WO2023143543A1 - Maintenance method and maintenance oil for circuit breaker and knife switch - Google Patents

Maintenance method and maintenance oil for circuit breaker and knife switch Download PDF

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Publication number
WO2023143543A1
WO2023143543A1 PCT/CN2023/073628 CN2023073628W WO2023143543A1 WO 2023143543 A1 WO2023143543 A1 WO 2023143543A1 CN 2023073628 W CN2023073628 W CN 2023073628W WO 2023143543 A1 WO2023143543 A1 WO 2023143543A1
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Prior art keywords
maintenance
metal
oil
indirect contact
parts
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PCT/CN2023/073628
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French (fr)
Chinese (zh)
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覃东明
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覃东明
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Publication of WO2023143543A1 publication Critical patent/WO2023143543A1/en

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/285Esters of aromatic polycarboxylic acids
    • C10M2207/2855Esters of aromatic polycarboxylic acids used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064Di- and triaryl amines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14Metal deactivation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/16Dielectric; Insulating oil or insulators
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/17Electric or magnetic purposes for electric contacts

Definitions

  • the invention relates to a maintenance method and maintenance oil for various metals in various devices, wires, mechanisms and appliances of a circuit system, and belongs to the field of antirust lubricating oil.
  • the lubricating oil used for the anti-rust lubrication of ordinary machinery is improved and then used in the maintenance of circuit wiring piles and the like.
  • the circuit board usually powders in less than a year.
  • the electronic components on the circuit board are either corroded or broken, or the solder feet are corroded and broken.
  • On the circuit board there are iron solder feet of electronic components, copper wire soldering/pressing joints, solder joints of tin material and many other metals. This requires the curing agent to have a good curing effect on all kinds of different metals, and has no or negligible effect on the electrical signal of the circuit board.
  • the wire terminal system terminal terminal assembly
  • the wires are aluminum-based and copper-based; the wiring pile has a copper-based main body and iron-based crimping and compression bolts.
  • the crimping bolts are not directly conductive, iron bolts are also very easy to oxidize and rust, and iron embroidery can promote the oxidation and corrosion process of the entire wiring pile system. Therefore, maintenance products must have a good protection function for every metal that may appear in the entire wiring pile wiring system. Therefore, the maintenance products are required to have a good maintenance effect on all kinds of metals, especially copper, aluminum, iron, and their respective alloys.
  • the liquid and oily protective products on the market for maintenance of electrical appliances have limited protection against many different types of metals.
  • Circuit equipment also requires as low maintenance times as possible, and life-long maintenance-free is the goal pursued.
  • life-long maintenance-free is the goal pursued.
  • outdoor surveillance cameras, leakage protectors, etc. it is very cumbersome to maintain only once: a series of tasks such as climbing, dismantling, etc., so it needs to be avoided as much as possible.
  • a traditional method is to use a multi-purpose rust-removing and loosening oil agent (such as WD-40) for maintenance, but this type of oil has a short curing time and evaporates in about a month, and this type of oil has insufficient maintenance ability for various metals , these problems were at least prior to the filing date of the present invention.
  • the maintenance oil of the present invention can use at least one of synthetic oil TMT and POE as the base oil of the maintenance oil, which can greatly reduce the number of maintenance and achieve the goal of life-long maintenance-free as much as possible.
  • the contact maintenance oil is mainly used for the maintenance of the two contacts of the electrical contacts, that is, the focus is on the maintenance of copper and silver systems. Although some such oils have a slightly longer curing time, they still have not reached the level of protection for various metals. Good level of maintenance ability; contact oil viscosity is low, only focus on cleaning and cleaning; there is no clear statement in the contact oil manual that it can be used for the maintenance of the wiring pile wiring system, that is, there is no clear statement in the product manual that the contact oil can be used It is confusing to use it for the maintenance of wiring pile wiring system.
  • most of the electrical appliances commonly used in daily life are electrical appliances that do not require electrical contacts to be live and frequently broken and closed. That is, contact oil is not necessary in daily use, and it is more of an industrial product.
  • the present invention provides a circuit breaker, a knife switch maintenance method and maintenance oil, which can have a good effect on various metals in the electrical appliances and electrical equipment of the circuit system.
  • Conservation especially for copper, aluminum, iron, and their respective alloys. Can provide long-life conservation. It can be used for plugs (male or female), solder feet of electronic components (soldered or unsoldered), wiring piles, wire heads, sockets (male or female), solder joints, wires or plugs on electrical equipment or electrical appliances.
  • the "maintenance oil” referred to in the present invention can also be referred to as any one of maintenance oil, protective oil, maintenance oil and anti-rust oil.
  • a kind of circuit breaker, knife switch maintenance oil contains (petroleum sulfonate barium, synthetic barium sulfonate, two free naphthalene sulfonate barium, heavy alkylbenzene sulfonate barium, N-oleic acid group sarcosine one of octadecylamine salts) and (zinc naphthenate, dodecenyl succinate, enyl succinate, 2-aminoethyl heptadecenyl imidazolinium dodecenyl succinate , octadecylamine oleate, heptadecenyl imidazolidinyl succinate, a mixture of zinc naphthenate and heptadecenyl imidazolidinyl succinate, one of imidazolinium alkyl phosphate ) and (one of the oil-soluble copper and copper alloy antirust agents for lub
  • the metal parts including the installation tights made of metal Firmware;
  • the installation fasteners include bolts, screws, and nuts;
  • the maintenance refers to anti-corrosion maintenance;
  • the various metal parts include metal conductors that are in indirect contact with metal conductors that transmit electrical energy or electrical signals When parts are in indirect contact, the metal in indirect contact refers to the metal with a resistance between the indirect contact metal and the metal conductor between ⁇ 0 ⁇ and ⁇ 1000 ⁇ .
  • this maintenance oil has an added component: one of the oil-soluble metal deactivators for lubricating oil; the deactivators include benzotriazole derivatives and thiadiazole derivatives.
  • the base oil of the maintenance oil described in 0012 or 0013 is at least one of PAO, TMT, and POE.
  • a maintenance method for a circuit breaker and a knife switch use the maintenance oil described in one of 0012, 0013, and 0014 to treat the circuit breaker and the knife switch when the circuit breaker and the knife switch are in normal working condition.
  • the metal parts include metal mounting fasteners;
  • the installation fasteners include bolts, screws, and nuts;
  • the maintenance refers to anti-corrosion maintenance;
  • the various metal parts include Metal conductors that transmit electrical energy or electrical signals have indirect contact metal parts.
  • indirect contact metals refer to metals with a resistance between the indirect contact metal and the metal conductor that is ⁇ 0 ⁇ and ⁇ 1000 ⁇ .
  • the maintenance oil for various wiring piles, wiring terminals, wire heads, and wire terminals is the same as 0012 or 0013 or 0014, the difference is that the name “circuit breaker, knife switch” is changed to "circuit In the system, various wiring piles, terminal blocks, wire heads, and wire terminals".
  • a maintenance method for various wiring piles, wiring terminals, wire heads, and wire terminals in a circuit system use 0016 curing oil to ensure that various wiring piles, wiring terminals, wire heads, and wire terminals work normally in the circuit system
  • the maintenance of the metal conductor itself that transmits electric energy or electrical signals includes the maintenance of the bare wire end of the wire;
  • the metal parts include metal mounting fasteners;
  • the mounting fasteners include bolts, screws, and nuts;
  • the maintenance refers to anti-corrosion maintenance;
  • the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals.
