CN1150171A - Multipurpose metal surface caring agent and preparing process thereof - Google Patents
Multipurpose metal surface caring agent and preparing process thereof Download PDFInfo
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- CN1150171A CN1150171A CN 95108888 CN95108888A CN1150171A CN 1150171 A CN1150171 A CN 1150171A CN 95108888 CN95108888 CN 95108888 CN 95108888 A CN95108888 A CN 95108888A CN 1150171 A CN1150171 A CN 1150171A
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- sulfonate
- metal surface
- barium mahogany
- sodium sulfonate
- petroleum sodium
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Lubricants (AREA)
Abstract
A multipurpose protecting agent for metal surface is prepared from petroleum products such as No.3 jet fuel and N32 mechine oil, and additives including berium petrosulfonate, sodium petrosulfonate, benzotriazole, oleic acid, dodecene butanedioic acid and tributyl phosphate, and integrates antirust, lubricating, dehumidifying, penetrating, cleaning and electric insulating functions into one whole.
Description
The present invention relates to a kind of is no fat non-silicon kind equipment maintaining agent and the fault eliminant that main raw material is aided with multiple additives with the deep processing petroleum product.
Continuous progress along with science and technology, mechanical means in all trades and professions also becomes increasingly complex, and along with increase its duration of service, mechanical means tends to self or changed by the influence of environment, as amassing grease, getting rusty, corrode or the like, for equipment in use, at first must be noted that maintenance, prevent that it from changing, otherwise will influence its functions of use, as lathe, milling machine, transfer equipment and various manual and electric instrument and use equipment etc.; For life-time service or the equipment that uses repeatedly, need to remove or clean, otherwise will have a strong impact on its work-ing life and performance, as the sparking plug on the vehicle, the storage battery contact place of store battery etc.For these equipment, people often adopt general rust-preventive agent, stain remover or lubricated, dehumidizier, the function singleness of these corrective maintenance agent, when maintenance and fault eliminating, often need use maintaining agent, bother during use, and its function be unreliable with various functions.For this class maintaining agent, people have proposed many new technical schemes: as the lithium base heavy-duty hyper-pressure lubricating ester (notification number be 1004088) of Chinese patent in 86 years bulletins, it mainly is to be added with one group of compound extreme-pressure additive of being made up of by, dibutyl dithiocaarbamate and dibutyl dithiocaarbamate oxygen moly-sulfide olefine sulfide oleum gossypii seminis, lead naphthenate, benzotriazole 18 in basic ester, and this lubricating ester only has a water resisting property can; A kind of pollution-free water-base lubricant of notification number 1022653 has and for example changed performances such as its viscosity, freezing point though change according to proportioning raw materials, can only be adapted to lubricated under light, heavy loading and the high and low speed conditions, and its subject range is narrower.
The present invention be directed to above-mentioned situation and providing a kind of is that main raw material is aided with multiple additives and makes with the deep processing petroleum product, integrates multipurpose metal surface caring agent of antirust, lubricated, dehumidifying, infiltration, decontamination, electrical insulation properties and preparation method thereof.
Multipurpose metal surface caring agent of the present invention is main raw material and is aided with multiple additives and is made that with the deep processing petroleum product it mainly consists of: A. deep processing petroleum product is No. 3 rocket engine fuels and N
32Machinery oil, the B. additive comprises having: barium mahogany sulfonate, petroleum sodium sulfonate, dodecenylsuccinic acid, benzotriazole, oleic acid, tributyl phosphate, 2,6 toluene di-tert-butyl phenols and propyl carbinol.
A. deep processing petroleum product:
Prepare the used deep processing petroleum product of maintaining agent of the present invention, be mainly No. 3 rocket engine fuels and N
32Machinery oil, No. 3 rocket engine fuels are that crude oil adopts deep processing to refine the kerosene that forms, and have high-performance, and used No. 3 rocket engine fuels all are the super-fuel (kerosene) that uses on the aircraft generally, and specific performance is please directly consulted aircraft fuel (kerosene); N
32The performance of machinery oil sees also the relevant handbook of machinery with oil.No. 3 rocket engine fuels and N
32The main lubricate of machinery oil, in the maintaining agent of making is major ingredient, and proportion is 65～88% (volume ratios, as follows), can select No. 3 rocket engine fuels for use for these two kinds of deep processing petroleum products shared respectively ratio in whole maintaining agent is 50～83%, N
32Machinery oil is 5～15%.These two kinds of oil all directly adopt the petroleum product of deep processing, and its course of processing does not elaborate at this, see also the data of relevant deep processing petroleum product.
