JP2018002643A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic which spreads well without stickiness when applied, has excellent sense of use, has good water resistance, has excellent makeup sustainability because of having good adhesion to the skin and can prevent adhesion to clothes or the like (secondary adhesion).SOLUTION: There is provided a cosmetic obtained by blending a silicone resin having constitutional units represented by the general formulas (A)(RSiO)a, (B)(RSiO)b, (C)(RSiO)c and (D)(SiO)d (where, R, Rand Rare independently a group selected from an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms and a fluorine-substituted alkyl group having 1 to 8 carbon atoms, a has a value of 0.2 to 0.5, b has a value of 0.0 to 0.1, c has a value of 0.3 to 0.6, d has a value of 0.2 to 0.4, the value of a+b+c+d is 1.0, the value of a/(c+d) is 0.3 to 0.9, and the value of c/d is 0.8 to 2.5) and having a weight-average molecular weight of 1500 to 20000.SELECTED DRAWING: None

Description

  The present invention relates to a cosmetic.

Conventionally, silicone resins have a film-forming ability and are excellent in water resistance, sweat resistance, and sebum resistance, so make-up cosmetics such as foundations, lipsticks, eye shadows, mascaras, UV protection cosmetics, and hair It is used as a raw material for cosmetics such as cosmetics. For example, skin cosmetics (Patent Document 1) containing an organic silicone resin consisting of units of average formula R _n SiO _{4-n / 2} and volatile hydrocarbon oil (Patent Document 1), R ₃ SiO _1/2 units and SiO _4/2 units Skin cosmetic containing a resin and a volatile silicone oil (Patent Document 2), R ₂ SiO _2/2 units, RSiO _3/2 units, and SiO _4/2 units at least two types, and optionally terminal R ₃ SiO Sunscreen cosmetics (Patent Document 3) containing silicone resin blocked with _1/2 unit, volatile oil and UV absorber and / or UV scattering agent, 70 mol% or more of R ₃ SiO _1/2 unit and SiO made _4/2, and the molar ratio of _R 3 _{SiO 1/2} units and _{SiO 4/2} units contains 1 to 70 wt% organic silicone resin is 0.5 / 1 to 1.5 / 1 Characterized by skin粧料 are (Patent Document 4), and the like known. Although these disclose that a film excellent in water resistance can be obtained, they are not disclosed in detail regarding the hardness and feel of the film due to the composition of the silicone resin.

Therefore, since these known techniques have SiO _4/2 units, there is a problem that it is easy to give a touch that is conspicuous from the hardness of the coating, and it is possible to improve the hardness and brittleness of the coating. _3/2 units 50 to 99 _mol%, made by blending a silicone resin R _{3 SiO 1/2} units is from 1 to 50 mol% cosmetics (Patent Document _{5), (a) R 3} SiO 1/2 A cosmetic comprising a unit and a silicone resin having a molar ratio of (B) RSiO _3/2 units of 1: 4.7 to 1: 7, a softening point of 50 to 110 ° C., and a weight average molecular weight of 8000 to 400,000. (Patent Document 6) has been proposed.

Since the crosslinking component is a silicone resin composed only of RSiO _3/2 units, the number of crosslinking points is small, and in order to improve the water resistance, sweat resistance, friction resistance, etc. more than before, the weight average It is necessary to make the molecular weight 8000 or more, and since the silanol groups remaining in the silicone resin exhibit thermosetting properties by long-term high-temperature heating, they are blocked with R ₃ SiCl or the like in order to reduce the silanol groups It is manufactured in the process.

Japanese Examined Patent Publication No. 04-59284 Japanese Patent Publication No. 06-15448 Japanese Patent Application Laid-Open No. 62-234012 JP-A-62-298511 Japanese Patent No. 2636538 Japanese Patent No. 5705538

  The present invention has been made in view of the above-mentioned problems, and since it does not become sticky at the time of application, it has good stretch, excellent use feeling, good water resistance, and good adhesion to the skin. The object is to provide a cosmetic that is excellent in durability and can prevent adhesion (secondary adhesion) to clothes or the like.

In order to achieve the above object, in the present invention, the structural unit is represented by the following general formulas (A), (B), (C), (D).
(A) (R ¹ ₃ SiO _1/2 ) a,
(B) (R ² ₂ SiO _2/2 ) b,
(C) (R ³ SiO _3/2 ) c and (D) (SiO _4/2 ) d
Wherein R ¹ , R ² and R ³ are independently selected from alkyl groups having 1 to 8 carbon atoms, aryl groups having 6 to 12 carbon atoms, and fluorine-substituted alkyl groups having 1 to 8 carbon atoms. Group,
a has a value of 0.2 to 0.5;
b has a value of 0.0 to 0.1;
c has a value of 0.3 to 0.6;
d has a value of 0.2 to 0.4;
The value of a + b + c + d is 1.0, the value of a / (c + d) is 0.3 to 0.9, and the value of c / d is 0.8 to 2.5)
A cosmetic comprising a silicone resin having a weight average molecular weight of 1500 to 20000.

  With such cosmetics, there is no stickiness when applied, good stretch, excellent use feeling, good water resistance, and good adhesion to the skin, so it has excellent makeup sustainability and is suitable for clothes, etc. The cosmetic can prevent adhesion (secondary adhesion).

  Moreover, it is preferable to contain the said silicone resin in 0.1-40 mass% of cosmetics total mass.

  If it is such a compounding quantity, it will become cosmetics which were especially excellent in makeup sustainability etc.

  Moreover, it is preferable that it further contains the oil agent chosen from silicone oil, hydrocarbon oil, ester oil, and glyceride oil.

  Thus, the cosmetic of the present invention can contain various oil agents depending on the purpose.

  Moreover, it is preferable that it further contains surfactant.

  Thus, it becomes easy to obtain an emulsion by containing surfactant.

  In this case, the surfactant is preferably a linear or branched organopolysiloxane whose hydrophilic group is polyoxyalkylene or polyglycerin, or an alkyl co-modified organopolysiloxane thereof.

  As the surfactant contained in the cosmetic of the present invention, these surfactants are particularly suitable.

  Moreover, it is preferable that the composition further comprises a composition comprising a crosslinked organopolysiloxane polymer and a liquid oil.

  Thus, the cosmetic of the present invention can contain the above-described composition according to the purpose.

  In this case, the crosslinked organopolysiloxane polymer may have a polyether group and / or a polyglycerin group.

  When the cosmetic composition of the present invention contains the above composition, the crosslinked organopolysiloxane polymer may have the above group.

Also, other than the silicone resin, R ₃ SiO _1/2 , R ₂ SiO _2/2 , RSiO _3/2 , and SiO _4/2
(R is the same as R ¹ above) Silicone selected from the group consisting of a silicone resin having a configuration selected from the above, a linear acrylic / silicone graft copolymer, and a linear acrylic / silicone block copolymer It is preferable that the film forming agent further be included.

  Thus, by containing a silicone film forming agent, the film forming ability of the cosmetic of the present invention can be further enhanced.

  Moreover, it is preferable that it further contains powder.

  Even when the cosmetic of the present invention contains powder, there is no change such as agglomeration of the powder, and the powder has excellent dispersion stability.

  Moreover, it is preferable that it further contains an ultraviolet absorption component.

  Such a cosmetic is a cosmetic that can effectively absorb ultraviolet rays.

  The cosmetic is preferably an aqueous, oily or emulsified skin care cosmetic, hair cosmetic, antiperspirant, makeup cosmetic, or UV protection cosmetic.

  Thus, the cosmetics of this invention can be made into various forms according to various cosmetics.

  If it is the cosmetics of the present invention, it does not become sticky at the time of application, has a good spread, is excellent in use feeling, has good water resistance, and has good adhesion to the skin. The cosmetic can prevent adhesion (secondary adhesion).

  Hereinafter, the present invention will be described in more detail.

  As mentioned above, there is no stickiness when applied, it has good spread, excellent touch feeling, good water resistance, and good adhesion to the skin, so it has excellent makeup sustainability and adheres to clothes ( There is a demand for cosmetics that can prevent secondary adhesion).

Silicone resins that can be blended into cosmetics are monofunctional R ₃ SiO _1/2 units, bifunctional R ₂ SiO _2/2 units, trifunctional RSiO _3/2 units, and tetrafunctional By adjusting the degree of crosslinking and the molecular weight by combining SiO _4/2 units, various shapes from liquid to solid can be designed. The present inventors have examined the composition of each unit in detail, and contain tetrafunctional SiO _4/2 units in a specific range of composition. Even at a low molecular weight, there is no stickiness, and there is no flexibility and brittleness. A film was obtained, and the production method could be easily produced in one stage, and a silicone resin having good stability over time could be found. Furthermore, by blending this into cosmetics, there is no stickiness at the time of application, it has good stretch, excellent use feeling, good water resistance, and good adhesion to the skin, so it has excellent makeup sustainability, The present inventors have found that it is possible to provide a cosmetic that can prevent adhesion to clothes or the like (secondary adhesion).

  Hereinafter, embodiments of the present invention will be described in detail, but the present invention is not limited thereto.

The cosmetic of the present invention has structural units represented by the following general formulas (A), (B), (C), (D)
(A) (R ¹ ₃ SiO _1/2 ) a,
(B) (R ² ₂ SiO _2/2 ) b,
(C) (R ³ SiO _3/2 ) c and (D) (SiO _4/2 ) d
A silicone resin having a weight average molecular weight of 1500 to 20000 (hereinafter also referred to as silicone resin (I)) is blended.

R ¹ , R ² and R ³ in the silicone resin (I) are independently an alkyl group having 1 to 8 carbon atoms, an aryl group having 6 to 12 carbon atoms, and a fluorine-substituted alkyl group having 1 to 8 carbon atoms. The group to be selected. Specifically, examples of the alkyl group having 1 to 8 carbon atoms include methyl group, ethyl group, propyl group, butyl group, pentyl group, hexyl group, heptyl group, and octyl group. A trifluoropropyl group etc. are mentioned as a C1-C8 fluorine-substituted alkyl group. Examples of the aryl group having 6 to 12 carbon atoms include a phenyl group and a tolyl group. Preferably, it is a C1-C3 alkyl group or a phenyl group, More preferably, it is chosen from a methyl group and a phenyl group. Further, 50% or more of R ¹ , R ² and R ³ are preferably methyl groups, and most preferably 70% or more of R ¹ , R ² and R ³ are methyl groups.

  The value of a + b + c + d is 1.0. a has a value of 0.2 to 0.5. If a is less than 0.2, the resin film becomes hard and brittle, and if it is more than 0.5, the resin film becomes sticky or becomes liquid. a is more preferably 0.25 to 0.40. b has a value of 0.0 to 0.1. When b is larger than 0.1, the resin film becomes sticky. b is more preferably 0.0 to 0.05. c has a value of 0.3 to 0.6. When c is smaller than 0.3, the resin film becomes hard and brittle, and when c is larger than 0.6, the resin film becomes sticky. c is more preferably 0.3 to 0.5. d has a value of 0.2 to 0.4. When d is smaller than 0.2, the resin film is sticky, and when d is larger than 0.4, the resin film becomes hard and brittle. d is more preferably 0.2 to 0.35.

  The value of a / (c + d) is 0.3 to 0.9. When a / (c + d) is smaller than 0.3, the resin film becomes hard and brittle, and when it is larger than 0.9, the resin film becomes sticky. a / (c + d) is more preferably 0.35 to 0.85. The value of c / d is 0.8 to 2.5. If c / d is less than 0.8, the resin film becomes hard and brittle, and if c / d is more than 2.5, the resin film becomes sticky. c / d is preferably 1.0 to 2.3.

