WO2022149350A1 - Device for manufacturing vapor deposition mask and method for manufacturing vapor deposition mask - Google Patents

Device for manufacturing vapor deposition mask and method for manufacturing vapor deposition mask Download PDF

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Publication number
WO2022149350A1
WO2022149350A1 PCT/JP2021/042022 JP2021042022W WO2022149350A1 WO 2022149350 A1 WO2022149350 A1 WO 2022149350A1 JP 2021042022 W JP2021042022 W JP 2021042022W WO 2022149350 A1 WO2022149350 A1 WO 2022149350A1
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WO
WIPO (PCT)
Prior art keywords
vapor deposition
deposition mask
manufacturing
eaves
release layer
Prior art date
Application number
PCT/JP2021/042022
Other languages
French (fr)
Japanese (ja)
Inventor
遼太郎 木村
Original Assignee
株式会社ジャパンディスプレイ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社ジャパンディスプレイ filed Critical 株式会社ジャパンディスプレイ
Priority to KR1020237019872A priority Critical patent/KR20230104962A/en
Priority to CN202180085691.8A priority patent/CN116724150A/en
Publication of WO2022149350A1 publication Critical patent/WO2022149350A1/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/04Coating on selected surface areas, e.g. using masks
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D1/00Electroforming
    • C25D1/10Moulds; Masks; Masterforms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/16Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
    • H10K71/166Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask

Definitions

  • One embodiment of the present invention relates to a vapor deposition mask manufacturing apparatus and a method for manufacturing a vapor deposition mask using the same.
  • the organic EL element has an anode electrode, a cathode electrode, and a layer containing an organic EL material provided between the anode electrode and the cathode electrode (hereinafter, referred to as “organic EL layer”).
  • the organic EL layer includes, for example, a functional layer such as a light emitting layer, an electron injection layer, and a hole injection layer.
  • the organic EL element emits light by applying a voltage to each of the anode electrode and the cathode electrode and passing a current between the anode electrode and the cathode electrode.
  • a vacuum vapor deposition method is used to form a light emitting layer of an organic EL element.
  • the vacuum vapor deposition method is a method in which a vapor deposition material is sublimated by heating it with a heater under vacuum and deposited (deposited) on the surface of a substrate.
  • a thin film of the vapor deposition material can be formed on the surface of the substrate.
  • a high-definition thin film pattern can be formed by using a mask (deposited mask) having a large number of fine aperture patterns.
  • the electrofine forming mask (EFM) manufactured by using the electroforming (electroforming) technique using electroplating (plating method) is one of the vapor deposition masks.
  • Patent Document 1 discloses a method of manufacturing a thin-film deposition mask by an electroforming technique.
  • the light emitting layer is not normally vapor-deposited on the organic EL element corresponding to the damaged portion of the vapor deposition mask.
  • the organic EL element of the organic EL display device manufactured by using the vapor deposition mask containing the defect deposits a light emitting layer. Not done. Since the organic EL element on which the light emitting layer is not vapor-deposited does not emit light, the organic EL display device causes a display defect.
  • the organic EL element of the organic EL display device manufactured by using the vapor deposition mask containing the defect may have a defect.
  • the light emitting layer is formed in the region where the light emitting layer should not be formed originally, which causes poor element separation. Therefore, in the manufacture of thin-film deposition masks, there is a demand for a technique that does not generate defects in addition to forming a large number of fine aperture patterns with high accuracy. Further, there is a demand for an apparatus (deposited mask manufacturing apparatus) for manufacturing a vapor deposition mask that does not generate defects.
  • One of the objects of the present invention is to provide an apparatus for manufacturing a thin-film deposition mask capable of suppressing defects, and a method for manufacturing the thin-film deposition mask.
  • the apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is provided so as to surround the support base material having a first surface for supporting the member to be plated and the outer periphery of the member to be plated on the first surface. It has a first support member, a second support member, and an electrode portion provided at a predetermined height from the first surface, and the first support member is provided on the first surface.
  • the second support member has a first wall portion and a first eaves portion protruding inward of the first surface at the upper portion of the first wall portion, and the second support member is the first surface.
  • the first wall portion has a second wall portion provided above and a second eaves portion protruding inward of the first surface at the upper portion of the second wall portion.
  • the second wall portion has a second step portion formed by projecting the electrode portion from the first surface at a predetermined height on the inner surface surface of the second wall portion.
  • the first support member and the second support member can sandwich the member to be plated between the first step portion, the second step portion, and the first surface. Is located in.
  • the first resist mask is formed in the inner region of the second surface with a first film thickness
  • the support has a first surface for supporting the member to be plated.
  • a base material, a first support member and a second support member provided on the first surface so as to surround the outer periphery of the member to be plated, and an electrode provided at a predetermined height from the first surface.
  • the first support member has a portion, and the first support member projects inward of the first wall portion provided on the first surface and an upper portion of the first wall portion.
  • the second support member has a first eaves portion, and the second support member is provided inside the first surface portion in the second wall portion provided on the first surface portion and in the upper part of the second wall portion.
  • the first wall portion has a second eaves portion that protrudes toward the surface, and the first wall portion has a first portion whose height decreases from the first surface to the predetermined height, and the first wall portion.
  • the second wall portion has a first step portion on the inner surface surface of the first wall portion, and the second wall portion is formed on the inner surface surface of the second wall portion from the first surface to the predetermined portion.
  • the first support member and the second support member have a second step portion formed by projecting the electrode portion at a height, and the first support member and the second support member are the first step portion and the second step portion.
  • the member to be plated is arranged so as to be able to sandwich the member to be plated between the stepped portion and the first surface, and the first eaves portion and the second eaves portion are the second surface of the member to be plated.
  • the length of the second eaves covering the second surface is larger than the length of the first eaves covering the member to be plated.
  • the distance between the end of the plating and the end of the first resist mask provided on the second surface is the same as the distance between the end of the first eaves and the end of the first resist mask.
  • the distance between the second eaves and the second surface is 10 mm, and the distance between the end of the second eaves and the end of the first resist mask is 4 mm. Then, with respect to the first resist mask, a release layer is provided on the second surface of each of the side on which the first step portion is provided and the side opposite to the side on which the first step portion is provided.
  • a method of manufacturing a vaporized mask including forming.
  • the schematic plan view of the vapor deposition mask unit produced by the method which concerns on one Embodiment of this invention is shown.
  • the cross-sectional structure along the A1-A2 line shown in FIG. 1 is shown.
  • 3 (A), 3 (B) and 3 (C) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • 4 (A) and 4 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • a schematic plan view showing an apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown.
  • a schematic plan view showing an apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown.
  • FIG. 7 (A) shows a cross-sectional structure along B1-B2 shown in FIG. 6, and FIG. 7 (B) shows a cross-sectional structure along C1-C2 shown in FIG.
  • a schematic plan view showing an apparatus and a method for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown.
  • 8 (A) shows a cross-sectional structure along D1-D2 shown in FIG. 8, and
  • FIG. 8 (B) shows a cross-sectional structure along E1-E2 shown in FIG.
  • FIG. 11 (A) and 11 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • 12 (A) and 12 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • 13 (A), 13 (B) and 13 (C) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • 14 (A) and 14 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention.
  • a schematic cross-sectional view showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention is shown.
  • 16 (A) and 16 (B) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention.
  • 17 (A) and 17 (B) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention.
  • a member or region is “above (or below)” another member or region, it is directly above (or directly below) the other member or region, unless otherwise specified. Includes not only certain cases but also above (or below) the other member or region, i.e., including the inclusion of another component above (or below) the other member or region. ..
  • includes A, B or C
  • contains any of A, B and C
  • is one selected from the group consisting of A, B and C.
  • the expression “including” does not exclude the case where ⁇ includes a plurality of combinations of A to C. Furthermore, these expressions do not exclude cases where ⁇ contains other elements.
  • FIG. 1 is a schematic plan view of the vapor deposition mask unit 100.
  • FIG. 2 is a cross-sectional structure along A1 and A2 shown in FIG.
  • the configuration of the vapor deposition mask unit 100 shown in FIGS. 1 and 2 is an example, and the configuration of the vapor deposition mask unit 100 is not limited to the configuration shown in FIGS. 1 and 2.
  • the vapor deposition mask unit 100 is a connection portion connecting at least one vapor deposition mask 102, a support frame 108 surrounding at least one vapor deposition mask 102, and a support frame 108 and at least one vapor deposition mask 102. Includes 106.
  • at least one vapor deposition mask 102 is composed of a plurality of vapor deposition masks 102, and the plurality of vapor deposition masks 102 are fixed to the support frame 108 via the connection portion 106, respectively.
  • the vapor deposition mask 102 has a plurality of openings 103.
  • the plurality of openings 103 are arranged in a predetermined region to form one mask pattern 104.
  • the vapor deposition mask 102 may include a plurality of mask patterns 104.
  • the vapor deposition mask 102 is connected to the connection portion 106 in a region where the mask pattern 104 is not formed, and is held by the support frame 108.
  • the vapor deposition mask 102 is a plate-shaped member, and the plurality of openings 103 are through holes penetrating the plate-shaped member. The details will be described later, but the vapor deposition mask 102 is formed by using a metal material.
  • a support frame 108 is provided to support the vapor deposition mask 102 in a flat plate shape.
  • a grid-like frame may be provided on the support frame 108 to hold the plurality of vapor deposition masks 102.
  • the support frame 108 corresponds to the size of the mother glass substrate
  • the mask pattern 104 is arranged corresponding to each display panel built in the mother glass substrate
  • the plurality of openings 103 correspond to the display panel. It is arranged corresponding to the arrangement of the pixels in.
  • the connecting portion 106 has a function of connecting the vapor deposition mask 102 and the support frame 108 and fixing them to each other. Therefore, although the support frame 108 does not directly contact the vapor deposition mask 102, the connection portion 106 is in contact with the vapor deposition mask 102 in the non-opening portion of the vapor deposition mask 102 (the region where the mask pattern 104 is not formed), and is in contact with the side surface of the support frame 108. Contact.
  • FIGS. 1 and 2 shows an embodiment in which a plurality of vapor deposition masks 102 are held on the support frame 108, but one embodiment of the present invention is not limited to this, and the support frame 108 is, for example, one.
  • the vapor deposition mask 102 may have a configuration in which the vapor deposition mask 102 is held via the connection portion 106.
  • the vapor deposition mask unit 100 is used in the process of forming an organic EL element in the process of manufacturing a display panel. Specifically, it is used in a step of forming a light emitting layer of an organic EL element by using a vacuum vapor deposition method. In the step of forming the light emitting layer, the vapor deposition region on the mother glass substrate side is arranged so as to match the mask pattern 104 on the vapor deposition mask 102 side, the vapor deposition material passes through the plurality of openings 103, and the vapor deposition material is deposited in the vapor deposition region. do.
  • the vapor deposition mask 102 and the connection portion 106 are formed by using a zero-valent metal material such as nickel (Ni), copper (Cu), titanium (Ti), and chromium (Cr). That is, the release layer 116 and the connection portion 106 have a metal film.
  • the composition of the materials of the vapor deposition mask 102 and the connection portion 106 may be the same as each other.
  • the support frame 108 Similar to the vapor deposition mask 102 and the connection portion 106, the support frame 108 also uses a zero-valent metal material such as nickel (Ni), iron (Fe), cobalt (Co), chromium (Cr), and manganese (Mn). It is formed.
  • the composition of the material of the support frame 108 may be an alloy containing iron (Fe) and chromium (Cr), or an alloy of iron (Fe), nickel (Ni), manganese (Mn), and the alloy may be carbon (C). ) May be included.
  • FIGS. 5 and 6 show a schematic view of the method of manufacturing the vapor deposition mask 102 and the vapor deposition mask manufacturing apparatus 150.
  • 7 (A) is a cross-sectional structure along B1-B2 shown in FIG. 6, and
  • FIG. 7 (B) is a cross-sectional structure along C1-C2 shown in FIG. Is a schematic cross-sectional view showing a method for manufacturing the vapor deposition mask 102 and the vapor deposition mask manufacturing apparatus 150
  • FIG. 9A is a cross-sectional structure along D1-D2 shown in FIG. 8, and FIG.
  • FIG. 9B is a cross-sectional structure. It is a cross-sectional structure along E1-E2 shown in FIG. 8, and FIG. 10 shows the relationship between the thickness of the outermost periphery of the release layer 116 with respect to the height of the eaves when the plating process is performed using the vapor deposition mask manufacturing apparatus 150.
  • 11 (A) to 17 (B) are schematic cross-sectional views showing a method of manufacturing the vapor deposition mask 102.
  • the manufacturing method of the vapor deposition mask 102 or the configuration of the vapor deposition mask manufacturing apparatus 150 shown in FIGS. 3A to 17B is an example, and the manufacturing method of the vapor deposition mask 102 or the configuration of the vapor deposition mask manufacturing apparatus 150 is shown in FIG.
  • the configuration is not limited to the configuration shown in 3 (A) to 17 (B). The same or similar configurations as those in FIGS. 1 and 2 will be omitted here.
  • FIG. 3A shows a step of forming the first resist mask 114 on the second surface 110A of the first support substrate 110.
  • the first support substrate 110 is made of metal.
  • the first support substrate 110 is, for example, copper (Cu), aluminum (Al), titanium (Ti), iron (Fe), nickel (Ni), cobalt (Co), chromium (Cr), molybdenum (Mo), manganese (Mo). It is formed using a metal material such as Mn) or an alloy thereof.
  • the alloy may be, for example, an alloy containing iron (Fe) and chromium (Cr), an alloy of iron (Fe), nickel (Ni), and manganese (Mn), even if the alloy contains carbon (C). good.
  • the first support substrate 110 may be made of stainless steel containing iron (Fe) as a main component and chromium (Cr) and nickel (Ni). Further, in one embodiment of the present invention, the first support substrate 110 is made of metal, but the first support substrate 110 is not limited to the metal.
  • the first support substrate 110 may be formed of an insulating material such as glass, quartz, ceramics, or plastic. In one embodiment of the present invention, the first support substrate 110 may be referred to as a member to be plated.
  • the first resist mask 114 is formed by photolithography using a photosensitive resin material.
  • a photosensitive resin material a coating type photoresist or a dry film resist (DFR) can be used.
  • the first resist mask 114 has a frame-like shape surrounding the plurality of vapor deposition masks 102 (all of the plurality of vapor deposition masks 102) when the plurality of vapor deposition masks 102 are arranged in the vapor deposition mask unit 100 shown in FIG.
  • FIG. 3B shows a stage of forming the release layer 116. Details of the steps for forming the release layer 116 will be described later.
  • the release layer 116 is formed in a region exposed from the frame-shaped first resist mask on the second surface 110A of the first support substrate 110 on which the first resist mask 114 is formed. Specifically, by using the vapor deposition mask manufacturing apparatus 150, the release layer 116 is provided on the side where the first step portion 156A is provided with respect to the first resist mask 114 provided on the second surface 110A.
  • the first step portion 156A is provided on both sides opposite to the side on which the first step portion 156A is provided. That is, the release layer 116 is provided on a part of the second surface 110A where the first resist mask 114 is not provided.
  • the release layer 116 is formed, for example, by using the same metal material as the material forming the vapor deposition mask 102. That is, the release layer 116 has a metal film.
  • the release layer 116 is formed by using a zero-valent metal material such as nickel (Ni), copper (Cu), titanium (Ti), and chromium (Cr).
  • the release layer 116 can be formed by using a plating method.
  • the release layer 116 is formed on the first support substrate 110 by a nickel plating process.
  • the first support substrate 110 may be washed and the release agent may be applied to the second surface 110A.
  • FIG. 3C shows a step of removing the first resist mask 114.
  • the first resist mask 114 is removed by the stripping liquid.
  • An opening 118 is formed in the region from which the first resist mask 114 has been removed.
  • the first resist mask 114 is removed from the first support substrate 110, and the release layer 116 is separated into an inner region 120 and an outer region 122 with the opening 118 interposed therebetween.
  • the film thickness d1 of the first resist mask 114 is formed to be the same as or substantially the same as the design film thickness d2 of the release layer 116. preferable.
  • the release layer 116 is formed by a plating method, the release layer 116 grows in a direction of increasing the film thickness from the second surface 110A of the first support substrate 110 having conductivity.
  • the release layer 116 grows to a desired design film thickness d2
  • the upper surface of the first resist mask 114 has a film thickness that does not come into contact with the release layer 116, so that the subsequent release step of the first resist mask 114 Can be done well.
  • the release layer 116 is formed thicker than the first resist mask 114 (d2> d1), and the release layer 116 grows so as to cover the upper surface of the first resist mask 114. .. If the first resist mask 114 is removed in such a state, there is a problem that a part of the release layer 116 is peeled off.
  • the first resist mask 114 when the first resist mask 114 is immersed in the release liquid, it swells, and a part of the release layer 116 covering the upper surface of the first resist mask 114 is pushed up accordingly, so that the release layer 116 is peeled off. If the peeling layer 116 is peeled off, the vapor deposition mask 102 later formed on the peeling layer 116 becomes a damaged defective product.
  • the light emitting layer is not vapor-deposited on the organic EL element corresponding to the damaged portion of the vapor deposition mask. Since the organic EL element on which the light emitting layer is not vapor-deposited does not emit light, there is a problem that the display is poor in the organic EL display device.
  • the release layer 116 formed by the plating method tends to have a larger film thickness because the growth of the film is more likely to be promoted in the vicinity of the outermost periphery than in the central portion. Therefore, if a condition is set so that the film thickness of the first resist mask 114 does not exceed the film thickness of the release layer 116 near the outermost periphery, the film thickness of the release layer 116 near the central portion may be insufficient.
