WO2022097476A1 - Cosmetic - Google Patents

Cosmetic Download PDF

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Publication number
WO2022097476A1
WO2022097476A1 PCT/JP2021/038745 JP2021038745W WO2022097476A1 WO 2022097476 A1 WO2022097476 A1 WO 2022097476A1 JP 2021038745 W JP2021038745 W JP 2021038745W WO 2022097476 A1 WO2022097476 A1 WO 2022097476A1
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WO
WIPO (PCT)
Prior art keywords
component
powder
iron
preferable
cosmetic
Prior art date
Application number
PCT/JP2021/038745
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French (fr)
Japanese (ja)
Inventor
卓志 竹下
匡人 栃木
祐二 増渕
Original Assignee
株式会社コーセー
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Application filed by 株式会社コーセー filed Critical 株式会社コーセー
Priority to JP2022560706A priority Critical patent/JPWO2022097476A1/ja
Priority to CN202180073212.0A priority patent/CN116782874A/en
Publication of WO2022097476A1 publication Critical patent/WO2022097476A1/en

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/12—Face or body powders for grooming, adorning or absorbing

Definitions

  • the present invention relates to cosmetics.
  • Makeup cosmetics such as foundations and concealers are used mainly for the purpose of adjusting the color of the skin and hiding the unevenness of the skin surface such as pores and wrinkles to make the skin beautiful.
  • color tone problems such as spots, freckles, and color unevenness, titanium oxide or the like, which has a high concealing property, has been mainly used.
  • Cosmetics with a high content of them are effective against color tone problems such as spots and freckles, but they have the disadvantage that the finish is white, thickened, and has an unnatural finish without transparency, and unevenness is rather noticeable. was there.
  • Japanese Unexamined Patent Publication No. 8-81332 Japanese Unexamined Patent Publication No. 11-43414 Japanese Unexamined Patent Publication No. 6-9210 Japanese Unexamined Patent Publication No. 7-258031
  • Patent Document 1 since it has a surface gloss, natural covering power cannot be obtained, and there are cases where makeup retention is not preferable. Further, in the technique of Patent Document 2, the cohesiveness is high and a smooth feeling of use may not be obtained in some cases. Further, in the techniques of Patent Documents 3 and 4, it is necessary to improve the tendency that unevenness is conspicuous in the case of a large shape having high glossiness, and there is a problem of long-lasting makeup due to a large color change when wet with sebum. was there.
  • the present invention has been made in view of the above circumstances, and its main purpose is to have a smooth spreading and spreading during application, and to have an effect of naturally covering color tone troubles of skin hills after application.
  • the synthetic phlogopite iron has a glossy feeling due to the inclusion of the synthetic phlogopite iron and the crosslinked non-emulsifying silicone elastomer. While naturally covering the color, a specific amount of cross-linked non-emulsifying silicone elastomer diffuses light, making it possible to achieve both a pore-covering effect, and by using these in combination, smooth elongation during application is possible. It was found that the above-mentioned problems were solved by the fact that the spread and the long-lasting makeup after application were good, and the present invention was completed.
  • the present invention is as follows.
  • the cosmetic according to [1] which contains one or more metal oxides selected from titanium oxide and zinc oxide having an average particle diameter of 0.1 to 4.0 ⁇ m as the component (C).
  • the component (D) which contains one or more powders selected from silicone powder, urethane powder, nylon powder, cellulose powder, polymethyl methacrylate powder and silica as the component (D).
  • the present technology can additionally adopt the following configurations.
  • the cosmetic according to any one of [1] to [12] is an oily or powdery solid cosmetic.
  • the cosmetic of the present invention has a smooth spread and spread when applied, has an effect of naturally covering color tone troubles of skin hills after application, has an excellent effect of covering unevenness on the skin surface, and further. Providing cosmetics with a long-lasting makeup effect.
  • component (A) titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m) , Titanium oxide coating amount 11-14%, tin oxide coating), (2) Component (A) Synthetic phlogopite iron (average particle size 5-11 ⁇ m, PDM-FE (manufactured by Topy Industries, Ltd.)), (3) It is a figure which shows the synthetic phlogopite (average particle diameter 5 ⁇ m) (PDM-5L: manufactured by Topy Industries, Ltd.).
  • the present invention is not limited to the following preferred embodiments, and can be freely changed within the scope of the present invention.
  • the percentage is expressed by mass (mass / mass%) unless otherwise specified.
  • the upper limit value (or less) and the lower limit value (or more) of each numerical range (to) can be arbitrarily combined.
  • the "average particle size" in the present specification is measured by an image analyzer (Luzex AP, manufactured by Nireco) by observing the surface state using a scanning electron microscope (JSM-7800 prime manufactured by JEOL Ltd.). It is a value (median diameter D50) obtained by the above, and refers to the major axis of the particles.
  • the present invention can provide a cosmetic containing the component (A) synthetic phlogopite iron and the component (B) a crosslinked non-emulsifying silicone elastomer, and the content of the component (B) in the cosmetic can be determined. It is preferably 0.1 to 5.0% by mass, and more preferably the [component (A) / component (B)] has a specific content mass ratio.
  • the component (A) is a blue light-cutting agent containing synthetic phlogopite iron coated with a metal oxide and / or synthetic phlogopite iron for blue light cutting or synthetic phlogopite iron coated with a metal oxide. It is preferable to have.
  • the component (C) is a powder of a metal oxide
  • the component (D) is an organic and / or an inorganic powder (more preferably, a plant-derived polysaccharide powder and / or a silica powder). Is more preferably used or contained in cosmetics.
  • the present invention has a smooth spreading and spreading during application, and after application, it has an effect of naturally covering color troubles (for example, color unevenness, stains, bears, etc.) of skin hills, and has an effect on the skin. It is possible to provide a cosmetic having an excellent covering effect on surface irregularities (for example, pores, wrinkles, etc.) and a high makeup lasting effect. Further, by adjusting the particle size of the component (A), it is possible to obtain a cosmetic having a covering effect without a feeling of discomfort and glare that emphasizes unevenness.
  • the synthetic phlogopite iron which is the component (A) used in the present invention, is a synthetic phlogopite containing at least an iron element in the crystal structure, and is preferably plate-shaped.
  • the component (A) synthetic phlogopite iron used in the present invention is preferably made from potassium silicate, magnesium oxide, aluminum oxide, silicon dioxide, iron oxide and the like as starting materials.
  • Component (A) Synthetic phlogopite iron may contain powder of synthetic phlogopite iron which may be coated with a metal oxide and / or surface-treated. When this component (A) is contained, smooth spreading and spreading are improved, and after application, there is no glare and a natural covering effect of skin hills is provided. It is effective for application to the site having.
  • the color tone of the component (A) is not particularly limited, but can be represented by a CIE1976L * a * b * color system, and the measured value of the CIE1976L * a * b * color system is a known CIE1976L * a * b. * It can be done using a color tone measuring device.
  • a color tone measuring device For the color tone of the CIE1976L * a * b * color system of the component (A), an incident angle of ⁇ 45 ° and a light receiving angle were obtained using a spectral chromaticity meter (for example, a spectral chromaticity meter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.)).
  • H (hue) is preferably in the range of 63 ⁇ L * ⁇ 83, 12 ⁇ C * ⁇ 32, 50 ⁇ h ⁇ 76.
  • the range of 63 ⁇ L * ⁇ 75, 18 ⁇ C * ⁇ 25, 50 ⁇ h ⁇ 70 is more preferable.
  • the range of 68 ⁇ L * ⁇ 75, 18 ⁇ C * ⁇ 25, 55 ⁇ h ⁇ 70 is more preferable, and specific examples thereof include, for example, 11 to 14% titanium oxide coating having an average particle diameter of 5 to 11 ⁇ m.
  • Synthetic phlogopite iron which is coated with tin oxide as a binder for titanium oxide.
  • the relative color tone of the component (A) is visible to the bare skin based on the relationship between the visible light relative spectral reflectance (when 720 nm is 1) and the visible light relative spectral reflectance of the bare skin (when 720 nm is 1).
  • the range between 410 nm and 540 nm is preferably in the range of -0.2 to +0.2, and more preferably -0.1 to +0.1.
  • / or between 540 nm and 620 nm preferably in the range of -0.5 to +0.5, more preferably in the range of -0.3 to +0.3, and / Or, between 620 nm and 710 nm, it is preferably in the range of -0.2 to +0.2, more preferably in the range of -0.1 to +0.1, and one, two or more. You may combine three kinds.
  • the component (A) is within the range of the relative color tone, it is possible to cover the color tone trouble of the skin hill and the unevenness of the skin surface.
  • the visible light relative spectral reflectance of the bare skin it is preferable to use the visible light relative spectral reflectance of the standard pigmented skin of Japanese women. Easy to use for strains or Mongoloid races (yellowish).
  • the visible light relative spectral reflectance can be measured according to the ⁇ visible light relative spectral reflectance test> described later [Example].
  • a melt synthesis method can be used, or a known melt synthesis method may be used.
  • raw materials such as potassium silicate, magnesium oxide, aluminum oxide, silicon dioxide and iron oxide are mixed in a predetermined number of moles and at 1400 ° C to 1600 ° C. After melting, it is cooled and crystallized, and the obtained crystal mass is atomized by a known pulverization method, treated in an acid aqueous solution with stirring, and then dehydrated, washed, and dried. This dry powder can be heat-treated at 700 to 1200 ° C.
  • synthetic phlogopite iron powder containing an iron element in the crystal structure. It is preferable to further coat the synthetic phlogopite iron powder with a metal oxide such as titanium oxide. Further, it is preferable to further treat the metal oxide-coated synthetic phlogopite composite or the titanium oxide-coated synthetic phlogopite composite with a surface treatment agent, and more preferably, a treatment agent for water-repellent treatment (hydrophobic treatment). The surface treatment is performed with an agent).
  • the blue light cutting agent used in the present invention is synthetic phlogopite iron having a blue light cutting effect, and is a powder used for blue light cutting.
  • the synthetic phlogopite iron for blue light cut is preferably one having a blue light cut effect having a wavelength of 380 to 500 nm because iron oxide is uniformly contained in the crystal, and the blue light cut function (380 to 500 nm shielding rate). ), As a suitable lower limit value, preferably 30% or more, more preferably 35% or more, more preferably 40% or more, more preferably 45% or more, still more preferably 50% or more.
  • a metal oxide-coated synthesis further coated with a metal oxide (preferably iron oxide, titanium oxide, tin oxide, zinc oxide and / or cerium oxide).
  • a metal oxide preferably iron oxide, titanium oxide, tin oxide, zinc oxide and / or cerium oxide.
  • Gold mica iron is preferable, and titanium oxide-coated synthetic gold mica iron complex and / or zinc oxide-coated synthetic metal mica iron complex is preferable, and the metal oxide-coated synthetic gold mica iron has a blue light cut function (blue light cut function). Those having a shielding rate of 380 to 500 nm) of 40% or more are preferable. More preferably, a titanium oxide and tin oxide-coated synthetic phlogopite composite is suitable.
  • the crystal structure of the coated titanium oxide tends to be rutile type, which is preferable from the viewpoint of the stability of the coated titanium oxide.
  • the blue light cut effect evaluation and the effect evaluation confirmation test will be described later [Example].
  • the component (A) used in the present invention is preferably titanium oxide-coated synthetic phlogopite iron whose surface is further coated with titanium oxide.
  • the composite powder of the component (A) coated with titanium oxide is particularly preferable in terms of its color.
  • the surface is coated with titanium oxide, so that the effect of covering uneven color is further enhanced, and in addition to a glossy finish, the color change when wet with sebum from a dry state is reduced. It is preferable because it enhances the long-lasting effect of makeup.
  • the composite powder of the component (A) coated with titanium oxide is preferable because it also has an excellent blue light blocking effect and an ultraviolet blocking effect.
  • synthetic phlogopite iron coated with 11 to 14% titanium oxide is preferable, and tin oxide coated with tin oxide as a binder is more preferable.
  • the amount of tin oxide is not particularly limited, but a coating of 0.5 to 2.0% is given as a preferable example, and an amount that can be formed into a rutile type is preferable.
  • the method of further coating the powder of synthetic phlogopite iron with titanium oxide may be performed by a known coating method.
  • a synthetic mica powder containing an iron element is suspended in a dilute aqueous solution of titanium acid, heated to 70 to 100 ° C., and the titanium salt is hydrolyzed onto the synthetic mica powder containing an iron element. It can be produced by precipitating hydrated titanium oxide particles and then firing at a high temperature of 700 to 1000 ° C. The surface may be coated after acid treatment before the reaction.
  • the titanium oxide-coated synthetic phlogopite iron used in [Example] described later can be produced.
  • the amount of surface treatment of each metal contained in the sample (powder) is determined by ICP (Inductively Coupled Plasma; Inductively Coupled Plasma; RACOS (Germany Spectro)) emission analysis of the sample prepared using a general method. It can be measured and obtained.
  • ICP Inductively Coupled Plasma
  • RACOS Germany Spectro
  • the coating amount of the metal oxide (preferably titanium oxide) in the component (A) further coated with the metal oxide (preferably titanium oxide) in the present invention is not particularly limited, but the coated component can be used.
  • the coating amount is preferably 1% or more, more preferably 5% or more, still more preferably 9% or more as a suitable lower limit value, and a suitable upper limit value.
  • the value is preferably 25% or less, more preferably 18% or less, still more preferably 14% or less, and the suitable numerical range is preferably 1 to 25%, more preferably 5 to 18%, and 9 to 14%. Is the most preferable. Within this range, it is more preferable because it is excellent in smoothness of spreading and spreading, a natural covering effect, and long-lasting makeup, and further a blue light cut effect can be obtained.
  • the component (A) is preferably surface-treated with a surface treatment agent (preferably a treatment agent for water-repellent treatment of the powder (hydrophobic agent)).
  • a surface treatment agent preferably a treatment agent for water-repellent treatment of the powder (hydrophobic agent)
  • a surface treatment agent preferably a treatment agent for water-repellent treatment of the powder (hydrophobic agent)
  • a surface treatment agent a known surface treatment agent can be used, and among the surface treatment agents, those treated with a silicone compound (also referred to as silicones) are more preferable.
  • powder of synthetic phlogopite iron treated with dimethicone or powder of synthetic phlogopite coated with titanium oxide treated with dimethicone is preferable.
  • a method for surface-treating powder such as synthetic phlogopite powder or titanium oxide-coated synthetic phlogopite composite with a surface treatment agent
  • a generally known method can be used and is not particularly limited.
  • the content of the surface-treated compound in the powder is not particularly limited, but is preferably 0.1 to 10%, more preferably 0.2 to 5%, still more preferably 0.5 to 3%.
  • the surface treatment methods of the component (A) and the component (C) described later can also be appropriately adopted.
  • a suitable lower limit value of the average particle size is preferably 2 ⁇ m or more, more preferably 5 ⁇ m or more, and a suitable upper limit value is preferably 30 ⁇ m or less. It is preferably 25 ⁇ m or less, more preferably 20 ⁇ m or less, still more preferably 15 ⁇ m or less, and even more preferably 11 ⁇ m or less.
  • the component (A) preferably has an average particle size of 2 to 20 ⁇ m, more preferably 5 to 15 ⁇ m, still more preferably 5 to 11 ⁇ m, and an aspect ratio in the range of 30 to 80. Is more suitable.
  • the synthetic gold mica iron of the component (A) has a metal oxide coating layer coated with a metal oxide in addition to the powder of the synthetic gold mica iron not coated with a metal oxide or surface-treated.
  • Powder of gold mica iron also referred to as "metal oxide-coated synthetic gold mica iron”
  • synthetic gold mica iron having a surface-treated layer treated with a surface treatment agent also called “surface-treated synthetic gold mica iron”
  • Powder of synthetic gold mica iron coated with a metal oxide coated with a surface treatment agent also referred to as “surface treatment-synthetic gold mica iron coated with a metal oxide”
  • One or more selected from these can be used.
  • a suitable lower limit value of the average particle size is preferably 2 ⁇ m or more, more preferably. Is 5 ⁇ m or more, and a suitable upper limit value is preferably 30 ⁇ m or less, more preferably 25 ⁇ m or less, still more preferably 20 ⁇ m or less, still more preferably 15 ⁇ m or less, still more preferably 11 ⁇ m or less.
  • the average particle size at this time is preferably the average particle size of synthetic phlogopite iron coated with a metal oxide.
  • the iron oxide equivalent content in the component (A) synthetic phlogopite iron is not particularly limited, but as a suitable lower limit, 8% or more is preferable, 9% or more is more preferable, and 10% or more is further preferable, and more preferable.
  • the upper limit is preferably 15% or less, more preferably 14% or less, and even more preferably 13% or less.
  • the iron oxide equivalent content in the synthetic phlogopite iron powder used for titanium oxide coating or surface treatment is not particularly limited, but as a suitable lower limit, 8% or more is preferable, and 9% or more is more preferable.
  • % Or more is more preferable, and as a suitable upper limit, 25% or less is preferable, 20% or less is more preferable, 17% or less is more preferable, 15% or less is more preferable, and 14% or less is more preferable. Within this range, it becomes easier to achieve both smoothness and a natural covering effect when using cosmetics, maintain the smooth shape of synthetic phlogopite iron, and easily realize the optimum color close to the skin color.
  • the iron oxide equivalent content in the synthetic phlogopite iron of the metal oxide coating (preferably titanium oxide coating) and / or the surface treatment of the component (A) is not particularly limited, but a suitable lower limit is 6% or more. Preferably, 7% or more is more preferable, 8% or more is further preferable, 9% or more is more preferable, and the preferable upper limit is 25% or less, 20% or less is more preferable, and 17% or less is more preferable.
  • the content of the component (A) synthetic phlogopite iron in the cosmetic of the present invention is not particularly limited, but is preferably 1% or more, preferably 3% or more, as a suitable lower limit in the total amount of cosmetics (100% by mass). More preferably, 4% or more is further preferable, 5% or more is further preferable, 7% or more is further preferable, and the preferable upper limit is 25% or less, 20% or less, more preferably 18% or less. Is more preferable, 15% or less is more preferable, and 12% or less is further preferable. This range is more preferable because it is superior in transparency, natural covering effect, and smooth spreading and spreading.
  • the content of the metal oxide coating (preferably titanium oxide) and / or the synthetic phlogopite iron in the surface treatment in the component (A) in the cosmetic of the present invention is not particularly limited, but the total amount of the cosmetic (100% by mass). ), As a suitable lower limit, 0.02% or more is preferable, 0.5% or more is more preferable, 1% or more is further preferable, 3% or more is further preferable, 5% or more is further preferable, and more. As a suitable upper limit, 25% or less is preferable, 20% or less is more preferable, 18% or less is further preferable, 15% or less is more preferable, and 12% or less is further preferable. This range is more preferable because it is superior in transparency, natural covering effect, and smooth spreading and spreading.
  • the content in the cosmetic at this time is preferably the content of synthetic phlogopite iron coated with a metal oxide, and more preferably the content of synthetic phlogopite iron coated with titanium oxide. It is more suitable.
  • the "crosslinked silicone elastomer" in the component (B) crosslinked non-emulsifying silicone elastomer used in the present invention is a polymer having a partially crosslinked structure obtained by crosslinking an organopolysiloxane. (Also referred to as “partially crosslinked silicone elastomer”), the silicone elastomer comprises RSiO units and RSiO 1.5 units, and may contain RSiO 0.5 units and / or SiO 2 units.
  • the component (B) is specifically obtained by the reaction of dimethylpolysiloxane containing a dimethylvinylsiloxy-terminated group and methylhydrogenpolysiloxane containing a trimethylsiloxy-terminated group in the presence of a platinum catalyst. May be done.
  • the "non-emulsifying property" in the component (B) crosslinked non-emulsifying silicone elastomer used in the present invention does not have the effect of making the water-soluble component finer and stabilizing the dispersion.
  • Specific examples of the component (B) include, but are not limited to, organopolysiloxane elastomers containing no polyoxyalkylene unit (particularly polyoxyethylene or polyoxypropylene) or polyglyceryl unit.
  • component (B) is non-emulsifying, it can be combined with an emulsifying property (that is, a crosslinked emulsifying silicone elastomer) as an optional component, and the combined use thereof also exhibits the expected effect of the present invention. Can be made to.
  • an emulsifying property that is, a crosslinked emulsifying silicone elastomer
  • the crosslinked emulsifying silicone elastomer those having a polyoxyalkylene unit or a polyglyceryl unit are preferable.
  • crosslinked non-emulsifying silicone elastomer examples include (dimethicone / vinyldimethicone) crosspolymer, dimethicone crosspolymer, (vinyldimethicone / lauryldimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone) crosspolymer. , (Dimethicone / lauryldimethicone) crosspolymer, (laurylpolydimethylsiloxyethyl dimethicone / bisvinyldimethicone) crosspolymer and the like, but are not limited thereto. One kind or two or more kinds selected from these can be used.
  • cross-linked non-emulsifying silicone elastomers It can also be used in combination with one or more cross-linked non-emulsifying silicone elastomers, a single type of cross-linked non-emulsifying silicone elastomer, or a combination of two or more different cross-linked non-emulsifying silicone elastomers. Can be used.
  • the component (B) in cosmetics, in addition to the effect of imparting a soft focus effect due to the characteristic of easily orienting to the concave portions of the skin and making unevenness such as pores inconspicuous, pores, wrinkles, etc.
  • the component (B) enters the skin to form a smooth surface, and the plate shape of the component (A) is lined up on the skin surface in a certain direction to have a uniform and natural covering effect and to prevent unevenness of the skin. It can also be expected to have the effect of preventing problems to be emphasized in advance.
  • the component (B) used in the present invention is a solid component of a polymer, and is selected from at least one hydrocarbon-based oil, at least one ester oil, or at least one silicone oil1. It is preferably in the form of a gel (also referred to as a silicone gel composition) formed from an elastomer organopolysiloxane contained in a seed or two or more kinds of solvents.
  • a gel also referred to as a silicone gel composition
  • the shape of the component (B) crosslinked non-emulsifying silicone elastomer may be either non-spherical or spherical, and the shape is not particularly limited.
  • the content of the crosslinked non-emulsifying silicone elastomer in the silicone gel composition containing the crosslinked non-emulsifying silicone elastomer and the solvent is not particularly limited, but is preferably 2 to 50% in terms of solid content.
  • the suitable lower limit value is preferably 5% or more, more preferably 10% or more, and the suitable upper limit value is preferably 40% or less, more preferably 30% or less.
  • the gel form (also referred to as a silicone gel composition) containing the component (B) include, for example, a mixture of a (dimethicone / vinyldimethicone) crosspolymer and a solvent (for example, a mixture of cyclopentasiloxane or dimethicone).
  • Dimethicone A mixture of a crosspolymer with a solvent (eg, a mixture with isododecane, or a mixture with cyclopentasiloxane); a solvent (eg, methyl (3,3,3-trifluoropropyl) containing a dimethylvinylsiloxy-terminated group).
  • a solvent eg, methyl (3,3,3-trifluoropropyl) containing a dimethylvinylsiloxy-terminated group.
  • Mixtures with a solvent eg, trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane
  • a solvent eg, trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane
  • One or more selected from these can be used.
  • a mixture of a (dimethicone / vinyl dimethicone) crosspolymer and a solvent a mixture of a dimethicone crosspolymer and a solvent, and a mixture of a (vinyldimethicone / lauryldimethicone) crosspolymer and a solvent are preferable.
  • gel forms more specifically, a mixture of (dimethicone / vinyl dimethicone) crosspolymer and dimethicone, a mixture of dimethicone crosspolymer and silolomethicone, (vinyldimethicone / lauryldimethicone) crosspolymer and triethylhexanoin. It is a mixture.
  • One type or two or more types can be selected from these gel forms.
  • the component (B) used in the present invention is an INCI name product (dimethicone / vinyldimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone) crosspolymer, (dimethicone / lauryldimethicone) crosspolymer, (laurylpoly).
  • Dimethylsiloxyethyl dimethicone / bisvinyl dimethicone) crosspolymers can be mentioned, and one or more selected from these can be used.
  • INCI's famous product dimethicone crosspolymer for example, those sold under the name of SFE 839 by Dow Corning's DC9040, DC9041 and DC9240, and DC9045
  • SFE 839 Dow Corning's DC9040, DC9041 and DC9240, and DC9045
  • the content of the component (B) crosslinked non-emulsifying silicone elastomer in the cosmetics of the present invention is preferably 0.1% or more, preferably 0.3%, as a suitable lower limit in the total amount of cosmetics (100% by mass).
  • the above is more preferable, 0.5% or more is further preferable, 1.0% or more is further preferable, and as a suitable upper limit, 5.0% or less is preferable, 4.0% or less is more preferable, and 3 More preferably, it is 0.0% or less.
  • it is preferable because it is excellent in transparency, natural covering power, and spreading and spreading, and has a soft focus effect of finish, smoothness when using cosmetics, and long-lasting makeup.
  • the content of the component (B) in the cosmetic of the present invention is , Can be obtained by converting the solid content of the silicone elastomer.
  • the content mass ratio (or mass ratio used) between the component (A) and the component (B), (A) / (B), is preferably 0.2 or more as a suitable lower limit value, and more preferably. It is 1.0 or more, more preferably 2.0 or more, and a suitable upper limit value is preferably 100.0 or less, more preferably 50.0 or less, still more preferably 40.0 or less, and even more preferably 30. It is 0 or less, more preferably 25.0 or less, more preferably 20.0 or less, and (A) / (B) is preferably 0.2 to 100.0 as the suitable numerical range. .0 to 50.0 is more preferable, and 1.5 to 40.0 is even more preferable. Within this range, it can be expected that both the natural covering power of the skin hill and the pore covering power are compatible.
  • the cosmetic of the present invention preferably further contains a metal oxide as the component (C), more preferably titanium oxide and / or zinc oxide, and the shape of the metal oxide is preferably powder.
  • the component (C) may contain one or more metal oxides selected from titanium oxide and zinc oxide having an average particle diameter of 0.1 to 4.0 ⁇ m. When the average particle size is in this range, it is more preferable because it makes it easy to adjust the smooth feeling of use at the time of application, the natural covering power, and has an excellent cosmetic lasting effect.
  • the shapes of titanium oxide and zinc oxide are not particularly limited to spherical, plate-shaped, needle-shaped, spindle-shaped and other shapes, and porous and non-porous particle structures and the like.
  • Specific commercially available products that can be used as the component (C) include, for example, MP-18, MP-701, MP-1133, MP-40, MP-100 and the like, or composite powders thereof (manufactured by TAYCA Corporation). ); MKR-1 (manufactured by Sakai Chemical Industry Co., Ltd.); SYMPHOLIGHT series (manufactured by JGC Catalysts and Chemicals Co., Ltd.); ZO-CX (manufactured by Sumitomo Osaka Cement Co., Ltd.); ST series (manufactured by Titan Kogyo Co., Ltd.), etc., but is not limited thereto. Further, the component (C) may be produced by a known production method and is not particularly limited.
  • the surface of the component (C) used in the present invention is further coated with an iron oxide or a hydroxide.
  • the component (C) used in the present invention may be coated with an oxide or hydroxide of silicon, an oxide of aluminum or a hydroxide as each layer in addition to the oxide or hydroxide of iron.
  • the coating amount is not particularly limited, but from the viewpoint of natural covering power, the iron oxide-coated metal oxide (preferably iron oxide-coated titanium dioxide or oxidation) is used.
  • iron-coated zinc oxide a suitable lower limit value is preferably 0.5% or more, more preferably 0.6% or more, still more preferably 0.7% or more, and a suitable upper limit value is 5% or less. Is preferable, more preferably 3.5% or less, still more preferably 3% or less, and the suitable numerical range is preferably 0.5 to 5%, more preferably 0.7 to 3.5%, and 0. 9.9 to 3% is more preferable.
  • the component (C) one kind or two or more kinds can be used as needed.
  • the method of coating with the iron oxide or the hydroxide is not particularly limited, and a known iron oxide coating treatment method can be used.
  • a known iron oxide coating treatment method can be used.
  • an aqueous solution of caustic soda is heated to 30 to 35 ° C., powder particles are dispersed, an aqueous solution containing ferric sulfate is added and stirred, and the mixture is reacted at 90 ° C. for about 2 hours.
  • the obtained complex compound is washed with water, neutralized and dried. After pulverization, it can be obtained by calcining the raw material particles and iron oxide or hydroxide (for example, about 750 to 900 ° C. for about 1 to 3 hours).
  • the average particle size of the component (C) in the present invention is not particularly limited, but as a suitable lower limit, it is preferably 0.1 ⁇ m or more, more preferably 0.15 ⁇ m or more, further preferably 0.2 ⁇ m or more, and further.
  • As a suitable upper limit it is preferably 4.0 ⁇ m or less, more preferably 3.0 ⁇ m or less, still more preferably 1.0 ⁇ m or less. Within this range, the natural covering effect of the skin hills is superior. Further, it is more preferable that the average particle size is 0.25 to 3.0 ⁇ m because it is easy to adjust a smoother feeling of use and a natural covering effect.
  • the content of the component (C) in the cosmetic of the present invention is not particularly limited, but is preferably 1% or more, more preferably 5% or more, and further preferably 5% or more as a suitable lower limit value in the total amount of cosmetics (100% by mass). It is preferably 7% or more, preferably 20% or less as a suitable upper limit value, more preferably 15% or less, still more preferably 12% or less, and the suitable numerical range is preferably 1 to 20%. 5 to 15% is more preferable, and 7 to 12% is even more preferable. This range is preferable because it is superior in the natural covering power and spreading of the skin hill.
  • the component (C) used in the present invention is more preferably in a plate-like form, and the component (C) itself may be in a plate-like shape, or on the surface of a plate-like body such as mica, synthetic mica, glass, silica, or alumina. It is more preferable that the shape is a composite plate-like powder to which the component (C) is adsorbed.
  • the component (A) may be contained in the plate-shaped powder base.
  • a commonly known surface treatment agent such as a silicone compound, a fatty acid metal salt, a fluorine compound and a surfactant, respectively.
  • a commonly known surface treatment agent such as a silicone compound, a fatty acid metal salt, a fluorine compound and a surfactant, respectively.
  • a hydrophobic surface treatment agent such as a silicone compound, a fatty acid metal salt, a fluorine compound and a surfactant, respectively.
  • the surface-treated with a hydrophobic surface treatment agent is used, the dispersibility of the metal oxide in the cosmetic can be improved, the adhesion to the skin can be increased, and the covering power and the long-lasting
  • the component (A) and / or the component treated with a silicone compound and / or a surface treatment agent having an adipose group having 16 to 24 carbon atoms (also referred to as a surface treatment compound).
  • (C) is preferably used.
  • the silicone compound is represented by INCI name (International Nomenclature Cosmetic Ingredient labeling names): dimethicone, methicone, hydrogendimethicone, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethylhexyl.
  • Examples thereof include dimethicone, (acrylate / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate) copolymer, triethoxycaprylylsilane and the like, and one or more selected from these can be used. Of these, dimethicone is preferable.
  • the component (B), which is a silicone compound, may be used as a surface treatment agent on the surface of the component (A) and / or the component (C).
  • surface treatment agents having a fatty acid group having 16 to 24 carbon atoms also referred to as surface treatment compounds
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids
  • surface treatment agents having a nitrogen source such as acylated amino acids, phospholipid
  • a smooth feeling of use can be obtained, especially when the continuous layer is air or in a formulation having poor spreadability. May be effective. Since all of them have a fat group having 16 to 24 carbon atoms, the adhesive force to the skin is enhanced, the effect of covering the skin hills is maximized with a small amount, and the effect of improving the long-lasting makeup is excellent.
  • a silicone surface treatment or a dimethicone surface treatment is preferable.
  • the surface treatment of the component (C) it is selected from silicone surface treatment (for example, dimethicone surface treatment), sphingolipid surface treatment (for example, ceramide NG surface treatment), phospholipid surface treatment (for example, hydrogenated phospholipid surface treatment) and the like. 1 type or 2 or more types are preferable.
  • the surface treatment agent for applying the surface treatment to the powder used in the present invention is not particularly limited, but for example, a trialkylsilylating agent, a trialkoxyalkylsilylating agent, a dimethylpolysiloxane, a methylhydrogenpolysiloxane, and the like.
  • Silicone compounds such as high-viscosity silicones, cross-linked silicones, fluorine-modified silicones, acrylic-silicone graft copolymers, and silicone resins; surfactants such as anionic surfactants, cationic surfactants, and nonionic surfactants; stearic acid Metal soaps such as aluminum; oils such as polyisobutylene, wax (for example, beeswax), higher fatty acids, higher alcohols; amino acid compounds such as N-acylamino acids; perfluoroalkylphosphoric acid and its salts, perfluoroalkylsilanes, etc. Fluoro compounds; phospholipids such as lecithin and hydrogenated phospholipids; sphingolipids such as ceramide NG (2) and the like can be mentioned, and one or more selected from these can be used.
  • the surface treatment agent may be used alone or in combination of two or more, and can be appropriately adjusted according to the dosage form of the cosmetic.
  • the treatment method is a wet treatment in which the treatment agent and powder are mixed in a slurry in a solvent, kneaded with a planetary mixer or the like, and then the solvent is removed for surface treatment, or the treatment agent is dissolved in the solvent and super
  • a dry treatment which is performed by stirring in a mixer such as a mixer, can be mainly used, and is preferable in that the surface treatment is efficiently performed and the dispersibility is improved.
  • the amount of surface treatment is not particularly limited.
  • the present invention further comprises one or more powders selected from silicone powder, urethane powder, nylon powder, cellulose powder, starch powder, polymethyl methacrylate powder and silica as the component (D) of the present invention. It is preferable to use or contain it in the powder. These powders are not particularly limited in terms of particle structure such as porous and non-porous, irregular shapes such as spherical, plate-like, and minute irregularities on the surface, but can be used as powder in cosmetics. The body. Spherical particles having high light scattering properties are particularly preferable in terms of the pore covering effect.
  • the silicone powder is not particularly limited, and examples thereof include crosslinked silicone and reticulated silicone block copolymers.
  • (dimethicone / vinyldimethicone) cross-polymer powder (vinyldimethicone / methicone).
  • examples thereof include a powder of (silsesquioxane) cross-polymer, a powder of (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) cross-polymer, and the powder is a component (B) that can be formed into a gel form. Is not included in.
  • a non-synthetic polymer is particularly preferable.
  • the synthetic polymer means a polymer obtained by organically synthesizing petroleum-based monomers and / or oligomers as a starting material.
  • Non-synthetic polymers can include polymers originating from naturally derived and / or plant derived polymers.
  • cellulose powder starch powder, which is an organic powder (preferably polysaccharide powder) derived from nature or plants, and silica, which is an inorganic powder. The above is more preferable in terms of the pore covering effect.
  • crystalline cellulose powder is preferable.
  • starch powders cross-linked or non-cross-linked starch powder derived from corn, starch powder derived from wheat, starch powder derived from rice, and powders of chemical modifications having these skeletons (for example, hydroxypropyl starch, octenyl succinate corn). Starch salt, etc.); One or more selected from metal oxide-coated starch (for example, titanium oxide-coated cornstarch, etc.) powder and the like are preferable.
  • the hydrophobized component (D) treated with the surface treatment agent described as the surface treatment agent for the component (A) and / or the component (C) is more preferable.
  • the average particle size of the component (D) used in the present invention is not particularly limited, but is preferably 0.5 ⁇ m or more as a suitable lower limit, more preferably 4.0 ⁇ m or more, and preferably 40 ⁇ m or less as a suitable upper limit. , 30 ⁇ m or less is more preferable. Within this range, the effect of making the skin groove less noticeable can be expected.
  • the lower limit is more preferably 15 ⁇ m or more
  • the upper limit is more preferably 15 ⁇ m or less.
  • the content of the component (D) in the cosmetic of the present invention is not particularly limited, but is preferably 5% or more, more preferably 8% or more as a suitable lower limit in the total amount of cosmetics (100% by mass). 10% or more is more preferable, and as a suitable upper limit, 50% or less is preferable, 40% or less is more preferable, 30% or less is more preferable, and 20% or less is more preferable. It is preferable that the component (D) is contained in this range because it improves a smooth feeling of use and is excellent in the effect of making the skin groove less noticeable. At the same time that the effect of the component (B) can be supplemented, the texture of the entire finished cosmetic can be adjusted.
  • the cosmetic of the present invention includes water-soluble polymers, ultraviolet absorbers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, beauty components, moisturizers, surfactants, and crosslinked emulsifying properties.
  • Any component such as a silicone elastomer and powders other than the above components (A), (C) and (D) can be appropriately contained as long as the effects of the present invention are not impaired.
  • the cosmetic of the present invention uses the above-mentioned components (A), (B) and the like, and appropriately adopts known production methods such as blending, mixing and emulsification to obtain the type and form of the target cosmetic. Can be prepared.
  • the cosmetic of the present invention can be applied to make-up cosmetics such as eye color, eyebrow, foundation, blusher, white powder, and foundation, skin care cosmetics such as milky lotion, cream, beauty essence, and body powder, and sunscreen cosmetics. It is possible, and one or more of them can be selected. Further, the cosmetic of the present invention may be a composition or may be used as a skin external preparation.
  • the form of the cosmetic of the present invention is not particularly limited, but may be powdery, liquid, paste, milky, creamy, gelled, solid or the like, and one or more of these may be used. You can choose. In particular, emulsified cosmetics, oily cosmetics, powdered cosmetics, and powdered solid cosmetics are preferable in order to exert a natural concealing effect.
  • the cosmetic of the present invention naturally covers unevenness (pores, wrinkles, etc.) on the skin surface and color troubles (stains, freckles, color unevenness, etc.) on the skin hills. It may be a cosmetic for use. As a result, for example, the unevenness of the skin and the difference in color tone are made inconspicuous, and the unnaturalness of the skin color or the appearance of the skin color such as lack of transparency due to whitening or thickening is reduced. be able to.
  • the present invention is the component (A) and the component (B) for use for the above-mentioned purposes such as to cover the unevenness of the skin surface and / or to naturally cover the color tone trouble of the skin hill.
  • the present invention provides the components (A) and components (A) and components (A) for producing various agents or compositions having the above-mentioned covering action for skin surface irregularities and / or natural covering action for skin hill color tone troubles.
  • B) can be used at least.
  • a method of using or applying the cosmetic of the present invention, at least a combination of the ingredients (A) and (B) or a mixture thereof, to the skin for example, a make-up method, for covering unevenness on the skin surface). It can be used for methods and / or methods for naturally covering skin hill color problems, etc.).
  • the cosmetic of the present invention may be used for non-medical purposes, and the "non-medical purpose" includes a medical act (for example, an act performed by a doctor), that is, an act of treating the human body by medical treatment. There is no concept.
  • Non-medical purposes include, for example, make-up, beauty and the like.
  • the blue light cut function shielding rate of 380 to 500 nm
  • Samples are component (A) synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, PDM-FE (manufactured by Topy Industries, Ltd.)) and titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, titanium oxide coating amount).
  • the blue light cut effect of the component (A) is highest in titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, titanium oxide coating amount 11 to 14%, tin oxide coating), and synthetic phlogopite iron (average particles). A little was seen even with a diameter of 5 to 11 ⁇ m), and no effect was seen with synthetic phlogopite (average particle diameter of 5 ⁇ m).
  • ⁇ Visible light relative spectral reflectance test> Component (A) Visible light relative spectral reflectance of synthetic gold mica iron coated with titanium oxide (average particle size 5 to 11 ⁇ m, titanium oxide coating amount 11 to 14%, tin oxide coating) and visibility of standard pigmented skin of Japanese women A comparison with the optical relative spectral reflectance is shown in FIG.
  • the component (A) is tapped on the cell 20 times in the measurement of the incident angle ⁇ 45 ° and the light receiving angle 0 ° using the variable spectroscopic colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.). When measured, the relative spectral reflectance curve when the reflection at 720 nm was 1 was compared with the relative spectral reflectance curve when the reflection at 720 nm of the bare skin was 1.
  • the color tone of the titanium oxide-coated synthetic phlogopite iron is in the range of 63 ⁇ L * ⁇ 75, 18 ⁇ C * ⁇ 25, 50 ⁇ h ⁇ 70, and that of the titanium oxide-coated synthetic phlogopite iron.
  • the color tone was in the range of 68 ⁇ L * ⁇ 75, 18 ⁇ C * ⁇ 25, 55 ⁇ h ⁇ 70.
  • Titanium oxide-coated synthetic phlogopite iron (average particle size 5 to 11 ⁇ m, titanium oxide coating amount 11 to 14%, tin oxide coating) has the effect of having a natural skin color close to that of bare skin. It was seen.
  • Tables 1 to 3 Examples 1 to 24 and Comparative Examples 1 to 5: Oil-based concealer Tables 4 to 6: Examples 25 to 43 and Comparative Examples 6 to 10: Powder foundation The oil-based concealers shown in Tables 1 to 3 and Table 4 The powder foundations shown in 6 to 6 were prepared, and the following evaluations were carried out for the natural covering effect of the skin hill, the pore covering effect, the long-lasting makeup, and the smooth spreading and spreading, and the judgment was made according to the following criteria. The results are also shown in Tables 1-6.
  • the content of the component (B) in the compositions (100% by mass) of Examples 1 to 43 and Comparative Examples 1 to 10 in the table is shown in terms of solid content.
  • the synthetic phlogopite iron coated with the metal oxide used in the table can be obtained by adopting a known coating method for commercially available synthetic phlogopite iron, and the synthetic phlogopite iron or metal oxidation of the surface treatment can be obtained.
  • the material-coated synthetic phlogopite iron can be obtained by adopting a known surface treatment method (see ⁇ Component (A)> and the like above).
  • the iron oxide equivalent content in the synthetic phlogopite iron, the metal oxide coating and / or the surface-treated synthetic phlogopite iron used in the above test and the following examples is 10 to 14%, and the aspect ratio is 30. ⁇ 80.
  • the content of the surface-treated compound in the dimethicone-treated titanium oxide-coated synthetic phlogopite (powder) used in the above test and the following examples is 0.5 to 3%.
  • KSG-16 manufactured by Shin-Etsu Chemical Co., Ltd.
  • Solid content (dimethicone / vinyldimethicone) crosspolymer 25%, solvent dimethicone)
  • PDM-FE Average particle size 5 to 11 ⁇ m manufactured by Topy Industries, Ltd.
  • iron oxide equivalent 10 to 14%)
  • Tables 1 to 3 A The components (1) to (11) are uniformly mixed and dissolved.
  • Ingredients (12) to (37) are added to A, and the mixture is uniformly mixed and dispersed.
  • C. B was filled in a container and cooled to obtain an oil-based concealer (solid).
  • Tables 4 to 6 A The components (1) to (21) were mixed and dispersed.
  • B The dispersed components (22) to (31) were added to A, and the mixture was pulverized with a palberizer.
  • C A powder foundation was obtained by compression molding into a gold plate container. At that time, the component (31) was evaporated.
  • evaluation methods The following evaluation items were evaluated by the following methods.
  • evaluation item I. Natural covering effect of skin hills b. Pore cover effect c. Makeup persistence d. Smooth stretch
  • each sample was subjected to a usage test by 20 specialized panels, and each panel evaluated and scored on a 5-point scale according to the following absolute evaluation criteria, and all the panels of each sample were evaluated. The average value is calculated from the total score, and the value rounded to the first decimal place is shown.
  • the natural covering effect of the skin hills was it a cosmetic film that naturally covered the color problems such as spots, freckles, and color unevenness seen on the skin hills when each sample was applied to the skin?
  • the pore covering effect whether or not the pores were hidden when each sample was applied to the skin, c.
  • the oil-based concealers of Examples 1 to 24 of the present invention have a natural covering effect on skin hills, a pore covering effect, long-lasting makeup, smooth spreading and spreading, in all items. It was an excellent oil-based concealer.
  • Comparative Example 1 in which a colored pearl agent coated with 12% titanium oxide and 12% iron oxide was used instead of the component (A) had a technical finish and had a poor natural covering effect on the skin hills, and when it was expanded. I could't be satisfied because it became uneven.
  • Comparative Example 2 in which synthetic phlogopite was used instead of the component (A), the natural covering effect of the skin hill was not satisfactory. In addition, the spread was poor.
  • Comparative Example 3 in which the component (B) was less than 0.1% was not satisfactory in terms of the pore covering effect because the light diffusing effect of the silicone elastomer was insufficient.
  • Comparative Example 4 in which the component (B) exceeded 5%, the natural covering effect was hindered and the quality was poor in makeup durability.
  • Comparative Example 5 in which the crosslinked emulsifying silicone elastomer was used instead of the component (B), the quality was such that the decorative film became sticky and the spread and spread became poor.
  • the powder foundations of Examples 25 to 43 of the present invention have a natural covering effect of skin hills, a pore covering effect, a long-lasting makeup, a smooth spreading and spreading, in all items. It was an excellent powder foundation.
  • Comparative Example 6 in which a colored pearl agent coated with 12% titanium oxide and 12% iron oxide was used instead of the component (A) had a technical finish, and the finish was very unnatural when used on the whole face. Therefore, the natural covering effect of the skin hills was extremely poor, and even when it was stretched, unevenness became conspicuous, and I was not satisfied.
  • Comparative Example 7 in which synthetic phlogopite was used instead of the component (A), the effect of correcting color unevenness was lowered, and the natural covering effect of the skin hill was not particularly satisfied.
  • Comparative Example 8 in which the component (B) is less than 0.1% is not particularly satisfactory in terms of the pore covering effect because the light diffusing effect of the silicone elastomer is insufficient.
  • Comparative Example 9 in which the component (B) exceeded 5%, the powder was too wet, and the smooth spreading and spreading was not a satisfactory quality.
  • Comparative Example 10 in which the crosslinked emulsifying silicone elastomer was used instead of the component (B), the decorative film was sticky and the quality was poorly spread.
  • the cosmetic of the present invention has a smooth spread and spread when applied, and has the effect of naturally covering color troubles (for example, color unevenness, stains, bears, etc.) of the skin hills after application.
  • color troubles for example, color unevenness, stains, bears, etc.
  • Example 44 Oily blusher (ingredient) (%) 1. 1. Dextrin palmitate * 14 10 2. 2. Microcrystalline wax (melting point 77-82 ° C) 4 3. 3. Trimethylsiloxysilicic acid * 15 6 4. Diglyceryl triisostearate 30 5.2 Cetyl ethylcaproate 20 6. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 2 7. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 2 8. Sorbitan sesquioleate 2 9. Red No. 202 0.5 10. Yellow No. 4 0.5 11. Black iron oxide 0.1 12. Talc remaining amount 13. Hydrophobization treatment Silicic acid anhydride * 16 2 14.
  • the oily blush of Example 44 was evaluated and judged using a brush according to the evaluation method of the above Example. As a result, it was an excellent oily blusher in all items, such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading.
  • Example 45 Powdered solid blusher (ingredient) (%) 1.
  • Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, titanium oxide coating amount 12%) 30 2.
  • Silicone treated mica 19 Remaining amount 3.
  • Synthetic phlogopite * 20 10 4.
  • Triethoxycaprylylsilane treated red iron oxide 0.2 5.
  • Red No. 226 0.5
  • Talc average particle diameter 10 ⁇ m
  • Dimethicone-treated zinc oxide average particle size 3.0 ⁇ m, hexagonal plate
  • Spherical silica * 22 1 10. Chlorphenesin 0.2 11.
  • Heavy liquid isoparaffin 0.5 14.
  • Squalene 1 15. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 7 16.
  • the powdered solid blusher of Example 45 was evaluated and judged according to the evaluation method of the above Example using a brush. As a result, it was a powder solid blusher that was excellent in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 46 White powder (ingredient) (%) 1.
  • Titanium oxide-coated synthetic phlogopite iron (average particle size 1 to 3 ⁇ m, titanium oxide coating amount 12%) 10 2.
  • Synthetic phlogopite iron * 7 15 3.
  • Silicone treated talc * 24 Remaining amount 4.
  • Mica Titanium * 25 10 5.
  • Silica treatment Silicone treatment Fine particles
  • Zinc oxide * 268 6. Boron Nitride * 27 5 7.
  • Spherical polyethylene * 28 5 Spherical cellulose powder * 29 10
  • Calcium carbonate * 30 1 10.
  • Bengala 1 12.
  • Yellow iron oxide 2 13.
  • Methyl paraoxybenzoate 0.2 15. 2-ethylhexyl paramethoxycinnamate 2 16.
  • Pentaerythrityl tetraisostearate 0.5 17. Stearoyl oxystearate octyldodecyl 0.5 18. Triethylhexanoin 3 19. (Vinyl Dimethicone / Lauryl Dimethicone) Cross polymer * 3 0.5 20. Squalene 0.2 21. Stealanium Heckrite * 32 1 22. Cellulose nanofiber 2% aqueous solution * 33 0.2 23. Rice casphingo glycolipid 0.1 24. Watercress extract 0.1 25. Hydrogenated lecithin 0.2 * 24: JA-46R (Made by Asada Flour Milling Co., Ltd.
  • Average particle diameter 9 ⁇ m Aspect ratio 50 * 25: TIMIRON STARLUSTER MP-115 (Merck, average particle diameter 20 ⁇ m, aspect ratio 300) * 26: MZ-510HPSX (average particle diameter 25 nm manufactured by TAYCA Corporation) * 27: SHP-3 (Made by Mizushima Ferroalloy Co., Ltd.
  • the white powder of Example 46 was evaluated and judged using a puff according to the evaluation method of the above Example. As a result, it was an excellent white powder in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 47 Eyebrow (ingredient) (%) 1. 1. Talc 20 2. 2. Mica remaining amount 3. Black iron oxide 10 4. Bengala 4 5. Al hydroxide treated titanium oxide (average particle size 1.0 ⁇ m) 6 6. Titanium oxide-coated synthetic phlogopite iron (average particle diameter 15 to 20 ⁇ m, titanium oxide coating amount 12%) 10 7. Black Iron Oxide Coated Mica Titanium 15 8. Zinc oxide (average particle size 3.0 ⁇ m, hexagonal plate) 2 9. Zinc stearate * 34 1 10. Red No. 226 0.1 11. Yellow No. 4 0.1 12. Red No. 202 0.1 13. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 10 14.
  • the eyebrow of Example 47 was evaluated and judged using a chip according to the evaluation method of the above Example. As a result, it was an excellent eyebrow in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 48 Solid powder eyeshadow (ingredient) (%) 1.
  • Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, titanium oxide coating amount 8%) 10 2.
  • Talc remaining amount 3. Titanium oxide treated with stearoyl glutamic acid 2Na * 35 15 4. Boron Nitride * 4 5 5.
  • Hydrophobicized silica (average particle size 12 ⁇ m) 5 6.
  • Gunjo 2 7. Red No. 202 0.5
  • Chlorphenesin 0.1 Bismuth Oxychloride * 375 11.
  • Barium sulfate (plate-shaped, average particle size: 15 ⁇ m) 3 12.
  • Example 48 The solid powder eyeshadow of Example 48 was evaluated and judged using a chip according to the evaluation method of the above Example. As a result, the natural covering effect of the skin hill, the pore covering effect, the long-lasting makeup, the smooth spreading and spreading, and the excellent eye shadow in all items.
  • Example 49 Reclaimed water foundation cosmetic (ingredient) (%) 1.
  • Triethoxycaprylylsilane treated iron oxide 3 3.
  • Methyltrimethicone 10 Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / Stearyl / Behenil) * 40 3 7.
  • Triethanolamine 1 19. Ascorbic acid glucoside 1 20. Remaining amount of purified water * 39: KP-578 (manufactured by Shin-Etsu Chemical Co., Ltd.) * 40: PLANDOOL-H (manufactured by Nippon Fine Chemical Co., Ltd.) * 41: KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.) * 42: XS66-B8226 (manufactured by Momentive)
  • the water-in-oil foundation cosmetic of Example 49 was stretched with a finger and evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an excellent foundation in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 50 Underwater oil type foundation cosmetic (ingredient) (%) 1.
  • Stearic acid 1 2.
  • Glyceryl monostearate 0.5
  • Cetanol 0.5
  • Sorbitan sesquioleate 0.5
  • Polyoxyethylene (20) Hardened castor oil 0.2
  • PEG-9 Dimethicone 0.3
  • Hydrogenated lecithin 0.1
  • Liquid paraffin 3
  • Decamethylcyclopentasiloxane 5 didimethylpolysiloxane (6CS: 25 ° C) 3
  • 2-ethylhexyl paramethoxycinnamate 3 13.
  • Talc (average particle diameter 5 ⁇ m) 2 25.
  • the oil-in-water foundation cosmetic of Example 50 was evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an excellent foundation in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 51 Water emulsified foundation cosmetics in solid oil (ingredients) (%) 1.
  • Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 ⁇ m, titanium oxide coating amount 12%) 10 2.
  • Hydrophobicized titanium oxide (average particle size 0.4 ⁇ m) 8 3.
  • Didimethylpolysiloxane (6CS: 25 ° C) 5
  • Trimethylsiloxysilicic acid * 45 3 7.
  • Isohexadecane 10 8. Liquid paraffin 5 9.
  • Dextrin palmitate 2 10. Candelilla low (melting point 70 ° C) 2 11. Inulin stearate 2 12. Glyceryl tribehenate (melting point 60 ° C) 2 13. Methylenebisbenzotriazolyl tetramethylbutylphenol 2 14. Silicone treated titanium oxide (average particle size: 0.035 ⁇ m) 10 15. Iron oxide 12 16. (Diphenyldimethicone / Vinyldiphenyldimethicone / Silsesquioxane) Crosspolymer * 46 2 17. L-Menthol 0.01 18. Methyl paraoxybenzoate 0.1 19.1,3-butylene glycol 5 20. Sodium L-monosodium 0.2 21.
  • the solid oil emulsified foundation cosmetic of Example 51 was evaluated and judged according to the evaluation method of the above Example. As a result, it was an excellent solid oil-in-water emulsified foundation cosmetic in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
  • Example 52 Aerosol type foundation cosmetic (ingredient) (%) 1.
  • Lecithin-treated Al hydroxide-treated titanium oxide (average particle size 0.27 ⁇ m) 10
  • Triethoxycaprylylsilane treated yellow iron oxide powder 1
  • Triethoxycaprylylsilane treated black iron oxide powder 0.5
  • Dimethicone-treated titanium oxide-coated synthetic phlogopite iron average particle size 5 to 11 ⁇ m, titanium oxide coating amount 12%) 10
  • Polyglyceryl-3 / polydimethylsiloxyethyl dimethicone 1 7. Decamethylcyclopentasiloxane 5 8.
  • Dimethylpolysiloxane Remaining amount 9. (Trifluoropropyldimethicone / trifluoropropyldivinyldimethicone) Crosspolymer 2 10. 2-ethylhexyl methoxycinnamate 8 11. (Trifluoroproyldimethylsiloxy / Trimethylsiloxy) silsesquioxane) * 475 12. PEG-9 Polydimethylsiloxyethyl Dimethicone * 16 2 13. Mixture of crosslinked organopolysiloxane polymer 2 14. Stearoxydimethicone 0.5 15. Canten 0.1 16. Emulsion of bisethylhexyloxyphenol methoxyphenyl triazine 2 17. Tripropylene glycol 3 18. Purified water 15 * 47: FR-5 (manufactured by Momentive)
  • the aerosol-type foundation cosmetic of Example 52 was sprayed onto a mat and then evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an aerosol-type foundation cosmetic that was excellent in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.

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Abstract

The present invention provides a cosmetic that has smooth spreadability during application, and after application, has an effect of naturally covering the color tone problems of the cristae cutis, has an excellent effect of covering the irregularities of the skin surface, and has a high cosmetic persistence effect.　The present invention relates to a cosmetic containing the following components (A) and (B): (A) a synthetic phlogopite iron; and (B) 0.1-5 mass% of a crosslinked non-emulsifiable silicone elastomer.

