely to collapse and the pressure resistance is improved.
  • the porosity of the electret film is at least the above lower limit, the piezoelectric properties can be further improved. Note that the porosity of the electret film is calculated by the method described below.
  • the thickness of the electret film in this embodiment is preferably 10 ⁇ m or more, more preferably 15 ⁇ m or more, even more preferably 20 ⁇ m or more, and preferably 1000 ⁇ m or less, more preferably 750 ⁇ m or less, and still more preferably 500 ⁇ m or less.
  • the thickness of the electret film is measured by the method described below.
  • FIG. 2 is an exploded perspective view showing the basic configuration of the sensor 10 used in the first embodiment of the present invention.
  • the sensor 10 preferably includes an electret film 11 and at least one pair of electrodes 12a, 12b.
  • the pair of electrodes 12a, 12b be provided so as to sandwich the electret film 11 therebetween.
  • the pair of electrodes 12a, 12b are provided with signal take-out lines 13a, 13b that output signals (voltages) from the electrodes 12a, 12b, respectively.
  • the signal take-out lines 13a and 13b function as output terminals T11 and T12 shown in FIG. 1, respectively.
  • the electrodes 12a, 12b need only have conductivity, and aluminum foil, copper foil, silver foil, gold foil, nickel foil, tin foil, carbon sheet, etc. are preferably used for the electrodes 12a, 12b.
  • the signal extraction lines 13a and 13b are not particularly limited, but preferably have a structure in which conductive wires are covered with an insulating material.
  • the conductive wire is preferably of a type made of a conductor such as copper or aluminum. Examples of the material for the insulating material include tetrafluoroethylene/ethylene copolymer (ETFE), vinyl chloride, and crosslinked polyethylene.
  • the diameter and length of the signal extraction lines 13a, 13b are not particularly limited, and can be appropriately selected depending on the size of the sensor 10, the types of the electrodes 12a, 12b, etc.
  • the thickness of the electrodes 12a, 12b is preferably 2 ⁇ m or more, more preferably 3 ⁇ m or more, even more preferably 5 ⁇ m or more, and preferably 100 ⁇ m or less, more preferably 75 ⁇ m or less, and still more preferably 50 ⁇ m or less.
  • the thickness of the electrodes 12a, 12b is 2 ⁇ m or more, the electrodes 12a, 12b can exhibit conductive stability.
  • the thickness of the electrodes 12a and 12b is 100 ⁇ m or less, the flexibility of the sensor 10 can be improved.
  • this embodiment includes the sensor 10, which is a piezo element type sensor, and the first detection circuit 20, which detects continuous pressure applied to the sensor 10 from the output voltage of the sensor 10. .
  • the first detection circuit 20 includes a capacitor 21 connected in parallel to the sensor 10 and a high input impedance circuit 22 connected in series to the sensor 10. Thereby, the first detection circuit 20 can obtain a signal obtained by integrating the pulsed signal output from the sensor 10. As a result, static information can be obtained using a single piezo element sensor that is cheaper than a load cell.
  • FIG. 3 is a block diagram showing the main part configuration of an electronic device according to a second embodiment of the present invention.
  • the same components as those shown in FIG. 1 are designated by the same reference numerals.
  • the electronic device 2 of this embodiment has a configuration in which a differentiation circuit 30 is added to the electronic device 1 shown in FIG.
  • Such an electronic device 2 is configured to acquire dynamic information in addition to static information using a single piezo element sensor.
  • the differentiating circuit 30 is connected to the output terminal T20 of the first detection circuit 20. That is, the differentiating circuit 30 is connected in series to the first detection circuit 20.
  • the differentiation circuit 30 is a circuit that detects changes in the pressure applied to the sensor 10 by time-differentiating the signal output from the output terminal T20 of the first detection circuit 20. That is, the differentiating circuit 30 obtains dynamic information from the detection result (static information) of the first detection circuit 20. Differentiator circuit 30 outputs the detection result from output terminal T30.
  • any well-known differentiating circuit can be used.
  • the differentiating circuit 30 may be an analog circuit or a digital circuit.
  • the signal output from the output terminal T20 of the first detection circuit 20 is a signal (static signal) obtained by integrating the pulse-like signal output from the sensor 10.
  • the signal output from the output terminal T30 of the differentiating circuit 30 is a signal (dynamic signal) obtained by differentiating the signal output from the output terminal T20 of the first detection circuit 20. Therefore, in this embodiment, static information and dynamic information can be acquired with one piezo element type sensor.
  • the sensor 10 in addition to the sensor 10 and the first detection circuit 20, the sensor 10 is connected in series with the first detection circuit 20, and the detection result of the first detection circuit 20 is differentiated to be applied to the sensor 10. It is equipped with a differentiation circuit 30 that detects changes in pressure. Therefore, static information and dynamic information can be acquired with one piezo element type sensor.
  • FIG. 4 is a block diagram showing the main part configuration of an electronic device according to a third embodiment of the present invention.
  • the same components as those shown in FIG. 1 are designated by the same reference numerals.
  • the electronic device 3 of this embodiment has a configuration in which a second detection circuit 40 is added to the electronic device 1 shown in FIG. Similar to the electronic device 2 shown in FIG. 3, such an electronic device 3 is configured to acquire dynamic information in addition to static information using a single piezo element sensor.
  • the second detection circuit 40 is a circuit including a resistor 41, and detects a change in the pressure applied to the sensor 10 from the output voltage of the sensor 10. That is, the second detection circuit 40 detects dynamic information from the output voltage of the sensor 10.
  • the second detection circuit 40 like the first detection circuit 20, is connected to the output terminal T11 of the sensor 10. That is, the first detection circuit 20 and the second detection circuit 40 are connected in parallel.
  • a resistor 41 of the second detection circuit 40 is connected in parallel to the sensor 10. Specifically, one end of the resistor 41 is connected to the output end T11 of the sensor 10, and the other end is grounded. One end of the resistor 41 (the end connected to the output end T11 of the sensor 10) is connected to the output end T40 of the second detection circuit 40.
  • the second detection circuit 40 outputs the detection result from the output terminal T40.
  • the input impedance of the second detection circuit 40 is, for example, 0.1 M ⁇ or more and 10 M ⁇ or less.
  • the input impedance of the high input impedance circuit 22 included in the first detection circuit 20 is set higher than the input impedance of the second detection circuit 40.
  • the input impedance of the high input impedance circuit 22 is greater than or equal to 10 4 times and less than or equal to 10 8 times the input impedance of the second detection circuit 40 .
  • the input impedance of the second detection circuit 40 is 0.1 M ⁇
  • the input impedance of the high input impedance circuit 22 is set to 1 G ⁇ or more and 10 T ⁇ or less.
  • the input impedance of the second detection circuit 40 is 10 M ⁇
  • the input impedance of the high input impedance circuit 22 is set to 0.1 T ⁇ or more and 1 PT ⁇ or less.
  • the signal output from the output terminal T20 of the first detection circuit 20 is a signal (static signal) obtained by integrating the pulse-like signal output from the sensor 10.
  • the signal output from the second detection circuit 40 is a signal (dynamic signal) similar to the pulse-like signal output from the sensor 10. Therefore, in this embodiment, static information and dynamic information can be acquired with one piezo element type sensor.
  • this embodiment includes the second detection circuit 40 that detects a change in the pressure applied to the sensor 10 from the output voltage of the sensor 10. Therefore, static information and dynamic information can be acquired with one piezo element type sensor.
  • FIG. 5 is a block diagram showing the main part configuration of an electronic device according to a fourth embodiment of the present invention.
  • the same components as those shown in FIG. 4 are designated by the same reference numerals.
  • the electronic device 4 of this embodiment has a configuration in which a switching circuit 50 is added to the electronic device 3 shown in FIG. Similar to the electronic device 3 shown in FIG. 4, such an electronic device 4 is configured to acquire dynamic information in addition to static information using a single piezo element sensor. The system is configured to selectively acquire dynamic information.
  • the switching circuit 50 is a circuit that includes one input terminal T50 and two output terminals T51 and T52, and connects the input terminal T50 to the output terminal T51 or the output terminal T52.
  • the input terminal T50 of the switching circuit 50 is connected to the output terminal T11 of the sensor 10, the output terminal T51 is connected to the first detection circuit 20, and the output terminal T52 is connected to the second detection circuit 40. ing.
  • the switching circuit 50 allows the sensor 10 to be connected to the first detection circuit 20 to obtain static information, or the sensor 10 to be connected to the second detection circuit 40 to obtain dynamic information.
  • the first detection circuit 20 or the second detection circuit 40 is connected to the sensor 10. It is equipped with a switching circuit 50 that switches between the two modes. Therefore, static information and dynamic information can be selectively acquired using a single piezo element type sensor.
  • the electronic device described above can be used as a bed sensor or a shelf sensor.
  • a bed sensor for example, by placing the film-like sensor 10 under the mattress of the bed, static information such as constant pressure and dynamic information such as the subject's vital data (respiration, pulse rate) can be detected. , body movements, etc.).
  • static information such as constant pressure
  • dynamic information such as the subject's vital data (respiration, pulse rate)
  • body movements etc.
  • a shelf sensor for example, by placing the film-like sensor 10 on the shelf, it can detect the weight of the items placed on the shelf (static information) and the changes in the weight of the items (static information). dynamic information).
  • Example 1 and Example 2 will be shown below to explain the electronic device of the present invention in more detail, but the present invention is not limited by the following examples as long as it does not exceed the gist thereof. Note that in Example 1 and Example 2, cases where two different types of organic polymer-based piezoelectric materials are applied to the electronic device shown in the third embodiment or the fourth embodiment are compared.
  • a resin composition for an electret film is obtained by mixing 0.1 part by mass of a 1:1 mixture with pentaerythritol ("IRGANOX-B225", manufactured by BASF) and melt-extruding it at 280 ° C. with a twin-screw extruder. Obtained.
  • the resin composition for an electret film was put into an extruder connected to a T-die with a lip opening of 1 mm, and molded, and guided by a cast roll to obtain a non-porous film with a thickness of 300 ⁇ m. Thereafter, the film was stretched 7 times in the transverse direction at a stretching temperature of 100° C. using film tenter equipment (manufactured by Kyoto Kikai Co., Ltd.) to obtain a porous film.
  • the porous electret film obtained was placed on a ground plate and charged using a wire electrode by applying a voltage of -11 kV with a distance between the electrodes of 20 mm to obtain a porous electret film.
  • the thickness of the obtained porous electret film was 55 ⁇ m, the porosity was 20%, and the ⁇ crystal production ability was 92%.
  • the thickness was measured at 10 points at random using a 1/1000 mm dial gauge, and the average value was determined.
  • the porosity was calculated based on the actual amount W1 of the measurement sample and the density of the resin composition for the electret film, using a porous electret film cut out to a size of 100 mm in width x 100 mm in length as the measurement sample. It was calculated based on the following formula from the mass W0 when the porosity was 0%.
  • Porosity (%) ⁇ (W0-W1)/W0 ⁇ 100
  • the ⁇ -crystal production ability was determined by differential scanning calorimetry (DSC) of a porous electret film performed by the method shown below.
  • the test device used was "DSC 204F1" manufactured by NETZSCH. First, the temperature was raised from 40°C to 200°C at a rate of 10°C/min under a nitrogen atmosphere, held for 1 minute, and then cooled to 40°C at a rate of 10°C/min.
  • the melting peak with a peak in the temperature range of 145 to 157°C was observed as the melting peak of ⁇ crystals, and the peak above 158°C was observed.
  • the heat of fusion is calculated from the base line drawn from the flat part on the high temperature side and the area of the region surrounded by the peak, and the heat of fusion of the ⁇ crystal is expressed as ⁇ H ⁇ , ⁇ crystal.
  • the heat of fusion of ⁇ H ⁇ was calculated using the following formula.
  • ⁇ crystal formation ability (%) [ ⁇ H ⁇ /( ⁇ H ⁇ + ⁇ H ⁇ )] ⁇ 100
  • a piezo element type sensor was produced by the following method.
