WO2022186121A1 - 基板製造装置 - Google Patents
基板製造装置 Download PDFInfo
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- WO2022186121A1 WO2022186121A1 PCT/JP2022/008225 JP2022008225W WO2022186121A1 WO 2022186121 A1 WO2022186121 A1 WO 2022186121A1 JP 2022008225 W JP2022008225 W JP 2022008225W WO 2022186121 A1 WO2022186121 A1 WO 2022186121A1
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- Prior art keywords
- condensing
- points
- condensing points
- substrate manufacturing
- light
- Prior art date
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- 239000000758 substrate Substances 0.000 title claims abstract description 62
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 42
- 239000004065 semiconductor Substances 0.000 claims abstract description 11
- 238000005259 measurement Methods 0.000 claims description 16
- 230000001678 irradiating effect Effects 0.000 claims description 6
- 238000000034 method Methods 0.000 description 18
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 14
- 229910002601 GaN Inorganic materials 0.000 description 12
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 11
- 229910052733 gallium Inorganic materials 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000010586 diagram Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000013078 crystal Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- NWAIGJYBQQYSPW-UHFFFAOYSA-N azanylidyneindigane Chemical compound [In]#N NWAIGJYBQQYSPW-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/50—Working by transmitting the laser beam through or within the workpiece
- B23K26/53—Working by transmitting the laser beam through or within the workpiece for modifying or reforming the material inside the workpiece, e.g. for producing break initiation cracks
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/0006—Working by laser beam, e.g. welding, cutting or boring taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/03—Observing, e.g. monitoring, the workpiece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/03—Observing, e.g. monitoring, the workpiece
- B23K26/032—Observing, e.g. monitoring, the workpiece using optical means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/0604—Shaping the laser beam, e.g. by masks or multi-focusing by a combination of beams
- B23K26/0613—Shaping the laser beam, e.g. by masks or multi-focusing by a combination of beams having a common axis
- B23K26/0617—Shaping the laser beam, e.g. by masks or multi-focusing by a combination of beams having a common axis and with spots spaced along the common axis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/062—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
- B23K26/0622—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/067—Dividing the beam into multiple beams, e.g. multifocusing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/067—Dividing the beam into multiple beams, e.g. multifocusing
- B23K26/0676—Dividing the beam into multiple beams, e.g. multifocusing into dependently operating sub-beams, e.g. an array of spots with fixed spatial relationship or for performing simultaneously identical operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/082—Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/0869—Devices involving movement of the laser head in at least one axial direction
- B23K26/0876—Devices involving movement of the laser head in at least one axial direction in at least two axial directions
- B23K26/0884—Devices involving movement of the laser head in at least one axial direction in at least two axial directions in at least in three axial directions, e.g. manipulators, robots
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28D—WORKING STONE OR STONE-LIKE MATERIALS
- B28D5/00—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor
- B28D5/0005—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by breaking, e.g. dicing
- B28D5/0011—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by breaking, e.g. dicing with preliminary treatment, e.g. weakening by scoring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28D—WORKING STONE OR STONE-LIKE MATERIALS
- B28D5/00—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor
- B28D5/04—Fine working of gems, jewels, crystals, e.g. of semiconductor material; apparatus or devices therefor by tools other than rotary type, e.g. reciprocating tools
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/38—Nitrides
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B30/00—Production of single crystals or homogeneous polycrystalline material with defined structure characterised by the action of electric or magnetic fields, wave energy or other specific physical conditions
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/67—Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
- H01L21/67005—Apparatus not specifically provided for elsewhere
- H01L21/67011—Apparatus for manufacture or treatment
- H01L21/67092—Apparatus for mechanical treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26
- B23K2103/56—Inorganic material, e.g. metals, not provided for in B23K2103/02 – B23K2103/26 semiconducting
Definitions
- the present disclosure relates to substrate manufacturing equipment.
