WO2022260212A1 - Ibc 블렌더를 이용한 핵연료 제조용 uo2 혼합 분말 제조 방법 및 이에 의해 제조된 핵연료 제조용 uo2 혼합 분말 - Google Patents
Ibc 블렌더를 이용한 핵연료 제조용 uo2 혼합 분말 제조 방법 및 이에 의해 제조된 핵연료 제조용 uo2 혼합 분말 Download PDFInfo
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- WO2022260212A1 WO2022260212A1 PCT/KR2021/011124 KR2021011124W WO2022260212A1 WO 2022260212 A1 WO2022260212 A1 WO 2022260212A1 KR 2021011124 W KR2021011124 W KR 2021011124W WO 2022260212 A1 WO2022260212 A1 WO 2022260212A1
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- WIPO (PCT)
- Prior art keywords
- powder
- nuclear fuel
- pellets
- lubricant
- mixing
- Prior art date
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- 239000000843 powder Substances 0.000 title claims abstract description 85
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 57
- 239000003758 nuclear fuel Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 238000002156 mixing Methods 0.000 claims abstract description 60
- 239000000314 lubricant Substances 0.000 claims abstract description 37
- 238000007873 sieving Methods 0.000 claims abstract description 7
- 238000005303 weighing Methods 0.000 claims abstract 2
- 239000008188 pellet Substances 0.000 claims description 85
- 239000011812 mixed powder Substances 0.000 claims description 40
- 239000011148 porous material Substances 0.000 claims description 31
- 239000011701 zinc Substances 0.000 claims description 22
- 238000000227 grinding Methods 0.000 claims description 18
- 230000007547 defect Effects 0.000 claims description 15
- 238000005245 sintering Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 238000003825 pressing Methods 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 239000004156 Azodicarbonamide Substances 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 3
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 3
- 229940083159 ethylene distearamide Drugs 0.000 claims description 3
- KINULKKPVJYRON-PVNXHVEDSA-N n-[(e)-[10-[(e)-(4,5-dihydro-1h-imidazol-2-ylhydrazinylidene)methyl]anthracen-9-yl]methylideneamino]-4,5-dihydro-1h-imidazol-2-amine;hydron;dichloride Chemical compound Cl.Cl.N1CCN=C1N\N=C\C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1\C=N\NC1=NCCN1 KINULKKPVJYRON-PVNXHVEDSA-N 0.000 claims description 3
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 claims description 3
- 238000002347 injection Methods 0.000 abstract description 3
- 239000007924 injection Substances 0.000 abstract description 3
- 239000003361 porogen Substances 0.000 abstract 2
- 239000000654 additive Substances 0.000 description 17
- 238000000465 moulding Methods 0.000 description 17
- 230000000996 additive effect Effects 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 4
- 230000002950 deficient Effects 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- OOAWCECZEHPMBX-UHFFFAOYSA-N oxygen(2-);uranium(4+) Chemical compound [O-2].[O-2].[U+4] OOAWCECZEHPMBX-UHFFFAOYSA-N 0.000 description 3
- FCTBKIHDJGHPPO-UHFFFAOYSA-N uranium dioxide Inorganic materials O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 3
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000011824 nuclear material Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/42—Selection of substances for use as reactor fuel
- G21C3/58—Solid reactor fuel Pellets made of fissile material
- G21C3/62—Ceramic fuel
- G21C3/623—Oxide fuels
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C21/00—Apparatus or processes specially adapted to the manufacture of reactors or parts thereof
- G21C21/02—Manufacture of fuel elements or breeder elements contained in non-active casings
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21C—NUCLEAR REACTORS
- G21C3/00—Reactor fuel elements and their assemblies; Selection of substances for use as reactor fuel elements
- G21C3/02—Fuel elements
- G21C3/04—Constructional details
- G21C3/045—Pellets
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E30/00—Energy generation of nuclear origin
- Y02E30/30—Nuclear fission reactors
Definitions
- the present invention relates to a method for preparing UO 2 mixed powder for producing nuclear fuel using an IBC blender and a UO 2 mixed powder for producing nuclear fuel produced thereby.
