JP5754866B2 - Cosmetics - Google Patents

Description

  The present invention relates to a cosmetic using composite particles obtained by attaching a silicone elastomer to the surface of an inorganic powder.

  Makeup cosmetics such as foundations are intended to hide morphological troubles such as skin wrinkles, pores, texture roughness, and color troubles such as skin spots and freckles, and to make the skin look smooth and beautiful. Emphasis is placed on a non-artificial natural finish (bare skin feel). In addition, the natural finish of cosmetics is evaluated when there is no unnatural luster, excellent uniformity of the makeup film, and high transparency. Conventionally, many new materials and new technologies have been proposed in order to obtain a natural finish feeling while following the effects of the makeup cosmetics. In particular, cosmetics containing various diffuse reflection powders are known as methods for concealing form troubles. Patent Document 1 discloses a wrinkle concealing multi-layer cosmetic comprising a first layer makeup base material containing an adhesive substance and a second layer makeup finish containing a powder that diffuses and reflects light. Has been proposed. For example, a light diffusion reflection type composite powder in which talc particles are coated with an acrylic polymer is used for this wrinkle concealing multilayer cosmetic.

  However, in this cosmetic, when the cosmetic film is held on the skin for a long time, the sebum is mixed with the adhesive substance, and thus the effect is reduced because the sebum is out of the proper mixing range of the powder and the adhesive substance. There was a drawback. Patent Document 2 discloses a flaky fine powder in which spherical fine particle silica is coated on the surface of a flaky material such as natural mica. Since this flaky fine powder uses spherical fine particles having a large surface diffusive scattering effect of light, when this flaky fine powder is used as a cosmetic compounding agent, “to suppress excessive gloss of the substrate mica and It is said that a so-called soft focus effect can be achieved, such as making the cosmetics inconspicuous, and a cosmetic product with improved slipperiness and feel during use can be obtained. ing.

  However, since the slidability of the flaky fine powder is very excellent, the cosmetics containing the flaky fine powder are liable to be distorted during application, and it is difficult to uniformly apply the cosmetics, and a natural finish can be obtained. There was a drawback of not. Furthermore, since the fine particle silica used as a coating agent reduces the contact area of the composite powder with the skin, the adhesion to the skin is reduced, and the composite powder is applied to the skin by physical impact such as rubbing by clothes. There was a fault that it was easy to peel off from above and the sustainability of the cosmetic effect was lowered. Further, when the ratio of the fine particle silica in the flaky fine powder is reduced to improve the adhesion of the composite powder to the skin, there is a drawback that a sufficient effect on the form trouble cannot be obtained.

  In addition, as a technique similar to these for the purpose of avoiding morphological troubles or producing a natural feeling of finish, this is coated with flaky extender pigment as a core and coated with colored pigment-containing titanium dioxide. Cosmetics containing a core-shell pigment coated with a light diffusing powder (Patent Document 3), and composite powders with a clay mineral surface coated with an inorganic metal hydroxide such as aluminum hydroxide. A compounding technique (Patent Document 4, Patent Document 5), a surface of a powder having a refractive index of 1.6 to 1.7, such as barium sulfate, and a layer coated with a metal oxide having a high refractive index; Cosmetics containing a powder having a layer coated with one or more selected from yellow iron oxide, black iron oxide and bengara (Patent Document 6), a composite of silica sol and zinc oxide Obtained by Silica / zinc oxide complex is added to the cosmetic cosmetics (Patent Document 7), and the like.

  However, although these composite powders exhibit a certain degree of soft focus effect due to their light diffusion effect, they are composed of inorganic metal oxides or inorganic metal hydroxides, so pay attention to the feeling of use of cosmetics. In this case, the composite powder itself was not sufficiently satisfactory in terms of softness, moistness, smoothness, etc. from the hardness of the composite powder itself. On the other hand, for the purpose of improving the feeling of use of cosmetic powder, that is, imparting a feeling of use such as a smooth feeling and smoothness, extensibility, adhesion and the like, Patent Document 8 describes the particle surface of scaly inorganic particles. Particles coated with polyurethane, styrene-butadiene copolymer, silicone elastomer, or polyolefin elastomer have been proposed, and a soft and moist feel is obtained.

  However, the particles coated with the silicone elastomer are not specifically exemplified. In another document, a particle in which a silicone elastomer is attached and coated on the surface of the particle and a method for producing the particle are proposed. Patent Document 9 proposes a method of pulverizing and mixing a silicone elastomer having a reactive functional group and silica. However, since the silica particles serving as the mother particles are pulverized, the initial shape and particle size are maintained. Unable to get particles. That is, there are disadvantages in that particles having a specific shape such as a spherical shape, a plate shape, or a rod shape cannot be obtained, and it is difficult to control the particle size. Patent Document 10 proposes a method in which a base particle and a curable silicone that becomes a silicone elastomer are mixed, and then the silicone is cured. The obtained particles have a plurality of base particles in the particles. Patent Document 11 proposes a method of emulsifying and dispersing a mixture of silica particles serving as mother particles and curable silicone serving as a silicone elastomer in water, and then curing the silicone. Patent Document 12 discloses silica particle water. A method has been proposed in which a mixture of a dispersion and a curable silicone that becomes a silicone elastomer is emulsified and dispersed in water, and then the silicone is cured. Some particles are not included.

  Therefore, the inventors of the present invention select a mixed water dispersion in which a powder and a silicone elastomer are dispersed from an acidic substance or an alkaline substance, an alkoxysilane, a silanol group-containing silane, and a partial condensate thereof in Patent Document 13. We have proposed composite particles in which a silicone elastomer is attached to the surface of the core powder using a silicone resin as a binder by adding a compound and hydrolyzing and condensing this compound. The material is soft and moist as a silicone elastomer, and has a soft and moist feeling of use. It has a good spread, softness, stickiness and mixing, and can impart a skin shape correction effect.

JP-A-6-128122 International Publication No. 92/03119 Pamphlet JP-A-8-188723 JP-A-9-20609 JP 2002-146238 A JP 2003-40737 A Japanese Patent No. 3702702 Japanese Patent No. 3963635 JP-A-8-3451 JP-A-3-294357 JP-A-2-232263 JP-A-3-281536 JP 2011-1332 A

  However, when the core powder is an inorganic powder, depending on the type, there is a problem that the silicone elastomer particles do not adhere or the adhesion becomes uneven, and the effect of imparting the above properties to the cosmetic becomes insufficient. there were.

  The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a cosmetic material that has good spread, softness, adhesion, and mixing, regardless of the type of inorganic powder that is the mother particle.

  In order to solve the above problems, the present invention provides a cosmetic production method comprising at least a mixed water dispersion in which inorganic powder and a silicone elastomer are dispersed, a cationic water-soluble polymer, and an alkaline substance. A compound selected from alkoxysilanes, silanol group-containing silanes, and partial condensates thereof is added to the blended mixed solution to cause hydrolysis / condensation reaction, whereby silicone is used as a binder on the surface of the inorganic powder. Provided is a method for producing a cosmetic, characterized in that a composite particle formed by attaching an elastomer is produced, and the cosmetic is produced using the composite particle.

  The cosmetics produced by such a production method have good spread, softness, adhesion, and mixing, and even when made-up cosmetics such as foundations, the skin shape correction effect is excellent.

  The cationic water-soluble polymer is a synthetic system in which the polymer skeleton is synthesized by any one of vinyl polymerization, addition polymerization, and condensation, and does not contain an anionic group or an amphoteric group. It is preferable to use it.

  If such a cationic water-soluble polymer is used, the polymer helps the silicone elastomer to be adsorbed to the inorganic powder, so that the silicone elastomer can be uniformly applied to the surface of the inorganic powder without aggregation. Since it can adhere, cosmetics with a good feeling of use such as smoothness and smoothness can be produced.

Moreover, it is preferable to use what was synthesize | combined without using the monomer which has a nonionic group as said cationic water-soluble polymer.
A cationic water-soluble polymer synthesized without using a monomer having a nonionic group can make the silicone elastomer adhering to the surface of the inorganic powder more uniform. It becomes more excellent due to the imparting effect.

Moreover, it is preferable to use a polymer of dimethyldiallylammonium chloride as the cationic water-soluble polymer.
The polymer of dimethyldiallylammonium chloride can make the silicone elastomer adhering to the surface of the inorganic powder more uniform.

  Moreover, it is preferable that the compounding quantity of the cationic water-soluble polymer with respect to the said mixed water dispersion shall be 0.0001-1 mass part with respect to 100 mass parts of water in the said mixed water dispersion.

  With such a blending amount, the silicone elastomer adhering to the surface of the inorganic powder can be made more uniform, and the adhering state becomes better, so that the spread, softness, adhesion and mixing are good. Further, it is possible to produce a cosmetic that is more excellent due to the skin shape correction effect.

  Further, the present invention is a cosmetic, and at least an alkoxysilane, a mixed liquid in which an inorganic powder and a silicone elastomer are dispersed, a mixed liquid containing a cationic water-soluble polymer, and an alkaline substance. A silicone resin produced by adding a compound selected from silanol group-containing silanes and partial condensates thereof to cause hydrolysis / condensation reaction, and attaching the silicone elastomer to the surface of the inorganic powder using a silicone resin as a binder. Provided is a cosmetic comprising composite particles.

  Such a cosmetic of the present invention has good spread, softness, adhesion, and mixing, and is excellent in skin shape correction effect.

  Further, the composite particle is a synthetic system in which the polymer skeleton is synthesized by any of vinyl polymerization, addition polymerization, and condensation as the cationic water-soluble polymer, and an anionic group and an amphoteric group It is preferable that it is manufactured using what does not contain.

  A cosmetic containing such composite particles has good usability such as smoothness and smoothness.

Moreover, it is preferable that the said composite particle is manufactured using what was synthesize | combined without using the monomer which has a nonionic group as said cationic water-soluble polymer.
Cosmetics containing such composite particles are more excellent due to various properties as cosmetics.

The composite particles are preferably produced using a polymer of dimethyldiallylammonium chloride as the cationic water-soluble polymer.
Cosmetics containing such composite particles are further excellent in various properties as cosmetics.

  In addition, the composite particle is produced by setting the blending amount of the cationic water-soluble polymer in the mixed water dispersion as 0.0001 to 1 part by weight with respect to 100 parts by weight of water in the mixed water dispersion. Preferably there is.

  With such a blending amount, the silicone elastomer adhering to the surface of the inorganic powder can be made more uniform, and the adhering state becomes better, and in particular, the spread, softness, adhesion, and mixing condition are It is a cosmetic which is good and has a better skin shape correction effect.

As described above, according to the present invention, it is possible to provide a cosmetic that is excellent in spreading, softness, stickiness, and mixing, and has an excellent skin shape correction effect.
The composite particles obtained by adhering a silicone elastomer with a silicone resin as a binder on the surface of the inorganic powder in the present invention are excellent in extensibility, usability, adhesion, dispersibility, shape correction effect, water resistance, and sebum resistance. Is. The present invention using such composite particles has a light spreading, is soft and can be spread evenly, has a very good dispersibility, sebum resistance and longevity, and can be applied to any makeup. Even if it is blended into the cosmetic, it is possible to provide a cosmetic having a very excellent stability that does not change with temperature and time.

Hereinafter, the present invention will be described in more detail.
As described above, when composite particles whose core powder is an inorganic powder are used in cosmetics, there is a problem that the effect of imparting the above properties to the cosmetics is insufficient depending on the type.

  As a result of intensive studies to solve the above problems, the present inventor has found that the silicone elastomer particles do not adhere or the adhesion is uneven, and the inorganic powder and the silicone elastomer are dispersed. Silicone elastomer particles using an alkaline substance and a compound selected from an alkoxysilane, a silanol group-containing silane, and a partial condensate thereof, and a hydrolysis / condensation reaction of the compound using a silicone resin as a binder. In the method for producing composite particles having adhered thereto, by adding a cationic water-soluble polymer to the above mixed aqueous dispersion, composite particles in which the adhesion of the silicone elastomer becomes uniform regardless of the type of inorganic powder Cosmetics formulated with these composite particles have the effect of improving skin shape troubles. The present invention has been found that it can be expressed objectively, has a soft and moist feeling as a smoothness unique to silicone elastomers, has a good spread, softness, adhesion and mixing, and has a skin shape correction effect. That led to

  That is, the method for producing a cosmetic according to the present invention includes at least an alkoxysilane in a mixed solution in which an inorganic powder and a silicone elastomer are dispersed, a mixed water dispersion containing a cationic water-soluble polymer, and an alkaline substance. , A silanol group-containing silane, and a composite particle obtained by adhering the silicone elastomer to the surface of the inorganic powder using a silicone resin as a binder by adding a compound selected from these condensates and hydrolyzing / condensing reaction And a cosmetic is produced using the composite particles.

  The cosmetic of the present invention contains at least an alkoxysilane and a silanol group in a mixed solution in which an inorganic powder and a silicone elastomer are dispersed, a mixture of a cationic water-soluble polymer, and an alkaline substance. A composite particle produced by adding a compound selected from silane and a partial condensate thereof to cause hydrolysis / condensation reaction, and having the silicone elastomer attached to the surface of the inorganic powder using a silicone resin as a binder. It is characterized by containing.

  Hereinafter, the present invention relates to I.D. Composite particles, II. Production method of composite particles, III. Method for producing cosmetics using composite particles, IV. The cosmetics containing composite particles will be described in this order.

I. Composite Particle The composite particle in the present invention is a particle obtained by attaching a silicone elastomer to a surface of an inorganic powder using a silicone resin as a binder. The state in which the silicone elastomer is adhered to the surface of the inorganic powder can be confirmed with an electron microscope.

  Here, in the present invention, the “adhesion” of the silicone elastomer using the silicone resin as a binder is more preferably a state in which the surface of the inorganic powder is coated and adhered with a uniform thickness without a gap. In the case where the effect of achieving is achieved, there is no particular limitation. For example, it may be in a state of being uniformly attached with a gap on the surface of the inorganic powder.

[Inorganic powder]
As the inorganic powder used in the present invention, powders that can be substantially used in cosmetics and those having a particle size in the entire range can be applied. Further, as long as the geometrical form is usually used for cosmetics, it may be any shape such as spherical, polyhedral, spindle, needle or plate, and any of nonporous and porous But you can.

  The average particle size is preferably in the range of 0.5 to 50 μm, more preferably 1 to 30 μm. If the particle size is 0.5 μm or more, the feeling of use such as a smooth feeling and smoothness and the effect of imparting extensibility are not deteriorated, and if it is 50 μm or less, the feeling of roughness does not appear. The average particle size is measured by appropriately selecting from a microscope method, a light scattering method, a laser diffraction method, a liquid phase precipitation method, an electric resistance method, etc. according to each shape.

  Specifically, as the inorganic powder, titanium oxide, mica titanium, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, cleaved talc, mica, Kaolin, sericite, muscovite, synthetic mica, phlogopite, mica, biotite, lithia mica, silicic acid, silicon dioxide, hydrous silicon dioxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, Barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramics, dicalcium phosphate, alumina, aluminum hydroxide, Tsu boron, nitride boron, include particles of glass.

  Furthermore, inorganic pigments can be mentioned. Specific examples include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide; yellow iron oxide, ocher and the like. Inorganic yellow pigments; inorganic black pigments such as black iron oxide and carbon black; inorganic purple pigments such as manganese violet and cobalt violet; inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate; Inorganic blue pigments such as bitumen, ultramarine blue, etc .; Colored pigments such as those obtained by lacquering tar pigments or lacquering natural pigments; titanium oxide coated mica, bismuth oxychloride, bismuth oxychloride coated with titanium oxide, titanium oxide coated Examples include pearl pigments such as talc, fish scale foil, and titanium oxide-coated colored mica.

  Furthermore, examples of the inorganic particles include metal fine particles made of aluminum, copper, stainless steel, silver or the like.