  • the step of forming the release layer 116 shown in FIG. 3B is the vapor-filmed mask manufacturing apparatus shown in FIG. This is done using 150.
  • the structure shown in FIG. 4A is formed by using the vapor deposition mask manufacturing apparatus 150 shown in FIGS. 5 and 6.
  • FIG. 5 shows, as an example, in the vapor deposition mask manufacturing apparatus 150, the second support member 164 is a detachable member, and the second support member 164 is the first surface 151A of the support base material 151 (FIG. 7 (A). )),
  • the second support member 164 was attached to the first surface 151A (FIG. 7 (A)) of the support base material 151 in the vapor deposition mask manufacturing apparatus 150.
  • the vapor deposition mask manufacturing apparatus 150 includes a support base material 151, a storage portion 152 for accommodating the first support substrate 110 (FIG. 8), and an outer edge portion 111 of the first support substrate 110 (FIG. 8). It has a frame mold portion 154 that covers FIG. 8).
  • the storage portion 152 is provided between the support base material 151 and the frame mold portion 154.
  • the frame form portion 154 is fixed to fix the first support member 162, the second support member 164, and the first support member 162 to the first surface 151A (FIG. 7A) of the support base material 151. It has members 166A and 166B, and a fixing member 168 for fixing the second support member 164 to the first surface 151A (FIG. 7A) of the support base material 151. Further, the frame form portion 154 has an opening 190 provided by the first support member 162 and the second support member 164.
  • the first support member 162 has a first eaves portion 162A (FIGS. 7A and 7B) and a first wall portion 157A.
  • the first support member 162 has a U-shape in a plan view.
  • the U-shaped shape includes a first side 190A, a second side 190B, and a third side 190C.
  • the first side 190A faces (opposes) the fourth side 190D included in the second support member 164.
  • the second side 190B faces (opposes) the third side 190C.
  • the first eaves portion 162A (FIGS. 7 (A) and 7 (B)) and the first wall portion 157A are provided on the first surface 151A (FIG. 7 (A)) of the support base material 151. Be done.
  • the first wall portion 157A is formed on the upper portion of the first surface 151A of the support base material 151, between the first surface 151A and the first eaves portion 162A, with the first surface 151A and the first eaves portion. It is provided so as to be in contact with 162A.
  • the first eaves portion 162A is provided so as to project inward of the first surface 151A at the upper part of the first wall portion 157A.
  • the first support member 162 is detachable from the first surface 151A of the support base material 151 by the fixing members 166A, 166B and 166C.
  • the number of fixing members 166 is arbitrary. In one embodiment of the present invention, the number of fixing members 166 is, for example, eight.
  • the second support member 164 has an electrode portion 163, a third support member 165, a fourth side 190D, a second eaves portion 165A, and a second wall portion 157B.
  • the electrode portion 163, the third support member 165, the fourth side 190D, the second eaves portion 165A, and the second wall portion 157B are the first surface 151A of the support base material 151 (FIG. 7). (A)) Provided above.
  • the second wall portion 157B is located on the upper portion of the first surface 151A of the support base material 151, between the first surface 151A of the support base material 151 and the second eaves portion 165A, and is the second support base material 151.
  • the electrode portion 163 is provided on the upper portion of the first surface 151A of the support base material 151 between the first surface 151A and the second eaves portion 165A so as to be in contact with the second eaves portion 165A.
  • the second eaves portion 165A is provided in the upper part of the electrode portion 163 so as to be in contact with the electrode portion 163 and to project inward of the first surface 151A.
  • the second support member 164 is detachable from the first surface 151A (FIG. 7A) of the support base material 151 by the fixing member 168.
  • the number of fixing members 168 is arbitrary.
  • the third support member 165 is provided so as to surround the electrode portion 163.
  • the number of fixing members 168 is, for example, two.
  • the first support member 162 and the second support member 164 removable from the first surface 151A (FIG. 7 (A)) of the support base material 151, the first support substrate. It is possible to store the 110 (FIG. 8) in the storage unit 152 and to remove the first support board 110 (FIG. 8) from the storage unit 152.
  • the first support member 162 and the second support member 162 and the second support member are supported.
  • the member 164 is provided adjacent to each other, the first eaves portion 162A and the second eaves portion 165A are provided adjacent to each other, and the first step portion 156A and the second step portion 156B are provided adjacent to each other.
  • the first wall portion 157A and the second wall portion 157B are provided adjacent to each other.
  • the opening 190 is composed of four sides, a first side 190A, a second side 190B, a third side 190C, and a fourth side 190D.
  • the length L1 is the length between the first side 190A and the fourth side 190D, and is also the length between the first eaves portion 162A and the second eaves portion 165A.
  • the length L2 is the length between the second side 190B and the third side 190C, and is also the length between the first eaves portion 162A and the first eaves portion 162A.
  • the length L3 of the storage portion 152 is a length corresponding to the length L1 of the opening 190
  • the length L4 of the storage portion 152 is a length corresponding to the length L2 of the opening 190.
  • the length L3 of the storage portion 152 is also the length between the first step portion 156A and the second step portion 156B.
  • the length L4 of the storage portion 152 is also the length of the first eaves portion 162A and the second eaves portion 165A. In one embodiment of the present invention, the length is also referred to as a distance.
  • the length L1 is shorter (smaller) than the length L2, the length L3 is shorter (smaller) than the length L4, the length L1 is shorter (smaller) than the length L3, and the length L2 is the length L4. Shorter (smaller) than. That is, the opening portion of the opening 190 is smaller than the storage portion 152. Further, the opening portion of the opening 190 is smaller than the first support substrate 110. Therefore, since the first support substrate 110 is securely stored and fixed in the storage portion 152, the position of the first support substrate 110 does not shift when the vapor deposition mask manufacturing apparatus 150 is immersed in the plating bath.
  • the film thickness of the release layer 116 formed on the first support substrate 110 is uniformly formed at the central portion and the outer peripheral portion of the release layer 116, and the release layer 116 is uniformly formed in the plane. ..
  • the length L1 may be referred to as the first width
  • the length L2 may be referred to as the second width
  • the length L3 may be referred to as the third width
  • the length L4 is sometimes called the fourth width.
  • the fixing member 166A penetrates and fixes the opening 176A provided in the first support member 162 and the opening 186A provided in the support base material 151.
  • the member 166B penetrates the opening 176B provided in the first support member 162 and the opening 186B provided in the support base material 151
  • the fixing member 166C is an opening 176C provided in the first support member 162.
  • the first support member 162 is attached to and fixed to the first surface 151A by penetrating the opening 186C provided in the support base material 151.
  • the fixing member 168 penetrates the opening 178 provided in the third support member 165, the opening 173 provided in the electrode portion 163, and the opening 186D provided in the support base material 151.
  • the support member 164 of 2 is attached to and fixed to the first surface 151A.
  • the first wall portion 157A has a first portion 157C and a first step portion 156A.
  • the first portion 157C is provided so that the height decreases from the first surface 151A over a predetermined height K.
  • the first step portion 156A is provided on the inner surface of the first wall portion 157A by the first portion 157C.
  • the second wall portion 157B has a second step portion 156B.
  • the second step portion 156B is formed by projecting the electrode portion 163 from the first surface 151A at a predetermined height K on the inner surface of the second wall portion 157B.
  • the electrode portion 163 is provided at a predetermined height K away from the first surface 151A, and projects to the opposite side of the second eaves portion 165A of the second support member 164 (third support member 165). There is. By projecting the electrode portion 163 to the opposite side with respect to the second eaves portion 165A, a connecting member such as a clip can be easily connected to the electrode portion 163. As a result, a voltage is easily applied to the electrode portion 163 via the connecting member during the plating process described later.
  • the first support substrate 110 is stored in the storage portion 152 and fixed. Specifically, the first support substrate 110 is placed on the first surface 151A of the support base material 151, and at least two sides around the first support substrate 110 are U-shaped of the first support member 162. It hits at least two sides of the corner of the shape of. For example, the two sides of the first support board 110 are abutted against the first side 190A and the second side 190B of the storage portion 152 and the third side 190C).
  • the outer edge portion 111 of one side of the first support board 110 abuts on the first step portion 156A.
  • a part of the outer edge portion 111 of the first support board 110 is fitted into the first step portion 156A of the first support member 162, and the first support board 110 has the first surface 151A and the first step. It is sandwiched between the portion 156A and the portion 156A.
  • the second support member 164 is attached to and fixed to the first surface 151A of the support base material 151.
  • the outer edge portion 111 of one side of the first support substrate 110 abuts on the second step portion 156B.
  • a part of the outer edge portion 111 of the first support board 110 is fitted into the second step portion 156B of the second support member 164, and the first support board 110 has the first surface 151A and the second step. It is sandwiched between the portion 156B and the portion 156B.
  • a part of the second surface 110A of the first support board 110 is exposed to the opening 190, and the remaining part of the second surface 110A of the first support board 110 is covered with the frame portion 154. ..
  • the first support member 162 and the second support member 164 are provided on the first surface 151A so as to surround the outer periphery of the first support substrate 110. Further, the first surface 151A of the support base material 151 can support the first support substrate 110.
  • the vapor deposition mask manufacturing apparatus 150 in which the first support substrate 110 is housed is immersed in a plating bath.
  • the plating process is performed by applying a voltage between the solution containing the metal material filled in the plating bath and the electrode portion 163.
  • the release layer 116 grows from the top of the second surface 110A of the conductive first support substrate 110 in the direction of increasing the film thickness, and the second surface of the first support substrate 110 is used.
  • the release layer 116 can be formed on the 110A.
  • the release layer 116 is opposite to the side where the first step portion 156A is provided and the side where the first step portion 156A is provided with respect to the first resist mask 114 provided on the second surface 110A.
  • the release layer 116 is provided on a part of the second surface 110A where the first resist mask 114 is not provided.
  • the release layer 116 has a metal film formed by using a metal material.
  • the first support member 162 or the first eaves portion 162A covers a part of the first resist mask 114 and the second surface 110A of the first support substrate 110.
  • the distance H between the portion of the first eaves portion 162A facing the first support substrate 110 and the second surface 110A is, for example, 10 mm.
  • the distance W between the end portion of the first eaves portion 162A of the first support member 162 and the end portion of the first resist mask 114 provided on the second surface 110A is, for example, 4 mm.
  • the design film thickness d2 of the release layer 116 is 120 ⁇ m.
  • the distance H is also referred to as the height of the eaves
  • the distance W is also referred to as the covering width.
  • the second support member 164 or the second eaves portion 165A covers a part of the first resist mask 114 and the second surface 110A of the first support substrate 110.
  • the distance H between the portion (plane) of the second eaves portion 165A facing the first support substrate 110 and the second surface 110A is, for example, 10 mm.
  • the distance W between the end of the second eaves 165A of the third support member 165 and the end of the first resist mask 114 provided on the second surface 110A is, for example, 4 mm, and the second eaves.
  • the length of the portion 165A covering the first support substrate 110 is longer (larger) than the length of the first eaves portion 162A covering the first support substrate 110.
  • the first support member 162 covers the first resist mask 114 and the first support substrate 110. Further, in the cross-sectional structure along E1-E2 (cross-sectional view) as well as the cross-sectional structure along D1-D2 (cross-sectional view), the portion of the first eaves portion 162A facing the first support substrate 110 (the portion facing the first support substrate 110).
  • the distance H between the surface) and the second surface 110A is 10 mm
  • the distance W between the end portion of the first eaves portion 162A and the end portion of the first resist mask 114 provided on the second surface 110A is It is 4 mm
  • the design film thickness d2 of the release layer 116 is 120 ⁇ m.
  • the first support board 110 When the first support board 110 is stored in the storage portion 152 and fixed, the first support board 110 abuts against at least two sides of the first support member 162 having a U-shaped corner portion sandwiched between them. 1
  • the support substrate 110 enters a part of the first support member 162 and the second support member 164 (third support member 165).
  • the first support substrate 110 is stably fixed to the storage portion 152, so that the film thickness of the release layer 116 formed on the first support substrate 110 is increased between the central portion and the outer peripheral portion of the release layer 116. It is uniformly formed, and the release layer 116 is uniformly formed in the plane.
  • the vapor deposition mask manufacturing apparatus 150 since the vapor deposition mask manufacturing apparatus 150 according to the embodiment of the present invention has an opening 190 and the distance W and the distance H are composed of predetermined values, the first eaves portion 162A is the first support. The substrate 110 and the first resist mask 114 can be covered. As a result, the vapor deposition mask manufacturing apparatus 150 can control the circulation of the solution containing the metal material filled in the plating bath in the vapor deposition mask manufacturing apparatus 150. That is, in the vicinity of the outermost periphery of the first support substrate 110, the circulation of the solution is suppressed, so that the ion concentration in the nearby solution decreases as the peeling layer 116 grows.
  • the thin-film mask manufacturing apparatus 150 uniformly forms the metal material whose circulation is controlled as the release layer 116 on the first support substrate 110, and adjusts the film thickness of the release layer 116 to the central portion and the outer periphery of the release layer 116. It can be formed uniformly with the parts.
  • the film thickness of the outermost circumference of the release layer 116 is 19.5 ⁇ m or more and 20.5 ⁇ m or less, and the distance H ( When the height H of the eaves is 6 mm, the thickness of the outermost circumference of the release layer 116 is 59.5 ⁇ m or more and 60.5 ⁇ m or less, and when the distance H (height H of the eaves) is 9 mm, the release layer The outermost peripheral thickness of the 116 is 99.5 ⁇ m or more and 100.5 ⁇ m or less, and when the distance H (height H of the eaves) is 10 mm, the outermost peripheral film thickness of the release layer 116 is 119.5 ⁇ m or more and 120.
  • the distance H (height H of the eaves portion) can be set using FIG.
  • the design film thickness d2 of the release layer 116 can be 120 ⁇ m by setting the distance H (height H of the eaves) to 10 mm.
  • the vapor deposition mask manufacturing apparatus 150 has an opening 190, and the distance W and the distance H are configured by predetermined values based on FIG. 10, and the film thickness of the release layer 116 is controlled. can do.
  • the film thickness of the release layer 116 does not vary between the central portion and the vicinity of the outermost periphery, the step of peeling the release layer 116 from the second surface 110A of the first support substrate 110, which will be described later. In the above, it is possible to prevent the peeling layer 116 from being peeled off or damaged.
  • FIG. 11A shows a stage in which the adhesive layer 124 is provided on the release layer 116.
  • the adhesive layer 124 it is preferable to use a resist film having a predetermined adhesive strength or adhesive strength in an unexposed state.
  • the resist film is, for example, a dry film resist.
  • the adhesive layer 124 covers the entire surface of the inner region 120 of the release layer 116, and the end portion of the adhesive layer 124 extends to the outside of the release layer 116.
  • the end of the adhesive layer 124 may extend to the outer region 122 of the release layer 116. Since the release layer 116 supplied as a film-like member has such a size, the inner region of the release layer 116 can be reliably covered.
  • the outer peripheral portion of the adhesive layer 124 is unexposed, and the inner region of the adhesive layer 124 may be exposed.
  • the outer peripheral portion 132 including the region overlapping the end portion of the peeling layer 116 is set as an unexposed region, and the region inside the outer peripheral portion 132 is exposed to be an exposed region, and is inside the outer peripheral portion 132.
  • a process of curing the exposed surface in the region may be performed. It is preferable that at least a part of the outer region 122 (the region to be exposed) overlaps with the release layer 116. Selective exposure of the adhesive layer 124 can be performed using a photomask.
  • the first photomask 126 in which the light-shielding portion 129 is formed so as to surround the translucent portion 130 is used.
  • the adhesive layer 124 is formed with a region (region inside the outer region 122) that is hardened as compared with the outer region 122 (unexposed region) and has a reduced adhesive strength.
  • the adhesive force on the surface of the dry film resist is lost by the exposure treatment, but the portion that is already in contact with another surface in the unexposed state is adhered even after being cured by light irradiation. Maintain power.
  • FIG. 12A shows a step in which the adhesive layer 124 is brought into close contact with the second surface 112A of the second support substrate 112, and the release layer 116 is bonded together with the first support substrate 110.
  • the second support substrate 112 is fixed at the unexposed outer peripheral portion 132 of the adhesive layer 124.
  • the interface between the adhesive layer 124 and the release layer 116 is already in close contact with each other before the exposure, and although the adhesive force is lost by the exposure, the adhesive force is maintained to some extent.
  • the second support substrate 112 is made of the same material as the first support substrate 110.
  • the interface between the unexposed outer peripheral portion 132 and the peeling layer 116 can be improved in adhesion by performing a baking treatment after bonding.
  • the baking treatment conditions are, for example, 60 ° C. for 1 hour.
  • FIG. 12B shows a step of peeling the peeling layer 116 from the second surface 110A of the first support substrate 110.
  • the peeling layer 116 can be peeled from the first support substrate 110 by applying a physical force to the interface with the first support substrate 110. For example, a jig having a sharp tip is pressed against the interface between the first support substrate 110 and the release layer 116 to form a portion that triggers peeling, and then an external force is applied so as to peel off the first support substrate 110. Can be added to peel off the release layer 116 from the first support substrate 110.
  • FIG. 13A shows a step of forming the second resist mask 138 on the second support substrate 112 provided with the release layer 116.
  • the second resist mask 138 is formed in a predetermined pattern. That is, the second resist mask 138 is selectively formed in the plurality of openings 103 and the region forming the dummy pattern 140 described later.
  • a negative photoresist is applied onto the release layer 116, and exposure is performed using a photomask so that the regions forming the plurality of openings 103 and the dummy pattern 140 are selectively exposed.
  • a positive photoresist is applied on the release layer 116, and exposure is performed using a photomask so that the non-opening is selectively exposed.