- Patent Document 1 discloses a method of producing a gallium nitride substrate from a gallium nitride ingot. Specifically, at a certain depth inside a gallium nitride ingot, a modified region is formed by depositing gallium and nitrogen by irradiating a pulse laser while scanning the focal point of the pulse laser at a constant speed. do. An interface is formed by forming a large number of modified regions on a plane. By heating the ingot to a temperature at which gallium melts and moving the first holding member and the second holding member away from each other, the ingot is separated from the interface to produce a gallium nitride substrate.
- a substrate manufacturing apparatus includes a stage on which a semiconductor substrate is arranged.
- a substrate manufacturing apparatus includes an irradiation unit that irradiates a semiconductor substrate placed on a stage with a pulse laser having a predetermined pulse period.
- the substrate manufacturing apparatus includes a control section that controls the relative position between the stage and the irradiation section.
- the irradiation unit generates a plurality of condensing points arranged in a straight line at a predetermined pitch.
- the control unit moves the relative positions of the stage and the irradiation unit at a predetermined speed in parallel with the straight line along which the plurality of condensing points are arranged.
- the predetermined speed is a speed at which the distance that a plurality of condensing points move in one period of the predetermined pulse period is the same as the predetermined pitch.
- the plurality of condensing points are moved in the linear direction along which the plurality of condensing points are aligned.
- the distance over which the plurality of condensing points move in one period of the predetermined pulse period is the same as the predetermined pitch.
- the laser output per irradiation can be reduced while the total amount of energy to be applied is the same or greater. It is possible to suppress the occurrence of unintended cracks and the like.
- the irradiation unit may be equipped with multiple laser light sources. Multiple focal points may be generated by multiple laser light sources.
- the pulse energy of some condensing points out of the plurality of condensing points may be different from the pulse energy of the other condensing points.
- the pulse energy of the condensing point on the front side in the traveling direction where the plurality of condensing points are moved by the control unit may be smaller than the pulse energy of the condensing point on the rear side in the traveling direction.
- the pulse energy of the condensing point on the front side in the direction of travel to which the plurality of condensing points are moved by the control unit may be greater than the pulse energy of the converging point on the rear side in the direction of travel.
- the pulse widths of some of the plurality of condensing points may be different from the pulse widths of the other condensing points.
- the pulse width of the condensing point on the front side in the traveling direction to which the plurality of condensing points are moved by the control unit may be smaller than the pulse width of the condensing point on the rear side in the traveling direction.
- the pulse width of the condensing point on the front side in the direction of travel to which the plurality of condensing points are moved by the control unit may be larger than the pulse width of the converging point on the rear side in the direction of travel.
- the wavelengths of some of the plurality of condensing points may be different from the wavelengths of the other condensing points.
- the wavelength of the condensing point on the front side in the traveling direction to which the plurality of condensing points are moved by the control unit may be larger than the wavelength of the condensing point on the rear side in the traveling direction.
- the wavelength of the condensing point on the front side in the traveling direction to which the plurality of condensing points are moved by the control unit may be smaller than the wavelength of the condensing point on the rear side in the traveling direction.
- a measurement unit may be further provided for measuring the modified region formed on the semiconductor substrate on the stage by a plurality of condensing points.
- the irradiating section may control the number of the plurality of condensing points according to the measurement result by the measuring section.
- the measurement unit may measure the size of the modified region.
- the irradiation unit may be controlled such that the smaller the size of the modified region, the greater the number of the plurality of condensing points.
- the present disclosure makes it possible to provide a substrate manufacturing apparatus capable of suppressing the occurrence of unintended cracks and the like.
- FIG. 1 is a schematic configuration diagram of a substrate manufacturing apparatus according to a first embodiment
- FIG. FIG. 4 is a schematic diagram showing a plurality of condensing points
- FIG. 4 is a schematic diagram showing multiple scan lines
- It is a figure which shows a mode that several condensing points move.
- It is a flow figure showing a substrate manufacturing method of a 1st embodiment.
- It is a figure which shows an example of the ingot in which the modified layer was formed.