B. additive
1. barium mahogany sulfonate and petroleum sodium sulfonate
Barium mahogany sulfonate, petroleum sodium sulfonate have tangible corrosion resistance, at No. 3 rocket engine fuels and N
32Add barium mahogany sulfonate and petroleum sodium sulfonate in the machinery oil, can make maintaining agent have stiction performance and kinetic friction performance preferably, and can in cold snap, keep its specified property; Barium mahogany sulfonate and petroleum sodium sulfonate account for 6～20% of whole maintaining agent, and the ratio between them according to circumstances can be selected for use 5: 1～2: 1; Petroleum sodium sulfonate and petroleum sodium sulfonate mainly play preservative activity in maintaining agent of the present invention, be a kind of sanitas.
2. benzotriazole and oleic acid
Benzotriazole and oleic acid respectively account for 1～4% of maintaining agent of the present invention, and benzotriazole and oleic acid mainly play the anti-rust and lubrication effect in maintaining agent.
3. other additive
Dodecenylsuccinic acid, tributyl phosphate, propyl carbinol and 2,6 toluene di-tert-butyl phenols account for 4～10% in whole maintaining agent, the ratio between them is 0.5～1: 0.5～1: 0.5～1: 0.5～2; These additives play effects such as conditioning, multiviscosisty, anti-attrition in maintaining agent.
Comprehensively above-mentioned, the composition proportioning of maintaining agent of the present invention is as follows:
No. 3 rocket engine fuels (kerosene) 50～83%, N
32Machinery oil 5～15%,
Barium mahogany sulfonate and petroleum sodium sulfonate 6～20%,
Benzotriazole 1～4%, oleic acid 1～4%;
Dodecenylsuccinic acid, tributyl phosphate, 2,6 toluene di-tert-butyl phenols and propyl carbinol 4～10%;
Wherein the ratio of barium mahogany sulfonate and petroleum sodium sulfonate is 5: 1～2: 1, and the ratio between dodecenylsuccinic acid, tributyl phosphate, propyl carbinol and 2,6 toluene di-tert-butyl phenols is 0.5～1: 0.5～1: 0.5～1: 0.5～2.
Followingly provide two specific embodiments:
Embodiment 1: the proportioning of each composition is as follows in the maintaining agent of the present invention:
No. 3 rocket engine fuels 65%, N
32Machinery oil 10%
Barium mahogany sulfonate 8%, petroleum sodium sulfonate 3%,
Benzotriazole 2%, oleic acid 2%,
Dodecenylsuccinic acid 2%, tributyl phosphate 2%;
Propyl carbinol 2%, 2,6 toluene di-tert-butyl phenols 4%.
Embodiment 2, and each composition proportioning is as follows in the maintaining agent of the present invention:
No. 3 rocket engine fuels 80%, N
32Machinery oil 8%,
Barium mahogany sulfonate 5%, petroleum sodium sulfonate 1%,
Benzotriazole 1%, oleic acid 1%,
Dodecenylsuccinic acid 1%, tributyl phosphate 1%,
Propyl carbinol 1%, 2,6 toluene di-tert-butyl phenols 1%.
Each composition is through manufacturing maintaining agent of the present invention among above-mentioned two embodiment, and that this maintaining agent has is antirust, lubricate, dehumidify, separate rust (infiltration), decontamination and electrical insulation properties.