  • a patterned second resist mask 138 can be obtained. It is preferable that the second resist mask 138 is also formed on the outer edge portion of the peeling layer 116 so that the peeling layer 116 can be easily peeled from the vapor deposition mask unit 100.
  • FIG. 13B shows a stage in which a plating pattern is formed in a region not covered by the second resist mask 138 by using a plating method to form a vapor deposition mask 102.
  • the plating pattern may be formed in one step or may be divided into several steps. When performing in a plurality of stages, the plating treatment may be performed so that different metals are formed in different stages. Further, the plating treatment may be performed so that the upper surface of the plating pattern is lower or higher than the upper surface of the second resist mask 138. In the latter case, the upper surface (surface) of the plating pattern may be polished to flatten the upper surface of the plating pattern.
  • FIG. 13C by removing the second resist mask 138 by etching with a release liquid and / or ashing, a mask pattern is formed on the release layer 116 by the plurality of openings 103.
  • the vapor deposition mask 102 can be manufactured.
  • a dummy pattern 140 separated from the vapor deposition mask 102 is formed.
  • the dummy pattern 140 is configured to surround the plurality of vapor deposition masks 102 in a plan view. Since the dummy pattern 140 and the vapor deposition mask 102 are formed at the same time, they can have the same composition and thickness as each other.
  • FIG. 14A shows one aspect of the protective film 142 for protecting the mask pattern 104 of the vapor deposition mask 102.
  • a dry film resist can be used for the protective film 142.
  • the protective film 142 has, for example, a structure in which a photocurable resin film 144 is sandwiched between a release film 145 and a protective film 146.
  • the photocurable resin film 144 contains a negative type photocurable resin. That is, it contains a polymer or oligomer that is cured by light.
  • the thickness of the photocurable resin film 144 can be arbitrarily selected, and can be selected from, for example, 20 ⁇ m or more and 500 ⁇ m or less, 50 ⁇ m or more and 200 ⁇ m or less, or 50 ⁇ m or more and 120 ⁇ m or less.
  • the protective film 146 contains a polymer material.
  • the polymer material can be selected from, for example, polyolefin, polyimide, polyester, polystyrene, fluorine-containing polyolefin and the like.
  • FIG. 14B shows a state in which the protective film 142 is placed on the vapor deposition mask 102. After the release film 145 is peeled off, the protective film 142 is arranged so that the photocurable resin film 144 is sandwiched between the vapor deposition mask 102 and the protective film 146. The protective film 142 is provided so as to cover at least all the mask patterns 104.
  • the photocurable resin film 144 is exposed. Specifically, as shown in FIG. 15, the second photomask 128 having the light-shielding portion 129 and the translucent portion 130 is arranged so that the translucent portion 130 overlaps with the mask pattern 104, and the second photomask 128 is placed. Use to expose. As a result, the solubility of the exposed portion in the developer is reduced.
  • FIG. 16A shows a state in which the protective film 146 is peeled off and developed after the photocurable resin film 144 is exposed, and the third resist mask 148 is formed on the mask pattern 104.
  • a third resist mask 148 is provided for each mask pattern 104. Since the support frame is formed on the dummy pattern 140 in a later step, the third resist mask 148 is not provided.
  • FIG. 16B shows a step of arranging the support frame 108 on the dummy pattern 140.
  • the support frame 108 is arranged between the respective mask patterns when the plurality of mask patterns 104 are formed.
  • the support frame 108 may have a wide outer shell pattern and a narrow pattern formed inside the outer shell pattern (a pattern formed between the mask patterns 104).
  • FIG. 17A shows a stage of forming the connection portion 106 by using the plating method.
  • the metal material is mainly deposited from the portion of the surface of the vapor deposition mask 102 that is not covered by the support frame 108 and the third resist mask 148.
  • a connecting portion 106 in contact with the upper surface of the vapor deposition mask 102 and the side surface of the support frame 108 is formed.
  • the connecting portion 106 the vapor deposition mask 102 and the support frame 108 are connected and fixed.
  • the thickness of the connecting portion 106 may be the same as the thickness of the third resist mask 148, and the thickness of the connecting portion 106 may be smaller than the thickness of the third resist mask 148.
  • the thickness of the connecting portion 106 may be larger than the thickness of the third resist mask 148.
  • the thickness of the connecting portion 106 is larger than the thickness of the third resist mask 148, the vapor deposition mask 102 and the support frame 108 are more firmly bonded to each other.
  • the thickness of the connecting portion 106 is equal to or less than the thickness of the third resist mask 148, it is possible to prevent the connecting portion 106 from being formed on the third resist mask 148. As a result, it is possible to suppress problems such as the connection portion 106 being destroyed when the third resist mask 148 is removed, or the mask pattern 104 being damaged due to the destruction of the connection portion 106. ..
  • the vapor deposition mask unit 100 can be formed on the second support substrate 112 by peeling the third resist mask 148 with a peeling liquid. After that, the peeling layer 116 is peeled from the second support substrate 112, and the peeling layer 116 is further peeled from the vapor deposition mask 102, whereby the vapor deposition mask unit 100 shown in FIG. 2 can be obtained.
  • the thin-film mask manufacturing apparatus 150 described above can also be used to accommodate the second support substrate 112 during the plating process at the time of forming the thin-film mask 102 shown in FIGS. 13 (B) and 13 (C).
  • the photocurable resin film 144 is exposed and developed to form the second resist mask 138 (.
  • steps (A to 16 (B)) and the step of removing the second resist mask 138 with the stripping liquid (FIGS. 17 (A) to 17 (B)) a wet treatment with a chemical solution is performed.
  • the vapor deposition mask manufacturing apparatus 150 or the manufacturing method of the vapor deposition mask 102 described above it is possible to prevent the film thickness d1 of the first resist mask 114 from becoming thicker than necessary. That is, it is possible to suppress the thickening of the first resist mask 114. Further, by using the thin-film deposition mask manufacturing apparatus 150 and the thin-film deposition mask 102 manufacturing method, it is possible to suppress the thickening of the first resist mask 114, so that it is possible to suppress the increase in cost due to the simplification of the manufacturing method and the manufacturing. can.
  • the above-mentioned configuration of the vapor deposition mask, the apparatus for manufacturing the vapor deposition mask, the method for manufacturing the vapor deposition mask, the configuration of the vapor deposition mask unit, and the method for manufacturing the vapor deposition mask unit are appropriately combined as long as they do not conflict with each other. Can be carried out. Further, based on the configuration of the vapor deposition mask, the equipment for manufacturing the vapor deposition mask, the manufacturing method of the vapor deposition mask, the configuration of the vapor deposition mask unit, and the manufacturing method of the vapor deposition mask unit, those skilled in the art may add, delete, or change the design as appropriate. As long as the gist of the present invention is provided, the above-mentioned ones, or the ones with additions, omissions, or changes in conditions are also included in the scope of the present invention.

Abstract

This device for manufacturing a vapor deposition mask has a support base material having a first surface for supporting a member subject to plating, a first support member and a second support member provided so as to surround the outer periphery of the member subject to plating on the first surface, and an electrode part provided so as to be set apart from the first surface by a prescribed height. The first support member has a first wall part provided on the first surface, and a first eave part projecting toward the inner side of the first surface at the upper section of the first wall part. The second support member has a second wall part provided on the first surface, and a second eave part projecting toward the inner side of the first surface at the upper section of the second wall part. The first wall part has a first portion in which the height decreases to a prescribed height from the first surface, and a first step part formed on the inner side surface of the first wall part due to the first portion. The second wall part has a second step part formed by the electrode part projecting, at a prescribed height from the first surface, on the inner-side surface of the second wall part.

Description

蒸着マスクの製造装置、及び蒸着マスクの製造方法Deposition mask manufacturing equipment and vapor deposition mask manufacturing method
 本発明の一実施形態は、蒸着マスクの製造装置、及びそれを用いた蒸着マスクの製造方法に関する。 One embodiment of the present invention relates to a vapor deposition mask manufacturing apparatus and a method for manufacturing a vapor deposition mask using the same.
 近年、発光素子として有機EL素子を用いる有機EL表示装置が知られている。有機EL素子は、アノード電極と、カソード電極と、アノード電極とカソード電極との間に設けられる有機EL材料を含む層(以下、「有機EL層」という)を有する。有機EL層は、例えば、発光層、電子注入層、正孔注入層といった機能層を含む。アノード電極と、カソード電極とのそれぞれに電圧を印加し、アノード電極と、カソード電極との間に電流を流すことで、有機EL素子は発光する。 In recent years, an organic EL display device using an organic EL element as a light emitting element has been known. The organic EL element has an anode electrode, a cathode electrode, and a layer containing an organic EL material provided between the anode electrode and the cathode electrode (hereinafter, referred to as “organic EL layer”). The organic EL layer includes, for example, a functional layer such as a light emitting layer, an electron injection layer, and a hole injection layer. The organic EL element emits light by applying a voltage to each of the anode electrode and the cathode electrode and passing a current between the anode electrode and the cathode electrode.
 有機EL素子の発光層の形成には、例えば、真空蒸着法が用いられる。真空蒸着法は、真空下において、蒸着材料をヒータによって加熱することにより昇華させ、基板の表面に堆積(蒸着)させる方法である。真空蒸着法を用いることで、基板の表面に、蒸着材料の薄膜を形成することができる。また、真空蒸着法では、多数の微細な開口パターンを備えたマスク(蒸着マスク)を用いることにより、高精細な薄膜パターンを形成することができる。 For example, a vacuum vapor deposition method is used to form a light emitting layer of an organic EL element. The vacuum vapor deposition method is a method in which a vapor deposition material is sublimated by heating it with a heater under vacuum and deposited (deposited) on the surface of a substrate. By using the vacuum vapor deposition method, a thin film of the vapor deposition material can be formed on the surface of the substrate. Further, in the vacuum vapor deposition method, a high-definition thin film pattern can be formed by using a mask (deposited mask) having a large number of fine aperture patterns.
 電界めっき(めっき法)を用いる電鋳(電気鋳造)技術を用いて製造されるエレクトロファインフォーミングマスク(EFM)は、蒸着マスクの一つである。例えば、特許文献1には、蒸着マスクを電鋳技術により製造する方法が開示されている。 The electrofine forming mask (EFM) manufactured by using the electroforming (electroforming) technique using electroplating (plating method) is one of the vapor deposition masks. For example, Patent Document 1 discloses a method of manufacturing a thin-film deposition mask by an electroforming technique.
特開2017-210633号公報Japanese Unexamined Patent Publication No. 2017-210633
 例えば、破損した蒸着マスクを用いて有機EL表示装置を製造すると、蒸着マスクの破損部分に対応する有機EL素子は発光層が正常に蒸着されない。例えば、蒸着マスクの製造不良により微細な開口パターンが塞がれている等の欠陥があると、当該欠陥を含む蒸着マスクを用いて製造された有機EL表示装置の有機EL素子は発光層を蒸着されない。発光層を蒸着されない有機EL素子は発光しないため、有機EL表示装置は表示不良をおこす。また、蒸着マスクの製造不良により、本来分離されていなければならない開口パターンが繋がっている等の欠陥があると、当該欠陥を含む蒸着マスクを用いて製造された有機EL表示装置の有機EL素子は、本来発光層が形成されてはならない領域に発光層が形成され、素子分離不良をおこす。したがって、蒸着マスクの製造では、多数の微細な開口パターンを精度良く形成することに加え、欠陥を生成しない技術が求められている。また、欠陥を生成しない蒸着マスクを製造する装置(蒸着マスク製造装置)が求められる。 For example, when an organic EL display device is manufactured using a damaged vapor deposition mask, the light emitting layer is not normally vapor-deposited on the organic EL element corresponding to the damaged portion of the vapor deposition mask. For example, if there is a defect such as a fine opening pattern being blocked due to a manufacturing defect of the vapor deposition mask, the organic EL element of the organic EL display device manufactured by using the vapor deposition mask containing the defect deposits a light emitting layer. Not done. Since the organic EL element on which the light emitting layer is not vapor-deposited does not emit light, the organic EL display device causes a display defect. Further, if there is a defect such as an opening pattern that should be originally separated due to a manufacturing defect of the vapor deposition mask, the organic EL element of the organic EL display device manufactured by using the vapor deposition mask containing the defect may have a defect. , The light emitting layer is formed in the region where the light emitting layer should not be formed originally, which causes poor element separation. Therefore, in the manufacture of thin-film deposition masks, there is a demand for a technique that does not generate defects in addition to forming a large number of fine aperture patterns with high accuracy. Further, there is a demand for an apparatus (deposited mask manufacturing apparatus) for manufacturing a vapor deposition mask that does not generate defects.
 本発明の一実施形態は、欠陥を抑制可能な蒸着マスクの製造装置、及び蒸着マスクの製造方法を提供することを目的の一つとする。 One of the objects of the present invention is to provide an apparatus for manufacturing a thin-film deposition mask capable of suppressing defects, and a method for manufacturing the thin-film deposition mask.
 本発明の一実施形態に係る蒸着マスクの製造装置は、被めっき部材を支持する第1面を有する支持母材と、前記第1面上で、前記被めっき部材の外周を囲むように設けられる第1の支持部材及び第2の支持部材と、前記第1面から所定の高さ離れて設けられる電極部と、を有し、前記第1の支持部材は、前記第1面上に設けられる第1の壁部と、前記第1の壁部の上部において前記第1面の内側に向けて突出する第1の庇部と、を有し、前記第2の支持部材は、前記第1面上に設けられる第2の壁部と、前記第2の壁部の上部において前記第1面の内側に向けて突出する第2の庇部と、を有し、前記第1の壁部は、前記第1面から前記所定の高さに亘って高さが減少する第1の部分と、前記第1の部分によって前記第1の壁部の内側面に第1の段差部と、を有し、前記第2の壁部は、前記第2の壁部の内側面に前記第1面から前記所定の高さで前記電極部が突出することで形成される第2の段差部を有し、前記第1の支持部材と前記第2の支持部材とは、前記第1の段差部及び前記第2の段差部と、前記第1面との間に前記被めっき部材を挟み込むことが可能なように配置されている。 The apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is provided so as to surround the support base material having a first surface for supporting the member to be plated and the outer periphery of the member to be plated on the first surface. It has a first support member, a second support member, and an electrode portion provided at a predetermined height from the first surface, and the first support member is provided on the first surface. The second support member has a first wall portion and a first eaves portion protruding inward of the first surface at the upper portion of the first wall portion, and the second support member is the first surface. The first wall portion has a second wall portion provided above and a second eaves portion protruding inward of the first surface at the upper portion of the second wall portion. It has a first portion whose height is reduced from the first surface to the predetermined height, and a first step portion on the inner surface of the first wall portion by the first portion. The second wall portion has a second step portion formed by projecting the electrode portion from the first surface at a predetermined height on the inner surface surface of the second wall portion. The first support member and the second support member can sandwich the member to be plated between the first step portion, the second step portion, and the first surface. Is located in.
 本発明の一実施形態に係る蒸着マスクの製造方法は、前記第2面の内側領域に第1の膜厚で前記第1レジストマスクを形成し、被めっき部材を支持する第1面を有する支持母材と、前記第1面上で、前記被めっき部材の外周を囲むように設けられる第1の支持部材及び第2の支持部材と、前記第1面から所定の高さ離れて設けられる電極部と、を有し、前記第1の支持部材は、前記第1面上に設けられる第1の壁部と、前記第1の壁部の上部において前記第1面の内側に向けて突出する第1の庇部と、を有し、前記第2の支持部材は、前記第1面上に設けられる第2の壁部と、前記第2の壁部の上部において前記第1面の内側に向けて突出する第2の庇部と、を有し、前記第1の壁部は、前記第1面から前記所定の高さに亘って高さが減少する第1の部分と、前記第1の部分によって前記第1の壁部の内側面に第1の段差部と、を有し、前記第2の壁部は、前記第2の壁部の内側面に前記第1面から前記所定の高さで前記電極部が突出することで形成される第2の段差部を有し、前記第1の支持部材と前記第2の支持部材とは、前記第1の段差部及び前記第2の段差部と、前記第1面との間に前記被めっき部材を挟み込むことが可能なように配置され、前記第1の庇部及び前記第2の庇部は、前記被めっき部材の第2面の一部を覆い、前記第2の庇部が前記第2面を覆う長さは、前記第1の庇部が前記被めっき部材を覆う長さより大きく、断面視において、前記第2の庇部の端部と前記第2面に設けられる第1レジストマスクの端部との距離は、前記第1の庇部の端部と前記第1レジストマスクの端部との距離と同等であり、前記第2の庇部と前記第2面との距離は10mmであり、前記第2の庇部の端部と前記第1レジストマスクの端部との距離は4mmである蒸着マスクの製造装置を用いて、前記第1レジストマスクに対して、前記第1の段差部が設けられる側及び前記第1の段差部が設けられる側の反対側の、ぞれぞれの前記第2面上に剥離層を形成する、ことを含む蒸着マスクの製造方法。 In the method for manufacturing a vapor deposition mask according to an embodiment of the present invention, the first resist mask is formed in the inner region of the second surface with a first film thickness, and the support has a first surface for supporting the member to be plated. A base material, a first support member and a second support member provided on the first surface so as to surround the outer periphery of the member to be plated, and an electrode provided at a predetermined height from the first surface. The first support member has a portion, and the first support member projects inward of the first wall portion provided on the first surface and an upper portion of the first wall portion. The second support member has a first eaves portion, and the second support member is provided inside the first surface portion in the second wall portion provided on the first surface portion and in the upper part of the second wall portion. The first wall portion has a second eaves portion that protrudes toward the surface, and the first wall portion has a first portion whose height decreases from the first surface to the predetermined height, and the first wall portion. The second wall portion has a first step portion on the inner surface surface of the first wall portion, and the second wall portion is formed on the inner surface surface of the second wall portion from the first surface to the predetermined portion. The first support member and the second support member have a second step portion formed by projecting the electrode portion at a height, and the first support member and the second support member are the first step portion and the second step portion. The member to be plated is arranged so as to be able to sandwich the member to be plated between the stepped portion and the first surface, and the first eaves portion and the second eaves portion are the second surface of the member to be plated. The length of the second eaves covering the second surface is larger than the length of the first eaves covering the member to be plated. The distance between the end of the plating and the end of the first resist mask provided on the second surface is the same as the distance between the end of the first eaves and the end of the first resist mask. Using a vapor deposition mask manufacturing apparatus, the distance between the second eaves and the second surface is 10 mm, and the distance between the end of the second eaves and the end of the first resist mask is 4 mm. Then, with respect to the first resist mask, a release layer is provided on the second surface of each of the side on which the first step portion is provided and the side opposite to the side on which the first step portion is provided. A method of manufacturing a vaporized mask, including forming.