  • the metal between the metal conductors has a resistance between ⁇ 0 ⁇ and ⁇ 1000 ⁇ .
  • a circuit board maintenance oil the same as 0012 or 0013 or 0014, the only difference is that the name “circuit breaker, knife switch” is changed to "circuit board”.
  • a circuit board maintenance method use the maintenance oil described in 0018 to treat at least one of all the various metal parts on the circuit board that are in contact with the metal conductors that transmit electric energy or electric signals when the circuit board is in normal working condition or more than one location, or to maintain the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of bare wire leads;
  • the metal parts include metal mounting fasteners; the mounting fasteners, Including bolts, screws, and nuts;
  • the maintenance refers to anti-corrosion maintenance;
  • the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. It refers to the metal between the indirect contact metal and the metal conductor with a resistance between ⁇ 0 ⁇ and ⁇ 1000 ⁇ .
  • An electrical equipment maintenance oil the same as 0012 or 0013 or 0014, the only difference is that the name “circuit breaker, knife switch” is changed to "electrical equipment”; the electrical equipment maintenance oil includes the components for discrete electrical equipment The maintenance oil for maintenance; the maintenance oil for electrical equipment does not include the maintenance oil for the maintenance of various parts inside the chemical electric energy storage device.
  • a maintenance method for electrical equipment use the maintenance oil described in subparagraph 0020 to treat at least one of all the various metal parts on the electrical equipment that are in contact with the metal conductors that transmit electrical energy or electrical signals when the electrical equipment is in normal working condition or more than one location, or to maintain the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of bare wire leads;
  • the metal parts include metal mounting fasteners; the mounting fasteners, Including bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance;
  • the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals.
  • the maintenance of electrical equipment includes the maintenance of discrete electrical equipment components; the maintenance of electrical equipment does not include maintenance of chemical electrical energy Maintenance of various parts inside the storage device.
  • the present invention is originally designed to be used for the maintenance of all kinds of metals on the electric knife switch wiring pile of the household 220V alternating current. It has a long maintenance life and reduces the number of maintenance; it has a good maintenance effect on various metals; it prolongs the service life of electrical appliances; the insulator is safe to use, and the electric strength is generally about 6kV ⁇ 15%/mm, and it is energized with 1000V DC Generally, the measured resistivity is about 1.5-2.5 ⁇ 107 ⁇ .m. In the 220V AC environment, there will be no short circuit or leakage.
  • the curing oil of the present invention adopts the oil containing silicone oil (generally phenyl silicone oil) as the base oil
  • the curing oil of the present invention can have a better effect on the maintenance of low-voltage and low-power electrical appliances (such as electrical appliances below 12V6W), because Silicone oil has higher resistivity and less signal loss; the harm of electric flashover and electric ablation caused by low-power electrical appliances is small.
  • Metal parts in indirect contact with electrical conductors need to be cured are also based on the reasons stated in 0025.
  • Metal parts that are in indirect contact with the transmission conductor generally do not transmit electrical energy or electrical signals, and mainly serve as supports for support.
  • Example 1 of the present invention Three types of liquid oily contact oils from different manufacturers were randomly purchased in the market for comparative testing with the curing oil obtained in Example 1 of the present invention. Under the same test conditions, in the test of the protective ability of iron, the samples protected by three contact oils have all been rusted, and the samples of the maintenance oil of the present invention have no rust; the test of the protective ability of copper, The curing oil sample of the present invention is better than two of the three contact oils, slightly better than or equal to one of them.
  • the following embodiment 1 is: 1. a circuit breaker, knife switch maintenance oil; 2. in a circuit system, various wiring piles, terminal blocks, wire ends, wire terminals maintenance oil; 3. a circuit board maintenance oil 4. a kind of maintenance oil for electrical equipment; the embodiment of each maintenance oil in the above 4 maintenance oils, that is, the embodiments of each maintenance oil in the above 4 maintenance oils are all the same, all being embodiment 1.
  • embodiment 2 is: A. a kind of maintenance method of circuit breaker, knife switch; B. in a kind of circuit system, the maintenance method of various wiring piles, terminal blocks, wire ends, wire terminals; C. a kind of The maintenance method of circuit board; D. a maintenance method of electrical equipment; the embodiment of each maintenance method in above 4 kinds of maintenance methods. If there is a stated part in the embodiment that exceeds the maintenance scope of a certain maintenance method, then this part is invalid.
  • A is suitable for the statement of a and b and c and e in embodiment 2; B is suitable for the statement of a and c and e in embodiment 2; C is suitable for a and b and c and d and e and in embodiment 2 The statement of f; D is suitable for the statements of a and b and c and d and e and f in Example 2.
  • Example 1 Diisooctyl diphenylamine 1%, 0.5 % thioether-containing polymer phenolic antioxidant, 1.5 % synthetic calcium sulfonate with low base value (T104), benzotriazole fatty acid amine salt (T406 ) 0.2%, barium petroleum sulfonate (T701) 3%, thiadiazole derivatives (T561) 0.05%, zinc naphthenate (T704) 3%, benzotriazole (T706) 0.25%, trimellitic acid Trimellitate (TMT)) 90.5%; the percentages mentioned are all weight percentages; the viscosity of trimellitate (TMT) is 70-75mm2/s at 40°C.
  • Preparation method pour all the ingredients into a blending kettle, stir to 75°C while raising the temperature, fully dissolve the solid ingredients at this temperature and stir the ingredients evenly. Usually, after heating up to 75°C, stir and mix for a few minutes at most; finally cool down to room temperature naturally, and pass through a filter with a pore size of ⁇ 23 microns to obtain this product.
  • Example 2 When needed: 1. Circuit circuit breaker, sword switch switch for maintenance; 2. Various wiring piles, wiring terminals, wire heads, and wire terminals in the circuit system are maintained; 3. Circuit board for maintenance; 4 . Electrical equipment is maintained; when any one of the above 4 items meets the requirements of this specification for metal parts or positions to provide maintenance and protection, a. Use/use the curing oil of the present invention obtained in Example 1 to provide corresponding metal parts or positions Conservation and protection.
  • the method is to smear the curing oil of the present invention on the corresponding parts or parts, and cover the corresponding parts or parts, preferably without dripping; To achieve the level of only wetting and only oil stains at the contacts, so as to reduce the amount of smearing, so as to achieve the effect of providing maintenance and reducing arc generation; c. In contacts that do not need live opening and closing work, such as plugging and unplugging male and female Head/cable, do not need to be wiped dry; d. Another thing to pay attention to is that this product cannot enter the pickup, that is, the microphone, so as to avoid the microphone from being "drowned”; e.