The silicone resin (I) has a weight average molecular weight of 1500 to 20000. The weight average molecular weight is more preferably 2000 to 15000. This silicone resin (I) has no brittleness and can form a transparent, uniform and non-sticky film. In particular, since the silicone resin (I) contains tetrafunctional SiO _4/2 units in a specific range of composition, even if it has a low molecular weight (for example, less than 8000 weight average molecular weight), it is not sticky and flexible. A film without brittleness can be formed, and stability over time, water resistance and the like are improved. Therefore, the cosmetic of the present invention blended with this composition is not sticky when applied, has a good spread, has a good feeling on use, has good water resistance, and has good adhesion to the skin. Adhering to clothes, etc. (secondary adhesion) can be prevented. In addition, a weight average molecular weight can be calculated | required as a weight average molecular weight of polystyrene conversion in a gel permeation chromatography (GPC) analysis.

  Since the silicone resin (I) is usually a solid, it may be a pulverized solid or a solution diluted with an oil that can be used in cosmetics.

The silicone resin (I) can be produced by a known method. That is, the organic silicon compound represented by the following general formulas (1) and (2) and the compound represented by the following formula (3), the following formula (4), and the following formula (5) are hydrolyzed and subjected to a condensation reaction. Can be manufactured. In addition, about the compound shown by following formula (3)-(5), it may replace with the said compound and may use the partial hydrolyzate, and may use the partial hydrolyzate in addition to the said compound. .
R ¹ ₃ SiOSiR ¹ ₃ (1)
R ¹ ₃ SiOR ⁴ (2)
R ² ₂ Si (OR ⁴ ) ₂ (3)
R ³ Si (OR ⁴ ) ₃ (4)
Si (OR ⁴ ) ₄ (5)
(R ¹ , R ² and R ³ are the same as above, and R ⁴ is any one of a hydrogen atom and an alkyl group having 1 to 4 carbon atoms)

  This hydrolysis and condensation reaction is preferably performed under acidic conditions, and an acidic substance is added as a catalyst. Examples of the acidic substance include hydrochloric acid, sulfuric acid, p-toluenesulfonic acid, methanesulfonic acid, trifluoromethanesulfonic acid, phosphoric acid, acetic acid, and citric acid. The amount used may be small, and is preferably in the range of 0.001 to 10% by mass of the entire system.

  Moreover, a solvent can be used when performing a hydrolysis and a condensation reaction. Examples of the solvent include hydrocarbon solvents such as toluene, xylene and isoparaffin, ether solvents such as tetrahydrofuran, and alcohol solvents such as methanol, ethanol, (iso) propyl alcohol and butanol. The solvent is preferably ethanol or (iso) propyl alcohol.

  Specific examples of the hydrolysis and condensation reaction include the following methods. First, a solvent and a hydrolyzable raw material are charged into a reactor, an acid is added, and water is added dropwise with stirring. The temperature at which water is dropped is preferably 0 to 80 ° C., particularly preferably 0 to 50 ° C., and the amount of water to be dropped is in the range of 0.6 to 2.0 in terms of molar ratio to the hydrolyzable group. preferable. After dripping water, it heats at 50-150 degreeC, Preferably it is 80-120 degreeC for 2 to 8 hours, and a hydrolysis and a condensation reaction are performed. After hydrolysis, the acid is removed. For removing the acid, a method of neutralizing with an alkali metal carbonate, alkali metal bicarbonate, alkali metal hydroxide or the like can be used. The acid can also be removed in the water washing step. After neutralizing the acid, an oil agent that can be used in cosmetics is added, and only the generated alcohols and excess water are removed by heating under normal pressure or reduced pressure to obtain a silicone resin solution. Moreover, the oil agent which can be used for cosmetics can also be added at the time of a hydrolysis and a condensation reaction.

  Since the silicone resin (I) is usually a solid, it is preferably a solution diluted with an oil that can be used in cosmetics, such as octamethyltrisiloxane, decamethyltetrasiloxane, decamethylcyclopentasiloxane, tristrimethylsiloxymethylsilane, etc. These volatile siloxane compounds and volatile hydrocarbon compounds such as isododecane can be used.

  In the cosmetic of the present invention, the blending amount of the silicone resin (I) is preferably in the range of 0.1 to 40% by mass with respect to the total mass of the cosmetic. If it is such a compounding quantity, it will become cosmetics which were especially excellent in makeup sustainability etc. This blending amount is more preferably in the range of 0.5 to 20% by mass.

  In the cosmetic of the present invention, one or more oil agents can be blended depending on the purpose. Solid, semi-solid, and liquid oils can be used as long as they are used in ordinary cosmetics. For example, natural animal and vegetable oils and fats, semi-synthetic oils and fats, hydrocarbon oils, higher fatty acids, and higher alcohols. , Ester oils, glyceride oils, conventional silicone oils, and fluorine-based oils can be used.

Examples of natural animal and vegetable oils and semi-synthetic oils and fats include avocado oil, linseed oil, almond oil, ibotarou, eno oil, olive oil, cacao butter, kapok wax, kaya oil, carnauba wax, liver oil, candelilla wax, refined candelilla wax, beef tallow , Beef leg fat, beef bone fat, hydrogenated beef tallow, kyounin oil, whale wax, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugarcane wax, sasanqua oil, safflower oil, shea butter, cinnagar oil, Cinnamon oil, jojoba wax, squalane, squalene, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil, nukarou, germ oil, horse fat, persic Oil, palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid methyl ester, sunflower oil, Walnut oil, Bayberry wax, Jojoba oil, Macadamia nut oil, Beeswax, Mink oil, Meadow foam oil, Cottonseed oil, Cotton wax, Mole, Owl kernel oil, Montan wax, Palm oil, Hardened palm oil, Tri-coconut oil Fatty acid glyceride, Sheep fat, Peanut oil Lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, hard lanolin, lanolin acetate, lanolin acetate alcohol, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, egg yolk oil Etc.
However, POE means polyoxyethylene (the same applies hereinafter).

  Examples of the hydrocarbon oil include linear, branched, and volatile hydrocarbon oils. Specifically, ozokerite, α-olefin oligomer, light isoparaffin, isododecane, isohexadecane, light liquid isoparaffin, squalane. , Synthetic squalane, vegetable squalane, squalene, ceresin, paraffin, paraffin wax, polyethylene wax, polyethylene / polypropylene wax, (ethylene / propylene / styrene) copolymer, (butylene / propylene / styrene) copolymer, liquid paraffin, liquid isoparaffin, pristane , Polyisobutylene, hydrogenated polyisobutene, microcrystalline wax, petrolatum, etc .; higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, urine Decylene acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid, 12-hydroxystearic acid.

  As higher alcohols, lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyl decanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol, Examples include cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (batyl alcohol), monooleyl glyceryl ether (ceracyl alcohol), and the like.

  Ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, di-2-ethyl Ethylene glycol hexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecyl oleate Decyl oleate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyrate , Isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isononyl isononanoate, isotridecyl isononanoate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyl palmitate Decyl, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, laurin Acid ethyl, hexyl laurate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, lauroyl sarcosine iso Lopyl ester, diisostearyl malate, etc .; As glyceride oil, acetoglyceryl, glyceryl triisooctanoate, glyceryl triisostearate, glyceryl triisopalmitate, glyceryl tribehenate, glyceryl monostearate, glyceryl di-2-heptylundecanoate Glyceryl trimyristate, and diglyceryl myristate isostearate.

  Silicone oils include dimethylpolysiloxane, tristrimethylsiloxymethylsilane, caprylylmethicone, phenyltrimethicone, tetrakistrimethylsiloxysilane, methylphenylpolysiloxane, methylhexylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane / methylphenylsiloxane Low to high viscosity linear or branched organopolysiloxanes such as copolymers, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, tetramethyl Cyclic organopolysiloxanes such as tetraphenylcyclotetrasiloxane, amino-modified organopolysiloxanes, pyrrolidone-modified resins Silicone rubbers such as ganopolysiloxane, pyrrolidone carboxylic acid modified organopolysiloxane, high degree of polymerization gum-like dimethylpolysiloxane, gum-like amino-modified organopolysiloxane, gum-like dimethylsiloxane / methylphenylsiloxane copolymer, and silicone gum And cyclic organopolysiloxane solutions of rubber, higher alkoxy-modified silicones such as stearoxy silicone, higher fatty acid-modified silicones, alkyl-modified silicones, long-chain alkyl-modified silicones, amino acid-modified silicones, and fluorine-modified silicones.

  Examples of the fluorinated oil include perfluoropolyether, perfluorodecalin, and perfluorooctane. The blending amount of these oil agents varies depending on the agent system, but a range of 1 to 98% by mass of the entire cosmetic is suitable.

  Water can be blended in the cosmetic of the present invention depending on the purpose. Although the compounding quantity changes with agent systems, the range of 1-95 mass% of the whole cosmetics is suitable.

  In the cosmetic of the present invention, one or more kinds of lower alcohols having 2 to 5 carbon atoms and polyhydric alcohols having 2 to 10 carbon atoms can be used depending on the purpose. Examples of the alcohol include lower alcohols such as ethanol and isopropanol, sugar alcohols such as sorbitol and maltose, sterols such as cholesterol, sitosterol, phytosterol, and lanosterol, butylene glycol, propylene glycol, dibutylene glycol, pentylene glycol, and the like. There are polyhydric alcohols. As a compounding quantity, the range of 0.1-98 mass% of the whole cosmetics is suitable.

  In the cosmetic of the present invention, a water-soluble or water-swellable polymer can be used depending on the purpose. For example, gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), starch (rice, corn, potato, wheat, etc.), alge colloid, trant gum, locust bean gum, etc. Polymers, xanthan gum, dextran, succinoglucan, pullulan and other microbial polymers, collagen, casein, albumin, gelatin and other animal polymers, carboxymethyl starch, methylhydroxypropyl starch and other starch polymers, methylcellulose , Ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nitrocellulose, cellulose Sodium sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose polymer such as cellulose powder, alginic acid polymers such as sodium alginate and propylene glycol alginate, vinyl polymers such as polyvinyl methyl ether and carboxyvinyl polymer, polyoxyethylene Polymers, polyoxyethylene polyoxypropylene copolymer-based polymers, acrylic polymers such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, acryloyldimethyltaurine salt copolymer, other synthetic water-soluble materials such as polyethyleneimine and cationic polymers Polymer, bentonite, magnesium aluminum silicate, montmorillonite, beidellite, nontronite, saponite, hectorite, silicic anhydride There is an inorganic-based water-soluble polymers, and the like.

  Among them, plant polymer, microbial polymer, animal polymer, starch polymer, cellulose polymer, alginic acid polymer, polyoxyethylene polyoxypropylene copolymer polymer, acrylic polymer, and One or more water-soluble thickeners selected from inorganic water-soluble polymers are preferably used. As a compounding quantity in the case of using a water-soluble or water-swellable polymer, the range of 0.1 to 25% by mass of the entire cosmetic is suitable.

  In the cosmetic of the present invention, one or more powders can be used depending on the purpose. As powder, if it is used for normal cosmetics, its shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particle structure (porous, Any non-porous) can be used, for example, inorganic powder, organic powder, surfactant metal salt powder, colored pigment, pearl pigment, metal powder pigment, tar dye, natural color Examples thereof include powders selected from pigments and the like. Even when the cosmetic of the present invention contains powder, there is no change such as agglomeration of the powder, and the powder has excellent dispersion stability.

  Specifically, as the inorganic powder, titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, Muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, Metal tungstate, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, silica, etc. It is below.

  Organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethylmethacrylate powder, cellulose, silk powder, nylon powder, 12 Nylon, 6 nylon, silicone powder, styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin , Microcrystalline fiber powder, starch powder, lauroyl lysine and the like.

  Surfactant metal salt powder (metal soap) includes zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, zinc sodium cetyl phosphate, etc. Can be mentioned.