- FIG. 1 is a schematic configuration diagram of the substrate manufacturing apparatus 1.
- the substrate manufacturing apparatus 1 includes a stage drive section 11 , a stage 12 , an irradiation section 13 , a measurement section 14 and a control section 15 .
- the stage drive unit 11 , the irradiation unit 13 and the measurement unit 14 are controlled by the control unit 15 .
- the control unit 15 is, for example, a PC.
- An ingot (semiconductor substrate) 30 to be processed is placed on the stage 12 .
- the irradiation unit 13 is a part that irradiates the ingot 30 placed on the stage 12 with a pulse laser having a predetermined pulse period.
- the irradiation unit 13 includes a laser light source 21 , a spatial light modulator 23 and a condenser lens 24 .
- the laser light source 21 is a device that outputs laser light that is transmissive to the ingot 30 .
- the oscillation frequency of the pulse laser is 50 kHz (that is, the pulse period is 0.02 ms) and the wavelength of the pulse laser is 532 nm.
- the spatial light modulator 23 is a device that modulates the phase of the pulse laser PL output from the laser light source 21 .
- the spatial light modulator 23 is a reflective liquid crystal (LCOS) spatial light modulator.
- the spatial light modulator 23 can freely shape the light beam pattern.
- the spatial light modulator 23 can modulate the pulse laser PL such that the pulse energy of some of the plurality of condensing points is different from the pulse energy of the other condensing points. can.
- the pulse laser PL is modulated so as to form six focal points P1 to P6, which will be described later. Note that the number of condensing points can be freely changed and is not limited to six. Also, the pulse energy at each focal point can be set individually.
- FIG. 2 is a cross-sectional view of ingot 30 at a depth at which a plurality of converging points P1-P6 are located. That is, FIG. 2 is a cross-sectional view of the ingot 30 on the surface on which the modified layer L1 is formed. Condensing points P1 to P6 are arranged on a straight line LX extending in the X direction. The irradiation unit 13 generates a plurality of condensing points P1 to P6.
- the condensing points P1 to P6 are arranged at equal intervals at a predetermined pitch PP.
- the predetermined pitch PP is 5 ⁇ m, and the peak power of each of the condensing points P1 to P6 is the same at 0.025W.
- the stage 12 By controlling the stage drive section 11 by the control section 15, the stage 12 can be moved in the X, Y, and Z directions. That is, the control unit 15 controls the relative position between the stage 12 and the irradiation unit 13 by the stage driving unit 11 .
- the control unit 15 sets the relative position between the stage 12 and the irradiation unit 13 (in other words, the position of the irradiation unit 13 with respect to the stage 12, or the position of the stage 12 with respect to the irradiation unit 13) to the plurality of converging points P1 to P6. are moved at a predetermined speed in parallel with the straight line LX on which are lined up.
- the measurement section 14 is a section that measures a large number of modified regions MA formed inside the ingot 30 . The modified area MA will be described later. In 1st Embodiment, the measurement part 14 is a camera. [Scanning processing of condensing points]
- the control unit 15 controls the stage driving unit 11 so that the condensing points P1 to P6 can be scanned on the scanning lines SL1 to SL6.
- the condensing points P1 to P6 move on the straight line LX along which the condensing points P1 to P6 are arranged.
- the scanning lines SL1 to SL6 are scanned at a predetermined speed.
- the predetermined speed is a speed at which the moving distance of the condensing points P1 to P6 in one period (0.02 ms) of the pulse laser is the same as the predetermined pitch PP (5 ⁇ m). In the first embodiment, the predetermined speed is 250mm/s.
- FIG. (a) to (f) of FIG. 4 show how the condensing points P1 to P6 move in the traveling direction TD for each period of the pulsed laser.
- attention is focused on one irradiation point IP.
- the condensing point P1 irradiates the irradiation point IP with the pulsed laser for the first time.
- the converging point P2 irradiates the irradiation point IP with the pulse laser for the second time.