- Nuclear fuel used in nuclear power plants generally uranium dioxide (UO 2 ) Pellets are widely used.
- Nuclear fuel, uranium dioxide (UO 2 ) pellets are made from UO 2 powder. More specifically, preparing a UO 2 mixed powder by mixing the UO 2 powder with an additive such as a pore former and a lubricant; Pressing the prepared UO 2 mixed powder to produce UO 2 molded pellets; sintering to produce UO 2 sintered pellets; and grinding to make the sintered pellets uniform in diameter to produce UO 2 grinding pellets, thereby preparing uranium dioxide (UO 2 ) pellets.
- an additive such as a pore former and a lubricant
- a pore forming agent and a lubricant are generally added and mixed using a mixing device in order to improve the fluidity of the powder and to improve the properties of the finally produced pellets. . Since the degree of mixing and homogeneity according to mixing have a great influence on the characteristics or quality of the finally produced pellets, the performance of the mixing device for mixing the powders is very important in the step of preparing the UO 2 mixed powder.
- the conventional manufacturing method of UO 2 mixed powder for manufacturing nuclear fuel requires about 4 hours of mixing time, and since the lubricant needs to be added several times in the mixing process for homogeneous distribution of the lubricant, the mixing time is long and the work is reduced. Continuity is deteriorated, workers must be on standby to add lubricant, and several problems arise in terms of economy, efficiency, and safety due to the nature of the nuclear fuel manufacturing method that handles nuclear materials.
- An object of the present invention is to provide a method for producing a UO 2 mixture powder for nuclear fuel production with a short mixing time and excellent mixing degree and homogeneity of the prepared UO 2 mixture powder.
- the present invention provides a method for producing UO 2 mixed powder for nuclear fuel production, comprising the steps of: (a) measuring and sieving a pore former and a lubricant using an automatic input device, and introducing the UO 2 powder into a UC container; and (b) mixing the UO 2 powder, the pore former, and the lubricant using an IBC Blender.
- the pore former may be U 3 O 8 powder or ADCA (Azodicarbonamide, C 2 H 4 N 4 O 2 ).
- the lubricant may be Acrawax (Ethylene distearamide, C 38 H 76 N 2 O 2 ) or Zinc steatrate (Zn-C 36 H 70 O 4 ).
- the UO 2 powder is 10 to 500 kg, and may include 0.08 to 10 parts by weight of the pore former and 0.05 to 1 part by weight of the lubricant based on 100 parts by weight of the UO 2 powder.
- the automatic input device may include a 300 ⁇ m sieving machine, remove granules present in the pore former and lubricant, and add the pore former and lubricant in a weight ratio set according to the weight of the UO 2 powder.
- the step (b) may be performed under conditions of a rotation speed of 10 to 14 rpm, a powder container filling rate of 50 to 70 vol%, a mixing time of 20 to 30 minutes, and forward mixing.
- Step (b) may further include reverse mixing for 10 minutes.
- the present invention may also provide a UO 2 mixed powder for producing nuclear fuel manufactured by the method for preparing the UO 2 mixed powder for producing nuclear fuel.
- the present invention also provides a UO 2 forming pellet manufacturing step of pressing the UO 2 mixture powder for producing the nuclear fuel; A UO 2 sintered pellet manufacturing step of sintering the UO 2 molded pellets; and a step of producing UO 2 grinding pellets by grinding the sintered pellets to make the sintered pellets uniform in diameter, wherein the defect rate is 5% or less and the density of the sintered pellets is 10.30-10.58 g/cm 3 , UO 2 nuclear fuel.
- a manufacturing method can be provided.
- the mixing time is short, and the mixing degree and homogeneity of the prepared UO 2 mixed powder are excellent.
- FIG. 1 is a diagram showing a method of mixing UO 2 powder using a conventionally used screw mixer.
- FIG. 2 is a diagram showing the configuration of an IBC blender used in the present invention.
- FIG 3 is a diagram showing Zn content and variation in UO 2 mixed powder according to mixing conditions at a rotation speed of an IBC blender of 10 rpm.
- FIG. 4 is a diagram showing Zn content and variation in UO 2 mixed powder according to mixing conditions at a rotation speed of an IBC blender of 14 rpm.