  • the curing oil in this embodiment is resistant to The electric strength is 6kV ⁇ 15%/mm, and the resistivity is 1.5-2.5 ⁇ 107 ⁇ .m. Comply with safe electricity regulations. Before using this product, it must be proved safe and feasible through calculation and experimental methods, so as to avoid breakdown and leakage , short circuit, signal distortion, etc. Due to the large number of electrical appliances, the electrical appliances cannot work normally after normal use of this oil for maintenance of parts, which means that this oil is not suitable for the maintenance of such parts. You can try the mode, which is also the common process of general new product production: try first and then use mode); f. When using this product on the circuit board, it is required that the components on the circuit board are well sealed, especially the capacitor, to avoid damage to the electronic circuit board. The original parameters of the component have an impact.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

The present invention provides a maintenance method and maintenance oil for a circuit breaker and a knife switch, a maintenance method and maintenance oil for various wiring piles, wiring terminals, wire ends and wire terminals in a circuit system, a maintenance method and maintenance oil for a circuit board, and a maintenance method and maintenance oil for an electrical appliance. The common point is that a better formula of the oil comprises a liquid oily substance composed of barium petroleum sulfonate, zinc naphthenate, benzotriazole and a thiadiazole derivative. The viscosity of the maintenance oil at 40°C is greater than or equal to 17 mm2/s. Preferably, base oil used in the maintenance oil is at least one of PAO, TMT and POE. The present invention is particularly suitable for occasions such as wiring piles, wire ends and circuit boards in the field of electrical appliances, which have a plurality of metals needing to be maintained together at the same time, is particularly suitable for the maintenance of copper, aluminum and iron as well as respective alloys thereof, and has the advantages of clear use, good effect, convenient filling and long maintenance time.

Description

一种电路断路器、闸刀开关养护方法及养护油A kind of circuit breaker, knife switch maintenance method and maintenance oil 技术领域technical field
本发明涉及一种电路系统各装置、线材、机构、器具中各种金属的养护方法及养护油,属于防锈润滑油领域。将用作普通机械防锈润滑用的润滑油加以改进再运用于电路接线桩等等的养护当中。The invention relates to a maintenance method and maintenance oil for various metals in various devices, wires, mechanisms and appliances of a circuit system, and belongs to the field of antirust lubricating oil. The lubricating oil used for the anti-rust lubrication of ordinary machinery is improved and then used in the maintenance of circuit wiring piles and the like.
背景技术Background technique
在日常使用大功率电器如电炒锅、电烤箱、电热水器时,由于电流大,通常导线多少都会有温升的情况,此时,断路器或闸刀开并上的导线和接线桩连接处,由于导线绝缘层已剥离,会造成直接与大气接触,即使在有外壳的情况下(如闸刀开关外壳),久而久之,在温度和大气氧气的作用下,电线头、接线桩都会被氧化腐蚀,从而形成高电阻氧化层。这种情况会引起接线部位温度升高,然后再促生更厚的氧化层,然后温升更高。这是个恶性循环过程,最终导致电路器材的烧坏。如果接线桩接线系统得到防护,将会把使用寿命延长。但现实中却很少会有人对接线桩接线系统进行养护,仿佛简单(未加任何养护)地把电线接于接线桩上是件理所应该的事。原因之一为市面上并没有用途这么明确的养护用品,即市面上没有专门用于接线桩一类的专用的养护油,如缺少本发明的一种电路闸刀开关养护油。When using high-power electrical appliances such as electric frying pans, electric ovens, and electric water heaters in daily use, due to the large current, usually the temperature of the wires will rise to some extent. , because the wire insulation layer has been peeled off, it will cause direct contact with the atmosphere, even in the case of a casing (such as a knife switch casing), over time, under the action of temperature and atmospheric oxygen, the wire head and wiring pile will be oxidized and corroded , thus forming a high resistance oxide layer. This situation will cause the temperature of the wiring part to rise, which will then promote the growth of a thicker oxide layer, and then the temperature rise will be higher. This is a vicious circle process that eventually leads to burnout of circuit equipment. If the post wiring system is protected, the service life will be extended. But in reality, few people maintain the wiring system of the wiring pile, as if it is a matter of course to simply (without any maintenance) connect the wires to the wiring pile. One of reason is that there is no such definite maintenance article of purpose on the market, promptly does not have on the market the special-purpose maintenance oil that is specially used in wiring pile class, as lacking a kind of circuit knife switch maintenance oil of the present invention.
一些在室外工作的电器,如监控摄像头,有时需要长期在非常恶劣(高温高湿,如在近地球赤道地区的夏天室外)的环境中工作,此时电路板通常不到一年时间便会粉化锈蚀,电路板上的电子元件不是锈蚀坏了便是焊脚锈蚀断了。而电路板上有铁质的电子元件焊脚,有铜质的导线焊/压接头,有锡材质的焊点等多种不同种类的金属。这就要求养护剂要具有对所有各种不同种类的金属都要有很好的养护作用的要求,并且对电路板电信号没有影响或可以忽略的影响。Some electrical appliances that work outdoors, such as surveillance cameras, sometimes need to work in a very harsh environment (high temperature and high humidity, such as outdoors in summer near the equator of the earth) for a long time. At this time, the circuit board usually powders in less than a year. Corrosion, the electronic components on the circuit board are either corroded or broken, or the solder feet are corroded and broken. On the circuit board, there are iron solder feet of electronic components, copper wire soldering/pressing joints, solder joints of tin material and many other metals. This requires the curing agent to have a good curing effect on all kinds of different metals, and has no or negligible effect on the electrical signal of the circuit board.
在电线接线桩系统(接线桩总成)中,也有多种金属需要同时维护的情况。维护品不能只对某一种金属起保护作用。如在电线接线桩系统中,电线有铝系的铜系的;接线桩有铜系的主体和铁系的压接压紧螺栓。虽然压紧压接螺栓不是直接导电用的,但铁质的螺栓也非常容易氧化生锈,并且铁绣能促进整个接线桩系统的氧化腐蚀过程。所以维护品必须具有对整个接线桩接线系统中可能出现的每种金属都要有很好的保护的功能。所以要求养护品具有对所有种类的金属都有好的养护作用的要求,特别是铜、铝、铁,以及他们各自的合金。市面上用于电器具领域养护的液体油状的防护品对多种不同种类的金属的防护能力有限。In the wire terminal system (terminal terminal assembly), there are also cases where multiple metals need to be maintained at the same time. Maintenance products cannot only protect a certain metal. For example, in the wiring pile system, the wires are aluminum-based and copper-based; the wiring pile has a copper-based main body and iron-based crimping and compression bolts. Although the crimping bolts are not directly conductive, iron bolts are also very easy to oxidize and rust, and iron embroidery can promote the oxidation and corrosion process of the entire wiring pile system. Therefore, maintenance products must have a good protection function for every metal that may appear in the entire wiring pile wiring system. Therefore, the maintenance products are required to have a good maintenance effect on all kinds of metals, especially copper, aluminum, iron, and their respective alloys. The liquid and oily protective products on the market for maintenance of electrical appliances have limited protection against many different types of metals.
电路器材还要求尽可能低的维护次数,终身免维护是追求的目标。如室外监控摄像机、漏电保护器等等,单单维护一次就非常繁琐:得爬高、拆解等等一系列工作,所以需要尽量避免。Circuit equipment also requires as low maintenance times as possible, and life-long maintenance-free is the goal pursued. For example, outdoor surveillance cameras, leakage protectors, etc., it is very cumbersome to maintain only once: a series of tasks such as climbing, dismantling, etc., so it needs to be avoided as much as possible.