  Examples of colored pigments include inorganic red pigments such as iron oxide, iron hydroxide, and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, black iron oxide, carbon black, etc. Lake inorganic black pigments, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue, and tar dyes And a synthetic resin powder obtained by compounding these powders.

  Examples of the pearl pigment include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, and titanium oxide-coated colored mica.

  Examples of the metal powder pigment include aluminum powder, copper powder, and stainless steel powder.

  As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 , Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207 and the like.

  Examples of natural pigments include carminic acid, laccaic acid, calsamine, bradylin, and crocin.

  These powders can be used as a composite of powders or treated with general oils, silicone oils, fluorine compounds, surfactants, etc., and directly bonded to hydrolyzable silyl groups and silicon atoms. Treated with alkyl groups having hydrogen atoms, hydrolyzable silyl groups or linear and / or branched organopolysiloxanes having hydrogen atoms directly bonded to silicon atoms, hydrolyzable silyl groups or silicon atoms Linear and / or branched organopolysiloxanes with hydrogen atoms directly bonded and co-modified with long-chain alkyls, hydrogen atoms directly bonded to hydrolyzable silyl groups and silicon atoms, and cooxylated with polyoxyalkylenes Modified linear and / or branched organopolysiloxanes, hydrolyzable silyl groups and acrylic-silicos having hydrogen atoms bonded directly to silicon atoms May be used alone, or two or more as necessary system copolymer.

  Moreover, as a compounding quantity of powder, the range of 0.1-99 mass% of the whole cosmetics is suitable. In particular, the blending amount in the case of a powdered solid cosmetic is preferably in the range of 80 to 99% by mass of the entire cosmetic.

  In the cosmetic of the present invention, one or more surfactants can be used depending on the purpose. Thus, it becomes easy to obtain an emulsion by containing surfactant. Such surfactants include anionic, cationic, nonionic and amphoteric active agents, but are not particularly limited, and any surfactant can be used as long as it is used in normal cosmetics. Things can also be used.

  Examples of anionic surfactants include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, condensates of amino acids and fatty acids, alkane sulfonates, alkene sulfonates, and fatty acid esters. Sulfonate, fatty acid amide sulfonate, formalin condensation sulfonate, alkyl sulfate, secondary higher alcohol sulfate, alkyl and allyl ether sulfate, fatty acid sulfate, fatty acid alkyl Sulfate ester salt of roll amide, sulfate ester salt such as funnel oil, alkyl phosphate, ether phosphate, alkyl allyl ether phosphate, amide phosphate, N-acyl lactate, N-acyl sarcosine salt, N- Acyl amino acid based activators It is below.

  Examples of the cationic surfactant include amine salts such as alkylamine salts, polyamines and amino alcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts and the like.

  Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, methyl glucoside fatty acid ester, alkyl polyglucoside, polyoxyethylene alkyl Ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, Polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, poly Oxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, linear or branched polyoxyalkylene modified organopolysiloxane, linear or branched polyoxyalkylene / alkyl co-modified Examples include organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, linear or branched polyglycerin / alkyl co-modified organopolysiloxane, alkanolamide, sugar ether, sugar amide and the like.

  Examples of the amphoteric surfactant include betaine, phosphatidylcholine, aminocarboxylate, imidazoline derivative, amidoamine type and the like. Among these surfactants, a linear or branched organopolysiloxane having a polyoxyalkylene chain or polyglycerin chain as a hydrophilic group (hydrophilic group) in the molecule, or an alkyl co-modified organopolysiloxane thereof. Is preferred. Examples of the alkyl co-modified organopolysiloxane include linear or branched organopolysiloxane having a long-chain alkyl group having 6 to 20 carbon atoms in addition to the above hydrophilic group.

  Further, in these surfactants, the content of the hydrophilic polyoxyalkylene group or polyglycerin residue preferably occupies 10 to 70% by mass in the molecule. A range of 0.1 to 20% by mass, particularly preferably 0.2 to 10% by mass is suitable.

In the cosmetic of the present invention, as a silicone film forming agent, R ₃ SiO _1/2 unit, R ₂ SiO _2/2 unit, RSiO _3/2 unit other than acrylic silicone resin and the above-mentioned silicone resin (I) And a silicone resin selected from silicone resins (hereinafter also referred to as silicone resin (II)) selected from SiO _4/2 units (R is the same as R ¹ described above). The acrylic silicone resin is an acrylic / silicone graft copolymer or an acrylic / silicone block copolymer. The acrylic silicone resin is preferably linear. Also, use an acrylic silicone resin containing in the molecule at least one selected from pyrrolidinyl groups, long-chain alkyl groups, polyoxyalkylene groups, and anionic groups such as fluoroalkyl groups and carboxyl groups. You can also. Thus, by containing a silicone film forming agent, the film forming ability of the cosmetic of the present invention can be further enhanced.

As the silicone resin (II), a resin composed of R ₃ SiO _1/2 unit, R ₂ SiO _2/2 unit and SiO _4/2 unit, and composed of R ₃ SiO _1/2 unit and RSiO _3/2 unit Resins composed of R ₃ SiO _1/2 units, R ₂ SiO _2/2 units and RSiO _3/2 units, R ₃ SiO _1/2 units, R ₂ SiO _2/2 units, RSiO _{3 /} Resins composed of ₂ units and SiO _4/2 units may be mentioned. Moreover, the network silicone which contains in a molecule | numerator at least 1 sort (s) selected from a pyrrolidinyl group, a long-chain alkyl group, a polyoxyalkylene group, a fluoroalkyl group, and an amino group can also be used. As a compounding quantity in the case of using a silicone film formation agent, 0.1-20 mass% is preferable with respect to the total amount of cosmetics, More preferably, it is 1-10 mass%.

In the cosmetic of the present invention, a composition comprising one or more cross-linked organopolysiloxane polymers and a liquid oil at room temperature can be used depending on the purpose. In this case, the crosslinked organopolysiloxane polymer may have a polyether group and / or a polyglycerin group. Moreover, you may mix and use the crosslinked organopolysiloxane polymer which has said group, and the crosslinked organopolysiloxane polymer which does not have said group. These cross-linked organopolysiloxane polymers preferably swell with liquid oil containing its own weight or more with respect to liquid oil. As liquid oil, fluorine-type oils, such as the said liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, a semisynthetic oil, can be used, for example, 0.65 mm < ² > / sec (25 degreeC) -100. Low viscosity silicone oil of 0.0 mm ² / sec (25 ° C.), liquid oil such as liquid paraffin, squalane, isododecane and isohexadecane, glyceride oil such as trioctanoin, isotridecyl isononanoate, N-acyl glutamate, lauroyl sarcosine Examples thereof include ester oils such as acid esters and natural animal and vegetable oils such as macadamia nut oil. In addition, the cross-linking agent of this cross-linked organopolysiloxane polymer has a cross-linked structure by reacting with hydrogen atoms having two or more vinyl reactive sites in the molecule and directly bonded to silicon atoms. It is preferable to form. Those having two or more vinyl reactive sites in the molecule include organopolysiloxanes having two or more vinyl groups in the molecule, polyoxyalkylenes having two or more allyl groups in the molecule, Examples include polyglycerin having two or more allyl groups, α, ω-alkenyl diene, and the like. In addition, a crosslinking agent having at least one selected from the group consisting of a polyoxyalkylene group, a polyglycerin residue, a long-chain alkyl group, an alkenyl group, an aryl group, and a fluoroalkyl group can also be used. As a compounding quantity in the case of using the composition which consists of a crosslinking | crosslinked organopolysiloxane polymer and a liquid oil agent at room temperature, 0.1-80 mass% is preferable with respect to the total amount of cosmetics, More preferably, it is 1-50 mass. %.

  The cosmetic of the present invention includes an olefin wax having an unsaturated group obtained by reacting one or two or more α-olefins with a diene depending on the purpose, and an organo group having one or more SiH bonds per molecule. Silicone-modified olefin wax obtained by addition reaction with hydrogen polysiloxane can be included. The α-olefin preferably has 2 to 12 carbon atoms such as ethylene, propylene, 1-butene, 1-hexene, 4-methyl 1-pentene, and the diene includes butadiene, isoprene, 1,4-hexadiene, vinyl norbornene, Ethylidene norbornene, dicyclopentadiene, and the like are preferable. As the organohydrogenpolysiloxane having a SiH bond, a linear or siloxane branched structure can be used.

  Furthermore, the cosmetics of the present invention include components used in normal cosmetics, oil-soluble gelling agents, antiperspirants, ultraviolet absorbing components (such as ultraviolet absorbers and ultraviolet absorbing scattering agents), moisturizers, antibacterial and antiseptics. Agent, antibacterial agent, fragrance, salt, antioxidant, pH adjuster, chelating agent, refreshing agent, anti-inflammatory agent, skin beautifying agent (whitening agent, cell activator, rough skin improving agent, blood circulation promoter, skin astringent, Antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, hair solidifying agents and the like can be added.

  Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, and dextrin palmitate , Dextrin stearate, dextrin fatty acid ester such as dextrin 2-ethylhexanoic acid palmitate, sucrose fatty acid ester such as sucrose palmitate, sucrose stearate, fructooligosaccharide stearate, 2-ethyl fructooligosaccharide Fructooligosaccharide fatty acid esters such as hexanoic acid esters, benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol, dimethylbenzyl dodecyl ammo Examples thereof include gelling agents selected from organically modified clay minerals such as nium montmorillonite clay and dimethyl dioctadecyl ammonium montmorillonite clay.

  Examples of the antiperspirant include an antiperspirant selected from aluminum chlorohydrate, aluminum chloride, aluminum sesquichlorohydrate, zirconyl hydroxychloride, aluminum zirconium hydroxychloride, aluminum zirconium glycine complex, and the like.

  Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic acid UV absorbers such as methyl anthranilate, salicylic acid UV absorbers such as methyl salicylate, octyl salicylate and trimethylcyclohexyl salicylate, and paramethoxysilicate. Cinnamic acid UV absorbers such as octyl cinnamate, benzophenone UV absorbers such as 2,4-dihydroxybenzophenone, urocanic acid UV absorbers such as ethyl urocanate, 4-t-butyl-4'-methoxy- Examples include dibenzoylmethane-based ultraviolet absorbers such as dibenzoylmethane, phenylbenzimidazole sulfonic acid, triazine derivatives and the like, and examples of ultraviolet absorption / scattering agents include fine particle titanium oxide, fine particle iron-containing titanium oxide, fine particle zinc oxide, fine particle cerium oxide, and the like. Them Complex etc., powder can be mentioned that absorb scattering ultraviolet rays can also be used a dispersion obtained by dispersing in advance oil powder that absorbs scattered these ultraviolet.

  Moisturizers include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, pentylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxy Examples include ethylene methyl glucoside, polyoxypropylene methyl glucoside, egg yolk lecithin, soybean lecithin, phosphatidyl choline, phosphatidyl ethanolamine, phosphatidyl serine, phosphatidyl glycerol, phosphatidylinositol, sphingophospholipid and the like.

  Antibacterial and antiseptics include paraoxybenzoic acid alkyl esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc., and antibacterial agents include benzoic acid, salicylic acid, carboxylic acid, sorbic acid, paraoxybenzoic acid alkyl ester , Parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, phenoxyethanol and the like.

  Examples of the fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant fragrances separated from flowers, leaves, materials, skins, etc .; animal fragrances such as musk and sivet. Synthetic perfumes such as hydrocarbons such as monoterpenes; alcohols such as aliphatic alcohols and aromatic alcohols; aldehydes such as terpene aldehydes and aromatic aldehydes; ketones such as alicyclic ketones; esters such as terpene esters Lactones; phenols; oxides; nitrogen-containing compounds; acetals and the like.

  Examples of the salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, and the like of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; Salts of organic acids such as dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, stearic acid; amine salts and amino acid salts include, for example, salts of amines such as triethanolamine, and amino acids such as glutamic acid There is salt. In addition, a salt such as hyaluronic acid and chondroitin sulfate, an aluminum zirconium glycine complex, and the like, and an acid-alkali neutralized salt used in cosmetic preparations can also be used.

