WO2023162599A1 - 油性固形化粧料 - Google Patents
油性固形化粧料 Download PDFInfo
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- WO2023162599A1 WO2023162599A1 PCT/JP2023/003133 JP2023003133W WO2023162599A1 WO 2023162599 A1 WO2023162599 A1 WO 2023162599A1 JP 2023003133 W JP2023003133 W JP 2023003133W WO 2023162599 A1 WO2023162599 A1 WO 2023162599A1
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- Prior art keywords
- oil
- mass
- component
- cleansing cosmetic
- based solid
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
Definitions
- the present invention relates to an oily solid cleansing cosmetic.
- oil-based cleansing cosmetic that has a good compatibility with makeup (cosmetic film on the skin) and has excellent performance (stain removal) in removing dirt such as keratin and sebum.
- Specific examples of oil-based cleansing cosmetics include cleansing oils, gel cleansing agents, and cleansing creams. It has a feature that it is easy to massage when applying, and its development is being diligently advanced.
- Patent Document 1 discloses (A) 1 to 30% by mass of solid oil having a melting point of 50 to 120° C., (B) 50 to 97% by mass of liquid oil, and (C) a nonionic having an HLB value of 5 to 13. 3 to 30% by mass of a surfactant, (D) 0.1 to 20% by mass of powder having a volume average particle size of 1 to 200 ⁇ m, and (E) 0.01 to 10% by mass of fumed silica. It is described that an oil-based solid cleansing cosmetic excellent in ease of rinsing and refreshing feeling after rinsing can be obtained by blending at a ratio (based on total cosmetic). However, when women with oily skin or men who generally have more sebum than women use this cosmetic, they still feel a sticky feeling when using it, and there has been a demand for a more refreshing feeling after rinsing off.
- Patent Document 2 describes a combination of Fischer-Tropsch wax, which is a hydrocarbon wax, and behenyl behenate, which is an ester-based solid oil. It is described that the solid oil has a low melting point and high oil-solidifying ability. However, according to the studies by the present inventors, it has been found that women and men with oily skin still feel sticky when using this cosmetic.
- the present invention was completed under such background art, and its object is to provide an oil-based solid cleansing cosmetic that is not sticky even when used by men and women with oily skin and provides an excellent refreshing feeling after rinsing. is to provide
- the present inventors used a solid oil containing a hydrocarbon wax, and the mass ratio of a nonionic surfactant having a specific HLB value to the solid oil The inventors have found that the above requirements can be satisfied by controlling the temperature, and have completed the present invention.
- the oil-based solid cleansing cosmetic of the present invention has excellent cleansing power and a non-sticky feel, and is easy to wash off and has a refreshing feeling after rinsing.
- the solid oil component (A) is an oil that is solid at normal temperature (25° C.) and contains hydrocarbon wax as at least a part thereof.
- the content of the hydrocarbon wax in the solid oil is preferably 5% by mass or more, more preferably 20 to 95% by mass, still more preferably 30 to 90% by mass.
- the solid oil has a melting point of 50 to 120°C, preferably 55 to 105°C, more preferably 60 to 100°C.
- the melting point of the solid oil can be measured by Melting Point Determination Method 2, which is a general test method of the Standards for Quasi-drug Ingredients. If the melting point is too low, the liquid oil of the component (B) cannot be uniformly solidified, and the oil-based solid cleansing cosmetic composition may liquefy due to vibration or impact during transportation or carrying, and may have poor shape retention. Poorly unable to maintain a solid shape. Conversely, if the melting point is excessively high, the composition will become hard and difficult to remove with fingers when used as a cleansing cosmetic. C) It becomes easy to cause oxidative deterioration of the component.
- Fischer-Tropsch wax and polyethylene which have high ability to solidify liquid oil in a small amount, can be preferably used.
- Commercially available hydrocarbon waxes include Paraffin Wax 135, Paraffin Wax 140, Paraffin Wax 150 and HNP-11 manufactured by Nippon Seiro Co., Ltd., which are paraffin waxes; HNP-9 manufactured by Nippon Seiro Co., Ltd., which is microcrystalline wax.