- FIG. 5 is a diagram showing the configuration of an automatic additive injection device for automatically injecting additives into a UC container containing UO 2 powder, and the UC Container is mounted on the IBC Blender of FIG. 2 to mix the powder.
- the present invention is a method for producing UO 2 mixed powder for nuclear fuel production, wherein (a) a pore former and a lubricant are measured and sieved using an automatic input device, and the UO 2 powder is placed in a UC container. putting in; and (b) mixing the UO 2 powder, the pore former, and the lubricant using an IBC Blender.
- the UO 2 powder is a starting material for preparing a UO 2 mixture powder for producing nuclear fuel and nuclear fuel pellets.
- the UO 2 powder has a specific surface area of 2.6 to 2.7 m 2 /g and an average particle size of 4.0 to 10 ⁇ m.
- the UO 2 powder may be used in an amount of 10 to 500 kg.
- the poreformer controls the sintered density of the sintered pellets and controls the size of the pores inside the sintered pellets, when molding pellets are prepared using the UO 2 mixed powder and sintered pellets are manufactured by sintering the molding pellets. It is a remedy that can As the pore forming agent, U 3 O 8 powder or ADCA (Azodicarbonamide, C 2 H 4 N 4 O 2 ) may be used.
- the pore former may be included in an amount of 0.08 to 10 parts by weight based on 100 parts by weight of the UO 2 powder.
- the lubricant is an agent added to form a thin film on the UO 2 powder particles, and improves the flowability of the powder particles to constantly adjust the amount charged to the die during powder molding, as well as Increase production speed. In addition, during powder molding, the pressure between powder particles and the frictional pressure between powder particles/die walls can be reduced to produce the desired molding density at the optimal molding pressure, which has the effect of extending the life of the die/punch. .
- Acrawax Ethylene distearamide, C 38 H 76 N 2 O 2
- Zinc steatrate Zn-C 36 H 70 O 4
- the lubricant may include 0.05 to 1 part by weight based on 100 parts by weight of the UO 2 powder.
- the IBC blender (Intermediate Bulk Containers Blender) refers to a blender that mixes contents by rotating a container itself in various directions.
- the automatic input device is a device that measures and sieves the pore former and the lubricant and puts them into a UC container containing UO 2 powder.
- the automatic injection device includes a 300 ⁇ m sieving machine, and can remove granules present in the pore former and lubricant.
- the automatic dosing device is shown in FIG. 5 .
- the automatic input device includes a first additive input device 1, a second additive input device 2, and an additive metering device 3, and each additive input device is a 300 ⁇ m sieve ( 4).
- the UC container refers to a standard container (Uranium-C (standard order) container) with a capacity of 700 Liter capable of handling uranium powder with a maximum concentration of 5.0 w / o certified by the Korea Institute of Nuclear Safety.
- the 300 ⁇ m sieving machine 4 is a sieving machine capable of removing substances such as granules and particles larger than 300 ⁇ m.
- the step (b) may be performed under conditions of a rotation speed of 10 to 14 rpm, a powder container filling rate of 50 to 70 vol%, a mixing time of 20 to 30 minutes, and forward mixing. Step (b) may further include reverse mixing for 10 minutes.
- a manufacturing method can be provided.
- 'defect rate' means the number of defective pellets generated in each step among all pellets manufactured from the UO 2 mixed powder through molding, sintering, and grinding processes. If the pellet does not satisfy the design conditions or specifications, it is judged to be defective.
- a certain amount of lubricant (here, 0.4 parts by weight compared to 100 parts by weight of the UO 2 powder and the U 3 O 8 powder; UO 2 powder 100 0.38 parts by weight compared to parts by weight) are added and mixed.
- Zn-stearate (Zn-C 36 H 70 O 4 ) powder was used as a lubricant.
- Zn-stearate contains 10% Zn.
- UO 2 +U 3 O 8 It was measured that the content of Zn was about 20 ppm in the powder.
- the mixing time and mixing direction (forward and reverse) of the IBC blender, the container filling rate and the number of rotations were set as variables.
- the container fill factor is expressed as a volume percent of powder relative to the total volume of the container.