  Antioxidants include tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, etc., and pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, Potassium carbonate, sodium bicarbonate, ammonium bicarbonate, etc., chelating agents such as alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc., refreshing agents such as L-menthol, camphor, etc., anti-inflammatory Examples of the agent include allantoin, glycyrrhizic acid and salts thereof, glycyrrhetinic acid and stearyl glycyrrhetinic acid, tranexamic acid, and azulene.

  As skin beautifying ingredients, placenta extract, whitening agents such as arbutin, glutathione, and yukinoshita extract, royal jelly, photosensitizer, cholesterol derivatives, cell activators such as calf blood extract, rough skin improver, nonyl acid wallenylamide, Nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, Examples thereof include blood circulation promoters such as acetylcholine, verapamil, cephalanthin and γ-oryzanol, skin astringents such as zinc oxide and tannic acid, and antiseborrheic agents such as sulfur and thianthol.

  Vitamins such as vitamin A oil, retinol, retinol acetate, retinol palmitate, etc., vitamin B2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmi Vitamin B6 such as tate, vitamin B12 and derivatives thereof, vitamin B such as vitamin B15 and derivatives thereof, L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, L- Vitamin C such as ascorbic acid phosphoric acid diester dipotassium, vitamin D such as ergocalciferol, cholecalciferol, α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate , Vitamin E such as dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, nicotinic acids such as vitamin H, vitamin P, nicotinic acid, benzyl nicotinate, nicotinamide, calcium pantothenate, D-pant There are pantothenic acids such as tenenyl alcohol, pantothenyl ethyl ether, acetyl pantothenyl ethyl ether, biotin and the like.

As amino acids, glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, tryptophan, etc., nucleic acid, deoxyribonucleic acid, etc., hormone, estradiol , Etenyl estradiol and the like.
Examples of the inclusion compound include cyclodextrin and the like.

  Examples of the hair solidifying agent include amphoteric, anionic, cationic and nonionic polymer compounds, such as polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, and the like. Acidic vinyl ether polymers such as vinyl ether / maleic anhydride alkyl half ester copolymer, acidic polyvinyl acetate polymers such as vinyl acetate / crotonic acid copolymer, (meth) acrylic acid / alkyl (meth) acrylate copolymer Polymer, acidic acrylic polymer such as (meth) acrylic acid / alkyl (meth) acrylate / alkylacrylamide copolymer, N-methacryloylethyl-N, N-dimethylammonium / α-N-methylcarboxybetaine / alkyl (Meth) acrylate copolymer, hydroxy Propyl (meth) acrylate / butylaminoethyl methacrylate / amphoteric acrylic polymer compounds such as acrylic acid octyl amide copolymers. In addition, naturally derived polymer compounds such as cellulose or derivatives thereof, keratin and collagen or derivatives thereof can also be suitably used.

  In the present invention, the dosage form or form of the cosmetic is not particularly limited, and is aqueous, oily, emulsified (water-in-oil emulsion, oil-in-water emulsion, non-water emulsion, W / O / W or O / W / O Multi-emulsions, etc.), suspensions, pastes, and solids.

  The use of the cosmetic may be arbitrary. For example, skin care cosmetics such as lotion, emulsion, cream, cleansing, pack, oil liquid, massage, beauty essence, beauty oil, hand cream, lip balm, wrinkle concealment; makeup base, concealer, white powder, powder foundation, Makeup cosmetics such as liquid foundation, cream foundation, oily foundation, blusher, eye shadow, mascara, eyeliner, eyebrow, lipstick, etc .; hair cosmetics (hair cosmetics) such as shampoo, rinse, treatment, set agent; sunscreen UV protection cosmetics such as oils, sunscreen emulsions, and sunscreen creams; in addition, detergents, deodorants, antiperspirants, and the like.

EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated more concretely, this invention is not limited to the following Example. The molar ratio of R ₃ SiO _1/2 unit, R ₂ SiO _2/2 unit, RSiO _3/2 unit, and SiO _4/2 unit was calculated from Si-NMR.

[Example 1]
The reactor was charged with 150 g of hexamethyldisiloxane, 415 g of triethoxymethylsilane, 245 g of ethyl polysilicate containing 40% of SiO ₂ , and 300 g of IPA (isopropyl alcohol) as a solvent, and 6 g of methanesulfonic acid was added thereto. It cooled to -20 degreeC and 180g of water was dripped, stirring. After completion of dropping, the mixture was heated at 70 to 90 ° C. for 5 hours for hydrolysis and condensation to obtain a silicone resin solution. Next, after adding 9.6 g of 25% aqueous sodium hydroxide solution and 1.24 g of calcium carbonate to neutralize the acid, 400 g of decamethylcyclopentasiloxane was added and heated to 130 ° C. After removing water, it was cooled. Further, after distilled off under reduced pressure, diluted adjusted to silicone resin concentration of 50% with decamethylcyclopentasiloxane, by filtration, the weight average molecular weight _{9350, (CH 3) 3 SiO} 1/2 units: CH ₃ A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of SiO _3/2 units: SiO _4/2 units of 0.32: 0.40: 0.28 was obtained.

[Example 2]
After performing hydrolysis, condensation, and neutralization in the same manner as in Example 1 except that the raw materials were changed to 135 g of hexamethyldisiloxane, 415 g of triethoxymethylsilane, and 175 g of ethyl polysilicate containing 40% of SiO ₂ , tris 400 g of trimethylsiloxymethylsilane was added and heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Furthermore, after distilling off under reduced pressure, dilution adjustment was carried out with tristrimethylsiloxymethylsilane so that the silicone resin concentration was 50%, followed by filtration to obtain a weight average molecular weight 2260, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO A 50% silicone resin tristrimethylsiloxymethylsilane solution having a molar ratio of _3/2 units: SiO _4/2 units of 0.30: 0.44: 0.26 was obtained.

Example 3
Hydrolysis and condensation in the same manner as in Example 1 except that 100 g of hexamethyldisiloxane, 220 g of triethoxymethylsilane, 321 g of trifluoropropyltriethoxysilane, and 185 g of ethyl polysilicate containing 40% SiO ₂ were used. After the summation, 450 g of isododecane was added, and the mixture was heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Further, after distilling off under reduced pressure, dilution adjustment is performed with isododecane so that the silicone resin concentration becomes 50%, and then filtration is performed to filter the weight average molecular weight 3950, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO _3/2 unit. A 50% silicone resin isododecane solution having a molar ratio of: CF ₃ C ₂ H ₄ SiO _3/2 units: SiO _4/2 units of 0.25: 0.25: 0.25: 0.25 was obtained.

Example 4
Hydrolysis, condensation and neutralization were carried out in the same manner as in Example 1 except that the raw material was changed to 200 g of hexamethyldisiloxane, 120 g of diethoxydiphenylsilane, 274 g of triethoxymethylsilane, and 232 g of ethyl polysilicate containing 40% SiO _2. After the operation, 450 g of isododecane was added, and the mixture was heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Further, after distilling off under reduced pressure, dilution adjustment is performed with isododecane so that the silicone resin concentration becomes 50%, followed by filtration to obtain a weight average molecular weight of 3210, (CH ₃ ) ₃ SiO _1/2 unit: (C ₆ H ₅ ) _2. A 50% silicone resin isododecane solution having a molar ratio of SiO _2/2 units: CH ₃ SiO _3/2 units: SiO _4/2 units of 0.40: 0.10: 0.25: 0.25 was obtained.

Example 5
After carrying out hydrolysis, condensation and neutralization in the same manner as in Example 1 except that the raw material was changed to 150 g of hexamethyldisiloxane, 423 g of triethoxymethylsilane, and 158 g of ethyl polysilicate containing 40% of SiO ₂ , decamethyl was obtained. After adding 420 g of cyclopentasiloxane and heating to 130 ° C., the produced ethanol and excess water were removed, followed by cooling. Furthermore, after depressurizingly distilling, after adjusting the dilution with decamethylcyclopentasiloxane so that the silicone resin concentration becomes 50%, the weight average molecular weight 4330, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO by filtering. A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of _3/2 units: SiO _4/2 units of 0.35: 0.45: 0.20 was obtained.

Example 6
After carrying out hydrolysis, condensation and neutralization in the same manner as in Example 1 except that the raw material was changed to 100 g of hexamethyldisiloxane, 308 g of triethoxymethylsilane, and 297 g of ethyl polysilicate containing 40% of SiO ₂ , decamethyl was obtained. After adding 350 g of cyclopentasiloxane and heating to 130 ° C., the produced ethanol and excess water were removed, followed by cooling. Furthermore, after depressurizingly distilling, after adjusting the dilution with decamethylcyclopentasiloxane so that the silicone resin concentration becomes 50%, the weight average molecular weight 4550, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO by filtration. A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of _3/2 units: SiO _4/2 units of 0.25: 0.35: 0.40 was obtained.

Example 7
After carrying out hydrolysis, condensation and neutralization in the same manner as in Example 1 except that the raw materials were changed to 100 g of hexamethyldisiloxane, 525 g of triethoxymethylsilane, and 179 g of ethyl polysilicate containing 40% of SiO ₂ , decamethyl was obtained. After adding 430 g of cyclopentasiloxane and heating to 130 ° C., ethanol and excess water produced were removed, and then cooled. Further, after distilling off under reduced pressure, dilution adjustment with decamethylcyclopentasiloxane was performed so that the silicone resin concentration was 50%, followed by filtration to obtain a weight average molecular weight of 5870, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of _3/2 units: SiO _4/2 units of 0.23: 0.55: 0.22 was obtained.

Example 8
Hydrolysis, condensation, and neutralization were performed in the same manner as in Example 1 except that the raw material was changed to 225 g of hexamethyldisiloxane, 46 g of diethoxydimethylsilane, 330 g of triethoxymethylsilane, and 185 g of ethyl polysilicate containing 40% SiO _2. After the operation, 450 g of isododecane was added, and the mixture was heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Further, after distilling off under reduced pressure, dilution adjustment is performed with isododecane so that the silicone resin concentration becomes 50%, followed by filtration to obtain a weight average molecular weight of 9200, (CH ₃ ) ₃ SiO _1/2 unit: (CH ₃ ) ₂ SiO ₂ A 50% silicone resin isododecane solution having a molar ratio of _{/ 2} units: CH ₃ SiO _3/2 units: SiO _4/2 units of 0.45: 0.05: 0.30: 0.20 was obtained.

Example 9
Raw hexamethyldisiloxane 120 g, diethyl diethoxy silane 18 g, triethoxy methyl silane 264 g, except for using ethyl polysilicate 278g containing SiO ₂ minutes 40% similarly hydrolyzed as in Example 1, condensation, neutralization Thereafter, 350 g of isododecane was added and heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Further, after distilled off under reduced pressure, diluted adjusted to the silicone resin concentration of 50% by isododecane, weight average molecular weight 3680 by _{filtration, (CH 3)} 3 _{SiO 1/2 units: (CH} 3) ₂ SiO 2 A 50% silicone resin isododecane solution having a molar ratio of _{/ 2} units: CH ₃ SiO _3/2 units: SiO _4/2 units of 0.30: 0.025: 0.30: 0.375 was obtained.

Example 10
Hydrolysis, condensation and neutralization were carried out in the same manner as in Example 1 except that the raw material was changed to 100 g of hexamethyldisiloxane, 37 g of diethyldiethoxysilane, 439 g of triethoxymethylsilane, and 148 g of ethyl polysilicate containing 40% of SiO _2. After the operation, 360 g of decamethylcyclopentasiloxane was added and heated to 130 ° C., and the produced ethanol and excess water were removed, followed by cooling. Furthermore, after distilling off under reduced pressure, dilution adjustment was performed with decamethylcyclopentasiloxane so that the silicone resin concentration was 50%, and then filtered to obtain a weight average molecular weight of 5000, (CH ₃ ) ₃ SiO _1/2 unit: (CH ₃ ) ₂ SiO _2/2 units: CH ₃ SiO _3/2 units: 50% silicone resin decamethylcyclopentasiloxane having a molar ratio of SiO _4/2 units of 0.25: 0.05: 0.50: 0.20 A solution was obtained.