- the solid oil may consist of only hydrocarbon waxes, but may contain other solid oils as desired.
- Solid oils that can be used in combination with hydrocarbon wax include Japanese wax, carnauba wax, candelilla wax, rice wax, waxes such as beeswax, hydrogenated jojoba oil, behenyl behenate, hydrogenated castor oil, Hardened oils, higher alcohols, silicone waxes and the like can be mentioned.
- Commercially available products thereof include purified candelilla wax NO. 1.
- the above component (A) may be composed of a single compound, or may be composed of an appropriate combination of two or more compounds.
- a hydrocarbon wax especially a Fischer-Tropsch wax and behenyl behenate
- the melting point of the solid oil is lowered and a high oil-solidifying ability is exhibited.
- the ratio [(b):(f)] of behenyl behenate (b) and Fischer-Tropsch wax (f)] is 10:90 to 90:10 by mass. , particularly preferably 20:80 to 90:10.
- the content of component (A) is 1 to 20% by mass, preferably 2 to 15% by mass, more preferably 3 to 10% by mass, based on the total oily solid cosmetic composition. If the amount of component (A) is too low, the shape retention will not be sufficient, and the massage effect will be reduced due to the excessive softness. Conversely, if the amount is excessively high, stickiness will be felt and it will be difficult to wash off, resulting in a reduced refreshing feeling after washing off.
- the (B) liquid oil used in the present invention is a semisolid or liquid oil having a melting point of less than 50°C at room temperature. Any of animal oil, vegetable oil and synthetic oil may be used as long as it is used in ordinary cosmetics.
- liquid oils include ethylhexyl palmitate, caprylic/capric triglyceride, triethylhexanoin, dicaprylyl carbonate, diisostearyl malate, diglyceryl triisostearate, decaglyceryl decaisostearate, dimer acid and dimer Oligomer ester with diol, pentaerythritol tetraisostearate, diglyceryl tetraisostearate, cetyl ethylhexanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, neopentyl glycol dioctoate, cholesterol fatty acid ester, jojoba oil, etc.
- Hydrocarbons such as volatile isoparaffin, polybutene, polyisobutylene, heavy liquid isoparaffin, liquid paraffin, ⁇
- Esters are preferably used from the standpoint of removal of makeup stains and ease of washing off, and ethylhexyl palmitate, caprylic/capric triglyceryl, triethylhexanoin, and dicaprylyl carbonate are preferably used.
- the content of (B) liquid oil is 50 to 97% by mass, preferably 55 to 95% by mass, more preferably 60 to 92% by mass, in the total amount of the oily solid cleansing cosmetic.
- good cleansing performance good makeup removal
- a nonionic surfactant having an HLB value in the range of 6 to 13 is used as component (C).
- a nonionic surfactant having an HLB value in the range of 6 to 13 means a nonionic surfactant having an HLB value in the range of 6 to 13, or an HLB value in the range It is a combination of multiple nonionic surfactants with values.
- a nonionic surfactant having an HLB value outside this range may be included, but from the viewpoint of a refreshing feeling after rinsing off, the content of a nonionic surfactant with an HLB value of less than 6 is It is preferably 1 mass % or less with respect to the whole material.
- HLB is an index that indicates the balance between hydrophilicity and lipophilicity as a value from 0 to 20. The closer to 0, the higher the lipophilicity, and the closer to 20, the higher the hydrophilicity.
- Various calculation methods are known for calculating the HLB value, and the values are described in catalogs and the like provided by manufacturers.
- the HLB value of the nonionic surfactant adopts the HLB value described in the manufacturer's catalog when the nonionic surfactant is a commercial product, and is not a commercial product.
- the HLB value of the nonionic surfactant is less than 6, even if you try to wash it off with water or lukewarm water after applying the makeup to the cleansing cosmetic on your skin, it will wash off cleanly because it does not blend well with water. I can't get a refreshing feeling after rinsing. Conversely, when the HLB value exceeds 13, hydrophobic makeup cannot be blended into the cleansing cosmetic, resulting in insufficient makeup removal. Above all, when the HLB value is in the range of 7 to 11, the ease of removing makeup and rinsing off is good.