- Analysis of the content of Zn included in the mixed powder and measurement of deviation were performed. To this end, one mixed powder was prepared for each experimental condition, and five samples were taken from one mixed powder to measure the content and variation of Zn. Zn content was measured by inductively coupled emission spectroscopy (ICP-OES). The degree of mixing was evaluated by comparing the measured Zn content and the theoretical Zn content, and the degree of homogeneity was evaluated through the deviation of the measured Zn content.
- ICP-OES inductively coupled emission spectroscopy
- the degree of mixing means the degree of mixing of additives, and the better the mixing, the closer the measured degree of mixing approaches the theoretical content. The lower the degree of mixing, the greater the number of unmixed additives.
- Homogeneity indicates how evenly the additives present in the mixed powder are mixed.
- the homogeneity was evaluated through the deviation of the measured Zn content, and the lower the deviation, the higher the homogeneity.
- Table 1 below shows the Zn content and variation in the UO 2 mixed powder according to each implementation condition.
- Forward and backward of the rotation direction mean relatively opposite directions, and the forward direction may mean clockwise or counterclockwise direction, and the reverse direction is a clockwise direction opposite to the forward direction. It can mean counterclockwise or clockwise.
- Table 1 The results of Table 1 are shown in FIGS. 3 and 4 according to the number of revolutions.
- Figure 3 shows the results of the IBC blender at a rotation speed of 10 rpm.
- the average Zn content of each of the samples mixed for 20 minutes and 30 minutes was 416 rpm and 422 rpm, respectively, and was measured close to the theoretical value (420 ppm). , and the variance was found to be small. However, it was found that the average Zn content was closer to the theoretical value at 30 minutes than at 20 minutes of mixing time, and the deviation was smaller. On the other hand, when the mixing time was increased from 30 minutes to 60 minutes, the average Zn content became farther from the theoretical value, and the deviation also increased. If the mixing time is excessively increased, it is considered that some of the additive materials are segregated.
- Figure 4 shows the results of the IBC blender at a rotation speed of 14 rpm.
- the average Zn content of each sample mixed for 20 minutes and 30 minutes was 421 rpm and 419 rpm, respectively, which were measured close to the theoretical value (420 ppm). , and the variance was found to be small.
- the average Zn content was closer to the theoretical value at 30 minutes than at 20 minutes of mixing time, and the deviation was smaller.
- the mixing time was increased from 30 minutes to 60 minutes, the average Zn content became farther from the theoretical value, and the deviation also increased. If the mixing time is excessively increased, it is considered that some of the additive materials are segregated.
- Other mixing conditions are shown in Table 2 below.
- Molded pellets were prepared by filling and pressing the UO 2 mixed powder into a punch and a die, and heat-treating the manufactured pellets in a gas environment for a certain period of time to prepare sintered pellets.
- the molded pellets and the sintered pellets prepared from the UO 2 mixture powder for nuclear fuel manufacture of the present invention have better characteristics than the molded pellets and sintered pellets manufactured from the UO 2 mixture powder for nuclear fuel manufacture prepared using a screw mixer. Excellent was confirmed. More specifically, in the case of molded pellets and sintered pellets manufactured from the UO 2 mixture powder for nuclear fuel production, the flowability of the UO 2 mixture powder is good, so that the molded pellets and the sintered pellets have a small variation in length and, accordingly, a small variation in density.
- micropores are uniformly distributed, which means that U 3 O 8 acting as a pore forming agent is uniformly distributed in the UO 2 mixed powder.
- the absence of coarse pores is because the lubricant was homogeneously distributed without crowding.
- the sintered pellets prepared from the UO 2 mixture powder for nuclear fuel production prepared using a screw mixer it can be confirmed that some coarse pores exist in the microstructure, indicating that the pore former and the lubricant are used in the UO 2 mixture powder. means that it is not evenly distributed.
- the lubricant can be initially injected only once, the mixing time is shortened, and the unmixed lubricant is not generated by reverse rotation, thereby improving the mixing rate. And homogeneity can be improved, the fluidity of the powder can be improved, and continuous operation is possible. In addition, it does not require a waiting worker to add lubricant, so it has excellent economy, efficiency, and safety.