[Comparative Example 1]
350 g of hexamethyldisiloxane as raw materials, 435 g of triethoxymethylsilane, 180 g of ethyl polysilicate containing 40% of SiO ₂ , and 300 g of IPA as a solvent are charged into a reactor, and 6 g of methanesulfonic acid is added and cooled to 10 to 20 ° C. While stirring, 180 g of water was added dropwise. After completion of dropping, the mixture was heated at 70 to 90 ° C. for 5 hours for hydrolysis and condensation to obtain a silicone resin solution. Next, 9.6 g of 25% aqueous sodium hydroxide solution and 1.24 g of calcium carbonate were added to neutralize the acid, 600 g of decamethylcyclopentasiloxane was added, and the mixture was heated to 130 ° C. After removing water, it was cooled. Further, after distilled off under reduced pressure, diluted with decamethylcyclopentasiloxane, by filtration, the weight average molecular weight _{3400, (CH 3) 3 SiO} 1/2 _units: CH _{3 SiO 3/2} units: SiO _{4 /} A 50% silicone resin decamethylcyclopentasiloxane solution having a ₂ unit molar ratio of 0.55: 0.30: 0.15 was obtained.

[Comparative Example 2]
Except that the raw materials were changed to 120 g of hexamethyldisiloxane, 435 g of triethoxymethylsilane, and 180 g of ethyl polysilicate containing 40% of SiO ₂ , the same operation as in Comparative Example 1 was performed, and the weight average molecular weight 4180, (CH ₃ ) ₃ SiO A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of _1/2 unit: CH ₃ SiO _3/2 unit: SiO _4/2 unit of 0.30: 0.30: 0.40 was obtained.

[Comparative Example 3]
Except for changing the raw material to 120 g of hexamethyldisiloxane and 791 g of triethoxymethylsilane, the same operation as in Comparative Example 1 was carried out, and the weight average molecular weight 3190, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO _3/2 unit. A 50% silicone resin decamethylcyclopentasiloxane solution having a molar ratio of 0.25: 0.75 was obtained.

[Comparative Example 4]
Compared except that the raw material was changed to 150 g of hexamethyldisiloxane and 420 g of ethyl polysilicate containing 40% SiO ₂ , 600 g of decamethylcyclopentasiloxane was changed to 300 g of isododecane, and the dilute solution used after distillation under reduced pressure was changed to isododecane. By operating in the same manner as in Example 1, a 50% silicone resin isododecane solution having a weight average molecular weight of 5220 and a molar ratio of (CH ₃ ) ₃ SiO _1/2 units: SiO _4/2 units of 0.40: 0.60 was obtained. It was.

[Comparative Example 5]
The raw material was changed to 350 g of hexamethyldisiloxane, 330 g of triethoxymethylsilane, 278 g of ethyl polysilicate containing 40% of SiO ₂ , and the same operation as in Comparative Example 1 was carried out except that decamethylcyclopentasiloxane was changed to 350 g. 50% silicone resin Deca having an average molecular weight of 6100, (CH ₃ ) ₃ SiO _1/2 unit: CH ₃ SiO _3/2 unit: SiO _4/2 unit molar ratio of 0.20: 0.40: 0.40 A methylcyclopentasiloxane solution was obtained.

[Comparative Example 6]
Comparative Example 1 except that 150 g of hexamethyldisiloxane, 91 g of diethoxydimethylsilane, 494 g of triethoxymethylsilane, and 139 g of ethyl polysilicate containing 40% SiO ₂ were used, and decamethylcyclopentasiloxane was changed to 480 g. In the same manner, the molar ratio of the weight average molecular weight 3890, (CH ₃ ) ₃ SiO _1/2 unit: (CH ₃ ) ₂ SiO _2/2 unit: CH ₃ SiO _3/2 unit: SiO _4/2 unit is A 50% silicone resin decamethylcyclopentasiloxane solution of 0.30: 0.10: 0.45: 0.15 was obtained.

The weight average molecular weight and each unit of each silicone resin obtained in Examples 1 to 10 and Comparative Examples 1 to 6 are as shown in the following table. The R ₃ SiO _1/2 unit, the R ₂ SiO _2/2 unit, the RSiO _3/2 unit, and the SiO _4/2 unit are represented as follows.
R ₃ SiO _1/2 units => M, R ₂ SiO _2/2 units => D, RSiO _3/2 units => T, and SiO _4/2 units => Q

  After removing the solvent of the silicone resin solution obtained in Examples and Comparative Examples to form a film, the appearance, stickiness, and fragility due to friction were evaluated. The results are shown in Table 2.

  In each of Examples 1 to 10, a uniform continuous film was obtained, and there was no stickiness and no brittleness, but Comparative Examples 1, 3, and 6 were high viscosity liquids without being a film. Nos. 4 and 5 were hard coatings with no stickiness but cracks, and the membranes were easily broken and fragile due to friction.

<Examples 11-12, Comparative Examples 7-8>
An emulsified cream foundation having the composition shown in Table 3 was prepared.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０１７
（注４）信越化学工業（株）製：ＫＦ−９６Ａ−６ｃｓ
（注５）信越化学工業（株）製：ＫＭＰ−５９０
（注６）信越化学工業（株）製：ＫＦ−９９０９処理
表３中の「←」は実施例１１と同じ配合量であることを意味する。

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6017
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-96A-6cs
(Note 5) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 6) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment “←” in Table 3 means the same amount as in Example 11.

[Preparation of cosmetics]
A part of components (1) to (4) and (5), (6) to (8), (16) to (20) and (21) were stirred and mixed so as to be uniform. Separately, components (9) and (10), which were separately dissolved in component (11), were gently added and emulsified. Components (12) to (15) and the remainder of (5) and (22) were added to the emulsion and mixed. This was filled in a predetermined container to prepare an emulsified cream foundation. The following evaluation was performed about the obtained emulsion type cream foundation.

[Usability evaluation]
About the obtained emulsified cream foundation, 50 female panelists applied the stretch at the time of application (extensibility), the stickiness, the uneven color of the finish, and the makeup feeling (persistence (evaluation after 8 hours after application)). The evaluation was made according to the following criteria, and the average of the evaluation results was taken.

[Secondary adhesion prevention effect]
The emulsified cream foundation was applied to the forehead of the specialized panel in the same manner, and when 20 minutes had passed after the application, tissue paper was pressed against the application part to prevent secondary adhesion of cosmetics according to the following criteria: evaluated. The average of the evaluation results was taken.

Based on the average score of the obtained evaluation results, the results are shown in Table 5 based on the following.
◎: Average point is 4.0 points or more ○: Average point is 3.0 points or more and less than 4.0 points Δ: Average point is 2.0 points or more and less than 3.0 points ×: Average point is less than 2.0 points

  As is clear from Table 5, the cosmetics of the present invention (Examples 11 and 12) were longer than those of Comparative Examples 7 and 8, had makeup, and were remarkably superior in terms of secondary adhesion prevention.

[Examples 13 and 14, Comparative Example 9]
Lipsticks having the compositions shown in Table 6 were prepared.

（注１）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注２）信越化学工業（株）製：ＫＦ−５４
（注３）信越化学工業（株）製：ＫＦ−６１０５
表６中の「←」は実施例１３と同じ配合量であることを意味する。

(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6105
“←” in Table 6 means the same blending amount as in Example 13.

<Preparation of cosmetics>
A: Components 1 to 12, 15 and 16 were heated and mixed uniformly.
B: Under heating, components 13 and 14 were added to A, mixed uniformly, and filled into a predetermined highly airtight container to obtain a lipstick.

[Usability evaluation]
About the obtained lipsticks, 50 women's professional panelists gave the above-mentioned elongation (extensibility), stickiness, uneven color finish, and mochi (continuity (evaluated 8 hours after application)) Evaluation was performed in the same manner as in the Examples, and the average of the evaluation results was taken. The results are shown in Table 7.

  As shown in Table 7, the lipsticks obtained in Examples 13 and 14 have no stickiness or oiliness, no bleeding, etc. compared to the lipstick obtained in Comparative Example 9, and the makeup is good. It was confirmed.

  Hereinafter, examples of cosmetic formulations will be described. In the following, “elongation” and “makeup mochi” were evaluated according to the same criteria as described above, and the foundation was also evaluated for secondary adhesion prevention properties according to the same criteria as described above.

[Example 15] Powder foundation composition Mass (%)
1. Silicone-treated titanium oxide (Note 1) 12.0
2. Silicone-treated sericite (Note 1) 35.0
3. Lecithin-treated talc 35.1
4). Lecithin-treated spherical nylon powder 5.0
5. Silicone-treated Bengala (Note 1) 0.4
6). Silicone-treated yellow iron oxide (Note 1) 2.0
7). Silicone-treated amber (Note 1) 0.4
8). Silicone-treated black iron oxide (Note 1) 0.1
9. Dissolved product of Example 1 3.0
10. Cross-linked dimethylpolysiloxane (Note 2) 4.0
11. Glyceryl trioctanoate 1.5
12 Silicone wax (Note 3) 1.5
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 3) Shin-Etsu Chemical Co., Ltd .: KP-562P

<Preparation of cosmetics>
A: Components 1 to 8 were mixed and ground uniformly.
B: Components 9 to 12 were uniformly mixed.
C: B was added to A to make it uniform, and pressed into a mold to obtain a powder foundation.

  The obtained powder foundation was lightly stretched, had good makeup persistence, and had no secondary adhesion.

[Example 16] Powder foundation composition Mass (%)
1. Capricylsilane-treated mica (Note 1) 40.0
2. Silicone-treated talc (Note 2) 20.0
3. Silicone-treated titanium oxide (Note 2) 8.0
4). Silicone-treated fine particle titanium oxide (Note 2) 5.0
5. Silicone-treated barium sulfate (Note 2) 8.9
6). Silicone-treated foundation pigment (Note 2) 7.0
7). Phenyl-modified hybrid silicone composite powder (Note 3) 2.0
8). Polymethylsilsesquioxane powder (Note 4) 0.4
9. Preservative 0.5
10. Fragrance 0.2
11. Dissolved product of Example 4 3.0
12 Glyceryl trioctanoate 3.0
13. Squalane 1.0
14 Vaseline 1.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: AES-3083 treatment (Note 2) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-300
(Note 4) Shin-Etsu Chemical Co., Ltd .: KMP-590

<Preparation of cosmetics>
A: Components 1 to 9 were mixed and ground uniformly.
B: Components 11 to 14 were uniformly mixed and added to A to make it uniform.
C: Component 10 was added to B and pressed into a mold to obtain a powder foundation.

  The obtained powder foundation extended lightly, was excellent in makeup persistence, and did not have secondary adhesion.

[Example 17] Stick-like W / O foundation composition Mass (%)
1. Ceresin 5.5
2. Inulin stearate 2.0
3. Neopentyl glycol dioctanoate 7.0
4). Triethylhexanoin 4.0
5. Dimethylpolysiloxane (6cs) 6.3
6). Dissolved product of Example 2 3.0
7). Cross-linked polyglycerin-modified silicone (Note 1) 4.0
8). Alkyl-modified branched polyglycerin-modified silicone (Note 2) 1.5
9. Polymethylsilsesquioxane powder (Note 3) 1.0
10. Silicone-treated titanium oxide (Note 4) 9.0
11. Silicone-treated foundation pigment (Note 5) 5.0
12 Lecithin 0.2
13. Polysorbate 80 0.3
14.1,3-BG 4.0
15. Preservative 0.5
16. Fragrance 0.2
17. Purified water 46.5
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-710
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6105
(Note 3) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 5) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment

<Preparation of cosmetics>
A: Components 1 to 9 were heated and dissolved to be uniform.
B: A part of components 10 to 13 and 14 were mixed and dispersed with a roller.
C: The remainders of component 14, 15 and 17 were uniformly dissolved, added to B, and uniformly dispersed under heating.
D: Under heating and stirring, C was added to A to emulsify, component 16 was added thereto, and the mixture was filled in a predetermined highly airtight container to obtain a stick-like W / O foundation.