传统中一个方法是使用多用途除锈松动油剂(如WD-40)进行养护,但此类油养护时间短,一个月时长左右就挥发完了,并且此类油对各种金属的养护能力不足,这些问题至少在本发明申请日之前是这样的。本发明养护油可以采用合成油TMT、POE中至少一种作为养护油的基础油,能极大地减少维护次数,尽可能地达到终身免维护的目标。A traditional method is to use a multi-purpose rust-removing and loosening oil agent (such as WD-40) for maintenance, but this type of oil has a short curing time and evaporates in about a month, and this type of oil has insufficient maintenance ability for various metals , these problems were at least prior to the filing date of the present invention. The maintenance oil of the present invention can use at least one of synthetic oil TMT and POE as the base oil of the maintenance oil, which can greatly reduce the number of maintenance and achieve the goal of life-long maintenance-free as much as possible.
还有一个通常的作法是采用涂抹凡士林的方法对线头和接线桩进行防护,但单纯的凡士林对金属的防护能力有限;凡士林是脂状的,加注不方便。Also having a common practice is to adopt the method for smearing vaseline to protect thread ends and wiring posts, but pure vaseline has limited protective ability to metal; vaseline is greasy, and filling is inconvenient.
另一个方法是考虑使用市面上液体油状的触点养护油进行养护。顾名思义,触点养护油主要为电触点两触头处进行维护,即重点为铜系和银系进行维护,一些此类油虽然养护时间稍长,但仍然没有达到对多种金属都有较好养护能力的水平;触点油粘度低,只注重清洁清洗作用;触点油说明书中没有明确的说明可以用于接线桩接线系统的养护,即产品说明书中没有明确的说明触点油可以用作接线桩接线系统养护的用途,让人无所适从。另一方面,日常生活中常用的电器大部份是不需要电触点带电经常断合工作的电器具,即触点油在日常使用中不是必备的,他更多的只是工业用品。Another method is to consider using liquid oily contact maintenance oil on the market for maintenance. As the name implies, the contact maintenance oil is mainly used for the maintenance of the two contacts of the electrical contacts, that is, the focus is on the maintenance of copper and silver systems. Although some such oils have a slightly longer curing time, they still have not reached the level of protection for various metals. Good level of maintenance ability; contact oil viscosity is low, only focus on cleaning and cleaning; there is no clear statement in the contact oil manual that it can be used for the maintenance of the wiring pile wiring system, that is, there is no clear statement in the product manual that the contact oil can be used It is confusing to use it for the maintenance of wiring pile wiring system. On the other hand, most of the electrical appliances commonly used in daily life are electrical appliances that do not require electrical contacts to be live and frequently broken and closed. That is, contact oil is not necessary in daily use, and it is more of an industrial product.
技术解决方案technical solution
为了解决背景技术中出现的问题或改进的需要,本发明提供了一种电路断路器、闸刀开关养护方法及养护油,能对电路系统各电器、电器器材中各种金属都具有很好的养护作用,特别是铜、铝、铁,以及他们各自的合金。可以提供较长寿命的养护。能对电器器材或电器器具上的插头(公或母)、电子元件焊脚(已焊的或未焊的)、接线桩、电线头、插排(公或母)、锡焊点、导线或金属熔焊点、金属铰接处、甚至电器器材或电器器具上的各种固定紧固金属件如金属螺钉等等各种金属进行养护。In order to solve the problems or improvement needs in the background technology, the present invention provides a circuit breaker, a knife switch maintenance method and maintenance oil, which can have a good effect on various metals in the electrical appliances and electrical equipment of the circuit system. Conservation, especially for copper, aluminum, iron, and their respective alloys. Can provide long-life conservation. It can be used for plugs (male or female), solder feet of electronic components (soldered or unsoldered), wiring piles, wire heads, sockets (male or female), solder joints, wires or plugs on electrical equipment or electrical appliances. Metal welding spots, metal hinges, and even various fixing and fastening metal parts on electrical appliances or electrical appliances such as metal screws and other metals for maintenance.
本发明所称“养护油”也可以称为维护油、防护油、保养油、防锈油中的任意一种。The "maintenance oil" referred to in the present invention can also be referred to as any one of maintenance oil, protective oil, maintenance oil and anti-rust oil.
本发明目的是通过如下技术方案实现的。The object of the present invention is achieved through the following technical solutions.
一种电路断路器、闸刀开关养护油,其配方中包含(石油磺酸钡、合成磺酸钡、二任基萘磺酸钡、重烷基苯磺酸钡、N-油酸基肌氨酸十八胺盐其中之一)和(环烷酸锌、十二烯基丁二酸、烯基丁二酸酯、2-氨乙基十七烯基咪唑啉十二烯基丁二酸盐、油酸十八烷胺、十七烯基咪唑啉烯基丁二酸盐、环烷酸锌和十七烯基咪唑啉烯基丁二酸盐的混合物、烷基磷酸咪唑啉盐其中之一)和(润滑油用油溶性铜及铜合金防锈剂其中之一)所组成的一种液体油状物;所述铜及铜合金防锈剂包括苯骈三氮唑、苯骈三氮唑脂肪酸胺盐、甲基苯骈三氮唑、巯基苯骈噻唑、甲基苯骈三氮唑和巯基苯骈噻唑的混合物、苯骈三氮唑十八胺、苯骈三氮唑二环已胺、N-乙酰基苯骈三氮唑;本养护油在40°C时的粘度为≥17mm²/s;所述电路断路器、闸刀开关养护油不仅仅指的是电路断路器、闸刀开关上的接线桩、电线裸导线头,而指的是在电路断路器、闸刀开关正常工作状态时电路断路器、闸刀开关上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护的养护油;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A kind of circuit breaker, knife switch maintenance oil, its formula contains (petroleum sulfonate barium, synthetic barium sulfonate, two free naphthalene sulfonate barium, heavy alkylbenzene sulfonate barium, N-oleic acid group sarcosine one of octadecylamine salts) and (zinc naphthenate, dodecenyl succinate, enyl succinate, 2-aminoethyl heptadecenyl imidazolinium dodecenyl succinate , octadecylamine oleate, heptadecenyl imidazolidinyl succinate, a mixture of zinc naphthenate and heptadecenyl imidazolidinyl succinate, one of imidazolinium alkyl phosphate ) and (one of the oil-soluble copper and copper alloy antirust agents for lubricating oil); the copper and copper alloy antirust agents include benzotriazole, benzotriazole fatty acid Amine salt, tolyltriazole, mercaptobenzothiazole, mixture of tolyltriazole and mercaptobenzothiazole, benzotriazole octadecylamine, benzotriazole dicyclohexylamine, N-acetyl benzotriazole; the viscosity of this curing oil at 40°C is ≥17mm²/s; the circuit breaker and knife switch maintenance oil does not only refer to the circuit breaker and knife switch It refers to all kinds of metal parts on the circuit breaker and knife switch that are in contact with the metal conductors that transmit electric energy or electrical signals when the circuit breaker and knife switch are in normal working condition. At least one of the parts or more than one position, or the maintenance of the metal conductor itself that transmits electrical energy or electrical signals, including the maintenance oil for the maintenance of bare wire ends; the metal parts, including the installation tights made of metal Firmware; the installation fasteners include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include metal conductors that are in indirect contact with metal conductors that transmit electrical energy or electrical signals When parts are in indirect contact, the metal in indirect contact refers to the metal with a resistance between the indirect contact metal and the metal conductor between ≥0Ω and ≤1000Ω.