- the converging point P6 irradiates the irradiation point IP with the pulse laser for the sixth time.
- the energy is applied six times by the six condensing points P1 to P6, making it possible to form the modified area MA at the irradiation point IP. That is, it is possible to form the modified area MA by dividing the seed forming step of forming a minute modified area MA (seed of the modified area MA) and the enlarging step of enlarging the formed modified area MA. can.
- the irradiation points IP can be formed on the scanning lines SL1 to SL6 in a state of being arranged at a predetermined pitch PP (5 ⁇ m).
- the spatial light modulator 23 allows the pulse energy at each of the focal points P1 to P6 to be individually set. Therefore, various pulse energy settings are possible.
- the pulse energies of the focal points P1 to P6 may be equal (first energy setting).
- the pulse energy at the focal point on the front side in the traveling direction TD may be made smaller than the pulse energy at the focal point on the rear side in the traveling direction TD (second energy setting).
- the pulse energy at the focal point on the front side in the traveling direction TD may be made larger than the pulse energy at the focal point on the rear side in the traveling direction TD (third energy setting).
- the peak output [W] is calculated by dividing the pulse energy [J] by the pulse width [s], when the pulse width is constant, the peak output can be increased as the pulse energy is increased.
- the integrated amount of energy can be linearly increased at each of the plurality of irradiation points IP.
- the integrated energy amount can be decreased in the first half of irradiation and increased in the second half.
- the integrated energy amount can be increased in the first half of irradiation and decreased in the second half.
- the manner in which the pulse energy changes may vary.
- the pulse energy may change linearly toward the front side in the traveling direction TD, or the pulse energy may change stepwise for each of a plurality of converging points.
- the substrate manufacturing method of the first embodiment will be explained using the flow of FIG.
- the substrate manufacturing method includes an irradiation process of step S10, a separation process of step S30, and a polishing process of step S40.
- the irradiation step is a step of forming N modified layers (N is a natural number equal to or greater than 1) in the ingot.
- FIG. 6 is a diagram showing an example of the ingot 30 on which the modified layer is formed by the irradiation process.
- FIG. 6 shows top and side views of ingot 30 .
- 1st Embodiment demonstrates the case where the number of modified layers is four.
- the ingot 30 is made of a gallium nitride (GaN) single crystal. GaN single crystals are colorless.
- the ingot 30 is formed with four modified layers L 1 to L 4 having different depths from the surface 30s.
- the ingot 30 is divided into five substrate layers 31-35 by the four modified layers L1 - L4.
- a modified layer is a layer in which a large number of modified regions exist within the XY plane.
- the modified region is a region where density, refractive index, mechanical strength, and other physical properties are different from those of the GaN crystal in its initial state.
- the modified region is a region formed by locally heating by the focal point of the pulse laser, and by evaporating nitrogen of GaN into gas. Gallium is precipitated in the modified region, and the modified region has a black color.
- step S10 The irradiation process of step S10 includes steps S11 to S19.
- step S11 the height of the stage 12 in the Z direction is adjusted so that the condensing point P is located at the depth where the modified layer LK of the K -th layer (K is a natural number of 1 or more and N or less) is formed.
- the lowermost modified layer L1 is a modified layer formed at a depth D1 from the surface 30s.
- step S12 one scanning line is scanned (see FIG. 3).
- step S13 it is determined whether scanning of all scanning lines has been completed. If the determination is negative (S13: NO), the process proceeds to step S14.
- step S14 it is determined whether or not a predetermined number of scanning lines (eg, 3 lines) have been scanned. If the determination is negative (S14: NO), the process returns to step S12 and the next scan is performed. If the determination is affirmative (S14: YES), the process proceeds to step S15, and the modified region is measured. Thereby, the modified region can be measured every time a predetermined number of scans are performed.
- the measurement in step S15 is performed using the measurement unit 14.
- a plurality of modified regions MA may be photographed by a camera, image processing may be performed by the control unit 15 to determine the size of each of the plurality of modified regions, and an average value may be calculated.