  The obtained stick-like W / O foundation was lightly stretched, excellent in makeup persistence, and had no secondary adhesion.

[Example 18] Polyhydric alcohol emulsified cheek red composition in solid oil Mass (%)
1. Cross-linked polyglycerin-modified silicone (Note 1) 5.0
2. Cross-linked dimethylpolysiloxane (Note 2) 5.0
3. Decamethylcyclopentasiloxane 3.0
4). Dimethylpolysiloxane (6cs) 19.7
5. Cetyl isooctanoate 5.0
6). Dissolved product of Example 3 10.0
7). Behenyl-modified acrylic silicone resin (Note 3) 3.0
8). Paraffin wax (melting point 80 ° C) 9.0
9. Dimethyl distearyl ammonium hectorite 0.3
10. Acrylic silicone-treated powder (Note 4) 25.0
11. Preservative 0.5
12 Fragrance 0.2
13.1,3-Butylene glycol 14.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-710
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KP-562P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment

<Preparation of cosmetics>
A: Components 1 to 9 and 12 were heated to 80 ° C. and mixed uniformly.
B: Component 10 was added to A and dispersed uniformly.
C: Ingredients 11 and 13 were mixed, heated to 80 ° C., emulsified in addition to B, poured into a metal pan and cooled to obtain a polyhydric alcohol emulsified cheek red in solid oil.

  The polyhydric alcohol emulsified cheek red in solid oil obtained as described above was lightly spread and neither sticky nor oily.

[Example 19] Creamy lipstick composition Mass (%)
1. Palmitic acid / dextrin ethylhexanoate (Note 1) 9.0
2. Triethylhexanoin 7.0
3. Dissolved product of Example 2 8.0
4). Alkyl-modified cross-linked dimethylpolysiloxane (Note 2) 8.0
5. Alkyl-modified branched polyglycerin-modified silicone (Note 3) 2.0
6). Decamethylcyclopentasiloxane 35.0
7.1,3-Butylene glycol 4.8
8). Purified water 18.0
9. Coloring pigment 6.0
10. Mica 2.0
11. Fragrance 0.2
Total 100.0
(Note 1) Chiba Flour Milling Co., Ltd .: Leopard TT
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-43
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6105

<Preparation of cosmetics>
A: A part of components 1 and 2 and 3 to 6 were heated and mixed uniformly.
B: 9 was mixed with the remainder of component 2 and dispersed with a roller, and added to A and mixed uniformly.
C: Components 7 and 8 were mixed, warmed, added to B and emulsified.
D: Components 10 and 11 were added to C to obtain creamy lipstick.

  The cream-like lipstick obtained as described above was light and easy to extend to the lips, had no stickiness or oiliness, and had a good hold.

[Example 20] Eyeliner composition Mass (%)
1. Tristrimethylsiloxymethylsilane (Note 1) 20.0
2. Polyether-modified silicone (Note 2) 3.0
3. Dissolved product of Example 2 33.5
4). Silicone reticulated resin dissolved product (Note 3) 15.0
5. Dimethyl distearyl ammonium hectorite 3.0
6). Silicone-treated black iron oxide (Note 4) 10.0
7.1,3-Butylene glycol 4.5
8). Sodium sulfate 0.5
9. Preservative 0.5
10. Purified water 10.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: TMF-1.5
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6017
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-7312T
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9901 treatment

<Preparation of cosmetics>
A: Components 1 to 5 were mixed, and component 6 was added and mixed and dispersed uniformly.
B: Components 7 to 10 were mixed.
C: B was added to A and emulsified to obtain an eyeliner.

  It was confirmed that the eyeliner obtained as described above is light and easy to draw on the eyeline, has a refreshing feeling, and has a very long makeup.

[Example 21] Mascara composition Mass (%)
1. Dissolved product of Example 1 26.5
2. Palmitic acid / dextrin ethylhexanoate (Note 1) 3.0
3. Ceresin 2.5
4). Behenyl-modified acrylic silicone resin (Note 2) 2.0
5. Beeslow 3.5
6). Triethylhexanoin 3.0
7). Dimethyl distearyl ammonium hectorite 4.0
8). Lecithin 0.5
9. Isododecane 34.0
10. Silicone-treated pigment (Note 3) 5.0
11. Silica 3.0
12 Talc 12.0
13. Branched polyether-modified silicone (Note 4) 1.0
Total 100.0
(Note 1) Chiba Flour Milling Co., Ltd .: Leopard TT
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-562P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6028P

<Preparation of cosmetics>
A: Ingredients 7 and 13 were added to ingredient 9, warmed and mixed uniformly.
B: Components 1 to 6 and 8 were added to A and mixed uniformly.
C: Components 10, 11, and 12 were added to B, and the mixture was made uniform with a roller to obtain a mascara.

  It was confirmed that the mascara obtained as described above is light and easy to adhere to the wrinkles, has a feeling of use without stickiness, and has a very good makeup.

[Example 22] Cream eye shadow composition Mass (%)
1. Decamethylcyclopentasiloxane 15.0
2. Dimethylpolysiloxane (6cs) 4.0
3. Dissolved product of Example 3 5.0
4). Branched polyether-modified silicone (Note 1) 1.5
5. Acrylic silicone resin-treated pigment (Note 2) 16.0
6). Sodium chloride 2.0
7). Propylene glycol 7.5
8). Preservative 0.5
9. Purified water 48.5
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment

<Preparation of cosmetics>
A: Components 1 to 4 were mixed, and component 5 was added and mixed and dispersed uniformly.
B: Components 6 to 9 were mixed.
C: B was added to A and emulsified to obtain a cream eye shadow.

  The cream eye shadow obtained as described above had a light spread and was neither oily nor powdery, and was good to hold.

[Example 23] Cream eye shadow composition Mass (%)
1. Acrylic silicone resin dissolved product (Note 1) 3.0
2. Stearyl-modified acrylic silicone resin (Note 2) 2.0
3. Branched polyether-modified silicone (Note 3) 1.5
4). Decamethylcyclopentasiloxane 20.3
5. Dissolved product of Example 4 10.0
6). Dimethyl distearyl ammonium hectorite 1.2
7). Acrylic silicone resin-treated pigment (Note 4) 20.0
8). Spherical nylon 3.0
9. Talc 4.0
10. Ethanol 5.0
11. Purified water 30.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-545
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment

<Preparation of cosmetics>
A: Components 1 to 6 were mixed, and components 7 to 9 were added and mixed and dispersed uniformly.
B: Components 10 to 11 were mixed.
C: B was added to A and emulsified to obtain a cream eye shadow.

  The cream eye shadow obtained as described above had a light spread, no oiliness or powderiness, freshness and good holding.

[Example 24] Suncut emulsion composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 3.0
2. Cross-linked dimethylpolysiloxane (Note 2) 2.0
3. Branched polyether-modified silicone (Note 3) 1.0
4). Dissolved product of Example 1 5.0
5. Decamethylcyclopentasiloxane 5.0
6). Isotridecyl isononanoate 4.0
7). Titanium oxide dispersion (Note 4) 25.0
8). Zinc oxide dispersion (Note 5) 35.0
9. 1,3-Butylene glycol 2.0
10. Sodium citrate 0.2
11. Sodium chloride 0.5
12 Purified water 17.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: SPD-T5
(Note 5) Shin-Etsu Chemical Co., Ltd .: SPD-Z5

<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 9 to 12 were mixed.
C: B was added to A and emulsified, and components 7 and 8 were added to obtain a suncut emulsion.

  The suncut emulsion obtained as described above had a light spread, no stickiness or oiliness, and good sweat resistance.

[Example 25] Suncut cream composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 3.0
2. Cross-linked dimethylpolysiloxane (Note 2) 2.0
3. Alkyl-modified branched polyether-modified silicone (Note 3) 1.0
4). Dissolved product of Example 3 7.0
5. Decamethylcyclopentasiloxane 15.5
6). Octyl methoxycinnamate 6.0
7). Acrylic silicone resin dissolved product (Note 4) 10.0
8). Lipophilicized fine particle zinc oxide (Note 5) 20.0
9. 1,3-Butylene glycol 1.8
10. Sodium citrate 0.2
11. Sodium chloride 0.5
12 Fragrance 0.2
13. Purified water 32.8
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-240
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-575
(Note 5) Shin-Etsu Chemical Co., Ltd .: AES-3083 treatment

<Preparation of cosmetics>
A: Component 7 was added to a part of component 5 to make it uniform, and component 8 was added and dispersed by a bead mill.
B: Components 1-4 and the remainder of component 5, 6 were mixed uniformly.
C: Components 9 to 11 and Component 13 were mixed and made uniform.
D: C was added to B to emulsify, and A and component 12 were added to obtain a sun cut cream.

  The suncut cream obtained as described above had no stickiness, light spread, light oiliness, a refreshing feeling of use and good holding.

[Example 26] Sun cut lotion (shaking type)
Composition Mass (%)
1. Branched polyether-modified silicone (Note 1) 2.0
2. Dissolved product of Example 2 5.0
3. Dimethylpolysiloxane (6cs) 3.0
4). Decamethylcyclopentasiloxane 7.8
5. Ethyl hexyl methoxycinnamate 7.5
6). Hybrid silicone composite powder (Note 2) 0.5
7). Dimethyl distearyl ammonium hectorite 0.2
8). Zinc oxide dispersion (Note 3) 45.0
9.1,3-Butylene glycol 3.0
10. Alcohol 5.0
11. Sodium citrate 0.2
12 Sodium chloride 0.5
13. Purified water 20.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSP-105
(Note 3) Shin-Etsu Chemical Co., Ltd .: SPD-Z6

<Preparation of cosmetics>
A: Components 1 to 7 were mixed uniformly.
B: Components 9 to 13 were mixed.
C: B was added to A to emulsify, and component 8 was added to obtain a shaking type sun cut lotion.

  The sun cut lotion obtained as described above had a light spread, no stickiness or oiliness, and was very excellent in holding.

[Example 27] Suntan emulsion composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 2.0
2. Cross-linked dimethylpolysiloxane (Note 2) 3.0
3. Polyether-modified silicone (Note 3) 1.5
4). Dissolved product of Example 1 2.0
5. Dimethylpolysiloxane (6cs) 10.0
6). Decamethylcyclopentasiloxane 15.3
7). Dihydroxyacetone 2.0
8). Glycerin 10.0
9.1,3-Butylene glycol 5.0
10. Sodium citrate 0.2
11. Sodium chloride 0.5
12 Antioxidant 0.5
13. Preservative 0.5
14 Fragrance 0.2
15. Purified water 47.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6017

<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 7 to 13 and Component 15 were mixed.
C: B was added to A to emulsify, and component 14 was added to obtain a suntan emulsion.

  The suntan emulsion obtained as described above had no stickiness, light spreading, light oiliness and a refreshing feeling.