优选地,此养护油在0012的基础上,增加了成分:润滑油用油溶性金属钝化剂其中之一;所述钝化剂包括苯三唑衍生物、噻二唑衍生物。Preferably, on the basis of 0012, this maintenance oil has an added component: one of the oil-soluble metal deactivators for lubricating oil; the deactivators include benzotriazole derivatives and thiadiazole derivatives.
优选地,0012或0013所述养护油的基础油为PAO、TMT、POE中的至少1种。Preferably, the base oil of the maintenance oil described in 0012 or 0013 is at least one of PAO, TMT, and POE.
一种电路断路器、闸刀开关的养护方法:使用0012、0013、0014其中之一所述的养护油,对在电路断路器、闸刀开关正常工作状态时电路断路器、闸刀开关上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A maintenance method for a circuit breaker and a knife switch: use the maintenance oil described in one of 0012, 0013, and 0014 to treat the circuit breaker and the knife switch when the circuit breaker and the knife switch are in normal working condition. At least one of the parts or more than one position of all the various metal parts that are in contact with the metal conductors that transmit electric energy or signals, or the maintenance of the metal conductors that transmit electric energy or signals, including the maintenance of bare wire ends Maintenance; the metal parts include metal mounting fasteners; the installation fasteners include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include Metal conductors that transmit electrical energy or electrical signals have indirect contact metal parts. In indirect contact, indirect contact metals refer to metals with a resistance between the indirect contact metal and the metal conductor that is ≥0Ω and ≤1000Ω.
一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护油,其同0012或0013或0014,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电路系统中,各种接线桩、接线端子、电线头、电线端子”。In a circuit system, the maintenance oil for various wiring piles, wiring terminals, wire heads, and wire terminals is the same as 0012 or 0013 or 0014, the difference is that the name "circuit breaker, knife switch" is changed to "circuit In the system, various wiring piles, terminal blocks, wire heads, and wire terminals".
一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护方法:使用0016的养护油,对在电路系统中,各种接线桩、接线端子、电线头、电线端子正常工作状态时电路系统中各种接线桩、接线端子、电线头、电线端子上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A maintenance method for various wiring piles, wiring terminals, wire heads, and wire terminals in a circuit system: use 0016 curing oil to ensure that various wiring piles, wiring terminals, wire heads, and wire terminals work normally in the circuit system At least one part or more than one position of all the various metal parts in the circuit system in the circuit system in contact with the metal conductors that transmit electric energy or signals, or The maintenance of the metal conductor itself that transmits electric energy or electrical signals includes the maintenance of the bare wire end of the wire; the metal parts include metal mounting fasteners; the mounting fasteners include bolts, screws, and nuts; The maintenance refers to anti-corrosion maintenance; the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. The metal between the metal conductors has a resistance between ≥0Ω and ≤1000Ω.
一种电路板养护油,同0012或0013或0014,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电路板”。A circuit board maintenance oil, the same as 0012 or 0013 or 0014, the only difference is that the name "circuit breaker, knife switch" is changed to "circuit board".
一种电路板养护方法:使用0018所述的养护油,对在电路板正常工作状态时电路板上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A circuit board maintenance method: use the maintenance oil described in 0018 to treat at least one of all the various metal parts on the circuit board that are in contact with the metal conductors that transmit electric energy or electric signals when the circuit board is in normal working condition or more than one location, or to maintain the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of bare wire leads; the metal parts include metal mounting fasteners; the mounting fasteners, Including bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. It refers to the metal between the indirect contact metal and the metal conductor with a resistance between ≥0Ω and ≤1000Ω.
一种电器器材养护油,同0012或0013或0014,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电器器材”;所述电器器材养护油,包括对分立的电器器材元件的养护的养护油;所述电器器材养护油,不包括对化学电能存储装置内部各部份进行养护的养护油。An electrical equipment maintenance oil, the same as 0012 or 0013 or 0014, the only difference is that the name "circuit breaker, knife switch" is changed to "electrical equipment"; the electrical equipment maintenance oil includes the components for discrete electrical equipment The maintenance oil for maintenance; the maintenance oil for electrical equipment does not include the maintenance oil for the maintenance of various parts inside the chemical electric energy storage device.
一种电器器材养护方法:使用0020所述的养护油,对在电器器材正常工作状态时电器器材上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属;所述电器器材养护,包括对分立的电器器材元件的养护;所述电器器材养护,不包括对化学电能存储装置内部各部份的养护。A maintenance method for electrical equipment: use the maintenance oil described in subparagraph 0020 to treat at least one of all the various metal parts on the electrical equipment that are in contact with the metal conductors that transmit electrical energy or electrical signals when the electrical equipment is in normal working condition or more than one location, or to maintain the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of bare wire leads; the metal parts include metal mounting fasteners; the mounting fasteners, Including bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. Refers to metals in indirect contact with metals and metal conductors with a resistance between ≥0Ω and ≤1000Ω; the maintenance of electrical equipment includes the maintenance of discrete electrical equipment components; the maintenance of electrical equipment does not include maintenance of chemical electrical energy Maintenance of various parts inside the storage device.
有益效果Beneficial effect
本发明最初设计是用于家庭220V交流电的电闸刀开关接线桩上全部各种金属的养护。具有维护寿命长,减少维护次数;对各种金属都具有很好的养护作用;延长电器具使用寿命;绝缘体,使用安全,耐电强度为一般为6kV±15%/mm左右,通电1000V直流电情况下一般测得电阻率为1.5-2.5×10⁷Ω.m左右,在220V交流电使用环境下,丝毫不会发生短路、漏电的情况,非常适合500V以下各种交直流电器具/材的养护;使用方便;对锡焊等焊接工艺无影响;用途较明确;本发明也能在电路板、插头插座等其他领域发挥很好的防锈防腐效果。The present invention is originally designed to be used for the maintenance of all kinds of metals on the electric knife switch wiring pile of the household 220V alternating current. It has a long maintenance life and reduces the number of maintenance; it has a good maintenance effect on various metals; it prolongs the service life of electrical appliances; the insulator is safe to use, and the electric strength is generally about 6kV±15%/mm, and it is energized with 1000V DC Generally, the measured resistivity is about 1.5-2.5×10⁷Ω.m. In the 220V AC environment, there will be no short circuit or leakage. It is very suitable for the maintenance of various AC and DC electrical appliances/materials below 500V; easy to use; It has no influence on welding processes such as soldering; the application is relatively clear; the present invention can also exert good antirust and anticorrosion effects in other fields such as circuit boards, plugs and sockets.