本発明の一実施形態に係る方法で作製される蒸着マスクユニットの模式的な平面図を示す。The schematic plan view of the vapor deposition mask unit produced by the method which concerns on one Embodiment of this invention is shown. 図1に示すA1-A2線に沿った断面構造を示す。The cross-sectional structure along the A1-A2 line shown in FIG. 1 is shown. 図3(A)、図3(B)及び図3(C)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。3 (A), 3 (B) and 3 (C) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention. 図4(A)、及び図4(B)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。4 (A) and 4 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention. 本発明の一実施形態に係る蒸着マスクを製造する装置を示す模式的な平面図を示す。A schematic plan view showing an apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown. 本発明の一実施形態に係る蒸着マスクを製造する装置を示す模式的な平面図を示す。A schematic plan view showing an apparatus for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown. 図7(A)は図6に示すB1-B2に沿った断面構造を示し、図7(B)は図6に示すC1-C2に沿った断面構造を示す。7 (A) shows a cross-sectional structure along B1-B2 shown in FIG. 6, and FIG. 7 (B) shows a cross-sectional structure along C1-C2 shown in FIG. 本発明の一実施形態に係る蒸着マスクを製造する装置及び方法を示す模式的な平面図を示す。A schematic plan view showing an apparatus and a method for manufacturing a vapor deposition mask according to an embodiment of the present invention is shown. 図8(A)は図8に示すD1-D2に沿った断面構造を示し、図8(B)は図8に示すE1-E2に沿った断面構造を示す。8 (A) shows a cross-sectional structure along D1-D2 shown in FIG. 8, and FIG. 8 (B) shows a cross-sectional structure along E1-E2 shown in FIG. 本発明の一実施形態に係る蒸着マスクを製造する装置を用いてめっき処理を行う場合の庇部の高さに対する剥離層の最外周の膜厚の関係を示すグラフである。It is a graph which shows the relationship of the film thickness of the outermost periphery of the peeling layer with respect to the height of the eaves part when the plating process is performed using the apparatus which manufactures the vapor deposition mask which concerns on one Embodiment of this invention. 図11(A)、及び図11(B)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。11 (A) and 11 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention. 図12(A)、及び図12(B)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。12 (A) and 12 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention. 図13(A)、図13(B)及び図13(C)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。13 (A), 13 (B) and 13 (C) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask according to an embodiment of the present invention. 図14(A)、及び図14(B)は本発明の一実施形態に係る蒸着マスクを製造する方法を示す模式的な断面図を示す。14 (A) and 14 (B) show schematic cross-sectional views showing a method of manufacturing a vapor deposition mask according to an embodiment of the present invention. 本発明の一実施形態に係る蒸着マスクユニットを製造する方法を示す模式的な断面図を示す。A schematic cross-sectional view showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention is shown. 図16(A)、及び図16(B)は本発明の一実施形態に係る蒸着マスクユニットを製造する方法を示す模式的な断面図を示す。16 (A) and 16 (B) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention. 図17(A)、及び図17(B)は本発明の一実施形態に係る蒸着マスクユニットを製造する方法を示す模式的な断面図を示す。17 (A) and 17 (B) show schematic cross-sectional views showing a method for manufacturing a vapor deposition mask unit according to an embodiment of the present invention.
 以下、本発明の実施の形態を、図面等を参照しながら説明する。但し、本発明は多くの異なる態様で実施することが可能であり、以下に例示する実施の形態の記載内容に限定して解釈されるものではない。図面は説明をより明確にするため、実際の態様に比べ、各部の幅、厚さ、形状等について模式的に表される場合があるが、あくまで一例であって、本発明の解釈を限定するものではない。また、本明細書と各図において、既出の図に関して前述したものと同様の要素には、同一の符号(又は数字の後にa、b、A、Bなど)を付して、詳細な説明を適宜省略することがある。さらに各要素に対する「第1」、「第2」と付記された文字は、各要素を区別するために用いられる便宜的な標識であり、特段の説明がない限りそれ以上の意味を有しない。 Hereinafter, embodiments of the present invention will be described with reference to drawings and the like. However, the present invention can be implemented in many different embodiments and is not construed as being limited to the description of the embodiments exemplified below. In order to clarify the explanation, the drawings may schematically represent the width, thickness, shape, etc. of each part as compared with the actual embodiment, but the drawings are merely examples and limit the interpretation of the present invention. It's not a thing. Further, in the present specification and each figure, the same elements as those described above with respect to the above-mentioned figures are designated by the same reference numerals (or numbers followed by a, b, A, B, etc.) to provide detailed explanations. It may be omitted as appropriate. Further, the characters added with "first" and "second" for each element are convenient signs used to distinguish each element, and have no further meaning unless otherwise specified.
 本明細書において、ある部材又は領域が他の部材又は領域の「上に(又は下に)」あるとする場合、特段の限定がない限りこれは他の部材又は領域の直上(又は直下)にある場合のみでなく他の部材又は領域の上方(又は下方)にある場合を含み、すなわち、他の部材又は領域の上方(又は下方)において間に別の構成要素が含まれている場合も含む。 As used herein, when a member or region is "above (or below)" another member or region, it is directly above (or directly below) the other member or region, unless otherwise specified. Includes not only certain cases but also above (or below) the other member or region, i.e., including the inclusion of another component above (or below) the other member or region. ..
 また、本明細書において「αはA、B又はCを含む」、「αはA,B及びCのいずれかを含む」、「αはA,B及びCからなる群から選択される一つを含む」、といった表現は、特に明示が無い限り、αはA乃至Cの複数の組み合わせを含む場合を排除しない。さらに、これらの表現は、αが他の要素を含む場合も排除しない。 Further, in the present specification, "α includes A, B or C", "α contains any of A, B and C", and "α is one selected from the group consisting of A, B and C". Unless otherwise specified, the expression "including" does not exclude the case where α includes a plurality of combinations of A to C. Furthermore, these expressions do not exclude cases where α contains other elements.
<1.蒸着マスクユニット100の構造>
 図1は、蒸着マスクユニット100の模式的な平面図である。図2は、図1に示すA1とA2に沿った断面構造である。図1及び図2に示す蒸着マスクユニット100の構成は一例であって、蒸着マスクユニット100の構成は、図1及び図2に示す構成に限定されない。
<1. Structure of thin-film mask unit 100>
FIG. 1 is a schematic plan view of the vapor deposition mask unit 100. FIG. 2 is a cross-sectional structure along A1 and A2 shown in FIG. The configuration of the vapor deposition mask unit 100 shown in FIGS. 1 and 2 is an example, and the configuration of the vapor deposition mask unit 100 is not limited to the configuration shown in FIGS. 1 and 2.
 図1に示すように、蒸着マスクユニット100は、少なくとも1つの蒸着マスク102と、少なくとも1つの蒸着マスク102を囲む支持フレーム108と、支持フレーム108と少なくとも1つの蒸着マスク102とを接続する接続部106を含む。図1に示す態様では、少なくとも1つの蒸着マスク102が複数の蒸着マスク102から成り、複数の蒸着マスク102が、それぞれ接続部106を介して支持フレーム108に固定される。 As shown in FIG. 1, the vapor deposition mask unit 100 is a connection portion connecting at least one vapor deposition mask 102, a support frame 108 surrounding at least one vapor deposition mask 102, and a support frame 108 and at least one vapor deposition mask 102. Includes 106. In the embodiment shown in FIG. 1, at least one vapor deposition mask 102 is composed of a plurality of vapor deposition masks 102, and the plurality of vapor deposition masks 102 are fixed to the support frame 108 via the connection portion 106, respectively.
 図1の挿入拡大図に示すように、蒸着マスク102は複数の開口103を有する。蒸着マスク102の中で、複数の開口103は、所定の領域内に配列されて1つのマスクパターン104を形成する。蒸着マスク102は、複数のマスクパターン104を含んでもよい。蒸着マスク102は、マスクパターン104が形成されない領域で接続部106と接続され、支持フレーム108に保持される。 As shown in the inserted enlarged view of FIG. 1, the vapor deposition mask 102 has a plurality of openings 103. In the vapor deposition mask 102, the plurality of openings 103 are arranged in a predetermined region to form one mask pattern 104. The vapor deposition mask 102 may include a plurality of mask patterns 104. The vapor deposition mask 102 is connected to the connection portion 106 in a region where the mask pattern 104 is not formed, and is held by the support frame 108.
 図2に示すように、蒸着マスク102は板状部材であり、複数の開口103は板状部材を貫通する貫通孔である。詳細は後述するが、蒸着マスク102は金属材料を用いて形成される。蒸着マスク102を平板状に支持するため、支持フレーム108が設けられる。複数の蒸着マスク102を保持するため、格子状の枠が支持フレーム108に設けられてもよい。蒸着マスクユニット100では、支持フレーム108がマザーガラス基板のサイズに対応し、マスクパターン104はマザーガラス基板の中に作り込まれる個々の表示パネルに対応して配置され、複数の開口103は表示パネル内の画素の配列に対応して配置される。 As shown in FIG. 2, the vapor deposition mask 102 is a plate-shaped member, and the plurality of openings 103 are through holes penetrating the plate-shaped member. The details will be described later, but the vapor deposition mask 102 is formed by using a metal material. A support frame 108 is provided to support the vapor deposition mask 102 in a flat plate shape. A grid-like frame may be provided on the support frame 108 to hold the plurality of vapor deposition masks 102. In the vapor deposition mask unit 100, the support frame 108 corresponds to the size of the mother glass substrate, the mask pattern 104 is arranged corresponding to each display panel built in the mother glass substrate, and the plurality of openings 103 correspond to the display panel. It is arranged corresponding to the arrangement of the pixels in.
 接続部106は、蒸着マスク102と支持フレーム108を接続し、これらを互いに固定する機能を有する。したがって、支持フレーム108は蒸着マスク102と直接接触しないものの、接続部106は蒸着マスク102の非開口部(マスクパターン104が形成されない領域)において蒸着マスク102と接し、かつ、支持フレーム108の側面と接する。 The connecting portion 106 has a function of connecting the vapor deposition mask 102 and the support frame 108 and fixing them to each other. Therefore, although the support frame 108 does not directly contact the vapor deposition mask 102, the connection portion 106 is in contact with the vapor deposition mask 102 in the non-opening portion of the vapor deposition mask 102 (the region where the mask pattern 104 is not formed), and is in contact with the side surface of the support frame 108. Contact.
 なお、図1及び図2に示す一例は、支持フレーム108に複数の蒸着マスク102が保持される態様を示すが、本発明の一実施形態はこれに限定されず、例えば、支持フレーム108に一つの蒸着マスク102が接続部106を介して保持される構成を有していてもよい。 The example shown in FIGS. 1 and 2 shows an embodiment in which a plurality of vapor deposition masks 102 are held on the support frame 108, but one embodiment of the present invention is not limited to this, and the support frame 108 is, for example, one. The vapor deposition mask 102 may have a configuration in which the vapor deposition mask 102 is held via the connection portion 106.
 本発明の一実施形態に係る蒸着マスクユニット100は、表示パネルの製造工程の中で、有機EL素子を形成する工程で用いられる。具体的には、真空蒸着法を用いて有機EL素子の発光層を形成する工程で用いられる。発光層を形成する工程では、マザーガラス基板側の蒸着領域が蒸着マスク102側のマスクパターン104と整合するように配置され、蒸着材料が複数の開口103を通過し、蒸着材料が蒸着領域に堆積する。 The vapor deposition mask unit 100 according to the embodiment of the present invention is used in the process of forming an organic EL element in the process of manufacturing a display panel. Specifically, it is used in a step of forming a light emitting layer of an organic EL element by using a vacuum vapor deposition method. In the step of forming the light emitting layer, the vapor deposition region on the mother glass substrate side is arranged so as to match the mask pattern 104 on the vapor deposition mask 102 side, the vapor deposition material passes through the plurality of openings 103, and the vapor deposition material is deposited in the vapor deposition region. do.
 蒸着マスク102、及び接続部106はニッケル(Ni)、銅(Cu)、チタン(Ti)、クロム(Cr)などの0価の金属材料を用いて形成される。すなわち、剥離層116、及び接続部106は、金属膜を有する。蒸着マスク102、及び接続部106の材料の組成は互いに同一であってもよい。蒸着マスク102、及び接続部106と同様に、支持フレーム108もニッケル(Ni)、鉄(Fe)、コバルト(Co)、クロム(Cr)、マンガン(Mn)などの0価の金属材料を用いて形成される。例えば、支持フレーム108の材料の組成は鉄(Fe)とクロム(Cr)とを含む合金、又は鉄(Fe)、ニッケル(Ni)、マンガン(Mn)の合金でもよく、合金には炭素(C)が含まれていてもよい。 The vapor deposition mask 102 and the connection portion 106 are formed by using a zero-valent metal material such as nickel (Ni), copper (Cu), titanium (Ti), and chromium (Cr). That is, the release layer 116 and the connection portion 106 have a metal film. The composition of the materials of the vapor deposition mask 102 and the connection portion 106 may be the same as each other. Similar to the vapor deposition mask 102 and the connection portion 106, the support frame 108 also uses a zero-valent metal material such as nickel (Ni), iron (Fe), cobalt (Co), chromium (Cr), and manganese (Mn). It is formed. For example, the composition of the material of the support frame 108 may be an alloy containing iron (Fe) and chromium (Cr), or an alloy of iron (Fe), nickel (Ni), manganese (Mn), and the alloy may be carbon (C). ) May be included.
<2.蒸着マスクユニット100の製造方法>
 図3(A)乃至図4(B)は蒸着マスク102の製造方法を示す模式的な断面図であり、図5及び図6は蒸着マスク102の製造方法及び蒸着マスク製造装置150を示す模式的な平面図であり、図7(A)は図6に示すB1-B2に沿った断面構造であり、図7(B)は図6に示すC1-C2に沿った断面構造であり、図8は蒸着マスク102の製造方法及び蒸着マスク製造装置150を示す模式的な断面図であり、図9(A)は図8に示すD1-D2に沿った断面構造であり、図9(B)は図8に示すE1-E2に沿った断面構造であり、図10は蒸着マスク製造装置150を用いてめっき処理を行う場合の庇部の高さに対する剥離層116の最外周の膜厚の関係を示すグラフであり、図11(A)乃至図17(B)は蒸着マスク102の製造方法を示す模式的な断面図である。図3(A)乃至図17(B)に示す蒸着マスク102の製造方法又は蒸着マスク製造装置150の構成は一例であって、蒸着マスク102の製造方法又は蒸着マスク製造装置150の構成は、図3(A)乃至図17(B)に示す構成に限定されない。図1及び図2と同一、又は類似する構成については、ここでの説明を省略する。
<2. Manufacturing method of thin-film mask unit 100>
3 (A) to 4 (B) are schematic cross-sectional views showing a method of manufacturing the vapor deposition mask 102, and FIGS. 5 and 6 show a schematic view of the method of manufacturing the vapor deposition mask 102 and the vapor deposition mask manufacturing apparatus 150. 7 (A) is a cross-sectional structure along B1-B2 shown in FIG. 6, and FIG. 7 (B) is a cross-sectional structure along C1-C2 shown in FIG. Is a schematic cross-sectional view showing a method for manufacturing the vapor deposition mask 102 and the vapor deposition mask manufacturing apparatus 150, FIG. 9A is a cross-sectional structure along D1-D2 shown in FIG. 8, and FIG. 9B is a cross-sectional structure. It is a cross-sectional structure along E1-E2 shown in FIG. 8, and FIG. 10 shows the relationship between the thickness of the outermost periphery of the release layer 116 with respect to the height of the eaves when the plating process is performed using the vapor deposition mask manufacturing apparatus 150. 11 (A) to 17 (B) are schematic cross-sectional views showing a method of manufacturing the vapor deposition mask 102. The manufacturing method of the vapor deposition mask 102 or the configuration of the vapor deposition mask manufacturing apparatus 150 shown in FIGS. 3A to 17B is an example, and the manufacturing method of the vapor deposition mask 102 or the configuration of the vapor deposition mask manufacturing apparatus 150 is shown in FIG. The configuration is not limited to the configuration shown in 3 (A) to 17 (B). The same or similar configurations as those in FIGS. 1 and 2 will be omitted here.