In above-mentioned said ratio, under the normal temperature state, be water sample amber look oleaginous fluid through the maintaining agent of processing and fabricating, smell fragrance, color is light amber Bose, its proportion is 800kg/m
3, and have and physical property such as low solidify, non-volatile; Owing to adopt deep processing petroleum refining thing, in addition multiple high-quality additive forms through processing and fabricating, has high flash point, characteristics such as high seepage force, and elastomeric material, metallic substance and various filamentary material had no effect; Its concrete technical indicator sees the following form:
| Project | Technical indicator | Assay | The method of inspection |
| Kinematic viscosity (40 ℃) | The 2-10 centistoke | 2.98 centistoke | ?GB256-88 |
| Flash-point ℃ (opening cup) | Be not less than 60 ℃ | ?78℃ | ?GB267-88 |
| Zero pour ℃ | ?≯-30℃ | ?-50℃ | ?GB510-83 |
| Water level % | 0.00 | 0.00 | GB260-88 |
| Corrosion (50 ℃ of 3h of copper sheet) | Qualified | Qualified | GB5096-85 |
| Surface tension | ＜44 dynes per centimeter | 20.7 dynes per centimeter | GB6541-86 |
| Interfacial tension | ＜36 dynes per centimeter | 23.9 dynes per centimeter | GB6541-86 |
| Resistance is alleviated in infiltration | ≥7.5kgm | 11kgm | Actual measurement |
| Water displacement experiment | Qualified | Qualified | SY2754-82 |
| Damp and hot experiment | 〉=500 hours | 500 hours rustless | GB2361-88 |
| Salt mist experiment | 〉=50 hours | 50 hours rustless | SY2757-88 |
Above-mentioned various composition can be made into maintaining agent of the present invention by following preparation method, and making method is as follows:
At first, measure barium mahogany sulfonate and petroleum sodium sulfonate, dodecenylsuccinic acid, benzotriazole, oleic acid, tributyl phosphate, 2,6 toluene di-tert-butyl phenols, No. 3 rocket engine fuels and N according to aforementioned proportion
32Machinery oil is stand-by, then barium mahogany sulfonate and petroleum sodium sulfonate are added in the reaction ax, after being heated to 150 ℃, directly be cooled to normal temperature, again dodecenylsuccinic acid, benzotriazole, oleic acid, tributyl phosphate, 2, cool to 50 ℃ after the 6 toluene di-tert-butyl phenol reacting by heating to 120 ℃, and with above-mentioned barium mahogany sulfonate and oil sulphur sodium is molten and, reheat reacts to 50 ℃; At last, above-mentioned solution and No. 3 rocket engine fuels and N
32Machinery oil molten and, add a spot of propyl carbinol again.
Maintaining agent by said ratio and the preparation of processing technique has superior properties of product: 1. because this maintaining agent has very strong adhesive force, can form in the metal surface thin and fine and close oil film, make metal surface and the external world fully isolated, prevent that the various corrosive gas such as aqueous vapor salt fog, acid mist, alkali mist are to the corrosion of various metal surfaces, and because it is better mobile, can in small structure, not produce and block phenomenon, the combination of its high osmosis and anticorrosion rust-proofing ability can be deep in the unapproachable matter-pole micro-structure of general antirust agent, and to the follow-up operation of part, as spray paint, heat treatment etc. has no effect. 2. has powerful loosening corrosion ability. This maintaining agent contains powerful bleeding agent, so can within very short time, infiltrate the sticky keys between inner loosening metal oxide (rust) molecule of corrosion, and bring into play lubricated function and lubricated, reach the alleviation resistance and remove fast the purpose of corrosion, and never can damage original paper; Screw and nut such as loosening corrosion. 3. good lubricated performance. This maintaining agent does not contain silicone oil, so be difficult for making dust to adhere to, the cleaning that can keep for a long time lubricated position, when being, use adopt the fine spray mode to use this maintaining agent, can form the thin layer lubricating oil film at lubricated position, when saving oil product, can ensure again good reliably lubricity; Such as positions such as the rain brush of lubricated automobile, door locks. 4. has good cleaning capacity. Can clean the floating rust, grease, sulphur matter, moisture content and other dirts that are attached in metal surface and the metal pore, and can within the quite a long time, prevent adhering to of dirt; Such as long-pending carbon, the grease of cleaning vehicle spark plug, the dirt of carburetor needle valve etc. 5. have unique dehumidifying, moisture-proof function. For the metal of being infected with moisture content, can be fast and the metal surface affine with moisture content and metal isolation, and can prevent the again subintrusion of aqueous vapor; Make moist by can start behind this maintaining agent of spraying at once such as the automobile distributor cap. 6. high-insulativity energy. Can not affect in use the current lead-through at circuit junction place, can make on the contrary electric current more unobstructed; Such as maintenance of power system knife switch etc.
Maintaining agent of the present invention is owing to have above-mentioned performance, can extensively be used for aerospace, military affairs, industry and the machinery mediation in each field such as civilian or maintenance and the repairing of machine tool. As in the vehicle maintenance and repairing, can remove greasy dirt and impurity on spark plug, the carburetor, can remove the aqueous vapor on the automobile distributor cap, engine is started at once, and can play the maintenance effect to above-mentioned each part, can guarantee that on weapons weapon uses at any time, be easy to the wiping maintenance, lifting is rotated flexibly; For all kinds of offshore set-ups, can play antirust, lubricated, grease removal, exsiccation, make that each parts runs well, electric current is unimpeded. Maintaining agent of the present invention can maintain and remove the metal equipment in each field to keep off and hinder in a word, has wide application prospect.