实际案例中,在室外高温高湿环境下工作的采用12V供电的监控摄像机,电路板在没有涂抹本发明养护油时,不到一年时间电路板元件及焊脚、焊点处便粉化腐蚀了;而电路板在涂抹本发明养护油只一次后,摄像机连续使用三年,电路板仍然未见粉化锈蚀现象,期间监控摄像机工作正常,未见信号有失真情况。唯一注意之处为拾音器(咪头)不能渗入本养护油,会发生把咪头淹死的情况,造成咪头不工作和失灵。另一个实际案例是,家用电闸刀开关在未涂抹本发明养护油进行养护时,通常只使用半年就烧坏了;而只涂抹过一次本发明养护油进行养护过的闸刀开关,连续使用几年仍然可以正常使用。In an actual case, when the surveillance camera using 12V power supply works in an outdoor high-temperature and high-humidity environment, when the circuit board is not coated with the curing oil of the present invention, the circuit board components, solder feet, and solder joints will be pulverized and corroded in less than a year. And the circuit board is only once after smearing the maintenance oil of the present invention, and the camera has been used continuously for three years, and the circuit board still has no pulverization and corrosion phenomenon. During this period, the monitoring camera works normally, and there is no signal distortion. The only thing to pay attention to is that the pickup (microphone) cannot penetrate into the curing oil, otherwise the microphone will be drowned, resulting in the microphone not working and malfunctioning. Another actual case is that when the household electric switch switch is not smeared with the curing oil of the present invention for maintenance, it usually burns out after only half a year of use; while the switch switch that has only been smeared with the curing oil of the present invention for maintenance once, it is used continuously for several days. Years can still be used normally.
当本发明养护油采用含有硅油(一般为苯基硅油)的油作为基础油时,本发明养护油能对低电压和小功率电器具(如12V6W以下电器具)的养护产生较好作用,因为硅油电阻率更大,信号损失小;小功率电器具产生电跳火和电烧蚀的危害性小。When the curing oil of the present invention adopts the oil containing silicone oil (generally phenyl silicone oil) as the base oil, the curing oil of the present invention can have a better effect on the maintenance of low-voltage and low-power electrical appliances (such as electrical appliances below 12V6W), because Silicone oil has higher resistivity and less signal loss; the harm of electric flashover and electric ablation caused by low-power electrical appliances is small.
接线桩上通常会有铁质的压紧导线的螺丝,此铁质螺丝如果用一般防锈油作防腐蚀养护时,由于一般防锈油成份不明,甚至有硬膜剂成份在内,一经涂抹,由于与输电导体相接触,会流入接线桩甚它部位中,造成接触不良等现象。所以养护此类部位时,要求一并用专用养护油对与输电导体相接触的全部金属都进行养护。如采用本发明养护油进行养护,会避免以上问题。There are usually iron screws that compress the wires on the wiring posts. If the iron screws are used for anti-corrosion maintenance with general anti-rust oil, the composition of the general anti-rust oil is unknown, and even contains hard film ingredients. , due to contact with the transmission conductor, it will flow into the wiring pile or even other parts, resulting in poor contact and other phenomena. Therefore, when maintaining such parts, it is required to use special curing oil to maintain all the metals in contact with the transmission conductor. If adopt curing oil of the present invention to carry out maintenance, can avoid above problem.
对于为何需要对与输电导体有间接接触的金属进行养护,一样基于0025所述理由。与输电导体有间接接触的金属件一般不传输电能或电信号,主要作为支座起支撑作用。The reasons why metals in indirect contact with electrical conductors need to be cured are also based on the reasons stated in 0025. Metal parts that are in indirect contact with the transmission conductor generally do not transmit electrical energy or electrical signals, and mainly serve as supports for support.
在市面上随意购买三款不同厂家的液体油状触点油,用于与本发明实施例1所得养护油作对比测试。在同等测试条件下,在对铁质的防护能力测试中,三款触点油防护的试样均已生锈,本发明养护油的试样未见生锈;对铜质防护能力的测试,本发明养护油试样好于三款触点油中的二款,稍好于或持平其中一款。Three types of liquid oily contact oils from different manufacturers were randomly purchased in the market for comparative testing with the curing oil obtained in Example 1 of the present invention. Under the same test conditions, in the test of the protective ability of iron, the samples protected by three contact oils have all been rusted, and the samples of the maintenance oil of the present invention have no rust; the test of the protective ability of copper, The curing oil sample of the present invention is better than two of the three contact oils, slightly better than or equal to one of them.
本发明的实施方式Embodiments of the present invention
以下所述实施例,仅是对本发明较佳具体实施例已,并非对本发明作其他形式的限制。The embodiments described below are only preferred specific embodiments of the present invention, and are not intended to limit the present invention in other forms.
以下实施例1为:①一种电路断路器、闸刀开关养护油;②一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护油;③一种电路板养护油;④一种电器器材养护油;以上4款养护油中每款养护油的实施例,即以上4款养护油中每款养护油的实施例都一样,都为实施例1。The following embodiment 1 is: 1. a circuit breaker, knife switch maintenance oil; 2. in a circuit system, various wiring piles, terminal blocks, wire ends, wire terminals maintenance oil; 3. a circuit board maintenance oil 4. a kind of maintenance oil for electrical equipment; the embodiment of each maintenance oil in the above 4 maintenance oils, that is, the embodiments of each maintenance oil in the above 4 maintenance oils are all the same, all being embodiment 1.
以下实施例2为:A.一种电路断路器、闸刀开关的养护方法;B.一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护方法;C.一种电路板的养护方法;D.一种电器器材的养护方法;以上4种养护方法中每种养护方法的实施例。如实施例中有超出某一项养护方法的养护范围的陈述部份,则这部份无效。如A为适合实施例2中a和b和c和e的陈述;B为适合实施例2中a和c和e的陈述;C为适合实施例2中a和b和c和d和e和f的陈述;D为适合实施例2中a和b和c和d和e和f的陈述。Following embodiment 2 is: A. a kind of maintenance method of circuit breaker, knife switch; B. in a kind of circuit system, the maintenance method of various wiring piles, terminal blocks, wire ends, wire terminals; C. a kind of The maintenance method of circuit board; D. a maintenance method of electrical equipment; the embodiment of each maintenance method in above 4 kinds of maintenance methods. If there is a stated part in the embodiment that exceeds the maintenance scope of a certain maintenance method, then this part is invalid. Such as A is suitable for the statement of a and b and c and e in embodiment 2; B is suitable for the statement of a and c and e in embodiment 2; C is suitable for a and b and c and d and e and in embodiment 2 The statement of f; D is suitable for the statements of a and b and c and d and e and f in Example 2.
实施例1:                                                                                                                                                   二异辛基二苯胺1%、含硫醚基高分子酚类抗氧剂0.5%、低碱值合成磺酸钙(T104)1.5%、苯骈三氮唑脂肪酸胺盐(T406)0.2%、石油磺酸钡(T701)3%、噻二唑衍生物(T561)0.05%、环烷酸锌(T704)3%、苯骈三氮唑(T706)0.25%、偏苯三酸酯(TMT))90.5%;所述百分比均为重量百分比;偏苯三酸酯(TMT)的粘度是40°C时为70-75mm²/s。制备方法:将全部各成份倒入调合釜中,边升温边搅拌至75°C,在此温度下充分溶解固体成份和搅拌均匀各成份。通常升温至75℃之后最多再搅拌混合几分钟即可;最后自然冷却到室温,过孔径≤23微米滤网即得本品。Example 1:                                                                                                                                                                                                                    Diisooctyl diphenylamine 1%, 0.5 % thioether-containing polymer phenolic antioxidant, 1.5 % synthetic calcium sulfonate with low base value (T104), benzotriazole fatty acid amine salt (T406 ) 0.2%, barium petroleum sulfonate (T701) 3%, thiadiazole derivatives (T561) 0.05%, zinc naphthenate (T704) 3%, benzotriazole (T706) 0.25%, trimellitic acid Trimellitate (TMT)) 90.5%; the percentages mentioned are all weight percentages; the viscosity of trimellitate (TMT) is 70-75mm²/s at 40°C. Preparation method: Pour all the ingredients into a blending kettle, stir to 75°C while raising the temperature, fully dissolve the solid ingredients at this temperature and stir the ingredients evenly. Usually, after heating up to 75°C, stir and mix for a few minutes at most; finally cool down to room temperature naturally, and pass through a filter with a pore size of ≤23 microns to obtain this product.