- step S16 it is determined whether or not the size of the modified area MA is within a predetermined allowable range. If it is within the allowable range, it is determined that the modified region MA is properly formed, and the process returns to step S12. Then the next scan is performed.
- step S17 the spatial light modulator 23 is adjusted to increase the number of condensing points without changing the pulse energy at each condensing point. Then, the process returns to step S12 and the next scan is performed. As a result, the integrated amount of energy applied to the modified area MA can be increased in subsequent scans, so that the size of the modified area MA can be increased.
- step S18 the spatial light modulator 23 is adjusted to reduce the number of condensing points without changing the pulse energy at each condensing point. Then, the process returns to step S12 and the next scan is performed. As a result, the integrated amount of energy applied to the modified area MA can be reduced in subsequent scans, so the size of the modified area MA can be reduced.
- the number of converging points to increase or decrease is not limited to one.
- two or more may be increased or decreased according to the difference value between the measured size of the modified region MA and the allowable range. That is, the irradiation unit 13 controls the number of multiple condensing points according to the measurement result by the measurement unit 14 .
- the irradiation unit 13 may be controlled such that the smaller the size of the modified region MA, the greater the number of the plurality of condensing points.
- step S13 When scanning of all the scanning lines is completed, it is determined in step S13 that the scanning has ended (S13: YES), and the process proceeds to step S19.
- step S19 it is determined whether or not the uppermost modified layer has been formed. If the determination is negative (S19: NO), the process proceeds to S20, and the stage 12 is moved in the -Z direction so that the focal point P moves to the depth at which the K+1 -th modified layer LK+1 is formed. Let Then, the process returns to S12 to form the next modified layer LK +1 .
- the modified layers L 1 to L 4 are formed one by one in order from the bottom. That is, the modified layer L1 at the deepest position from the surface 30s to the modified layer L4 at the shallowest position are sequentially formed one by one. Thereby, the presence of the previously formed modified layer does not hinder the subsequent formation of the modified layer.
- step S19 S19: YES
- step S10 the irradiation process in step S10 ends, and the process proceeds to step S30.
- step S30 by applying heat and stress to the ingot 30, cracks extending from the multiple modified regions MA formed in the modified layers L1 to L4 are propagated in the in - plane direction.
- the substrate layers 31 to 35 of the ingot can be separated from each other using the positions where the modified layers L 1 to L 4 were formed as boundaries.
- polishing step of step S40 the front and rear surfaces of each of the separated substrate layers 31-35 are polished. Thereby, the damaged layer can be removed and the surface can be planarized.
- the polishing process may be performed using, for example, CMP (Chemical Mechanical Polishing). [effect]
- Energy per irradiation can be reduced while the total amount of energy to be applied is equal to or greater than that in the case of applying energy in one irradiation. Therefore, the energy of each of the plurality of condensing points can be reduced to such an extent that large amounts of gallium are not precipitated. Then, by repeatedly applying energy to the same point from a plurality of condensing points, the modified area MA can be gradually formed. It is possible to enlarge the modified region MA while suppressing a large amount of gallium precipitation and an increase in the precipitation position.
- the modified area MA can be formed by irradiating a plurality of times.
- position control of such a table is generally difficult. For example, let us consider a case where the pulse period is 0.02 ms, the pitch between the irradiation points is 5 ⁇ m, and the pulse laser is applied six times per irradiation point, as in the first embodiment. In this case, it is necessary to repeatedly control the table so that it moves 5 ⁇ m every 0.1 ms. Also, the travel time is 0.02 ms.
- the table should be moved at a constant speed. Controlling the table at a constant speed can sufficiently improve the positional accuracy as compared with the above-described repetitive control. Therefore, it is possible to irradiate the same irradiation point with the laser a plurality of times with high accuracy.
- a seed forming step of forming minute modified regions MA seeds of the modified regions MA
- the formed modified regions It can be processed separately into an enlargement step of enlarging the MA.