  In addition, among the skin shape correction effects, in particular, the three-dimensional makeup effect, that is, the T zone from the forehead to the nose muscles looks bright and high, or the reflection of light in the U zone from the cheek to the chin is suppressed, When light interference powder such as titanium mica is selected as the inorganic powder of the present invention for the purpose of producing an optical correction effect that makes the sagging of the face less noticeable, the interference reflected light is reflected at 550 nm to 700 nm. It is particularly preferable to use a red light interference powder having a red peak and / or a blue light interference powder having a reflection peak at 400 nm to 500 nm.

  The inorganic powder may be surface-treated with metal soap, silane, silicone, silicone resin, fluorine compound, amino acid, iron oxide, titanium oxide, iron oxide titanium oxide, or aluminum hydroxide.

[Silicone elastomer]
The silicone elastomer used in the present invention is produced by, for example, a method of emulsifying a curable liquid silicone composition to be described later, and therefore the shape is often spherical. Depending on the reaction conditions, even if it is substantially spherical or partially agglomerated particles, the effect is not greatly impaired. Further, the particle size is preferably smaller than the above-mentioned inorganic powder to which the silicone elastomer is attached in order to effectively express the feeling of use of the silicone elastomer. If it is smaller than the inorganic powder, it is possible to more remarkably exhibit characteristics such as a feeling of use such as smoothness and smoothness of the powder, extensibility and adhesion. The smaller particle size is not particularly limited, and for example, when it is produced by a method of emulsifying curable liquid silicone, the minimum particle size obtained by the method is the lower limit.

  The amount of the silicone elastomer is not particularly limited in the case where the effect of addition to cosmetics is manifested, but is more favorable, such as a more pronounced soft focus effect, smooth feeling, smoothness, extensibility, moist feeling, softness, etc. When a feeling of use is desired, the amount is preferably 0.5 parts by mass or more, more preferably 1 part by mass or more, and further preferably 2 parts by mass or more with respect to 100 parts by mass of the inorganic powder. When the amount of silicone elastomer increases, the cohesiveness increases, and the feeling of use such as smoothness and smoothness and the extensibility may be poor. Therefore, the amount is preferably 100 parts by mass or less with respect to 100 parts by mass of the inorganic powder. Preferably it is 70 mass parts or less, More preferably, it is 50 mass parts or less.

The silicone elastomer has the following formula (1)
-(R ¹ ₂ SiO _2/2 ) _n- (1)
It is a rubber elastic body which has the linear organosiloxane block shown by these.
R ¹ in the formula is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms, and n is a positive number of 5 to 5,000.

Examples of R ¹ include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tetradecyl group, pentadecyl group, hexadecyl group. Group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, henicosyl group, docosyl group, tricosyl group, tetrasyl group, triacotyl group and the like alkyl group; cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group and the like cycloalkyl group Aryl groups such as phenyl, tolyl and naphthyl groups; aralkyl groups such as benzyl, phenethyl and β-phenylpropyl groups; alkenyl groups such as vinyl and allyl groups; and carbon atoms of these groups Some or all of the hydrogen atoms are Atoms, chlorine atoms, bromine atoms, iodine atoms) and / or hydrocarbon groups substituted with substituents such as acryloyloxy groups, methacryloyloxy groups, epoxy groups, glycidoxy groups, amino groups, mercapto groups, carboxyl groups, etc. Is mentioned.

  The rubber hardness of the silicone elastomer is preferably 10 or more as measured by a type E durometer as defined in JIS K 6253, and preferably 90 or less as measured by a type A durometer. More preferably, it is 20 or more in the type E durometer and 80 or less in the type A durometer. If it is 10 or more in the type E durometer, the cohesiveness does not become too high, and the feeling of use such as smooth feeling and smoothness and extensibility can be kept good. Moreover, if it is 90 or less with a type A durometer, the soft touch does not become poor.

  The silicone elastomer may be sticky so long as the feeling of use such as smoothness and smoothness and the extensibility are not significantly reduced. The silicone elastomer may contain cosmetically acceptable components such as silicone oil, organosilane, silicone resin, inorganic particles, organic particles, and hydrocarbon liquid oil.

The silicone elastomer is obtained from a curable liquid silicone composition.
The curing reaction includes a condensation reaction between a methoxysilyl group (≡SiOCH ₃ ) and a hydroxysilyl group (≡SiOH), a hydrosilyl group (≡SiH) and a hydroxysilyl group (≡SiOH), a mercaptopropylsilyl group (≡Si— Examples include radical reaction between C ₃ H ₆ SH) and vinylsilyl group (≡SiCH═CH ₂ ) and addition reaction between vinylsilyl group (≡SiCH═CH ₂ ) and hydrosilyl group (≡SiH). From the viewpoint of reactivity, it is preferable to use a condensation reaction or an addition reaction.

For example, when a silicone elastomer is obtained by curing by addition reaction, the following average composition formula (2)
R ² _a R ³ _b SiO _{(4-ab) / 2} (2)
An organopolysiloxane having at least two monovalent olefinically unsaturated groups in one molecule represented by the following average composition formula (3)
R ⁴ _c H _d SiO _{(4-cd) / 2} (3)
The organohydrogenpolysiloxane having at least three hydrogen atoms bonded to silicon atoms in one molecule represented by the formula is such that the hydrosilyl group is 0.5 to 2 per one monovalent olefinically unsaturated group. What is necessary is just to carry out addition polymerization of the curable liquid silicone composition mix | blended by the ratio in presence of a platinum-type catalyst.

Here, in the average composition formula (2), R ² is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms, excluding an aliphatic unsaturated group, and R ³ has 2 to 6 carbon atoms. These are monovalent olefinically unsaturated groups. a and b are positive numbers represented by 0 ≦ a <3, 0 <b ≦ 3, and 0.1 ≦ a + b ≦ 3, and preferably 0 ≦ a ≦ 2.295, 0.005 ≦ b ≦ 2. 3, 0.5 ≦ a + b ≦ 2.3.
In the average composition formula (3), R ⁴ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding an aliphatic unsaturated group. c and d are positive numbers represented by 0 ≦ c <3, 0 <d ≦ 3, 0.1 ≦ c + d ≦ 3, preferably 0 ≦ c ≦ 2.295, 0.005 ≦ d ≦ 2.3. 0.5 ≦ c + d ≦ 2.3.

Examples of R ² include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tetradecyl group, pentadecyl group, hexadecyl group. Group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group, henicosyl group, docosyl group, tricosyl group, tetrasyl group, triacotyl group and the like alkyl group; cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group and the like cycloalkyl group Aryl groups such as phenyl group, tolyl group and naphthyl group; aralkyl groups such as benzyl group, phenethyl group and β-phenylpropyl group; and some or all of hydrogen atoms bonded to carbon atoms of these groups are halogen atoms (Fluorine atom, chlorine atom, bromine atom, iodine source ) Atoms and / or acryloyloxy groups such as, methacryloyloxy group, an epoxy group, glycidoxy group, etc. hydrocarbon group substituted with a substituent such as a carboxyl group. R ² is preferably 80 mol% or more, preferably 90 mol% or more, and is a non-reactive group such as an alkyl group, an aryl group, an aralkyl group, or a cycloalkyl group.
Examples of R ³ include a vinyl group, an allyl group, a butenyl group, a pentenyl group, a hexenyl group, and the like, but industrially a vinyl group is preferable. Examples of R ⁴ are the same as R ² .

Since the kinematic viscosity at 25 ° C. of the organopolysiloxane and organohydrogenpolysiloxane having an olefinically unsaturated group can be obtained efficiently in the following production, 1,000,000 mm ² / S or less is preferable, More preferably, it is 500,000 mm < ² > / s or less.
This kinematic viscosity is a value measured with a capillary viscometer.
In addition, the structure of the organopolysiloxane having an olefinically unsaturated group and the organohydrogenpolysiloxane may be linear, cyclic, or branched.

Examples of the platinum-based catalyst include platinum group metals such as platinum (including platinum black), rhodium, and palladium; H ₂ PtCl ₄ · kH ₂ O, H ₂ PtCl ₆ · kH ₂ O, NaHPtCl ₆ · kH ₂ O, KHPtCl ₆ · kH ₂ O, Na ₂ PtCl ₆ · kH ₂ O, K ₂ PtCl ₄ · kH ₂ O, PtCl ₄ · kH ₂ O, PtCl ₂ , Na ₂ HPtCl ₄ · kH ₂ O (where, k Is an integer from 0 to 6, preferably 0 or 6), such as platinum chloride, chloroplatinic acid and chloroplatinate; alcohol-modified chloroplatinic acid (see US Pat. No. 3,220,972) A complex of chloroplatinic acid and an olefin (see US Pat. Nos. 3,159,601, 3,159,662, and 3,775,452); A platinum group metal such as palladium supported on alumina, silica, carbon or the like; rhodium-olefin complex; chlorotris (triphenylphosphine) rhodium (Wilkinson catalyst); platinum chloride, chloroplatinic acid or chloroplatinate And a vinyl group-containing siloxane, in particular, a vinyl group-containing siloxane complex.

  For example, when a silicone elastomer is obtained by curing by a condensation reaction, an organopolysiloxane having at least two hydroxyl groups bonded to silicon atoms in one molecule and at least three hydrogen atoms bonded to silicon atoms in one molecule. What is necessary is just to carry out condensation polymerization of the liquid silicone composition consisting of the organohydrogenpolysiloxane having in the presence of a condensation catalyst.

In the present invention, a silicone elastomer is preferably used as the aqueous dispersion.
The method for preparing the aqueous dispersion of the silicone elastomer is not particularly limited, and a known method for preparing the aqueous dispersion of the silicone elastomer is used. For example, it can be produced by emulsifying a curable liquid silicone composition in water using a surfactant and then causing a curing reaction. For example, when a silicone elastomer is obtained by curing by an addition reaction, a surfactant and water are added to the curable liquid silicone composition comprising an organopolysiloxane having an olefinically unsaturated group and an organohydrogenpolysiloxane. There is a method of emulsifying and making an emulsion and then adding a platinum-based catalyst to carry out addition polymerization.

Moreover, the method of using the curable liquid silicone composition manufactured by emulsion polymerization as another method is mentioned. For example, when a silicone elastomer is obtained by curing by a condensation reaction, the general formula [R ⁵ ₂ SiO] _m (R ⁵ is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms, m is a number of 3 to 7). ) Is added to the cyclopolysiloxane to emulsify, and then acid is added to cause the polymerization reaction, followed by neutralization by addition of alkali, An emulsion of organopolysiloxane containing a hydroxyl group bonded to a silicon atom at the end is prepared. A method in which an organotrialkoxysilane and a condensation catalyst are added to this and subjected to condensation polymerization can be mentioned.

  The surfactant used for emulsification of the curable liquid silicone composition is not particularly limited. For example, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkylphenyl ether, polyethylene glycol fatty acid ester, Sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbit fatty acid ester, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene Castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester Polyoxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyethylene alkylamine, alkyl alkanolamide, sucrose fatty acid ester, methyl glucoside fatty acid ester, alkyl polyglycoside, Linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene-modified organopolysiloxane, polyoxyethylene / alkyl co-modified organopolysiloxane, linear or branched polyoxyethylene polyoxy Propylene / alkyl co-modified organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, linear or Nonionic surfactants such as branched polyglycerin / alkyl co-modified organopolysiloxanes; alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkylphenyl ether sulfates, fatty acid alkylolamide sulfuric acid Ester salt, alkylbenzene sulfonate, polyoxyethylene alkyl phenyl ether sulfonate, α-olefin sulfonate, α-sulfo fatty acid ester salt, alkyl naphthalene sulfonic acid, alkyl diphenyl ether disulfonate, alkane sulfonate, N- Acyl taurate, dialkyl sulfosuccinate, monoalkyl sulfosuccinate, polyoxyethylene alkyl ether sulfosuccinate, fatty acid salt, polyoxyethylene alkyl ether Anionic surfactants such as alkyl carboxylate, N-acyl amino acid salt, monoalkyl phosphate salt, dialkyl phosphate salt, polyoxyethylene alkyl ether phosphate salt; alkyltrimethylammonium salt, dialkyldimethylammonium salt, Polyoxyethylene alkyldimethylammonium salt, dipolyoxyethylenealkylmethylammonium salt, tripolyoxyethylenealkylammonium salt, alkylbenzyldimethylammonium salt, alkylpyridium salt, monoalkylamine salt, dialkylamine salt, trialkylamine salt, mono Cationic surfactants such as alkylamidoamine salts; alkyldimethylamine oxide, alkyldimethylcarboxybetaine, alkylamidopropyl dimethylcal Examples thereof include amphoteric surfactants such as boxybetaine, alkylhydroxysulfobetaine, and alkylcarboxymethylhydroxyethylimidazolinium betaine.

  These surfactants can be used individually by 1 type or in combination of 2 or more types as appropriate. Preferably, it is selected from nonionic surfactants. The amount of the surfactant used is preferably in the range of 0.1 to 50 parts by mass with respect to 100 parts by mass of the curable liquid silicone composition.

  When emulsifying, a general emulsifying disperser may be used. Examples thereof include a high-speed rotary centrifugal type agitator such as a homodisper; a high-speed rotary shear type agitator such as a homomixer; and a high-pressure jet type such as a homogenizer. Emulsifying and dispersing machine; colloid mill; ultrasonic emulsifying machine and the like.

[Silicone resin]
In the present invention, a silicone resin is used as a binder between inorganic powder and silicone elastomer. By using a silicone resin as a binder, composite particles made by attaching a silicone elastomer to the surface of an inorganic powder make the silicone elastomer adhere to the surface of the inorganic powder, making it difficult for it to fall off the surface of the powder. It becomes possible to improve the uniformity of the film and give a better feeling of use. The silicone resin may be partially or entirely attached to the inorganic powder surface and / or the silicone elastomer surface.

The silicone resin in the present invention is selected from [R ⁶ SiO _3/2 ], [R ⁶ ₂ SiO _2/2 ], [R ⁶ ₃ SiO _1/2 ] and [SiO _4/2 ], and at least [R ⁶ It is a polymer comprising one or more structural units containing [SiO _3/2 ] or [SiO _4/2 ]. Here, R < ⁶ > is a C1-C20 monovalent organic group each independently. By the method described later, a silicone resin is produced by hydrolysis / condensation reaction of a compound selected from alkoxysilane, silanol group-containing silane and these partial condensates, but the silanol group remains without partial condensation reaction. Precisely, it is a copolymer including those selected from the following structural units containing silanol groups.

_{Unless it} is a structure containing [R ⁶ SiO _3/2 ] or [SiO _4/2 ], it cannot be a resinous solid. If the structural unit contains at least [R ⁶ SiO _3/2 ] or [SiO _4/2 ], is a resin-like solid at room temperature and is insoluble in an oil used in cosmetics as described below, The ratio, the degree of polymerization, and the hardness are not particularly limited. However, when the melting point is low, the composite particles are fused with each other during storage in a high-temperature atmosphere or in the drying step. Therefore, the melting point is preferably 50 ° C. or higher, more preferably 80 ° C. or higher. Since there is a decrease in slipperiness when there are many [SiO _4/2 ] units, it is selected from [R ⁶ SiO _3/2 ], [R ⁶ ₂ SiO _2/2 ] and [R ⁶ ₃ SiO _1/2 ], ^[R 6 _{SiO 3/2]} one or polymer is preferably composed of two or more structural units containing, structure preferably further 50 mol% or more ^[R 6 _{SiO 3/2]} units, more preferably It is 70 mol% or more.