- the nonionic surfactant of component (C) may be either solid or liquid, but if a nonionic surfactant that is liquid at 25°C is used, excellent performance in terms of make-up removal and ease of rinsing is achieved. is obtained.
- nonionic surfactants having an HLB value of 6 to 13 used as component (C) include polyglyceryl-4 stearate, polyglyceryl-2 oleate, polyglyceryl-2 isostearate, and polyglyceryl-10 distearate.
- fatty acid polyoxyethylene alkyl ethers such as laureth-8 isostearate and steareth-12 stearate; PEG-15 glyceryl tristearate, PEG-5 glyceryl triisostearate, PEG-10 glyceryl triisostearate , PEG-20 glyceryl triisostearate, polyoxyethylene fatty acid glyceryl such as PEG-20 glyceryl triisostearate; fatty acid polyoxyethylene such as PEG-15 hydrogenated castor oil isostearate, PEG-20 hydrogenated castor oil triisostearate, etc. hydrogenated castor oil; and the like.
- sorbitan fatty acid ester polyoxyethylene sorbitan fatty acid ester, polyoxyethylene polyoxypropylene copolymer, ether of polyoxyethylene polyoxypropylene copolymer and long-chain alcohol, ether of polybutylene glycol polyglycerin copolymer and long-chain alcohol, etc.
- polyoxyethylene fatty acid ester, polyoxyethylene fatty acid glyceryl, fatty acid polyoxyethylene hydrogenated castor oil and fatty acid polyoxyethylene alkyl ether are preferably used from the viewpoint of ease of makeup removal and washing off.
- the fatty acid residue includes carbon atoms such as myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, and the like. It is preferably a residue of a higher fatty acid of 10 to 22. Among them, it is preferably a residue of a branched higher fatty acid that makes the nonionic surfactant liquid and has excellent oxidation resistance stability, especially isostearic acid residue. groups are preferred.
- Examples of commercially available nonionic surfactants that are liquid at 25°C and used as component (C) include Emarex RWIS-320 (PEG-20 hydrogenated castor oil triisostearate; manufactured by Nippon Emulsion Co., Ltd.; HLB value 6 ), Uniox GT-20IS (PEG-20 glyceryl triisostearate; manufactured by NOF Corporation; HLB value: 10.4), and commercial products that are solid at 25°C include, for example, Emarex GWS- 320 (PEG-20 glyceryl tristearate; manufactured by Nippon Emulsion; HLB value 8), Emarex SWS-12 (steareth-12 stearate; manufactured by Nippon Emulsion; HLB value 8), Emarex 608 (steareth-8; Japan Emulsion; HLB value 9), etc.
- Emarex GWS- 320 PEG-20 glyceryl tristearate; manufactured by Nippon Emulsion; HLB value 8
- Emarex SWS-12 steareth-12
- the amount of component (C) used is 15 to 40% by mass, preferably 15 to 35% by mass, more preferably 18 to 30% by mass in the total amount of the oily solid cleansing cosmetic. If the amount is too small, the easiness of rinsing off and the feeling of freshness after rinsing off will be reduced, and if the amount is too large, there is concern of irritation to the skin.
- the mass ratio [(C)/(A)] of the nonionic surfactant as component (C) and the solid oil as component (A) is 2 to 10. , preferably 2.2.5-8, more preferably 3-7. If the value of [(C)/(A)] is too small, the solid oil tends to remain on the skin even after rinsing, and a refreshing feeling cannot be obtained after rinsing. If it is excessively large, there is concern about dryness and irritation to the skin.
- the powder used in the present invention has a volume average particle size of 1 to 200 ⁇ m, preferably 2 to 100 ⁇ m, more preferably 5 to 50 ⁇ m.
- the powder used in the present invention has a volume average particle size of 1 to 200 ⁇ m, preferably 2 to 100 ⁇ m, more preferably 5 to 50 ⁇ m.
- the volume average particle size is measured using a laser diffraction/scattering particle size distribution analyzer (eg, LA-950 manufactured by Horiba Ltd.), using 95% by volume ethanol as a solvent, and ultrasonically dispersing for 5 minutes (Honda Electronics Co., Ltd. (manufactured ultrasonic cleaner W-113, 28 kHz), and does not refer to the primary particle size.
- a laser diffraction/scattering particle size distribution analyzer eg, LA-950 manufactured by Horiba Ltd.
- 95% by volume ethanol as a solvent
- ultrasonically dispersing for 5 minutes Honda Electronics Co., Ltd. (manufactured ultrasonic cleaner W-113, 28 kHz)
- the blending amount of component (D) is 0.1 to 20% by mass, preferably 0.2 to 15% by mass, more preferably 1 to 10% by mass, based on the total cosmetic composition. When the component (D) is contained within this range, makeup removal and massage effects are improved.
- the powder of component (D) is not particularly limited as long as it can be used in cosmetics, and its material (organic, inorganic, etc.), shape (spherical, needle-like, plate-like, etc.) and particle structure. Any one can be used regardless of whether it is (porous, non-porous, etc.). Among them, porous powders or powders with a large specific surface area are preferably used because they are excellent in the ability to adsorb make-up stains and excess sebum.
- Powders of component (D) include, for example, talc, muscovite, synthetic mica, phlogopite, synthetic fluorine phlogopite, sericite, zeolite, kaolin, bentonite, saponite, hectorite, natural clay, sea mud, and activated clay.
- Clay minerals such as silicic acid, silicic anhydride (silica), magnesium silicate, magnesium aluminum silicate, calcium silicate, barium sulfate, magnesium carbonate, boron nitride, bismuth oxychloride, alumina, zirconium oxide, hydroxyapatite, etc.
- Inorganic oxide or inorganic salt silicone powder, silicone elastic powder, polyurethane powder, cellulose powder, nylon powder, silk powder, PMMA powder, starch, polyethylene powder, lauroyl lysine, metal soap, plant powder (apricot kernel, walnut kernel , glucomannan powder, etc.); charcoal powder such as activated carbon, medicinal charcoal, bamboo charcoal; and composites and granules thereof.
- Natural clay and sea mud which are clay minerals, do not necessarily have the same composition and hue depending on the place of production, but they are all mixtures of kaolin, montmorillonite, mica, and the like. Specific examples of natural clay and sea mud includeixie lava clay, Tanakura clay, Palau white mud, Sparclay (trade name) and Tersil (trade name) from Brazil, and Clargile (trade name) from France.
- the present invention further contains fumed silica as component (E).
- fumed silica as component (E).
- a cleansing cosmetic from a composition containing solid oil
- the powder can be uniformly dispersed.
- make-up cosmetics such as lipstick generally weigh several grams, so the time from filling to solidification is extremely short, and the dispersibility of the powder contained in the formulation is impaired. Less risk.
- the weight per product is generally about 100 grams or more. is long, during which sedimentation of powder components may occur. When the powder component settles, the dispersion of the powder component becomes non-uniform, and the uneven content of the powder component occurs in the vertical direction of the cosmetic. As a result, the appearance of the cosmetic is spoiled, and the quality stability is also spoiled.
- Component (E), fumed silica is fine amorphous silica, also called fumed silica, and appears as a fluffy, light white powder.
- Fumed silica can be obtained, for example, by subjecting a raw material such as silicon tetrachloride to high temperature hydrolysis in an oxyhydrogen flame.
- the primary particle size of the fumed silica is from 1 to 50 nm, preferably from 3 to 25 nm, particularly preferably from 5 to 15 nm. If the primary particle size is excessively large, sedimentation of the component (D) cannot be effectively suppressed when the formulation is melt-filled in the manufacturing process of the cleansing cosmetic.
- the primary particle size can be determined as the average value of 30 to 50 particles measured by transmission electron micrographs or field emission scanning electron micrographs, and the values are listed in catalogs provided by manufacturers. there is In this specification, the primary particle size of fumed silica adopts the value described in the manufacturer's catalog.
- the specific surface area of the fumed silica is preferably 30 m 2 /g or more, more preferably 50 to 400 m 2 /g, particularly preferably 100 to 400 m 2 /g. If the specific surface area is excessively small, sedimentation of the component (D) cannot be effectively suppressed when the formulation is melt-filled in the manufacturing process of the cleansing cosmetic.
- the blending amount of component (E) is 0.01 to 10% by mass, preferably 0.1 to 5% by mass, more preferably 0.2 to 3% by mass, based on the total cosmetic composition.
- the ratio (E/D) of component (E) to component (D) is preferably 0.01-10, more preferably 0.05-5.
- the component (E) may be hydrophilic untreated fumed silica or hydrophobized fumed silica.
- hydrophobic treatment include dimethyldichlorosilane treatment, trimethylsiloxy treatment with trimethylsilyl chloride or hexamethyldisilazane, octylsilanization treatment, dimethylsilicone oil treatment, coating baking treatment using methylhydrogenpolysiloxane, and metal soap treatment. coating and the like.
- untreated ones are preferably used from the viewpoint of ease of washing away.
- component (E) Commercial products of component (E) include untreated fumed silica AEROSIL 50, AEROSIL 130, AEROSIL 200, AEROSIL 200V, AEROSIL 200CF, AEROSIL 200FAD, AEROSIL 300, AEROSIL 300CF, AEROSIL 380, AEROSIL 380S.
- hydrophobized ones include AEROSIL R972, AEROSIL R972V, AEROSIL R972CF, AEROSIL R974, AEROSIL R976S, AEROSIL RX200, AEROSIL RX300, AEROSIL RY200, AEROSIL R202, AEROSIL R805, AEROSIL R812, AEROSIL RA200H (or more , manufactured by Nippon Aerosil Co., Ltd.), CAB-O-SIL TS530 (manufactured by Cabot Corporation), and the like.
- the oily solid cleansing cosmetic of the present invention may contain a small amount of water as the (F) component.
- the content of water is preferably 5% by mass or less of the total amount of the cosmetic, and within this range, the nonionic surfactant of component (C) and water are in a solubilized state, i.e., an oily component as a dispersion medium. is present, and the component (C) and water form reverse micelles.
- the nonionic surfactant of the component (C) is easily dissolved in the oil, and the component (C) is not separated or precipitated even during long-term storage, thereby improving the storage stability.
- the effect is remarkable when the water content is 0.02 to 3% by mass.
- the oil-based solid cleansing cosmetic of the present invention includes components used in ordinary cosmetics, such as powders other than the component (D), dyes, oily gelling agents, oil-soluble resins, polyhydric alcohols, lower alcohols, and ultraviolet rays.
- Additives such as absorbers, UV scattering agents, moisturizers, fragrances, antioxidants, preservatives, antifoaming agents, cosmetic ingredients, and various extracts can be contained within a range that does not impair the effects of the present invention.
- the oil-based solid cleansing cosmetic composition of the present invention does not show fluidity at normal temperature (25°C) and normal pressure (1 atm), and its shape is not particularly limited. Specific examples of the shape include a stick shape, a bar shape, a plate shape, and a shape formed by pouring into a container.
- These various cleansing cosmetics can be prepared according to a conventional method. For example, all raw materials are heated to a melting point or higher, mixed uniformly, poured into a container or a mold in a molten state, and cooled or left to cool to obtain an oily solid cleansing cosmetic.
- the oil-based solid cleansing cosmetic composition of the present invention is non-sticky and provides an excellent refreshing feeling after rinsing, so it can be suitably used as a cleansing cosmetic composition for oily skin, especially for men.
- the oil-based solid cleansing cosmetic composition of the present invention has properties required for massage cosmetics, that is, moderate viscosity and smoothness and long-lasting smoothness, in addition to a makeup-removing function. Therefore, apart from the oily solid cleansing cosmetic of the present invention, it can also be used as a massage cosmetic.
- the makeup can be removed by rinsing with water or lukewarm water after blending the cosmetic composition with the makeup. Therefore, when conventional oily solid cleansing cosmetics are used, it is possible to omit the operation of washing the face with soap or the like, which was thought to be necessary after use.