- the energy given by one laser irradiation exceeds a certain energy threshold, a large amount of gallium is likely to be precipitated or the position of the gallium is likely to rise.
- the energy thresholds are comparable in both the speciation and expansion steps.
- the pulse energies of the focal points P1 to P6 should be equal (first energy setting). This makes it possible to equalize each of the energies that are divided and given six times.
- the energy threshold is higher for the expansion step than for the seeding step.
- the state is unstable until the seeds of the modified region MA are formed, but the change stabilizes once the seeds of the modified region MA are formed.
- the pulse energy at the focal point on the front side in the traveling direction TD should be made smaller than the pulse energy at the focal point on the rear side in the traveling direction TD (second energy setting).
- the peak output can be made larger in the second half of the expansion step than in the first half of the seed formation step. It becomes possible to expand the modified area MA efficiently.
- the energy threshold is higher for the speciation step than for the expansion step.
- the pulse energy at the focal point on the front side in the traveling direction TD should be made larger than the pulse energy at the focal point on the rear side in the traveling direction TD (third energy setting).
- the peak output can be made larger in the first half of the seed formation step than in the second half of the expansion step. It becomes possible to efficiently form the seeds of the modified region MA.
- the substrate manufacturing apparatus 1 can measure the size of the modified region MA during the formation of one modified layer ( FIG. 5 , step S15). Then, when the size of the modified area MA is smaller than the allowable range, the integrated amount of energy applied to the modified area MA can be increased by increasing the number of condensing points (step S17). ). On the other hand, if the size of the modified area MA is larger than the allowable range, the integrated amount of energy applied to the modified area MA can be reduced by reducing the number of condensing points (step S18 ). In-situ feedback control makes it possible to form an appropriately sized modified region MA. [Second embodiment]
- a substrate manufacturing apparatus 1a (FIG. 7) of the second embodiment differs from the substrate manufacturing apparatus 1 (FIG. 1) of the first embodiment in that it includes a plurality of laser light sources 21a and 22a. Parts common to those of the substrate manufacturing apparatus 1 of the first embodiment are denoted by the same reference numerals, and descriptions thereof are omitted.
- the irradiation unit 13a includes laser light sources 21a and 22a.
- Condensing points P1 to P3 are formed by modulating the pulse laser PL1 output from the laser light source 21a.
- Condensing points P4 to P6 are formed by modulating the pulse laser PL2 output from the laser light source 22a.
- the pulse laser PL1 and the pulse laser PL2 have the same oscillation frequency and wavelength, but different pulse widths. Therefore, the converging points P1 to P3 and the converging points P4 to P6 have different pulse widths.
- the spatial light modulator 23 modulates the pulse lasers PL1 and PL2 so that the pulse energies of the focal points P1 to P6 are the same.
- the pulse width can be set in various ways.
- the pulse widths of the condensing points P1 to P6 may be equal (first pulse width setting).
- the pulse widths of the focal points P1 to P3 on the front side in the traveling direction TD may be set smaller than the pulse widths of the focal points P4 to P6 on the rear side (second pulse width setting).
- the pulse width of the condensing points P1 to P3 may be set larger than the pulse width of the condensing points P4 to P6 (third pulse width setting). Since the peak output [W] is calculated by dividing the pulse energy [J] by the pulse width [s], when the pulse energy is constant, the smaller the pulse width, the larger the peak output.
- the pulse widths of the condensing points P1 to P6 should be equal (first pulse width setting). This makes it possible to equalize each of the energies that are divided and given six times.
- the pulse width of the converging points P1 to P3 on the front side in the traveling direction TD should be made smaller than the pulse width of the converging points P4 to P6 on the rear side (second pulse width setting).
- the peak output can be made larger in the first half of the seed formation step than in the second half of the expansion step. It becomes possible to efficiently form the seeds of the modified region MA.
- the pulse width of the focal points P1 to P3 on the front side should be made larger than the pulse width of the focal points P4 to P6 on the rear side (third pulse width setting).