  • a conductive copper foil adhesive tape "E20CU” manufactured by DIC, electrode thickness 19 ⁇ m, adhesive layer thickness 21 ⁇ m
  • electrode thickness 19 ⁇ m, adhesive layer thickness 21 ⁇ m is cut into 5 mm square pieces, and the copper foil is attached to a 10 mm square protective film (Kapton) through the adhesive layer.
  • a protective film with electrodes was obtained by pasting it on the center of a tape (thickness: 50 ⁇ m). Two of these protective films with electrodes were arranged so that the two electrodes faced each other, and a porous electret film cut out into a 6 mm square was further arranged between the two electrodes.
  • one signal take-out electric wire (Junflon wrapping wire electric wire, manufactured by Junkosha Co., Ltd.) having a line width of 0.56 mm was sandwiched between the protective film and the adhesive layer of the conductive copper foil adhesive tape. Subsequently, the ends of the protective film were heat-sealed using a heat sealer to obtain the sensor of Example 1.
  • Example 1 Dynamic stimulation and static stimulation
  • the sensor 10 of Example 1 was installed on a load cell, and the waveforms of the output voltages of the first detection circuit 20 and the second detection circuit 40 were obtained when a robot applied pressure from above the sensor.
  • the capacitance of the capacitor 21 of the first detection circuit 20 was 1000 pF
  • the input impedance of the high input impedance circuit 22 was 1 T ⁇ .
  • the input impedance of the second detection circuit 40 was set to 1 M ⁇ .
  • FIG. 6 is a diagram showing the waveform of the output voltage obtained by the second detection circuit 40 when the sensor 10 of Example 1 is used.
  • FIG. 6 also shows the output waveform WF0 of the load cell indicating the state of pressurization by the robot.
  • the waveform WF2 of the output signal acquired by the second detection circuit 40 has a pulse shape, and information regarding the change in pressure applied to the sensor 10 (dynamic stimulation) can be confirmed.
  • FIG. 7 is a diagram showing the waveform of the output voltage obtained by the first detection circuit 20 when the sensor 10 of Example 1 is used.
  • FIG. 7 also shows the output waveform WF0 of the load cell indicating the state of pressurization by the robot.
  • the waveform WF1 of the output signal acquired by the first detection circuit 20 (a circuit with higher input impedance than the second detection circuit 40 and including the capacitor 21) is approximated to the output waveform WF0 of the load cell. , it is possible to check how long the pressure continues to be applied to the sensor 10 (static stimulation).
  • FIG. 8 is a diagram showing the relationship between the magnitude of the load applied to the sensor 10 and the magnitude of the output voltage of the first detection circuit 20 in the first embodiment. As shown in FIG. 8, it was confirmed that the signal strength tended to increase as the load increased.
  • Example 2 Polyvinylidene fluoride film> A piezo element type sensor was produced in the same manner as in Example 1 using a polyvinylidene fluoride film (Kureha KF Piezo Film, manufactured by Kureha Corporation) with a thickness of 80 ⁇ m as an organic polymer piezoelectric material.
  • a polyvinylidene fluoride film Kureha KF Piezo Film, manufactured by Kureha Corporation
  • FIG. 9 is a diagram showing the waveform of the output voltage obtained by the first detection circuit 20 when the sensor 10 of Example 2 is used. Note that, in addition to the waveform WF1 of the output voltage acquired by the first detection circuit 20, in addition to the waveform WF1 of the output voltage acquired by the first detection circuit 20, FIG. 9 also shows the output waveform WF0 of the load cell indicating the state of pressurization by the robot. As shown in FIG. 9, the output voltage waveform WF1 acquired by the first detection circuit 20 is similar to the output waveform WF0 of the load cell, which indicates how long pressure continues to be applied to the sensor 10 (static stimulus) was confirmed.

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CN202380027042.1A CN118871758A (zh) 2022-03-18 2023-03-14 电子设备、床传感器以及货架用传感器
EP23770801.1A EP4495564A4 (en) 2022-03-18 2023-03-14 ELECTRONIC DEVICE, BED SENSOR AND SHELF SENSOR
KR1020247030074A KR20240160111A (ko) 2022-03-18 2023-03-14 전자 기기, 베드 센서, 및 선반용 센서

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