- the present invention will be described in more detail below with examples and comparative examples, but the present invention is not limited by these examples.
- the compounding amount in the formulations below is % by mass based on the total amount.
- evaluation methods for the oil-based solid cleansing cosmetics of the present invention in the following examples and comparative examples are as follows.
- Examples 1-3 and Comparative Examples 1-4 Oil-based solid cleansing cosmetic
- An oily solid cleansing cosmetic having the formulation shown in Table 1 was prepared according to the following manufacturing procedure.
- the oily solid cleansing cosmetic thus obtained was evaluated for non-stickiness, ease of makeup removal, ease of rinsing, and refreshing feeling after rinsing by the methods described above.
- the evaluation results are shown in Table 1.
- the oily solid cleansing cosmetics of Examples 1 and 2 were excellent in non-stickiness, good makeup removal, ease of rinsing, and refreshing feeling after rinsing.
- the oily solid cleansing cosmetic of Example 3 was excellent in non-stickiness, ease of makeup removal, and ease of rinsing, and had a good refreshing feeling after rinsing.
- the content of the component (C) is low, and the [(C)/(A)] ratio of the oily solid cleansing cosmetic composition is less than 2. 1).
- the oily solid cleansing cosmetic composition (Comparative Example 2) that did not contain the components (D) and (E) was significantly inferior in ease of rinsing and fresh feeling after rinsing.
- Example 4 Furthermore, the content of the (A) component is higher than in Example 1, and the [(C) / (A)] ratio is less than 2. Compared to the oily solid cleansing cosmetic (Comparative Example 3), and Example 3 The oily solid cleansing cosmetic composition (Comparative Example 4) with a high component (A) content and a low component (C) content (Comparative Example 4) was inferior in ease of rinsing and refreshing feeling after rinsing.
- the oil-based solid cosmetics suitable for oily skins, especially men's use which are excellent in the cleansing performance and the refreshing feeling after rinsing off are provided.
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Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2022-026453 | 2022-02-24 | ||
| JP2022026453A JP2023122763A (ja) | 2022-02-24 | 2022-02-24 | 油性固形化粧料 |
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| Publication Number | Publication Date |
|---|---|
| WO2023162599A1 true WO2023162599A1 (ja) | 2023-08-31 |
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| Application Number | Title | Priority Date | Filing Date |
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| PCT/JP2023/003133 Ceased WO2023162599A1 (ja) | 2022-02-24 | 2023-02-01 | 油性固形化粧料 |
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| Country | Link |
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| JP (1) | JP2023122763A (https=) |
| WO (1) | WO2023162599A1 (https=) |
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| JP7678927B1 (ja) * | 2024-11-21 | 2025-05-16 | ニベア花王株式会社 | 化粧料組成物 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110059404A (ko) * | 2009-11-27 | 2011-06-02 | 한국콜마 주식회사 | 물로 워시오프 할 수 있는 스틱형 클렌징 화장료 조성물 |
| WO2020039918A1 (ja) * | 2018-08-18 | 2020-02-27 | ジェイオーコスメティックス株式会社 | 油性固形クレンジング化粧料 |
| WO2020039917A1 (ja) * | 2018-08-18 | 2020-02-27 | ジェイオーコスメティックス株式会社 | 油性固形化粧料 |
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| CN103957882A (zh) * | 2011-11-21 | 2014-07-30 | 荷兰联合利华有限公司 | 软固体止汗组合物 |
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- 2022-02-24 JP JP2022026453A patent/JP2023122763A/ja active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110059404A (ko) * | 2009-11-27 | 2011-06-02 | 한국콜마 주식회사 | 물로 워시오프 할 수 있는 스틱형 클렌징 화장료 조성물 |
| WO2020039918A1 (ja) * | 2018-08-18 | 2020-02-27 | ジェイオーコスメティックス株式会社 | 油性固形クレンジング化粧料 |
| WO2020039917A1 (ja) * | 2018-08-18 | 2020-02-27 | ジェイオーコスメティックス株式会社 | 油性固形化粧料 |
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