R ⁶ in the above formula is, for example, methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, Alkyl groups such as tetradecyl group, pentadecyl group, hexadecyl group, heptadecyl group, octadecyl group, nonadecyl group, eicosyl group; cycloalkyl groups such as cyclobutyl group, cyclopentyl group, cyclohexyl group, cycloheptyl group; phenyl group, tolyl group, naphthyl group An aryl group such as a group; an aralkyl group such as a benzyl group, a phenethyl group or a β-phenylpropyl group; an alkenyl group such as a vinyl group or an allyl group; and a part or all of hydrogen atoms bonded to carbon atoms of these groups Sources such as halogen atoms (fluorine atoms, chlorine atoms, bromine atoms, iodine atoms) And / or acryloyloxy group, methacryloyloxy group, an epoxy group, glycidoxy group, an amino group, a mercapto group, such as a hydrocarbon group substituted with a substituent such as a carboxyl group. By the method described later, a resinous silicone is produced by hydrolysis / condensation reaction of a compound selected from alkoxysilane, silanol group-containing silane, and partial condensates thereof. From the viewpoint of the condensation reactivity, R ⁶ is 50. It is preferable that mol% or more is a methyl group, and more preferably 70 mol% or more.

  The amount of the silicone resin is not particularly limited, but is preferably 10 parts by mass or more, more preferably 20 parts by mass or more, with respect to 100 parts by mass of the silicone elastomer, from the viewpoint of further improving the uniformity of adhesion due to the silicone elastomer. More preferably, it is 30 parts by mass or more. Further, when the amount of the silicone resin increases, the soft feel of the silicone elastomer may not be exhibited. Moreover, 500 mass parts or less are preferable with respect to 100 mass parts of silicone elastomer, More preferably, it is 300 mass parts or less, More preferably, it is 200 mass parts or less.

II. Production method of composite particles The composite particles in the present invention include an alkoxysilane in a mixed solution in which at least a mixed water dispersion in which an inorganic powder and a silicone elastomer are dispersed, a cationic water-soluble polymer, and an alkaline substance are blended. It can be obtained by adding a compound selected from silanol group-containing silanes and partial condensates thereof to cause hydrolysis / condensation reaction.

[Mixed water dispersion in which inorganic powder and silicone elastomer are dispersed]
The mixed water dispersion in which the inorganic powder and the silicone elastomer are dispersed can be obtained, for example, by mixing inorganic powder, a dispersion of the silicone elastomer, and water as necessary.

  3-150 mass parts is preferable with respect to 100 mass parts of water mix | blended, and, as for inorganic powder, 5-50 mass parts is more preferable. If it is 3 parts by mass or more, the production efficiency is also good, and if it is 150 parts by mass or less, the viscosity of the mixed water dispersion does not become too high, and the silicone elastomer is easily adhered to the inorganic powder. As the inorganic powder, one prepared in advance in an aqueous dispersion may be used.

  The method for producing the silicone elastomer is not particularly limited, but it is preferable to use one produced in the form of the aqueous dispersion. A preferable blending amount is as described above.

[Cationic water-soluble polymer]
In the present invention, a cationic water-soluble polymer is blended in a mixed water dispersion in which inorganic powder and silicone elastomer are dispersed. If a cationic water-soluble polymer is used, the polymer will help the silicone elastomer adsorb to the inorganic powder, and the silicone elastomer will adhere uniformly to the surface of the inorganic powder without agglomerating the silicone elastomer. Can do.

  Here, the cationic water-soluble polymer is a water-soluble polymer having a cationic group in the molecule, and the cationic group is specifically a quaternary ammonium salt or an amino group. The cationic water-soluble polymer used in the present invention is not particularly limited, but a synthetic system in which the polymer skeleton is synthesized by vinyl polymerization, addition polymerization, condensation or the like is preferable. Moreover, what does not contain an anionic group and an amphoteric group is preferable. The average molecular weight is 5,000 to 10,000,000, preferably 10,000 to 1,000,000.

  Examples of cationic water-soluble polymers include dimethyldiallylammonium chloride / polymer, dimethyldiallylammonium chloride / acrylamide copolymer, dimethyldiallylammonium chloride / vinylimidazoline / vinylpyrrolidone copolymer, and vinylimidazoline polymer. , Methyl vinyl imidazolium chloride polymer, methyl vinyl imidazolium chloride / vinyl pyrrolidone copolymer, methyl vinyl imidazolium methyl sulfate / vinyl pyrrolidone / vinyl caprolactam copolymer, methyl vinyl imidazolium chloride / vinyl imidazoline / vinyl Pyrrolidone / methacrylic acid amide copolymer, ethyl trimethylammonium acrylate polymer, ethyl acrylate trimethyl Ammonium chloride / vinyl pyrrolidone copolymer, ethyltrimethylammonium acrylate chloride / acrylamide copolymer, ethyltrimethylammonium methacrylate polymer, ethyltrimethylammonium methacrylate methylsulfate / acrylamide copolymer, ethyl methacrylate Copolymer of trimethylammonium chloride / methyl methacrylate, ethyltrimethylammonium methacrylate / dimethylacrylamide / polyethylene glycol dimethacrylate, ethyltrimethylammonium methacrylate / acrylamidopropyltrimethylammonium chloride / dimethylacrylamide Coalescence, ethyl trimethylammonium methacrylate Copolymer of rhoride / acrylamidopropyltrimethylammonium chloride / dimethylacrylamide / hydroxyethyl methacrylate, polymer of acrylamidepropyltrimethylammonium chloride, copolymer of acrylamidepropyltrimethylammonium chloride / acrylamide, acrylamidepropyltrimethylammonium chloride / dimethylacrylamide / Copolymer of hydroxyethyl methacrylate, polymer of methacrylamide propyl trimethyl ammonium chloride, copolymer of methacrylamide propyl trimethyl ammonium chloride / vinyl pyrrolidone, ethylene imine polymer, quaternized product of ethylene imine polymer, allylamine Examples include hydrochloride polymers and polylysine. These can be used individually by 1 type or in combination of 2 or more types.

Among these, those that do not use a monomer having a nonionic group are preferable. For example, a polymer of dimethyldiallylammonium chloride, a polymer of vinylimidazoline, a polymer of methylvinylimidazolium chloride, an ethyltrimethylammonium acrylate chloride, and the like. Polymer, ethyltrimethylammonium methacrylate polymer, acrylamidepropyltrimethylammonium chloride polymer, methacrylamidopropyltrimethylammonium chloride polymer, ethyleneimine polymer, quaternized ethyleneimine polymer, allylamine hydrochloride It is selected from a salt polymer, polylysine and the like.
Particularly preferred is a polymer of dimethyldiallylammonium chloride.

  The cationic water-soluble polymer may be blended as it is in the mixed water dispersion in which the inorganic powder and the silicone elastomer are dispersed, or may be blended as an aqueous solution. Further, the blending order is not particularly limited, and the inorganic water and the silicone elastomer mixed water dispersion may be added after the cationic water-soluble polymer is blended and dissolved in water first.

  The amount of the cationic water-soluble polymer to be blended is preferably 0.0001 to 1 part by mass with respect to 100 parts by mass of water in the mixed water dispersion. When the blending amount is 0.0001 parts by mass to 1 part by mass, the silicone elastomer adhering to the surface of the inorganic powder can be made more uniform, and the adhesion state is also improved. More preferably, it is the range of 0.001-0.1 mass part.

[Alkaline substances]
The alkaline substance is a catalyst for hydrolysis / condensation reaction of alkoxysilane, silanol group-containing silane, and partial condensates thereof.
The alkaline substance is preferably added to water in which the inorganic powder and the silicone elastomer are dispersed and the cationic water-soluble polymer is dissolved, but the blending order is not particularly limited, and the alkaline substance is first dissolved in water. After that, other components may be blended, or after adding a part of the other components, an alkaline substance may be added, and the remaining components may be added sequentially.

  The blending amount of the alkaline substance is preferably such that the pH of the mixed liquid of at least the alkaline substance and the mixed aqueous dispersion in which the inorganic powder and the silicone elastomer are dispersed is 10.0 to 13.0, more preferably 10. The amount is in the range of 5 to 12.5. When an alkaline substance in an amount such that the pH is 10.0 to 13.0 is added, the hydrolysis / condensation reaction of a compound selected from the alkoxysilanes, silanol group-containing silanes described below, and partial condensates thereof is sufficient. Become.

The alkaline substance is not particularly limited, and examples thereof include alkali metal hydroxides such as potassium hydroxide, sodium hydroxide and lithium hydroxide; alkaline earth metal hydroxides such as calcium hydroxide and barium hydroxide; potassium carbonate and carbonate Alkali metal carbonates such as sodium; ammonia; tetraalkylammonium hydroxides such as tetramethylammonium hydroxide and tetraethylammonium hydroxide; or monomethylamine, monoethylamine, monopropylamine, monobutylamine, monopentylamine, dimethylamine, diethylamine Further, amines such as trimethylamine, triethanolamine and ethylenediamine can be used.
Among them, ammonia is most suitable because it can be easily removed from the resulting silicone fine particle powder by volatilization. As ammonia, a commercially available aqueous ammonia solution can be used.

[Alkoxysilane, silanol group-containing silane, and partial condensates thereof]
In the present invention, an alkoxysilane, a silanol group-containing silane, and a portion thereof are further added to a mixed solution in which an inorganic powder and a silicone elastomer are dispersed, a mixture of a cationic water-soluble polymer, and an alkaline substance. A compound selected from condensates is added.
Alkoxysilanes, silanol group-containing silanes, and partial condensates thereof are hydrolyzed and condensed by the catalytic action of the above-mentioned alkaline substance to form resinous silicone.

Alkoxysilane is represented by the general formula R ⁶ Si (OR ⁷ ) ₃ , R ⁶ ₂ Si (OR ⁷ ) ₂ , R ⁶ ₃ SiOR ⁷ and Si (OR ⁷ ) ₄ . R ⁶ in the formula is the same as described above, R ⁷ is an unsubstituted monovalent hydrocarbon group having 1 to 6 carbon atoms, and R ⁷ includes a methyl group, an ethyl group, a propyl group, a butyl group, A pentyl group and a hexyl group are exemplified, and a methyl group is preferable from the viewpoint of reactivity. Alkoxysilane R ⁶ Si (OR ⁷ ) ₃ , R ⁶ ₂ Si (OR ⁷ ) ₂ , R ⁶ ₃ SiOR ⁷ , and Si (OR ⁷ ) ₄ are each a structural unit of resin-like silicone [R ⁶ SiO _3/2. ], [R ⁶ ₂ SiO _2/2 ], [R ⁶ ₃ SiO _1/2 ], [SiO _4/2 ]. Therefore, the blending ratio of R ⁶ Si (OR ⁷ ) ₃ , R ⁶ ₂ Si (OR ⁷ ) ₂ , R ⁶ ₃ SiOR ⁷ , Si (OR ⁷ ) ₄ is set to a desired resinous silicone structure. Just decide. That is, in a molar ratio, the desired structural unit [R ⁶ SiO _3/2 ]: [R ⁶ ₂ SiO _2/2 ]: [R ⁶ ₃ SiO _1/2 ]: [SiO _4/2 ] = R ⁶ Si (OR ⁷ ) ₃ , R ⁶ ₂ Si (OR ⁷ ) ₂ , R ⁶ ₃ SiOR ⁷ , Si (OR ⁷ ) ₄ may be used.

A silanol group-containing silane is a compound in which R ^{7 in} the general formula of the alkoxysilane is hydrogen. What is necessary is just to select suitably from an alkoxysilane, silanol group containing silane, and these condensates so that it may become a desired structural unit.

  While stirring the mixed water containing inorganic powder, silicone elastomer, cationic water-soluble polymer, and alkaline substance, a compound selected from alkoxysilane, silanol group-containing silane, and partial condensates thereof is added to the hydrolysis / Allow condensation reaction. Compounds selected from alkoxysilanes, silanol group-containing silanes and partial condensates thereof may be gradually added dropwise, or may be added in a form dissolved in water or dispersed in water, You may add what mix | blended water-soluble organic solvents, such as alcohol.

  Stirring may cause aggregation of inorganic particles when strong stirring is performed, so it is preferable to use paddle blades, propeller blades, swept blades, saddle blades, etc., but it is preferable to use inorganic powder, alkoxysilane, silanol group The stirring intensity | strength in which the compound chosen from containing silane and these partial condensates is disperse | distributed in a liquid mixture is required.

  The temperature at which a compound selected from alkoxysilane, silanol group-containing silane and partial condensates thereof is added to the mixed solution is preferably 0 to 60 ° C, more preferably 0 to 39 ° C. If this temperature is 0 ° C. or higher, the mixed solution does not solidify, and if it is 60 ° C. or lower, the obtained particles do not aggregate.

  Resin-like silicone is formed on the surface of the inorganic powder and / or the surface of the silicone elastomer by the hydrolysis / condensation reaction. At the same time, the inorganic powder and the silicone elastomer adhere to each other. Composite particles to which a silicone elastomer is adhered are formed using a silicone-like binder.

  For the purpose of uniformly adhering the silicone elastomer to the surface of the inorganic powder, a water-soluble organic solvent such as alcohol may be added to the mixed solution. When the particles are surface-treated with a silylating agent, the finished composite particles may be treated, but a compound selected from the above alkoxysilanes, silanol group-containing silanes and partial condensates thereof is added to the mixture. Then, a silylating agent may be added and treated. Examples of the silylating agent include dimethyldichlorosilane, trimethylchlorosilane, trimethylmethoxysilane, trimethylsilanol group-containing silane, hexamethyldisilazane, and the like.

  It is preferable to continue stirring for a while after completion of the addition of a compound selected from alkoxysilane, silanol group-containing silane and partial condensates thereof until the hydrolysis / condensation reaction is completed. In order to accelerate the reaction, heating may be performed at 40 to 100 ° C., or an alkaline substance may be added. Thereafter, if necessary, an acidic substance may be added for neutralization.

[Powdering]
After the hydrolysis / condensation reaction, water is removed. The removal of water can be performed, for example, by heating the mixed solution after the reaction under normal pressure or reduced pressure, and specifically, a method of removing water by leaving the mixed solution standing under heating, mixing Examples thereof include a method of removing moisture while stirring and flowing the liquid under heating, a method of spraying and dispersing the mixed liquid in a hot air stream like a spray dryer, and a method of using a fluidized heat medium.

In addition, as a pretreatment of this operation, the mixed solution may be concentrated by a method such as filtration separation such as heat dehydration and pressure filtration, centrifugation, decantation, etc. You may wash.
When the powder obtained by removing water from the mixed solution after the reaction is agglomerated, it may be crushed or classified by a pulverizer such as a jet mill, a ball mill, or a hammer mill.

  The composite particles in the present invention are particles obtained by attaching a silicone elastomer to a surface of an inorganic powder using a silicone resin as a binder. For the purpose of imparting and improving water repellency and improving dispersibility in an oil agent, The surface may be treated with a silylating agent, silicone oil, waxes, paraffins, organic fluorine compounds, surfactants and the like.

III. Method for Producing Cosmetics Using Composite Particles In the method for producing cosmetics of the present invention, composite particles produced by the above method, wherein the silicone elastomer is adhered to the surface of the inorganic powder using a silicone resin as a binder ( Hereinafter, a cosmetic is produced using (A).
More specifically, a desired cosmetic is produced by mixing, emulsifying, and the like using the composite particles (A) and other various cosmetic ingredients described below.

IV. Cosmetics containing composite particles The cosmetic of the present invention is characterized by containing composite particles (A). The compounding ratio of the composite particles (A) is not particularly limited, and is appropriately selected in the range of 0.1 to 95.0% by mass with respect to the whole cosmetics according to each preparation.

  In addition to the composite particles (A), various components used in normal cosmetics can be blended in the cosmetic of the present invention. Examples of the components include (B) oil agent, (C) water, (D) a compound having an alcoholic hydroxyl group, (E) a water-soluble or water-swellable polymer compound, and (F) particles other than the composite particles in the present invention. , (G) a surfactant, (H) a composition comprising a cross-linked organopolysiloxane and a liquid oil at room temperature, (I) a silicone resin, (J) a silicone wax, and other additives. These can be used individually by 1 type or in combination of 2 or more types.