 図3(A)は、第1支持基板110の第2の面110Aに、第1レジストマスク114を形成する段階を示す。本発明の一実施形態では、第1支持基板110は金属製である。第1支持基板110は、例えば銅(Cu)、アルミニウム(Al)、チタン(Ti)、鉄(Fe)、ニッケル(Ni)、コバルト(Co)、クロム(Cr)、モリブデン(Mo)、マンガン(Mn)などの金属材料、又はこれらの合金を用いて形成される。合金は、例えば鉄(Fe)とクロム(Cr)を含む合金、鉄(Fe)、ニッケル(Ni)、及びマンガン(Mn)の合金でもよく、合金には炭素(C)が含まれていてもよい。例えば、第1支持基板110は、鉄(Fe)を主成分とし、クロム(Cr)、ニッケル(Ni)を含有するステンレス鋼で形成されていてもよい。また、本発明の一実施形態では、第1支持基板110は金属製である例を示すが、第1支持基板110は金属製に限定されない。例えば、第1支持基板110は、ガラス、石英、セラミクス、プラスチックなどの絶縁物から形成されてもよい。本発明の一実施形態では、第1支持基板110は被めっき部材と呼ぶことがある。 FIG. 3A shows a step of forming the first resist mask 114 on the second surface 110A of the first support substrate 110. In one embodiment of the invention, the first support substrate 110 is made of metal. The first support substrate 110 is, for example, copper (Cu), aluminum (Al), titanium (Ti), iron (Fe), nickel (Ni), cobalt (Co), chromium (Cr), molybdenum (Mo), manganese (Mo). It is formed using a metal material such as Mn) or an alloy thereof. The alloy may be, for example, an alloy containing iron (Fe) and chromium (Cr), an alloy of iron (Fe), nickel (Ni), and manganese (Mn), even if the alloy contains carbon (C). good. For example, the first support substrate 110 may be made of stainless steel containing iron (Fe) as a main component and chromium (Cr) and nickel (Ni). Further, in one embodiment of the present invention, the first support substrate 110 is made of metal, but the first support substrate 110 is not limited to the metal. For example, the first support substrate 110 may be formed of an insulating material such as glass, quartz, ceramics, or plastic. In one embodiment of the present invention, the first support substrate 110 may be referred to as a member to be plated.
 第1レジストマスク114は、感光性の樹脂材料を用い、フォトリソグラフィによって形成する。感光性の樹脂材料としては、塗布型のフォトレジスト、又はドライフィルムレジスト(DFR)を用いることができる。第1レジストマスク114は、図1において示す蒸着マスクユニット100において、複数の蒸着マスク102が配置されるとき、それら(複数の蒸着マスク102全部)を囲む枠状の形態を有する。 The first resist mask 114 is formed by photolithography using a photosensitive resin material. As the photosensitive resin material, a coating type photoresist or a dry film resist (DFR) can be used. The first resist mask 114 has a frame-like shape surrounding the plurality of vapor deposition masks 102 (all of the plurality of vapor deposition masks 102) when the plurality of vapor deposition masks 102 are arranged in the vapor deposition mask unit 100 shown in FIG.
 図3(B)は、剥離層116を形成する段階を示す。剥離層116を形成する段階の詳細は後述する。剥離層116は、第1レジストマスク114が形成された第1支持基板110の第2の面110Aにおいて、枠状の第1レジストマスクから露出した領域に形成される。具体的には、蒸着マスク製造装置150を用いることで、剥離層116は、第2の面110Aに設けられた第1レジストマスク114に対して、第1の段差部156Aが設けられる側と、第1の段差部156Aが設けられる側の反対側の両方に設けられる。すなわち、剥離層116は、第1レジストマスク114が設けられない第2の面110Aの一部に設けられる。剥離層116は、例えば、蒸着マスク102を形成する材料と同じ金属材料を用いて形成される。すなわち、剥離層116は、金属膜を有する。剥離層116は、例えば、ニッケル(Ni)、銅(Cu)、チタン(Ti)、クロム(Cr)などの0価の金属材料を用いて形成される。剥離層116は、めっき法を用いて形成することができる。例えば、剥離層116は、第1支持基板110上にニッケルめっき処理によって作製される。めっき法を用いて剥離層116を形成する場合、第1支持基板110を洗浄し、第2の面110Aに離型剤が塗布されていてもよい。 FIG. 3B shows a stage of forming the release layer 116. Details of the steps for forming the release layer 116 will be described later. The release layer 116 is formed in a region exposed from the frame-shaped first resist mask on the second surface 110A of the first support substrate 110 on which the first resist mask 114 is formed. Specifically, by using the vapor deposition mask manufacturing apparatus 150, the release layer 116 is provided on the side where the first step portion 156A is provided with respect to the first resist mask 114 provided on the second surface 110A. The first step portion 156A is provided on both sides opposite to the side on which the first step portion 156A is provided. That is, the release layer 116 is provided on a part of the second surface 110A where the first resist mask 114 is not provided. The release layer 116 is formed, for example, by using the same metal material as the material forming the vapor deposition mask 102. That is, the release layer 116 has a metal film. The release layer 116 is formed by using a zero-valent metal material such as nickel (Ni), copper (Cu), titanium (Ti), and chromium (Cr). The release layer 116 can be formed by using a plating method. For example, the release layer 116 is formed on the first support substrate 110 by a nickel plating process. When the release layer 116 is formed by the plating method, the first support substrate 110 may be washed and the release agent may be applied to the second surface 110A.
 図3(C)は、第1レジストマスク114を除去する段階を示す。第1レジストマスク114は、剥離液により除去される。第1レジストマスク114が除去された領域には開口部118が形成される。換言すると、第1レジストマスク114が第1支持基板110上から除去され、剥離層116は開口部118を挟んで内側領域120と外側領域122に分離される。 FIG. 3C shows a step of removing the first resist mask 114. The first resist mask 114 is removed by the stripping liquid. An opening 118 is formed in the region from which the first resist mask 114 has been removed. In other words, the first resist mask 114 is removed from the first support substrate 110, and the release layer 116 is separated into an inner region 120 and an outer region 122 with the opening 118 interposed therebetween.
 剥離層116を形成する場合において、図4(A)に示すように、第1レジストマスク114の膜厚d1は、剥離層116の設計膜厚d2と同じまたは略同等に形成されていることが好ましい。剥離層116をめっき法で形成する場合、剥離層116は導電性を有する第1支持基板110の第2の面110A上から膜厚を増す方向に成長する。剥離層116が所望の設計膜厚d2となるまで成長したとき、第1レジストマスク114の上面が剥離層116に接しない程度の膜厚とすることで、後の第1レジストマスク114の剥離工程を良好に行うことができる。 When the release layer 116 is formed, as shown in FIG. 4A, the film thickness d1 of the first resist mask 114 is formed to be the same as or substantially the same as the design film thickness d2 of the release layer 116. preferable. When the release layer 116 is formed by a plating method, the release layer 116 grows in a direction of increasing the film thickness from the second surface 110A of the first support substrate 110 having conductivity. When the release layer 116 grows to a desired design film thickness d2, the upper surface of the first resist mask 114 has a film thickness that does not come into contact with the release layer 116, so that the subsequent release step of the first resist mask 114 Can be done well.
 一般的に、剥離層116を形成する段階では、蒸着マスク102の最外周に電界が集中する。その結果、蒸着マスク102の最外周の膜厚は、蒸着マスクの内側の膜厚と比較して厚くなる。したがって、図4(B)に示すように、剥離層116が第1レジストマスク114より厚く(d2>d1)形成され、第1レジストマスク114の上面に被さるように剥離層116が成長してしまう。このような状態で第1レジストマスク114を除去すると剥離層116の一部が剥がれてしまうことが問題となる。すなわち、第1レジストマスク114を剥離液に浸漬すると膨潤し、それに伴って第1レジストマスク114の上面に被さった剥離層116の一部が押し上げられるため、剥離層116が剥がれてしまう。剥離層116が剥がれてしまうと、後に剥離層116上に形成される蒸着マスク102は破損した不良品となってしまう。破損した蒸着マスクを用いて有機EL表示装置を製造すると、蒸着マスクの破損部分に対応する有機EL素子は発光層を蒸着されない。発光層を蒸着されない有機EL素子は発光しないため、有機EL表示装置では、表示不良となることが問題となる。 Generally, at the stage of forming the release layer 116, the electric field is concentrated on the outermost periphery of the vapor deposition mask 102. As a result, the film thickness on the outermost circumference of the vapor deposition mask 102 is thicker than the film thickness on the inside of the vapor deposition mask. Therefore, as shown in FIG. 4B, the release layer 116 is formed thicker than the first resist mask 114 (d2> d1), and the release layer 116 grows so as to cover the upper surface of the first resist mask 114. .. If the first resist mask 114 is removed in such a state, there is a problem that a part of the release layer 116 is peeled off. That is, when the first resist mask 114 is immersed in the release liquid, it swells, and a part of the release layer 116 covering the upper surface of the first resist mask 114 is pushed up accordingly, so that the release layer 116 is peeled off. If the peeling layer 116 is peeled off, the vapor deposition mask 102 later formed on the peeling layer 116 becomes a damaged defective product. When an organic EL display device is manufactured using a damaged vapor deposition mask, the light emitting layer is not vapor-deposited on the organic EL element corresponding to the damaged portion of the vapor deposition mask. Since the organic EL element on which the light emitting layer is not vapor-deposited does not emit light, there is a problem that the display is poor in the organic EL display device.
 前述した通り、めっき法により形成される剥離層116は、中央部よりも最外周付近で膜の成長が促進されやすく、膜厚が大きくなる傾向がある。従って、最外周付近で第1レジストマスク114の膜厚を剥離層116の膜厚が越えないような条件を設定すると、中央部付近での剥離層116の膜厚が不足する場合がある。 As described above, the release layer 116 formed by the plating method tends to have a larger film thickness because the growth of the film is more likely to be promoted in the vicinity of the outermost periphery than in the central portion. Therefore, if a condition is set so that the film thickness of the first resist mask 114 does not exceed the film thickness of the release layer 116 near the outermost periphery, the film thickness of the release layer 116 near the central portion may be insufficient.
 このような不具合を解消するために、本発明の一実施形態に係る蒸着マスク102の製造方法では、図3(B)に示す剥離層116を形成する段階を、図5に示す蒸着マスク製造装置150を用いて行う。具体的には、本発明の一実施形態に係る蒸着マスク102の製造方法では、図5及び図6に示す蒸着マスク製造装置150を用いて、図4(A)に示す構造を形成する。 In order to eliminate such a problem, in the method for manufacturing a vapor-filmed mask 102 according to an embodiment of the present invention, the step of forming the release layer 116 shown in FIG. 3B is the vapor-filmed mask manufacturing apparatus shown in FIG. This is done using 150. Specifically, in the method for manufacturing a vapor deposition mask 102 according to an embodiment of the present invention, the structure shown in FIG. 4A is formed by using the vapor deposition mask manufacturing apparatus 150 shown in FIGS. 5 and 6.
 図5は、蒸着マスク製造装置150において、一例として、第2の支持部材164が着脱自在な部材であり、第2の支持部材164が支持母材151の第1の面151A(図7(A))から取り外された態様を示し、図6は、蒸着マスク製造装置150において、第2の支持部材164が支持母材151の第1の面151A(図7(A))に取り着けられた態様を示す。図5又は図6に示すように、蒸着マスク製造装置150は、支持母材151と、第1支持基板110(図8)を収納する収納部152と、第1支持基板110の外縁部111(図8)を覆う枠型部154とを有する。収納部152は支持母材151と枠型部154との間に設けられる。 FIG. 5 shows, as an example, in the vapor deposition mask manufacturing apparatus 150, the second support member 164 is a detachable member, and the second support member 164 is the first surface 151A of the support base material 151 (FIG. 7 (A). )), In FIG. 6, the second support member 164 was attached to the first surface 151A (FIG. 7 (A)) of the support base material 151 in the vapor deposition mask manufacturing apparatus 150. The aspect is shown. As shown in FIG. 5 or FIG. 6, the vapor deposition mask manufacturing apparatus 150 includes a support base material 151, a storage portion 152 for accommodating the first support substrate 110 (FIG. 8), and an outer edge portion 111 of the first support substrate 110 (FIG. 8). It has a frame mold portion 154 that covers FIG. 8). The storage portion 152 is provided between the support base material 151 and the frame mold portion 154.
 枠型部154は、第1の支持部材162と、第2の支持部材164と、第1の支持部材162を支持母材151の第1の面151A(図7(A))に固定する固定部材166A及び166Bと、第2の支持部材164を支持母材151の第1の面151A(図7(A))に固定する固定部材168とを有する。また、枠型部154は、第1の支持部材162と、第2の支持部材164とによって設けられる開口部190を有する。 The frame form portion 154 is fixed to fix the first support member 162, the second support member 164, and the first support member 162 to the first surface 151A (FIG. 7A) of the support base material 151. It has members 166A and 166B, and a fixing member 168 for fixing the second support member 164 to the first surface 151A (FIG. 7A) of the support base material 151. Further, the frame form portion 154 has an opening 190 provided by the first support member 162 and the second support member 164.
 第1の支持部材162は、第1の庇部162A(図7(A)、図7(B))と、第1の壁部157Aとを有する。第1の支持部材162は、平面視において、コの字型の形状を有する。コの字型の形状は、第1の辺190Aと、第2の辺190Bと、第3の辺190Cを含む。第1の辺190Aは、第2の支持部材164に含まれる第4の辺190Dと向かい合う(対向する)。第2の辺190Bは、第3の辺190Cと向かい合う(対向する)。第1の庇部162A(図7(A)、図7(B))と、第1の壁部157Aとは、支持母材151の第1の面151A(図7(A))上に設けられる。第1の壁部157Aは、支持母材151の第1の面151Aの上部において、第1の面151Aと第1の庇部162Aとの間に、第1の面151Aと第1の庇部162Aとに接するように設けられる。第1の庇部162Aは、第1の壁部157Aの上部において、第1の面151Aの内側に向けて突出するように設けられる。第1の支持部材162は、固定部材166A、166B及び166Cによって、支持母材151の第1の面151Aに着脱自在である。固定部材166の個数は任意である。本発明の一実施形態では、固定部材166の個数は例えば8個である。 The first support member 162 has a first eaves portion 162A (FIGS. 7A and 7B) and a first wall portion 157A. The first support member 162 has a U-shape in a plan view. The U-shaped shape includes a first side 190A, a second side 190B, and a third side 190C. The first side 190A faces (opposes) the fourth side 190D included in the second support member 164. The second side 190B faces (opposes) the third side 190C. The first eaves portion 162A (FIGS. 7 (A) and 7 (B)) and the first wall portion 157A are provided on the first surface 151A (FIG. 7 (A)) of the support base material 151. Be done. The first wall portion 157A is formed on the upper portion of the first surface 151A of the support base material 151, between the first surface 151A and the first eaves portion 162A, with the first surface 151A and the first eaves portion. It is provided so as to be in contact with 162A. The first eaves portion 162A is provided so as to project inward of the first surface 151A at the upper part of the first wall portion 157A. The first support member 162 is detachable from the first surface 151A of the support base material 151 by the fixing members 166A, 166B and 166C. The number of fixing members 166 is arbitrary. In one embodiment of the present invention, the number of fixing members 166 is, for example, eight.
 第2の支持部材164は、電極部163と、第3の支持部材165と、第4の辺190Dと、第2の庇部165Aと、第2の壁部157Bとを有する。電極部163と、第3の支持部材165と、第4の辺190Dと、第2の庇部165Aと、第2の壁部157Bとは、支持母材151の第1の面151A(図7(A))上に設けられる。第2の壁部157Bは、支持母材151の第1の面151Aの上部において、支持母材151の第1の面151Aと第2の庇部165Aとの間に、支持母材151の第1の面151Aと第2の庇部165Aとに接するように設けられる。電極部163は、支持母材151の第1の面151Aの上部において、第1の面151Aと第2の庇部165Aとの間に、第2の庇部165Aに接するように設けられる。第2の庇部165Aは、電極部163の上部において、電極部163に接し、第1の面151Aの内側に向けて突出するように設けられる。第2の支持部材164は、固定部材168によって、支持母材151の第1の面151A(図7(A))に着脱自在である。固定部材168の個数は任意である。第3の支持部材165は、電極部163を取り囲むように設けられる。本発明の一実施形態では、固定部材168の個数は例えば2個である。例えば、第1の支持部材162又は第2の支持部材164の少なくともいずれか一方を支持母材151の第1の面151A(図7(A))から着脱自在とすることで、第1支持基板110(図8)を収納部152に収納することと、第1支持基板110(図8)を収納部152から取り外すこととが可能なる。 The second support member 164 has an electrode portion 163, a third support member 165, a fourth side 190D, a second eaves portion 165A, and a second wall portion 157B. The electrode portion 163, the third support member 165, the fourth side 190D, the second eaves portion 165A, and the second wall portion 157B are the first surface 151A of the support base material 151 (FIG. 7). (A)) Provided above. The second wall portion 157B is located on the upper portion of the first surface 151A of the support base material 151, between the first surface 151A of the support base material 151 and the second eaves portion 165A, and is the second support base material 151. It is provided so as to be in contact with the surface 151A of 1 and the second eaves portion 165A. The electrode portion 163 is provided on the upper portion of the first surface 151A of the support base material 151 between the first surface 151A and the second eaves portion 165A so as to be in contact with the second eaves portion 165A. The second eaves portion 165A is provided in the upper part of the electrode portion 163 so as to be in contact with the electrode portion 163 and to project inward of the first surface 151A. The second support member 164 is detachable from the first surface 151A (FIG. 7A) of the support base material 151 by the fixing member 168. The number of fixing members 168 is arbitrary. The third support member 165 is provided so as to surround the electrode portion 163. In one embodiment of the present invention, the number of fixing members 168 is, for example, two. For example, by making at least one of the first support member 162 and the second support member 164 removable from the first surface 151A (FIG. 7 (A)) of the support base material 151, the first support substrate. It is possible to store the 110 (FIG. 8) in the storage unit 152 and to remove the first support board 110 (FIG. 8) from the storage unit 152.