[Example 28] Suntan cream composition Mass (%)
1. Alkyl-modified cross-linked polyether-modified silicone (Note 1) 4.0
2. Alkyl-modified cross-linked dimethylpolysiloxane (Note 2) 2.0
3. Alkyl-modified branched polyether-modified silicone (Note 3) 1.0
4). Dissolved product of Example 3 5.0
5. Decamethylcyclopentasiloxane 10.3
6). Stearyl-modified acrylic silicone (Note 4) 1.0
7). Dimethyloctylparaaminobenzoic acid 1.5
8.4-t-butyl-4'-methoxy-dibenzoylmethane 1.5
9. Kaolin 0.5
10. Pigment 8.0
11. Titanium oxide coated mica 8.0
12 Dioctadecyldimethylammonium chloride 0.1
13. Sodium L-glutamate 3.0
14.1,3-Butylene glycol 4.0
15. Sodium citrate 0.2
16. Sodium chloride 0.5
17. Antioxidant 0.5
18. Preservative 0.5
19. Fragrance 0.2
20. Purified water 48.2
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-320
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-42
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-561P

<Preparation of cosmetics>
A: Components 1 to 8, 17 and 18 were heated and mixed.
B: After heating and stirring a part of components 12 and 20, components 9 to 11 were added and dispersed.
C: The remaining components 13 to 16 and 20 were uniformly dissolved and mixed with B.
D: While stirring, C was gradually added to A to emulsify, and after cooling, component 19 was added to obtain a suntan cream.

  The suntan cream obtained as described above was fine in texture, lightly spread, free of stickiness and oiliness, gave a refreshing feeling of use and was also good.

[Example 29] Liquid W / O foundation composition Mass (%)
1. Decamethylcyclopentasiloxane 18.0
2. Dimethylpolysiloxane (6cs) 2.0
3. Dissolved product of Example 1 7.0
4). Alkyl-modified branched polyether-modified silicone (Note 1) 2.0
5. Ethylhexyl paramethoxycinnamate 3.0
6). Fluorine-modified silicone (Note 2) 2.0
7). Polymethylsilsesquioxane powder (Note 3) 1.5
8). Fluorine compound-treated foundation pigment (Note 4) 9.3
9. Fluorine compound-treated mica titanium (Note 4) 2.0
10. Silicone-treated fine particle titanium oxide (Note 5) 8.0
11. Alkyl-modified branched polyglycerin-modified silicone (Note 6) 1.2
12 Ethanol 3.0
13.1,3-Butylene glycol 4.3
14 Glycerin 1.5
15. Magnesium sulfate 0.5
16. Antioxidant 0.5
17. Preservative 0.5
18. Fragrance 0.2
19. Purified water 33.5
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 2) Shin-Etsu Chemical Co., Ltd .: FL-5
(Note 3) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 4) 5% coated with perfluoroalkylethyl phosphate diethanolamine salt (Note 5) Shin-Etsu Chemical Co., Ltd .: KF-9909 treated (Note 6) Shin-Etsu Chemical Co., Ltd .: KF-6105

<Preparation of cosmetics>
A: A part of component 1 and components 11 and 12 were mixed and dispersed uniformly.
B: Components 8 to 10 were mixed uniformly.
C: The remainder of component 1 and 2 to 7 were mixed, and B was added and dispersed and mixed uniformly.
D: Components 13 to 18 were mixed and made uniform.
E: While stirring, D was gradually added to C to emulsify, and A and component 19 were added to obtain a liquid W / O foundation.

  The liquid W / O foundation obtained as described above was smooth and free from stickiness, lightly spreading, not oily, having good makeup, and having no secondary adhesion.

[Example 30] Hair cream composition Mass (%)
1. Decamethylcyclopentasiloxane 16.0
2. Methylphenyl polysiloxane (Note 1) 2.0
3. Dissolved product of Example 1 4.0
4). Squalane 5.0
5. Silicone network resin dissolved product (Note 2) 2.0
6). Sorbitan sesquiisostearate 1.5
7). Alkyl-modified branched polyether-modified silicone (Note 3) 2.0
8). Sodium sorbitol sulfate 2.0
9. Sodium chondroitin sulfate 1.0
10. Sodium hyaluronate 0.5
11. Propylene glycol 2.3
12 Preservative 1.5
13. Vitamin E acetate 0.1
14 Antioxidant 0.5
15. Fragrance 0.2
16. Purified water 59.4
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-7312J
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038

<Preparation of cosmetics>
A: Components 1 to 7 and Components 12 to 14 were mixed uniformly.
B: Components 8 to 11 and 16 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 15 was added to obtain a hair cream.

  The hair cream obtained as described above was not oily, spread lightly, had water resistance, water repellency and sweat resistance, and had good durability.

[Example 31] Hair cream composition Mass (%)
1. Dissolved silicone gum (Note 1) 10.0
2. Silicone reticulated resin dissolved product (Note 2) 10.0
3. Dissolved product of Example 3 10.0
4). Glyceryl tri-2-ethylhexanoate 5.0
5. Vaseline 5.0
6). Stearic acid 1.5
7). Cetyl alcohol 0.5
8). Polyglyceryl monooleate 1.5
9. Glyceryl monostearate 1.5
10. Polyether-modified silicone (Note 3) 0.5
11.1,3-butylene glycol 5.0
12 (Acrylates / alkyl acrylate (C10-30))
Cross polymer (Note 4) 0.3
13. Triethanolamine 0.3
14 Preservative 0.5
15. Fragrance 0.2
16. Purified water 48.2
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-9028
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-7312J
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 4) Noveon: Pemulen TR-1

<Preparation of cosmetics>
A: Components 1 to 10 and Component 14 were dissolved by heating.
B: Components 11 to 13 and 16 were mixed and heated.
C: While stirring, A was gradually added to B to emulsify, and after cooling, component 15 was added to obtain a hair cream.

  The hair cream obtained as described above has a light spread, gives gloss and smoothness to the hair, has an excellent setting effect on the hair, and is water-resistant and sweat-resistant and has good durability. It was.

[Example 32] Moisturizing O / W cream composition Mass (%)
1. Dissolved product of Example 1 4.0
2. Liquid paraffin 4.5
3. Macadamia nut oil 5.0
4). Dimethylpolysiloxane (viscosity 6 mm ² / s: 25 ° C.) 5.0
5. Octyl paramethoxycinnamate 5.0
6). Alkyl-modified branched polyglycerin-modified silicone (Note 1) 1.5
7). Propylene glycol 8.0
8). Glycerin 3.0
9. Preservative 0.5
10. Fragrance 0.2
11. Purified water 63.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6105

<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 7 to 11 were mixed and then emulsified in addition to A to obtain a moisturizing O / W cream.

  The moisturizing O / W cream obtained as described above spreads lightly, gives a refreshing feeling of use, and maintains the moisturizing effect.

[Example 33] O / W emollient cream composition Mass (%)
1. Cross-linked dimethylpolysiloxane (Note 1) 7.0
2. Cross-linked dimethylpolysiloxane (Note 2) 30.0
3. Dissolved product of Example 2 6.0
4). Decamethylcyclopentasiloxane 5.0
5.1,3-Butylene glycol 4.0
6). Branched polyglycerin-modified silicone (Note 3) 0.6
7). Branched polyglycerin-modified silicone (Note 4) 0.3
8). (Acrylamide / acryloyldimethyltaurine Na) copolymer (Note 5) 0.6
9. Ammonium dimethyltaurate / VP copolymer (Note 6)
0.7
10. Sodium chloride 0.1
11. Purified water 45.7
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6104
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6100
(Note 5) manufactured by Sepic Corporation: Shimurugel 600
(Note 6) Made by Clariant: Aristoflex AVC

<Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 11 were mixed uniformly.
C: While stirring, A was gradually added to B and mixed to obtain an O / W emollient cream.

  The O / W emollient cream obtained as described above has no oiliness and is smooth, spreads lightly, and maintains the effect of protecting the skin.

[Example 34] Hand cream composition Mass (%)
1. Decamethylcyclopentasiloxane 25.0
2. Dissolved product of Example 4 10.0
3. Liquid paraffin 5.0
4). Amino-modified silicone gum dissolved product (Note 1) 8.0
5. Branched polyether-modified silicone (Note 2) 2.0
6). Hybrid silicone composite powder (Note 3) 2.5
7). Distearyldimethylammonium chloride 0.8
8). Vitamin E acetate 0.1
9. Polyethylene glycol 400 1.0
10. Glycerin 10.0
11. Aluminum magnesium silicate 1.2
12 Preservative 0.5
13. Fragrance 0.2
14 Purified water 33.7
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-8108
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-102

<Preparation of cosmetics>
A: Components 1 to 8 and Component 12 were mixed uniformly.
B: Components 9 to 11 and 14 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 13 was added to obtain a hand cream.

  The hand cream obtained as described above is not oily and smooth, spreads lightly and maintains the effect of protecting the skin.

[Example 35] O / W cream composition Mass (%)
1. Dimethylpolysiloxane (6cs) 7.0
2. Stearyl-modified acrylic silicone resin (Note 1) 8.0
3. Dissolved product of Example 3 5.0
4). Glyceryl triisostearate 10.0
5. Cetanol 1.0
6). Stearic acid 3.0
7). Glyceryl monostearate 1.5
8). Sorbitan sesquioleate 0.5
9. Monooleic acid polyoxyethylene sorbitan 1.0
10. Sodium hydroxide (1% by weight aqueous solution) 10.0
11.1,3-butylene glycol 5.0
12 Preservative 0.5
13. Fragrance 0.2
14 Purified water 47.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-561P

<Preparation of cosmetics>
A: Components 1 to 9 were heated and mixed.
B: Components 10 to 12 and 14 were mixed and heated.
C: While stirring, B was gradually added to A to emulsify, and after cooling, Component 13 was added to obtain an O / W cream.

  It was confirmed that the O / W cream obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and has a refreshing feeling.

[Example 36] O / W cream composition Mass (%)
1. Polyglyceryl monooleate 1.0
2. Cetyl alcohol 0.5
3. Stearic acid 1.0
4). Glyceryl monostearate 1.0
5. Dissolved product of Example 1 2.0
6). Macadamia nut oil 9.0
7). Cross-linked dimethylpolysiloxane (Note 1) 0.5
8). (Acrylates / alkyl acrylate (C10-30))
Cross polymer (Note 2) 0.2
9. Methylcellulose 0.1
10. Triethanolamine 0.2
11.1,3-butylene glycol 7.0
12 Preservative 0.5
13. Fragrance 0.2
14 Purified water 76.8
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 2) Noveon: Pemulen TR-1

<Preparation of cosmetics>
A: Components 1 to 7 were heated and mixed uniformly.
B: Components 8 to 12 and 14 were mixed and heated.
C: While stirring, B was gradually added to A to emulsify, and after cooling, Component 13 was added to obtain an O / W cream.

  It was confirmed that the O / W cream obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and maintains a freshness of the skin.

[Example 37] Antiperspirant composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 7.0
2. Dissolved product of Example 2 8.0
3. Decamethylcyclopentasiloxane 9.0
4.1,3-Butylene glycol 5.0
5. Sodium citrate 0.2
6). Glycine salt of aluminum zirconium tetrachloride hydrate 20.0
7). Purified water 50.8
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210

<Preparation of cosmetics>
A: Components 1 to 3 were mixed uniformly.
B: Components 4 to 7 were mixed uniformly.
C: Under stirring, B was gradually added to A and emulsified to obtain an antiperspirant.

  It was confirmed that the antiperspirant obtained as described above spreads lightly, does not whiten the skin, and has a good antiperspirant effect.

[Example 38] Wrinkle concealer composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 5.0
2. Cross-linked dimethylpolysiloxane (Note 2) 55.0
3. Dissolved product of Example 1 15.0
4). Decamethylcyclopentasiloxane 8.0
5. Hybrid silicone composite powder (Note 3) 12.0
6). Dissolved silicone gum (Note 4) 5.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-101
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9028

<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly to obtain a wrinkle concealer.

  It was confirmed that the wrinkle concealer obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and can maintain the sealing effect.

[Example 39] Cleansing cream composition Mass (%)
1. Dimethylpolysiloxane (6cs) 5.0
2. Methylphenyl polysiloxane (Note 1) 5.0
3. Liquid paraffin 5.0
4). Jojoba oil 2.0
5. Dissolved product of Example 4 4.0
6). Branched polyether-modified silicone (Note 2) 2.0
7). Dextrin fatty acid ester 0.8
8). Aluminum monostearate 0.2
9. Aluminum chloride 1.0
10. Glycerin 10.0
11. Preservative 0.5
12 Fragrance 0.2
13. Purified water 64.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-56
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028

<Preparation of cosmetics>
A: Components 1 to 8 were heated and mixed.
B: Components 9 to 11 and 13 were heated and mixed.
C: While stirring, B was gradually added to A to emulsify, and after cooling, component 12 was added to obtain a cleansing cream.

  It was confirmed that the cleansing cream obtained as described above has a light spread, moist and fresh, and gives a refreshing feeling.

[Example 40] Transparent cleansing lotion composition Mass (%)
1. Decamethylcyclopentasiloxane 50.8
2. Dissolved product of Example 1 5.0
3. Neopentyl glycol dioctanoate 6.0
4). Silica 0.2
5.1,3-Butylene glycol 5.0
6). Glycerin 6.0
7). Polyether-modified silicone (Note 1) 5.0
8). Polyether-modified silicone (Note 2) 3.0
9. PEG-60 hydrogenated castor oil 2.0
10. Purified water 17.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6013

<Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 10 were mixed uniformly.
C: While stirring, A was gradually added to B and emulsified to obtain a transparent cleansing lotion.

  It was confirmed that the transparent cleansing lotion obtained as described above is lightly spread, gives a moist and fresh feeling, and has a high cleansing effect.

[Example 41] W / O cheek red composition Mass (%)
1. Acrylic silicone resin dissolved product (Note 1) 10.0
2. Stearyl-modified acrylic silicone resin (Note 2) 2.0
3. Branched polyether-modified silicone (Note 3) 1.5
4). Decamethylcyclopentasiloxane 15.0
5. Glyceryl triisostearate 3.0
6). Dissolved product of Example 2 5.0
7). Dimethyl distearyl ammonium hectorite 1.5
8). Spherical nylon 3.0
9. Talc 4.0
10. Hoho red pigment (acrylic silicone treatment) (Note 4) 20.0
11. Alcohol 5.0
12 Fragrance 0.2
13. Purified water 29.8
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-545
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment

<Preparation of cosmetics>
A: Components 1 to 7 were heated and mixed.
B: Components 8 to 10 and Component 12 were mixed uniformly and mixed with A.
C: Components 11 and 13 were mixed.
D: While stirring, C was gradually added to B and emulsified to obtain W / O cheek.

  The W / O cheeks obtained as described above had no stickiness or oiliness, light spreading, excellent adhesion, and good makeup.

[Example 42] W / O liquid foundation composition Mass (%)
1. Cross-linked polyether-modified silicone (Note 1) 3.0
2. Cross-linked dimethylpolysiloxane (Note 2) 5.0
3. Branched polyether-modified silicone (Note 3) 2.0
4). Decamethylcyclopentasiloxane 20.0
5. Cetyl isooctanoate 5.0
6). Dissolved product of Example 2 10.0
7). Dimethyl distearyl ammonium hectorite 1.2
8). Foundation pigment (silicone treatment) (Note 4) 14.0
9. Acrylic silicone resin dissolved product (Note 5) 10.0
10.1,3-butylene glycol 5.0
11. Xanthan gum 0.1
12 Sodium citrate 0.2
13. Sodium chloride 0.5
14 Preservative 0.5
15. Fragrance 0.2
16. Purified water 23.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 5) Shin-Etsu Chemical Co., Ltd .: KP-575

<Preparation of cosmetics>
A: A part of component 4 and component 9 were mixed, and component 8 was uniformly dispersed.
B: The remaining components 1 to 4 and components 5 to 7 were mixed uniformly.
C: Components 10 to 14 and Component 16 were mixed uniformly.
D: While stirring, C was gradually added to B and emulsified, and A and component 15 were added to obtain a W / O liquid foundation.

  The W / O liquid foundation obtained as described above had no stickiness or oiliness, light spread, light makeup, and no secondary adhesion.

[Example 43] W / O type cream composition Mass (%)
1. Cross-linked alkyl / polyether-modified silicone (Note 1) 3.0
2. Cross-linked alkyl-modified dimethylpolysiloxane (Note 2) 4.0
3. Alkyl-modified branched polyether-modified silicone (Note 3) 1.0
4). Meadow Home Oil 3.5
5. Jojoba oil 2.5
6). Macadamia nut oil 5.0
7). Dissolved product of Example 3 7.5
8). Hybrid silicone composite powder (Note 4) 3.0
9.1,3-Butylene glycol 8.0
10. Glycine 3.0
11. Sodium citrate 0.2
12 Sodium chloride 0.5
13. Preservative 0.5
14 Fragrance 0.2
15. Purified water 58.1
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-340
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-44
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KSP-100

<Preparation of cosmetics>
A: Components 1 to 8 were mixed uniformly.
B: Components 9 to 13 and Component 15 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 14 was added to obtain a W / O cream.

  It was confirmed that the W / O cream obtained as described above has no stickiness or oiliness and maintains a moist feeling on the skin.

[Example 44] Cuticle coat composition Mass (%)
1. Polyether-modified silicone (Note 1) 3.0
2. Polyether-modified silicone (Note 2) 2.0
3. PEG-40 hydrogenated hydrogenated castor oil 1.0
4). Dissolved product of Example 4 3.0
5. Silicone gum dissolved product (Note 3) 40.0
6). Decamethylcyclopentasiloxane 40.0
7). Alcohol 4.3
8). Preservative 0.5
9. Fragrance 0.2
10. Purified water 6.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6013
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-9028

<Preparation of cosmetics>
A: Components 1 to 3 and 7 to 10 were mixed uniformly.
B: Components 4 to 6 were mixed uniformly.
C: Under stirring, B was added to A and emulsified to obtain a cuticle coat.

  It was confirmed that the cuticle coat obtained as described above spreads lightly, suppresses hairiness, and gives gloss and smoothness.

[Example 45] Hair treatment composition Mass (%)
1. Dissolved silicone gum (Note 1) 5.0
2. Diphenyl dimethicone (Note 2) 4.0
3. Dissolved product of Example 4 1.0
4). Cetyl octanoate 1.0
5. Cetyl alcohol 0.5
6). Polyether-modified silicone (Note 3) 1.0
7). PEG-60 hydrogenated hydrogenated castor oil 1.0
8). Glyceryl monostearate 0.5
9. Carboxyvinyl polymer (1% by weight aqueous solution) 25.0
10. Xanthan gum (1% by weight aqueous solution) 7.0
11.1,3-butylene glycol 5.0
12 Alcohol 7.0
13. Preservative 0.5
14 Fragrance 0.2
15. Purified water 41.3
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: MK-15H
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6013

<Preparation of cosmetics>
A: Components 1 to 8 were dissolved by heating.
B: Components 11 to 15 were dissolved by heating.
C: Under stirring, B was added to A to emulsify, and components 9 and 10 were further added thereto to obtain a hair treatment.

  It was confirmed that the hair treatment obtained as described above spreads lightly and gives the hair gloss and smoothness.

[Example 46] Nail enamel composition Mass (%)
1. Dissolved product of Example 2 35.0
2. Tristrimethylsiloxymethylsilane (Note 1) 5.0
3. Nitrocellulose 3.0
4). Kanfa 0.5
5. Acetyltributyl citrate 1.0
6). Dimethyl distearyl ammonium hectorite 0.5
7). Butyl acetate 30.0
8). Ethyl acetate 13.0
9. Isopropyl alcohol 5.0
10. Coloring pigment 7.0
Total 100.0
(Note 1) Shin-Etsu Chemical Co., Ltd .: TMF-1.5

<Preparation of cosmetics>
A: Components 7 to 9 were mixed, and components 4 to 6 were added and mixed uniformly.
B: Components 1 to 3 were added to A and mixed.
C: Component 10 was added to B and mixed to obtain a nail enamel.

  It was confirmed that the nail enamel obtained as described above has a light spreading, gives gloss to the nails and is excellent in holding.

[Example 47] Nail enamel overcoat composition Mass (%)
1. Dissolved product of Example 4 6.0
2. Nitrocellulose 17.0
3. Alkyd resin 4.0
4). Acetyltriethyl citrate 5.0
5. Butyl acetate 29.0
6). Ethyl acetate 25.0
7). Isopropyl alcohol 3.0
8). n-Butyl alcohol 1.0
9. Toluene 10.0
Total 100.0

<Preparation of cosmetics>
A: Components 5 to 9 were mixed, and component 4 was added and mixed uniformly.
B: Components 1 to 3 were added to A and mixed to obtain a nail enamel overcoat.

  It was confirmed that the nail enamel overcoat obtained as described above spreads lightly, increases the gloss of the enamel, and is easy to hold.

  The present invention is not limited to the above embodiment. The above-described embodiment is an exemplification, and the present invention has substantially the same configuration as the technical idea described in the claims of the present invention, and any device that exhibits the same function and effect is the present invention. It is included in the technical scope of the invention.

Claims (11)

The structural unit is the following general formula (A), (B), (C), (D)
(A) (R ¹ ₃ SiO _1/2 ) a,
(B) (R ² ₂ SiO _2/2 ) b,
(C) (R ³ SiO _3/2 ) c and (D) (SiO _4/2 ) d
Wherein R ¹ , R ² and R ³ are independently selected from alkyl groups having 1 to 8 carbon atoms, aryl groups having 6 to 12 carbon atoms, and fluorine-substituted alkyl groups having 1 to 8 carbon atoms. Group,
a has a value of 0.2 to 0.5;
b has a value of 0.0 to 0.1;
c has a value of 0.3 to 0.6;
d has a value of 0.2 to 0.4;
The value of a + b + c + d is 1.0, the value of a / (c + d) is 0.3 to 0.9, and the value of c / d is 0.8 to 2.5)
A cosmetic comprising a silicone resin having a weight average molecular weight of 1500 to 20000.   The cosmetic according to claim 1, wherein the silicone resin is contained in an amount of 0.1 to 40% by mass of the total mass of the cosmetic.   The cosmetic according to claim 1 or 2, further comprising an oil selected from silicone oil, hydrocarbon oil, ester oil, and glyceride oil.   The cosmetic according to any one of claims 1 to 3, further comprising a surfactant.   The cosmetic according to claim 4, wherein the surfactant is a linear or branched organopolysiloxane whose hydrophilic group is polyoxyalkylene or polyglycerin, or an alkyl co-modified organopolysiloxane thereof. .   The cosmetic according to any one of claims 1 to 5, further comprising a composition comprising a crosslinked organopolysiloxane polymer and a liquid oil.   The cosmetic according to claim 6, wherein the crosslinked organopolysiloxane polymer has a polyether group and / or a polyglycerin group. R ₃ SiO _1/2 , R ₂ SiO _2/2 , RSiO _3/2 , and SiO _4/2 other than the silicone resin
(R is the same as R ¹ above) Silicone selected from the group consisting of a silicone resin having a configuration selected from the above, a linear acrylic / silicone graft copolymer, and a linear acrylic / silicone block copolymer The cosmetic according to any one of claims 1 to 7, further comprising a film forming agent.   The cosmetic according to any one of claims 1 to 8, further comprising a powder.   The cosmetic according to any one of claims 1 to 9, further comprising an ultraviolet absorbing component.   2. The cosmetic according to claim 1, wherein the cosmetic is an aqueous, oily or emulsified skin care cosmetic, hair cosmetic, antiperspirant, makeup cosmetic, or UV protection cosmetic. Cosmetics given in any 1 paragraph of Claim 10.