(B) The oil agent may be solid, semi-solid, or liquid. For example, natural animal and vegetable oils and fats, semi-synthetic oils and fats, hydrocarbon oils, higher alcohols, ester oils, silicone oils, and fluorine oils are used. can do.
Natural animal and plant oils and semi-synthetic oils and fats include avocado oil, linseed oil, almond oil, ibotarou, eno oil, olive oil, cacao butter, kapok wax, kaya oil, carnauba wax, liver oil, candelilla wax, refined candelilla wax, beef tallow, Beef leg fat, beef bone fat, hydrogenated beef fat, kyounin oil, whale wax, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugar cane wax, sasanqua oil, safflower oil, shea butter, cinnamon oil, cinnamon Oil, jojoba wax, squalane, squalene, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil, nukarou, germ oil, horse fat, persic oil , Palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid methyl ester, sunflower oil, grape oil Bayberry wax, jojoba oil, macadamia nut oil, beeswax, mink oil, meadow foam oil, cottonseed oil, cotton wax, owl, owl kernel oil, montan wax, coconut oil, hydrogenated coconut oil, tricoconut oil fatty acid glyceride, sheep fat, peanut oil, lanolin, Liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin acetate alcohol, lanolin fatty acid isopropyl, polyoxyethylene lanolin alcohol ether, polyoxyethylene lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, polyoxyethylene hydrogenated lanolin alcohol ether And egg yolk oil.

  Examples of the hydrocarbon oil include linear or branched hydrocarbon oils, which may be volatile hydrocarbon oils or non-volatile hydrocarbon oils. Specifically, ozokerite, α-olefin oligomer, light isoparaffin, isododecane, isohexadecane, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, squalene, ceresin, paraffin, paraffin wax, polyethylene wax, polyethylene / polypropylene wax, (Ethylene / propylene / styrene) copolymer, (butylene / propylene / styrene) copolymer, liquid paraffin, liquid isoparaffin, pristane, polyisobutylene, hydrogenated polyisobutene, microcrystalline wax, petrolatum, etc .; As higher fatty acids, lauric acid, myristic acid , Palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosa Ntaen acid (EPA), docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid.

  Examples of the higher alcohol include alcohols having preferably 6 or more carbon atoms, more preferably 10 to 30 carbon atoms. Specific examples of higher alcohols include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyl decanol, octyl dodecanol, cetostearyl alcohol, 2-decyltetra alcohol Examples include decinol, cholesterol, phytosterol, polyoxyethylene cholesterol ether, monostearyl glycerol ether (batyl alcohol), monooleyl glyceryl ether (ceralkyl alcohol), and the like.

  Ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, di-2-ethyl Ethylene glycol hexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate Decyl oleate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyrate , Isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isononyl isononanoate, isotridecyl isononanoate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyl palmitate Decyl, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, laurin Acid ethyl, hexyl laurate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, lauroyl sarcosine iso Lopyl ester, diisostearyl malate, etc .; acetoglyceryl, glyceryl triisooctanoate, glyceryl triisostearate, glyceryl triisopalmitate, glyceryl tribehenate, glyceryl monostearate, glyceryl di-2-heptylundecanoate, glyceryl trimyristate And glyceride oils such as diglyceryl myristate isostearate.

  Silicone oils include dimethylpolysiloxane, tristrimethylsiloxymethylsilane, caprylylmethicone, phenyltrimethicone, tetrakistrimethylsiloxysilane, methylphenylpolysiloxane, methylhexylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane / methylphenylsiloxane Low to high viscosity linear or branched organopolysiloxanes such as copolymers, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, tetramethyl Cyclic organopolysiloxanes such as tetraphenylcyclotetrasiloxane, amino-modified organopolysiloxanes, pyrrolidone-modified ol Silicone rubber such as nopolysiloxane, pyrrolidone carboxylic acid modified organopolysiloxane, high degree of gummed dimethylpolysiloxane, gummed amino modified organopolysiloxane, gummed dimethylsiloxane / methylphenylsiloxane copolymer, and silicone gum Cyclic organopolysiloxane solution of rubber and rubber, trimethylsiloxysilicic acid, cyclic siloxane solution of trimethylsiloxysilicic acid, higher alkoxy modified silicone such as stearoxy silicone, higher fatty acid modified silicone, alkyl modified silicone, long chain alkyl modified silicone, amino acid modified Examples include silicone, fluorine-modified silicone, silicone resin, and dissolved silicone resin.

Examples of the fluorinated oil include perfluoropolyether, perfluorodecalin, and perfluorooctane.
(B) The compounding quantity of an oil agent is suitably selected from the range of 1-98 mass% of the whole cosmetics depending on the dosage form of cosmetics.

  (C) Although the compounding quantity of water is dependent on the dosage form of cosmetics, it is suitably selected from 1-95 mass% of the whole cosmetics.

  (D) Examples of the compound having an alcoholic hydroxyl group include ethanol, isopropanol and the like, preferably lower alcohols having 2 to 5 carbon atoms; sugar alcohols such as sorbitol and maltose. Moreover, sterols, such as cholesterol, sitosterol, phytosterol, lanosterol; polyhydric alcohols, such as butylene glycol, propylene glycol, dibutylene glycol, pentylene glycol, etc. are mentioned. As a compounding quantity, it selects from the range of 0.1-98 mass% of the whole cosmetics suitably.

  (E) Examples of water-soluble or water-swellable polymer compounds include gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), starch (rice, corn, potato, wheat, etc. ), Plant polymer compounds such as algae colloid, Trant gum, locust bean gum; microbial polymer compounds such as xanthan gum, dextran, succinoglucan, pullulan; animal polymer compounds such as collagen, casein, albumin, gelatin; Starch polymers such as carboxymethyl starch and methylhydroxypropyl starch; methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose Cellulose, hydroxypropylcellulose, nitrocellulose, cellulose sodium sulfate, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder cellulosic polymer compounds; alginic acid polymer compounds such as sodium alginate and propylene glycol alginate; polyvinyl methyl ether, carboxyvinyl Vinyl polymer compounds such as polymers; acrylics such as polyoxyethylene polymer compounds, polyoxyethylene polyoxypropylene copolymer polymer compounds, sodium polyacrylate, polyethyl acrylate, polyacrylamide, and acryloyldimethyltaurine salt copolymers Polymer compounds; polyethyleneimine, other synthetic water-soluble polymer compounds such as cationic polymers, bentonite, aluminum silicate Um magnesium, montmorillonite, beidellite, nontronite, saponite, hectorite, and inorganic-based water-soluble polymer compound such as silicic anhydride. These water-soluble polymer compounds also include film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone. As a compounding quantity, the range of 0.1-25 mass% of the whole cosmetics is suitable.

(F) Examples of the particles other than the composite particles in the present invention include inorganic particles, organic particles, inorganic / organic composite powders, and silicone resin particles.
Examples of inorganic particles include titanium oxide, mica titanium, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, cleaved talc, mica, kaolin, seric Sight, muscovite, synthetic mica, phlogopite, sauroite, biotite, lithia mica, silicic acid, silicon dioxide, fumed silica, hydrous silicon dioxide, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate , Barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramics, dicalcium phosphate, alumina, hydroxide Aluminum, boron nitride, nitride boron, include microparticles made of glass or the like.

Examples of the inorganic particles include pigment-based inorganic fine particles. Specific examples include inorganic red pigments such as iron oxide, iron hydroxide, and iron titanate; inorganic brown pigments such as γ-iron oxide. Inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide and carbon black; inorganic purple pigments such as manganese violet and cobalt violet; chromium hydroxide, chromium oxide, cobalt oxide and titanic acid Inorganic green pigments such as cobalt; Inorganic blue pigments such as bitumen and ultramarine blue; Colored pigments such as tar-type pigments raked and natural pigments raked; titanium oxide-coated mica, bismuth oxychloride, titanium oxide Examples thereof include pearl pigments such as coated bismuth oxychloride, titanium oxide coated talc, fish scale foil, and titanium oxide coated colored mica.
Furthermore, examples of the inorganic particles include metal fine particles made of aluminum, copper, stainless steel, silver or the like.

  Examples of the organic particles include polyamide, polyacrylic acid / acrylic ester, polyester, polyethylene, polypropylene, polystyrene, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, polyurethane, vinyl resin, urea resin, melamine Examples thereof include powders made of resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethyl methacrylate (for example, polymethyl methacrylate), cellulose, silk, nylon, phenol resin, epoxy resin, polycarbonate, and the like.

  Examples of the organic particles include surfactant metal salt powder (metal soap). Specific examples include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, myristic acid. Examples thereof include powder made of magnesium, zinc cetyl phosphate, calcium cetyl phosphate, sodium cetyl phosphate, and the like.

  Further, examples of the organic particles include organic dyes. Specific examples include red No. 3, red No. 104, red No. 106, red No. 201, red No. 202, red No. 204, red No. 205, red 220, Red 226, Red 227, Red 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401 , Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 404, Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange Tar pigments such as No. 207; natural pigments such as carminic acid, laccaic acid, calsamine, bradylin and crocin.

  Examples of the inorganic / organic composite powder include composite powder in which a general-purpose inorganic powder surface is coated with an organic powder by a publicly known method.

  Examples of the silicone resin particles include silicone elastomer particles, polymethylsilsesquioxane particles (specific examples: manufactured by Shin-Etsu Chemical Co., Ltd .: KMP-590, 591, etc.), and the surface of the silicone elastomer particles is made of polymethylsilsesquioxane. Particles formed by coating (specific examples include KSP-100, 101, 102, 105, 300, 411, 441, etc.).

  Particles other than the composite particles in the present invention have a particle surface of silanes such as caprylsilane (manufactured by Shin-Etsu Chemical Co., Ltd .: AES-3083) or a silylating agent, dimethyl silicone (manufactured by Shin-Etsu Chemical Co., Ltd .: KF-96AK series). , Silicone oils and waxes such as methyl hydrogen type polysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd .: KF-99P, KF-9901, etc.), silicone branched type silicone treating agent (Shin-Etsu Chemical Industrial Co., Ltd .: KF-9908, KF-9909, etc.) , Paraffins, and perfluoroalkyl treated with organic fluorine compounds such as phosphates, surfactants, amino acids such as N-acylglutamic acid, metal soaps such as aluminum stearate and magnesium myristate, and the like can also be used. The blending amount is not particularly limited, and may be close to 100% of the entire cosmetic.

  (G) As the surfactant, there are nonionic, anionic, cationic and amphoteric active agents, and the same ones as those used for the production of the composite particles in the present invention described above are exemplified. Among these surfactants, linear or branched polyoxyethylene-modified organopolysiloxane, linear or branched polyoxyethylene polyoxypropylene-modified organopolysiloxane, linear or branched polyoxyethylene / alkyl co-modified organo Polysiloxane, linear or branched polyoxyethylene polyoxypropylene / alkyl co-modified organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, linear or branched polyglycerin / alkyl co-modified organopolysiloxane It is preferable. In these surfactants, the content of the hydrophilic polyoxyethylene group, polyoxyethylene polyoxypropylene group or polyglycerin residue preferably occupies 10 to 70% by mass in the molecule. Specific examples include Shin-Etsu Chemical Co., Ltd .: KF-6011, 6043, 6028, 6038, 6100, 6104, 6105 and the like. As a compounding quantity, 0.1-20 mass% of the whole cosmetics is preferable, More preferably, it is the range of 0.2-10 mass%. The HLB of the surfactant is not limited, but is preferably 2 to 14.5.

(H) In a composition comprising a cross-linked organopolysiloxane and a liquid oil at room temperature, the cross-linked organopolysiloxane preferably swells with the liquid oil containing its own weight or more with respect to the liquid oil. As the liquid oil, fluorinated oils such as liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, etc. in the component (B) can be used. For example, 0.65 mm ² / s ( 25 ° C.) to 100 mm ² / s (25 ° C.) low viscosity silicone oil, liquid paraffin, squalane, isododecane, isohexadecane and other hydrocarbon oils, glyceride oil such as trioctanoin, isononanoic acid isotridecyl, N-acyl glutamic acid ester And natural animal and vegetable oils such as ester oils such as lauroyl sarcosine and macadamia nut oils. In addition, the crosslinking agent of this crosslinkable organopolysiloxane forms a crosslinked structure by reacting with hydrogen atoms that have two or more vinylic reactive sites in the molecule and are directly bonded to silicon atoms. It is preferable to do. Those having two or more vinyl reactive sites in the molecule include organopolysiloxanes having two or more vinyl groups in the molecule, polyoxyalkylenes having two or more allyl groups in the molecule, Examples include polyglycerin having two or more allyl groups, α, ω-alkenyl diene, and the like. Also, a crosslinked organopolysiloxane containing at least one selected from the group consisting of a polyoxyalkylene moiety, a polyglycerin moiety, a long-chain alkyl moiety, an alkenyl moiety, an aryl moiety, and a fluoroalkyl moiety in the crosslinking molecule is used. You can also As specific examples, manufactured by Shin-Etsu Chemical Co., Ltd .: KSG series (trade name), in particular, KSG-15, 16, 41, 42, 43, 44, 042Z, 045Z, KSG-210, 710, 310, 320, 330, 340 320Z, 350Z, 810, 820, 830, 840, 820Z, 850Z and the like. As a compounding quantity in the case of using the composition which consists of a crosslinking | crosslinked organopolysiloxane and a liquid oil at room temperature, 0.1-80 mass% of the whole cosmetics is preferable, More preferably, it is 1-50 mass%.

(I) The silicone resin is preferably an acrylic / silicone graft or block copolymer acrylic silicone resin. An acrylic silicone resin containing in the molecule at least one selected from a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety, and an anion moiety such as carboxylic acid can also be used. Specific examples include Shin-Etsu Chemical Co., Ltd .: cyclic organopolysiloxane solution of acrylic / silicone graft copolymer: KP-545 and the like. Further, this silicone resin includes a resin composed of R ⁸ ₃ SiO _0.5 units and SiO ₂ units, a resin composed of R ⁸ ₃ SiO _0.5 units, R ⁸ ₂ SiO units, and SiO ₂ units, R ⁸ Resin composed of ₃ SiO _0.5 units and R ⁸ SiO _1.5 units, resin composed of R ⁸ ₃ SiO _0.5 units, R ⁸ ₂ SiO units and R ⁸ SiO _1.5 units, R ⁸ _A silicone network compound composed of a resin composed of ₃ SiO _0.5 units, R ⁸ ₂ SiO units, R ⁸ SiO _1.5 units and SiO ₂ units is preferred. R ⁸ in the formula is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms. Specific examples include: Shin-Etsu Chemical Co., Ltd .: cyclic siloxane solution of trimethylsiloxysilicic acid: KF-7312J. In addition, a silicone network compound containing in the molecule at least one selected from a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety, a polyglycerin moiety, a fluoroalkyl moiety, and an amino moiety can also be used. As a compounding quantity when using silicone resins, such as an acrylic silicone resin and a silicone network compound, 0.1-20 mass% of the whole cosmetics is preferable, More preferably, it is 1-10 mass%.

  (J) The silicone wax is preferably an acrylic / silicone graft or block copolymer acrylic silicone resin. An acrylic silicone resin containing in the molecule at least one selected from a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety, and an anion moiety such as carboxylic acid can also be used. Specific examples include Shin-Etsu Chemical Co., Ltd .: acrylic / silicone graft copolymers: KP-561P, 562P, and the like. The silicone wax is preferably a polylactone-modified polysiloxane in which a lactone compound having a 5-membered ring or more is combined with a polylactone that is a ring-opening polymer. Furthermore, this silicone wax is a silicone-modified olefin wax obtained by addition reaction of an olefin wax having an unsaturated group consisting of an α-olefin and a diene and an organohydrogenpolysiloxane having one or more molecules of SiH bond. It is. The α-olefin of the olefin wax preferably has 2 to 12 carbon atoms such as ethylene, propylene, 1-butene, 1-hexene, 4-methyl 1-pentene, and the diene is butadiene, isoprene, 1,4 hexadiene, vinyl. Norbornene, ethylidene norbornene, dicyclopentadiene and the like are preferable. As the organohydrogenpolysiloxane having a SiH bond, a linear or siloxane branched structure can be used. As a compounding quantity in the case of using a silicone wax, 0.1-30 mass% of the whole cosmetics is preferable, More preferably, it is 1-10 mass%.