实施例2:                                                                                                                                                   当在需要向:①.电路断路器、闸刀开关进行养护;②.电路系统中各种接线桩、接线端子、电线头、电线端子进行养护;③.电路板进行养护;④.电器器材进行养护;以上4项中任意一符合本说明书所规定的金属零件或部位提供养护保护时,a.使用/运用实施例1所制得的本发明养护油对相应金属零件或部位提供养护保护。方法为在相应零件或部位涂抹本发明养护油,覆盖相应零件或部位,以不滴淌为宜;b.需要带电开合工作的触点,在涂抹本养护油后,需要再抹干,以达到在触点处只润湿、只产生油渍的水平,达到减少涂抹量,以便达到既可以提供养护又可以减少电弧产生的效果;c.在无需带电开合工作的接点,如插拔公母头/排线,则不需抹干处理;d.另一个需要注意之处为,本品不能进入到拾音器即咪头内,避免咪头被“淹死”;e.本实施例养护油耐电强度为6kV±15%/mm,电阻率为1.5-2.5×10⁷Ω.m,遵守安全用电规程,使用本品前需经过计算和实验方法证明安全可行方可使用,避免产生击穿、漏电、短路、信号失真、等情况。由于电器众多,零部件在正常使用本油养护后电器不能正常工作,则说明本油不适用于此类零部件的养护,此时本发明养护油发挥的只是提供一种养护方案选择项功能(可试一试模式,这个也是一般新品生产的普通工艺:先试后用模式);f.在电路板上使用本品时,要求电路板上各元件密封性良好,特别是电容,避免对电子元件原本参数产生影响。Example 2: When needed: ①. Circuit circuit breaker, sword switch switch for maintenance; ②. Various wiring piles, wiring terminals, wire heads, and wire terminals in the circuit system are maintained; ③. Circuit board for maintenance; ④ . Electrical equipment is maintained; when any one of the above 4 items meets the requirements of this specification for metal parts or positions to provide maintenance and protection, a. Use/use the curing oil of the present invention obtained in Example 1 to provide corresponding metal parts or positions Conservation and protection. The method is to smear the curing oil of the present invention on the corresponding parts or parts, and cover the corresponding parts or parts, preferably without dripping; To achieve the level of only wetting and only oil stains at the contacts, so as to reduce the amount of smearing, so as to achieve the effect of providing maintenance and reducing arc generation; c. In contacts that do not need live opening and closing work, such as plugging and unplugging male and female Head/cable, do not need to be wiped dry; d. Another thing to pay attention to is that this product cannot enter the pickup, that is, the microphone, so as to avoid the microphone from being "drowned"; e. The curing oil in this embodiment is resistant to The electric strength is 6kV±15%/mm, and the resistivity is 1.5-2.5×10⁷Ω.m. Comply with safe electricity regulations. Before using this product, it must be proved safe and feasible through calculation and experimental methods, so as to avoid breakdown and leakage , short circuit, signal distortion, etc. Due to the large number of electrical appliances, the electrical appliances cannot work normally after normal use of this oil for maintenance of parts, which means that this oil is not suitable for the maintenance of such parts. You can try the mode, which is also the common process of general new product production: try first and then use mode); f. When using this product on the circuit board, it is required that the components on the circuit board are well sealed, especially the capacitor, to avoid damage to the electronic circuit board. The original parameters of the component have an impact.

Claims (10)

  1. 一种电路断路器、闸刀开关养护油,其特征在于,其配方中包含(石油磺酸钡、合成磺酸钡、二任基萘磺酸钡、重烷基苯磺酸钡、N-油酸基肌氨酸十八胺盐其中之一)和(环烷酸锌、十二烯基丁二酸、烯基丁二酸酯、2-氨乙基十七烯基咪唑啉十二烯基丁二酸盐、油酸十八烷胺、十七烯基咪唑啉烯基丁二酸盐、环烷酸锌和十七烯基咪唑啉烯基丁二酸盐的混合物、烷基磷酸咪唑啉盐其中之一)和(润滑油用油溶性铜及铜合金防锈剂其中之一)所组成的一种液体油状物;所述铜及铜合金防锈剂包括苯骈三氮唑、苯骈三氮唑脂肪酸胺盐、甲基苯骈三氮唑、巯基苯骈噻唑、甲基苯骈三氮唑和巯基苯骈噻唑的混合物、苯骈三氮唑十八胺、苯骈三氮唑二环已胺、N-乙酰基苯骈三氮唑;本养护油在40°C时的粘度为≥17mm²/s;所述电路断路器、闸刀开关养护油不仅仅指的是电路断路器、闸刀开关上的接线桩、电线裸导线头,而指的是在电路断路器、闸刀开关正常工作状态时电路断路器、闸刀开关上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护的养护油,包括对电线裸导线头进行养护的养护油;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A kind of circuit breaker, knife switch maintenance oil, it is characterized in that, its formula contains (petroleum sulfonate barium, synthetic barium sulfonate, two radical naphthalene sulfonate barium, heavy alkylbenzene sulfonate barium, N-oil One of the octadecylamine salts of acid group sarcosine) and (zinc naphthenate, dodecenyl succinate, alkenyl succinate, 2-aminoethyl heptadecenyl imidazolinium dodecenyl Succinate, octadecylamine oleate, heptadecenyl imidazolinenyl succinate, mixture of zinc naphthenate and heptadecenyl imidazolinenyl succinate, imidazoline alkyl phosphate salt) and (one of the oil-soluble copper and copper alloy antirust agents for lubricating oil); the copper and copper alloy antirust agents include benzotriazole, benzotriazole Triazole fatty acid amine salt, tolyltriazole, mercaptobenzothiazole, mixture of tolyltriazole and mercaptobenzothiazole, benzotriazole octadecylamine, benzotriazole di Cyclohexylamine, N-acetyl benzotriazole; the viscosity of this maintenance oil at 40°C is ≥17mm²/s; the maintenance oil for circuit breakers and knife switches not only refers to circuit breakers, The wiring piles and bare wire ends on the knife switch refer to all metal conductors on the circuit breaker and knife switch that are in contact with the metal conductors that transmit electric energy or electrical signals when the circuit breaker and knife switch are in normal operation. At least one part or more than one position of various metal parts, or the curing oil for curing the metal conductor itself that transmits electric energy or electrical signals, including the curing oil for curing the bare wire ends of electric wires; the metal parts , including installation fasteners made of metal; the installation fasteners include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; Metal conductors have metal parts that are in indirect contact. In indirect contact, the indirect contact metal refers to the metal with a resistance between the indirect contact metal and the metal conductor with a resistance between ≥ 0Ω and ≤ 1000Ω.
  2. 根据权利要求1所述一种电路断路器、闸刀开关养护油,其特征在于,同权利要求1,区别是增加了成分:润滑油用油溶性金属钝化剂其中之一;所述钝化剂包括苯三唑衍生物、噻二唑衍生物。According to claim 1, a maintenance oil for circuit breakers and knife switches is characterized in that, the same as claim 1, the difference is that the composition is added: one of the oil-soluble metal passivators for lubricating oil; the passivation Agents include benzotriazole derivatives, thiadiazole derivatives.
  3. 根据权利要求1或2所述的一种电路断路器、闸刀开关养护油,其特征在于,本养护油基础油为PAO、TMT、POE中的至少1种。A maintenance oil for circuit breakers and knife switches according to claim 1 or 2, characterized in that the base oil of the maintenance oil is at least one of PAO, TMT and POE.
  4. 一种电路断路器、闸刀开关的养护方法,其特征在于,使用权利要求1至3其中之一所述的养护油,对在电路断路器、闸刀开关正常工作状态时电路断路器、闸刀开关上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A maintenance method for a circuit breaker and a knife switch, characterized in that the maintenance oil described in any one of claims 1 to 3 is used to protect the circuit breaker and the switch when the circuit breaker and the knife switch are in normal working condition. At least one of the various metal parts on the knife switch that is in contact with the metal conductors that transmit electrical energy or electrical signals or at least one position, or the maintenance of the metal conductors that transmit electrical energy or electrical signals, including wires The bare wire head is maintained; the metal parts include metal installation fasteners; the installation fasteners include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal Parts include metal parts that are in indirect contact with metal conductors that transmit electrical energy or electrical signals. In indirect contact, the indirect contact metal refers to the metal with a resistance between the indirect contact metal and the metal conductor that is ≥0Ω and ≤1000Ω.
  5. 一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护油,其特征在于,同权利要求1或2或3,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电路系统中,各种接线桩、接线端子、电线头、电线端子”。In a circuit system, the maintenance oil for various wiring piles, wiring terminals, wire heads, and wire terminals is characterized in that it is the same as claim 1 or 2 or 3, and the difference is only that the name "circuit breaker, knife switch" , changed to "in the circuit system, various wiring posts, terminal blocks, wire heads, and wire terminals".
  6. 一种电路系统中,各种接线桩、接线端子、电线头、电线端子的养护方法,其特征在于,使用权利要求5的养护油,对在电路系统中,各种接线桩、接线端子、电线头、电线端子正常工作状态时电路系统中各种接线桩、接线端子、电线头、电线端子上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A maintenance method for various wiring posts, wiring terminals, wire ends, and wire terminals in a circuit system, characterized in that the maintenance oil of claim 5 is used to prevent various wiring posts, wiring terminals, and wires from being used in the circuit system. At least one of all the various metal parts on the various wiring posts, terminal blocks, wire heads, and wire terminals in the circuit system that are in contact with the metal conductors that transmit electrical energy or electrical signals or More than one location, or the maintenance of the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of the bare lead of the wire; the metal parts include metal mounting fasteners; the mounting fasteners include Bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts mentioned above include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. The most important is the metal between the indirect contact metal and the metal conductor with a resistance between ≥ 0Ω and ≤ 1000Ω.
  7. 一种电路板养护油,其特征在于,同权利要求1或2或3,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电路板”。A circuit board maintenance oil is characterized in that it is the same as claim 1 or 2 or 3, and the difference is only that the name "circuit breaker, knife switch" is changed to "circuit board".
  8. 一种电路板养护方法,其特征在于,使用权利要求7的养护油,对在电路板正常工作状态时电路板上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属。A circuit board maintenance method, characterized in that, using the maintenance oil according to claim 7, at least one of all the various metal parts on the circuit board that are in contact with the metal conductors that transmit electric energy or electric signals when the circuit board is in normal operation One of a kind of parts or more than one position, or the maintenance of the metal conductor itself that transmits electric energy or electrical signals, including the maintenance of bare wire ends of electric wires; the metal parts include metal mounting fasteners; the installation Fasteners include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or electrical signals. The metal in indirect contact refers to the metal with the resistance between the indirect contact metal and the metal conductor between ≥0Ω and ≤1000Ω.
  9. 一种电器器材养护油,其特征在于,同权利要求1或2或3,区别仅仅是把名称“电路断路器、闸刀开关”,改为“电器器材”;所述电器器材养护油,包括对分立的电器器材元件的养护的养护油;所述电器器材养护油,不包括对化学电能存储装置内部各部份进行养护的养护油。An electrical equipment maintenance oil, characterized in that it is the same as claim 1 or 2 or 3, the difference is only that the name "circuit breaker, knife switch" is changed to "electrical equipment"; the electrical equipment maintenance oil includes The maintenance oil for the maintenance of discrete electrical equipment components; the maintenance oil for electrical equipment does not include the maintenance oil for the internal parts of the chemical electric energy storage device.
  10. 一种电器器材养护方法,其特征在于,利用权利要求9所述的养护油,对在电器器材正常工作状态时电器器材上与输送电能或电信号的金属导体相接触的所有各种金属零件中至少其中之一种零件或一处位置以上,或对输送电能或电信号的金属导体本身进行养护,包括对电线裸导线头进行养护;所述金属零件,包括金属材质的安装紧固件;所述安装紧固件,包括螺栓、螺钉、螺母;所述养护,指的是防腐蚀养护;所述各种金属零件,包括与输送电能或电信号的金属导体有间接接触的金属零件,间接接触时,间接接触的金属指的是间接接触金属与金属导体之间电阻为≥0Ω而≤1000Ω之间的金属;所述电器器材养护,包括对分立的电器器材元件的养护;所述电器器材养护,不包括对化学电能存储装置内部各部份的养护。A maintenance method for electrical equipment, characterized in that the maintenance oil described in claim 9 is used to treat all metal parts on the electrical equipment that are in contact with metal conductors that transmit electric energy or electrical signals when the electrical equipment is in normal operation. At least one of the parts or more than one position, or the maintenance of the metal conductor itself that transmits electrical energy or electrical signals, including the maintenance of the bare wire head of the wire; the metal parts include metal mounting fasteners; all The installation fasteners mentioned above include bolts, screws, and nuts; the maintenance refers to anti-corrosion maintenance; the various metal parts include metal parts that are in indirect contact with metal conductors that transmit electric energy or In this case, the metal in indirect contact refers to the metal with a resistance between the indirect contact metal and the metal conductor between ≥0Ω and ≤1000Ω; the maintenance of electrical equipment includes the maintenance of discrete electrical equipment components; the maintenance of electrical equipment , does not include the maintenance of various parts inside the chemical electrical energy storage device.
PCT/CN2023/073628 2022-01-25 2023-01-28 Maintenance method and maintenance oil for circuit breaker and knife switch WO2023143543A1 (en)

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CN102206531A (en) * 2010-03-31 2011-10-05 比亚迪股份有限公司 Rust preventive oil and preparation method thereof
CN105038920A (en) * 2015-06-24 2015-11-11 李云军 Method for manufacturing antirust oil of instrument
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