Description

化粧料Cosmetics
　本発明は、化粧料に関するものである。 The present invention relates to cosmetics.
　ファンデーションやコンシーラーに代表されるメイクアップ化粧料は、肌の色を整え、毛穴やしわといった肌表面の凹凸を隠すことによって肌を美しく演出することを主要な目的として使用されている。しみ、そばかす、色むらといった色調トラブルをカバーする為には、従来、主として高い隠ぺい性を有する酸化チタン等が用いられてきた。それらを高含有した化粧料では、しみ、そばかす等の色調トラブルに対しては効果があるものの、仕上がりが白く、厚ぼったくなり透明感のない不自然な仕上がりになり、凹凸がかえって目立ってしまうという欠点があった。 Makeup cosmetics such as foundations and concealers are used mainly for the purpose of adjusting the color of the skin and hiding the unevenness of the skin surface such as pores and wrinkles to make the skin beautiful. In order to cover color tone problems such as spots, freckles, and color unevenness, titanium oxide or the like, which has a high concealing property, has been mainly used. Cosmetics with a high content of them are effective against color tone problems such as spots and freckles, but they have the disadvantage that the finish is white, thickened, and has an unnatural finish without transparency, and unevenness is rather noticeable. was there.
　このような不自然な仕上がり課題を解決するため、例えば、肌の母斑、血管腫、赤ら顔、しみ、そばかす等によって生じた肌の濃色部分（色調トラブル部分）に対して、補色、又は、補色近傍の色域を透過干渉光として有する物質を含有することを特徴とする肌色調整用組成物が提案されている（例えば特許文献１参照）。この方法によれば、肌をくすませることなく、色調トラブルを改善することが可能である。 In order to solve such an unnatural finish problem, for example, complementary colors or complementary colors to dark skin parts (color tone trouble parts) caused by nevus, hemangiomas, reddish face, stains, freckles, etc. of the skin are used. A composition for adjusting skin color, which comprises a substance having a color range in the vicinity of complementary colors as transmitted interference light, has been proposed (see, for example, Patent Document 1). According to this method, it is possible to improve the color tone trouble without dullness of the skin.
　また、これ以外にも干渉色の反射光の観測方向による色の変化が少ない特定の粉体と、酸化鉄・酸化チタン焼結有色顔料とを含有する、皮膚化粧料が提案されている（例えば特許文献２参照）。この方法によれば、透明感を持たせつつ、肌の色相を組み合わせによって変化させることができると共に、皮脂による化粧崩れも生じない化粧料が得られるという提案である。 In addition to this, skin cosmetics containing a specific powder having little color change depending on the observation direction of the reflected light of the interference color and an iron oxide / titanium oxide sintered colored pigment have been proposed (for example). See Patent Document 2). According to this method, it is proposed that a cosmetic product can be obtained in which the hue of the skin can be changed by a combination while maintaining a transparent feeling, and the makeup does not collapse due to sebum.
　一方、自然な皮膚の色に近い色彩を有する粉体として、鉄含有合成雲母を特定の温度で熱処理することによって、従来の合成雲母には全く見られなかった耐光性のある鮮やかな赤色の外観を呈し、しかも紫外線遮断能にも極めて優れた新規合成雲母が得られることを見いだし、色だけではなく紫外線を効果的に遮断する合成雲母を化粧料へ含有する試みもなされている（例えば特許文献３参照）。さらに、鉄元素を含有する合成雲母粉体に酸化物で被覆した複合マイカ粉体が提案されている（例えば特許文献４参照）。乾燥時は略白色であるが、液体に濡れると肌色に変色することを特徴とし、従来にない色彩を付与したパ－ル感を発現する複合マイカ粉体を提供すること試みもなされている。 On the other hand, by heat-treating iron-containing synthetic mica at a specific temperature as a powder having a color close to the natural skin color, a bright red appearance with light resistance that was not seen in conventional synthetic mica at all. It has been found that a novel synthetic mica that exhibits the above and is extremely excellent in UV blocking ability can be obtained, and attempts have been made to include synthetic mica that effectively blocks UV rays as well as color in cosmetics (for example, Patent Documents). 3). Further, a composite mica powder obtained by coating a synthetic mica powder containing an iron element with an oxide has been proposed (see, for example, Patent Document 4). Attempts have been made to provide a composite mica powder that is substantially white when dried, but changes to a flesh color when wet with a liquid, and exhibits a pearly feeling with an unprecedented color.
特開平８－８１３３２号公報Japanese Unexamined Patent Publication No. 8-81332 特開平１１－４３４１４号公報Japanese Unexamined Patent Publication No. 11-43414 特開平６－９２１０号公報Japanese Unexamined Patent Publication No. 6-9210 特開平7－２５８０３１号公報Japanese Unexamined Patent Publication No. 7-258031
　しかしながら、特許文献１の技術では、表面光沢を有するため自然なカバー力が得られず、化粧持ちが好ましくない場合があった。また、特許文献２の技術では、凝集性が高く、滑らかな使用感を得られない場合があった。さらに、特許文献３や４の技術では、光沢性が高く、大きい形状の場合に凹凸が目立つ傾向を改善する必要があり、皮脂に濡れた時に色変化が大きいことによる化粧持ちの課題が生じる場合があった。 However, in the technique of Patent Document 1, since it has a surface gloss, natural covering power cannot be obtained, and there are cases where makeup retention is not preferable. Further, in the technique of Patent Document 2, the cohesiveness is high and a smooth feeling of use may not be obtained in some cases. Further, in the techniques of Patent Documents 3 and 4, it is necessary to improve the tendency that unevenness is conspicuous in the case of a large shape having high glossiness, and there is a problem of long-lasting makeup due to a large color change when wet with sebum. was there.
　このように、従来の技術においては、毛穴・しわ等のような肌表面の凹凸のカバー効果を有しつつ、色むら、しみ、クマ等のような皮丘の自然なカバー効果をも同時に満たす化粧料の着想がなかったが、本発明者らはこれら効果を同時に満たす化粧料の提供を試みた。 As described above, in the conventional technique, while having the effect of covering the unevenness of the skin surface such as pores and wrinkles, it also simultaneously satisfies the natural covering effect of the skin hills such as uneven color, stains and bears. Although there was no idea of cosmetics, the present inventors tried to provide cosmetics satisfying these effects at the same time.
　本発明は、上記事情に鑑みてなされたもので、その主な目的は、塗布時は滑らかな伸び広がりを有しており、塗布後は、皮丘の色調トラブルを自然にカバーする効果を有し、肌表面の凹凸のカバー効果に優れ、さらに化粧持続効果の高い化粧料を提供することにある。 The present invention has been made in view of the above circumstances, and its main purpose is to have a smooth spreading and spreading during application, and to have an effect of naturally covering color tone troubles of skin hills after application. However, it is an object of the present invention to provide a cosmetic having an excellent effect of covering unevenness on the surface of the skin and having a high effect of sustaining makeup.
　本発明者らは、上記課題を解決するために、鋭意検討した結果、合成金雲母鉄と架橋型非乳化性シリコーンエラストマーとを含有することで、驚くべきことに、合成金雲母鉄でツヤ感を付与して色味を自然にカバーしつつも、特定量の架橋型非乳化性シリコーンエラストマーによって光を拡散させ、毛穴カバー効果との両立が可能となり、しかもこれら併用により塗布時のなめらかな伸び広がり及び塗布後の化粧持続性も良好であったことで、上記課題が解決されることを見出し、本発明を完成するに至った。 As a result of diligent studies to solve the above problems, the present inventors have surprisingly found that the synthetic phlogopite iron has a glossy feeling due to the inclusion of the synthetic phlogopite iron and the crosslinked non-emulsifying silicone elastomer. While naturally covering the color, a specific amount of cross-linked non-emulsifying silicone elastomer diffuses light, making it possible to achieve both a pore-covering effect, and by using these in combination, smooth elongation during application is possible. It was found that the above-mentioned problems were solved by the fact that the spread and the long-lasting makeup after application were good, and the present invention was completed.
　すなわち、本発明は、以下のとおりである。
〔１〕
　次の成分（Ａ）及び（Ｂ）；
（Ａ）合成金雲母鉄（Ｂ）架橋型非乳化性シリコーンエラストマー０．１～５．０質量％
を含有する化粧料である。
〔２〕
　さらに成分（Ｃ）として、平均粒子径０．１～４．０μｍの酸化チタン及び酸化亜鉛から選ばれる１種又は２種以上の金属酸化物を含有する〔１〕記載の化粧料である。
〔３〕
　さらに成分（Ｄ）として、シリコーンパウダー、ウレタンパウダー、ナイロンパウダー、セルロースパウダー、ポリメタクリル酸メチルパウダー及びシリカから選ばれる１種又は２種以上の粉体を含有する〔１〕又は〔２〕に記載の化粧料である。
〔４〕
　前記成分（Ｃ）が、さらに酸化鉄で被覆されている〔２〕に記載の化粧料である。
〔５〕
　前記成分（Ａ）が、さらに酸化チタンで被覆されている〔１〕～〔４〕の何れか１つに記載の化粧料である。
〔６〕
　前記成分（Ａ）と成分（Ｂ）の含有質量割合、（Ａ）／（Ｂ）が、１．０～１００．０である〔１〕～〔５〕の何れか１つに記載の化粧料である。
〔７〕
　前記成分（Ａ）が、分光色彩計を用いて、入射角－４５°、受光角０°の測定において、セルに成分（Ａ）を２０回タッピングさせて測定した際に、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系で規定される測色値Ｌ＊、Ｃ＊、ｈが、６３＜Ｌ＊＜８３、１２＜Ｃ＊＜３２、５０＜ｈ＜７６である〔５〕に記載の化粧料である。
〔８〕
　前記成分（Ｄ）が、セルロースパウダー、デンプンパウダー、及びシリカから選ばれる１種又は２種以上の粉体を含有する〔３〕～〔７〕の何れか一項に記載の化粧料。
〔９〕
　前記成分（Ａ）が、ブルーライトカット剤である〔１〕～〔８〕の何れか一項に記載の化粧料である。 That is, the present invention is as follows.
[1]
The following components (A) and (B);
(A) Synthetic phlogopite iron (B) Cross-linked non-emulsifying silicone elastomer 0.1-5.0% by mass
It is a cosmetic containing.
[2]
Further, the cosmetic according to [1], which contains one or more metal oxides selected from titanium oxide and zinc oxide having an average particle diameter of 0.1 to 4.0 μm as the component (C).
[3]
Further described in [1] or [2], which contains one or more powders selected from silicone powder, urethane powder, nylon powder, cellulose powder, polymethyl methacrylate powder and silica as the component (D). Cosmetics.
[4]
The cosmetic according to [2], wherein the component (C) is further coated with iron oxide.
[5]
The cosmetic according to any one of [1] to [4], wherein the component (A) is further coated with titanium oxide.
[6]
The cosmetic according to any one of [1] to [5], wherein the content mass ratio of the component (A) and the component (B), (A) / (B) is 1.0 to 100.0. Is.
[7]
CIE1976L * a * b when the component (A) was measured by tapping the component (A) 20 times on the cell in the measurement of the incident angle −45 ° and the light receiving angle 0 ° using a spectrocolorimeter. * The cosmetics according to [5], wherein the colorimeters L *, C *, and h defined by the color system are 63 <L * <83, 12 <C * <32, 50 <h <76. be.
[8]
The cosmetic according to any one of [3] to [7], wherein the component (D) contains one or more powders selected from cellulose powder, starch powder, and silica.
[9]
The cosmetic according to any one of [1] to [8], wherein the component (A) is a blue light-cutting agent.
　また、本技術は、以下の構成をさらに追加採用することも可能である。
〔１０〕
　前記成分（Ｃ）が、板状形状、又は（Ａ）以外の板状粉体に被覆複合化されている〔２〕～〔６〕の何れか１つに記載の化粧料である。
〔１１〕
　前記成分（Ａ）の平均粒子径が、５～１１μｍである〔１〕～〔１０〕の何れか１つに記載の化粧料である。
〔１２〕
　前記成分（Ａ）又は（Ｃ）をさらに疎水化表面処理剤で表面処理した〔１〕～〔１１〕の何れか１つに記載の化粧料である。
〔１３〕
　前記〔１〕～〔１２〕の何れか１つに記載の化粧料が、油性又は粉末の固形化粧料である。 In addition, the present technology can additionally adopt the following configurations.
[10]
The cosmetic according to any one of [2] to [6], wherein the component (C) is coated with a plate-shaped powder or a plate-shaped powder other than (A).
[11]
The cosmetic according to any one of [1] to [10], wherein the average particle size of the component (A) is 5 to 11 μm.
[12]
The cosmetic according to any one of [1] to [11], wherein the component (A) or (C) is further surface-treated with a hydrophobic surface treatment agent.
[13]
The cosmetic according to any one of [1] to [12] is an oily or powdery solid cosmetic.
　本発明の化粧料は、塗布時は滑らかな伸び広がりを有しており、塗布後は、皮丘の色調トラブルを自然にカバーする効果を有し、肌表面の凹凸のカバー効果に優れ、さらに化粧持続効果の高い化粧料を提供する。 The cosmetic of the present invention has a smooth spread and spread when applied, has an effect of naturally covering color tone troubles of skin hills after application, has an excellent effect of covering unevenness on the skin surface, and further. Providing cosmetics with a long-lasting makeup effect.
成分（Ａ）と比較品の各波長の透過率（１００％－透過率＝遮蔽率）；具体的には、（１）成分（Ａ）酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）と、（２）成分（Ａ）合成金雲母鉄（平均粒子径５～１１μｍ、ＰＤＭ－ＦＥ（トピー工業社製））と、（３）合成金雲母　（平均粒子径５μｍ）（ＰＤＭ-５L：トピー工業社製））を示す図である。Permeability of each wavelength of component (A) and comparative product (100% -permeability = shielding rate); Specifically, (1) component (A) titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm) , Titanium oxide coating amount 11-14%, tin oxide coating), (2) Component (A) Synthetic phlogopite iron (average particle size 5-11 μm, PDM-FE (manufactured by Topy Industries, Ltd.)), (3) It is a figure which shows the synthetic phlogopite (average particle diameter 5 μm) (PDM-5L: manufactured by Topy Industries, Ltd.). 成分（Ａ）酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）（左）と、成分（Ａ）合成金雲母鉄（平均粒子径５～１１μｍ、ＰＤＭ－ＦＥ（トピー工業社製））（中央）と、合成金雲母（平均粒子径５μｍ）（ＰＤＭ-５L：トピー工業社製））（右）と、における各粉体のブルーライトカット機能（３８０～５００ｎｍの遮蔽率）を示す図である。Component (A) Titanium oxide-coated synthetic gold mica iron (average particle size 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating) (left) and component (A) Synthetic gold mica iron (average particle size 5) ~ 11 μm, PDM-FE (manufactured by Topy Industries) (center) and synthetic gold mica (average particle size 5 μm) (PDM-5L: manufactured by Topy Industries)) (right), blue light of each powder It is a figure which shows the cut function (shielding ratio of 380 to 500 nm). 成分（Ａ）と素肌の可視光相対分光反射率比較；具体的には、酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）と素肌の比較を示す図である。Comparison of visible light relative spectral reflectance of component (A) and bare skin; specifically, titanium oxide-coated synthetic phlogopite iron (average particle size 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating) and bare skin It is a figure which shows the comparison of.
　以下、本発明の好ましい実施形態について詳細に説明する。ただし、本発明は以下の好ましい実施形態に限定されず、本発明の範囲内で自由に変更することができるものである。なお、本明細書において百分率は特に断りのない限り質量による表示である（質量／質量％）。また、各数値範囲（～）の上限値（以下）と下限値（以上）は、所望により、任意に組み合わせることができる。さらに、本明細書における「平均粒子径」とは、走査型電子顕微鏡（日本電子製、ＪＳＭ－７８００ｐｒｉｍｅ）を用いて、表面状態を観察し、画像解析装置（ルーゼックスＡＰ、ニレコ社製）による測定により求めた値（メジアン径Ｄ５０）であり、粒子の長径を指すものとする。 Hereinafter, preferred embodiments of the present invention will be described in detail. However, the present invention is not limited to the following preferred embodiments, and can be freely changed within the scope of the present invention. In the present specification, the percentage is expressed by mass (mass / mass%) unless otherwise specified. Further, the upper limit value (or less) and the lower limit value (or more) of each numerical range (to) can be arbitrarily combined. Further, the "average particle size" in the present specification is measured by an image analyzer (Luzex AP, manufactured by Nireco) by observing the surface state using a scanning electron microscope (JSM-7800 prime manufactured by JEOL Ltd.). It is a value (median diameter D50) obtained by the above, and refers to the major axis of the particles.
　本発明は、成分（Ａ）合成金雲母鉄、成分（Ｂ）架橋型非乳化性シリコーンエラストマーを含有する化粧料を提供することができ、当該成分（Ｂ）の化粧料中の含有量は、０．１～５．０質量％であることが好適であり、さらに当該〔成分（Ａ）／成分（Ｂ）〕が特定の含有質量割合であることがより好適である。また、本発明は、成分（Ａ）が、金属酸化物被覆の合成金雲母鉄及び／又はブルーライトカット用の合成金雲母鉄若しくは金属酸化物被覆の合成金雲母鉄を含むブルーライトカット剤であることが好適である。さらに、本発明は、成分（Ｃ）として金属酸化物の粉体、成分（Ｄ）として有機及び／又は無機の粉体（より好適には植物由来の多糖類粉体及び／又はシリカ粉体）を、使用すること又は化粧料に含有させることが、より好適である。 The present invention can provide a cosmetic containing the component (A) synthetic phlogopite iron and the component (B) a crosslinked non-emulsifying silicone elastomer, and the content of the component (B) in the cosmetic can be determined. It is preferably 0.1 to 5.0% by mass, and more preferably the [component (A) / component (B)] has a specific content mass ratio. Further, in the present invention, the component (A) is a blue light-cutting agent containing synthetic phlogopite iron coated with a metal oxide and / or synthetic phlogopite iron for blue light cutting or synthetic phlogopite iron coated with a metal oxide. It is preferable to have. Further, in the present invention, the component (C) is a powder of a metal oxide, and the component (D) is an organic and / or an inorganic powder (more preferably, a plant-derived polysaccharide powder and / or a silica powder). Is more preferably used or contained in cosmetics.
　本発明によれば、塗布時は滑らかな伸び広がりを有しており、塗布後は、皮丘の色調トラブル（例えば、色ムラ、シミ、クマ等）を自然にカバーする効果を有し、肌表面の凹凸（例えば、毛穴、シワ等）のカバー効果に優れ、さらに化粧持続効果の高い化粧料を提供することができる。さらに、成分（Ａ）の粒子径調整により凹凸を強調させるような違和感のあるぎらつき感がないカバー効果を有する化粧料にすることも可能である。 According to the present invention, it has a smooth spreading and spreading during application, and after application, it has an effect of naturally covering color troubles (for example, color unevenness, stains, bears, etc.) of skin hills, and has an effect on the skin. It is possible to provide a cosmetic having an excellent covering effect on surface irregularities (for example, pores, wrinkles, etc.) and a high makeup lasting effect. Further, by adjusting the particle size of the component (A), it is possible to obtain a cosmetic having a covering effect without a feeling of discomfort and glare that emphasizes unevenness.
＜成分（Ａ）＞
　本発明に用いる成分（Ａ）である合成金雲母鉄とは、結晶構造中に鉄元素を少なくとも含有する合成金雲母であり、板状であることが好ましい。本発明に用いる成分（Ａ）合成金雲母鉄とは、ケイフッ化カリウム、酸化マグネシウム、酸化アルミニウム、二酸化珪素及び酸化鉄等を出発原料とすることが好ましい。成分（Ａ）合成金雲母鉄には、金属酸化物被覆及び／又は表面処理がされていてもよい合成金雲母鉄の粉体が含まれていてもよい。この成分（Ａ）を含有すると、滑らかな伸び広がりを向上させ、適用後は、ぎらつき感がなく、皮丘の自然なカバー効果を提供し、とりわけ、色むら、しみ、クマ等の色調トラブルを有する部位への適用に有効である。 <Ingredient (A)>
The synthetic phlogopite iron, which is the component (A) used in the present invention, is a synthetic phlogopite containing at least an iron element in the crystal structure, and is preferably plate-shaped. The component (A) synthetic phlogopite iron used in the present invention is preferably made from potassium silicate, magnesium oxide, aluminum oxide, silicon dioxide, iron oxide and the like as starting materials. Component (A) Synthetic phlogopite iron may contain powder of synthetic phlogopite iron which may be coated with a metal oxide and / or surface-treated. When this component (A) is contained, smooth spreading and spreading are improved, and after application, there is no glare and a natural covering effect of skin hills is provided. It is effective for application to the site having.
　成分（Ａ）の色調は、特に限定はしないが、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系で表すことができ、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系の測定値は、公知のＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系測定機器を用いて行うことができる。成分（Ａ）のＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系の色調は、分光色彩計（例えば、分光色彩計ＳＥ７７００（日本電色工業株式会社製））を用いて、入射角－４５°、受光角０°の測定において、セルに成分（Ａ）を２０回タッピングさせて測定した際に、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系で規定される測色値Ｌ＊（明度）、Ｃ＊（彩度）、ｈ（色相）が、６３＜Ｌ＊＜８３、１２＜Ｃ＊＜３２、５０＜ｈ＜７６の範囲であると好ましい。６３＜Ｌ＊＜７５、１８＜Ｃ＊＜２５、５０＜ｈ＜７０の範囲がより好ましい。特に、６８＜Ｌ＊＜７５、１８＜Ｃ＊＜２５、５５＜ｈ＜７０の範囲がさらに好ましく、具体的な例としては、例えば、平均粒子径５～１１μｍの酸化チタン１１～１４％被覆の合成金雲母鉄であり酸化スズを酸化チタンの結合剤として被覆しているものが挙げられる。この成分（Ａ）を含有すると、滑らかな伸び広がりを向上させ、適用後は、ぎらつき感がなく、皮丘の自然なカバー効果を提供し、とりわけ、色むら、しみ、クマ等の色調トラブルを有する部位への適用に有効である。 The color tone of the component (A) is not particularly limited, but can be represented by a CIE1976L * a * b * color system, and the measured value of the CIE1976L * a * b * color system is a known CIE1976L * a * b. * It can be done using a color tone measuring device. For the color tone of the CIE1976L * a * b * color system of the component (A), an incident angle of −45 ° and a light receiving angle were obtained using a spectral chromaticity meter (for example, a spectral chromaticity meter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.)). In the measurement of 0 °, when the cell is tapped with the component (A) 20 times and measured, the color measurement values L * (brightness) and C * (saturation) specified by the CIE1976L * a * b * color system are used. ), H (hue) is preferably in the range of 63 <L * <83, 12 <C * <32, 50 <h <76. The range of 63 <L * <75, 18 <C * <25, 50 <h <70 is more preferable. In particular, the range of 68 <L * <75, 18 <C * <25, 55 <h <70 is more preferable, and specific examples thereof include, for example, 11 to 14% titanium oxide coating having an average particle diameter of 5 to 11 μm. Synthetic phlogopite iron, which is coated with tin oxide as a binder for titanium oxide. When this component (A) is contained, smooth spreading and spreading are improved, and after application, there is no glare and a natural covering effect of skin hills is provided. It is effective for application to the site having.
　成分（Ａ）の相対色調は、可視光相対分光反射率（７２０ｎｍを１とした場合）と、素肌の可視光相対分光反射率（７２０ｎｍを１とした場合）との関係に基づき、素肌の可視光相対分光反射率を相対基準（１．０）とした場合、４１０ｎｍ～５４０ｎｍの間では好適には－０．２～＋０．２の範囲内、より好適には－０．１～＋０．１の範囲内であり、及び／又は、５４０ｎｍ～６２０ｎｍの間では好適には－０．５～＋０．５の範囲内、より好適には－０．３～＋０．３の範囲内であり、及び／又は、６２０ｎｍ～７１０ｎｍの間では好適には－０．２～＋０．２の範囲内、より好適には－０．１～＋０．１の範囲内であり、これらから１種、２種又は３種を組み合わせてもよい。成分（Ａ）は当該相対色調の範囲内になることで皮丘の色調トラブル及び肌表面の凹凸をカバーすることができる。このとき対比する素肌の可視光相対分光反射率は、日本人女性の標準色素肌の可視光相対分光反射率を用いることが好ましく、この相対基準を用いる場合には、成分（Ａ）を日本人系又はモンゴロイド人種系（黄色系）に使用しやすい。可視光相対分光反射率は、後記〔実施例〕の＜可視光相対分光反射率試験＞に従って測定することができる。 The relative color tone of the component (A) is visible to the bare skin based on the relationship between the visible light relative spectral reflectance (when 720 nm is 1) and the visible light relative spectral reflectance of the bare skin (when 720 nm is 1). When the optical relative spectral reflectance is used as the relative reference (1.0), the range between 410 nm and 540 nm is preferably in the range of -0.2 to +0.2, and more preferably -0.1 to +0.1. And / or between 540 nm and 620 nm, preferably in the range of -0.5 to +0.5, more preferably in the range of -0.3 to +0.3, and / Or, between 620 nm and 710 nm, it is preferably in the range of -0.2 to +0.2, more preferably in the range of -0.1 to +0.1, and one, two or more. You may combine three kinds. When the component (A) is within the range of the relative color tone, it is possible to cover the color tone trouble of the skin hill and the unevenness of the skin surface. For the visible light relative spectral reflectance of the bare skin to be compared at this time, it is preferable to use the visible light relative spectral reflectance of the standard pigmented skin of Japanese women. Easy to use for strains or Mongoloid races (yellowish). The visible light relative spectral reflectance can be measured according to the <visible light relative spectral reflectance test> described later [Example].
　本発明に用いる成分（Ａ）の粉体の結晶構造中に鉄元素を含有する合成雲母粉体の製造方法は、溶融合成法を用いることができ、公知の溶解合成方法を用いてもよい。溶融合成法で鉄元素を含有する合成雲母を製造するには、ケイフッ化カリウム、酸化マグネシウム、酸化アルミニウム、二酸化珪素及び酸化鉄等の原料を所定のモル数で混合し、１４００℃～１６００℃で溶融後、冷却して結晶化させ、得られた結晶塊は、公知の粉砕方法で微粉化し、酸水溶液中で、撹拌しながら処理した後、脱水、洗浄、乾燥する。この乾燥粉体を、７００～１２００℃で熱処理して前記結晶構造中に鉄元素を含有する合成金雲母鉄粉体とすることができる。当該合成金雲母鉄の粉体に対してさらに酸化チタン等の金属酸化物で被覆することが好ましい。また、金属酸化物被覆合成金雲母鉄複合体又は酸化チタン被覆合成金雲母鉄複合体に対して、さらに表面処理剤で処理することが好ましく、より好適には撥水化処理する処理剤（疎水化剤）で表面処理を施すことである。 As a method for producing a synthetic mica powder containing an iron element in the crystal structure of the powder of the component (A) used in the present invention, a melt synthesis method can be used, or a known melt synthesis method may be used. In order to produce synthetic mica containing an iron element by the melt synthesis method, raw materials such as potassium silicate, magnesium oxide, aluminum oxide, silicon dioxide and iron oxide are mixed in a predetermined number of moles and at 1400 ° C to 1600 ° C. After melting, it is cooled and crystallized, and the obtained crystal mass is atomized by a known pulverization method, treated in an acid aqueous solution with stirring, and then dehydrated, washed, and dried. This dry powder can be heat-treated at 700 to 1200 ° C. to obtain synthetic phlogopite iron powder containing an iron element in the crystal structure. It is preferable to further coat the synthetic phlogopite iron powder with a metal oxide such as titanium oxide. Further, it is preferable to further treat the metal oxide-coated synthetic phlogopite composite or the titanium oxide-coated synthetic phlogopite composite with a surface treatment agent, and more preferably, a treatment agent for water-repellent treatment (hydrophobic treatment). The surface treatment is performed with an agent).
　本発明に用いるブルーライトカット剤とは、ブルーライトカット効果を有する合成金雲母鉄であり、ブルーライトカットのために用いる粉体である。当該ブルーライトカット用の合成金雲母鉄としては、結晶内に酸化鉄を均一に含むため、３８０～５００ｎｍ波長のブルーライトカット効果を有するものが好ましく、当該ブルーライトカット機能（３８０～５００ｎｍ遮蔽率）が、好適な下限値として、好ましくは３０％以上、より好ましくは３５％以上、より好ましくは４０％以上、より好ましくは４５％以上、より好ましくは５０％以上が挙げられる。当該ブルーライトカットの目的に用いる合成金雲母鉄として、さらに金属酸化物（好適には、酸化鉄、酸化チタン、酸化スズ、酸化亜鉛及び／又は酸化セリウム）で被覆された、金属酸化物被覆合成金雲母鉄が好ましく、より好ましくは酸化チタン被覆合成金雲母鉄複合体及び／又は酸化亜鉛被覆合成金属雲母鉄複合体が好適であり、金属酸化物被覆合成金雲母鉄は、ブルーライトカット機能（３８０～５００ｎｍ遮蔽率）が４０％以上のものが好適である。さらに好ましくは、酸化チタン及び酸化スズ被覆合成金雲母鉄複合体が好適である。酸化スズを併用すると被覆した酸化チタンの結晶構造はルチル型となりやすく、被覆した酸化チタンの安定性上より好ましい。ブルーライトカット効果評価及びその効果評価確認試験については、後記〔実施例〕にて示す。 The blue light cutting agent used in the present invention is synthetic phlogopite iron having a blue light cutting effect, and is a powder used for blue light cutting. The synthetic phlogopite iron for blue light cut is preferably one having a blue light cut effect having a wavelength of 380 to 500 nm because iron oxide is uniformly contained in the crystal, and the blue light cut function (380 to 500 nm shielding rate). ), As a suitable lower limit value, preferably 30% or more, more preferably 35% or more, more preferably 40% or more, more preferably 45% or more, still more preferably 50% or more. As the synthetic gold mica iron used for the purpose of the blue light cut, a metal oxide-coated synthesis further coated with a metal oxide (preferably iron oxide, titanium oxide, tin oxide, zinc oxide and / or cerium oxide). Gold mica iron is preferable, and titanium oxide-coated synthetic gold mica iron complex and / or zinc oxide-coated synthetic metal mica iron complex is preferable, and the metal oxide-coated synthetic gold mica iron has a blue light cut function (blue light cut function). Those having a shielding rate of 380 to 500 nm) of 40% or more are preferable. More preferably, a titanium oxide and tin oxide-coated synthetic phlogopite composite is suitable. When tin oxide is used in combination, the crystal structure of the coated titanium oxide tends to be rutile type, which is preferable from the viewpoint of the stability of the coated titanium oxide. The blue light cut effect evaluation and the effect evaluation confirmation test will be described later [Example].