  Other additives include oil-soluble gelling agents, antiperspirants, UV absorbers, UV absorption scattering agents, moisturizers, antibacterial preservatives, fragrances, salts, antioxidants, pH adjusters, chelating agents, and cooling agents. , Anti-inflammatory agents, skin beautifying agents (whitening agents, cell activators, rough skin improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, hair Solidifying agents and the like.

  Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid and α, γ-di-n-butylamine; dextrin palmitate Dextrin fatty acid esters such as dextrin stearate, dextrin 2-ethylhexanoic acid palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide stearate, 2-ethyl fructooligosaccharide Fructooligosaccharide fatty acid esters such as hexanoic acid ester; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol; dimethylbenzyl dodecyl ammo Examples thereof include organically modified clay minerals such as nitro montmorillonite clay and dimethyl dioctadecyl ammonium montmorillonite clay.

  Antiperspirants include aluminum chlorohydrate, aluminum chloride, aluminum sesquichlorohydrate, zirconyl hydroxychloride, aluminum zirconium hydroxychloride, aluminum zirconium glycine complex and the like.

  Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid; anthranilic acid UV absorbers such as methyl anthranilate; salicylic acid UV absorbers such as methyl salicylate, octyl salicylate and trimethylcyclohexyl salicylate; Cinnamic acid UV absorbers such as octyl cinnamate; Benzophenone UV absorbers such as 2,4-dihydroxybenzophenone; Urocanic acid UV absorbers such as ethyl urocanate; 4-t-butyl-4′-methoxy- Examples include dibenzoylmethane-based ultraviolet absorbers such as dibenzoylmethane; phenylbenzimidazolesulfonic acid, triazine derivatives, etc. Ultraviolet absorbing and scattering agents include particulate titanium oxide, particulate iron-containing titanium oxide, particulate zinc oxide, particulate cerium oxide, and the like. Them Complex etc., include particles that absorb scattering ultraviolet rays can also be used a dispersion obtained by dispersing the particles that absorb scattering these ultraviolet advance oil.

  Moisturizers include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, pentylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxy Examples include ethylene methyl glucoside, polyoxypropylene methyl glucoside, egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipid and the like.

  As an antibacterial preservative, paraoxybenzoic acid alkyl ester, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc., as antibacterial agents, benzoic acid, salicylic acid, carboxylic acid, sorbic acid, paraoxybenzoic acid alkyl ester, Parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, phenoxyethanol and the like can be mentioned.

  As the fragrance, there are natural fragrance and synthetic fragrance. Natural fragrances include plant fragrances isolated from flowers, leaves, materials, fruit skins, etc., and animal fragrances such as musk and sivet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, and esters such as terpene esters. , Lactones, phenols, oxides, nitrogen-containing compounds, acetals and the like.

  Examples of the salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, and the like of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; Salts of organic acids such as dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid and stearic acid; amine salts and amino acid salts include, for example, salts of amines such as triethanolamine, and amino acids such as glutamic acid And the like. In addition, salts such as hyaluronic acid and chondroitin sulfate, aluminum zirconium glycine complexes, and the like, and acid-alkali neutralized salts used in cosmetic formulations can also be used.

  Examples of the antioxidant include tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid and the like, and examples of the pH adjuster include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl- Malic acid, potassium carbonate, sodium hydrogen carbonate, ammonium hydrogen carbonate and the like can be mentioned. Examples of the chelating agent include alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid and the like. -Anti-inflammatory agents such as menthol and camphor include allantoin, glycyrrhizic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene and the like.

  As a skin beautifying component, whitening agents such as placenta extract, arbutin, glutathione, and yukinoshita extract; cell activating agents such as royal jelly, photosensitizer, cholesterol derivative, and calf blood extract; rough skin ameliorating agent; Nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, Examples include blood circulation promoters such as acetylcholine, verapamil, cephalanthin, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; and antiseborrheic agents such as sulfur and thianthol.

As vitamins, vitamin A oil, retinol, retinol acetate, vitamin A such as retinol palmitate; riboflavin, riboflavin butyrate, vitamin B ₂ such as flavin adenine nucleotide, pyridoxine hydrochloride, pyridoxine dioctanoate, Piridokishintori Vitamin B ₆ such as palmitate, vitamin B ₁₂ and derivatives thereof, vitamin B such as vitamin B ₁₅ and derivatives thereof; L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sulfate Vitamin Cs such as sodium and L-ascorbic acid phosphate diester dipotassium; Vitamin Ds such as ergocalciferol and cholecalciferol; α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate Vitamins such as nicotinic acid dl-α-tocopherol and dl-α-tocopherol succinate; nicotinic acids such as nicotinic acid, benzyl nicotinate and nicotinamide; vitamin H, vitamin P, calcium pantothenate, D- Examples include pantothenic acids such as pantothenyl alcohol, pantothenyl ethyl ether, and acetyl pantothenyl ethyl ether, and biotin.

  Examples of amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

Examples of the nucleic acid include deoxyribonucleic acid.
Examples of hormones include estradiol and ethenyl estradiol.
Examples of the inclusion compound include cyclodextrin and the like.

  Examples of hair fixatives include amphoteric, anionic, cationic, and nonionic polymer compounds, such as polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers, polyvinylpyrrolidone polymer compounds, methyl Acid vinyl ether polymer compounds such as vinyl ether / maleic anhydride alkyl half ester copolymers, acid polyvinyl acetate polymer compounds such as vinyl acetate / crotonic acid copolymers, (meth) acrylic acid / alkyl (meth) acrylates Copolymers, acidic acrylic polymer compounds such as (meth) acrylic acid / alkyl (meth) acrylate / alkylacrylamide copolymers, N-methacryloylethyl-N, N-dimethylammonium / α-N-methylcarboxybetaine / Alkyl (meth) acrylate copolymer, hydride Kishipuropiru (meth) acrylate / butylaminoethyl methacrylate / amphoteric acrylic polymer compounds such as acrylic acid octyl amide copolymers. In addition, naturally derived polymer compounds such as cellulose or derivatives thereof, keratin and collagen or derivatives thereof can also be suitably used.

  The cosmetic of the present invention can be applied to various cosmetics. For example, skin care products, makeup products, hair products, antiperspirant products, UV protection products, etc. are mentioned. Skin care cosmetics, makeup cosmetics, antiperspirant cosmetics, UV protection cosmetics, etc. are particularly preferred. Cosmetics for external use, such as cosmetics for external use and hair cosmetics.

  As skin care cosmetics, for example, lotion, milky lotion, cream, cleansing, pack, oil liquid, massage fee, cosmetic liquid, beauty oil, cleaning agent, deodorant, hand cream, lip balm, wrinkle concealment and the like can be mentioned. Examples of the makeup cosmetics include makeup bases, concealers, white powders, powder foundations, liquid foundations, cream foundations, oily foundations, blushers, eye colors, eye shadows, mascaras, eye liners, eyebrows, lipsticks and the like. Examples of antiperspirant cosmetics include roll-on type, cream type, solution type, and stick type. Examples of the UV protection cosmetic include sunscreen oil, sunscreen milky lotion, sunscreen cream and the like. Examples of hair cosmetics include shampoos, rinses, treatments, and set agents.

  Examples of the cosmetic composition of the present invention include powder, oily liquid, water-in-oil emulsion, oil-in-water emulsion, non-water emulsion, W / O / W type, O / W / O type multi-emulsion, etc. Any of these may be used. The properties of the cosmetic of the present invention include liquid, emulsion, cream, solid, paste, gel, powder, press, multilayer, mousse, spray, stick, pencil, etc. Various properties can be selected.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example. In the examples, the viscosity is a value measured at 25 ° C., and “%” representing the concentration and the content rate represents “% by mass”.

[Production Example 1]
(Manufacture of aqueous dispersion of silicone elastomer)
400 g of methyl vinyl polysiloxane having a kinematic viscosity of 4,900 mm ² / s represented by the following formula (4) and 7 g of methyl hydrogen polysiloxane having a kinematic viscosity of 30 mm ² / s represented by the following formula (5) The amount of 1.1 of hydrosilyl groups per vinyl group) was charged into a 1 liter glass beaker and mixed and dissolved using a homomixer. Thereafter, 33 g of polyoxyethylene lauryl ether (trade name: Emulgen 109P, manufactured by Kao Corporation) and 35 g of water were added, and the mixture was further stirred using a homomixer. The thickened material was kneaded for 15 minutes using a homodisper. Next, when 523 g of water was added and mixed using a homomixer, a uniform white emulsion was obtained. This emulsion was transferred to a glass flask having a capacity of 1 liter equipped with a stirrer with a vertical stirring blade, adjusted to a temperature of 15 to 20 ° C., and then stirred with a toluene solution of a chloroplatinic acid-olefin complex (with a platinum content of 0.1%). 5%) 0.6 g, 1.2 g of polyoxyethylene lauryl ether (trade name: Emulgen 109P, manufactured by Kao Corporation) was added and stirred for 24 hours at the same temperature, and an aqueous dispersion of silicone elastomer Got.

It was 280 nm when the volume average particle diameter of the obtained silicone elastomer was measured using "Laser diffraction / scattering type particle size distribution analyzer LA-920" (manufactured by Horiba, Ltd.). The formula (4), the kinematic viscosity is represented by methyl vinyl polysiloxane 4,900mm ² / s, the equation (5), a kinematic viscosity of 30 mm ² / s methylhydrogenpolysiloxane, and platinum chloride A toluene solution of acid-olefin complex (platinum content: 0.5%) is mixed at the above-mentioned blending ratio, poured into an aluminum petri dish so that the thickness becomes 10 mm, left at 25 ° C. for 6 hours, and then a constant temperature bath at 50 ° C. For 1 hour. The obtained cured product was a rubber elastic body without stickiness, and its hardness was 20 as measured by a durometer A hardness meter.

[Production Example 2]
(Production of composite particles 1)
In a glass flask having a capacity of 3 liters equipped with a stirrer with a vertical stirring blade, 120 g of talc particles (trade name: JA-69R, manufactured by Asada Flour Milling Co., Ltd., shape = plate shape, average particle size = 10 μm) and the above 40% dimethyl was added to a mixed water dispersion obtained by mixing 41 g of the silicone elastomer aqueous dispersion obtained in Production Example 1 (an amount of 14 parts by mass of the silicone elastomer with respect to 100 parts by mass of the talc particles) and 1,280 g of water. Diallylammonium chloride polymer aqueous solution (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (amount to be 0.01 parts by mass with respect to 100 parts by mass of water), and 28 30% aqueous ammonia was charged. The pH of the liquid at this time was 11.5. After adjusting the temperature to 5 to 10 ° C., 29 g of methyltrimethoxysilane (an amount in which the silicone resin after hydrolysis and condensation reaction becomes 85 parts by mass with respect to 100 parts by mass of the silicone elastomer) is dropped over 20 minutes. The liquid temperature was kept at 5 to 10 ° C. and further stirred for 1 hour. Subsequently, it heated to 55-60 degreeC, it stirred for 1 hour, maintaining the temperature, and the hydrolysis and condensation reaction of methyltrimethoxysilane was completed. The obtained suspension was dehydrated using a pressure filter. The dehydrated product was transferred to a 3 liter glass flask equipped with a stirrer with a vertical stirring blade, added with 1,000 g of water, stirred for 30 minutes, and then dehydrated using a pressure filter. Again, the dehydrated product was transferred to a glass flask, and the flask was immersed in an oil bath at 110 ° C. and dried with stirring to obtain fluid particles.

  When the obtained particles were observed with an electron microscope, spherical particles of about 300 nm were uniformly attached to the surface of the plate-like particles, and it was a composite particle formed by attaching a silicone elastomer to the surface of the talc particles. confirmed. Moreover, it turned out that resin-like silicone becomes a binder and the silicone elastomer is made to adhere to a talc particle. That is, if there is no binder for attaching the silicone elastomer to the surface of the talc particles, even if the silicone elastomer is attached to the surface of the talc particles, it is considered that the silicone elastomer is detached from the surface of the talc particles by the water washing and drying operation. . When the silicone elastomer falls off, the silicone elastomer has high cohesiveness, and thus it is considered that the particles are aggregated. However, particles having such a shape were not observed with an electron microscope.

  Furthermore, after weighing 20 g of sodium bromide, polyoxyethylene lauryl ether (trade name: Emulgen 109P, Kao (manufactured)) 0.5 g, water 80 g and composite particles 5 g in a 100 mL glass bottle and shaking for 30 minutes, When the silicone elastomer dropped off from the surface of the talc particles, the silicone elastomer floated because the specific gravity was smaller than that of sodium bromide water, but the whole amount had settled. This suggests that the silicone resin becomes a binder and the silicone elastomer is adhered to the talc particles.

[Production Example 3]
(Production of composite particles 2)
In a glass flask having a capacity of 3 liters equipped with a stirrer with a vertical stirring blade, 120 g of mica particles (trade name: Y-2300X, manufactured by Yamaguchi Mica Co., Ltd., shape = plate shape, average particle size = 19 μm) and the above 40% dimethyl was added to a mixed water dispersion obtained by mixing 39 g of the silicone elastomer aqueous dispersion obtained in Production Example 1 (amount of silicone elastomer of 13 parts by mass with respect to 100 parts by mass of mica particles) and 1,284 g of water. Diallylammonium chloride polymer aqueous solution (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (amount to be 0.01 parts by mass with respect to 100 parts by mass of water), and 28 30% aqueous ammonia was charged. The pH of the liquid at this time was 11.4. After adjusting the temperature to 5 to 10 ° C., 27 g of methyltrimethoxysilane (an amount in which the silicone resin after hydrolysis / condensation reaction becomes 85 parts by mass with respect to 100 parts by mass of the silicone elastomer) is dropped over 20 minutes. The liquid temperature was kept at 5 to 10 ° C. and further stirred for 1 hour. Subsequently, it heated to 55-60 degreeC, it stirred for 1 hour, maintaining the temperature, and the hydrolysis and condensation reaction of methyltrimethoxysilane was completed. The obtained suspension was dehydrated using a pressure filter. The dehydrated product was transferred to a 3 liter glass flask equipped with a stirrer with a vertical stirring blade, added with 1,000 g of water, stirred for 30 minutes, and then dehydrated using a pressure filter. Again, the dehydrated product was transferred to a glass flask, and the flask was immersed in an oil bath at 110 ° C. and dried with stirring to obtain fluid particles.

  Observation of the obtained particles with an electron microscope reveals that spherical particles of about 300 nm are uniformly attached to the surface of the plate-like particles, and that the composite particles are formed by attaching a silicone elastomer to the surface of the mica particles. confirmed. Moreover, it turned out that a silicone resin becomes a binder and makes the silicone elastomer adhere to the mica particle.

  Furthermore, after weighing 20 g of sodium bromide, polyoxyethylene lauryl ether (trade name: Emulgen 109P, Kao (manufactured)) 0.5 g, water 80 g and composite particles 5 g in a 100 mL glass bottle and shaking for 30 minutes, When the silicone elastomer dropped off from the surface of the mica particles, the silicone elastomer floated because the specific gravity was smaller than that of sodium bromide water, but the whole amount had settled. This suggests that the silicone resin becomes a binder and the silicone elastomer is adhered to the mica particles.