- the defect rate in the UO 2 pellet manufacturing process is 5 to 10% in the conventional method (defect rate in the molding process: 1 to 2%, defect rate in the grinding process: 5 to 8%), and 3 to 5% in the present invention (defect rate in the molding process: 0 %, grinding process defect rate: 3 ⁇ 5%).
- Pellets are generally defective in a molding process for producing molded pellets by pressing UO 2 mixed powder and in a grinding process for grinding sintered pellets. Defects in the molding process occur because the molding pellets are damaged or the length of the molding pellets exceeds the specified range during manufacture of the molded product. Defects in the grinding process are caused by damage by unground parts, cracks or pores present on the surface of the grinding pellets. In the molding process, the defect rate was 1 to 2% in the conventional method, but 0% in the present invention. In addition, the defect rate in the grinding process was 5 to 8%, whereas the defect rate was 3 to 5% in the present invention.
- the reason why the defect rate is small in the grinding pellets manufactured by applying the present invention is that there is no ungrinding part on the surface of the pellet and there is no damage due to pores.
- the reason why no unground parts are generated is that the decrease in molding pressure due to friction is small when molding powder particles in which a lubricant is homogeneously dispersed.
- the damage caused by the pores is mainly a phenomenon caused by the residual lubricant remaining after sintering due to poor mixing, and the pellets manufactured by the present technology showed little damage of this shape.
- the lubricant and the pore former are uniformly distributed, thereby improving the properties and quality of the pellets in molding pellets, sintered pellets, and grinding pellets manufactured from the UO 2 mixed powder. You can see that it makes it better.
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- Plasma & Fusion (AREA)
- General Engineering & Computer Science (AREA)
- High Energy & Nuclear Physics (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Powder Metallurgy (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
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Abstract
Description
Claims (9)
- 핵연료 제조용 UO2 혼합 분말의 제조 방법으로서,(a) 기공형성제 및 윤활제를 자동 투입 장치를 이용하여 계량 및 체질하고, UO2 분말을 포함하는 UC 컨테이너에 투입하는 단계; 및(b) IBC Blender를 이용하여 상기 UO2 분말, 기공형성제 및 윤활제를 혼합하는 단계를 포함하는, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항에 있어서,상기 기공형성제는 U3O8 분말 또는 ADCA(Azodicarbonamide, C2H4N4O2)인, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항에 있어서,상기 윤활제는 Acrawax(Ethylene distearamide, C38H76N2O2) 또는 Zinc steatrate(Zn-C36H70O4)인, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항에 있어서,상기 UO2 분말은 10~500kg이며, 상기 UO2 분말 100중량부에 대해 상기 기공형성제 0.08~10중량부 및 상기 윤활제 0.05~1중량부 포함하는, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항에 있어서,상기 자동 투입 장치는 300㎛ 체질기를 포함하며, 상기 기공형성제 및 윤활제에 존재하는 과립을 제거하고, 상기 UO2 분말 중량에 따라 설정된 중량 비율로 상기 기공 형성제 및 윤활제를 첨가하는 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항 내지 제 5 항 중 어느 한 항에 있어서,상기 (b) 단계는 회전수 10~14rpm, 분말의 컨테이너 충전율 50~70vol%, 혼합 시간 20~30분 및 정방향 혼합의 조건에서 수행되는, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 6 항에 있어서,상기 (b) 단계는 추가로 10분 동안 역방향으로 혼합하는 것을 포함하는, 핵연료 제조용 UO2 혼합 분말의 제조 방법.
- 제 1 항의 핵연료 제조용 UO2 혼합 분말의 제조 방법에 의해 제조된 핵연료 제조용 UO2 혼합 분말.
- 제 8 항의 핵연료 제조용 UO2 혼합 분말을 프레싱하는 UO2 성형 펠렛 제조 단계;상기 UO2 성형 펠렛을 소결하는 UO2 소결 펠렛 제조 단계; 및상기 소결 펠렛을 연삭하여 소결 펠렛의 직경을 일정하게 하는 UO2 연삭 펠렛 제조 단계를 포함하고,불량률이 5% 이하이며, 상기 소결 펠렛의 밀도는 10.30~10.58g/cm3인, UO2 핵연료 제조 방법.
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Application Number | Priority Date | Filing Date | Title |
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EP21945279.4A EP4354461A1 (en) | 2021-06-10 | 2021-08-20 | Method for preparing uo2 mixture powder for nuclear fuel manufacturing by means of ibc blender, and uo2 mixture powder for nuclear fuel manufacturing, prepared thereby |
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KR1020210075397A KR102324478B1 (ko) | 2021-06-10 | 2021-06-10 | Ibc 블렌더를 이용한 핵연료 제조용 uo2 혼합 분말 제조 방법 및 이에 의해 제조된 핵연료 제조용 uo2 혼합 분말 |
KR10-2021-0075397 | 2021-06-10 |
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PCT/KR2021/011124 WO2022260212A1 (ko) | 2021-06-10 | 2021-08-20 | Ibc 블렌더를 이용한 핵연료 제조용 uo2 혼합 분말 제조 방법 및 이에 의해 제조된 핵연료 제조용 uo2 혼합 분말 |
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EP (1) | EP4354461A1 (ko) |
KR (1) | KR102324478B1 (ko) |
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Citations (7)
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KR20030080920A (ko) * | 2002-04-11 | 2003-10-17 | 한국원자력연구소 | 불량 uo₂분말을 재활용한 uo₂소결체의 제조방법 |
KR20040029408A (ko) | 2001-08-08 | 2004-04-06 | 프라마톰 아엔페 게엠베하 | 혼합산화물 핵연료 분말 및 혼합산화물 핵연료 소결체의제조 방법 |
KR101001202B1 (ko) | 2008-11-11 | 2010-12-15 | 한국수력원자력 주식회사 | Mn 및 Al 화합물 첨가제를 함유한 이산화우라늄 핵연료소결체 및 이의 제조 방법 |
KR20120068407A (ko) * | 2010-12-17 | 2012-06-27 | 한국원자력연구원 | 다공성 UO2+x 소결펠렛의 제조방법 |
KR101407633B1 (ko) * | 2012-12-28 | 2014-06-13 | 한국원자력연구원 | U3o8 첨가에 따른 uo2 소결밀도 감소 경감화 방법 |
EP2386351B1 (en) * | 2010-05-12 | 2014-09-03 | Matcon Limited | Apparatus for mixing |
JP2020514049A (ja) * | 2016-12-23 | 2020-05-21 | マトコン・リミテッド | 混合のための装置 |
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2021
- 2021-06-10 KR KR1020210075397A patent/KR102324478B1/ko active IP Right Grant
- 2021-08-20 WO PCT/KR2021/011124 patent/WO2022260212A1/ko active Application Filing
- 2021-08-20 EP EP21945279.4A patent/EP4354461A1/en active Pending
Patent Citations (7)
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KR20040029408A (ko) | 2001-08-08 | 2004-04-06 | 프라마톰 아엔페 게엠베하 | 혼합산화물 핵연료 분말 및 혼합산화물 핵연료 소결체의제조 방법 |
KR20030080920A (ko) * | 2002-04-11 | 2003-10-17 | 한국원자력연구소 | 불량 uo₂분말을 재활용한 uo₂소결체의 제조방법 |
KR101001202B1 (ko) | 2008-11-11 | 2010-12-15 | 한국수력원자력 주식회사 | Mn 및 Al 화합물 첨가제를 함유한 이산화우라늄 핵연료소결체 및 이의 제조 방법 |
EP2386351B1 (en) * | 2010-05-12 | 2014-09-03 | Matcon Limited | Apparatus for mixing |
KR20120068407A (ko) * | 2010-12-17 | 2012-06-27 | 한국원자력연구원 | 다공성 UO2+x 소결펠렛의 제조방법 |
KR101407633B1 (ko) * | 2012-12-28 | 2014-06-13 | 한국원자력연구원 | U3o8 첨가에 따른 uo2 소결밀도 감소 경감화 방법 |
JP2020514049A (ja) * | 2016-12-23 | 2020-05-21 | マトコン・リミテッド | 混合のための装置 |
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KR102324478B1 (ko) | 2021-11-12 |
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