- the peak output can be made larger in the second half of the expansion step than in the first half of the seed formation step. It becomes possible to expand the modified area MA efficiently.
- the pulse width when irradiating the same irradiation point with the pulse laser a predetermined number of times. For example, let us consider a case where the pulse period is set to 0.02 ms and the pulse laser is applied six times per irradiation point as in the second embodiment. In this case, it is necessary to change the pulse width with a period of 0.1 ms, but it is difficult to perform such control on the laser light source.
- the substrate manufacturing apparatus 1a of the second embodiment may be provided with a plurality of laser light sources having different pulse widths. This makes it possible to irradiate the same irradiation point with a plurality of condensing points having pulse widths different from each other.
- the laser light source 21a and the laser light source 22a have different pulse widths, but the present invention is not limited to this, and various parameters may be different.
- the laser light source 21a and the laser light source 22a may have different wavelengths. By varying the wavelength, it is possible to vary the absorption coefficient of GaN. Since GaN absorbs a laser with a wavelength shorter than 362 nm, the wavelength must be longer than this wavelength.
- Various wavelengths can be set.
- the wavelengths of the condensing points P1 to P6 may be the same (first wavelength setting).
- the wavelength of the focal points P1 to P3 on the front side in the traveling direction TD may be set larger than the wavelength of the focal points P4 to P6 on the rear side (second wavelength setting).
- the wavelengths of the condensing points P1 to P3 may be smaller than the wavelengths of the condensing points P4 to P6 (third wavelength setting). Which wavelength setting is to be used can be appropriately determined according to the change in the absorption coefficient of GaN with respect to the wavelength.
- any one of pulse energy, pulse width, and wavelength is made different among a plurality of condensing points, but it is not limited to this form.
- Two or more of pulse energy, pulse width and wavelength may be varied.
- the pulse energy of the focal points P1 to P3 is made smaller than the pulse energy of the focal points P4 to P6, and the pulse width of the focal points P1 to P3 is made larger than the pulse width of the focal points P4 to P6.
- the parameters that are made different among the plurality of condensing points are not limited to pulse energy, pulse width, and wavelength, and may be various. For example, different pulse waveforms may be used.
- the technology of the present disclosure is applicable not only to gallium nitride (GaN), but also to substrate formation of various compound semiconductors.
- GaN gallium nitride
- substrate formation of various compound semiconductors For example, it can be applied to the formation of substrates of other types of nitride semiconductors such as aluminum nitride (AlN) and indium nitride (InN).
- AlN aluminum nitride
- InN indium nitride
- Numerical values in the present disclosure are examples and are not limited to the above values. That is, the number of scanning lines SL1 to SL6 in FIG. 3 is an example. The number of modified layers and substrate layers in FIG. 6 is an example. The period of the pulsed laser, the predetermined pitch PP, and the values of the peak power are examples. In the substrate manufacturing apparatus 1a (FIG. 7) of the second embodiment, the number of laser light sources is not limited to two, and may be three or more.
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Abstract
Description
[第1実施形態]
[基板製造装置の構成]
[集光点の走査処理]
[基板製造方法]
[効果]
[第2実施形態]
以上、本発明の実施例について詳細に説明したが、これらは例示に過ぎず、特許請求の範囲を限定するものではない。特許請求の範囲に記載の技術には、以上に例示した具体例を様々に変形、変更したものが含まれる。
Claims (13)
- 半導体基板が配置されるステージと、
前記ステージに配置された前記半導体基板に所定パルス周期のパルスレーザを照射する照射部と、
前記ステージと前記照射部との相対位置を制御する制御部と、
を備える基板製造装置であって、
前記照射部は、所定ピッチで直線上に並んでいる複数の集光点を生成し、
前記制御部は、前記ステージと前記照射部との相対位置を、前記複数の集光点が並んでいる直線と平行に所定速度で移動させ、
前記所定速度は、前記複数の集光点が前記所定パルス周期の1周期で移動する距離が前記所定ピッチと同一となる速度である、基板製造装置。 - 前記照射部は複数のレーザ光源を備えており、
前記複数のレーザ光源によって前記複数の集光点が生成されている、請求項1に記載の基板製造装置。 - 前記複数の集光点のうちの一部の集光点のパルスエネルギが、他の集光点のパルスエネルギと異なっている、請求項1または2に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点のパルスエネルギが、前記進行方向の後側の集光点のパルスエネルギよりも小さい、請求項3に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点のパルスエネルギが、前記進行方向の後側の集光点のパルスエネルギよりも大きい、請求項3に記載の基板製造装置。
- 前記複数の集光点のうちの一部の集光点のパルス幅が、他の集光点のパルス幅と異なっている、請求項1~5の何れか1項に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点のパルス幅が、前記進行方向の後側の集光点のパルス幅よりも小さい、請求項6に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点のパルス幅が、前記進行方向の後側の集光点のパルス幅よりも大きい、請求項6に記載の基板製造装置。
- 前記複数の集光点のうちの一部の集光点の波長が、他の集光点の波長と異なっている、請求項1~8の何れか1項に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点の波長が、前記進行方向の後側の集光点の波長よりも大きい、請求項9に記載の基板製造装置。
- 前記複数の集光点のうち、前記制御部によって前記複数の集光点が移動する進行方向の前側の集光点の波長が、前記進行方向の後側の集光点の波長よりも小さい、請求項9に記載の基板製造装置。
- 前記複数の集光点によって前記ステージ上の前記半導体基板に形成された改質領域を測定する測定部をさらに備え、
前記照射部は、前記測定部による測定結果に応じて、前記複数の集光点の数を制御する、請求項1~11の何れか1項に記載の基板製造装置。 - 前記測定部は、前記改質領域の大きさを測定し、
前記照射部は、前記改質領域の大きさが小さいほど前記複数の集光点の数が多くなるように制御する、請求項12に記載の基板製造装置。
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CN202280018274.6A CN116917559A (zh) | 2021-03-02 | 2022-02-28 | 基板制造装置 |
DE112022001333.8T DE112022001333T5 (de) | 2021-03-02 | 2022-02-28 | Substrat-Herstellungsvorrichtung |
KR1020237032363A KR20230153408A (ko) | 2021-03-02 | 2022-02-28 | 기판 제조 장치 |
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JP2003536266A (ja) * | 2000-06-01 | 2003-12-02 | ジェネラル スキャニング インコーポレイテッド | 増幅され波長シフトされたパルス列を使用してターゲット材料を処理するためのエネルギー効率の良い方法及びシステム |
WO2005084874A1 (ja) * | 2004-03-05 | 2005-09-15 | Olympus Corporation | レーザ加工装置 |
JP2013240801A (ja) * | 2012-05-18 | 2013-12-05 | Miyachi Technos Corp | レーザ加工方法及びレーザ加工装置 |
WO2017030040A1 (ja) * | 2015-08-18 | 2017-02-23 | 浜松ホトニクス株式会社 | 加工対象物切断方法及び加工対象物切断装置 |
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JP6633326B2 (ja) | 2015-09-15 | 2020-01-22 | 株式会社ディスコ | 窒化ガリウム基板の生成方法 |
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JP2003536266A (ja) * | 2000-06-01 | 2003-12-02 | ジェネラル スキャニング インコーポレイテッド | 増幅され波長シフトされたパルス列を使用してターゲット材料を処理するためのエネルギー効率の良い方法及びシステム |
WO2005084874A1 (ja) * | 2004-03-05 | 2005-09-15 | Olympus Corporation | レーザ加工装置 |
JP2013240801A (ja) * | 2012-05-18 | 2013-12-05 | Miyachi Technos Corp | レーザ加工方法及びレーザ加工装置 |
WO2017030040A1 (ja) * | 2015-08-18 | 2017-02-23 | 浜松ホトニクス株式会社 | 加工対象物切断方法及び加工対象物切断装置 |
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