[Production Example 4]
(Production of composite particles 3)
In a glass flask with a capacity of 3 liters equipped with a stirrer with a vertical stirring blade, 120 g of sericite particles (trade name: Sanshin Mica FSE, manufactured by Sanshin Mining Co., Ltd., shape = plate, average particle size = 10 μm) Into a mixed water dispersion obtained by mixing 41 g of the silicone elastomer aqueous dispersion obtained in Production Example 1 above (an amount in which the silicone elastomer is 14 parts by mass with respect to 100 parts by mass of sericite) and 1,281 g of water, % Dimethyldiallylammonium chloride polymer aqueous solution (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (amount to be 0.01 parts by mass with respect to 100 parts by mass of water), And 30 g of 28% aqueous ammonia were charged. The pH of the liquid at this time was 11.4. After adjusting the temperature to 5 to 10 ° C., 28 g of methyltrimethoxysilane (an amount in which the silicone resin after hydrolysis and condensation reaction is 85 parts by mass with respect to 100 parts by mass of the silicone elastomer) is dropped over 20 minutes. The liquid temperature was kept at 5 to 10 ° C. and further stirred for 1 hour. Subsequently, it heated to 55-60 degreeC, it stirred for 1 hour, maintaining the temperature, and the hydrolysis and condensation reaction of methyltrimethoxysilane was completed. The obtained suspension was dehydrated using a pressure filter. The dehydrated product was transferred to a 3 liter glass flask equipped with a stirrer with a vertical stirring blade, added with 1,000 g of water, stirred for 30 minutes, and then dehydrated using a pressure filter. Again, the dehydrated product was transferred to a glass flask, and the flask was immersed in an oil bath at 110 ° C. and dried with stirring to obtain fluid particles.

  Observation of the obtained particles with an electron microscope reveals that spherical particles of about 300 nm are uniformly attached to the surface of the plate-like particles, and the composite particles are formed by attaching a silicone elastomer to the sericite surface. confirmed. Moreover, it turned out that a silicone resin becomes a binder and the silicone elastomer is made to adhere to a sericite.

  Furthermore, after weighing 20 g of sodium bromide, polyoxyethylene lauryl ether (trade name: Emulgen 109P, Kao (manufactured)) 0.5 g, water 80 g and composite particles 5 g in a 100 mL glass bottle and shaking for 30 minutes, When the silicone elastomer dropped off from the surface of the sericite particles, the silicone elastomer floated because the specific gravity was smaller than that of sodium bromide water, but the whole amount had settled. Therefore, it is suggested that the silicone resin becomes a binder and the silicone elastomer is adhered to the sericite particles.

[Production Example 5]
(Production of composite particles 4)
In a glass flask with a capacity of 3 liters equipped with a stirrer with a vertical stirring blade, 150 g of mica titanium particles (trade name: Flamenco Red 420C, manufactured by BASF, shape = plate, particle size = 6-48 μm) and the above production 40% dimethyldiallyl was added to a mixed aqueous dispersion obtained by mixing 31 g of the silicone elastomer aqueous dispersion obtained in Example 1 (an amount of silicone elastomer of 8 parts by mass with respect to 100 parts by mass of mica titanium) and 1,261 g of water. Ammonium chloride polymer aqueous solution (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (amount to be 0.01 parts by mass with respect to 100 parts by mass of water), and 28% 30 g of aqueous ammonia was charged. The pH of the liquid at this time was 11.4. After adjusting the temperature to 5 to 10 ° C., 28 g of methyltrimethoxysilane (the amount of 109 parts by mass of the silicone resin after hydrolysis / condensation reaction with respect to 100 parts by mass of the silicone elastomer) was dropped over 20 minutes. The liquid temperature was kept at 5 to 10 ° C. and further stirred for 1 hour. Subsequently, it heated to 55-60 degreeC, it stirred for 1 hour, maintaining the temperature, and the hydrolysis and condensation reaction of methyltrimethoxysilane was completed. The obtained suspension was dehydrated using a pressure filter. The dehydrated product was transferred to a 3 liter glass flask equipped with a stirrer with a vertical stirring blade, added with 1,000 g of water, stirred for 30 minutes, and then dehydrated using a pressure filter. Again, the dehydrated product was transferred to a glass flask, and the flask was immersed in an oil bath at 110 ° C. and dried with stirring to obtain fluid particles.

  Observation of the obtained particles with an electron microscope reveals that spherical particles of about 300 nm are uniformly attached to the surface of the plate-like particles, and are composite particles in which a silicone elastomer is attached to the surface of titanium mica. confirmed. It was also found that the silicone resin was a binder and the silicone elastomer was adhered to the mica titanium.

  Furthermore, after weighing 20 g of sodium bromide, polyoxyethylene lauryl ether (trade name: Emulgen 109P, Kao (manufactured)) 0.5 g, water 80 g and composite particles 5 g in a 100 mL glass bottle and shaking for 30 minutes, When the silicone elastomer dropped off from the surface of the titanium mica particles, the silicone elastomer floated because the specific gravity was smaller than that of sodium bromide water, but the whole amount had settled. Therefore, it is suggested that the silicone resin becomes a binder and the silicone elastomer is adhered to the mica titanium particles.

[Production Example 6]
(Production of composite particles 5)
40% dimethyldiallylammonium chloride polymer aqueous solution of Production Example 2 (trade name: ME polymer H40W, manufactured by Toho Chemical Co., Ltd., average molecular weight = 240,000) 0.33 g (0.01 parts by mass with respect to 100 parts by mass of water) A fluid particle was obtained in the same manner as in Production Example 2 except that the amount of
When the obtained particles were observed with an electron microscope, spherical particles adhered to the surface of the plate-like particles were little but aggregates of spherical particles not adhered were observed.

[Production Example 7]
(Production of composite particles 6)
40% dimethyldiallylammonium chloride polymer aqueous solution of Production Example 3 (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (0.01 parts by mass with respect to 100 parts by mass of water) The fluid particles were obtained in the same manner as in Production Example 3 except that the amount of
When the obtained particles were observed with an electron microscope, spherical particles adhered to the surface of the plate-like particles were little but aggregates of spherical particles not adhered were observed.

[Production Example 8]
(Production of composite particles 7)
40% dimethyldiallylammonium chloride polymer aqueous solution of Production Example 5 (trade name: ME polymer H40W, manufactured by Toho Chemical Industry Co., Ltd., average molecular weight = 240,000) 0.33 g (0.01 parts by mass with respect to 100 parts by mass of water) The fluid particles were obtained in the same manner as in Production Example 5 except that the amount of
When the obtained particles were observed with an electron microscope, spherical particles adhered to the surface of the plate-like particles were little but aggregates of spherical particles not adhered were observed.

<Characteristic evaluation for cosmetics>
The composite particles obtained in the production example are spread (extensibility), softness (feel), and stickiness (adhesiveness / homogeneity) when applying a simple powder mixture prescribed below by 10 expert panelists. The dispersibility of the powder and the skin shape correction effect (soft focus effect) were evaluated. The results are shown in Table 2.

<Prescription>
Powder simple mixture Preparation composite particles 4 parts Untreated talc 92 parts of dimethyl polysiloxane ^{(6 mm} 2/2 seconds (25 ℃)) 2 parts
Squalane 2 parts <br/> 100 parts in total

[Example 1]
A simple mixture containing the composite particles of Production Example 2.
[Example 2]
A simple mixture containing the composite particles of Production Example 3.
[Example 3]
A simple mixture containing the composite particles of Production Example 5.
[Comparative Example 1]
A simple mixture containing the composite particles of Production Example 6.
[Comparative Example 2]
A simple mixture containing the composite particles of Production Example 7.
[Comparative Example 3]
A simple mixture containing the composite particles of Production Example 8.

<Production method>
During the formulation of the simple powder mixture, the powder portions (composite particles of production example and untreated talc) were weighed and stirred for 1 minute with a high-speed blender. The oil phase (dimethylpolysiloxane and squalane) was added thereto, and the mixture was further stirred for 6 minutes, and then passed through a 100 mesh filter to obtain a powder simple mixture or a powder simple mixture blank.

<Evaluation>
About spreading (extensibility), softness (feel), adhesion (adhesiveness / homogeneity), powder mixing (dispersibility), and skin shape correction effect (soft focus effect) when applying a simple powder mixture Evaluation was made according to the evaluation criteria shown in Table 1. The results were determined according to the following criteria based on the average score of 10 people (Table 2).

<Criteria>
◎: Average point is 4.5 points or more ○: Average point is 3.5 points or more and less than 4.5 points Δ: Average point is 2.5 points or more and less than 3.5 points ×: Average point is 1.5 points or more Less than 2.5 points XX: Average point is less than 1.5 points

  As is clear from Table 2, the cosmetics according to the present invention (Examples 1 to 3) are more spread (extensibility), soft (feel), and sticky (adhesiveness / adhesiveness) than the cosmetics of Comparative Examples 1 to 3. (Homogeneity) and the like are good, the powder is well mixed (dispersibility), and the skin shape correction effect (soft focus effect) is demonstrated to be excellent.

[Examples 4 and 5 and Comparative Example 4] Powder Foundation In the following examples, powder foundations were prepared with the compounding composition ratios shown in Table 3 using the powder of composite particles obtained in the above Examples.

（注１）メチルハイドロジェンポリシロキサン処理：製造例２で用いたタルク、又は、製造例４で用いたセリサイト９５部を反応器に仕込み、これにメチルハイドロジェンポリシロキサン５部をトルエンに希釈した溶液を徐々に加えながら攪拌した。さらに、昇温してトルエンを留去し、１５０℃で３時間攪拌することにより焼き付け処理を行って、メチルハイドロジェンポリシロキサン処理タルク及びメチルハイドロジェンポリシロキサン処理セリサイトを其々得た。
（注２）ポリメチルシルセスキオキサン：ＫＭＰ−５９０（信越化学工業（株）製）
（注３）トリエトキシシリルエチルポリジメチルシロキシエチルヘキシルジメチコン：ＫＦ−９９０９（信越化学工業（株）製） <Prescription>

(Note 1) Methyl hydrogen polysiloxane treatment: 95 parts of talc used in Production Example 2 or sericite used in Production Example 4 are charged into a reactor, and 5 parts of methyl hydrogen polysiloxane are diluted in toluene. The solution was stirred as it was slowly added. Furthermore, the temperature was raised, toluene was distilled off, and the baking treatment was performed by stirring at 150 ° C. for 3 hours to obtain methylhydrogenpolysiloxane-treated talc and methylhydrogenpolysiloxane-treated sericite, respectively.
(Note 2) Polymethylsilsesquioxane: KMP-590 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone: KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

<Preparation of cosmetics>
Ingredients (4) to (14) were put into a Henschel mixer and stirred and mixed. Separately uniformly dissolved components (1) to (3) were added thereto, and stirring and mixing were further continued. Further, (15) was added thereto. This mixture was pulverized with a hammer mill and press-molded into a predetermined aluminum pan to obtain a powder foundation. The following evaluation was performed about the obtained powder foundation. In Comparative Example 4, neither component (5) nor (10) was blended.

<Usability evaluation>
About the obtained powder foundation, 10 female panelists applied a cosmetic test product to spread (extensibility), softness (feel), adhesion (adhesion / homogeneity), and skin shape correction effect. (Soft focus effect) is evaluated according to the criteria shown in Table 4, and spreads (extensibility), softness (feel), stickiness (adhesiveness / homogeneity), and finish of cosmetics when applying cosmetics Was evaluated for its naturalness (feeling of bare skin) and makeup lasting (sustainability).

＜判定基準＞
得られた平均点が４．５点以上 ◎
得られた平均点が３．５点以上４．５点未満 ○
得られた平均点が２．５点以上３．５点未満 △
得られた平均点が１．５点以上２．５点未満 ×
得られた平均点が１．５点未満 ×× <Evaluation criteria>
About spread (extensibility), softness (feel), stickiness (adhesiveness / homogeneity), cosmetic finish naturalness (feeling of skin), and longevity (durability) when applying cosmetic test products Evaluation was made according to the criteria shown in Table 4, and the average points obtained were judged as ◯ according to the following criteria. The results are as shown in Table 5.

<Criteria>
The average score obtained is 4.5 or more.
The average score obtained is 3.5 or more and less than 4.5 ○
The average score obtained is 2.5 or more and less than 3.5
The obtained average score is 1.5 or more and less than 2.5 ×
The average score obtained is less than 1.5 points.

  As is clear from Table 5, Examples 4 and 5 have better usability, a natural finish, good makeup lasting and superior powder foundation compared to Comparative Example 4.

[Example 6] Oil-in-water cream (component) Mass (%)
1. Cross-linked dimethylpolysiloxane (Note 1) 10.0
2. Glyceryl trioctanoate 5.0
3. Composite powder of production example 5 (titanium mica) 1.0
4). Dipropylene glycol 7.0
5. Glycerin 5.0
6). Methylcellulose (2% aqueous solution) (Note 2) 7.0
7). Polyacrylamide emulsifier (Note 3) 2.0
8). Preservative appropriate amount 9. Perfume appropriate amount
10. Remaining amount of purified water <br/> Total 100.0
(Note 1) Cross-linked dimethylpolysiloxane; KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Methylcellulose; Metroles SM-4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3): Polyacrylamide emulsifier; Sepigel 305 (manufactured by SEPIC)

(Production method)
A: Components 4 to 10 were mixed.
B: Components 1 to 3 were mixed and added to A to emulsify with stirring.

  The oil-in-water cream obtained as described above has a fine texture, light spreading, no stickiness or oiliness, and a soft feeling of use, as well as a skin shape correction effect, and a long-lasting makeup. In addition, it was confirmed that there was no change in temperature or change with time and that the stability was excellent.

[Example 7] Emulsified cream foundation (component) Mass (%)
1. Alkyl-modified cross-linked polyether-modified silicone (Note 1) 2.0
2. Alkyl-modified cross-linked dimethylpolysiloxane (Note 2) 2.0
3. Liquid paraffin 2.0
4). Trioctanoin 5.0
5. Isotridecyl isononanoate 9.0
6). Alkyl / polyether co-modified silicone (Note 3) 1.5
7). Hybrid silicone composite powder (Note 4) 2.0
8). Composite powder (Mica) of Production Example 3 1.0
9. Triethoxysilylethyl polydimethylsiloxyethylhexyl 2.5
Dimethicone (Note 5) treated iron oxide10. Triethoxysilylethyl polydimethylsiloxyethylhexyl 7.5
Dimethicone (Note 5) treated titanium oxide 11.1,3-butylene glycol 5.0
12 Sodium citrate 3.0
13. Magnesium sulfate 3.0
14 Preservative appropriate amount15. Perfume appropriate amount
16. Remaining amount of purified water <br/> Total 100.0
(Note 1) Alkyl-modified cross-linked polyether-modified silicone; KSG-310 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Alkyl-modified cross-linked dimethylpolysiloxane; KSG-41 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Alkyl / polyether co-modified silicone; KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) Hybrid silicone composite powder; KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 5) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone: KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 6 were mixed uniformly, and components 7 to 10 were added to make uniform.
B: Components 11 to 14 and 16 were dissolved.
C: While stirring, B was gradually added to A to emulsify, and after cooling, component 15 was added to obtain an emulsified cream foundation.

  The emulsified cream foundation obtained as described above has a low viscosity, fine texture, light spreading, no stickiness and oiliness, and a soft feeling of use and also has a skin shape correction effect, It was confirmed that the makeup lasts well and there is no change in temperature or change over time, and the stability is excellent.

[Example 8] Water-in-oil cream (component) Mass (%)
1. Alkyl-modified cross-linked polyether-modified silicone (Note 1) 6.0
2. Alkyl-modified cross-linked dimethylpolysiloxane (Note 2) 2.0
3. Liquid paraffin 13.5
4). Macadamia nut oil 5.0
5. Alkyl / polyether co-modified silicone (Note 3) 1.0
6). Hybrid silicone composite powder (Note 4) 2.0
7). Composite powder (Mica) of Production Example 3 1.0
8). Sodium citrate 0.2
9. Dipropylene glycol 8.0
10. Glycerin 3.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0
(Note 1) Alkyl-modified cross-linked polyether-modified silicone; KSG-310 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Alkyl-modified cross-linked dimethylpolysiloxane; KSG-41 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Alkyl / polyether co-modified silicone; KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) Hybrid silicone composite powder; KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 7 were mixed.
B: Components 8 to 13 were mixed and dissolved, added to A, and emulsified with stirring to obtain a water-in-oil cream.

  The water-in-oil cream obtained as described above has a fine texture, light spread, no stickiness or oiliness, a soft feeling of use and a skin shape correction effect. It was confirmed that it has excellent stability as well as no change in temperature or change over time.