Claims (2)
1, a kind of multipurpose metal surface caring agent is to be that main raw material is aided with multiple additives and is made with the deep processing petroleum product, and it is characterized in that: it is as follows that it forms proportioning:
No. 3 rocket engine fuels (kerosene) 50～83%, N
32Machinery oil 5～15%,
Barium mahogany sulfonate and petroleum sodium sulfonate 6～20%,
Benzotriazole 1～4%, oleic acid 1～4%;
Dodecenylsuccinic acid, tributyl phosphate, 2,6 toluene di-tert-butyl phenols and propyl carbinol 4～10%;
Wherein the ratio of barium mahogany sulfonate and petroleum sodium sulfonate is 5: 1～2: 1, and the ratio between dodecenylsuccinic acid, tributyl phosphate, propyl carbinol and 2,6 toluene di-tert-butyl phenols is 0.5～1: 0.5～1: 0.5～1: 0.5～2.
2, a kind of preparation method of multipurpose metal surface caring agent is characterized in that:
Its preparation method is as follows;
1. measure various solution according to aforementioned proportion;
2. barium mahogany sulfonate and petroleum sodium sulfonate are added in the reaction ax, be heated to 150 ℃ after, directly be cooled to normal temperature;
3. cool to 50 ℃ after dodecenylsuccinic acid, benzotriazole, oleic acid, tributyl phosphate and 2, the 6 toluene di-tert-butyl phenol reacting by heating to 120 ℃, and with above-mentioned barium mahogany sulfonate and petroleum sodium sulfonate is molten and, reheat reacts to 50 ℃;
4. above-mentioned solution and No. 3 rocket engine fuels and N
32Machinery oil molten and, add a spot of propyl carbinol again and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95108888A CN1049002C (en) | 1995-11-14 | 1995-11-14 | Multipurpose metal surface caring agent and preparing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95108888A CN1049002C (en) | 1995-11-14 | 1995-11-14 | Multipurpose metal surface caring agent and preparing process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1150171A true CN1150171A (en) | 1997-05-21 |
| CN1049002C CN1049002C (en) | 2000-02-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95108888A Expired - Fee Related CN1049002C (en) | 1995-11-14 | 1995-11-14 | Multipurpose metal surface caring agent and preparing process thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082085C (en) * | 1999-08-31 | 2002-04-03 | 中国石油化工集团公司 | Volatile lubricating oil for machining metals |
| CN101586053B (en) * | 2009-05-22 | 2012-03-07 | 中南大学 | Magnesium board rolling lubricant |
| CN105441177A (en) * | 2015-11-19 | 2016-03-30 | 苏州紫光伟业激光科技有限公司 | Maintaining agent for pneumatic marking machine |
| WO2023143543A1 (en) * | 2022-01-25 | 2023-08-03 | 覃东明 | Maintenance method and maintenance oil for circuit breaker and knife switch |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103074146B (en) * | 2013-01-15 | 2014-08-20 | 深圳市佛莱邦科技有限公司 | Multifunctional spray type lubricating and cleaning maintenance agent and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1004088B (en) * | 1988-01-21 | 1989-05-03 | 同济大学 | High-frequency hydraulic vibration pile driver |
| CN1022653C (en) * | 1991-03-13 | 1993-11-03 | 浙江大学 | Method for making transistor with silicon single crystal thin section |
-
1995
- 1995-11-14 CN CN95108888A patent/CN1049002C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1082085C (en) * | 1999-08-31 | 2002-04-03 | 中国石油化工集团公司 | Volatile lubricating oil for machining metals |
| CN101586053B (en) * | 2009-05-22 | 2012-03-07 | 中南大学 | Magnesium board rolling lubricant |
| CN105441177A (en) * | 2015-11-19 | 2016-03-30 | 苏州紫光伟业激光科技有限公司 | Maintaining agent for pneumatic marking machine |
| WO2023143543A1 (en) * | 2022-01-25 | 2023-08-03 | 覃东明 | Maintenance method and maintenance oil for circuit breaker and knife switch |
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| Publication number | Publication date |
|---|---|
| CN1049002C (en) | 2000-02-02 |
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