　本発明に用いる成分（Ａ）は、さらに表面に酸化チタンで被覆されている、酸化チタン被覆合成金雲母鉄が好ましい。酸化チタンで被覆した成分（Ａ）の複合粉体は、特に、その色彩の点で好ましい。本発明による組成物の適用時、酸化チタンが表面に被覆されていることで、色ムラカバー効果がより高まり、艶やかな仕上がりに加え、乾燥状態から皮脂に濡れたときの色変化の低減等により、化粧持続効果も高まるため好ましい。さらに、酸化チタンで被覆した成分（Ａ）の複合粉体は、優れたブルーライトカット効果や紫外線遮断作用も有しているため好ましい。具体的な例としては、酸化チタン１１～１４％被覆の合成金雲母鉄が好ましく、酸化スズを酸化チタンの結合剤として被覆しているものがより好ましい。酸化スズの量は特に限定しないが、０．５～２．０％被覆したものが好ましい例として挙げられ、ルチル型にできる量が好ましい。 The component (A) used in the present invention is preferably titanium oxide-coated synthetic phlogopite iron whose surface is further coated with titanium oxide. The composite powder of the component (A) coated with titanium oxide is particularly preferable in terms of its color. When the composition according to the present invention is applied, the surface is coated with titanium oxide, so that the effect of covering uneven color is further enhanced, and in addition to a glossy finish, the color change when wet with sebum from a dry state is reduced. It is preferable because it enhances the long-lasting effect of makeup. Further, the composite powder of the component (A) coated with titanium oxide is preferable because it also has an excellent blue light blocking effect and an ultraviolet blocking effect. As a specific example, synthetic phlogopite iron coated with 11 to 14% titanium oxide is preferable, and tin oxide coated with tin oxide as a binder is more preferable. The amount of tin oxide is not particularly limited, but a coating of 0.5 to 2.0% is given as a preferable example, and an amount that can be formed into a rutile type is preferable.
　本発明の成分（Ａ）において、合成金雲母鉄の粉体をさらに酸化チタンで被覆する方法は、公知の被覆方法で行えば良い。例えば、希薄なチタン酸水溶液中に鉄元素を含有する合成雲母粉体を懸濁させ、７０～１００℃に加温し、チタン塩を加水分解して鉄元素を含有する合成雲母粉体上に水和酸化チタン粒子を析出させ、その後７００～１０００℃の高温で焼成して製造することができる。なお、反応前に表面を酸処理後に被覆しても良い。このような公知の被覆方法によって、後記〔実施例〕にて使用した酸化チタン被覆合成金雲母鉄を製造することができる。なお、試料（粉体）に含まれる各金属の表面処理量は、一般的な手法を用いて調製された試料をＩＣＰ（Inductively Coupled Plasma；誘導結合プラズマ；ＡＲＣＯＳ（独スペクトロ社））発光分析により測定して得ることができる。 In the component (A) of the present invention, the method of further coating the powder of synthetic phlogopite iron with titanium oxide may be performed by a known coating method. For example, a synthetic mica powder containing an iron element is suspended in a dilute aqueous solution of titanium acid, heated to 70 to 100 ° C., and the titanium salt is hydrolyzed onto the synthetic mica powder containing an iron element. It can be produced by precipitating hydrated titanium oxide particles and then firing at a high temperature of 700 to 1000 ° C. The surface may be coated after acid treatment before the reaction. By such a known coating method, the titanium oxide-coated synthetic phlogopite iron used in [Example] described later can be produced. The amount of surface treatment of each metal contained in the sample (powder) is determined by ICP (Inductively Coupled Plasma; Inductively Coupled Plasma; RACOS (Germany Spectro)) emission analysis of the sample prepared using a general method. It can be measured and obtained.
　本発明における金属酸化物（好適には酸化チタン）でさらに被覆されている成分（Ａ）中の金属酸化物（好適には酸化チタン）の被覆量は、特に限定されないが、被覆された成分を含む成分（Ａ）として１００％換算した場合に、当該被覆量は、好適な下限値として好ましくは１％以上、より好ましくは５％以上、さらに好ましくは９％以上であり、また、好適な上限値として好ましくは２５％以下、より好ましくは１８％以下、さらに好ましくは１４％以下であり、当該好適な数値範囲として、１～２５％が好ましく、５～１８％がより好ましく、９～１４％が最も好ましい。この範囲であれば、伸び広がりの滑らかさ、自然なカバー効果、化粧持続性に優れるため、さらにブルーライトカット効果が得られるため、より好ましい。 The coating amount of the metal oxide (preferably titanium oxide) in the component (A) further coated with the metal oxide (preferably titanium oxide) in the present invention is not particularly limited, but the coated component can be used. When converted to 100% as the component (A) to be contained, the coating amount is preferably 1% or more, more preferably 5% or more, still more preferably 9% or more as a suitable lower limit value, and a suitable upper limit value. The value is preferably 25% or less, more preferably 18% or less, still more preferably 14% or less, and the suitable numerical range is preferably 1 to 25%, more preferably 5 to 18%, and 9 to 14%. Is the most preferable. Within this range, it is more preferable because it is excellent in smoothness of spreading and spreading, a natural covering effect, and long-lasting makeup, and further a blue light cut effect can be obtained.
　また、成分（Ａ）は、さらに表面処理剤（好適には粉体を撥水化処理する処理剤（疎水化剤））により表面処理を施しているものが好ましい。当該表面処理剤は、公知の表面処理剤を用いることができ、この表面処理剤のうち、シリコーン化合物（シリコーン類ともいう）で表面処理されているものがより好ましい。さらにこのうち、ジメチコン処理されている合成金雲母鉄の粉体又はジメチコン処理されている酸化チタン被覆合成金雲母鉄の粉体が好適である。表面処理剤にて合成金雲母鉄粉体又は酸化チタン被覆合成金雲母鉄複合体などの粉体に表面処理する方法は、通常公知の方法を用いることができ、特に限定されない。このとき、粉体中の表面処理化合物の含有量は、特に限定されないが、０．１～１０％が好ましく、０．２～５％がより好ましく、０．５～３％がさらに好ましい。なお、表面処理に関しては、後述の成分（Ａ）及び成分（Ｃ）の表面処理方法も適宜採用することができる。 Further, the component (A) is preferably surface-treated with a surface treatment agent (preferably a treatment agent for water-repellent treatment of the powder (hydrophobic agent)). As the surface treatment agent, a known surface treatment agent can be used, and among the surface treatment agents, those treated with a silicone compound (also referred to as silicones) are more preferable. Further, among these, powder of synthetic phlogopite iron treated with dimethicone or powder of synthetic phlogopite coated with titanium oxide treated with dimethicone is preferable. As a method for surface-treating powder such as synthetic phlogopite powder or titanium oxide-coated synthetic phlogopite composite with a surface treatment agent, a generally known method can be used and is not particularly limited. At this time, the content of the surface-treated compound in the powder is not particularly limited, but is preferably 0.1 to 10%, more preferably 0.2 to 5%, still more preferably 0.5 to 3%. Regarding the surface treatment, the surface treatment methods of the component (A) and the component (C) described later can also be appropriately adopted.
　本発明に用いる成分（Ａ）合成金雲母鉄としては、平均粒子径の好適な下限値が好ましくは２μｍ以上、より好ましくは５μｍ以上であり、また、好適な上限値が好ましくは３０μｍ以下、より好ましくは２５μｍ以下、さらに好ましくは２０μｍ以下、さらにより好ましくは１５μｍ以下、より好ましくは１１μｍ以下である。成分（Ａ）として、好ましくは、平均粒子径が２～２０μｍ、より好ましくは５～１５μｍ、さらに好ましくは、５～１１μｍであり、また、さらにアスペクト比が３０～８０の範囲内のものであると一層好適である。この範囲であれば、凹凸を強調させるような違和感のあるぎらつき感がなく肌表面の凹凸（例えば、毛穴、シワ等）のカバー効果に優れ、さらに、伸び広がりの滑らかさ、自然なカバー効果、化粧持続性に優れるため、より好ましい。そのような合成金雲母鉄として、例えば、ＰＤＭ－ＦＥ（トピー工業株式会社製）を挙げることができる。予めシリコーン類、フッ素化合物類、金属石鹸類、油剤類等で表面処理したものを用いてもよい。なお、成分（Ａ）合成金雲母鉄には、金属酸化物被覆や表面処理がされていない合成金雲母鉄の粉体の他に、金属酸化物被覆処理された金属酸化物被覆層を有する合成金雲母鉄（「金属酸化物被覆合成金雲母鉄」ともいう）の粉体、表面処理剤の表面処理が施された表面処理層を有する合成金雲母鉄（「表面処理合成金雲母鉄」ともいう）の粉体、表面処理剤の表面処理が施された金属酸化物被覆の合成金雲母鉄の粉体（「表面処理－金属酸化物被覆合成金雲母鉄」ともいう）も含むことができ、これらから選択される１種又は２種以上を用いることができる。 As the component (A) synthetic phlogopite iron used in the present invention, a suitable lower limit value of the average particle size is preferably 2 μm or more, more preferably 5 μm or more, and a suitable upper limit value is preferably 30 μm or less. It is preferably 25 μm or less, more preferably 20 μm or less, still more preferably 15 μm or less, and even more preferably 11 μm or less. The component (A) preferably has an average particle size of 2 to 20 μm, more preferably 5 to 15 μm, still more preferably 5 to 11 μm, and an aspect ratio in the range of 30 to 80. Is more suitable. Within this range, there is no discomforting glare that emphasizes unevenness, and the effect of covering unevenness on the skin surface (for example, pores, wrinkles, etc.) is excellent, and the smoothness of spreading and spreading, the natural covering effect. , It is more preferable because it has excellent long-lasting makeup. As such synthetic phlogopite iron, for example, PDM-FE (manufactured by Topy Industries, Ltd.) can be mentioned. Those which have been surface-treated with silicones, fluorine compounds, metal soaps, oils and the like in advance may be used. In addition, the synthetic gold mica iron of the component (A) has a metal oxide coating layer coated with a metal oxide in addition to the powder of the synthetic gold mica iron not coated with a metal oxide or surface-treated. Powder of gold mica iron (also referred to as "metal oxide-coated synthetic gold mica iron"), synthetic gold mica iron having a surface-treated layer treated with a surface treatment agent (also called "surface-treated synthetic gold mica iron") Powder of synthetic gold mica iron coated with a metal oxide coated with a surface treatment agent (also referred to as "surface treatment-synthetic gold mica iron coated with a metal oxide") can also be included. , One or more selected from these can be used.
　成分（Ａ）における金属酸化物被覆（好適には酸化チタン被覆）及び／又は表面処理の合成金雲母鉄の平均粒子径としては、平均粒子径の好適な下限値が好ましくは２μｍ以上、より好ましくは５μｍ以上であり、また、好適な上限値が好ましくは３０μｍ以下、より好ましくは２５μｍ以下、さらに好ましくは２０μｍ以下、さらにより好ましくは１５μｍ以下、より好ましくは１１μｍ以下である。このときの平均粒子径は、金属酸化物被覆の合成金雲母鉄の平均粒子径であることが好適である。 As the average particle size of the metal oxide coating (preferably titanium oxide coating) and / or the surface-treated synthetic phlogopite iron in the component (A), a suitable lower limit value of the average particle size is preferably 2 μm or more, more preferably. Is 5 μm or more, and a suitable upper limit value is preferably 30 μm or less, more preferably 25 μm or less, still more preferably 20 μm or less, still more preferably 15 μm or less, still more preferably 11 μm or less. The average particle size at this time is preferably the average particle size of synthetic phlogopite iron coated with a metal oxide.
　成分（Ａ）合成金雲母鉄中における酸化鉄換算含有量は、特に制限しないが、好適な下限として、８％以上が好ましく、９％以上がより好ましく、１０％以上がさらに好ましく、また、好適な上限としては１５％以下が好ましく、１４％以下がより好ましく、１３％以下がより好ましい。また、酸化チタン被覆又は表面処理に用いられる合成金雲母鉄粉体中における酸化鉄換算含有量は、特に制限しないが、好適な下限として、８％以上が好ましく、９％以上がより好ましく、１０％以上がさらに好ましく、また、好適な上限としては２５％以下が好ましく、２０％以下がより好ましく、１７％以下がより好ましく、１５％以下がより好ましく、１４％以下がより好ましい。この範囲であると、化粧料の使用時のなめらかさと自然なカバー効果をより両立しやすく、合成金雲母鉄の平滑な形状を維持し、肌色に近しい最適な色を実現しやすくなる。 The iron oxide equivalent content in the component (A) synthetic phlogopite iron is not particularly limited, but as a suitable lower limit, 8% or more is preferable, 9% or more is more preferable, and 10% or more is further preferable, and more preferable. The upper limit is preferably 15% or less, more preferably 14% or less, and even more preferably 13% or less. The iron oxide equivalent content in the synthetic phlogopite iron powder used for titanium oxide coating or surface treatment is not particularly limited, but as a suitable lower limit, 8% or more is preferable, and 9% or more is more preferable. % Or more is more preferable, and as a suitable upper limit, 25% or less is preferable, 20% or less is more preferable, 17% or less is more preferable, 15% or less is more preferable, and 14% or less is more preferable. Within this range, it becomes easier to achieve both smoothness and a natural covering effect when using cosmetics, maintain the smooth shape of synthetic phlogopite iron, and easily realize the optimum color close to the skin color.
　成分（Ａ）における金属酸化物被覆（好適には酸化チタン被覆）及び／又は表面処理の合成金雲母鉄中における酸化鉄換算含有量は、特に制限しないが、好適な下限として、６％以上が好ましく、７％以上がより好ましく、８％以上がさらに好ましく、９％以上がより好ましく、また、好適な上限としては２５％以下が好ましく、２０％以下がより好ましく、１７％以下がより好ましい。 The iron oxide equivalent content in the synthetic phlogopite iron of the metal oxide coating (preferably titanium oxide coating) and / or the surface treatment of the component (A) is not particularly limited, but a suitable lower limit is 6% or more. Preferably, 7% or more is more preferable, 8% or more is further preferable, 9% or more is more preferable, and the preferable upper limit is 25% or less, 20% or less is more preferable, and 17% or less is more preferable.
　本発明の化粧料中における成分（Ａ）合成金雲母鉄の含有量は、特に限定されないが、化粧料総量（１００質量％）中、好適な下限として、１％以上が好ましく、３％以上がより好ましく、４％以上がさらに好ましく、５％以上がよりさらに好ましく、７％以上がよりさらに好ましく、また、好適な上限としては、２５％以下が好ましく、２０％以下がより好ましく、１８％以下がさらに好ましく、１５％以下がより好ましく、１２％以下がさらに好ましい。この範囲であれば、透明感、自然なカバー効果、滑らかな伸び広がりにより優れるため、より好ましい。 The content of the component (A) synthetic phlogopite iron in the cosmetic of the present invention is not particularly limited, but is preferably 1% or more, preferably 3% or more, as a suitable lower limit in the total amount of cosmetics (100% by mass). More preferably, 4% or more is further preferable, 5% or more is further preferable, 7% or more is further preferable, and the preferable upper limit is 25% or less, 20% or less, more preferably 18% or less. Is more preferable, 15% or less is more preferable, and 12% or less is further preferable. This range is more preferable because it is superior in transparency, natural covering effect, and smooth spreading and spreading.
　本発明の化粧料中の成分（Ａ）における金属酸化物被覆（好適には酸化チタン）及び／又は表面処理の合成金雲母鉄の含有量は、特に限定されないが、化粧料総量（１００質量％）中、好適な下限として、０．０２％以上が好ましく、０．５％以上がより好ましく、１％以上がさらに好ましく、３％以上がよりさらに好ましく、５％以上がよりさらに好ましく、また、好適な上限としては、２５％以下が好ましく、２０％以下がより好ましく、１８％以下がさらに好ましく、１５％以下がより好ましく、１２％以下がさらに好ましい。この範囲であれば、透明感、自然なカバー効果、滑らかな伸び広がりにより優れるため、より好ましい。このときの化粧料中の含有量は、金属酸化物被覆の合成金雲母鉄の含有量であることが好適であり、より好適には酸化チタン被覆の合成金雲母鉄の含有量であることがさらに好適である。 The content of the metal oxide coating (preferably titanium oxide) and / or the synthetic phlogopite iron in the surface treatment in the component (A) in the cosmetic of the present invention is not particularly limited, but the total amount of the cosmetic (100% by mass). ), As a suitable lower limit, 0.02% or more is preferable, 0.5% or more is more preferable, 1% or more is further preferable, 3% or more is further preferable, 5% or more is further preferable, and more. As a suitable upper limit, 25% or less is preferable, 20% or less is more preferable, 18% or less is further preferable, 15% or less is more preferable, and 12% or less is further preferable. This range is more preferable because it is superior in transparency, natural covering effect, and smooth spreading and spreading. The content in the cosmetic at this time is preferably the content of synthetic phlogopite iron coated with a metal oxide, and more preferably the content of synthetic phlogopite iron coated with titanium oxide. It is more suitable.
＜成分（Ｂ）＞
　本発明に用いる成分（Ｂ）架橋型非乳化性シリコーンエラストマーにおける「架橋型シリコーンエラストマー」とは、オルガノポリシロキサンを架橋結合させて得られる一部に三次元架橋構造を有する重合物のことであり（「部分架橋型シリコーンエラストマー」ともいう）、当該シリコーンエラストマーはＲＳｉＯ単位及びＲＳｉＯ１．５単位よりなり、ＲＳｉＯ０．５単位及び／又はＳｉＯ２単位を含んでいても良い。成分（Ｂ）は、具体的には、白金触媒の存在下における、ジメチルビニルシロキシ末端基を含有するジメチルポリシロキサンの、及び、トリメチルシロキシ末端基を含有するメチルハイドロジェンポリシロキサンの反応により、得られてもよい。本発明に用いる成分（Ｂ）架橋型非乳化性シリコーンエラストマーにおける「非乳化性」とは、水溶性成分を微細化して分散安定化する効果を有しないものである。成分（Ｂ）の具体例としては、例えば、ポリオキシアルキレン単位（とりわけポリオキシエチレン又はポリオキシプロピレン）又はポリグリセリル単位を含有しないオルガノポリシロキサンエラストマーが挙げられるが、これらに限定されない。また、成分（Ｂ）は、非乳化性であるが、任意成分として、乳化性（すなわち、架橋型乳化性シリコーンエラストマー）と組み合わせることができ、これらの併用においても本発明の期待する効果を発揮させることができる。架橋型乳化性シリコーンエラストマーとして、ポリオキシアルキレン単位又はポリグリセリル単位を有するものが好ましい。 <Ingredient (B)>
The "crosslinked silicone elastomer" in the component (B) crosslinked non-emulsifying silicone elastomer used in the present invention is a polymer having a partially crosslinked structure obtained by crosslinking an organopolysiloxane. (Also referred to as "partially crosslinked silicone elastomer"), the silicone elastomer comprises RSiO units and RSiO 1.5 units, and may contain RSiO 0.5 units and / or SiO 2 units. The component (B) is specifically obtained by the reaction of dimethylpolysiloxane containing a dimethylvinylsiloxy-terminated group and methylhydrogenpolysiloxane containing a trimethylsiloxy-terminated group in the presence of a platinum catalyst. May be done. The "non-emulsifying property" in the component (B) crosslinked non-emulsifying silicone elastomer used in the present invention does not have the effect of making the water-soluble component finer and stabilizing the dispersion. Specific examples of the component (B) include, but are not limited to, organopolysiloxane elastomers containing no polyoxyalkylene unit (particularly polyoxyethylene or polyoxypropylene) or polyglyceryl unit. Further, although the component (B) is non-emulsifying, it can be combined with an emulsifying property (that is, a crosslinked emulsifying silicone elastomer) as an optional component, and the combined use thereof also exhibits the expected effect of the present invention. Can be made to. As the crosslinked emulsifying silicone elastomer, those having a polyoxyalkylene unit or a polyglyceryl unit are preferable.
　より好適な成分（Ｂ）架橋型非乳化性シリコーンエラストマーとして、例えば、(ジメチコン／ビニルジメチコン)クロスポリマー、ジメチコンクロスポリマー、（ビニルジメチコン／ラウリルジメチコン)クロスポリマー、(ジメチコン／フェニルビニルジメチコン)クロスポリマー、(ジメチコン／ラウリルジメチコン)クロスポリマー、（ラウリルポリジメチルシロキシエチルジメチコン／ビスビニルジメチコン）クロスポリマー等が挙げられるが、これらに限定されない。これらから選択される１種又は２種以上を用いることができる。 More Suitable Ingredients (B) Examples of the crosslinked non-emulsifying silicone elastomer include (dimethicone / vinyldimethicone) crosspolymer, dimethicone crosspolymer, (vinyldimethicone / lauryldimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone) crosspolymer. , (Dimethicone / lauryldimethicone) crosspolymer, (laurylpolydimethylsiloxyethyl dimethicone / bisvinyldimethicone) crosspolymer and the like, but are not limited thereto. One kind or two or more kinds selected from these can be used.
　１種又は２種以上の架橋型非乳化性シリコーンエラストマーを組み合わせても使用でき、単一の種類の架橋型非乳化性シリコーンエラストマー、又は異なる種類の架橋型非乳化性シリコーンエラストマーを２種以上組合せて使用できる。 It can also be used in combination with one or more cross-linked non-emulsifying silicone elastomers, a single type of cross-linked non-emulsifying silicone elastomer, or a combination of two or more different cross-linked non-emulsifying silicone elastomers. Can be used.
　なお、成分（Ｂ）を化粧料に使用又は含有することで、肌の凹部に配向しやすい特性によりソフトフォーカス効果を付与して毛穴等の凹凸を目立たなくさせる効果に加えて、毛穴やしわ等に成分（Ｂ）が入り込んで平滑な表面を形成し、その上を成分（Ａ）の板状が肌表面に一定方向に並ぶことにより、均一で自然なカバー効果を有するとともに、肌の凹凸を強調する不具合を予め防止する効果も期待できる。 In addition, by using or containing the component (B) in cosmetics, in addition to the effect of imparting a soft focus effect due to the characteristic of easily orienting to the concave portions of the skin and making unevenness such as pores inconspicuous, pores, wrinkles, etc. The component (B) enters the skin to form a smooth surface, and the plate shape of the component (A) is lined up on the skin surface in a certain direction to have a uniform and natural covering effect and to prevent unevenness of the skin. It can also be expected to have the effect of preventing problems to be emphasized in advance.
　本発明に用成分（Ｂ）は、重合物の固体分のことであり、少なくとも１種の炭化水素系油、少なくとも１種のエステル油、及び又は少なくとも１種のシリコーン油等から選択される１種又は２種以上の溶媒に含まれるエラストマーオルガノポリシロキサンから形成されたゲルの形態（シリコーンゲル組成物ともいう）であることが好ましい。これらのゲル中で、成分（Ｂ）架橋型非乳化性シリコーンエラストマーの形状は、非球形でも球形でもどちらでもよく、特に形状は限定しない。成分（Ｂ）架橋型非乳化性シリコーンエラストマー及び溶媒を含むシリコーンゲル組成物中の当該架橋型非乳化性シリコーンエラストマーの含有量は、特に限定されないが、固形分換算で、好ましくは２～５０％程度であり、好適な下限値として好ましくは５％以上、より好ましくは１０％以上であり、また好適な上限値として好ましくは４０％以下、より好ましくは３０％以下である。 The component (B) used in the present invention is a solid component of a polymer, and is selected from at least one hydrocarbon-based oil, at least one ester oil, or at least one silicone oil1. It is preferably in the form of a gel (also referred to as a silicone gel composition) formed from an elastomer organopolysiloxane contained in a seed or two or more kinds of solvents. In these gels, the shape of the component (B) crosslinked non-emulsifying silicone elastomer may be either non-spherical or spherical, and the shape is not particularly limited. Component (B) The content of the crosslinked non-emulsifying silicone elastomer in the silicone gel composition containing the crosslinked non-emulsifying silicone elastomer and the solvent is not particularly limited, but is preferably 2 to 50% in terms of solid content. The suitable lower limit value is preferably 5% or more, more preferably 10% or more, and the suitable upper limit value is preferably 40% or less, more preferably 30% or less.
　前記成分（Ｂ）を含むゲル形態（シリコーンゲル組成物ともいう）として、具体的には、例えば、（ジメチコン／ビニルジメチコン）クロスポリマーと溶媒との混合物（例えば、シクロペンタシロキサンとの混合物、ジメチコンとの混合物、メチルトリメチコンとの混合物、又はイソドデカンとの混合物）；（ジメチコン／フェニルビニルジメチコン）クロスポリマーと、溶媒との混合物（例えば、ジフェニルエチルシロキシフェニルトリメチコンとの混合物；（ビニルジメチコン／ラウリルジメチコンクロスポリマー）と、溶媒との混合物（例えば、ミネラルオイルとの混合物、イソドデカンとの混合物、トリエチルヘキサノインとの混合物、又はスクアランとの混合物）；（ラウリルポリジメチルシロキシエチルジメチコン／ビス－ビニルジメチコン）クロスポリマーと、溶媒との混合物（例えば、イソドデカンとの混合物、又はシクロペンタシロキサンとの混合物）；溶媒（例えば、ジメチルビニルシロキシ末端基を含有するメチル（３，３，３－トリフルオロプロピル）ポリシロキサン）と、ジメチルビニルシロキシ末端基を含有するジメチルシロキサン－メチル（３，３，３－トリフルオロプロピル）シロキサンコポリマーとの混合物；（トリフルオロプロピルジメチコン／トリフルオロプロピルジビニルジメチコン）クロスポリマーと、溶媒（例えば、トリフルオロプロピルシクロテトラシロキサン／トリフルオロプロピルシクロペンタシロキサン）との混合物等が挙げられるが、これらに限定されない。これらから選択される１種又は２種以上を用いることができる。 Specific examples of the gel form (also referred to as a silicone gel composition) containing the component (B) include, for example, a mixture of a (dimethicone / vinyldimethicone) crosspolymer and a solvent (for example, a mixture of cyclopentasiloxane or dimethicone). Mixture with, mixture with methyltrimethicone, or mixture with isododecane); (dimethicone / phenylvinyldimethicone) mixture with crosspolymer and solvent (eg, mixture with diphenylethylsiloxyphenyltrimethicone; (vinyldimethicone /) A mixture of lauryldimethicone crosspolymer) and a solvent (eg, a mixture with mineral oil, a mixture with isododecane, a mixture with triethylhexanoin, or a mixture with squalane); (laurylpolydimethylsiloxyethyldimethicone / bis-vinyl). Dimethicone) A mixture of a crosspolymer with a solvent (eg, a mixture with isododecane, or a mixture with cyclopentasiloxane); a solvent (eg, methyl (3,3,3-trifluoropropyl) containing a dimethylvinylsiloxy-terminated group). ) Polysiloxane) and a mixture of dimethylsiloxane-methyl (3,3,3-trifluoropropyl) siloxane copolymer containing a dimethylvinylsiloxy terminal group; (trifluoropropyldimethicone / trifluoropropyldivinyldimethicone) crosspolymer. , Mixtures with a solvent (eg, trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane) and the like, but are not limited to these. One or more selected from these can be used.
　前記成分（Ｂ）を含むゲル形態のうち、（ジメチコン／ビニルジメチコン）クロスポリマーと溶媒との混合物、ジメチコンクロスポリマーと溶媒との混合物、（ビニルジメチコン／ラウリルジメチコン）クロスポリマーと溶媒との混合物が好ましい。ゲル形態のうち、より具体的に好ましくは、（ジメチコン／ビニルジメチコン）クロスポリマーとジメチコンとの混合物、ジメチコンクロスポリマーとシロロメチコンとの混合物、（ビニルジメチコン／ラウリルジメチコン）クロスポリマーとトリエチルヘキサノインとの混合物である。これらゲル形態から１種又は２種以上を選択することができる。 Among the gel forms containing the component (B), a mixture of a (dimethicone / vinyl dimethicone) crosspolymer and a solvent, a mixture of a dimethicone crosspolymer and a solvent, and a mixture of a (vinyldimethicone / lauryldimethicone) crosspolymer and a solvent are preferable. Of the gel forms, more specifically, a mixture of (dimethicone / vinyl dimethicone) crosspolymer and dimethicone, a mixture of dimethicone crosspolymer and silolomethicone, (vinyldimethicone / lauryldimethicone) crosspolymer and triethylhexanoin. It is a mixture. One type or two or more types can be selected from these gel forms.
　本発明に用いる成分（Ｂ）は、より具体的には、ＩＮＣＩ名製品(ジメチコン／ビニルジメチコン)クロスポリマー、(ジメチコン／フェニルビニルジメチコン)クロスポリマー、(ジメチコン／ラウリルジメチコン)クロスポリマー、（ラウリルポリジメチルシロキシエチルジメチコン／ビスビニルジメチコン）クロスポリマーが挙げられ、これらから選択される１種又は２種以上を用いることができる。市販品としては、信越化学工業株式会社によりＫＳＧ－６、ＫＳＧ－１５、ＫＳＧ－１６、ＫＳＧ－０１６Ｆ、ＫＳＧ－１８、ＫＳＧ－１９、ＫＳＧ－４１、ＫＳＧ－４２、ＫＳＧ－４３、ＫＳＧ－４４、ＫＳＧ－０４２Ｚ、ＫＳＧ－０４５Ｚ、ＫＳＧ－０４８Ｚ、ＫＳＧ－５１、ＫＳＧ－５２等の名称で販売されているものが挙げられる。また、ＩＮＣＩ名製品ジメチコンクロスポリマー、例えばＣ３～２０アルキル基で架橋されたジメチコンであるＤｏｗ Ｃｏｒｎｉｎｇ社製ＤＣ９０４０、ＤＣ９０４１、ＤＣ９２４０、及びＤＣ９０４５Ｇｅｎｅｒａｌ Ｅｌｅｃｔｒｉｃ社によりＳＦＥ ８３９の名称で販売されているものが挙げられ、これらから選択される１種又は２種以上を用いることができる。 More specifically, the component (B) used in the present invention is an INCI name product (dimethicone / vinyldimethicone) crosspolymer, (dimethicone / phenylvinyldimethicone) crosspolymer, (dimethicone / lauryldimethicone) crosspolymer, (laurylpoly). Dimethylsiloxyethyl dimethicone / bisvinyl dimethicone) crosspolymers can be mentioned, and one or more selected from these can be used. As commercial products, KSG-6, KSG-15, KSG-16, KSG-016F, KSG-18, KSG-19, KSG-41, KSG-42, KSG-43, KSG-44 by Shin-Etsu Chemical Co., Ltd. , KSG-042Z, KSG-045Z, KSG-048Z, KSG-51, KSG-52 and the like. In addition, INCI's famous product dimethicone crosspolymer, for example, those sold under the name of SFE 839 by Dow Corning's DC9040, DC9041 and DC9240, and DC9045 General Electrical, which are dimethicones crosslinked with C3 to 20 alkyl groups, can be mentioned. , One or more selected from these can be used.
　本発明の化粧料中における成分（Ｂ）架橋型非乳化性シリコーンエラストマーの含有量は、化粧料総量（１００質量％）中、好適な下限として、０．１％以上が好ましく、０．３％以上がより好ましく、０．５％以上がさらに好ましく、１．０％以上がよりさらに好ましく、また、好適な上限としては、５．０％以下が好ましく、４．０％以下がより好ましく、３．０％以下がさらに好ましい。この範囲であれば、透明感、自然なカバー力、伸び広がりにより優れ、仕上がりのソフトフォーカス効果や、化粧料の使用時のなめらかさや化粧持続性が高いため好ましい。なお、成分（Ｂ）及び油剤を含む市販品又はゲル形態等を使用又は配合することで、本発明の化粧料を得る場合には、本発明の化粧料中の成分（Ｂ）の含有量は、シリコーンエラストマーの固形分換算にて、求めることができる。 The content of the component (B) crosslinked non-emulsifying silicone elastomer in the cosmetics of the present invention is preferably 0.1% or more, preferably 0.3%, as a suitable lower limit in the total amount of cosmetics (100% by mass). The above is more preferable, 0.5% or more is further preferable, 1.0% or more is further preferable, and as a suitable upper limit, 5.0% or less is preferable, 4.0% or less is more preferable, and 3 More preferably, it is 0.0% or less. Within this range, it is preferable because it is excellent in transparency, natural covering power, and spreading and spreading, and has a soft focus effect of finish, smoothness when using cosmetics, and long-lasting makeup. When the cosmetic of the present invention is obtained by using or blending a commercially available product containing the component (B) and an oil agent or a gel form, the content of the component (B) in the cosmetic of the present invention is , Can be obtained by converting the solid content of the silicone elastomer.
　なお、前記成分（Ａ）と前記成分（Ｂ）との含有質量割合（又は使用質量割合）である（Ａ）／（Ｂ）は、好適な下限値として０．２以上が好ましく、より好ましくは１．０以上、さらに好ましくは２．０以上であり、また、好適な上限値として１００．０以下が好ましく、より好ましくは５０．０以下、さらに好ましくは４０．０以下、より好ましくは３０．０以下、より好ましくは２５．０以下、より好ましくは２０．０以下であり、当該好適な数値範囲として、（Ａ）／（Ｂ）は、０．２～１００．０であると好ましく、１．０～５０．０がより好ましく、１．５～４０．０がさらに好ましい。この範囲であると、皮丘の自然なカバー力と毛穴カバー力の両立がより期待できる。 The content mass ratio (or mass ratio used) between the component (A) and the component (B), (A) / (B), is preferably 0.2 or more as a suitable lower limit value, and more preferably. It is 1.0 or more, more preferably 2.0 or more, and a suitable upper limit value is preferably 100.0 or less, more preferably 50.0 or less, still more preferably 40.0 or less, and even more preferably 30. It is 0 or less, more preferably 25.0 or less, more preferably 20.0 or less, and (A) / (B) is preferably 0.2 to 100.0 as the suitable numerical range. .0 to 50.0 is more preferable, and 1.5 to 40.0 is even more preferable. Within this range, it can be expected that both the natural covering power of the skin hill and the pore covering power are compatible.
＜成分（Ｃ）＞
　本発明の化粧料には、さらに成分（Ｃ）として、金属酸化物、より好適には酸化チタン及び／又は酸化亜鉛を含有することが好ましく、金属酸化物の形状は粉体が好ましい。より好適な態様として、成分（Ｃ）として、平均粒子径０．１～４．０μｍの酸化チタン及び酸化亜鉛から選ばれる１種又は２種以上の金属酸化物を含有してもよい。平均粒子径がこの範囲であると、塗布時の滑らかな使用感、自然なカバー力を調整しやすくし、化粧もち効果に優れるためより好ましい。この酸化チタン及び酸化亜鉛の形状は、球状、板状、針状、紡錘状等の形状、多孔質、無孔質等の粒子構造等は特に限定されない。 <Ingredient (C)>
The cosmetic of the present invention preferably further contains a metal oxide as the component (C), more preferably titanium oxide and / or zinc oxide, and the shape of the metal oxide is preferably powder. As a more preferred embodiment, the component (C) may contain one or more metal oxides selected from titanium oxide and zinc oxide having an average particle diameter of 0.1 to 4.0 μm. When the average particle size is in this range, it is more preferable because it makes it easy to adjust the smooth feeling of use at the time of application, the natural covering power, and has an excellent cosmetic lasting effect. The shapes of titanium oxide and zinc oxide are not particularly limited to spherical, plate-shaped, needle-shaped, spindle-shaped and other shapes, and porous and non-porous particle structures and the like.
　成分（Ｃ）として用いることが可能な具体的な市販品としては、例えば、ＭＰ－１８、ＭＰ－７０１、ＭＰ－１１３３、ＭＰ－４０、ＭＰ－１００等又はそれらの複合粉体（テイカ社製）；ＭＫＲ－１（堺化学工業社製）；ＳＹＭＰＨＯＬＩＧＨＴシリーズ（日揮触媒化成社製）；ＲＯＮＡＥＬＡＩＲ　ＢＬＡＮＣＳＥＡＬＥＲ（メルクパフォーマンスマテリアルズ社製）；ＸＺ－３００Ｆ、ＸＺ－１０００Ｆ、ＸＺ－３０００Ｆ等（堺化学工業社製）；ＺｎＯ－ＣＸ（住友大阪セメント社製）；ＳＴシリーズ（チタン工業社製）等が挙げられるが、これに限定されるものではない。また、成分（Ｃ）は公知の製造方法で製造してもよく、特に限定しない。 Specific commercially available products that can be used as the component (C) include, for example, MP-18, MP-701, MP-1133, MP-40, MP-100 and the like, or composite powders thereof (manufactured by TAYCA Corporation). ); MKR-1 (manufactured by Sakai Chemical Industry Co., Ltd.); SYMPHOLIGHT series (manufactured by JGC Catalysts and Chemicals Co., Ltd.); ZO-CX (manufactured by Sumitomo Osaka Cement Co., Ltd.); ST series (manufactured by Titan Kogyo Co., Ltd.), etc., but is not limited thereto. Further, the component (C) may be produced by a known production method and is not particularly limited.
　また本発明に用いる成分（Ｃ）は、さらに鉄の酸化物又は水酸化物にて表面が被覆されていることが好ましい。本発明に用いる成分（Ｃ）は、鉄の酸化物又は水酸化物の他に、ケイ素の酸化物又は水酸化物、アルミニウムの酸化物又は水酸化物を各層として被覆していても良い。 Further, it is preferable that the surface of the component (C) used in the present invention is further coated with an iron oxide or a hydroxide. The component (C) used in the present invention may be coated with an oxide or hydroxide of silicon, an oxide of aluminum or a hydroxide as each layer in addition to the oxide or hydroxide of iron.
　成分（Ｃ）がさらに酸化鉄で被覆されている場合の被覆量は、特に限定されないが、自然なカバー力の観点から、酸化鉄被覆金属酸化物中（好適には酸化鉄被覆二酸化チタン又は酸化鉄被覆酸化亜鉛中）、好適な下限値として０．５％以上が好ましく、より好ましくは０．６％以上、さらに好ましくは０．７％以上であり、また、好適な上限値として５％以下が好ましく、より好ましくは３．５％以下、さらに好ましくは３％以下であり、当該好適な数値範囲として、０．５～５％が好ましく、０．７～３．５％がより好ましく、０．９～３％がさらに好ましい。本発明において成分（Ｃ）は、必要に応じて１種又は２種以上を用いることができる。 When the component (C) is further coated with iron oxide, the coating amount is not particularly limited, but from the viewpoint of natural covering power, the iron oxide-coated metal oxide (preferably iron oxide-coated titanium dioxide or oxidation) is used. (In iron-coated zinc oxide), a suitable lower limit value is preferably 0.5% or more, more preferably 0.6% or more, still more preferably 0.7% or more, and a suitable upper limit value is 5% or less. Is preferable, more preferably 3.5% or less, still more preferably 3% or less, and the suitable numerical range is preferably 0.5 to 5%, more preferably 0.7 to 3.5%, and 0. 9.9 to 3% is more preferable. In the present invention, as the component (C), one kind or two or more kinds can be used as needed.
　前記鉄の酸化物又は水酸化物による被覆を行う方法は特に限定されず、公知の酸化鉄の被覆処理方法を利用して行うことができる。例えば、一例として、苛性ソーダ水溶液を３０～３５℃に加温し、粉体粒子を分散させて、硫酸第二鉄を含む水溶液を添加・撹拌し、９０℃で２時間程度反応させる。得られた複合化合物を水洗・中和し乾燥させる。粉砕した後に、原料粒子と鉄の酸化物又は水酸化物を焼成（例えば、７５０～９００℃程度、１～３時間程度）して得ることができる。
　本発明における成分（Ｃ）の平均粒子径は、特に限定されないが、好適な下限として、好ましくは０．１μｍ以上であり、０．１５μｍ以上がより好ましく、０．２μｍ以上がさらに好ましく、また、好適な上限として、好ましくは４．０μｍ以下であり、３．０μｍ以下がより好ましく、１．０μｍ以下がさらに好ましい。この範囲であれば、皮丘の自然なカバー効果により優れる。また、平均粒子径が、０．２５～３．０μｍであると、さらに滑らかな使用感と自然なカバー効果を調整しやすいためさらに好ましい。 The method of coating with the iron oxide or the hydroxide is not particularly limited, and a known iron oxide coating treatment method can be used. For example, as an example, an aqueous solution of caustic soda is heated to 30 to 35 ° C., powder particles are dispersed, an aqueous solution containing ferric sulfate is added and stirred, and the mixture is reacted at 90 ° C. for about 2 hours. The obtained complex compound is washed with water, neutralized and dried. After pulverization, it can be obtained by calcining the raw material particles and iron oxide or hydroxide (for example, about 750 to 900 ° C. for about 1 to 3 hours).
The average particle size of the component (C) in the present invention is not particularly limited, but as a suitable lower limit, it is preferably 0.1 μm or more, more preferably 0.15 μm or more, further preferably 0.2 μm or more, and further. As a suitable upper limit, it is preferably 4.0 μm or less, more preferably 3.0 μm or less, still more preferably 1.0 μm or less. Within this range, the natural covering effect of the skin hills is superior. Further, it is more preferable that the average particle size is 0.25 to 3.0 μm because it is easy to adjust a smoother feeling of use and a natural covering effect.
　本発明の化粧料中における成分（Ｃ）の含有量は、特に限定されないが、化粧料総量（１００質量％）中、好適な下限値として１％以上が好ましく、より好ましくは５％以上、さらに好ましくは７％以上であり、また、好適な上限値として２０％以下が好ましく、より好ましくは１５％以下、さらに好ましくは１２％以下であり、当該好適な数値範囲として、１～２０％が好ましく、５～１５％がより好ましく、７～１２％がさらに好ましい。この範囲であれば、皮丘の自然なカバー力、伸び広がりにより優れるため、好ましい。 The content of the component (C) in the cosmetic of the present invention is not particularly limited, but is preferably 1% or more, more preferably 5% or more, and further preferably 5% or more as a suitable lower limit value in the total amount of cosmetics (100% by mass). It is preferably 7% or more, preferably 20% or less as a suitable upper limit value, more preferably 15% or less, still more preferably 12% or less, and the suitable numerical range is preferably 1 to 20%. 5 to 15% is more preferable, and 7 to 12% is even more preferable. This range is preferable because it is superior in the natural covering power and spreading of the skin hill.
　本発明に用いる成分（Ｃ）は、特に板状の形態がより好ましく、成分（Ｃ）自体が板状でもよく、又は、例えば雲母、合成雲母、ガラス、シリカ、アルミナ等の板状母体表面に成分（Ｃ）が吸着している複合板状粉体の形状であるとより好ましい。板状粉体母体に成分（Ａ）を含んでもよい。 The component (C) used in the present invention is more preferably in a plate-like form, and the component (C) itself may be in a plate-like shape, or on the surface of a plate-like body such as mica, synthetic mica, glass, silica, or alumina. It is more preferable that the shape is a composite plate-like powder to which the component (C) is adsorbed. The component (A) may be contained in the plate-shaped powder base.
＜成分（Ａ）又は（Ｃ）の表面処理方法＞
　また、本発明に用いる成分（Ａ）と成分（Ｃ）は、さらに各々、シリコーン化合物、脂肪酸金属塩、フッ素化合物、界面活性剤等の通常公知の表面処理剤により表面処理を施していることが好ましい。中でも、疎水化表面処理剤で表面処理されたものを用いると、金属酸化物の化粧料中の分散性を向上させ、肌への付着性が増し、カバー力、化粧持ちを向上させることができる点で好ましい。 <Surface treatment method for component (A) or (C)>
Further, the component (A) and the component (C) used in the present invention are further subjected to surface treatment with a commonly known surface treatment agent such as a silicone compound, a fatty acid metal salt, a fluorine compound and a surfactant, respectively. preferable. Above all, when the surface-treated with a hydrophobic surface treatment agent is used, the dispersibility of the metal oxide in the cosmetic can be improved, the adhesion to the skin can be increased, and the covering power and the long-lasting makeup can be improved. It is preferable in terms of points.
　本発明の化粧料において、例えば、シリコーン化合物、及び／又は、炭素数が１６～２４の脂肪基を有する表面処理剤（表面処理化合物ともいう）で処理された、成分（Ａ）及び／又は成分（Ｃ）が好適に用いられる。 In the cosmetic of the present invention, for example, the component (A) and / or the component treated with a silicone compound and / or a surface treatment agent having an adipose group having 16 to 24 carbon atoms (also referred to as a surface treatment compound). (C) is preferably used.
　シリコーン化合物としては、より具体的には、ＩＮＣＩ名（International Nomenclature Cosmetic Ingredient labeling names）で表すと、ジメチコン、メチコン、ハイドロゲンジメチコン、トリエトキシシリルエチルポリジメチルシロキシエチルジメチコン、トリエトキシシリルエチルポリジメチルシロキシエチルヘキシルジメチコン、（アクリレーツ／アクリル酸トリデシル／メタクリル酸トリエトキシシリルプロピル／メタクリル酸ジメチコン）コポリマー、トリエトキシカプリリルシランなどが挙げられ、これらから選択される一種又は二種以上用いることができる。このうち、ジメチコンが好適である。
　シリコーン化合物による表面処理の中では、ジメチコン処理が伸び広がりと化粧持ちの点でより好ましい。なお、シリコーン化合物である成分（Ｂ）を表面処理剤として成分（Ａ）及び／又は成分（Ｃ）の表面に用いてもよい。 More specifically, the silicone compound is represented by INCI name (International Nomenclature Cosmetic Ingredient labeling names): dimethicone, methicone, hydrogendimethicone, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethylhexyl. Examples thereof include dimethicone, (acrylate / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate) copolymer, triethoxycaprylylsilane and the like, and one or more selected from these can be used. Of these, dimethicone is preferable.
Among the surface treatments with silicone compounds, the dimethicone treatment is more preferable in terms of spreading and spreading and long-lasting makeup. The component (B), which is a silicone compound, may be used as a surface treatment agent on the surface of the component (A) and / or the component (C).
　炭素数が１６～２４の脂肪基を有する表面処理剤（表面処理化合物ともいう）の中では、具体的には、アシル化アミノ酸、リン脂質、スフィンゴ脂質等の窒素源を有する表面処理剤や、エステル基を有する油剤、脂肪酸（塩）、高級アルコール、エトキシシラン表面処理剤、アルキルチタネート表面処理剤から選ばれる１種又は２種以上がより好ましい。
　特に、脂肪基として結晶性の高い飽和直鎖脂肪基を有する表面処理剤で表面処理されたものを用いた場合、カバー力が出やすいため、伸び広がりの良い剤型において、肌上での付着力を向上させることが期待できる。また、不飽和脂肪基、又は分岐飽和脂肪基を有する表面処理剤を用いた場合は、滑らかな使用感を得ることができ、連続層が空気である場合、又は伸び広がりの悪い剤型において特に効果を発揮する可能性がある。いずれも、炭素数が１６～２４の脂肪基を有するため、肌への付着力が高まり、皮丘のカバー効果を少量で最大限発揮させ、化粧もちを向上させる効果に優れる。 Among the surface treatment agents having a fatty acid group having 16 to 24 carbon atoms (also referred to as surface treatment compounds), specifically, surface treatment agents having a nitrogen source such as acylated amino acids, phospholipids and sphingolipids, and surface treatment agents. One or more selected from an oil agent having an ester group, a fatty acid (salt), a higher alcohol, an ethoxysilane surface treatment agent, and an alkyl titanate surface treatment agent are more preferable.
In particular, when a surface-treated agent having a highly crystalline saturated linear adipose group is used as the adipose group, the covering power is easily obtained. It can be expected to improve the wearing power. Further, when a surface treatment agent having an unsaturated fatty acid group or a branched saturated fatty acid group is used, a smooth feeling of use can be obtained, especially when the continuous layer is air or in a formulation having poor spreadability. May be effective. Since all of them have a fat group having 16 to 24 carbon atoms, the adhesive force to the skin is enhanced, the effect of covering the skin hills is maximized with a small amount, and the effect of improving the long-lasting makeup is excellent.
　成分（Ａ）の表面処理として、シリコーン表面処理、又はジメチコン表面処理が好ましい。また、成分（Ｃ）の表面処理として、シリコーン表面処理（例えばジメチコン表面処理）、スフィンゴ脂質表面処理（例えばセラミドＮＧ表面処理）、リン脂質表面処理（例えば水添リン脂質表面処理）等から選択される１種又は２種以上が好ましい。 As the surface treatment of the component (A), a silicone surface treatment or a dimethicone surface treatment is preferable. Further, as the surface treatment of the component (C), it is selected from silicone surface treatment (for example, dimethicone surface treatment), sphingolipid surface treatment (for example, ceramide NG surface treatment), phospholipid surface treatment (for example, hydrogenated phospholipid surface treatment) and the like. 1 type or 2 or more types are preferable.
　なお、本発明に用いる粉体に表面処理を施すための表面処理剤として、特に限定されないが、例えば、トリアルキルシリル化剤、トリアルコキシアルキルシリル化剤、ジメチルポリシロキサン、メチルハイドロジェンポリシロキサン、高粘度シリコーン、架橋型シリコーン、フッ素変性シリコーン、アクリルーシリコーングラフト共重合体、シリコーン樹脂等のシリコーン化合物；アニオン界面活性剤、カチオン界面活性剤、非イオン界面活性剤等の界面活性剤；ステアリン酸アルミニウム等の金属石鹸類；ポリイソブチレン、ワックス（例えばミツロウ）、高級脂肪酸、高級アルコール等の油剤類；Ｎ－アシルアミノ酸等のアミノ酸化合物；パーフルオロアルキルリン酸及びこの塩、パーフルオロアルキルシラン等のフッ素化合物；レシチン、水添リン脂質等のリン脂質；セラミドＮＧ（２）等のスフィンゴ脂質等が挙げられ、これらから選択される１種又は２種以上を用いることができる。 The surface treatment agent for applying the surface treatment to the powder used in the present invention is not particularly limited, but for example, a trialkylsilylating agent, a trialkoxyalkylsilylating agent, a dimethylpolysiloxane, a methylhydrogenpolysiloxane, and the like. Silicone compounds such as high-viscosity silicones, cross-linked silicones, fluorine-modified silicones, acrylic-silicone graft copolymers, and silicone resins; surfactants such as anionic surfactants, cationic surfactants, and nonionic surfactants; stearic acid Metal soaps such as aluminum; oils such as polyisobutylene, wax (for example, beeswax), higher fatty acids, higher alcohols; amino acid compounds such as N-acylamino acids; perfluoroalkylphosphoric acid and its salts, perfluoroalkylsilanes, etc. Fluoro compounds; phospholipids such as lecithin and hydrogenated phospholipids; sphingolipids such as ceramide NG (2) and the like can be mentioned, and one or more selected from these can be used.
　表面処理剤は１種又は２種以上組み合わせて用いてもよく、化粧料の剤型に応じて、適宜調整することができる。また、その処理方法は、溶媒に処理剤と粉体をスラリー状に混合し、プラネタリーミキサー等で混練後、溶媒を除去して表面処理する湿式処理や、溶媒に処理剤を溶解し、スーパーミキサー等の混合機内で、攪拌して処理する乾式処理が主に用いることができ、効率良く表面処理され、分散性が向上する点で好ましい。表面処理量は、特に限定しない。 The surface treatment agent may be used alone or in combination of two or more, and can be appropriately adjusted according to the dosage form of the cosmetic. In addition, the treatment method is a wet treatment in which the treatment agent and powder are mixed in a slurry in a solvent, kneaded with a planetary mixer or the like, and then the solvent is removed for surface treatment, or the treatment agent is dissolved in the solvent and super A dry treatment, which is performed by stirring in a mixer such as a mixer, can be mainly used, and is preferable in that the surface treatment is efficiently performed and the dispersibility is improved. The amount of surface treatment is not particularly limited.
＜成分（Ｄ）＞
　本発明は、さらに成分（Ｄ）として、シリコーンパウダー、ウレタンパウダー、ナイロンパウダー、セルロースパウダー、デンプンパウダー、ポリメタクリル酸メチルパウダー及びシリカから選ばれる１種又は２種以上の粉体を本発明の化粧料に使用又は含有することが好ましい。これらの粉体は、多孔質、無孔質等の粒子構造、球状、板状、表面に微小の凹凸がある等の異形状等特に限定されないが、化粧料において粉体として用いることができる粉体である。毛穴カバー効果の点で光散乱性の高い球状粒子が特に好ましい。シリコーンパウダーは、特に限定されないが、架橋型シリコーン・網状型シリコーンブロック共重合体が挙げられ、具体的には、ＩＮＣＩ名で、（ジメチコン／ビニルジメチコン）クロスポリマーの粉体、（ビニルジメチコン／メチコンシルセスキオキサン）クロスポリマーの粉体、（ジフェニルジメチコン／ビニルジフェニルジメチコン／シルセスキオキサン）クロスポリマーの粉体等を挙げることができ、当該粉体はゲル形態にできるような成分（Ｂ）には含まれない。 <Component (D)>
The present invention further comprises one or more powders selected from silicone powder, urethane powder, nylon powder, cellulose powder, starch powder, polymethyl methacrylate powder and silica as the component (D) of the present invention. It is preferable to use or contain it in the powder. These powders are not particularly limited in terms of particle structure such as porous and non-porous, irregular shapes such as spherical, plate-like, and minute irregularities on the surface, but can be used as powder in cosmetics. The body. Spherical particles having high light scattering properties are particularly preferable in terms of the pore covering effect. The silicone powder is not particularly limited, and examples thereof include crosslinked silicone and reticulated silicone block copolymers. Specifically, under the INCI name, (dimethicone / vinyldimethicone) cross-polymer powder, (vinyldimethicone / methicone). Examples thereof include a powder of (silsesquioxane) cross-polymer, a powder of (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) cross-polymer, and the powder is a component (B) that can be formed into a gel form. Is not included in.
　なお、成分（Ｄ）のうち、特に、非合成ポリマーがより好ましい。合成ポリマーとは、石油系のモノマー及び／又はオリゴマーを出発原料として、これらから有機合成にて高分子化又は重合化したポリマーを意味する。非合成ポリマーは、天然由来及び／又は植物由来のポリマーを出発原料とするポリマーを含むことができる。また、成分（Ｄ）のうち、例えば、天然由来又は植物由来の有機粉末（好適には多糖類粉末）であるセルロースパウダー、デンプンパウダー、及び無機粉体であるシリカから選ばれる１種又は２種以上が、毛穴カバー効果の点でより好ましい。セルロースパウダーのうち、結晶セルロースパウダーが好ましい。デンプンパウダーのうち、架橋若しくは非架橋の、トウモロコシ由来のデンプンパウダー、小麦由来のデンプンパウダー、米由来のデンプンパウダー、及びこれらの骨格を有する化学修飾物のパウダー（例えば、ヒドロキシプロピルデンプン、オクテニルコハク酸トウモロコシデンプン塩等）；金属酸化物被覆デンプン（例えば酸化チタン被覆コーンスターチ等）パウダー等から選択される１種又は２種以上が好ましい。なお、前記成分（Ａ）及び／又は成分（Ｃ）の表面処理剤として記載した表面処理剤で処理された、疎水化された成分（Ｄ）がより好ましい。 Of the components (D), a non-synthetic polymer is particularly preferable. The synthetic polymer means a polymer obtained by organically synthesizing petroleum-based monomers and / or oligomers as a starting material. Non-synthetic polymers can include polymers originating from naturally derived and / or plant derived polymers. Further, among the components (D), for example, one or two selected from cellulose powder, starch powder, which is an organic powder (preferably polysaccharide powder) derived from nature or plants, and silica, which is an inorganic powder. The above is more preferable in terms of the pore covering effect. Of the cellulose powders, crystalline cellulose powder is preferable. Among starch powders, cross-linked or non-cross-linked starch powder derived from corn, starch powder derived from wheat, starch powder derived from rice, and powders of chemical modifications having these skeletons (for example, hydroxypropyl starch, octenyl succinate corn). Starch salt, etc.); One or more selected from metal oxide-coated starch (for example, titanium oxide-coated cornstarch, etc.) powder and the like are preferable. The hydrophobized component (D) treated with the surface treatment agent described as the surface treatment agent for the component (A) and / or the component (C) is more preferable.
　本発明に用いる成分（Ｄ）の平均粒子径は、特に限定されないが、好適な下限として、０．５μｍ以上が好ましく、４．０μｍ以上がより好ましく、また、好適な上限として、４０μｍ以下が好ましく、３０μｍ以下がより好ましい。この範囲であれば、より皮溝を目立たせなくする効果が期待できる。特に、油性化粧料の場合は、下限として１５μｍ以上がさらに好ましく、粉末固形化粧料の場合は、上限として１５μｍ以下がさらに好ましい。 The average particle size of the component (D) used in the present invention is not particularly limited, but is preferably 0.5 μm or more as a suitable lower limit, more preferably 4.0 μm or more, and preferably 40 μm or less as a suitable upper limit. , 30 μm or less is more preferable. Within this range, the effect of making the skin groove less noticeable can be expected. In particular, in the case of oil-based cosmetics, the lower limit is more preferably 15 μm or more, and in the case of powder solid cosmetics, the upper limit is more preferably 15 μm or less.
　本発明の化粧料中における成分（Ｄ）の含有量は、特に制限はないが、化粧料総量（１００質量％）中、好適な下限として、５％以上が好ましく、８％以上がより好ましく、１０％以上がさらに好ましく、また、好適な上限として、５０％以下が好ましく、４０％以下がより好ましく、さらに３０％以下がより好ましく、より好ましくは２０％以下である。成分（Ｄ）をこの範囲で含有すると、滑らかな使用感を向上させ、より皮溝を目立たせなくする効果に優れるため好ましい。成分（Ｂ）の効果を補足することができると同時に、化粧料の仕上がり全体の質感を調整することができる。 The content of the component (D) in the cosmetic of the present invention is not particularly limited, but is preferably 5% or more, more preferably 8% or more as a suitable lower limit in the total amount of cosmetics (100% by mass). 10% or more is more preferable, and as a suitable upper limit, 50% or less is preferable, 40% or less is more preferable, 30% or less is more preferable, and 20% or less is more preferable. It is preferable that the component (D) is contained in this range because it improves a smooth feeling of use and is excellent in the effect of making the skin groove less noticeable. At the same time that the effect of the component (B) can be supplemented, the texture of the entire finished cosmetic can be adjusted.
＜成分（Ａ）～（Ｄ）以外の成分＞
　本発明の化粧料には、上記成分以外に、水溶性高分子、紫外線吸収剤、パラオキシ安息香酸誘導体、フェノキシエタノール等の防腐剤、ビタミン類、美容成分、保湿剤、界面活性剤、架橋型乳化性シリコーンエラストマー、上記成分（Ａ）、（Ｃ）及び（Ｄ）以外の粉体等の任意成分を本発明の効果を損なわない範囲で適宜含有することができる。本発明の化粧料は、上述した成分（Ａ）及び（Ｂ）等を用いて、配合、混合、乳化等の公知の製造方法を適宜採用することで、目的とする化粧料の種類や形態を調製することができる。 <Ingredients other than ingredients (A) to (D)>
In addition to the above components, the cosmetic of the present invention includes water-soluble polymers, ultraviolet absorbers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, beauty components, moisturizers, surfactants, and crosslinked emulsifying properties. Any component such as a silicone elastomer and powders other than the above components (A), (C) and (D) can be appropriately contained as long as the effects of the present invention are not impaired. The cosmetic of the present invention uses the above-mentioned components (A), (B) and the like, and appropriately adopts known production methods such as blending, mixing and emulsification to obtain the type and form of the target cosmetic. Can be prepared.
＜化粧料＞
　本発明の化粧料は、アイカラー、アイブロウ、ファンデーション、頬紅、白粉、下地等のメイクアップ化粧料、乳液、クリーム、美容液、ボディパウダー等のスキンケア化粧料、日焼け止め化粧料等への応用が可能であり、これらから１種又は２種以上を選択することができる。また、本発明の化粧料は、組成物であってもよく、また皮膚外用剤としても使用してもよい。 <Cosmetics>
The cosmetic of the present invention can be applied to make-up cosmetics such as eye color, eyebrow, foundation, blusher, white powder, and foundation, skin care cosmetics such as milky lotion, cream, beauty essence, and body powder, and sunscreen cosmetics. It is possible, and one or more of them can be selected. Further, the cosmetic of the present invention may be a composition or may be used as a skin external preparation.
　また、本発明の化粧料の形態は、特に限定されないが、粉末状、液状、ペースト状、乳液状、クリーム状、ゲル状、固形状等の何れでもよく、これらから１種又は２種以上を選択することができる。特に自然なコンシーリング効果を発揮する上で、乳化化粧料、油性化粧料や粉末化粧料、粉末固形化粧料が好ましい。 The form of the cosmetic of the present invention is not particularly limited, but may be powdery, liquid, paste, milky, creamy, gelled, solid or the like, and one or more of these may be used. You can choose. In particular, emulsified cosmetics, oily cosmetics, powdered cosmetics, and powdered solid cosmetics are preferable in order to exert a natural concealing effect.
　また、本発明の別の側面として、本発明の化粧料は、肌表面の凹凸（毛穴、しわ等）をカバーするため及び皮丘の色調トラブル（しみ、そばかす、色むら等）を自然にカバーするために使用するための化粧料であってもよい。これにより、例えば、肌の凹凸及び色調違い等を目立たなくするとともに、白浮きや厚ぼったさによる透明感のない等のような肌色の不自然さ又は肌色が不自然にみえることを少なくすることができる。また、本発明は、上述した、肌表面の凹凸をカバーするための及び／又は皮丘の色調トラブルを自然にカバーするための等の目的に使用するための、成分（Ａ）及び成分（Ｂ）若しくはこれらを少なくとも含む組成物、又はこれらの使用を提供することができる。また、本発明は、上述した肌表面凹凸のカバー作用及び／又は皮丘の色調トラブルの自然なカバー作用等を有する各種剤又は各種組成物等の製造のために、成分（Ａ）及び成分（Ｂ）を少なくとも使用することができる。また、本発明の化粧料、少なくとも成分（Ａ）及び成分（Ｂ）の併用若しくはこれらの混合物を、肌に使用又は塗布する、方法（例えば、メイクアップ方法、肌表面の凹凸をカバーするための方法及び／又は皮丘の色調トラブルを自然にカバーするための方法等）に使用することができる。また、本発明の化粧料は、非医療目的の使用であってもよく、「非医療目的」とは、医療行為（例えば、医師が行う行為）、すなわち、医療による人体への処置行為を含まない概念である。非医療目的として、例えば、メイクアップ、美容等が挙げられる。 Further, as another aspect of the present invention, the cosmetic of the present invention naturally covers unevenness (pores, wrinkles, etc.) on the skin surface and color troubles (stains, freckles, color unevenness, etc.) on the skin hills. It may be a cosmetic for use. As a result, for example, the unevenness of the skin and the difference in color tone are made inconspicuous, and the unnaturalness of the skin color or the appearance of the skin color such as lack of transparency due to whitening or thickening is reduced. be able to. Further, the present invention is the component (A) and the component (B) for use for the above-mentioned purposes such as to cover the unevenness of the skin surface and / or to naturally cover the color tone trouble of the skin hill. ) Or a composition containing at least these, or use thereof. Further, the present invention provides the components (A) and components (A) and components (A) for producing various agents or compositions having the above-mentioned covering action for skin surface irregularities and / or natural covering action for skin hill color tone troubles. B) can be used at least. In addition, a method of using or applying the cosmetic of the present invention, at least a combination of the ingredients (A) and (B) or a mixture thereof, to the skin (for example, a make-up method, for covering unevenness on the skin surface). It can be used for methods and / or methods for naturally covering skin hill color problems, etc.). Further, the cosmetic of the present invention may be used for non-medical purposes, and the "non-medical purpose" includes a medical act (for example, an act performed by a doctor), that is, an act of treating the human body by medical treatment. There is no concept. Non-medical purposes include, for example, make-up, beauty and the like.
　以下に実施例等を挙げて、本発明を更に説明する。なお、これらは本発明を何ら限定するものではない。 The present invention will be further described below with reference to examples and the like. It should be noted that these do not limit the present invention in any way.
＜ブルーライトカット効果評価＞
　成分（Ａ）のブルーライトカット効果評価を以下のように行った（図１及び図２参照）。
　成分（Ａ）と比較品の各波長の透過率（１００％－透過率＝遮蔽率）を測定したものを図１に示す。なお、透過率から、ブルーライトカット機能（３８０～５００ｎｍの遮蔽率）を算出し、図２に示す。
　サンプルは、成分（Ａ）合成金雲母鉄（平均粒子径５～１１μｍ、ＰＤＭ－ＦＥ（トピー工業社製））と、酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）と、合成金雲母　（平均粒子径５μｍ）（ＰＤＭ-５L：トピー工業社製））である。成分（Ａ）のサンプルをＩＰＡ（イソプロピルアルコール）に２０％濃度になるように懸濁し、デスパ分散した。１２．５μｍのドクターブレードで石英板に塗布膜を引き、乾燥後、積分球ＵＶ－２６００（ＵＶ－ＶＩＳ　ＳＰＥＣＴＲＯＰＨＯＴＯＭＥＴＥＲ）（島津製作所社製）を用いてで透過率を測定した。 <Blue light cut effect evaluation>
The blue light cut effect of the component (A) was evaluated as follows (see FIGS. 1 and 2).
FIG. 1 shows a measurement of the transmittance (100% -transmittance = shielding rate) of each wavelength of the component (A) and the comparative product. The blue light cut function (shielding rate of 380 to 500 nm) is calculated from the transmittance and is shown in FIG.
Samples are component (A) synthetic phlogopite iron (average particle diameter 5 to 11 μm, PDM-FE (manufactured by Topy Industries, Ltd.)) and titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm, titanium oxide coating amount). 11-14%, coated with tin oxide) and synthetic phlogopite (average particle size 5 μm) (PDM-5L: manufactured by Topy Industries, Ltd.). A sample of component (A) was suspended in IPA (isopropyl alcohol) to a concentration of 20% and dispersed in despa. A coating film was drawn on a quartz plate with a 12.5 μm doctor blade, dried, and then the transmittance was measured using an integrating sphere UV-2600 (UV-VIS SPECTROPHOTOMETER) (manufactured by Shimadzu Corporation).
　成分（Ａ）のブルーライトカット効果は、酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）が最も高く、合成金雲母鉄（平均粒子径５～１１μｍ）でも少し見られ、合成金雲母（平均粒子径５μｍ）に関しては、効果が見られなかった。 The blue light cut effect of the component (A) is highest in titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating), and synthetic phlogopite iron (average particles). A little was seen even with a diameter of 5 to 11 μm), and no effect was seen with synthetic phlogopite (average particle diameter of 5 μm).
＜可視光相対分光反射率試験＞
　成分（Ａ）酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）の可視光相対分光反射率と、日本人女性の標準色素肌の可視光相対分光反射率との比較を図３に示す。前記成分（Ａ）を変分光色彩計ＳＥ７７００（日本電色工業株式会社製）を用いて、入射角－４５°、受光角０°の測定において、セルに成分（Ａ）を２０回タッピングさせて測定した際に、７２０ｎｍの反射を１とした場合の相対分光反射率曲線を、素肌の７２０ｎｍの反射を１とした場合の相対分光反射率曲線と比較した。 <Visible light relative spectral reflectance test>
Component (A) Visible light relative spectral reflectance of synthetic gold mica iron coated with titanium oxide (average particle size 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating) and visibility of standard pigmented skin of Japanese women A comparison with the optical relative spectral reflectance is shown in FIG. The component (A) is tapped on the cell 20 times in the measurement of the incident angle −45 ° and the light receiving angle 0 ° using the variable spectroscopic colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.). When measured, the relative spectral reflectance curve when the reflection at 720 nm was 1 was compared with the relative spectral reflectance curve when the reflection at 720 nm of the bare skin was 1.
　＜ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系測定試験＞
　また、分光色彩計ＳＥ７７００（日本電色工業株式会社製）を用いて、入射角－４５°、受光角０°の測定において、セルに成分（Ａ）を２０回タッピングさせて測定した際に、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系で規定される測色値Ｌ＊（明度）、Ｃ＊（彩度）、ｈ（色相）を求めた。成分（Ａ）のうち合成金雲母鉄の色調は、６３＜Ｌ＊＜８３、１２＜Ｃ＊＜３２、５０＜ｈ＜７６の範囲であった。成分（Ａ）のうち、酸化チタン被覆合成金雲母鉄の色調は、６３＜Ｌ＊＜７５、１８＜Ｃ＊＜２５、５０＜ｈ＜７０の範囲であり、酸化チタン被覆合成金雲母鉄の色調は、６８＜Ｌ＊＜７５、１８＜Ｃ＊＜２５、５５＜ｈ＜７０の範囲であった。 <CIE1976L * a * b * Color system measurement test>
Further, when the component (A) was tapped 20 times on the cell in the measurement of the incident angle −45 ° and the light receiving angle 0 ° using the spectral colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.), the measurement was performed. The colorimeters L * (brightness), C * (saturation), and h (hue) defined by the CIE1976L * a * b * color system were obtained. Of the component (A), the color tone of synthetic phlogopite iron was in the range of 63 <L * <83, 12 <C * <32, 50 <h <76. Of the component (A), the color tone of the titanium oxide-coated synthetic phlogopite iron is in the range of 63 <L * <75, 18 <C * <25, 50 <h <70, and that of the titanium oxide-coated synthetic phlogopite iron. The color tone was in the range of 68 <L * <75, 18 <C * <25, 55 <h <70.
　成分（Ａ）酸化チタン被覆合成金雲母鉄（平均粒子径５～１１μｍ、酸化チタン被覆量１１～１４％、酸化スズ被覆）の可視光反射強度は、素肌に近しい、自然な肌色である効果が見られた。 Component (A) Titanium oxide-coated synthetic phlogopite iron (average particle size 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating) has the effect of having a natural skin color close to that of bare skin. It was seen.
　表１～３：実施例１～２４及び比較例１～５：油性コンシーラー
　表４～６：実施例２５～４３及び比較例６～１０：パウダーファンデーション
　表１～３に示す油性コンシーラーと、表４～６に示すパウダーファンデーションを調製し、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がりについて下記の評価を実施し、下記判定基準により判定した。その結果も併せて表１～６に示す。 Tables 1 to 3: Examples 1 to 24 and Comparative Examples 1 to 5: Oil-based concealer Tables 4 to 6: Examples 25 to 43 and Comparative Examples 6 to 10: Powder foundation The oil-based concealers shown in Tables 1 to 3 and Table 4 The powder foundations shown in 6 to 6 were prepared, and the following evaluations were carried out for the natural covering effect of the skin hill, the pore covering effect, the long-lasting makeup, and the smooth spreading and spreading, and the judgment was made according to the following criteria. The results are also shown in Tables 1-6.
　なお、表中の実施例１～４３、比較例１～１０の組成物（１００質量％）中における成分（Ｂ）の含有量は、固形分換算にて、示す。
　また、表中で使用した金属酸化物被覆の合成金雲母鉄は、市販品の合成金雲母鉄を公知の被覆方法を採用することで得ることができ、表面処理の合成金雲母鉄又は金属酸化物被覆合成金雲母鉄は、公知の表面処理方法を採用することで得ることができる（上記＜成分（Ａ）＞等参照）。また、上記試験及び下記実施例にて使用した合成金雲母鉄、金属酸化物被覆及び／又は表面処理の合成金雲母鉄中における酸化鉄換算含有量は１０～１４％であり、アスペクト比は３０～８０である。また、上記試験及び下記実施例にて使用したジメチコン処理酸化チタン被覆合成金雲母鉄（粉体）中における表面処理化合物の含有量は０．５～３％である。 The content of the component (B) in the compositions (100% by mass) of Examples 1 to 43 and Comparative Examples 1 to 10 in the table is shown in terms of solid content.
Further, the synthetic phlogopite iron coated with the metal oxide used in the table can be obtained by adopting a known coating method for commercially available synthetic phlogopite iron, and the synthetic phlogopite iron or metal oxidation of the surface treatment can be obtained. The material-coated synthetic phlogopite iron can be obtained by adopting a known surface treatment method (see <Component (A)> and the like above). Further, the iron oxide equivalent content in the synthetic phlogopite iron, the metal oxide coating and / or the surface-treated synthetic phlogopite iron used in the above test and the following examples is 10 to 14%, and the aspect ratio is 30. ~ 80. The content of the surface-treated compound in the dimethicone-treated titanium oxide-coated synthetic phlogopite (powder) used in the above test and the following examples is 0.5 to 3%.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
＊１：ＫＳＧ－１６（信越化学工業社製）（固形分：（ジメチコン／ビニルジメチコン）クロスポリマー２５％、溶媒ジメチコン）
＊７：ＰＤＭ－ＦＥ（トピー工業社製　平均粒子径５～１１μｍ）（酸化鉄換算：１０～１４％） * 1: KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Solid content: (dimethicone / vinyldimethicone) crosspolymer 25%, solvent dimethicone)
* 7: PDM-FE (Average particle size 5 to 11 μm manufactured by Topy Industries, Ltd.) (iron oxide equivalent: 10 to 14%)
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
＊６：ＭＰ－１００（テイカ社製　平均粒子径１．０μｍ） * 6: MP-100 (Made by TAYCA, average particle size 1.0 μm)
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
＊２：ＤＯＷＳＩＬ　９０４０　ＳＩＬＩＣＯＮＥ　ＥＬＡＳＴＯＭＥＲ　ＢＬＥＮＤ（Ｄｏｗ Ｃｏｒｎｉｎｇ社製）（固形分：ジメチコンクロスポリマー１２．６％、溶媒シクロメチコン８７．４％）
＊３：ＫＳＧ－４３（信越化学工業社製）（固形分：（ビニルジメチコン／ラウリルジメチコン）クロスポリマー３０％、溶媒トリエチルヘキサノイン７０％）
＊４：ＫＳＧ－７１０（信越化学工業社製）（固形分：ジメチコン／ポリグリセリン－３）クロスポリマー　２４．１％、溶媒ジメチコン他添加剤）
＊５：ＫＳＧ－２１０（信越化学工業社製）（固形分：（ジメチコン／（ＰＥＧ－１０／１５））クロスポリマー２５％、溶媒ジメチコン他添加剤）
＊８：ＫＳＰ－１０２（信越化学工業社製　平均粒子径３０μｍ）
＊９：ＰＬＡＳＴＩＣ　ＰＯＷＤＥＲ　ＣＳ－４００（根上工業社製　平均粒子径１５ｍ） * 2: DOWNSIL 9040 SILICONE Elastomer BLEND (manufactured by Dow Corning) (solid content: 12.6% dimethicone crosspolymer, 87.4% solvent cyclomethicone)
* 3: KSG-43 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Solid content: (vinyl dimethicone / lauryl dimethicone) crosspolymer 30%, solvent triethylhexanoin 70%)
* 4: KSG-710 (manufactured by Shin-Etsu Chemical Co., Ltd.) (solid content: dimethicone / polyglycerin-3) crosspolymer 24.1%, solvent dimethicone and other additives)
* 5: KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Solid content: (dimethicone / (PEG-10 / 15)) 25% crosspolymer, solvent dimethicone and other additives)
* 8: KSP-102 (Shin-Etsu Chemical Co., Ltd. average particle diameter 30 μm)
* 9: PLASTIC POWDER CS-400 (Made by Negami Kogyo Co., Ltd., average particle diameter 15 m)
（製造方法）表１～３
Ａ．成分（１）～（１１）を均一に混合溶解する。
Ｂ．Ａに成分（１２）～（３７）を加え、均一に混合分散する。
Ｃ．Ｂを容器に充填し、冷却して油性コンシーラー（固形）を得た。 (Manufacturing method) Tables 1 to 3
A. The components (1) to (11) are uniformly mixed and dissolved.
B. Ingredients (12) to (37) are added to A, and the mixture is uniformly mixed and dispersed.
C. B was filled in a container and cooled to obtain an oil-based concealer (solid).
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
＊１３：ＢＯＲＯＮ　ＮＩＴＲＡＤＥ　ＰＯＷＤＥＲ　ＣＣＳ－１０２（モメンティブ社製） * 13: BORON NITRADE POWDER CCS-102 (manufactured by Momentive)
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006
＊１０：マツモトマイクロスフェアーＭ－１０１（松本油脂製薬株式会社製　平均粒子径１０μｍ）
＊１１：ＫＳＰ－１０１（信越化学工業社製　平均粒子径１２μｍ）
＊１２：ＰＬＡＳＴＩＣ　ＰＯＷＤＥＲ　Ｄ－４００（根上工業社製　平均粒子径１５μｍ） * 10: Matsumoto Microsphere M-101 (Matsumoto Yushi Pharmaceutical Co., Ltd., average particle diameter 10 μm)
* 11: KSP-101 (Shin-Etsu Chemical Co., Ltd., average particle diameter 12 μm)
* 12: PLASTIC POWDER D-400 (Made by Negami Kogyo Co., Ltd., average particle diameter 15 μm)
（製造方法）表４～６
Ａ：成分（１）～（２１）を混合分散した。
Ｂ：Ａに分散した成分（２２）～（３１）を加え、パルベライザーにて粉砕した。
Ｃ：金皿容器に圧縮成型をしてパウダーファンデーションを得た。その際成分（３１）は、蒸発していた。 (Manufacturing method) Tables 4 to 6
A: The components (1) to (21) were mixed and dispersed.
B: The dispersed components (22) to (31) were added to A, and the mixture was pulverized with a palberizer.
C: A powder foundation was obtained by compression molding into a gold plate container. At that time, the component (31) was evaporated.
（評価方法）
下記評価項目について各々下記方法により評価を行った。
（評価項目）
イ．皮丘の自然なカバー効果
ロ．毛穴カバー効果
ハ．化粧持続性
ニ．滑らかな伸び広がり (Evaluation methods)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
I. Natural covering effect of skin hills b. Pore cover effect c. Makeup persistence d. Smooth stretch
　評価項目イ、ロ、ハ及びニについては、各試料について専門パネル２０名による使用テストを行い、パネル各人が下記絶対評価基準にて５段階に評価し評点を付け、各試料のパネル全員の評点合計から、その平均値を算出し、小数点以下第１位を四捨五入した値を示している。
イ．皮丘の自然なカバー効果に関しては、各試料を肌に塗布した際、皮丘に見られる、しみ、そばかす、色むらといった色調トラブルが自然にカバーできている化粧膜だったか、ロ．毛穴カバー効果に関しては、各試料を肌に塗布した際、毛穴が隠れた仕上がりであったかどうか、ハ．化粧持続性に関してはパネルに通常の生活を６時間してもらった後に、涙や汗、肌の動きにより化粧膜がくずれていないか、ニ．滑らかな伸び広がりに関しては、各試料を肌に塗布した際に、ムラにならず、試料が滑らかに伸び広げられたかを評価した。
＜絶対評価基準＞
（評点）：（評価）
　５　：非常に効果が高い
　４　：やや効果が高い
　３　：普通（効果はあるが期待する効果とまではいえない）
　２　：やや効果が低い
　１　：効果が低い For evaluation items (a), (b), (c), and (d), each sample was subjected to a usage test by 20 specialized panels, and each panel evaluated and scored on a 5-point scale according to the following absolute evaluation criteria, and all the panels of each sample were evaluated. The average value is calculated from the total score, and the value rounded to the first decimal place is shown.
I. Regarding the natural covering effect of the skin hills, was it a cosmetic film that naturally covered the color problems such as spots, freckles, and color unevenness seen on the skin hills when each sample was applied to the skin? Regarding the pore covering effect, whether or not the pores were hidden when each sample was applied to the skin, c. Regarding the makeup persistence, after having the panel live a normal life for 6 hours, check if the makeup film has collapsed due to tears, sweat, or skin movements. Regarding the smooth spread and spread, it was evaluated whether the sample was spread and spread smoothly without unevenness when each sample was applied to the skin.
<Absolute evaluation criteria>
(Score): (Evaluation)
5: Very high effect 4: Somewhat high effect 3: Normal (Effect but not expected effect)
2: Slightly low effect 1: Low effect
　表１～３の結果から明らかなように、本発明の実施例１～２４の油性コンシーラーは、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れた油性コンシーラーであった。成分（Ａ）の代わりに酸化チタン１２％、酸化鉄１２％被覆合成金雲母の着色パール剤を用いた比較例１は、技巧的な仕上がりとなり皮丘の自然のカバー効果が乏しく、伸び広げる際にもムラになってしまい満足することができなかった。成分（Ａ）の代わりに合成金雲母を用いた比較例２は、皮丘の自然のカバー効果が満足するものではなかった。また伸び広がりについても乏しいものであった。成分（Ｂ）が０．１％未満である比較例３は、シリコーンエラストマーの光拡散効果が不十分であるため、特に毛穴カバー効果の点で満足のいくものではなかった。成分（Ｂ）が５％を超える比較例４は、自然なカバー効果を妨げられ、化粧持続性に乏しい品質であった。成分（Ｂ）の代わりに架橋型乳化性シリコーンエラストマーを用いた比較例５は、化粧膜にべたつきが生じ、伸び広がりが悪くなってしまう品質であった。 As is clear from the results in Tables 1 to 3, the oil-based concealers of Examples 1 to 24 of the present invention have a natural covering effect on skin hills, a pore covering effect, long-lasting makeup, smooth spreading and spreading, in all items. It was an excellent oil-based concealer. Comparative Example 1 in which a colored pearl agent coated with 12% titanium oxide and 12% iron oxide was used instead of the component (A) had a technical finish and had a poor natural covering effect on the skin hills, and when it was expanded. I couldn't be satisfied because it became uneven. In Comparative Example 2 in which synthetic phlogopite was used instead of the component (A), the natural covering effect of the skin hill was not satisfactory. In addition, the spread was poor. Comparative Example 3 in which the component (B) was less than 0.1% was not satisfactory in terms of the pore covering effect because the light diffusing effect of the silicone elastomer was insufficient. In Comparative Example 4 in which the component (B) exceeded 5%, the natural covering effect was hindered and the quality was poor in makeup durability. In Comparative Example 5 in which the crosslinked emulsifying silicone elastomer was used instead of the component (B), the quality was such that the decorative film became sticky and the spread and spread became poor.
　表４～６の結果から明らかなように、本発明の実施例２５～４３のパウダーファンデーションは、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたパウダーファンデーションであった。成分（Ａ）の代わりに酸化チタン１２％、酸化鉄１２％被覆合成金雲母の着色パール剤を用いた比較例６は、技巧的な仕上がりとなり、全顔使用すると非常に不自然な仕上がりとあるため、皮丘の自然なカバー効果が著しく乏しく、伸び広げる際にも、ムラが目立ってしまうため、満足することができなかった。成分（Ａ）の代わりに合成金雲母を用いた比較例７は、色ムラの補正効果が下がることで、特に皮丘の自然のカバー効果が満足するものではなかった。成分（Ｂ）が０．１％未満である比較例８は、シリコーンエラストマーの光拡散効果が不十分であるため、特に毛穴カバー効果の点で満足のいくものではない。成分（Ｂ）が５％を超える比較例９は、粉体が濡れ過ぎてしまい、滑らかな伸び広がりが満足のいく品質ではなかった。成分（Ｂ）の代わりに架橋型乳化性シリコーンエラストマーを用いた比較例１０は、化粧膜にべたつきが生じ、伸び広がりが悪い品質であった。 As is clear from the results of Tables 4 to 6, the powder foundations of Examples 25 to 43 of the present invention have a natural covering effect of skin hills, a pore covering effect, a long-lasting makeup, a smooth spreading and spreading, in all items. It was an excellent powder foundation. Comparative Example 6 in which a colored pearl agent coated with 12% titanium oxide and 12% iron oxide was used instead of the component (A) had a technical finish, and the finish was very unnatural when used on the whole face. Therefore, the natural covering effect of the skin hills was extremely poor, and even when it was stretched, unevenness became conspicuous, and I was not satisfied. In Comparative Example 7 in which synthetic phlogopite was used instead of the component (A), the effect of correcting color unevenness was lowered, and the natural covering effect of the skin hill was not particularly satisfied. Comparative Example 8 in which the component (B) is less than 0.1% is not particularly satisfactory in terms of the pore covering effect because the light diffusing effect of the silicone elastomer is insufficient. In Comparative Example 9 in which the component (B) exceeded 5%, the powder was too wet, and the smooth spreading and spreading was not a satisfactory quality. In Comparative Example 10 in which the crosslinked emulsifying silicone elastomer was used instead of the component (B), the decorative film was sticky and the quality was poorly spread.
　すなわち、本発明の化粧料では、塗布時は滑らかな伸び広がりを有しており、塗布後は、皮丘の色調トラブル（例えば、色ムラ、シミ、クマ等）を自然にカバーする効果を有し、凹凸を強調させるような違和感のあるぎらつき感がなく肌表面の凹凸（例えば、毛穴、シワ等）のカバー効果に優れ、さらに化粧持続効果の高い化粧料を提供することができる。 That is, the cosmetic of the present invention has a smooth spread and spread when applied, and has the effect of naturally covering color troubles (for example, color unevenness, stains, bears, etc.) of the skin hills after application. However, it is possible to provide a cosmetic having an excellent effect of covering unevenness (for example, pores, wrinkles, etc.) on the skin surface without a feeling of discomfort and glare that emphasizes unevenness, and further has a high makeup-sustaining effect.
実施例４４：油性頬紅
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．パルミチン酸デキストリン　＊１４　　　　　　　　　　　　１０
２．マイクロクリスタリンワックス（融点７７～８２℃）　　　　　４
３．トリメチルシロキシケイ酸　＊１５　　　　　　　　　　　　　６
４．トリイソステアリン酸ジグリセリル　　　　　　　　　　　　３０
５．２－エチルヘキサン酸セチル　　　　　　　　　　　　　　　２０
６．ジメチルポリシロキサン（２５℃、動粘度６ＣＳ）　　　　　　２
７．（ジメチコン／ビニルジメチコン）クロスポリマー　＊１　　　２
８．セスキオレイン酸ソルビタン　　　　　　　　　　　　　　　　２
９．赤色２０２号　　　　　　　　　　　　　　　　　　　　　　　０．５
１０．黄色４号　　　　　　　　　　　　　　　　　　　　　　　　０．５
１１．黒色酸化鉄　　　　　　　　　　　　　　　　　　　　　　　０．１
１２．タルク　　　　　　　　　　　　　　　　　　　　　　　　　残量
１３．疎水化処理無水ケイ酸　＊１６　　　　　　　　　　　　　　２
１４．球状セルロース末　＊１７　　　　　　　　　　　　　　　　３
１５．ポリエチレン末　＊１８　　　　　　　　　　　　　　　　　０．２
１６．合成金雲母鉄　＊７　　　　　　　　　　　　　　　　　　　２
１７．ミツロウ２％処理酸化チタン（平均粒子径０．２７μｍ）　　３
＊１４：レオパールＴＬ２（千葉製粉社製）
＊１５：ＫＦ－９０２１（固形分５０％デカメチルシクロペンタシロキサン溶液）（信越化学工業社製）
＊１６：ＡＥＲＯＳＩＬ　Ｒ－９７６Ｓ（日本アエロジル社製）
＊１７：ＣＥＬＬＵＬＯＢＥＡＤＳ Ｄ－３０（大東化成工業社製）
＊１８：ミペロンＰＭ－２００（三井化学社製）
なお、赤色２０２号（一般名: リソールルビンBCA Lithol Rubine BCA.）、赤色２２６号（一般名: ヘリンドンピンクCN Helindone Pink CN）、黄色２０２号（一般名: ウラニンUranine）、黄色４号（一般名：タートラジン Tartrazine）である。 Example 44: Oily blusher (ingredient) (%)
1. 1. Dextrin palmitate * 14 10
2. 2. Microcrystalline wax (melting point 77-82 ° C) 4
3. 3. Trimethylsiloxysilicic acid * 15 6
4. Diglyceryl triisostearate 30
5.2 Cetyl ethylcaproate 20
6. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 2
7. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 2
8. Sorbitan sesquioleate 2
9. Red No. 202 0.5
10. Yellow No. 4 0.5
11. Black iron oxide 0.1
12. Talc remaining amount 13. Hydrophobization treatment Silicic acid anhydride * 16 2
14. Spherical cellulose powder * 17 3
15. Polyethylene powder * 18 0.2
16. Synthetic phlogopite iron * 7 2
17. Beeswax 2% treated titanium oxide (average particle size 0.27 μm) 3
* 14: Leopard TL2 (manufactured by Chiba Flour Milling Co., Ltd.)
* 15: KF-9021 (50% solid content decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 16: AEROSIL R-976S (manufactured by Aerosil Japan)
* 17: CELLOLOBEADS D-30 (manufactured by Daito Kasei Kogyo Co., Ltd.)
* 18: Miperon PM-200 (manufactured by Mitsui Chemicals, Inc.)
In addition, Red No. 202 (generic name: Lithol Rubine BCA.), Red No. 226 (generic name: Herindone Pink CN), Yellow No. 202 (generic name: Uranine Uranine), Yellow No. 4 (generic name). : Tartrazine).
（製造方法）
Ａ．成分（１）～（８）を加熱し、均一溶解する。
Ｂ．Ａに成分（９）～（１７）を加え、均一に分散する。
Ｃ．Ｂを金皿に流し込み、冷却固化して油性頬紅得た。 (Production method)
A. Ingredients (1) to (8) are heated and uniformly dissolved.
B. Ingredients (9) to (17) are added to A and uniformly dispersed.
C. B was poured into a gold plate and cooled and solidified to obtain an oily blusher.
　本実施例４４の油性頬紅を、ブラシを用いて前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れた油性頬紅であった。 The oily blush of Example 44 was evaluated and judged using a brush according to the evaluation method of the above Example. As a result, it was an excellent oily blusher in all items, such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading.
実施例４５：粉末固形頬紅
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．酸化チタン被覆合成金雲母鉄
　　（平均粒子径　５～１１μｍ、酸化チタン被覆量　１２％）３０
２．シリコーン処理マイカ　＊１９　　　　　　　　　　　　　残量
３．合成金雲母＊２０　　　　　　　　　　　　　　　　　　　１０
４．トリエトキシカプリリルシラン処理赤酸化鉄　　　　　　　　０．２
５．赤色２２６号　　　　　　　　　　　　　　　　　　　　　　０．５
６．タルク（平均粒子径　１０μｍ）　　　　　　　　　　　　　５
７．ジメチコン処理酸化亜鉛（平均粒子径３．０μｍ、六角板状）２
８．球状セルロース＊２１　　　　　　　　　　　　　　　　　　２
９．球状シリカ＊２２　　　　　　　　　　　　　　　　　　　　１
１０．クロルフェネシン　　　　　　　　　　　　　　　　　　　０．２
１１．トリイソステアリン酸ジグリセリル　　　　　　　　　　　１
１２．リンゴ酸ジイソステアリル　　　　　　　　　　　　　　　１
１３．重質流動イソパラフィン　　　　　　　　　　　　　　　　０．５
１４．スクワラン　　　　　　　　　　　　　　　　　　　　　　１
１５．ジメチルポリシロキサン（２５℃、動粘度６ＣＳ）　　　　７
１６．（ジメチコン／ビニルジメチコン）クロスポリマー＊２３　　１
１７．ローズマリー葉エキス　　　　　　　　　　　　　　　　　０．１
１８．グリセリン　　　　　　　　　　　　　　　　　　　　　　０．５
１９．アボカド油　　　　　　　　　　　　　　　　　　　　　　０．１
２０．ミネラルオイル　　　　　　　　　　　　　　　　　　　　０．２
２１．トコフェロール　　　　　　　　　　　　　　　　　　　　０．０１
 
＊１９：Ｙ－３０００（ヤマグチマイカ社製　平均粒子径　２３μｍ　アスペクト比７０）２％ジメチコン処理
＊２０：　ミクロマイカ　ＭＫ－２００Ｋ（片倉コープアグリ社製　平均粒子径７μｍ、アスペクト比６０）　
＊２１：ＣＥＬＬＵＬＯＢＥＡＤＳ　Ｄ－５　（大東化成工業社製　平均粒子径　５μｍ）
＊２２：サンスフェアＮＰ－３０　（ＡＧＣエスアイテック社製　　平均粒子径　４μｍ）
＊２３：ＫＳＧ－１５（信越化学工業社製） Example 45: Powdered solid blusher (ingredient) (%)
1. 1. Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm, titanium oxide coating amount 12%) 30
2. 2. Silicone treated mica * 19 Remaining amount 3. Synthetic phlogopite * 20 10
4. Triethoxycaprylylsilane treated red iron oxide 0.2
5. Red No. 226 0.5
6. Talc (average particle diameter 10 μm) 5
7. Dimethicone-treated zinc oxide (average particle size 3.0 μm, hexagonal plate) 2
8. Spherical cellulose * 21 2
9. Spherical silica * 22 1
10. Chlorphenesin 0.2
11. Diglyceryl triisostearate 1
12. Diisostearyl malate 1
13. Heavy liquid isoparaffin 0.5
14. Squalene 1
15. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 7
16. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 23 1
17. Rosemary leaf extract 0.1
18. Glycerin 0.5
19. Avocado oil 0.1
20. Mineral oil 0.2
21. Tocopherol 0.01

* 19: Y-3000 (Yamaguchi Mica average particle diameter 23 μm, aspect ratio 70) 2% dimethicone treatment * 20: Micromica MK-200K (Katakura Corp. Agri average particle diameter 7 μm, aspect ratio 60)
* 21: CELLOLOBEADS D-5 (Average particle diameter 5 μm manufactured by Daito Kasei Kogyo Co., Ltd.)
* 22: Sunsphere NP-30 (AGC SI Tech Co., Ltd., average particle diameter 4 μm)
* 23: KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)
（製造方法）
Ａ．成分（１）～（１０）を均一に混合する。
Ｂ．Ａに成分（１１）～（２１）を均一に混合したものを加えて、均一に分散し、粉砕後、化粧料基材を得た。
Ｃ．これを気密性樹脂容器に圧縮充填し、頬紅を得た。 (Production method)
A. The components (1) to (10) are uniformly mixed.
B. A uniformly mixed component (11) to (21) was added to A, uniformly dispersed, and pulverized to obtain a cosmetic base material.
C. This was compressed and filled in an airtight resin container to obtain a blusher.
　本実施例４５の粉末固形頬紅を、ブラシを用いて前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れた粉末固形頬紅であった。 The powdered solid blusher of Example 45 was evaluated and judged according to the evaluation method of the above Example using a brush. As a result, it was a powder solid blusher that was excellent in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例４６：白粉
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．酸化チタン被覆合成金雲母鉄
　　　（平均粒子径１～３μｍ、酸化チタン被覆量１２％）　　　１０
２．合成金雲母鉄＊７　　　　　　　　　　　　　　　　　　　　１５
３．シリコーン処理タルク＊２４　　　　　　　　　　　　　　　残量
４．雲母チタン＊２５　　　　　　　　　　　　　　　　　　　　１０
５．シリカ処理シリコーン処理微粒子酸化亜鉛＊２６　　　　　　　８
６．窒化ホウ素＊２７　　　　　　　　　　　　　　　　　　　　　５
７．球状ポリエチレン＊２８　　　　　　　　　　　　　　　　　　５
８．球状セルロースパウダー＊２９　　　　　　　　　　　　　　１０
９．炭酸カルシウム＊３０　　　　　　　　　　　　　　　　　　　１
１０．球状シリカ＊３１　　　　　　　　　　　　　　　　　　　　２
１１．ベンガラ　　　　　　　　　　　　　　　　　　　　　　　　１
１２．黄酸化鉄　　　　　　　　　　　　　　　　　　　　　　　　２
１３．黒酸化鉄　　　　　　　　　　　　　　　　　　　　　　　　０．３
１４．パラオキシ安息香酸メチル　　　　　　　　　　　　　　　　０．２
１５．パラメトキシケイ皮酸２－エチルヘキシル　　　　　　　　　２
１６．テトライソステアリン酸ペンタエリスリチル　　　　　　　　０．５
１７．ステアロイルオキシステアリン酸オクチルドデシル　　　　　０．５
１８．トリエチルヘキサノイン　　　　　　　　　　　　　　　　　３
１９．（ビニルジメチコン／ラウリルジメチコン）
　　クロスポリマー＊３　　　　　　　　　　　　　　　　　　　　０．５
２０．スクワラン　　　　　　　　　　　　　　　　　　　　　　　０．２
２１．ステアラニウムヘクライト＊３２　　　　　　　　　　　　　１
２２．セルロースナノファイバー２％水溶液＊３３　　　　　　　　０．２
２３．コメヌカスフィンゴ糖脂質　　　　　　　　　　　　　　　　０．１
２４．オランダカラシエキス　　　　　　　　　　　　　　　　　　０．１
２５．水添レシチン　　　　　　　　　　　　　　　　　　　　　　０．２
 
＊２４：ＪＡ－４６Ｒ（浅田製粉社製　平均粒子径　９μｍ　アスペクト比５０）
＊２５：ＴＩＭＩＲＯＮ　ＳＴＡＲＬＵＳＴＥＲ　ＭＰ－１１５（メルク社製、平均粒子径２０μｍ、アスペクト比３００）
＊２６：ＭＺ－５１０ＨＰＳＸ　（テイカ社製　平均粒子径　２５ｎｍ）
＊２７：ＳＨＰ－３　（水島合金鉄社製　平均粒子径　６μｍ　アスペクト比１０）
＊２８：ミペロン　ＰＭ－２００（三井化学社製　平均粒子径　１０μｍ）
＊２９：ＣＥＬＬＵＬＯＢＥＡＤＳ　Ｄ－３０（大東化成工業社製　平均粒子径　３０μｍ）
＊３０：ＰＣチョーク　（白石工業社製　平均粒子径　１μｍ）
＊３１：ＣＨＩＦＦＯＮＳＩＬ　Ｐ－３Ｒ（日揮触媒化成社製　平均粒子径　６μｍ）
＊３２：ＢＥＮＴＯＮＥ　２７Ｖ（エレメンティス社製）
＊３３：レオクリスタＣ－２ＳＰ（第一工業製薬社製） Example 46: White powder (ingredient) (%)
1. 1. Titanium oxide-coated synthetic phlogopite iron (average particle size 1 to 3 μm, titanium oxide coating amount 12%) 10
2. 2. Synthetic phlogopite iron * 7 15
3. 3. Silicone treated talc * 24 Remaining amount 4. Mica Titanium * 25 10
5. Silica treatment Silicone treatment Fine particles Zinc oxide * 268
6. Boron Nitride * 27 5
7. Spherical polyethylene * 28 5
8. Spherical cellulose powder * 29 10
9. Calcium carbonate * 30 1
10. Spherical silica * 31 2
11. Bengala 1
12. Yellow iron oxide 2
13. Black iron oxide 0.3
14. Methyl paraoxybenzoate 0.2
15. 2-ethylhexyl paramethoxycinnamate 2
16. Pentaerythrityl tetraisostearate 0.5
17. Stearoyl oxystearate octyldodecyl 0.5
18. Triethylhexanoin 3
19. (Vinyl Dimethicone / Lauryl Dimethicone)
Cross polymer * 3 0.5
20. Squalene 0.2
21. Stealanium Heckrite * 32 1
22. Cellulose nanofiber 2% aqueous solution * 33 0.2
23. Rice casphingo glycolipid 0.1
24. Watercress extract 0.1
25. Hydrogenated lecithin 0.2

* 24: JA-46R (Made by Asada Flour Milling Co., Ltd. Average particle diameter 9 μm Aspect ratio 50)
* 25: TIMIRON STARLUSTER MP-115 (Merck, average particle diameter 20 μm, aspect ratio 300)
* 26: MZ-510HPSX (average particle diameter 25 nm manufactured by TAYCA Corporation)
* 27: SHP-3 (Made by Mizushima Ferroalloy Co., Ltd. Average particle diameter 6 μm Aspect ratio 10)
* 28: Miperon PM-200 (Mitsui Chemicals, Inc., average particle size 10 μm)
* 29: CELLOLOBEADS D-30 (average particle diameter 30 μm manufactured by Daito Kasei Kogyo Co., Ltd.)
* 30: PC choke (average particle diameter 1 μm manufactured by Shiraishi Kogyo Co., Ltd.)
* 31: CHIFFONSIL P-3R (Average particle diameter 6 μm manufactured by JGC Catalysts and Chemicals Co., Ltd.)
* 32: BENTONE 27V (manufactured by Elementis)
* 33: Leo Crysta C-2SP (manufactured by Dai-ichi Kogyo Seiyaku Co., Ltd.)
（製造方法）
Ａ．成分（１）～（１４）を均一に混合する。
Ｂ．Ａに、成分（１５）～（２５）を均一に混合したものを加えて、均一に分散し、粉砕後、化粧料基材を得た。
Ｃ．前記化粧料基材１００部に表中記載の溶剤を７０部添加して混合し、スラリー状の混合物を得た。
Ｄ．前記混合物を丸型の金皿容器（直径７ｃｍ）に１０．０ｇ乗せ、プレス圧２．０ｋｇｆ／ｃｍ２、プレス時間４秒、紙６枚の条件で２回圧縮し、溶剤を一部除去した。その後、７０℃で１０時間乾燥させ、溶剤を除去し、白粉を得た。 (Production method)
A. The components (1) to (14) are uniformly mixed.
B. A uniformly mixed component (15) to (25) was added to A, uniformly dispersed, and pulverized to obtain a cosmetic base material.
C. 70 parts of the solvent shown in the table was added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture.
D. 10.0 g of the mixture was placed on a round gold plate container (diameter 7 cm) and compressed twice under the conditions of a press pressure of 2.0 kgf / cm2, a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. Then, it was dried at 70 degreeC for 10 hours, the solvent was removed, and white powder was obtained.
　本実施例４６の白粉を、パフを用いて前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れた白粉であった。 The white powder of Example 46 was evaluated and judged using a puff according to the evaluation method of the above Example. As a result, it was an excellent white powder in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例４７：アイブロウ
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．タルク　　　　　　　　　　　　　　　　　　　　　　　　　２０
２．マイカ　　　　　　　　　　　　　　　　　　　　　　　　　残量
３．黒酸化鉄　　　　　　　　　　　　　　　　　　　　　　　　１０
４．ベンガラ　　　　　　　　　　　　　　　　　　　　　　　　　４
５．水酸化Ａｌ処理酸化チタン（平均粒子径１．０μｍ）　　　　　６
６．酸化チタン被覆合成金雲母鉄
　　　（平均粒子径１５～２０μｍ、酸化チタン被覆量１２％）　１０
７．黒酸化鉄被覆雲母チタン　　　　　　　　　　　　　　　　　１５
８．酸化亜鉛（平均粒子径３．０μｍ、六角板状）　　　　　　　　２
９．ステアリン酸亜鉛＊３４　　　　　　　　　　　　　　　　　　１
１０．赤色２２６号　　　　　　　　　　　　　　　　　　　　　　０．１
１１．黄色４号　　　　　　　　　　　　　　　　　　　　　　　　０．１
１２．赤色２０２号　　　　　　　　　　　　　　　　　　　　　　０．１
１３．ジメチルポリシロキサン（２５℃、動粘度６ＣＳ）　　　　１０
１４．（ジメチコン／ビニルジメチコン）クロスポリマー　＊１　　３
１５．カルナバロウ　　　　　　　　　　　　　　　　　　　　　　０．５
１６．マイクロクリスタリンワックス　　　　　　　　　　　　　　０．５
１７．トリメチルシロキシケイ酸　　　　　　　　　　　　　　　　１
１８．パラフィン　　　　　　　　　　　　　　　　　　　　　　　０．３
１９．ミツロウ　　　　　　　　　　　　　　　　　　　　　　　　０．２
２０．イソステアリン酸デキストリン　　　　　　　　　　　　　　１
２１．ダマスクバラ花エキス　　　　　　　　　　　　　　　　　　０．２
２２．レモン果実エキス　　　　　　　　　　　　　　　　　　　　０．１
２３．エタノール　　　　　　　　　　　　　　　　　　　　　　　０．１
２４．精製水　　　　　　　　　　　　　　　　　　　　　　　　　０．２
＊３４　ＭＺ－２（日油社製　平均粒子径　　１．５μｍ） Example 47: Eyebrow (ingredient) (%)
1. 1. Talc 20
2. 2. Mica remaining amount 3. Black iron oxide 10
4. Bengala 4
5. Al hydroxide treated titanium oxide (average particle size 1.0 μm) 6
6. Titanium oxide-coated synthetic phlogopite iron (average particle diameter 15 to 20 μm, titanium oxide coating amount 12%) 10
7. Black Iron Oxide Coated Mica Titanium 15
8. Zinc oxide (average particle size 3.0 μm, hexagonal plate) 2
9. Zinc stearate * 34 1
10. Red No. 226 0.1
11. Yellow No. 4 0.1
12. Red No. 202 0.1
13. Didimethylpolysiloxane (25 ° C, kinematic viscosity 6CS) 10
14. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 3
15. Carnauba wax 0.5
16. Microcrystalline wax 0.5
17. Trimethylsiloxysilicic acid 1
18. Paraffin 0.3
19. Beeswax 0.2
20. Dextrin isostearate 1
21. Damask rose flower extract 0.2
22. Lemon fruit extract 0.1
23. Ethanol 0.1
24. Purified water 0.2
* 34 MZ-2 (Average particle size 1.5 μm manufactured by NOF CORPORATION)
（製造方法）
Ａ．成分（１）～（１２）を均一に混合する。
Ｂ．Ａに、成分（１３）～（２４）を均一に混合したものを加えて、均一に分散し、粉砕後、化粧料基材を得た。
Ｃ．前記化粧料基材１００部に表中記載の溶剤を４０部添加して混合し、スラリー状の混合物を得た。
Ｄ．前記混合物を丸型の金皿容器（直径２ｃｍ）に２．０ｇ乗せ、プレス圧２．０ｋｇｆ／ｃｍ２、プレス時間４秒、紙６枚の条件で２回圧縮し、溶剤を一部除去した。その後、７０℃で１０時間乾燥させ、溶剤を除去し、アイブロウを得た。 (Production method)
A. The components (1) to (12) are uniformly mixed.
B. A uniformly mixed component (13) to (24) was added to A, uniformly dispersed, and pulverized to obtain a cosmetic base material.
C. 40 parts of the solvent shown in the table was added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture.
D. 2.0 g of the mixture was placed on a round gold plate container (diameter 2 cm) and compressed twice under the conditions of a press pressure of 2.0 kgf / cm2, a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. Then, it was dried at 70 degreeC for 10 hours, the solvent was removed, and the eyebrow was obtained.
　本実施例４７のアイブロウを、チップを用いて前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたアイブロウであった。 The eyebrow of Example 47 was evaluated and judged using a chip according to the evaluation method of the above Example. As a result, it was an excellent eyebrow in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例４８：固形粉末状アイシャドウ
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．酸化チタン被覆合成金雲母鉄
　　（平均粒子径５～１１μｍ、酸化チタン被覆量８％）　　　１０
２．タルク　　　　　　　　　　　　　　　　　　　　　　　　　残量
３．ステアロイルグルタミン酸２Ｎａ処理酸化チタン　＊３５　１５
４．窒化硼素　＊４　　　　　　　　　　　　　　　　　　　　　５
５．疎水化シリカ（平均粒子径１２μｍ）　　　　　　　　　　　５
６．群青　　　　　　　　　　　　　　　　　　　　　　　　　　２
７．赤色２０２号　　　　　　　　　　　　　　　　　　　　　　０．５
８．オルガノポリシロキサンエラストマーパウダー　＊３６　　　１
９．クロルフェネシン　　　　　　　　　　　　　　　　　　　　０．１
１０．オキシ塩化ビスマス　＊３７　　　　　　　　　　　　　　５
１１．硫酸バリウム（板状、平均粒子径：１５μｍ）　　　　　　３
１２．（ジメチコン／ビニルジメチコン）クロスポリマー　＊１　１
１３．ジメチルポリシロキサン（６ＣＳ：２５℃）　　　　　　　７
１４．ジペンタエリトリット脂肪酸エステル　＊３８　　　　　　１
１５．オリーブ油　　　　　　　　　　　　　　　　　　　　　　０．５
１６．香料　　　　　　　　　　　　　　　　　　　　　　　　　０．０１
 
＊３５：ＮＡＩ－チタンＭＰ－１１３３（三好化成社製　平均粒子径　０．２７μｍ）
＊３６：ＫＳＰ－３００（信越化学工業社製　平均粒子径　５μｍ）
＊３７：ＰＥＡＲＬ－ＧＬＯ　ＵＶＲ（ＥＮＧＥＬＨＡＲＤ社製）
＊３８：コスモール１６８ＡＲＶ（日清オイリオグループ社製） Example 48: Solid powder eyeshadow (ingredient) (%)
1. 1. Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm, titanium oxide coating amount 8%) 10
2. 2. Talc remaining amount 3. Titanium oxide treated with stearoyl glutamic acid 2Na * 35 15
4. Boron Nitride * 4 5
5. Hydrophobicized silica (average particle size 12 μm) 5
6. Gunjo 2
7. Red No. 202 0.5
8. Organopolysiloxane Elastomer Powder * 36 1
9. Chlorphenesin 0.1
10. Bismuth Oxychloride * 375
11. Barium sulfate (plate-shaped, average particle size: 15 μm) 3
12. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 1
13. Didimethylpolysiloxane (6CS: 25 ° C) 7
14. Dipentaerythrit fatty acid ester * 38 1
15. Olive oil 0.5
16. Fragrance 0.01

* 35: NAI-Titanium MP-1133 (average particle size 0.27 μm manufactured by Miyoshi Kasei, Inc.)
* 36: KSP-300 (Shin-Etsu Chemical Co., Ltd. average particle size 5 μm)
* 37: PEARL-GLO UVR (manufactured by ENGELHARD)
* 38: Cosmall 168ARV (manufactured by Nisshin Oillio Group)
（製造方法）
Ａ．成分（１）～（１１）をヘンシェルミキサー（三井三池社製）で均一に分散する。
Ｂ．成分（１２）～（１６）を均一に混合する。
Ｃ．Ａをヘンシェルミキサーにて攪拌しながら、Ｂを添加し、均一分散する。
Ｄ．Ｃをパルベライザーにて粉砕する。
Ｅ．Ｄを金皿に充填し、圧縮成型し、固形粉末状のアイシャドウを得た。 (Production method)
A. Ingredients (1) to (11) are uniformly dispersed with a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.).
B. The components (12) to (16) are uniformly mixed.
C. While stirring A with a Henschel mixer, B is added and uniformly dispersed.
D. C is crushed with a palberizer.
E. D was filled in a gold plate and compression-molded to obtain a solid powder eyeshadow.
［結果］
　本実施例４８の固形粉末状アイシャドウを、チップを用いて前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたアイシャドウであった。 [result]
The solid powder eyeshadow of Example 48 was evaluated and judged using a chip according to the evaluation method of the above Example. As a result, the natural covering effect of the skin hill, the pore covering effect, the long-lasting makeup, the smooth spreading and spreading, and the excellent eye shadow in all items.
実施例４９：油中水型ファンデーション化粧料
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．ジメチコン２％処理　酸化チタン被覆合成金雲母鉄
　　　（平均粒子径　５～１１μｍ、酸化チタン被覆量　１２％）１０
２．トリエトキシカプリリルシラン処理酸化鉄　　　　　　　　　　３
３．ジメチコン処理水酸化Ａｌ処理酸化チタン
　　（平均粒子径０．４μｍ）　　　　　　　　　　　　　　　　１０
４．（アクリレーツ／アクリル酸エチルヘキシル／
　　メタクリル酸ジメチコン）コポリマー＊３９　　　　　　　　　２
５．メチルトリメチコン　　　　　　　　　　　　　　　　　　　１０
６．ダイマージリノール酸（フィトステリル／イソステアリル／セチル／
　　ステアリル／ベヘニル）　＊４０　　　　　　　　　　　　　　３
７．パラメトキシケイ皮酸２－エチルヘキシル　　　　　　　　　　５
８．ジメチルポリシロキサン（６ＣＳ：２５℃）　　　　　　　　　５
９．（ジメチコン／ビニルジメチコン）クロスポリマー　＊１　　　２
１０．（ジメチコン／ＰＥＧ－１０／１５）クロスポリマー＊５　　１
１１．ラウリルＰＥＧ－９ポリジメチルシロキシエチル
　　ジメチコン＊４１　　　　　　　　　　　　　　　　　　　　　１
１２．トリフルオロアルキルジメチルトリメチルシロキシケイ酸＊４２
　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　５
１３．ビスエチルヘキシルオキシフェノールメトキシ
　　フェニルトリアジン　　　　　　　　　　　　　　　　　　　　０．５
１４．球状ポリエチレン末　　　　　　　　　　　　　　　　　　　３
１５．マイカ　　　　　　　　　　　　　　　　　　　　　　　　１０
１６．フェニルベンズイミダゾールスルホン酸　　　　　　　　　　２
１７．エタノール　　　　　　　　　　　　　　　　　　　　　　１０
１８．トリエタノールアミン　　　　　　　　　　　　　　　　　　１
１９．アスコルビン酸グルコシド　　　　　　　　　　　　　　　　１
２０．精製水　　　　　　　　　　　　　　　　　　　　　　　　残量
 
＊３９：ＫＰ－５７８（信越化学工業株式会社製）
＊４０：ＰＬＡＮＤＯＯＬ－Ｈ（日本精化社製）
＊４１：ＫＦ－６０３８（信越化学工業株式会社製）
＊４２：ＸＳ６６－Ｂ８２２６（モメンティブ社製） Example 49: Reclaimed water foundation cosmetic (ingredient) (%)
1. 1. Dimethicone 2% treatment Titanium oxide coated synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide coating 12%) 10
2. 2. Triethoxycaprylylsilane treated iron oxide 3
3. 3. Dimethicone treated Al hydroxide treated Titanium oxide (average particle size 0.4 μm) 10
4. (Acrylate / ethylhexyl acrylate /
Dimethicone Methacrylic Acid) Copolymer * 392
5. Methyltrimethicone 10
6. Dimer dilinoleic acid (phytosteryl / isostearyl / cetyl /
Stearyl / Behenil) * 40 3
7. 2-ethylhexyl paramethoxycinnamate 5
8. Didimethylpolysiloxane (6CS: 25 ° C) 5
9. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 2
10. (Dimethicone / PEG-10 / 15) Cross Polymer * 5 1
11. Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone * 41 1
12. Trifluoroalkyldimethyltrimethylsiloxysilicic acid * 42
5
13. Bisethylhexyloxyphenol methoxy phenyltriazine 0.5
14. Spherical polyethylene powder 3
15. Mica 10
16. Phenylbenzimidazole sulfonic acid 2
17. Ethanol 10
18. Triethanolamine 1
19. Ascorbic acid glucoside 1
20. Remaining amount of purified water
* 39: KP-578 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 40: PLANDOOL-H (manufactured by Nippon Fine Chemical Co., Ltd.)
* 41: KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 42: XS66-B8226 (manufactured by Momentive)
（製造方法）
Ａ．成分を（１）～（５）を３本ローラーで均一に分散する。
Ｂ．成分（６）～（１３）を８０℃で溶解混合し、室温冷却後Ａ及び（１４）～（１５）を加え分散する。
Ｃ．成分（１６）～（２０）を均一に混合溶解する。
Ｄ．ＢにＣを加え乳化し、油中水型ファンデーションを得た。 (Production method)
A. The components (1) to (5) are uniformly dispersed by three rollers.
B. The components (6) to (13) are dissolved and mixed at 80 ° C., cooled to room temperature, and then A and (14) to (15) are added and dispersed.
C. The components (16) to (20) are uniformly mixed and dissolved.
D. C was added to B and emulsified to obtain a water-in-oil foundation.
　本実施例４９の油中水型ファンデーション化粧料を、指で伸ばして前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたファンデーションであった。 The water-in-oil foundation cosmetic of Example 49 was stretched with a finger and evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an excellent foundation in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例５０：水中油型ファンデーション化粧料
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．ステアリン酸　　　　　　　　　　　　　　　　　　　　　　１
２．モノステアリン酸グリセリル　　　　　　　　　　　　　　　０．５
３．セタノール　　　　　　　　　　　　　　　　　　　　　　　０．５
４．セスキオレイン酸ソルビタン　　　　　　　　　　　　　　　０．５
５．ポリオキシエチレン（２０）硬化ヒマシ油　　　　　　　　　０．２
６．ＰＥＧ－９ジメチコン　　　　　　　　　　　　　　　　　　０．３
７．水添レシチン　　　　　　　　　　　　　　　　　　　　　　０．１
８．流動パラフィン　　　　　　　　　　　　　　　　　　　　　３
９．デカメチルシクロペンタシロキサン　　　　　　　　　　　　５
１０．ジメチルポリシロキサン（６ＣＳ：２５℃）　　　　　　　３
１１．トリフルオロアルキルジメチルトリメチル
　　シロキシケイ酸　＊４１　　　　　　　　　　　　　　　　　２
１２．パラメトキシケイ皮酸２－エチルヘキシル　　　　　　　　３
１３．（ジメチコン／ビニルジメチコン）クロスポリマー＊２３　１
１４．ＰＥＧ－９ポリジメチルシロキシエチルジメチコン＊４３　１
１５．精製水　　　　　　　　　　　　　　　　　　　　　　　　残量
１６．カルボキシビニルポリマー　　　　　　　　　　　　　　　１
１７．トリエタノールアミン　　　　　　　　　　　　　　　　　０．１
１８．１，３－ブチレングリコール　　　　　　　　　　　　　１０
１９．フェノキシエタノール　　　　　　　　　　　　　　　　　１
２０．リン脂質０．５％処理　酸化チタン被覆合成金雲母鉄
　　　（平均粒子径　５～１１μｍ、酸化チタン被覆量　１２％）３
２１．トリエトキシカプリリルシラン処理　微粒子酸化亜鉛※４４
　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　２
２２．レシチン処理水酸化Ａｌ酸化チタン（平均粒子径０．２５μｍ）
　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　８
２３．レシチン処理酸化鉄　　　　　　　　　　　　　　　　　　２
２４．タルク（平均粒子径５μｍ）　　　　　　　　　　　　　　２
２５．球状セルロース　　　　　　　　　　　　　　　　　　　　１
２６．シリカ　　　　　　　　　　　　　　　　　　　　　　　　０．５
 
＊４３：ＫＦ－６０２８（信越化学工業株式会社製）
＊４４：ＭＺ－５００ＦＴをトリエトキシカプリリルシラン処理したもの（テイカ株式会社製） Example 50: Underwater oil type foundation cosmetic (ingredient) (%)
1. 1. Stearic acid 1
2. 2. Glyceryl monostearate 0.5
3. 3. Cetanol 0.5
4. Sorbitan sesquioleate 0.5
5. Polyoxyethylene (20) Hardened castor oil 0.2
6. PEG-9 Dimethicone 0.3
7. Hydrogenated lecithin 0.1
8. Liquid paraffin 3
9. Decamethylcyclopentasiloxane 5
10. Didimethylpolysiloxane (6CS: 25 ° C) 3
11. Trifluoroalkyldimethyltrimethylsiloxysilicic acid * 421
12. 2-ethylhexyl paramethoxycinnamate 3
13. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 23 1
14. PEG-9 Polydimethylsiloxyethyl Dimethicone * 43 1
15. Remaining amount of purified water 16. Carboxyvinyl polymer 1
17. Triethanolamine 0.1
18.1,3-butylene glycol 10
19. Phenoxyethanol 1
20. Phospholipid 0.5% treatment Titanium oxide coated synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide coating 12%) 3
21. Triethoxycaprylylsilane treatment Fine particle zinc oxide * 44
2
22. Lecithin-treated Al hydroxide hydroxide Titanium oxide (average particle size 0.25 μm)
8
23. Lecithin-treated iron oxide 2
24. Talc (average particle diameter 5 μm) 2
25. Spherical cellulose 1
26. Silica 0.5

* 43: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 44: MZ-500FT treated with triethoxycaprylylsilane (manufactured by TAYCA CORPORATION)
（製造方法）
Ａ．成分（１８）～（２６）を均一に分散混合する。
Ｂ．成分（１）～（１４）を約９０℃に加熱し、均一に混合する。
Ｃ．Ｂに約９０℃に加熱した成分（１５）～（１７）を添加し、乳化後、冷却する。
Ｄ．ＣにＡを加え混合し、水中油型リキッドファンデーションを得た。 (Production method)
A. The components (18) to (26) are uniformly dispersed and mixed.
B. Ingredients (1) to (14) are heated to about 90 ° C. and mixed uniformly.
C. The components (15) to (17) heated to about 90 ° C. are added to B, emulsified, and then cooled.
D. A was added to C and mixed to obtain an oil-in-water liquid foundation.
　本実施例５０の水中油型ファンデーション化粧料を、前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたファンデーションであった。 The oil-in-water foundation cosmetic of Example 50 was evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an excellent foundation in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例５１：固形状油中水乳化型ファンデーション化粧料
（成分）　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．酸化チタン被覆合成金雲母鉄
　　（平均粒子径　５～１１μｍ、酸化チタン被覆量　１２％）１０
２．疎水化処理酸化チタン（平均粒子径０．４μｍ）　　　　　　８
３．（アクリレーツ／アクリル酸エチルヘキシル／
　　メタクリル酸ジメチコン）コポリマー　＊３９　　　　　　　２
４．（ジメチコン／ビニルジメチコン）クロスポリマー＊１　　　２
５．ジメチルポリシロキサン（６ＣＳ：２５℃）　　　　　　　　５
６．トリメチルシロキシケイ酸＊４５　　　　　　　　　　　　　３
７．イソヘキサデカン　　　　　　　　　　　　　　　　　　　１０
８．流動パラフィン　　　　　　　　　　　　　　　　　　　　　５
９．パルミチン酸デキストリン　　　　　　　　　　　　　　　　２
１０．キャンデリラロウ（融点７０℃）　　　　　　　　　　　　２
１１．ステアリン酸イヌリン　　　　　　　　　　　　　　　　　２
１２．トリベヘン酸グリセリル（融点６０℃）　　　　　　　　　２
１３．メチレンビスベンゾトリアゾリルテトラメチルブチルフェノール
　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　２
１４．シリコーン処理酸化チタン（平均粒子径：０．０３５μｍ）
　　　　　　　　　　　　　　　　　　　　　　　　　　　　　１０
１５．酸化鉄　　　　　　　　　　　　　　　　　　　　　　　１２
１６．（ジフェニルジメチコン／ビニルジフェニルジメチコン／
　　シルセスキオキサン）クロスポリマー＊４６　　　　　　　　２
１７．Ｌ－メントール　　　　　　　　　　　　　　　　　　　　０．０１
１８．パラオキシ安息香酸メチル　　　　　　　　　　　　　　　０．１
１９．１，３－ブチレングリコール　　　　　　　　　　　　　　５
２０．Ｌ－グルタミン酸ナトリウム　　　　　　　　　　　　　　０．２
２１．精製水　　　　　　　　　　　　　　　　　　　　　　　　残量
 
＊４５：ＫＦ－７３１２Ｊ（信越化学工業株式会社製）
＊４６：ＫＳＰ－３００（信越化学工業株式会社製） Example 51: Water emulsified foundation cosmetics in solid oil (ingredients) (%)
1. 1. Titanium oxide-coated synthetic phlogopite iron (average particle diameter 5 to 11 μm, titanium oxide coating amount 12%) 10
2. 2. Hydrophobicized titanium oxide (average particle size 0.4 μm) 8
3. 3. (Acrylate / ethylhexyl acrylate /
Dimethicone Methacrylic Acid) Copolymer * 392
4. (Dimethicone / Vinyl Dimethicone) Cross Polymer * 1 2
5. Didimethylpolysiloxane (6CS: 25 ° C) 5
6. Trimethylsiloxysilicic acid * 45 3
7. Isohexadecane 10
8. Liquid paraffin 5
9. Dextrin palmitate 2
10. Candelilla low (melting point 70 ° C) 2
11. Inulin stearate 2
12. Glyceryl tribehenate (melting point 60 ° C) 2
13. Methylenebisbenzotriazolyl tetramethylbutylphenol 2
14. Silicone treated titanium oxide (average particle size: 0.035 μm)
10
15. Iron oxide 12
16. (Diphenyldimethicone / Vinyldiphenyldimethicone /
Silsesquioxane) Crosspolymer * 46 2
17. L-Menthol 0.01
18. Methyl paraoxybenzoate 0.1
19.1,3-butylene glycol 5
20. Sodium L-monosodium 0.2
21. Remaining amount of purified water
* 45: KF-7312J (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 46: KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd.)
（製造方法）
Ａ．成分（１）～（５）、（８）～（１６）を７５℃でホモミキサーにて混合後、４０℃にて成分（６）と（７）を添加する。
Ｂ．成分（１７）～（２１）を混合する。
Ｃ．ＡにＢを徐々に注入して乳化し、８５℃まで加熱後、６０℃まで冷却して容器に流し込み、室温まで冷却して、固形状油中水型ファンデーションを得た。 (Production method)
A. The components (1) to (5) and (8) to (16) are mixed at 75 ° C. with a homomixer, and then the components (6) and (7) are added at 40 ° C.
B. Ingredients (17) to (21) are mixed.
C. B was gradually injected into A and emulsified, heated to 85 ° C., cooled to 60 ° C., poured into a container, and cooled to room temperature to obtain a solid oil-in-water foundation.
　本実施例５１の固形状油中水乳化型ファンデーション化粧料を、前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れた固形状油中水乳化型ファンデーション化粧料であった。 The solid oil emulsified foundation cosmetic of Example 51 was evaluated and judged according to the evaluation method of the above Example. As a result, it was an excellent solid oil-in-water emulsified foundation cosmetic in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.
実施例５２：エアゾール型ファンデーション化粧料
（成分）　　　　　　　　　　　　　　　　　　　　　　　　　（％）
１．レシチン処理水酸化Ａｌ処理酸化チタン
　　（平均粒子径０．２７μｍ）　　　　　　　　　　　　　　　１０
２．トリエトキシカプリリルシラン処理赤色酸化鉄　　　　　　　　０．８
３．トリエトキシカプリリルシラン処理黄色酸化鉄粉末　　　　　　１
４．トリエトキシカプリリルシラン処理黒色酸化鉄粉末　　　　　　０．５
５．ジメチコン処理酸化チタン被覆合成金雲母鉄
　　　（平均粒子径　５～１１μｍ、酸化チタン被覆量　１２％）１０
６．ポリグリセリル－３／ポリジメチルシロキシエチルジメチコン　１
７．デカメチルシクロペンタシロキサン　　　　　　　　　　　　　５
８．ジメチルポリシロキサン　　　　　　　　　　　　　　　　　残量
９．（トリフルオロプロピルジメチコン／トリフルオロ
プロピルジビニルジメチコン）クロスポリマー　　　　　　　　　　２
１０．メトキシケイ皮酸２－エチルヘキシル　　　　　　　　　　　８
１１．（トリフルオロプロイルジメチルシロキシ／
トリメチルシロキシ）シルセスキオキサン）＊４７　　　　　　　　５
１２．ＰＥＧ－９ポリジメチルシロキシエチルジメチコン＊１６　　２
１３．架橋型オルガノポリシロキサン重合物の混合物　　　　　　　２
１４．ステアロキシジメチコン　　　　　　　　　　　　　　　　　０．５
１５．カンテン　　　　　　　　　　　　　　　　　　　　　　　　０．１
１６．ビスエチルヘキシルオキシフェノールメトキシフェニル
　　　　トリアジンのエマルジョン　　　　　　　　　　　　　　　２
１７．トリプロピレングリコール　　　　　　　　　　　　　　　　３
１８．精製水　　　　　　　　　　　　　　　　　　　　　　　　１５
 
＊４７：ＦＲ－５（モメンティブ社製） Example 52: Aerosol type foundation cosmetic (ingredient) (%)
1. 1. Lecithin-treated Al hydroxide-treated titanium oxide (average particle size 0.27 μm) 10
2. 2. Triethoxycaprylylsilane treated red iron oxide 0.8
3. 3. Triethoxycaprylylsilane treated yellow iron oxide powder 1
4. Triethoxycaprylylsilane treated black iron oxide powder 0.5
5. Dimethicone-treated titanium oxide-coated synthetic phlogopite iron (average particle size 5 to 11 μm, titanium oxide coating amount 12%) 10
6. Polyglyceryl-3 / polydimethylsiloxyethyl dimethicone 1
7. Decamethylcyclopentasiloxane 5
8. Dimethylpolysiloxane Remaining amount 9. (Trifluoropropyldimethicone / trifluoropropyldivinyldimethicone) Crosspolymer 2
10. 2-ethylhexyl methoxycinnamate 8
11. (Trifluoroproyldimethylsiloxy /
Trimethylsiloxy) silsesquioxane) * 475
12. PEG-9 Polydimethylsiloxyethyl Dimethicone * 16 2
13. Mixture of crosslinked organopolysiloxane polymer 2
14. Stearoxydimethicone 0.5
15. Canten 0.1
16. Emulsion of bisethylhexyloxyphenol methoxyphenyl triazine 2
17. Tripropylene glycol 3
18. Purified water 15

* 47: FR-5 (manufactured by Momentive)
（製造方法）
Ａ．成分（１）～（６）を３本ローラーにて混練する。
Ｂ．Ａと成分（７）～（１４）を５０℃で加熱混合し、均一に分散させる。
Ｃ．成分（１５）～（１８）を混合し、Ｂに添加し、常温で乳化し、原液を得た。
Ｄ．Ｃで得られた原液９ｇをアルミ製耐圧容器に充填した後バルブを固着し、バルブを通じてＬＰＧ０．１５　１０ｇ及びジメチルエーテル　２ｇを耐圧容器に充填し、エアゾール型ファンデーションを得た。 (Production method)
A. Ingredients (1) to (6) are kneaded with three rollers.
B. A and the components (7) to (14) are heated and mixed at 50 ° C. and uniformly dispersed.
C. Ingredients (15) to (18) were mixed, added to B, and emulsified at room temperature to obtain a stock solution.
D. After filling 9 g of the undiluted solution obtained in C into a pressure-resistant container made of aluminum, the valve was fixed, and 0.15 10 g of LPG and 2 g of dimethyl ether were filled in the pressure-resistant container through the valve to obtain an aerosol-type foundation.
　本実施例５２のエアゾール型ファンデーション化粧料を、マットに噴射後前記実施例の評価方法に従って評価及び判定を行った。その結果、皮丘の自然なカバー効果、毛穴カバー効果、化粧持続性、滑らかな伸び広がり、全ての項目において優れたエアゾール型ファンデーション化粧料であった。 The aerosol-type foundation cosmetic of Example 52 was sprayed onto a mat and then evaluated and judged according to the evaluation method of the above-mentioned Example. As a result, it was an aerosol-type foundation cosmetic that was excellent in all items such as natural covering effect of skin hills, pore covering effect, long-lasting makeup, and smooth spreading and spreading.

Claims (9)

  1. 　次の成分（Ａ）及び（Ｂ）；
    （Ａ）合成金雲母鉄
    （Ｂ）架橋型非乳化性シリコーンエラストマー０．１～５．０質量％
    を含有する化粧料。     The following components (A) and (B);
    (A) Synthetic phlogopite iron (B) Cross-linked non-emulsifying silicone elastomer 0.1-5.0% by mass
    Cosmetics containing.
  2. 　さらに成分（Ｃ）として、平均粒子径０．１～４．０μｍの酸化チタン及び酸化亜鉛から選ばれる１種又は２種以上の金属酸化物
    を含有する請求項１記載の化粧料。     The cosmetic according to claim 1, further comprising one or more metal oxides selected from titanium oxide and zinc oxide having an average particle diameter of 0.1 to 4.0 μm as the component (C).
  3. 　さらに成分（Ｄ）として、シリコーンパウダー、ウレタンパウダー、ナイロンパウダー、セルロースパウダー、デンプンパウダー、ポリメタクリル酸メチルパウダー及びシリカから選ばれる１種又は２種以上の粉体を含有する請求項１又は２に記載の化粧料。 Further, claim 1 or 2 containing one or more powders selected from silicone powder, urethane powder, nylon powder, cellulose powder, starch powder, polymethyl methacrylate powder and silica as the component (D). The listed cosmetics.
  4. 　前記成分（Ｃ）が、さらに酸化鉄で被覆されている請求項２に記載の化粧料。 The cosmetic according to claim 2, wherein the component (C) is further coated with iron oxide.
  5. 　前記成分（Ａ）が、さらに酸化チタンで被覆されている請求項１～４の何れか一項に記載の化粧料。 The cosmetic according to any one of claims 1 to 4, wherein the component (A) is further coated with titanium oxide.
  6. 　前記成分（Ａ）と前記成分（Ｂ）の含有質量割合である（Ａ）／（Ｂ）が、１．０～１００．０である請求項１～５の何れか一項に記載の化粧料。 The cosmetic according to any one of claims 1 to 5, wherein (A) / (B), which is the content mass ratio of the component (A) and the component (B), is 1.0 to 100.0. ..
  7. 　前記成分（Ａ）が、分光色彩計を用いて、入射角－４５°、受光角０°の測定において、セルに成分（Ａ）を２０回タッピングさせて測定した際に、ＣＩＥ１９７６Ｌ＊ａ＊ｂ＊表色系で規定される測色値Ｌ＊、Ｃ＊、ｈが、６３＜Ｌ＊＜８３、１２＜Ｃ＊＜３２、５０＜ｈ＜７６である請求項５に記載の化粧料。 CIE1976L * a * b when the component (A) was measured by tapping the component (A) 20 times on the cell in the measurement of the incident angle −45 ° and the light receiving angle 0 ° using a spectrocolorimeter. * The cosmetic according to claim 5, wherein the colorimetric values L *, C *, and h defined by the color system are 63 <L * <83, 12 <C * <32, 50 <h <76.
  8. 　前記成分（Ｄ）が、セルロースパウダー、デンプンパウダー、及びシリカから選ばれる１種又は２種以上の粉体を含有する請求項３、５～７の何れか一項に記載の化粧料。 The cosmetic according to any one of claims 3, 5 to 7, wherein the component (D) contains one or more powders selected from cellulose powder, starch powder, and silica.
  9. 　前記成分（Ａ）が、ブルーライトカット剤である請求項１～８の何れか一項に記載の化粧料。
          The cosmetic according to any one of claims 1 to 8, wherein the component (A) is a blue light-cutting agent.
PCT/JP2021/038745 2020-11-04 2021-10-20 Cosmetic WO2022097476A1 (en)

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Publication number Priority date Publication date Assignee Title
WO2024085115A1 (en) * 2022-10-17 2024-04-25 株式会社コーセー Solid powder cosmetic

Citations (6)

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JPH11279432A (en) * 1998-03-30 1999-10-12 Shiseido Co Ltd Coloring agent by using synthetic fluorophlogophite powder, and cosmetic obtained by compounding the same
JP2000290526A (en) * 1999-04-02 2000-10-17 Topy Ind Ltd Pearly lustrous pigment, paint composition, cosmetic, ink and plastic containing said pigment
JP2006348007A (en) * 2005-06-13 2006-12-28 Milott:Kk Cosmetic
JP2008088317A (en) * 2006-10-03 2008-04-17 Kose Corp White composite powder and cosmetic incorporated with the same
JP2011063560A (en) * 2009-09-18 2011-03-31 Nippon Menaade Keshohin Kk Solid powder cosmetic product
JP2016037497A (en) * 2014-08-08 2016-03-22 株式会社 資生堂 Solid powder cosmetic

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11279432A (en) * 1998-03-30 1999-10-12 Shiseido Co Ltd Coloring agent by using synthetic fluorophlogophite powder, and cosmetic obtained by compounding the same
JP2000290526A (en) * 1999-04-02 2000-10-17 Topy Ind Ltd Pearly lustrous pigment, paint composition, cosmetic, ink and plastic containing said pigment
JP2006348007A (en) * 2005-06-13 2006-12-28 Milott:Kk Cosmetic
JP2008088317A (en) * 2006-10-03 2008-04-17 Kose Corp White composite powder and cosmetic incorporated with the same
JP2011063560A (en) * 2009-09-18 2011-03-31 Nippon Menaade Keshohin Kk Solid powder cosmetic product
JP2016037497A (en) * 2014-08-08 2016-03-22 株式会社 資生堂 Solid powder cosmetic

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024085115A1 (en) * 2022-10-17 2024-04-25 株式会社コーセー Solid powder cosmetic

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TW202233157A (en) 2022-09-01
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