[Example 9] Water-in-oil cream (component) Mass (%)
1. Decamethylcyclopentasiloxane 16.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 4.0
3. Polyether-modified silicone (Note 1) 5.0
4). POE (5) octyldodecyl ether 1.0
5. Polyoxyethylene sorbitan monostearate (20 EO) 0.5
6). Composite powder of Production Example 5 (titanium mica) 2.0
7). Plate-like barium sulfate (Note 2) 2.0
8). Liquid paraffin 2.0
9. Macadamia nut oil 1.0
10. Ogon Extract (Note 3) 1.0
11. Gentian extract (Note 4) 0.5
12 Ethanol 5.0
13.1,3-Butylene glycol 2.0
14 Preservative appropriate amount15. Perfume appropriate amount
16. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Plate-like barium sulfate; HL (manufactured by Sakai Chemical Industry Co., Ltd.)
(Note 3) Ogon extract; extracted with 50% 1,3-butylene glycol water (Note 4) Gentian extract; extracted with 20% ethanol water

(Production method)
A: Components 6 to 9 were mixed and dispersed uniformly.
B: Components 1 to 5 were mixed and A was added.
C: After mixing components 10 to 14 and 16, B was added to emulsify.
D: Component 15 was added to C to obtain a water-in-oil cream.

  The water-in-oil cream obtained as described above is not only fine and non-sticky, but also has a light spread and excellent adhesion, and a soft feeling of use and a skin shape correction effect. Yes, the makeup is very good. In addition, it was confirmed that it was stable with no change with temperature or with time.

[Example 10] Eyeliner (component) Mass (%)
1. Decamethylcyclopentasiloxane 39.0
2. Polyether-modified silicone (Note 1) 3.0
3. Organic silicone resin (Note 2) 15.0
4). Dioctadecyldimethylammonium salt modified montmorillonite 3.0
5. Methylhydrogenpolysiloxane-treated black iron oxide 8.0
6). Composite powder (Mica) of Production Example 3 2.0
7.1,3-Butylene glycol 5.0
8). Sodium dehydroacetate Preservative appropriate amount
10. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Organic silicone resin: KF-7712J (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 4 were mixed, and components 5 and 6 were added and mixed and dispersed uniformly.
B: Components 7 to 10 were mixed.
C: B was gradually added to A and emulsified to obtain an eyeliner.

  The eyeliner obtained as described above was light and easy to draw, had a refreshing and refreshing feeling, and had a feeling of use without stickiness. In addition, it was confirmed that there was no change in temperature or change over time, and the usability and stability were excellent, and the durability of the makeup was very good as well as excellent water resistance and sweat resistance.

[Example 11] Foundation (component) Mass (%)
1. Decamethylcyclopentasiloxane 45.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 5.0
3. Polyether-modified branched silicone (Note 1) 3.5
4). Octadecyldimethylbenzylammonium salt modified montmorillonite 1.5
5. Composite powder (Mica) of Production Example 3 2.0
6). Triethoxysilylethyl polydimethylsiloxyethylhexyl 2.5
6. Dimethicone (Note 2) treated iron oxide Triethoxysilylethyl polydimethylsiloxyethylhexyl 7.5
Dimethicone (Note 2) treated titanium oxide8. Dipropylene glycol 5.0
9. P-Hydroxybenzoic acid methyl ester 0.3
10. Perfume appropriate amount
11. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified branched silicone; KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone: KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 4 were heated and mixed, and components 5 to 7 were added to make uniform.
B: Components 8 to 9 and 11 were dissolved.
C: Under stirring, B was gradually added to A to emulsify, and after cooling, component 10 was added to obtain a foundation.

  The foundation obtained as described above has a fine texture, light spreading, no stickiness or oiliness, a soft feeling of use and a skin shape correction effect, and a long-lasting makeup. It was confirmed that there was no temperature change or change over time, and the stability was excellent.

[Example 12] Eye shadow (component) Mass (%)
1. Decamethylcyclopentasiloxane 17.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 10.0
3. Polyether-modified branched silicone (Note 1) 2.0
4). PEG (10) lauryl ether 0.5
5. Composite powder (Mica) of Production Example 3 2.0
6). Composite powder (talc) of Production Example 2 1.0
7). Composite powder of Production Example 5 (titanium mica) 6.0
8). 8. Methyl hydrogen polysiloxane-treated inorganic coloring pigment Sodium chloride 2.0
10. Propylene glycol 8.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified branched silicone; KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 4 were mixed, and components 5 to 8 were added and dispersed uniformly.
B: Components 9 to 11 and 13 were uniformly dissolved.
C: Under stirring, B was gradually added to A to emulsify, and component 12 was added to obtain an eye shadow.

  The eye shadow obtained as described above had a soft feeling of use with no spreading and light oiliness and powderiness. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, and the makeup was not easily broken, and it was excellent in stability with no change in temperature or change with time.

[Example 13] Lipstick (component) Mass (%)
1. Candelilla wax 7.0
2. Polyethylene wax 8.0
3. Long chain alkyl-containing acrylic silicone resin (Note 1) 12.0
4). Methylphenyl polysiloxane (Note 2) 3.0
5. Isotridecyl isononanoate 20.0
6). Glyceryl isostearate 16.0
7). Polyglyceryl triisostearate 28.5
8). Composite powder (Mica) of Production Example 3 0.5
9. Composite powder of Production Example 5 (titanium mica) 5.0
10. Organic pigment
11. Perfume proper amount <br/> Total 100.0
(Note 1) Long-chain alkyl-containing acrylic silicone resin; KP-561P (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Methylphenylpolysiloxane; KF-54 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: A part of components 1 to 6 and 7 were heated and mixed and dissolved.
B: The remainder of components 8 to 10 and 7 were mixed uniformly and added to A to make it uniform.
C: Component 11 was added to B to obtain a lipstick.

  The lipstick obtained as described above is light and does not feel oily or powdery, gives a soft feeling of use, has good water resistance and water repellency, and has good stability. Was also excellent.

[Example 14] Lipstick (component) Mass (%)
1. Polyethylene 7.0
2. Microcrystalline wax 3.0
3. Long chain alkyl-containing acrylic silicone resin (Note 1) 10.5
4). Triethylhexanoin 19.5
5. Neopentyl glycol diethylhexanoate 15.0
6). Neopentyl glycol dicaprate 7.0
7). Hydrogenated polyisobutene 2.5
8). Methylphenyl polysiloxane (Note 2) 7.5
9. Diglyceryl triisostearate0.8
10. Composite powder of Production Example 5 (titanium mica) 6.0
11. Coloring pigment appropriate amount
12 Perfume proper amount <br/> Total 100.0
(Note 1) Long-chain alkyl-containing acrylic silicone resin; KP-561P (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Methylphenylpolysiloxane; KF-54HV; Viscosity 5,850 cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A: Components 1 to 8 were heated and mixed and dissolved.
B: Components 9 and 11 were mixed uniformly and added to A to make it uniform.
C: Components 10 and 12 were added to B and uniformly mixed to obtain a lipstick.

  The lipstick obtained as described above is light and does not feel oily or powdery, and gives it a glossy and soft feeling of use, as well as good water resistance and water repellency. The stability was also excellent.

[Example 15] Eyeliner (component) Mass (%)
1. Decamethylcyclopentasiloxane 6.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 5.0
3. Jojoba oil 2.0
4). Polyether-modified silicone (Note 1) 1.0
5. Alkyl / polyether co-modified silicone (Note 2) 1.0
6). Acrylic silicone resin (Note 3) 15.0
7). Composite powder (Mica) of Production Example 3 2.0
8). Methylhydrogenpolysiloxane-treated black iron oxide 18.0
9. Ethanol 5.0
10. Preservative appropriate amount
11. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Alkyl / polyether co-modified silicone; KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Acrylic silicone resin; KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 6 were mixed with stirring, and 7 and 8 were added thereto and dispersed uniformly.
B: Components 9 to 11 were dissolved with stirring.
C: While stirring, B was gradually added to A to emulsify to obtain an eyeliner.

  The eyeliner obtained as described above is light and does not feel oily or powdery, and gives a soft feeling of use, as well as good water resistance, water repellency and sweat resistance. It was good and difficult to break the makeup. In addition, it was confirmed that there was no change in temperature or change with time and that the stability was excellent.

[Example 16] Liquid emulsified foundation (component) Mass (%)
1. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 4.5
2. Decamethylcyclopentasiloxane 30.0
3. Squalane 4.0
4). Neopentyl glycol dioctanoate 3.0
5. Triisostearic acid diglyceride 2.0
6). α-monoisostearyl glyceryl ether 1.0
7). Polyether-modified silicone (Note 1) 1.0
8). Alkyl / polyether co-modified silicone (Note 2) 0.5
9. Aluminum distearate 0.2
10. Composite powder (sericite) of Production Example 4 2.0
11. Composite powder (talc) of Production Example 2 1.0
12 Methyl hydrogen polysiloxane-treated iron oxide pigment Amount 13. Glycerin 3.0
14 Preservative appropriate amount15. Perfume appropriate amount
16. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Alkyl / polyether co-modified silicone; KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 9 were heated and mixed, and components 10 to 12 were added to make uniform.
B: Components 13 to 14 and 16 were dissolved by heating.
C: While stirring, B was gradually added to A to emulsify, and after cooling, component 15 was added to obtain a liquid emulsion foundation.

  The liquid emulsified foundation obtained as described above has a low viscosity, fine texture, light spreading, no stickiness or oiliness, and a soft feeling of use and also has a skin shape correction effect, It was confirmed that the makeup lasts well and there is no change in temperature or change over time, and the stability is excellent.

[Example 17] Liquid foundation (component) Mass (%)
1. Decamethylcyclopentasiloxane 16.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 8.0
3. Octyl paramethoxycinnamate 3.0
4.12-Hydroxystearic acid 1.0
5. Fluorine-modified silicone (Note 1) 15.0
6). Fluoroalkyl-polyether co-modified silicone (Note 2) 5.0
7). Spherical polymethylsilsesquioxane powder (Note 3) 1.0
8). Composite powder (talc) of Production Example 2 1.0
9. Composite powder of production example 5 (titanium mica) 1.0
10. 10. Methyl hydrogen polysiloxane-treated iron oxide pigment Ethanol 15.0
12 Glycerin 3.0
13. Magnesium sulfate 1.0
14 Preservative appropriate amount15. Perfume appropriate amount
16. Remaining amount of purified water <br/> Total 100.0
(Note 1) Fluorine-modified silicone; FL-50 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Fluoroalkyl-polyether co-modified silicone; FPD-4694 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Spherical polymethylsilsesquioxane powder; KMP-590 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 7 to 10 were mixed uniformly.
B: Components 1 to 6 were heated and mixed at 70 ° C., and A was added and dispersed and mixed uniformly.
C: Components 11 to 14 and 16 were heated to 40 ° C., gradually added to B to emulsify, cooled, and component 15 was added to obtain a liquid foundation.

  The liquid foundation obtained as described above has no stickiness, light spread, and a soft feeling of use, and also has a skin shape correction effect. It was confirmed to be very excellent.

[Example 18] Eyeliner (component) Mass (%)
1. Decamethylcyclopentasiloxane 22.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 5.0
3. Methyl hydrogen polysiloxane-treated black iron oxide 20.0
4). Composite powder (Mica) of Production Example 3 1.0
5. Organic silicone resin (Note 1) 10.0
6). Vitamin E acetate 0.2
7). Jojoba oil 2.0
8). Dimethyl distearyl ammonium hectorite 3.0
9. Polyether-modified silicone (Note 2) 2.0
10. Ethanol 3.0
11.1,3-butylene glycol 5.0
12 Preservative appropriate amount
13. Remaining amount of purified water <br/> Total 100.0
(Note 1) Organosilicone resin; KF-7312J (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 2 and 5 to 9 were mixed, and components 3 and 4 were added and uniformly mixed and dispersed.
B: Components 10 to 13 were mixed.
C: B was gradually added to A and emulsified to obtain an eyeliner.

  The eyeliner obtained as described above has a refreshing and cool feeling of supernatant that is light and easy to draw, has a soft feeling without stickiness, and does not change with temperature or with time. It was confirmed that both the sweatiness and the makeup lasting were very good.

[Example 19] Foundation (component) Mass (%)
1. Decamethylcyclopentasiloxane 27.0
2. Methylphenylpolysiloxane 3.0
3. Neopentyl glycol dioctanoate 10.0
4). Polyether-modified silicone (Note 1) 4.0
5. Glyceryl trioctanoate 3.0
6). Composite powder (talc) of Production Example 2 1.0
7). Composite powder (sericite) of Production Example 4 1.0
8). Composite powder of Production Example 5 (titanium mica) 2.0
9. Aluminum stearate treated titanium oxide 6.0
10. Methyl hydrogen polysiloxane-treated iron oxide pigment Appropriate amount 11.1,3-butylene glycol 7.0
12 Sodium chloride 0.5
13. Preservative appropriate amount14. Perfume appropriate amount
15. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6017 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 5 were mixed and dissolved, and components 6 to 10 were uniformly dispersed.
B: Components 11 to 13 and 15 were mixed and then emulsified in addition to A.
C: Component 14 was added to B to obtain a foundation.

  The foundation obtained as described above has no stickiness, light spreading, excellent adhesion, soft feeling of use, skin shape correction effect, very long-lasting makeup, and It has been found that it does not change with temperature and with time, and has excellent stability.

[Example 20] Brushing agent spray (component) Mass (%)
1. Isopropyl myristate 1.0
2. Stearyltrimethylammonium chloride 0.05
3. Composite powder (Mica) of Production Example 3 0.5
4). Ethanol 25.0
5. Perfume appropriate amount
6). Propellant remaining amount <br/> Total 100.0

(Production method)
A: Components 1 to 5 were mixed.
B: After A was packed in an aerosol can, the component 6 was filled to obtain a brushing agent spray.

  The brushing agent spray obtained as described above has a very smooth feeling of use, is excellent in sustainability, has excellent powder dispersibility during use, is very comby and glossy. It was confirmed to be good.

[Example 21] Rinse (component) Mass (%)
1. Ethylene glycol distearate 3.0
2. Cetanol 2.0
3. Propylene glycol monostearate 3.0
4). Dimethylpolysiloxane (100 mm ² / sec (25 ° C.)) 3.0
5. Glycerol monostearate 4.0
6). Polyoxyethylene (3) stearate 4.0
7). Acetyltrimethylammonium chloride 5.0
8). Polyoxyethylene (20) cetyl ether 2.0
9. Composite powder (Mica) of Production Example 3 1.0
10.1,3-butylene glycol 5.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0

(Production method)
A: Components 1 to 9 were stirred and mixed.
B: Components 10 to 11 and 13 were heated and mixed.
C: B was added to A, mixed, cooled, and component 12 was added to obtain a rinse.

  The rinse obtained as described above has no stickiness or weight when used, gives the hair an excellent gloss, gives it a smooth, smooth and voluminous feel, has a good combing ability, and is durable. Was also confirmed to be excellent.

[Example 22] Rinse-in shampoo (component) Mass (%)
1. Laminated amidopropyldimethylaminoacetic acid betaine (30%) 15.0
2. Polyoxyethylene (3) sodium lauryl ether sulfate (27%) 4.0
3. Polyoxyethylene (150) distearate 0.5
4). Cationized cellulose (4%) 0.5
5. Glycerin 3.0
6). Dimethylpolysiloxane (million mm ² / sec (25 ° C.)) 1.0
7). Dimethylpolysiloxane (100 mm ² / sec (25 ° C.)) 3.0
8). Composite powder (Mica) of Production Example 3 1.0
9. Preservative appropriate amount10. Perfume appropriate amount
11. Remaining amount of purified water <br/> Total 100.0

(Production method)
A: Components 1 to 5, 9 and 11 were heated and mixed.
B: Components 6 to 8 were mixed and dispersed.
C: After B was added to A and mixed, cooling and component 10 were added to obtain a rinse-in shampoo.