 図6と図7(A)と図7(B)に示すように、第2の支持部材164が第1の面151Aに取り着けられた態様では、第1の支持部材162と第2の支持部材164とは隣接して設けられ、第1の庇部162Aと第2の庇部165Aとは隣接して設けられ、第1の段差部156Aと第2の段差部156Bとは隣接して設けられ、第1の壁部157Aと第2の壁部157Bとは隣接して設けられる。また、開口部190は、第1の辺190Aと、第2の辺190Bと、第3の辺190Cと、第4の辺190Dとの4つの辺から構成される。長さL1は、第1の辺190Aと第4の辺190Dとの長さであり、第1の庇部162Aと第2の庇部165Aとの間の長さでもある。長さL2は、第2の辺190Bと第3の辺190Cとの長さであり、第1の庇部162Aと第1の庇部162Aとの間の長さでもある。また、収納部152の長さL3は、開口部190の長さL1に対応する長さであり、収納部152の長さL4は、開口部190の長さL2に対応する長さである。収納部152の長さL3は、第1の段差部156Aと第2の段差部156Bとの間の長さでもある。収納部152の長さL4は、第1の庇部162Aと第2の庇部165Aとの長さでもある。なお、本発明の一実施形態では、長さを距離とも呼ぶ。 As shown in FIGS. 6A, 7A and 7B, in the embodiment in which the second support member 164 is attached to the first surface 151A, the first support member 162 and the second support member 162 and the second support member are supported. The member 164 is provided adjacent to each other, the first eaves portion 162A and the second eaves portion 165A are provided adjacent to each other, and the first step portion 156A and the second step portion 156B are provided adjacent to each other. The first wall portion 157A and the second wall portion 157B are provided adjacent to each other. Further, the opening 190 is composed of four sides, a first side 190A, a second side 190B, a third side 190C, and a fourth side 190D. The length L1 is the length between the first side 190A and the fourth side 190D, and is also the length between the first eaves portion 162A and the second eaves portion 165A. The length L2 is the length between the second side 190B and the third side 190C, and is also the length between the first eaves portion 162A and the first eaves portion 162A. Further, the length L3 of the storage portion 152 is a length corresponding to the length L1 of the opening 190, and the length L4 of the storage portion 152 is a length corresponding to the length L2 of the opening 190. The length L3 of the storage portion 152 is also the length between the first step portion 156A and the second step portion 156B. The length L4 of the storage portion 152 is also the length of the first eaves portion 162A and the second eaves portion 165A. In one embodiment of the present invention, the length is also referred to as a distance.
 長さL1は長さL2よりも短く(小さく)、長さL3は長さL4よりも短く(小さく)は、長さL1は長さL3よりも短く(小さく)、長さL2は長さL4よりも短い(小さい)。すなわち、開口部190の開口部部分は、収納部152より小さい。また、開口部190の開口部部分は、第1支持基板110より小さい。よって、第1支持基板110が収納部152に、確実に収納及び固定されるため、蒸着マスク製造装置150をめっき浴に浸漬する際に、第1支持基板110の位置がずれることがない。その結果、第1支持基板110の上に形成される剥離層116の膜厚が剥離層116の中心部と外周部とで一様に形成され、剥離層116が面内で均一に形成される。本発明の一実施形態では、長さL1は第1の幅とよぶことがあり、長さL2は第2の幅とよぶことがあり、長さL3は第3の幅とよぶことがあり、長さL4は第4の幅とよぶことがある。 The length L1 is shorter (smaller) than the length L2, the length L3 is shorter (smaller) than the length L4, the length L1 is shorter (smaller) than the length L3, and the length L2 is the length L4. Shorter (smaller) than. That is, the opening portion of the opening 190 is smaller than the storage portion 152. Further, the opening portion of the opening 190 is smaller than the first support substrate 110. Therefore, since the first support substrate 110 is securely stored and fixed in the storage portion 152, the position of the first support substrate 110 does not shift when the vapor deposition mask manufacturing apparatus 150 is immersed in the plating bath. As a result, the film thickness of the release layer 116 formed on the first support substrate 110 is uniformly formed at the central portion and the outer peripheral portion of the release layer 116, and the release layer 116 is uniformly formed in the plane. .. In one embodiment of the invention, the length L1 may be referred to as the first width, the length L2 may be referred to as the second width, and the length L3 may be referred to as the third width. The length L4 is sometimes called the fourth width.
 図7(A)と図7(B)によれば、固定部材166Aが、第1の支持部材162に設けられる開口部176Aと、支持母材151に設けられる開口部186Aとを貫通し、固定部材166Bが、第1の支持部材162に設けられる開口部176Bと、支持母材151に設けられる開口部186Bとを貫通し、固定部材166Cが、第1の支持部材162に設けられる開口部176Cと、支持母材151に設けられる開口部186Cとを貫通することで、第1の支持部材162が第1の面151Aに取り着けられ、固定される。また、固定部材168が、第3の支持部材165に設けられる開口部178と、電極部163に設けられる開口部173と、支持母材151に設けられる開口部186Dとを貫通することで、第2の支持部材164が第1の面151Aに取り着けられ、固定される。 According to FIGS. 7A and 7B, the fixing member 166A penetrates and fixes the opening 176A provided in the first support member 162 and the opening 186A provided in the support base material 151. The member 166B penetrates the opening 176B provided in the first support member 162 and the opening 186B provided in the support base material 151, and the fixing member 166C is an opening 176C provided in the first support member 162. The first support member 162 is attached to and fixed to the first surface 151A by penetrating the opening 186C provided in the support base material 151. Further, the fixing member 168 penetrates the opening 178 provided in the third support member 165, the opening 173 provided in the electrode portion 163, and the opening 186D provided in the support base material 151. The support member 164 of 2 is attached to and fixed to the first surface 151A.
 図7(A)に示すように、第1の壁部157Aは、第1の部分157Cと、第1の段差部156Aとを有する。第1の部分157Cは、第1の面151Aから所定の高さKに亘って高さが減少するように設けられる。第1の段差部156Aは、第1の部分157Cによって第1の壁部157Aの内側面に設けられる。第2の壁部157Bは、第2の段差部156Bを有する。第2の段差部156Bは、第2の壁部157Bの内側面に第1の面151Aから所定の高さKで電極部163が突出することで形成される。電極部163は、第1の面151Aから所定の高さK離れて設けられ、第2の支持部材164(第3の支持部材165)の第2の庇部165Aに対して反対側に突出している。電極部163が、第2の庇部165Aに対して反対側に突出することで、クリップなどの接続部材が電極部163に接続されやすくなる。その結果、後述するめっき処理の際に、接続部材を経由して電極部163に電圧が印加され易くなる。 As shown in FIG. 7A, the first wall portion 157A has a first portion 157C and a first step portion 156A. The first portion 157C is provided so that the height decreases from the first surface 151A over a predetermined height K. The first step portion 156A is provided on the inner surface of the first wall portion 157A by the first portion 157C. The second wall portion 157B has a second step portion 156B. The second step portion 156B is formed by projecting the electrode portion 163 from the first surface 151A at a predetermined height K on the inner surface of the second wall portion 157B. The electrode portion 163 is provided at a predetermined height K away from the first surface 151A, and projects to the opposite side of the second eaves portion 165A of the second support member 164 (third support member 165). There is. By projecting the electrode portion 163 to the opposite side with respect to the second eaves portion 165A, a connecting member such as a clip can be easily connected to the electrode portion 163. As a result, a voltage is easily applied to the electrode portion 163 via the connecting member during the plating process described later.
 図8、図9(A)及び図9(B)は、蒸着マスク製造装置150を用いて剥離層116を形成する段階を示す。以降の説明では、図1乃至図7(B)と同一、又は類似する構成についての説明を省略する場合がある。 8, 9 (A) and 9 (B) show the steps of forming the release layer 116 using the vapor deposition mask manufacturing apparatus 150. In the following description, the description of the same or similar configuration as in FIGS. 1 to 7 (B) may be omitted.
 図8、図9(A)及び図9(B)に示すように、剥離層116を形成する段階では、第1支持基板110を収納部152に収納し、固定する。具体的には、第1支持基板110を支持母材151の第1の面151Aに載置し、第1支持基板110の周囲の少なくとも2辺を、第1の支持部材162のコの字型の形状の角部を挟んだ少なくとも2辺に突き当てる。例えば、第1支持基板110の2辺を、収納部152の第1の辺190Aと第2の辺190Bとに第3の辺190C)に、突き当てる。 As shown in FIGS. 8, 9 (A) and 9 (B), at the stage of forming the release layer 116, the first support substrate 110 is stored in the storage portion 152 and fixed. Specifically, the first support substrate 110 is placed on the first surface 151A of the support base material 151, and at least two sides around the first support substrate 110 are U-shaped of the first support member 162. It hits at least two sides of the corner of the shape of. For example, the two sides of the first support board 110 are abutted against the first side 190A and the second side 190B of the storage portion 152 and the third side 190C).
 このとき、第1支持基板110の点線の円162C(図9(A))に示すように、第1支持基板110の1辺の外縁部111は、第1の段差部156Aに突き当たる。換言すると、第1支持基板110の外縁部111の一部は、第1の支持部材162の第1の段差部156Aに嵌め込まれ、第1支持基板110は第1の面151Aと第1の段差部156Aとの間に挟みこまれる。 At this time, as shown by the dotted circle 162C (FIG. 9A) of the first support board 110, the outer edge portion 111 of one side of the first support board 110 abuts on the first step portion 156A. In other words, a part of the outer edge portion 111 of the first support board 110 is fitted into the first step portion 156A of the first support member 162, and the first support board 110 has the first surface 151A and the first step. It is sandwiched between the portion 156A and the portion 156A.
 次に、第2の支持部材164を支持母材151の第1の面151Aに取り着け、固定する。このとき、点線の円164C(図9(A))に示すように、第1支持基板110の1辺の外縁部111は、第2の段差部156Bに突き当たる。換言すると、第1支持基板110の外縁部111の一部は、第2の支持部材164の第2の段差部156Bに嵌め込まれ、第1支持基板110は第1の面151Aと第2の段差部156Bとの間に挟みこまれる。第1支持基板110の第2の面110Aの一部は、開口部190に対して露出され、第1支持基板110の第2の面110Aの残りの一部は、枠型部154に覆われる。 Next, the second support member 164 is attached to and fixed to the first surface 151A of the support base material 151. At this time, as shown in the dotted circle 164C (FIG. 9A), the outer edge portion 111 of one side of the first support substrate 110 abuts on the second step portion 156B. In other words, a part of the outer edge portion 111 of the first support board 110 is fitted into the second step portion 156B of the second support member 164, and the first support board 110 has the first surface 151A and the second step. It is sandwiched between the portion 156B and the portion 156B. A part of the second surface 110A of the first support board 110 is exposed to the opening 190, and the remaining part of the second surface 110A of the first support board 110 is covered with the frame portion 154. ..
 結果として、第1の支持部材162及び第2の支持部材164は、第1の面151A上で、第1支持基板110の外周を囲むように設けられる。また、支持母材151の第1の面151Aは、第1支持基板110を支持ずることができる。 As a result, the first support member 162 and the second support member 164 are provided on the first surface 151A so as to surround the outer periphery of the first support substrate 110. Further, the first surface 151A of the support base material 151 can support the first support substrate 110.
 続いて、第1支持基板110が収納された蒸着マスク製造装置150をめっき浴に浸漬する。めっき浴に充填された金属材料を含む溶液と、電極部163との間に電圧を印加することで、めっき処理を行う。蒸着マスク製造装置150を用いることで、剥離層116は導電性を有する第1支持基板110の第2の面110A上から膜厚が増す方向に成長し、第1支持基板110の第2の面110A上に剥離層116を形成することができる。換言すると、剥離層116は、第2の面110Aに設けられた第1レジストマスク114に対して、第1の段差部156Aが設けられる側と、第1の段差部156Aが設けられる側の反対側の両方に設けられる。すなわち、剥離層116は、第1レジストマスク114が設けられない第2の面110Aの一部に設けられる。剥離層116は、金属材料を用いて形成された金属膜を有する。 Subsequently, the vapor deposition mask manufacturing apparatus 150 in which the first support substrate 110 is housed is immersed in a plating bath. The plating process is performed by applying a voltage between the solution containing the metal material filled in the plating bath and the electrode portion 163. By using the vapor deposition mask manufacturing apparatus 150, the release layer 116 grows from the top of the second surface 110A of the conductive first support substrate 110 in the direction of increasing the film thickness, and the second surface of the first support substrate 110 is used. The release layer 116 can be formed on the 110A. In other words, the release layer 116 is opposite to the side where the first step portion 156A is provided and the side where the first step portion 156A is provided with respect to the first resist mask 114 provided on the second surface 110A. Provided on both sides. That is, the release layer 116 is provided on a part of the second surface 110A where the first resist mask 114 is not provided. The release layer 116 has a metal film formed by using a metal material.
 図9(A)に示すように、第1の支持部材162又は第1の庇部162Aは第1レジストマスク114と第1支持基板110の第2の面110Aの一部とを覆う。D1-D2に沿った断面構造(断面視)において、第1の庇部162Aの第1支持基板110に面した部分と、第2の面110Aとの距離Hは、例えば、10mmである。また、第1の支持部材162の第1の庇部162Aの端部と第2の面110Aに設けられた第1レジストマスク114の端部との距離Wは、例えば4mmである。このとき、剥離層116の設計膜厚d2は、120μmである。本発明の一実施形態において、距離Hは庇部の高さともよばれ、距離Wは被覆幅ともよばれる。 As shown in FIG. 9A, the first support member 162 or the first eaves portion 162A covers a part of the first resist mask 114 and the second surface 110A of the first support substrate 110. In the cross-sectional structure (cross-sectional view) along D1-D2, the distance H between the portion of the first eaves portion 162A facing the first support substrate 110 and the second surface 110A is, for example, 10 mm. Further, the distance W between the end portion of the first eaves portion 162A of the first support member 162 and the end portion of the first resist mask 114 provided on the second surface 110A is, for example, 4 mm. At this time, the design film thickness d2 of the release layer 116 is 120 μm. In one embodiment of the present invention, the distance H is also referred to as the height of the eaves, and the distance W is also referred to as the covering width.
 第2の支持部材164又は第2の庇部165Aは第1レジストマスク114と第1支持基板110の第2の面110Aの一部とを覆う。D1-D2に沿った断面構造(断面視)において、第2の庇部165Aの第1支持基板110に面した部分(面)と、第2の面110Aとの距離Hは、例えば10mmであり、第3の支持部材165の第2の庇部165Aの端部と第2の面110Aに設けられた第1レジストマスク114の端部との距離Wは、例えば4mmであり、第2の庇部165Aが第1支持基板110を覆う長さは、第1の庇部162Aが第1支持基板110を覆う長さより長い(大きい)。 The second support member 164 or the second eaves portion 165A covers a part of the first resist mask 114 and the second surface 110A of the first support substrate 110. In the cross-sectional structure (cross-sectional view) along D1-D2, the distance H between the portion (plane) of the second eaves portion 165A facing the first support substrate 110 and the second surface 110A is, for example, 10 mm. The distance W between the end of the second eaves 165A of the third support member 165 and the end of the first resist mask 114 provided on the second surface 110A is, for example, 4 mm, and the second eaves. The length of the portion 165A covering the first support substrate 110 is longer (larger) than the length of the first eaves portion 162A covering the first support substrate 110.
 図9(B)に示すように、第1の支持部材162は第1レジストマスク114と第1支持基板110とを覆う。また、D1-D2に沿った断面構造(断面視)と同様に、E1-E2に沿った断面構造(断面視)においても、第1の庇部162Aの第1支持基板110に面した部分(面)と、第2の面110Aとの距離Hは10mmであり、第1の庇部162Aの端部と第2の面110Aに設けられた第1レジストマスク114の端部との距離Wは4mmであり、剥離層116の設計膜厚d2は120μmである。 As shown in FIG. 9B, the first support member 162 covers the first resist mask 114 and the first support substrate 110. Further, in the cross-sectional structure along E1-E2 (cross-sectional view) as well as the cross-sectional structure along D1-D2 (cross-sectional view), the portion of the first eaves portion 162A facing the first support substrate 110 (the portion facing the first support substrate 110). The distance H between the surface) and the second surface 110A is 10 mm, and the distance W between the end portion of the first eaves portion 162A and the end portion of the first resist mask 114 provided on the second surface 110A is It is 4 mm, and the design film thickness d2 of the release layer 116 is 120 μm.
 第1支持基板110を収納部152に収納し、固定するとき、第1支持基板110は第1の支持部材162のコの字型の形状の角部を挟んだ少なくとも2辺に突き当て、第1支持基板110が第1の支持部材162及び第2の支持部材164(第3の支持部材165)の一部に入り込む。その結果、第1支持基板110が収納部152に安定的に固定されるため、第1支持基板110の上に形成される剥離層116の膜厚が剥離層116の中心部と外周部とで一様に形成され、剥離層116が面内で均一に形成される。 When the first support board 110 is stored in the storage portion 152 and fixed, the first support board 110 abuts against at least two sides of the first support member 162 having a U-shaped corner portion sandwiched between them. 1 The support substrate 110 enters a part of the first support member 162 and the second support member 164 (third support member 165). As a result, the first support substrate 110 is stably fixed to the storage portion 152, so that the film thickness of the release layer 116 formed on the first support substrate 110 is increased between the central portion and the outer peripheral portion of the release layer 116. It is uniformly formed, and the release layer 116 is uniformly formed in the plane.
 また、本発明の一実施形態に係る蒸着マスク製造装置150は、開口部190を有し、距離Wと距離Hとが所定の値で構成されるため、第1の庇部162Aが第1支持基板110及び第1レジストマスク114を覆うことができる。その結果、蒸着マスク製造装置150は、蒸着マスク製造装置150内における、めっき浴に充填された金属材料を含む溶液の循環を制御することができる。つまり、第1支持基板110の最外周付近では、溶液の循環が抑制されることにより、剥離層116の成長に伴って近傍の溶液中のイオン濃度が低下する。それに伴い、第1支持基板110の最外周付近での剥離層116の成長速度が低下するため、中央部に比べて膜厚が大きくなるのを抑制することができる。したがって、蒸着マスク製造装置150は、循環を制御された金属材料を剥離層116として、第1支持基板110の上に均一に形成し、剥離層116の膜厚を剥離層116の中心部と外周部とで一様に形成することができる。 Further, since the vapor deposition mask manufacturing apparatus 150 according to the embodiment of the present invention has an opening 190 and the distance W and the distance H are composed of predetermined values, the first eaves portion 162A is the first support. The substrate 110 and the first resist mask 114 can be covered. As a result, the vapor deposition mask manufacturing apparatus 150 can control the circulation of the solution containing the metal material filled in the plating bath in the vapor deposition mask manufacturing apparatus 150. That is, in the vicinity of the outermost periphery of the first support substrate 110, the circulation of the solution is suppressed, so that the ion concentration in the nearby solution decreases as the peeling layer 116 grows. Along with this, the growth rate of the release layer 116 near the outermost periphery of the first support substrate 110 decreases, so that it is possible to suppress the film thickness from becoming larger than that in the central portion. Therefore, the thin-film mask manufacturing apparatus 150 uniformly forms the metal material whose circulation is controlled as the release layer 116 on the first support substrate 110, and adjusts the film thickness of the release layer 116 to the central portion and the outer periphery of the release layer 116. It can be formed uniformly with the parts.
 図10に示すように、例えば、距離H(庇部の高さH)が3.5mmのとき、剥離層116の最外周の膜厚は19.5μm以上20.5μm以下であり、距離H(庇部の高さH)が6mmのとき、剥離層116の最外周の膜厚は59.5μm以上60.5μm以下であり、距離H(庇部の高さH)が9mmのとき、剥離層116の最外周の膜厚は99.5μm以上100.5μm以下であり、距離H(庇部の高さH)が10mmのとき、剥離層116の最外周の膜厚は119.5μm以上120.5μm以下である。すなわち、剥離層116の設計膜厚d2を設定した場合、図10を用いて距離H(庇部の高さH)を設定することができる。例えば、本発明の一実施形態では、上述のように、距離H(庇部の高さH)が10mmとすることで、剥離層116の設計膜厚d2が120μmとすることができる。 As shown in FIG. 10, for example, when the distance H (height H of the eaves portion) is 3.5 mm, the film thickness of the outermost circumference of the release layer 116 is 19.5 μm or more and 20.5 μm or less, and the distance H ( When the height H of the eaves is 6 mm, the thickness of the outermost circumference of the release layer 116 is 59.5 μm or more and 60.5 μm or less, and when the distance H (height H of the eaves) is 9 mm, the release layer The outermost peripheral thickness of the 116 is 99.5 μm or more and 100.5 μm or less, and when the distance H (height H of the eaves) is 10 mm, the outermost peripheral film thickness of the release layer 116 is 119.5 μm or more and 120. It is 5 μm or less. That is, when the design film thickness d2 of the release layer 116 is set, the distance H (height H of the eaves portion) can be set using FIG. For example, in one embodiment of the present invention, as described above, the design film thickness d2 of the release layer 116 can be 120 μm by setting the distance H (height H of the eaves) to 10 mm.
 本発明の一実施形態に係る蒸着マスク製造装置150は、開口部190を有し、図10に基づいて、距離Wと距離Hとが所定の値で構成され、剥離層116の膜厚を制御することができる。その結果、剥離層116の膜厚が中央部と最外周付近との間でばらつきを生ずることがないため、後述する、剥離層116を第1支持基板110の第2の面110Aから剥離する段階において、剥離層116が剥がれること、破損することなどを抑制することができる。 The vapor deposition mask manufacturing apparatus 150 according to the embodiment of the present invention has an opening 190, and the distance W and the distance H are configured by predetermined values based on FIG. 10, and the film thickness of the release layer 116 is controlled. can do. As a result, since the film thickness of the release layer 116 does not vary between the central portion and the vicinity of the outermost periphery, the step of peeling the release layer 116 from the second surface 110A of the first support substrate 110, which will be described later. In the above, it is possible to prevent the peeling layer 116 from being peeled off or damaged.
 図11(A)は、剥離層116の上に接着層124を設ける段階を示す。接着層124は、未露光の状態で所定の接着力又は粘着力を有するレジストフィルムを用いることが好ましい。レジストフィルムは、例えば、ドライフィルムレジストである。接着層124は剥離層116の内側領域120の全面を覆い、接着層124の端部が剥離層116の外側に広がっていることが好ましい。接着層124の端部は、剥離層116の外側領域122まで広がっていてもよい。フィルム状の部材として供給される剥離層116がこのような大きさを有することで、剥離層116の内側領域を確実に覆うことができる。 FIG. 11A shows a stage in which the adhesive layer 124 is provided on the release layer 116. As the adhesive layer 124, it is preferable to use a resist film having a predetermined adhesive strength or adhesive strength in an unexposed state. The resist film is, for example, a dry film resist. It is preferable that the adhesive layer 124 covers the entire surface of the inner region 120 of the release layer 116, and the end portion of the adhesive layer 124 extends to the outside of the release layer 116. The end of the adhesive layer 124 may extend to the outer region 122 of the release layer 116. Since the release layer 116 supplied as a film-like member has such a size, the inner region of the release layer 116 can be reliably covered.
 図11(B)に示すように、接着層124の外周部は未露光であり、接着層124の内側領域は露光されてもよい。具体的には、接着層124において、剥離層116の端部と重なる領域を含む外周部132を未露光領域とし、外周部132より内側の領域を露光して露光領域とし、外周部132より内側の領域の露光面を硬化させる処理を行ってもよい。外側領域122(露光処理される領域)は、少なくとも一部が剥離層116と重なっていることが好ましい。接着層124の選択的な露光は、フォトマスクを用いて行うことができる。例えば、接着層124として用いられる感光性のドライフィルムレジストがポジ型である場合、透光部130を囲むように遮光部129が形成された第1フォトマスク126が用いられる。このような露光処理により、接着層124には、外側領域122(未露光領域)と比べて硬化し、接着力が低下した領域(外側領域122の内側の領域)が形成される。 As shown in FIG. 11B, the outer peripheral portion of the adhesive layer 124 is unexposed, and the inner region of the adhesive layer 124 may be exposed. Specifically, in the adhesive layer 124, the outer peripheral portion 132 including the region overlapping the end portion of the peeling layer 116 is set as an unexposed region, and the region inside the outer peripheral portion 132 is exposed to be an exposed region, and is inside the outer peripheral portion 132. A process of curing the exposed surface in the region may be performed. It is preferable that at least a part of the outer region 122 (the region to be exposed) overlaps with the release layer 116. Selective exposure of the adhesive layer 124 can be performed using a photomask. For example, when the photosensitive dry film resist used as the adhesive layer 124 is of the positive type, the first photomask 126 in which the light-shielding portion 129 is formed so as to surround the translucent portion 130 is used. By such an exposure process, the adhesive layer 124 is formed with a region (region inside the outer region 122) that is hardened as compared with the outer region 122 (unexposed region) and has a reduced adhesive strength.
 なお、ドライフィルムレジストは、上述のように、露光処理によって表面の粘着力は失われるが、未露光の状態で既に他の表面と接している箇所は、光照射により硬化した後も、その接着力を維持する。 As described above, the adhesive force on the surface of the dry film resist is lost by the exposure treatment, but the portion that is already in contact with another surface in the unexposed state is adhered even after being cured by light irradiation. Maintain power.
 図12(A)は、第2支持基板112の第2の面112Aに接着層124を密接させて、剥離層116を第1支持基板110ごと張り合わせる段階を示す。このとき、接着層124の大部分は露光されており、その表面は粘着力を失っている。よって第2支持基板112は、接着層124の未露光の外周部132において固定される。一方、接着層124と剥離層116との界面は、露光前の時点で既に密着させており、露光によって粘着力は失われるものの、ある程度の密着力は保たれている。なお、第2支持基板112は、第1支持基板110と同様の材料で形成される。 FIG. 12A shows a step in which the adhesive layer 124 is brought into close contact with the second surface 112A of the second support substrate 112, and the release layer 116 is bonded together with the first support substrate 110. At this time, most of the adhesive layer 124 is exposed, and its surface loses its adhesive strength. Therefore, the second support substrate 112 is fixed at the unexposed outer peripheral portion 132 of the adhesive layer 124. On the other hand, the interface between the adhesive layer 124 and the release layer 116 is already in close contact with each other before the exposure, and although the adhesive force is lost by the exposure, the adhesive force is maintained to some extent. The second support substrate 112 is made of the same material as the first support substrate 110.
 また、未露光の外周部132と剥離層116との界面は、貼り合わせ後にベーク処理を行うことで、密着性を増すことができる。ベーク処理の条件は、例えば、60℃、1時間である。 Further, the interface between the unexposed outer peripheral portion 132 and the peeling layer 116 can be improved in adhesion by performing a baking treatment after bonding. The baking treatment conditions are, for example, 60 ° C. for 1 hour.
 図12(B)は、剥離層116を第1支持基板110の第2の面110Aから剥離する段階を示す。剥離層116は、第1支持基板110との界面に物理的な力を作用させることで、第1支持基板110から剥離することができる。例えば、鋭利な先端を有する治具を、第1支持基板110と剥離層116との界面に押し当てて剥離のきっかけとなる部分を形成し、その後、第1支持基板110を引き剥がすように外力を加えることで、剥離層116を第1支持基板110から剥離することができる。 FIG. 12B shows a step of peeling the peeling layer 116 from the second surface 110A of the first support substrate 110. The peeling layer 116 can be peeled from the first support substrate 110 by applying a physical force to the interface with the first support substrate 110. For example, a jig having a sharp tip is pressed against the interface between the first support substrate 110 and the release layer 116 to form a portion that triggers peeling, and then an external force is applied so as to peel off the first support substrate 110. Can be added to peel off the release layer 116 from the first support substrate 110.
 図13(A)は、剥離層116が設けられた第2支持基板112上に、第2レジストマスク138を形成する段階を示す。第2レジストマスク138は所定のパターンで形成される。すなわち、第2レジストマスク138は、複数の開口103、及び後述するダミーパターン140を形成する領域に選択的に形成される。例えば、ネガ型のフォトレジストを剥離層116上に塗布し、複数の開口103とダミーパターン140を形成する領域が選択的に露光されるように、フォトマスクを用いて露光を行う。また、ポジ型のフォトレジストを剥離層116上に塗布し、非開口部が選択的に露光されるように、フォトマスクを用いて露光を行う。その後、現像を行うことで、パターニングされた第2レジストマスク138を得ることができる。なお、第2レジストマスク138は、剥離層116を蒸着マスクユニット100から容易に剥離することができるように、剥離層116の外縁部にも形成することが好ましい。 FIG. 13A shows a step of forming the second resist mask 138 on the second support substrate 112 provided with the release layer 116. The second resist mask 138 is formed in a predetermined pattern. That is, the second resist mask 138 is selectively formed in the plurality of openings 103 and the region forming the dummy pattern 140 described later. For example, a negative photoresist is applied onto the release layer 116, and exposure is performed using a photomask so that the regions forming the plurality of openings 103 and the dummy pattern 140 are selectively exposed. Further, a positive photoresist is applied on the release layer 116, and exposure is performed using a photomask so that the non-opening is selectively exposed. Then, by developing, a patterned second resist mask 138 can be obtained. It is preferable that the second resist mask 138 is also formed on the outer edge portion of the peeling layer 116 so that the peeling layer 116 can be easily peeled from the vapor deposition mask unit 100.
 図13(B)は、めっき法を用いて、第2レジストマスク138によって被覆されていない領域にめっきパターンを形成し、蒸着マスク102を形成する段階を示す。めっきパターンの形成は、一段階で行ってもよく、数段階に分けて行ってもよい。複数の段階で行う場合、異なる段階で異なる金属が形成されるように、めっき処理を行ってもよい。また、めっき処理は、めっきパターンの上面が第2レジストマスク138の上面よりも低くなるように行ってもよく、高くなるように行ってもよい。後者の場合、めっきパターンの上面(表面)を研磨することでめっきパターン上面の平坦化を行ってもよい。次に、図13(C)に示すように、第2レジストマスク138を剥離液によるエッチング、及び/又はアッシングによって除去することで、剥離層116上に複数の開口103によってマスクパターンが形成される蒸着マスク102を製造することができる。 FIG. 13B shows a stage in which a plating pattern is formed in a region not covered by the second resist mask 138 by using a plating method to form a vapor deposition mask 102. The plating pattern may be formed in one step or may be divided into several steps. When performing in a plurality of stages, the plating treatment may be performed so that different metals are formed in different stages. Further, the plating treatment may be performed so that the upper surface of the plating pattern is lower or higher than the upper surface of the second resist mask 138. In the latter case, the upper surface (surface) of the plating pattern may be polished to flatten the upper surface of the plating pattern. Next, as shown in FIG. 13C, by removing the second resist mask 138 by etching with a release liquid and / or ashing, a mask pattern is formed on the release layer 116 by the plurality of openings 103. The vapor deposition mask 102 can be manufactured.
 なお、図13(B)及び図13(C)に示すように、蒸着マスク102を形成するとき、蒸着マスク102から離隔するダミーパターン140が形成される。ダミーパターン140は、平面視において複数の蒸着マスク102を囲むように構成される。ダミーパターン140と蒸着マスク102は同時に形成されるため、これらは互いに同一の組成と厚さを有することができる。 As shown in FIGS. 13B and 13C, when the vapor deposition mask 102 is formed, a dummy pattern 140 separated from the vapor deposition mask 102 is formed. The dummy pattern 140 is configured to surround the plurality of vapor deposition masks 102 in a plan view. Since the dummy pattern 140 and the vapor deposition mask 102 are formed at the same time, they can have the same composition and thickness as each other.
 図14(A)は、蒸着マスク102のマスクパターン104を保護するための保護フィルム142の一態様を示す。保護フィルム142は、ドライフィルムレジストを用いることができる。保護フィルム142は、例えば、光硬化性樹脂膜144が、剥離膜145と保護膜146とによって挟まれた構造を有する。光硬化性樹脂膜144には、ネガ型の光硬化性樹脂が含まれる。すなわち、光によって硬化する高分子又はオリゴマーが含まれる。光硬化性樹脂膜144の厚さは任意に選択することができ、例えば、20μm以上500μm以下、50μm以上200μm以下、又は50μm以上120μm以下の範囲から選択することができる。保護膜146は高分子材料を含む。高分子材料は、例えばポリオレフィン、ポリイミド、ポリエステル、ポリスチレン、又はフッ素含有ポリオレフィンなどから選択することができる。 FIG. 14A shows one aspect of the protective film 142 for protecting the mask pattern 104 of the vapor deposition mask 102. A dry film resist can be used for the protective film 142. The protective film 142 has, for example, a structure in which a photocurable resin film 144 is sandwiched between a release film 145 and a protective film 146. The photocurable resin film 144 contains a negative type photocurable resin. That is, it contains a polymer or oligomer that is cured by light. The thickness of the photocurable resin film 144 can be arbitrarily selected, and can be selected from, for example, 20 μm or more and 500 μm or less, 50 μm or more and 200 μm or less, or 50 μm or more and 120 μm or less. The protective film 146 contains a polymer material. The polymer material can be selected from, for example, polyolefin, polyimide, polyester, polystyrene, fluorine-containing polyolefin and the like.
 図14(B)は、保護フィルム142が蒸着マスク102の上に配置された状態を示す。保護フィルム142は、剥離膜145を剥離した後、光硬化性樹脂膜144が蒸着マスク102と保護膜146によって挟まれるように配置される。保護フィルム142は、少なくとも全てのマスクパターン104を覆うように設けられる。 FIG. 14B shows a state in which the protective film 142 is placed on the vapor deposition mask 102. After the release film 145 is peeled off, the protective film 142 is arranged so that the photocurable resin film 144 is sandwiched between the vapor deposition mask 102 and the protective film 146. The protective film 142 is provided so as to cover at least all the mask patterns 104.
 次に、光硬化性樹脂膜144を露光する。具体的には、図15に示すように、遮光部129と透光部130を有する第2フォトマスク128を、透光部130がマスクパターン104と重なるように配置し、第2フォトマスク128を用いて露光を行う。その結果、露光された部分の現像液に対する溶解性が低下する。 Next, the photocurable resin film 144 is exposed. Specifically, as shown in FIG. 15, the second photomask 128 having the light-shielding portion 129 and the translucent portion 130 is arranged so that the translucent portion 130 overlaps with the mask pattern 104, and the second photomask 128 is placed. Use to expose. As a result, the solubility of the exposed portion in the developer is reduced.
 図16(A)は、光硬化性樹脂膜144を露光した後、保護膜146を剥離して現像を行い、マスクパターン104の上に第3レジストマスク148が形成された状態を示す。図16(A)に示されるように、剥離層116の上に複数のマスクパターン104が形成される場合には、それぞれのマスクパターン104ごとに第3レジストマスク148が設けられる。なお、ダミーパターン140の上には後の工程で支持フレームが形成されるため、第3レジストマスク148は設けられていない。 FIG. 16A shows a state in which the protective film 146 is peeled off and developed after the photocurable resin film 144 is exposed, and the third resist mask 148 is formed on the mask pattern 104. As shown in FIG. 16A, when a plurality of mask patterns 104 are formed on the release layer 116, a third resist mask 148 is provided for each mask pattern 104. Since the support frame is formed on the dummy pattern 140 in a later step, the third resist mask 148 is not provided.
 図16(B)は、ダミーパターン140の上に支持フレーム108を配置する段階を示す。支持フレーム108は、複数のマスクパターン104が形成されるとき、それぞれのマスクパターンの間に配置される。支持フレーム108は、外郭のパターンが幅広であり、外郭のパターンの内側に形成されるパターン(マスクパターン104の間に形成されるパターン)が幅狭の形態を有していてもよい。 FIG. 16B shows a step of arranging the support frame 108 on the dummy pattern 140. The support frame 108 is arranged between the respective mask patterns when the plurality of mask patterns 104 are formed. The support frame 108 may have a wide outer shell pattern and a narrow pattern formed inside the outer shell pattern (a pattern formed between the mask patterns 104).
 図17(A)は、めっき法を用い、接続部106を形成する段階を示す。接続部106では、蒸着マスク102の表面のうち支持フレーム108と第3レジストマスク148に覆われていない部分から主に、金属材料が堆積する。その結果、図17(A)に示すように、蒸着マスク102の上面、及び支持フレーム108の側面に接する接続部106が形成される。接続部106が形成されることにより、蒸着マスク102と支持フレーム108が接続され、固定される。 FIG. 17A shows a stage of forming the connection portion 106 by using the plating method. In the connection portion 106, the metal material is mainly deposited from the portion of the surface of the vapor deposition mask 102 that is not covered by the support frame 108 and the third resist mask 148. As a result, as shown in FIG. 17A, a connecting portion 106 in contact with the upper surface of the vapor deposition mask 102 and the side surface of the support frame 108 is formed. By forming the connecting portion 106, the vapor deposition mask 102 and the support frame 108 are connected and fixed.
 接続部106を形成した結果、接続部106の厚さは第3レジストマスク148の厚さと同じであってもよく、接続部106の厚さは第3レジストマスク148の厚さよりも小さくてもよく、図17(A)に示すように、接続部106の厚さは第3レジストマスク148の厚さよりも大きくてもよい。接続部106の厚さが第3レジストマスク148の厚さよりも大きい場合、蒸着マスク102と支持フレーム108との間は、より強固に結合する。一方、接続部106の厚さが第3レジストマスク148の厚さ以下場合、接続部106が第3レジストマスク148の上に形成されることを抑制できる。その結果、第3レジストマスク148の除去の際に、接続部106が破壊されること、または、接続部106の破壊に起因してマスクパターン104が破損することなどの不具合を抑制することができる。 As a result of forming the connecting portion 106, the thickness of the connecting portion 106 may be the same as the thickness of the third resist mask 148, and the thickness of the connecting portion 106 may be smaller than the thickness of the third resist mask 148. , As shown in FIG. 17A, the thickness of the connecting portion 106 may be larger than the thickness of the third resist mask 148. When the thickness of the connecting portion 106 is larger than the thickness of the third resist mask 148, the vapor deposition mask 102 and the support frame 108 are more firmly bonded to each other. On the other hand, when the thickness of the connecting portion 106 is equal to or less than the thickness of the third resist mask 148, it is possible to prevent the connecting portion 106 from being formed on the third resist mask 148. As a result, it is possible to suppress problems such as the connection portion 106 being destroyed when the third resist mask 148 is removed, or the mask pattern 104 being damaged due to the destruction of the connection portion 106. ..
 図17(B)に示すように、第3レジストマスク148を、剥離液を用いて剥離することで、第2支持基板112上に蒸着マスクユニット100を形成することができる。その後、剥離層116を第2支持基板112から剥離し、さらに剥離層116を蒸着マスク102から剥離することで、図2に示す蒸着マスクユニット100を得ることができる。 As shown in FIG. 17B, the vapor deposition mask unit 100 can be formed on the second support substrate 112 by peeling the third resist mask 148 with a peeling liquid. After that, the peeling layer 116 is peeled from the second support substrate 112, and the peeling layer 116 is further peeled from the vapor deposition mask 102, whereby the vapor deposition mask unit 100 shown in FIG. 2 can be obtained.
 なお、蒸着マスク102は微細なマスクパターン104が形成されるため、中央部と最外周近傍とで膜厚が均一になることは同様に要求される。従って、前述した蒸着マスク製造装置150は、図13(B)(C)に示した蒸着マスク102の形成時のめっき処理の際に、第2支持基板112を収めるために用いることもできる。 Since the thin-film mask 102 forms a fine mask pattern 104, it is similarly required that the film thickness is uniform between the central portion and the vicinity of the outermost periphery. Therefore, the thin-film mask manufacturing apparatus 150 described above can also be used to accommodate the second support substrate 112 during the plating process at the time of forming the thin-film mask 102 shown in FIGS. 13 (B) and 13 (C).
 本実施形態に係る蒸着マスクユニット100の製造工程において、剥離層116を第2支持基板112に転載した後に、光硬化性樹脂膜144を露光及び現像して第2レジストマスク138を形成する段階(図16(A)から図16(B))、及び第2レジストマスク138を剥離液で除去する段階(図17(A)から図17(B))において、薬液によるウエット処理が行われる。 In the manufacturing process of the vapor deposition mask unit 100 according to the present embodiment, after the release layer 116 is transferred to the second support substrate 112, the photocurable resin film 144 is exposed and developed to form the second resist mask 138 (. In the steps (A to 16 (B)) and the step of removing the second resist mask 138 with the stripping liquid (FIGS. 17 (A) to 17 (B)), a wet treatment with a chemical solution is performed.
 以上説明した、蒸着マスク製造装置150、又は蒸着マスク102の製造方法を用いることで、第1レジストマスク114の膜厚d1を必要以上に厚くすることを抑制できる。すなわち、第1レジストマスク114の厚膜化を抑制できる。また、蒸着マスク製造装置150、蒸着マスク102の製造方法を用いることで、第1レジストマスク114の厚膜化を抑制できるため、製造方法の簡略化及び製造に伴いコストの増加を抑制することができる。 By using the vapor deposition mask manufacturing apparatus 150 or the manufacturing method of the vapor deposition mask 102 described above, it is possible to prevent the film thickness d1 of the first resist mask 114 from becoming thicker than necessary. That is, it is possible to suppress the thickening of the first resist mask 114. Further, by using the thin-film deposition mask manufacturing apparatus 150 and the thin-film deposition mask 102 manufacturing method, it is possible to suppress the thickening of the first resist mask 114, so that it is possible to suppress the increase in cost due to the simplification of the manufacturing method and the manufacturing. can.
 本発明の実施形態として上述した蒸着マスクの構成、蒸着マスクの製造装置、蒸着マスクの製造方法、蒸着マスクユニットの構成、及び蒸着マスクユニットの製造方法は、相互に矛盾しない限りにおいて、適宜組み合わせて実施することができる。また、蒸着マスクの構成、蒸着マスクの製造装置、蒸着マスクの製造方法、蒸着マスクユニットの構成、及び蒸着マスクユニットの製造方法を基にして、当業者が適宜構成要素の追加、削除もしくは設計変更を行ったもの、又は、工程の追加、省略もしくは条件変更を行ったものも、本発明の要旨を備えている限り、本発明の範囲に含まれる。 As the embodiment of the present invention, the above-mentioned configuration of the vapor deposition mask, the apparatus for manufacturing the vapor deposition mask, the method for manufacturing the vapor deposition mask, the configuration of the vapor deposition mask unit, and the method for manufacturing the vapor deposition mask unit are appropriately combined as long as they do not conflict with each other. Can be carried out. Further, based on the configuration of the vapor deposition mask, the equipment for manufacturing the vapor deposition mask, the manufacturing method of the vapor deposition mask, the configuration of the vapor deposition mask unit, and the manufacturing method of the vapor deposition mask unit, those skilled in the art may add, delete, or change the design as appropriate. As long as the gist of the present invention is provided, the above-mentioned ones, or the ones with additions, omissions, or changes in conditions are also included in the scope of the present invention.
 また、上述した実施形態の態様によりもたらされる作用効果とは異なる他の作用効果であっても、本明細書の記載から明らかなもの、又は、当業者において容易に予測し得るものについては、当然に本発明によりもたらされるものと解される。 In addition, even if the action / effect is different from the action / effect brought about by the above-described embodiment, those that are clear from the description of the present specification or those that can be easily predicted by those skilled in the art are of course. Is understood to be brought about by the present invention.
 100:蒸着マスクユニット、102:蒸着マスク、103:開口、104:マスクパターン、106:接続部、108:支持フレーム、110:第1支持基板、110A:第2の面、111:外縁部、112:第2支持基板、112A:第2の面、114:第1レジストマスク、116:剥離層、118:開口部、120:内側領域、122:外側領域、124:接着層、126:第1フォトマスク、128:第2フォトマスク、129:遮光部、130:透光部、132:外周部、138:第2レジストマスク、140:ダミーパターン、142:保護フィルム、144:光硬化性樹脂膜、145:剥離膜、146:保護膜、148:第3レジストマスク、150:蒸着マスク製造装置、151:支持母材、151A:第1の面、152:収納部、154:枠型部、156A:第1の段差部、156B:第2の段差部、157A:第1の壁部、157B:第2の壁部、157C:第1の部分、162:第1の支持部材、162A:第1の庇部、162C:円、163:電極部、164:第2の支持部材、164C:円、165:第3の支持部材、165A:第2の庇部、166:固定部材、166A:固定部材、166B:固定部材、166C:固定部材、168:固定部材、173:開口部、176A:開口部、176B:開口部、176C:開口部、178:開口部、186A:開口部、186B:開口部、186C:開口部、186D:開口部、190:開口部、190A:第1の辺、190B:第2の辺、190C:第3の辺、190D:第4の辺 100: vapor deposition mask unit, 102: vapor deposition mask, 103: opening, 104: mask pattern, 106: connection portion, 108: support frame, 110: first support substrate, 110A: second surface, 111: outer edge portion, 112 : 2nd support substrate, 112A: 2nd surface, 114: 1st resist mask, 116: peeling layer, 118: opening, 120: inner region, 122: outer region, 124: adhesive layer, 126: 1st photo Mask, 128: second photomask, 129: light-shielding part, 130: translucent part, 132: outer peripheral part, 138: second resist mask, 140: dummy pattern, 142: protective film, 144: photocurable resin film, 145: Release film, 146: Protective film, 148: Third resist mask, 150: Vapor deposition mask manufacturing equipment, 151: Support base material, 151A: First surface, 152: Storage part, 154: Frame mold part, 156A: First step portion, 156B: second step portion, 157A: first wall portion, 157B: second wall portion, 157C: first portion, 162: first support member, 162A: first Mask, 162C: Circle, 163: Electrode, 164: Second support member, 164C: Circle, 165: Third support member, 165A: Second chest, 166: Fixing member, 166A: Fixing member, 166B: fixing member, 166C: fixing member, 168: fixing member, 173: opening, 176A: opening, 176B: opening, 176C: opening, 178: opening, 186A: opening, 186B: opening, 186C: Opening, 186D: Opening, 190: Opening, 190A: First side, 190B: Second side, 190C: Third side, 190D: Fourth side

Claims (13)

  1.  被めっき部材を支持する第1面を有する支持母材と、
     前記第1面上で、前記被めっき部材の外周を囲むように設けられる第1の支持部材及び第2の支持部材と、
     前記第1面から所定の高さ離れて設けられる電極部と、を有し、
     前記第1の支持部材は、前記第1面上に設けられる第1の壁部と、前記第1の壁部の上部において前記第1面の内側に向けて突出する第1の庇部と、を有し、
     前記第2の支持部材は、前記第1面上に設けられる第2の壁部と、前記第2の壁部の上部において前記第1面の内側に向けて突出する第2の庇部と、を有し、
     前記第1の壁部は、前記第1面から前記所定の高さに亘って高さが減少する第1の部分と、前記第1の部分によって前記第1の壁部の内側面に第1の段差部と、を有し、
     前記第2の壁部は、前記第2の壁部の内側面に前記第1面から前記所定の高さで前記電極部が突出することで形成される第2の段差部を有し、
     前記第1の支持部材と前記の第2の支持部材とは、前記第1の段差部及び前記第2の段差部と、前記第1面との間に前記被めっき部材を挟み込むことが可能なように配置されている、蒸着マスクの製造装置。
    A support base material having a first surface that supports the member to be plated, and
    A first support member and a second support member provided on the first surface so as to surround the outer periphery of the member to be plated, and
    It has an electrode portion provided at a predetermined height away from the first surface, and has.
    The first support member includes a first wall portion provided on the first surface, a first eaves portion protruding inward of the first surface at the upper portion of the first wall portion, and the like. Have and
    The second support member includes a second wall portion provided on the first surface, a second eave portion protruding inward of the first surface at the upper portion of the second wall portion, and the like. Have and
    The first wall portion has a first portion whose height decreases from the first surface to the predetermined height, and a first portion on the inner surface of the first wall portion by the first portion. With a stepped part,
    The second wall portion has a second step portion formed on the inner surface surface of the second wall portion by projecting the electrode portion from the first surface at the predetermined height.
    The first support member and the second support member can sandwich the member to be plated between the first step portion, the second step portion, and the first surface. The equipment for manufacturing vapor deposition masks, which is arranged so as to.
  2.  前記第1の庇部と前記第2の庇部との距離は、前記第1の段差部と前記第2の段差部との距離より小さい、請求項1に記載の蒸着マスクの製造装置。 The vapor deposition mask manufacturing apparatus according to claim 1, wherein the distance between the first eaves portion and the second eaves portion is smaller than the distance between the first step portion and the second step portion.
  3.  前記第1の庇部及び前記第2の庇部は、前記被めっき部材の第2面の一部を覆い、
     前記第2の庇部が前記第2面を覆う長さは、前記第1の庇部が前記被めっき部材を覆う長さより大きい、請求項2に記載の蒸着マスクの製造装置。
    The first eaves portion and the second eaves portions cover a part of the second surface of the member to be plated.
    The apparatus for manufacturing a thin-film deposition mask according to claim 2, wherein the length of the second eaves covering the second surface is larger than the length of the first eaves covering the member to be plated.
  4.  断面視において、前記第2の庇部と前記第2面との距離は、前記第1の庇部と前記第2面との距離と同等である、請求項3に記載の蒸着マスクの製造装置。 The apparatus for manufacturing a thin-film deposition mask according to claim 3, wherein the distance between the second eaves and the second surface is equivalent to the distance between the first eaves and the second surface in a cross-sectional view. ..
  5.  断面視において、前記第2の庇部の端部と前記第2面に設けられる第1レジストマスクの端部との距離は、前記第1の庇部の端部と前記第1レジストマスクの端部との距離と同等である、請求項3に記載の蒸着マスクの製造装置。 In a cross-sectional view, the distance between the end of the second eaves and the end of the first resist mask provided on the second surface is the end of the first eaves and the end of the first resist mask. The apparatus for manufacturing a vapor deposition mask according to claim 3, which has the same distance as the part.
  6.  断面視において、前記第2の庇部と前記第2面との距離は10mmであり、前記第2の庇部の端部と前記第1レジストマスクの端部との距離は4mmである、請求項5に記載の蒸着マスクの製造装置。 Claimed that the distance between the second eaves and the second surface is 10 mm and the distance between the end of the second eaves and the end of the first resist mask is 4 mm in a cross-sectional view. Item 5. The apparatus for manufacturing a vapor deposition mask according to Item 5.
  7.  断面視において、前記第1レジストマスクに対して、前記第1の段差部が設けられる側と、前記第1の段差部が設けられる側の反対側とに、剥離層が設けられる、請求項5に記載の蒸着マスクの製造装置。 5. The fifth aspect of the present invention, wherein a release layer is provided on the side where the first step portion is provided and the opposite side of the side where the first step portion is provided with respect to the first resist mask in a cross-sectional view. The equipment for manufacturing the vapor deposition mask described in 1.
  8.  前記第2面の内側領域に第1の膜厚で前記第1レジストマスクを形成し、
     請求項6に記載の蒸着マスクの製造装置を用いて、前記第1レジストマスクに対して、前記第1の段差部が設けられる側及び前記第1の段差部が設けられる側の反対側の、ぞれぞれの前記第2面上に剥離層を形成する、ことを含む蒸着マスクの製造方法。
    The first resist mask is formed in the inner region of the second surface with a first film thickness.
    Using the vapor deposition mask manufacturing apparatus according to claim 6, the side opposite to the side where the first step portion is provided and the side opposite to the side where the first step portion is provided, with respect to the first resist mask. A method for producing a thin-film deposition mask, which comprises forming a release layer on each of the second surfaces.
  9.  前記第1の段差部及び前記第2の段差部と、前記第1面との間に、前記被めっき部材を挟み込む、請求項8に記載の蒸着マスクの製造方法。 The method for manufacturing a thin-film deposition mask according to claim 8, wherein the member to be plated is sandwiched between the first step portion and the second step portion and the first surface.
  10.  前記剥離層を金属膜で形成する、請求項9に記載の蒸着マスクの製造方法。 The method for manufacturing a vapor deposition mask according to claim 9, wherein the release layer is formed of a metal film.
  11.  前記剥離層をめっき法で形成する、請求項10に記載の蒸着マスクの製造方法。 The method for manufacturing a vapor deposition mask according to claim 10, wherein the release layer is formed by a plating method.
  12.  前記剥離層の厚さは、前記第1の膜厚と同等である、請求項8に記載の蒸着マスクの製造方法。 The method for manufacturing a thin-film deposition mask according to claim 8, wherein the thickness of the release layer is the same as that of the first film thickness.
  13.  前記剥離層の厚さは、119.5μm以上120.5μm以下である、請求項8に記載の蒸着マスクの製造方法。 The method for manufacturing a thin-film deposition mask according to claim 8, wherein the thickness of the release layer is 119.5 μm or more and 120.5 μm or less.
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