  The rinse-in shampoo obtained as described above has no stickiness or weight when used, gives an excellent gloss to the hair, gives it a smooth, smooth, and voluminous feel, has good combability, and continues to be used. It was confirmed that the properties were also excellent.

[Example 23] Treatment (component) Mass (%)
1. Ethylene glycol distearate 1.0
2. Liquid paraffin 10.0
3. Squalane 5.0
4). Stearyl alcohol 1.5
5. Dimethylpolysiloxane (10 mm ² / sec (25 ° C.)) 3.0
6). Stearic acid 6.0
7). Polyoxyethylene (3) stearyl alcohol 4.5
8). Polyoxyethylene (150) cetyl ether 2.0
9. Composite powder (Mica) of Production Example 3 1.0
10.1,3-butylene glycol 6.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0

(Production method)
A: Components 1 to 9 were heated and mixed.
B: Components 10 to 11 and 13 were mixed and dispersed.
C: After B was added to A and mixed, cooling and component 12 were added to obtain a treatment.

  The treatments obtained as described above have no stickiness or weight when used, give the hair an excellent gloss, give it a smooth, smooth, and voluminous feel, have good combing, and maintain its usability. Was also confirmed to be excellent.

[Example 24] Water-in-oil type antiperspirant (component) Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 7.0
2. Decamethylcyclopentasiloxane 13.0
3. Glyceryl trioctanoate 7.0
4). Dipropylene glycol 5.0
5. Sodium citrate 0.2
6). Aluminum / Zirconium Tetrachlorohydrate 18.0
7). Composite powder (talc) of Production Example 2 2.0
8). Fluorine-modified hybrid silicone composite powder (Note 2) 2.0
9. Perfume appropriate amount
10. Remaining amount of purified water <br/> Total 100.0
(Note 1) Cross-linked polyether-modified silicone; KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Fluorine-modified hybrid silicone composite powder; KSP-200 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 3 were mixed.
B: Components 4 to 10 were mixed.
C: B was added to A and mixed and emulsified to obtain a water-in-oil type antiperspirant.

  The water-in-oil type antiperspirant obtained as described above has light spread, no stickiness or oily feeling, no change with temperature and time, and very excellent usability and stability. It was.

[Example 25] Roll-on type antiperspirant (component) Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 20.0
2. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 10.0
3. Cross-linked dimethylpolysiloxane (Note 2) 15.0
4). Decamethylcyclopentasiloxane 30.0
5. Aluminum / Zirconium Tetrachlorohydrate 20.0
6). Composite powder (Mica) of Production Example 3 5.0
7). Perfume proper amount <br/> Total 100.0
(Note 1) Cross-linked polyether-modified silicone; KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Cross-linked dimethylpolysiloxane; KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 4 were mixed.
B: Components 5 to 7 were added to A and dispersed uniformly to obtain a roll-on type antiperspirant.

  The roll-on type antiperspirant obtained as described above has a light spread, no stickiness or oily feeling, no change with temperature and time, and excellent usability and stability. .

[Example 26] Sunscreen emulsion (component) Mass (%)
1. Decamethylcyclopentasiloxane 20.0
2. Methylphenylpolysiloxane 3.0
3. Sorbitan monoisostearate 1.0
4). Polyether-modified silicone (Note 1) 0.5
5. Trimethylsiloxysilicic acid (Note 2) 1.0
6). Octyl paramethoxycinnamate 4.0
7). Composite powder of production example 5 (titanium mica) 1.0
8). Aluminum stearate-treated fine particle titanium oxide 6.0
9. Sorbitol 2.0
10. Sodium chloride 2.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0
(Note 1) Polyether-modified silicone; KF-6015 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Trimethylsiloxysilicic acid; X-21-5250 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 6 were heated and mixed, and components 7 and 8 were uniformly dispersed.
B: Components 9 to 11 and 13 were heated and mixed.
C: Under stirring, B was gradually added to A to emulsify, and after cooling, component 12 was added to obtain a sunscreen emulsion.

  The sunscreen emulsion obtained as described above has a fine texture, light spread, no stickiness, a soft feeling of use and a skin shape correction effect. Furthermore, it was confirmed that the anti-ultraviolet rays preventive effect was maintained because the makeup lasting was good, and that it was excellent in stability with no temperature change or change with time.

[Example 27] Sun cut cream (component) Mass (%)
1. Decamethylcyclopentasiloxane 20.0
2. Acrylic silicone resin (Note 1) 12.0
3. Glyceryl trioctanoate 5.0
4). Octyl paramethoxycinnamate 6.0
5. Cross-linked polyether-modified silicone (Note 2) 5.0
6). Alkyl silicone / polyether co-modified silicone (Note 3) 6.5
7). Composite powder of production example 5 (titanium mica) 1.0
8). Aluminum stearate treated fine particle titanium oxide 15.0
9. Sodium chloride 0.5
10.1,3-butylene glycol 2.0
11. Preservative appropriate amount 12. Perfume appropriate amount
13. Remaining amount of purified water <br/> Total 100.0
(Note 1) Acrylic silicone resin; KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Crosslinked polyether-modified silicone; KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Alkyl silicone / polyether co-modified silicone; KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Component 2 was added to a part of component 1 to make it uniform, and component 8 was added and dispersed with a bead mill.
B: The remainder of component 1 and 3-7 were mixed to make uniform.
C: Components 9 to 11 and 13 were mixed and dissolved.
D: C was added to B and emulsified to disperse A, and further component 12 was added to obtain a sun cut cream.

  The sun cut cream obtained as described above has no stickiness, light spread and lightness, excellent adhesion, soft use feeling, skin shape correction effect, and excellent makeup. . Moreover, it was confirmed that it was very stable against temperature changes and aging.

[Example 28] Nail enamel (component) Mass (%)
1. Acrylic silicone resin (Note 1) 45.0
2. Methyl trimethicone (Note 2) 5.0
3. Nitrocellulose 3.0
4). Kanfa 0.5
5. Acetyltributyl citrate 1.0
6). Dimethyl distearyl ammonium hectorite 0.5
7). Butyl acetate 30.0
8). Ethyl acetate 10.0
9. Isopropyl alcohol 5.0
10. Composite powder (Mica) of Production Example 3 Appropriate amount Total 100.0
(Note 1) Acrylic silicone resin; KP-549 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Methyltrimethicone; TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 7 to 9 are mixed, and components 4 to 6 are added thereto and mixed uniformly.
B: Components 1 to 3 are added to A and mixed.
C: Component 10 was added to B and mixed to obtain a nail enamel.

  The nail enamel obtained as described above has a light spread, provides visual smoothness, is water and oil resistant, and has a feeling of pressure on the nails, yellowing of the nails and temperature. In addition, it was confirmed that there was no change in the decorative film over time and the stability was also excellent.

[Example 29] Teak color component Mass (%)
1. Cross-linked dimethylpolysiloxane (Note 1) 28.0
2. Decamethylcyclopentasiloxane 34.5
3. Neopentyl glycol dioctanoate 9.0
4). Stearoyl inulin 10.0
5. Hybrid silicone composite powder (Note 2) 2.0
6). Red No. 202 appropriate amount 7. Alkyl / silicone branched silicone (Note 3) treated iron oxide Alkyl / silicone branched silicone (Note 3) treated titanium oxide Tocopherol appropriate amount10. Composite powder of Production Example 5 (titanium mica) 5.0
11. Composite powder of production example 3 (mica) 11.5
Total 100.0
(Note 1) Cross-linked dimethylpolysiloxane; KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Hybrid silicone composite powder; KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Alkyl / silicone branched silicone; KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 5 were mixed, heated to 80 ° C., and uniformly dispersed.
B: Components 6 to 11 were added to A and uniformly dispersed at 80 ° C.
C: Returned to room temperature to obtain a cheek color.

  The cheek color obtained as described above may be in the form of a sponge and may have a feeling of use with no spread of oil and powder as well as light spreading. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, the makeup was not easily broken, and there was no change with temperature and with time, and the stability was excellent.

[Example 30] Eye color component Mass (%)
1. Isotridecyl isononanoate 20.0
2. Squalane 20.0
3. Hybrid silicone composite powder (Note 1) 6.0
4). Dextrin palmitate 10.0
5. Cross-linked dimethylpolysiloxane (Note 2) 12.0
6). Barium sulfate 5.0
7). Polyethylene terephthalate / Al powder 4.5
8). Composite powder of Production Example 5 (titanium mica) 13.5
9. Tocopherol appropriate amount10. Glass flake powder for cosmetics (Note 3) 1.5
11. Iron oxide-coated glass flake powder for cosmetics (Note 4) 7.5
Total 100.0
(Note 1) Hybrid silicone composite powder; KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Cross-linked dimethylpolysiloxane; KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Glass flake (manufactured by Nippon Sheet Glass Co., Ltd.)
(Note 4) Iron oxide coated glass flakes; Metashine (manufactured by Nippon Sheet Glass Co., Ltd.)

(Production method)
A: Components 1 to 5 were mixed, heated to 90 ° C., and uniformly dispersed.
B: Components 6 to 11 were added to A and further dispersed uniformly at 90 ° C.
C: The eye color was obtained by returning to room temperature.

  The eye color obtained as described above may be in the form of a jelly, has a light spread, and has a feeling of use with no oiliness and powderiness. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, the makeup was not easily broken, and there was no change with temperature and with time, and the stability was excellent.

[Example 31] Foundation component Mass (%)
1. Dimethylpolysiloxane (6 mm ² / sec (25 ° C.)) 23.0
2. Organic silicone resin (Note 1) 10.0
3. Alkyl / silicone branched / crosslinked dimethylpolysiloxane (Note 2) 34.0
4). Hybrid silicone composite powder (Note 3) 8.0
5. Squalane 1.0
6). Jojoba oil 1.0
7). Diphenylsiloxyphenyl trimethicone (Note 4) 1.0
8). PMMA spherical powder 2.0
9. Alkyl / silicone branched silicone (Note 5) treated iron oxide Alkyl / silicone branched silicone (Note 5) treated titanium oxide 6.0
11. Aluminum stearate treated fine particle titanium oxide 9.0
12 Tocopherol appropriate amount13. Composite powder (talc) of Production Example 2 3.0
14 Composite powder (sericite) of Production Example 4 2.0
Total 100.0
(Note 1) Organic silicone resin; KF-7712L (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Alkyl / silicone branched / crosslinked dimethylpolysiloxane; KSG-048Z (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Hybrid silicone composite powder; KSP-105 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) Diphenylsiloxyphenyl trimethicone; KF-56A (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 5) Alkyl silicone branched silicone; KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: A part of component 1 and components 2 to 8 were mixed and dispersed uniformly.
B: Components 9 to 14 were uniformly dispersed using the remainder of Component 1 by a roll mill.
C: Component B was uniformly dispersed in A to obtain a foundation.

  The foundation obtained as described above can be removed in a souffle-like shape, has a light spread, and has a feeling of use with no oiliness and powderiness. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, the makeup was not easily broken, and there was no change with temperature and with time, and the stability was excellent.

[Example 32] Eye color component Mass (%)
1. Dimethylpolysiloxane (20 mm ² / sec (25 ° C.)) 1.0
2. Diphenylsiloxyphenyl trimethicone (Note 1) 1.0
3. Squalane 1.5
4). Vaseline 2.5
5. Spherical polymethylsilsesquioxane powder (Note 2) 2.0
6). PMMA spherical powder 1.0
7). Zinc myristate 8.0
8). Fumed silica 0.5
9. Alkyl / silicone branched silicone (Note 3) treated iron oxide 11. Alkyl / silicone branched silicone (Note 3) Ultramarine treatment Alkyl / silicone branched silicone (Note 3) treated titanium oxide Tocopherol appropriate amount13. Composite powder (talc) 20.0 of production example 2
14 Composite powder (Mica) of Production Example 3 10.0
15. Composite powder (sericite) of Production Example 4 10.0
16. Composite powder of Production Example 5 (titanium mica) 25.0
Total 100.0
(Note 1) Diphenylsiloxyphenyl trimethicone; KF-56A (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Spherical polymethylsilsesquioxane powder; KMP-590 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Alkyl / silicone branched silicone; KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 5 to 16 were put into a Henschel mixer and stirred and mixed.
B: Components 1 to 4 were uniformly dispersed, added to A, and further stirred and mixed.
C: The mixture was pulverized with a hammer mill and pressed into a predetermined aluminum pan to obtain an eye color.

  The eye color obtained as described above was easy to remove, lightly spread, and had a feeling of use with no oiliness or powderiness. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, the makeup was not easily broken, and there was no change with temperature and with time, and the stability was excellent.

[Example 33] Eye color component Mass (%)
1. Isododecane 17.0
2. Acrylic silicone resin (Note 1) 20.0
3. Long chain alkyl-containing acrylic silicone resin (Note 2) 2.0
4). Hybrid silicone composite powder (Note 3) 6.0
5. Vaseline 10.0
6). Alkyl-modified cross-linked dimethylpolysiloxane (Note 4) 12.0
7). Barium sulfate 5.0
8). Organic pigment appropriate amount9. Alkyl / silicone branched silicone (Note 5) treated iron oxide Alkyl / silicone branched silicone (Note 5) treated titanium oxide Composite powder of Production Example 5 (titanium mica) 20.0
12 Tocopherol appropriate amount
13. Perfume proper amount <br/> Total 100.0
(Note 1) Acrylic silicone resin; KP-550 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) Long-chain alkyl-containing acrylic silicone resin; KP-561P (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) Hybrid silicone composite powder; KSP-441 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) Alkyl-modified cross-linked dimethylpolysiloxane; KSG-42 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 5) Alkyl silicone branched silicone; KF-9909 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
A: Components 1 to 6 were mixed and dispersed uniformly.
B: Components 7 to 13 were added to A and dispersed uniformly to obtain an eye color.

  The eye color obtained as described above was easy to remove, lightly spread, and had a feeling of use with no oiliness or powderiness. In addition, it was confirmed that the water resistance, water repellency and sweat resistance were good and good, the makeup was not easily broken, and there was no change with temperature and with time, and the stability was excellent.

  The present invention is not limited to the above embodiment. The above-described embodiment is an exemplification, and the present invention has substantially the same configuration as the technical idea described in the claims of the present invention, and any device that exhibits the same function and effect is the present invention. It is included in the technical scope of the invention.

Claims (5)

  A cosmetic, at least a mixed water dispersion in which an inorganic powder and a silicone elastomer are dispersed, a cationic water-soluble polymer, and an alkaline substance are mixed with an alkoxysilane, a silanol group-containing silane, And composite particles produced by adding a compound selected from these partial condensates and hydrolyzing and condensing them, and having the silicone elastomer attached to the surface of the inorganic powder using a silicone resin as a binder Cosmetics characterized by that.   The composite particle is a synthetic system in which the polymer skeleton is synthesized by any one of vinyl polymerization, addition polymerization, and condensation as the cationic water-soluble polymer, and includes an anionic group and an amphoteric group. The cosmetic according to claim 1, wherein the cosmetic is produced using a non-existing product. The composite particles include, as the cationic water-soluble polymer, a polymer of dimethyldiallylammonium chloride, a polymer of vinylimidazoline, a polymer of methylvinylimidazolium chloride, a polymer of ethyltrimethylammonium acrylate, an ethyl methacrylate Polymer of trimethylammonium chloride, polymer of acrylamidopropyltrimethylammonium chloride, polymer of methacrylamidopropyltrimethylammonium chloride, polymer of ethyleneimine, quaternized product of polymer of ethyleneimine, polymer of allylamine hydrochloride, polylysine The cosmetic according to claim 2, wherein the cosmetic is produced using a material selected from the group consisting of:   The cosmetic according to claim 3, wherein the composite particles are produced using a polymer of dimethyldiallylammonium chloride as the cationic water-soluble polymer.   The composite particles are produced by setting the blending amount of the cationic water-soluble polymer in the mixed water dispersion to 0.0001 to 1 part by mass with respect to 100 parts by mass of water in the mixed water dispersion. The cosmetic according to any one of claims 1 to 4, wherein: