JP4993508B2 - Cosmetics containing a film-forming polymer - Google Patents

Description

The present invention relates to a cosmetic, and more particularly to a cosmetic having a cycloolefin skeleton and containing a film-forming polymer. The polymer is excellent in compatibility with various oils, particularly silicone oils, extends well without giving a sticky feeling on the skin or hair, and has an effect of preventing makeup from adhering to clothes or the like.

In order to improve the durability of cosmetics and the like, blending a film-forming polymer is widely performed. For example, various silicone resins and silicone-modified acrylic resins are used. However, these film-forming polymers have a problem that the strength of the film is weak, and when the film is rubbed with clothes after being applied, makeup easily adheres to clothes (hereinafter referred to as “secondary adhesion”). is there. On the other hand, when the film strength is increased, the elongation on the skin is deteriorated, and a tingling sensation appears.

On the other hand, a polycycloolefin polymer is known (Patent Document 1). The polymer is excellent in film forming ability and is used for gas permeable membranes, contact lenses and the like.
JP 2007-291150 A

  The present inventors have found that a compound having a predetermined functional group introduced into the skeleton of the polycycloolefin polymer can solve the problems of the conventional film-forming polymer, thereby completing the present invention.

（式中、Ｒ^１は、互いに独立に、炭素数１〜１２の、フッ素置換されていてよいアルキル基であり、Ｘは（ｉ）で示される基及び／又は（ｉｉ）で示される基であり、ａは１〜３の整数であり、ｂは０〜２の整数である）

（Ｒ^２は、互いに独立に、炭素数１〜１２の、フッ素置換されていてよいアルキル基であり、ｄは１〜５の整数であり、ｃは３〜５の整数である。） That is, the present invention is a cosmetic comprising a polymer having a repeating unit of the following formula (1), provided that the carbon-carbon double bond of the polymer main chain may be partially hydrogenated.

(In the formula, R ¹ , independently of each other, is an alkyl group having 1 to 12 carbon atoms which may be substituted with fluorine, and X is a group represented by (i) and / or a group represented by (ii). A is an integer of 1 to 3, and b is an integer of 0 to 2)

(R ² is independently an alkyl group having 1 to 12 carbon atoms which may be fluorine-substituted, d is an integer of 1 to 5, and c is an integer of 3 to 5.)

The polymer is excellent in compatibility with various oils, and particularly improves the stability of cosmetics containing powder. It is a film-forming polymer that extends well without stickiness on the skin or hair and has the effect of preventing makeup from adhering to clothes and the like .

  Hereinafter, (I) a polymer, (II) a method for producing a polymer and its hydride, and (III) a cosmetic will be described in this order.

(I) Polymer In the following repeating unit (1), R ¹ is an alkyl group having 1 to 12 carbon atoms which may be substituted with fluorine, such as a methyl group, an ethyl group, an n-propyl group, Examples include a butyl group, a pentyl group, and a trifluoromethyl group. Of these, a methyl group is preferred.

a is an integer of 1 to 3, and a combination thereof, for example, a may be a polymer in which a repeating unit of 2 and a repeating unit of 3 are present as a mixture. a is preferably 3. b is an integer of 0 to 2 and may be a combination thereof. In view of polymerizability, b is preferably 0, 1 or a combination thereof, and most preferably 0.

上式中、Ｒ^２は、互いに独立に、炭素数１〜１２の、フッ素置換されていてよいアルキル基であり、例えば、Ｒ^１について上述した基が包含され、好ましくはメチル基、及びトリフロロメチル基である。ｄは１〜５の整数であり、ｃは３〜５の整数である。 X is a linear or cyclic diorganopolysiloxane residue represented by the following formula (i) or (ii), or a combination thereof.

In the above formula, R ² is independently an alkyl group having 1 to 12 carbon atoms which may be substituted with fluorine, and includes, for example, the groups described above for R ¹ , preferably a methyl group and trifluoro It is a methyl group. d is an integer of 1 to 5, and c is an integer of 3 to 5.

式（ｉｉ）の基の例として下記の基が挙げられる。

As an example of the group of formula (i), the following trimethylsiloxy group is

Examples of groups of formula (ii) include the following groups:

In addition to the repeating unit (1), a copolymer containing a repeating unit of the following formula (2) may be used. The bond between units (1) and (2) is random. In the formula (2), R ³ is a group independently selected from a hydrogen atom, an alkyl group which may be substituted with fluorine, a hydroxyalkyl group, a polyoxyalkylene group, a polyglyceryl group, and an alkoxysilyl group, b is an integer of 0-2. Preferably R ³ is a triethoxysilyl group.

The ratio of the repeating unit of the formula (2) is preferably in the range of 5% to 50%, more preferably 10 to 20% of the total number of repeating units. If the ratio is less than the lower limit, the effect of introducing the repeating unit of formula (2) may not be obtained, and if the ratio exceeds the upper limit, the effect of X of formula (1) may not be sufficient. is there.

The polymer or copolymer (hereinafter abbreviated as “polymer”) may be one in which at least a part of the carbon-carbon double bond of the main chain is hydrogenated. Hydrogenation improves the thermal stability of the polymer. The hydrogenation rate can be obtained, for example, by comparing the peak intensity after hydrogenation with the peak intensity derived from the main chain carbon-carbon double bond in the ¹ H-NMR spectrum of the polycycloolefin before hydrogenation. it can. Preferably, 50 to 100%, more preferably 80% or more, and most preferably 90% or more of the carbon-carbon double bonds of the main chain are hydrogenated.

The polymer preferably has a polystyrene-equivalent number average weight molecular weight determined by GPC of 300 to 1,000,000, more preferably 500 to 50,000. When the molecular weight exceeds the upper limit, the viscosity may be high and the feeling of use may be deteriorated, for example, the stickiness may be felt. On the other hand, if the molecular weight is less than the lower limit, film formation may be difficult.

（ここで、Ｒ¹、Ｘ、a、bは上述の通りである。） (II) Production method of polymer and hydride thereof The polymer can be produced by subjecting a compound represented by the following formula (3) to metathesis polymerization.

(Here, R ¹ , X, a, and b are as described above.)

Examples of the organosilicon compound of the formula (3) include the following, where Me represents a methyl group. Moreover, you may use these mixtures.

（ここで、Ｒ¹、Ｘ、aは上述の通りである。） The organosilicon compound (3) can be prepared by subjecting a vinyl group-containing compound represented by the following formula (5) or (6) and cyclopentadiene to a Diels-Alder reaction. The details of the preparation method will be described in Examples below.

(Here, R ¹ , X, and a are as described above.)

（ここで、Ｒ¹、Ｒ^２、aは上述の通りである。） In formula (3), X is an example of a vinyl group-containing compound that prepares the product of formula (i), and tristrimethylsiloxyvinylsilane is an example of a vinyl group-containing compound that prepares the product of formula (ii). A compound of the following formula (6) can be exemplified.

(Here, R ¹ , R ² and a are as described above.)

（ここで、Ｒ^３、ｂは上述の通りである） The polymer containing the repeating unit of the formula (2) is obtained by using the compound represented by the following formula (4) in such an amount that the ratio of the repeating unit of the formula (2) is the above ratio. It can obtain by attaching | subjecting to metathesis polymerization.

(Where R ³ and b are as described above).

これの化合物は、Ｒ^３の末端にビニル基が結合された化合物と、シクロペンタジエンをＤｉｅｌｓ−Ａｌｄｅｒ反応に付することによって調製することができる。 The following are mentioned as an example of the said compound.

These compounds can be prepared by subjecting a compound in which a vinyl group is bonded to the terminal of R ³ and cyclopentadiene to Diels-Alder reaction.

  In the metathesis polymerization, a monomer is dissolved in an aromatic hydrocarbon solvent such as toluene or xylene according to a conventional method, and the polymerization is carried out by stirring in a nitrogen atmosphere at a temperature of 40 to 60 ° C. under normal pressure in the presence of a polymerization catalyst. . As the polymerization catalyst, tungsten, molybdenum or ruthenium complex called carbene complex can be used, preferably Grubbs first generation catalyst, Grubbs second generation catalyst or Hoveyda-Grubbs catalyst. The amount of the catalyst used can be polymerized at a concentration of 1 to 1000 ppm, preferably 5 to 500 ppm, relative to the raw material monomer. If it is less than 5 ppm, the polymerization rate is slow and the practicality is poor, and if it exceeds 500 ppm, it may be economically undesirable.

  The hydrogenation reaction of the obtained polymer is performed, for example, by converting the main chain carbon-carbon double bond of the silicone-modified polycycloolefin into a saturated single bond using hydrogen gas in the presence of a hydrogenation catalyst. be able to.

  The hydrogenation catalyst to be used is not particularly limited, such as a homogeneous catalyst and a heterogeneous catalyst, and those generally used for hydrogenation of olefin compounds can be appropriately used.

Examples of the homogeneous catalyst include, for example, dichlorotris (triphenylphosphine) rhodium known as a Wilkinson complex, a ruthenium carbene complex catalyst described in the above metasis polymerization catalyst, JP-A-7-2929, JP-A-11-109460, JP-A-11-158256. And transition metal complex catalysts composed of ruthenium compounds described in JP-A-11-193323 and the like.

Examples of the heterogeneous catalyst include a hydrogenation catalyst in which a metal such as nickel, palladium, platinum, rhodium, or ruthenium is supported on a carrier such as carbon, silica, celite, alumina, or titanium oxide. More specifically, for example, nickel-alumina, palladium-carbon and the like can be used. These hydrogenation catalysts can be used alone or in combination of two or more.

Among these, noble metal complex catalysts such as rhodium and ruthenium, palladium-carbon, etc. from the point that the main chain carbon-carbon double bond of the polymer can be selectively hydrogenated without causing side reactions such as functional groups. It is preferable to use a palladium-supported catalyst, particularly a ruthenium carbene complex catalyst.

The ruthenium carbene complex catalyst can be used as both a ring-opening metathesis reaction catalyst and a hydrogenation catalyst. In this case, the ring-opening metathesis reaction and the hydrogenation reaction can be performed continuously. When the ring-opening metathesis reaction and the hydrogenation reaction are continuously performed using the ruthenium carbene complex catalyst, a catalyst modifier such as ethyl vinyl ether or a vinyl compound or α-olefin is added to activate the catalyst. Therefore, a method of starting the hydrogenation reaction is also preferably employed.

The hydrogenation reaction is preferably performed in an organic solvent. As an organic solvent, it can select conveniently by the solubility of the hydride to produce | generate, The organic solvent similar to the above-mentioned polymerization solvent can be used. Therefore, the reaction can be carried out without changing the solvent after the polymerization reaction, either directly from the reaction solution or from the reaction solution or by adding a hydrogenation catalyst.

The conditions for the hydrogenation reaction may be appropriately selected according to the type of hydrogenation catalyst used. The usage-amount of a hydrogenation catalyst is 0.01-50 weight part normally with respect to 100 weight part of ring-opening polymers, Preferably it is 0.05-10 weight part. When the reaction temperature is 100 ° C. to 200 ° C. or higher, side reactions tend to occur. The reaction pressure of hydrogen is usually 0.01 to 10.0 MPa, preferably 0.1 to 5.0 MPa. When the hydrogen pressure is 0.01 MPa or less, the hydrogenation reaction rate decreases. If it is 5.0 MPa or more, a high voltage device is required.

  By the hydrogenation reaction performed as described above, 50% or more, preferably 80% or more, and most preferably 90% or more of the main chain carbon-carbon double bonds can be hydrogenated.

(III) Cosmetics The above polymer (hereinafter sometimes referred to as “component (A)”) is a skin care product, makeup product, hair product, antiperspirant product, UV protection product, etc., particularly skin, It is suitable as a raw material for cosmetics used externally for hair, eyebrows, or eyelashes. In particular, it is suitable for skin care products and make-up products that have makeup and secondary adhesion problems. Depending on the type and dosage form of the cosmetic, the component A) is 0.1 to 10% by weight of the cosmetic weight for powder cosmetics such as foundation, and 0.1 to 7.5% by weight for liquid cosmetics such as emulsion. It is preferable to mix.

According to the purpose, one or more B) oil agents can be blended in the cosmetic. As long as it is used for normal cosmetics, any oil agent such as solid, semi-solid, and liquid can be used.

B) Examples of the oil include fluorine oils such as silicone oil, hydrocarbon oil, higher fatty acid, higher alcohol oil, ester oil, natural animal and vegetable oil, and semi-synthetic oil.

Silicone oils such as dimethylpolysiloxane, caprylylmethicone, phenyltrimethicone, methylphenylpolysiloxane, methylhexylpolysiloxane, methylhydrogenpolysiloxane, dimethylsiloxane / methylphenylsiloxane copolymer, etc. Cyclic organopolysiloxanes such as linear or branched organopolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane Branched organopolysiloxanes such as tristrimethylsiloxymethylsilane and tetrakistrimethylsiloxysilane, amino-modified organo Silicone such as lysiloxane, pyrrolidone modified organopolysiloxane, pyrrolidone carboxylic acid modified organopolysiloxane, high degree of gummed dimethylpolysiloxane, gummed amino modified organopolysiloxane, gummed dimethylsiloxane / methylphenylsiloxane copolymer Rubber, cyclic organopolysiloxane solution of silicone gum or rubber, trimethylsiloxysilicic acid, trimethylsiloxysilicic acid containing titanium oxide, cyclic organopolysiloxane solution of trimethylsiloxysilicic acid, higher alkoxy-modified organopolysiloxane such as stearoxysilicone, Higher fatty acid-modified organopolysiloxane, alkyl-modified organopolysiloxane, long-chain alkyl-modified organopolysiloxane, amino-modified organopolysiloxane, fluorine Sex organopolysiloxane, dissolution products of silicone resin and silicone resin and the like.

B) Linear, branched, or cyclic such as octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tristrimethylsiloxymethylsilane, tetrakistrimethylsiloxysilane as part of the oil It is preferable to use a volatile silicone oil at room temperature (25 ° C.). The component A) is excellent in compatibility with these oils, and is preferably added to the cosmetic as a solution previously dissolved in these silicone oils.

Examples of the hydrocarbon oil include linear, branched, and volatile hydrocarbon oils. Specifically, ozokerite, α-olefin oligomer, hexane, heptane, octane, cyclohexane, toluene, benzene, xylene. , Cyclohexene, light isoparaffin, isododecane, light liquid isoparaffin, squalane, synthetic squalane, vegetable squalane, squalene, ceresin, paraffin, paraffin wax, polyethylene wax, polyethylene / polypropylene wax, (ethylene / propylene / styrene) copolymer, (butylene / Propylene / styrene) copolymer, liquid paraffin, liquid isoparaffin, pristane, polyisobutylene, hydrogenated polyisobutene, microcrystalline wax, petroleum jelly and the like.

As higher fatty acids, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), isostearic acid , 12-hydroxystearic acid and the like.

Higher alcohol oils include lauryl alcohol, myristyl alcohol, palmityl alcohol, stearyl alcohol, behenyl alcohol, hexadecyl alcohol, oleyl alcohol, isostearyl alcohol, hexyl decanol, octyldodecanol, cetostearyl alcohol, 2-decyltetradecinol , Cholesterol, phytosterol, POE cholesterol ether, monostearyl glycerin ether (batyl alcohol), monooleyl glyceryl ether (ceracyl alcohol) and the like.

Ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, N-alkyl glycol monoisostearate, isocetyl isostearate, triisostearate tris Methylolpropane, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, octyldodecyl gum ester, Oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, triethyl citrate, 2-ethyl succinate Hexyl, amyl acetate, ethyl acetate, butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isononyl isononanoate, isotridecyl isononanoate, isopropyl palmitate, palmitate 2-ethylhexyl acid, 2-hexyldecyl palmitate, 2-heptylundecyl palmitate, cholesteryl 12-hydroxystearylate, dipentaerythritol fatty acid ester, isopropyl myristate, octyldodecyl myristate, 2-hexyldecyl myristate, myristine Myristyl acid, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, N-lauroyl-L-glutamic acid-2-octy Dodecyl ester, lauroyl sarcosine isopropyl ester, and the like diisostearyl malate is. Examples of the glyceride oil include acetoglyceryl, glyceryl triisooctanoate, glyceryl triisostearate, glyceryl triisopalmitate, glyceryl monostearate, glyceryl di-2-heptylundecanoate, glyceryl trimyristate, and diglyceryl myristate. Is mentioned.

Natural animal and plant oils and semi-synthetic oils and fats include avocado oil, linseed oil, almond oil, ibotarou, eno oil, olive oil, cacao butter, kapok wax, kaya oil, carnauba wax, liver oil, candelilla wax, refined candelilla wax, beef tallow, Beef leg fat, beef bone fat, hydrogenated beef fat, kyounin oil, whale wax, hydrogenated oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sugar cane wax, sasanqua oil, safflower oil, shea butter, cinnamon oil, cinnamon Oil, jojoba wax, squalane, squalene, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil, nukarou, germ oil, horse fat, persic oil , Palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid methyl ester, sunflower oil, grape oil Bayberry wax, jojoba oil, macadamia nut oil, beeswax, mink oil, minchiro, meadow foam oil, cottonseed oil, cotton wax, molasses, owl kernel oil, montan wax, coconut oil, hardened coconut oil, tricoconut oil fatty acid glyceride, sheep fat, peanut oil, Lanolin, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin wax, hard lanolin, lanolin acetate, lanolin acetate alcohol, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, egg yolk Oil etc. are mentioned. However, POE means polyoxyethylene.

Examples of the fluorinated oil include perfluoropolyoxyalkylene, perfluorodecalin, and perfluorooctane.

B) The blending amount of the oil is appropriately adjusted in accordance with the dosage form of the cosmetic in the range of 1 to 98% by weight of the cosmetic. The linear, branched, or cyclic volatile silicone oil at 25 ° C. is preferably mixed in a weight ratio of 1: 2 to 100: 1, more preferably 1: Mix 1-70: 1.

In the cosmetic of the present invention, a compound having an alcoholic hydroxyl group in one or more C) molecular structures can be used depending on the purpose. For example, there are lower alcohols such as ethanol, isopropanol and butanol, sugar alcohols such as sorbitol and maltose, etc., and sterols such as cholesterol, sitosterol, phytosterol and lanosterol, and many such as butylene glycol, propylene glycol, dibutylene glycol and pentylene glycol In general, water-soluble monohydric alcohols and water-soluble polyhydric alcohols are often used. The blending amount may be in the range of 0.1 to 98% by weight of the entire cosmetic.

  In the cosmetic of the present invention, one or more of D) a water-soluble polymer or a water-swellable polymer can be used depending on the purpose.

Examples of the water-soluble polymer include gum arabic, tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), starch (rice, corn, potato, wheat, etc.), alge colloid, Plant-based polymers such as trant gum and locust bean gum; microbial polymers such as xanthan gum, dextran, succinoglucan and pullulan; animal-based polymers such as collagen, casein, albumin and gelatin; carboxymethyl starch and methylhydroxypropyl starch Starch-based polymers such as: methylcellulose, ethylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, Cellulosic polymers such as trocellulose, sodium cellulose sulfate, sodium carboxymethylcellulose, crystalline cellulose, cellulose acetate, cellulose powder; alginic acid polymers such as sodium alginate and propylene glycol alginate; vinyl such as polyvinyl methyl ether and carboxyvinyl polymer Polyoxyethylene polymer; polyoxyethylene polyoxypropylene copolymer polymer; acrylic polymer such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, acryloyldimethyltaurine salt copolymer; polyethyleneimine, Other synthetic water-soluble polymers such as cationic polymers; bentonite, magnesium aluminum silicate, montmorillonite, beidellite, non Ronaito, saponite, hectorite, and the like inorganic water-soluble polymers such as anhydrous silicic acid. These water-soluble polymers also include film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone. As a compounding quantity, the range of 0 to 25 weight% of the whole cosmetics is suitable.

  E) Water can also be mix | blended with the cosmetics of this invention. The blending amount varies depending on the agent system, but may be in the range of 1 to 99% by weight of the entire cosmetic.

F) powder can be mix | blended with the cosmetics of this invention. If the powder is used in ordinary cosmetics, its shape (spherical, needle-like, plate-like, dendritic, fibrous, amorphous, etc.) and particle size (smoke, fine particles, pigment grade, etc.) ), Any particle structure (porous, nonporous, hollow, hollow porous, etc.) can be used. Examples of such powders include inorganic powders, organic powders, surfactant metal salt powders, colored pigments, pearl pigments, metal powder pigments, natural dyes, and the like.

Examples of inorganic powders include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, muscovite, Synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, metal tungstate Salt, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, silicon nitride, boron nitride, silica Silylated silica. Of these, zinc oxide and titanium oxide are preferred. Further, extender pigments such as calcium carbonate and talc are also preferably used. A) component can improve the dispersibility in cosmetics of these powders.

Examples of organic powders include polyamide powder, polyacrylic acid / acrylate powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane powder, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethyl Methacrylate powder, cellulose powder, silk powder, nylon powder such as 12 nylon and 6 nylon, or these fibrous powders, crosslinked silicone fine powder having a structure in which dimethylpolysiloxane is crosslinked, crosslinked spherical polymethylsilsesquioxide Sun fine powder, fine powder obtained by coating the surface of cross-linked spherical organopolysiloxane rubber with polymethylsilsesquioxane particles, hydrophobized silica, steel -Acrylic acid copolymer, divinylbenzene-styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, or the lamination of these resins , Microcrystalline fiber powder, starch powder, fatty acid starch derivative powder, lauroyl lysine and the like.

In particular, a crosslinked spherical dimethylpolysiloxane fine powder having a structure in which dimethylpolysiloxane is crosslinked on a part of the powder, a crosslinked spherical polymethylsilsesquioxane fine powder, and a crosslinked spherical dimethylpolysiloxane rubber surface with polymethylsil Fine powder formed by coating with sesquioxane particles, fine powder formed by coating the cross-linked spherical diphenylpolysiloxane rubber surface with polymethylsilsesquioxane particles, and hydrophobized silica are preferred. KMP-590 is a commercially available product. , KSP-100, KSP-101, KSP-102, KSP-105, KSP-300 (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.

Surfactant metal salt powder (metal soap) includes: zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, sodium cetyl phosphate, palmitic Examples thereof include zinc acid, aluminum palmitate, and zinc laurate.

Colorants include pigments and dyes. Specific examples of colored pigments include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, black iron oxide , Inorganic black pigments such as carbon black, silica-coated iron pigments, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, bitumen and ultramarine blue Inorganic blue pigments such as those obtained by rake formation of tar dyes, those obtained by rake formation of natural dyes, and synthetic resin powders obtained by combining these powders.

Examples of the pearl pigment include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, silica-coated mica titanium, fish scale foil, and titanium oxide-coated colored mica.

Examples of the metal powder pigment include aluminum powder, copper powder, and stainless steel powder.

As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207, etc .; natural pigments include carminic acid, laccaic acid, and calsamine , Bradylin, crocin and the like.

Further, powders that absorb and scatter ultraviolet rays, such as fine particle titanium oxide, fine particle iron-containing titanium oxide, fine particle zinc oxide, fine particle cerium oxide, and a composite thereof, may also be mentioned. In addition, these powders that absorb and scatter ultraviolet rays are separately surface-treated with aluminum oxide, aluminum hydroxide, silica, silica gel, zinc silicate, etc., mainly for the purpose of blocking the surface activity of the powder. It may be.

These powders are within the range that does not interfere with the effects of the present invention, those obtained by compounding powders, those that are separately treated with general oils, silicone oils, fluorine compounds, surfactants, metal soaps, etc., hydrolyzable silyls Straight-chain and / or branched organopolysiloxane having a hydrolyzable silyl group or a hydrogen atom directly bonded to a silicon atom; Linear and / or branched organopolysiloxanes having hydrogen atoms directly bonded to decomposable silyl groups or silicon atoms and co-modified with long-chain alkyl, hydrogen atoms directly bonded to hydrolyzable silyl groups or silicon atoms And a linear and / or branched organopolysiloxane co-modified with polyoxyalkylene, a hydrogen atom directly bonded to a hydrolyzable silyl group or a silicon atom With acrylic - silicone copolymers can also be used, it may be used if desired one, or two or more. These powders are treated with a surface treatment agent such as AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574 (all manufactured by Shin-Etsu Chemical Co., Ltd.). Can be used.

  G) surfactant can be used for the cosmetics of this invention. Such surfactants include anionic, cationic, nonionic and amphoteric active agents, but are not particularly limited, and any surfactant can be used as long as it is used in normal cosmetics. Things can also be used.

  Examples of anionic surfactants include sodium stearate, potassium stearate, triethanolamine stearate, sodium palmitate, potassium palmitate, triethanolamine palmitate, sodium laurate, potassium laurate, triethanolamine laurate, etc. Fatty acid soaps; alkyl ether carboxylic acids and salts thereof; condensates of amino acids and fatty acids, alkane sulfonates, alkene sulfonates, sulfonates of fatty acid esters, sulfonates of fatty acid amides, formalin condensation sulfonates Alkyl sulfate ester, secondary higher alcohol sulfate ester, alkyl and allyl ether sulfate ester, fatty acid ester sulfate ester, fatty acid alkylolamide sulfate ester, funnel oil, etc. Sulfate esters, alkyl phosphates, ether phosphates, alkyl allyl ether phosphates, amide phosphates, N-acyl lactates, N-acyl sarcosine salts, N-acyl amino acid based surfactants, etc .; cationic surface activity Examples of the agent include amine salts such as alkylamine salts, polyamines and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridium salts, imidazolium salts and the like.

  Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, methyl glucoside fatty acid ester, alkyl polyglucoside, polyoxyethylene alkyl Ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, Polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, poly Oxyethylene phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, linear or branched polyoxyalkylene modified organopolysiloxane, linear or branched polyoxyalkylene Alkyl co-modified organopolysiloxane, linear or branched polyglycerin-modified organopolysiloxane, linear or branched polyglycerin / alkyl co-modified organopolysiloxane, alkanolamide, sugar ether, sugar amide, etc .; amphoteric surface activity Examples of the agent include betaine, phosphatidylcholine, aminocarboxylate, imidazoline derivative, amidoamine type and the like.

  Among these surfactants, a linear or branched organopolysiloxane having a polyoxyethylene chain in the molecule, a linear or branched organopolysiloxane having a polyglycerin chain in the molecule, or an alkyl copolymer thereof. A surfactant which is a modified organopolysiloxane is preferred. Commercially available products include KF-6011, KF-6011P, KF-6043, KF-6012, KF-6013, KF-6015, KF-6016, KF-6017, KF-6028, KF-6028P, KF-6038, KF. -6100, KF-6104, KF-6105 (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like. Moreover, the surfactant which is 1-10 as HLB is preferable, and it is preferable that a compounding quantity is 0.1-20 weight% of the whole cosmetics, and the range of 0.2-10 weight% is especially suitable. is there.

In the cosmetic of the present invention, one or more H) cross-linked organopolysiloxanes may be used depending on the purpose. The cross-linked organopolysiloxane is preferably one that swells by containing the liquid oil of its own weight or more with respect to the liquid oil. The liquid oil, may be used those described as B) oil agent, for example, 0.65 mm ² / s (25 ℃) ~100.0mm ² / s (25 ° C.) low viscosity silicone oil, liquid paraffin, Examples include hydrocarbon oils such as squalane and isododecane, glyceride oils such as trioctanoin, ester oils such as isotridecyl isononanoate, N-acyl glutamate esters, lauroyl sarcosine esters, and natural animal and vegetable oils such as macadamian nut oils.

Moreover, the crosslinking agent of this cross-linked organopolysiloxane has a cross-linked structure by reacting with hydrogen atoms having two or more vinyl reactive sites in the molecule and directly bonded to silicon atoms. It is preferable. Those having two or more vinyl reactive sites in the molecule include organopolysiloxanes having two or more vinyl groups in the molecule, polyoxyalkylenes having two or more allyl groups in the molecule, Examples include polyglycerin having two or more allyl groups, α, ω-alkenyl diene, and the like.

Further, the crosslinked organopolysiloxane contains in the molecule at least one part selected from the group consisting of a polyoxyalkylene part, a polyglycerin part, an alkyl part, an alkenyl part, an aryl part, and a fluoroalkyl part. May be. These cross-linked organopolysiloxanes are not particularly limited, but commercially available products include KSG-15, KSG-16, KSG-18, KSG-1610, USG-103, KSG made into a paste with silicone oil. -210, KSG-240, KSG-710, USG-106, KSG-41, KSG-42, KSG-43, KSG-44, KSG-310, KSG-320, pasted with hydrocarbon oil or triglyceride oil, KSG-330, KSG-340, KSG-810, KSG-820, KSG-830, KSG-840 (all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.

The amount of the crosslinked organopolysiloxane is preferably 0.01 to 40% by weight, particularly preferably 0.1 to 30% by weight, based on the total amount of the cosmetic.

In the cosmetic of the present invention, one or two or more I) silicone resins can be used depending on the purpose. I) The silicone resin is preferably an acrylic silicone resin of an acrylic / silicone graft or block copolymer, and further contains an anionic moiety such as a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety, or a carboxylic acid. An acrylic silicone resin containing in the molecule at least one portion selected from the inside is preferred. Commercially available products include KP-541, KP-543, KP-545, KP-549, KP-550, KP-571, KP-575, KP-581 dissolved in silicone oil, hydrocarbon oil or alcohol (all Shin-Etsu Chemical Co., Ltd.).

This silicone resin is preferably a silicone network compound represented as MQ, MDQ, MT, MTQ, MDT, or MDTQ as a constituent component. M, D, T, and Q represent R ₃ SiO _0.5 unit, R ₂ SiO unit, RSiO _1.5 unit, and SiO ₂ unit, respectively, and are commonly used in the silicone industry. . The silicone reticulated resin is generally known as MQ resin, MT, or MDT resin, and may have a portion indicated as MDQ, MTQ, or MDTQ. Specifically, it is commercially available as a solution such as decamethylcyclopentasiloxane or dimethicone, and is at least selected from a pyrrolidone moiety, a long-chain alkyl moiety, a polyoxyalkylene moiety and a fluoroalkyl moiety, and an amino moiety. One kind of part may be contained in the molecule.

When a silicone resin such as an acrylic silicone resin or a silicone network compound is used, the blending amount is preferably 0.1 to 20% by weight, particularly 1 to 10% by weight, based on the total amount of the cosmetic. preferable.

  The cosmetic of the present invention may contain J) silicone wax depending on the purpose. This silicone wax is preferably a polylactone-modified polysiloxane in which a lactone compound having a 5-membered ring or more is combined with a polylactone which is a ring-opening polymer. Alternatively, the silicone wax is an acrylic-modified polysiloxane containing at least one portion selected from an anion portion such as a pyrrolidone portion, a long-chain alkyl portion, a polyoxyalkylene portion, a fluoroalkyl portion, and a carboxylic acid in the molecule. It is preferable that Examples of commercially available products include KP-561P and KP-562P (both manufactured by Shin-Etsu Chemical Co., Ltd.) as waxes having a long-chain alkyl group.

Alternatively, the silicone wax is preferably a silicone-modified olefin wax obtained by addition reaction of an olefin wax and an organohydrogenpolysiloxane having one or more molecules of SiH bond. The olefin wax is obtained by copolymerizing ethylene and at least one diene, or at least one olefin selected from ethylene and an α-olefin having 3 to 12 carbon atoms and at least one diene. It is obtained by copolymerization, and as this diene, vinyl norbornene is suitable.

Whatever silicone wax is selected, when silicone wax is used, its blending amount is preferably 0.1 to 20% by weight, particularly 1 to 10% by weight, based on the total amount of the cosmetic. Is preferred.

  Furthermore, the cosmetics of the present invention include components, oil-soluble gelling agents, organically modified clay minerals, resins, antiperspirants, and UV absorbers that are used in ordinary cosmetics as long as they do not interfere with the effects of the present invention. , UV absorbing / scattering agent, moisturizer, antiseptic, antibacterial agent, fragrance, salt, antioxidant, pH adjuster, chelating agent, refreshing agent, anti-inflammatory agent, skin care ingredients (whitening agent, cell activator, rough skin improvement Agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, hair solidifying agents, and the like.

Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate and zinc myristate; amino acid derivatives such as N-lauroyl-L-glutamic acid-α, γ-di-n-butylamine; dextrin palmitate Dextrin fatty acid esters such as dextrin stearate, dextrin 2-ethylhexanoic acid palmitate; sucrose fatty acid esters such as sucrose palmitate and sucrose stearate; fructooligosaccharide stearate, 2-ethyl fructooligosaccharide Fructooligosaccharide fatty acid esters such as hexanoic acid esters; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol and dibenzylidene sorbitol, dimethylbenzyl dodecyl ammo Examples thereof include gelling agents selected from organically modified clay minerals such as nium montmorillonite clay and dimethyl dioctadecyl ammonium montmorillonite clay.

Examples of the antiperspirant include an antiperspirant selected from aluminum chlorohydrate, aluminum chloride, aluminum sesquichlorohydrate, zirconyl hydroxychloride, aluminum zirconium hydroxychloride, aluminum zirconium glycine complex, and the like.

Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic acid UV absorbers such as methyl anthranilate, salicylic acid UV absorbers such as methyl salicylate, octyl salicylate and trimethylcyclohexyl salicylate, and paramethoxysilicate. Cinnamic acid UV absorbers such as octyl cinnamate, benzophenone UV absorbers such as 2,4-dihydroxybenzophenone, urocanic acid UV absorbers such as ethyl urocanate, 4-t-butyl-4'-methoxy- Examples include dibenzoylmethane-based ultraviolet absorbers such as dibenzoylmethane, phenylbenzimidazole sulfonic acid, etc., and examples of ultraviolet absorption / scattering agents include particulate titanium oxide, particulate iron-containing titanium oxide, particulate zinc oxide, particulate cerium oxide, and their UV, such as composite The absorbent scattering powder and the like, can also be used a dispersion obtained by dispersing in advance oil these ultraviolet absorbing scattering agents.

Moisturizers include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, pentylene glycol, glucose, xylitol, maltitol, polyethylene glycol, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, polyoxy Examples include ethylene methyl glucoside, polyoxypropylene methyl glucoside, egg yolk lecithin, soybean lecithin, phosphatidyl choline, phosphatidyl ethanolamine, phosphatidyl serine, phosphatidyl glycerol, phosphatidylinositol, sphingophospholipid and the like.

Antibacterial and antiseptics include paraoxybenzoic acid alkyl esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc., and antibacterial agents include benzoic acid, salicylic acid, carboxylic acid, sorbic acid, paraoxybenzoic acid alkyl ester , Parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, photosensitizer, phenoxyethanol and the like.

Examples of the salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, and the like of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; Salts of organic acids such as dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, stearic acid; amine salts and amino acid salts include, for example, salts of amines such as triethanolamine, and amino acids such as glutamic acid There is salt. In addition, a salt such as hyaluronic acid and chondroitin sulfate, an aluminum zirconium glycine complex, etc., and an acid-alkali neutralized salt used in cosmetic formulations can also be used.

Antioxidants include tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, etc., and pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, Potassium carbonate, sodium bicarbonate, ammonium bicarbonate, etc., chelating agents such as alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc., refreshing agents such as L-menthol, camphor, etc., anti-inflammatory Examples of the agent include allantoin, glycyrrhizic acid and salts thereof, glycyrrhetinic acid and stearyl glycyrrhetinic acid, tranexamic acid, and azulene.

As skin beautifying ingredients, placenta extract, whitening agents such as arbutin, glutathione, and yukinoshita extract, royal jelly, photosensitizer, cholesterol derivatives, cell activators such as calf blood extract, rough skin improver, nonyl acid wallenylamide, Nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, Examples thereof include blood circulation promoters such as acetylcholine, verapamil, cephalanthin and γ-oryzanol, skin astringents such as zinc oxide and tannic acid, and antiseborrheic agents such as sulfur and thianthol.

Vitamins such as vitamin A oil, retinol, retinol acetate, retinol palmitate, etc., vitamin B2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmi Vitamin B6 such as tate, vitamin B12 and derivatives thereof, vitamin B such as vitamin B15 and derivatives thereof, L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, L- Vitamin C such as ascorbic acid phosphoric acid diester dipotassium, vitamin D such as ergocalciferol, cholecalciferol, α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate , Vitamin E such as dl-α-tocopherol nicotinate, dl-α-tocopherol succinate, nicotinic acids such as vitamin H, vitamin P, nicotinic acid, benzyl nicotinate, nicotinamide, calcium pantothenate, D-pant There are pantothenic acids such as tenenyl alcohol, pantothenyl ethyl ether, acetyl pantothenyl ethyl ether, biotin and the like.

As amino acids, glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, tryptophan, etc., nucleic acid, deoxyribonucleic acid, etc., hormone, estradiol , Etenyl estradiol and the like.

Examples of polymer compounds for fixing to hair and nails include amphoteric, anionic, cationic, and nonionic polymer compounds, such as polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers. Polymer compounds, acidic vinyl ether polymer compounds such as methyl vinyl ether / alkyl maleic anhydride alkyl half ester copolymers, acidic polyvinyl acetate polymers such as vinyl acetate / crotonic acid copolymers, (meth) acrylic acid / alkyl (Meth) acrylate copolymer, acidic acrylic polymer such as (meth) acrylic acid / alkyl (meth) acrylate / alkylacrylamide copolymer, N-methacryloylethyl-N, N-dimethylammonium α-N- Methyl carboxybetaine / alkyl (meth) acrylate copolymer Body, hydroxypropyl (meth) acrylate / butylaminoethyl methacrylate / amphoteric acrylic polymer compounds such as acrylic acid octyl amide copolymers. In addition, cellulose or derivatives thereof, naturally derived polymer compounds such as keratin and collagen or derivatives thereof, alkyd resins, epoxy resins, phenol resins, unsaturated polyesters, acrylic copolymers, urethane resins, various rubbers (NBR, SBR, Synthetic resins such as SIS, SBS, EPDM, etc.) and chlorinated polyethylene can also be suitably used.

Examples of cosmetics include powder, oily, water-in-oil emulsion, oil-in-water emulsion, non-water emulsion, and multi-emulsions such as W / O / W and O / W / O. Cosmetics such as lotions, emulsions, creams, cleansings, packs, massages, serums, beauty oils, cleaning agents, deodorants, hand creams, lip balms, wrinkle masks Skin care cosmetics such as products, makeup base, concealer, white powder, powder foundation, liquid foundation, cream foundation, oily foundation, blusher, eye shadow, mascara, eyeliner, eyebrow, lipstick, makeup cosmetics, enamel, under Beauty nail such as coat, overcoat, shampoo, Vinegar, treatments, hair cosmetics such as setting agent, antiperspirant cosmetic, like ultraviolet protection cosmetics, such as sunscreen oil, sunscreen lotion and sunscreen cream.

The product forms of these cosmetics are liquid, emulsion, cream, solid, paste, gel, powder, press, multilayer, mousse, aerosol, spray, stick, etc. Various forms can be selected.

Furthermore, when applying or transferring these cosmetics to the skin, nails, head hair, eyebrows, or eyelashes, it is also possible to use fingers, and select various applicators such as brushes, tips, puffs, spatulas, etc. Can be used.

  Hereinafter, the present invention will be described in more detail by way of examples. In addition, this invention is not limited by this. Unless otherwise specified, “%” described below means “% by weight”.

これをモノマーＡとする。 Monomer Production Example 1: Synthesis of tris (trimethylsiloxy) silylnorbornene 307 g of dicyclopentadiene and 750 g of tristrimethylsiloxyvinylsilane were charged into a 2 liter reactor and reacted at 160 to 170 ° C. for 8 hours under a nitrogen seal. It was. When the reaction solution was distilled under reduced pressure, 757 g of a fraction having a boiling point of 118 to 120 ° C./5 mmHg was obtained. ^The structure was confirmed by ¹ H-NMR analysis (measuring device LAMBDA LA-300W manufactured by JEOL) and infrared spectroscopic analysis (measuring device Perkin Elmer FT-IR Spectrometer Spectrum One), and the compound represented by the following structural formula It was confirmed that there was.

This is monomer A.

これをモノマーＢとする。 Monomer Production Example 2: Synthesis of perfluorobutylnorbornene 40 g of dicyclopentadiene and 73 g of 1H, 1H, 2H-perfluoro-1-hexene were charged into a 200 ml reactor, and sealed at 150 to 160 ° C. under a nitrogen seal. The reaction was performed for 12 hours. When the reaction solution was distilled under reduced pressure, 71 g of a fraction having a boiling point of 108 to 110 ° C./5 mmHg was obtained. ^The structure was confirmed by ¹ H-NMR analysis (measuring device LAMBDA LA-300W manufactured by JEOL) and infrared spectroscopic analysis (measuring device Perkin Elmer FT-IR Spectrometer Spectrum One), and the compound represented by the following structural formula It was confirmed that there was.

This is monomer B.

Polymer production example 1: Synthesis of tris (trimethylsiloxy) silylnorbornene ring-opened polymer 50 g of monomer A was placed in a 3 liter four-necked flask equipped with a stirrer and dissolved in 2 liters of toluene. Ar (or N ₂ ) substitution. The mixture was heated with stirring so that the monomer was uniformly diffused, and kept at 40 ° C. A catalyst solution prepared by dissolving Grubbs first generation catalyst [benzylidene-bis (tricyclohexylphosphine) dichlororuthenium] in 0.105 g of toluene (110 ml) was quickly added thereto. After 20 minutes, 1 ml of ethyl vinyl ether was added to stop the polymerization and stirred for 5 minutes to obtain a polymer solution. The obtained reaction liquid was poured into a large amount of methanol, and the deposited one was dried under reduced pressure to obtain a solid. This is polymer A. A part of the polymer A was collected and subjected to gel permeation chromatography (measurement apparatus HLC-8220 manufactured by Tosoh Corporation), and its molecular weight was examined using polystyrene as a standard. Mn = 163,000, Mw / Mn = 1.75.

Polymer production example 2: Synthesis of tris (trimethylsiloxy) silylnorbornene-b-perfluorobutylnorbornene ring-opening copolymer Instead of using 50 g of monomer A in polymer production example 1, 45 g of monomer A and monomer A polymer was synthesized in the same manner as in Production Example 1 except that the mixed monomer of B5g was used. This is polymer B. A part of the polymer B was collected and subjected to gel permeation chromatography. The molecular weight was examined by using polystyrene as a standard. The results were Mn = 14,000 and Mw / Mn = 1.85.

Polymer production example 3: Synthesis of tris (trimethylsiloxy) silylnorbornene-b-norbornenemethanol ring-opening copolymer Instead of using 50 g of monomer A in polymer production example 1, 45 g of monomer A and 5-norbornene A polymer was synthesized in the same manner as in Production Example 1 except that a mixed monomer of -2-methanol 5 g was used. This is polymer C. A part of the polymer C was collected and subjected to gel permeation chromatography. The molecular weight was examined using polystyrene as a standard. The results were Mn = 145,000 and Mw / Mn = 1.91.

Polymer production example 4: Synthesis of tris (trimethylsiloxy) silylnorbornene ring-opened polymer hydride 25 g of polymer A and 1 liter of toluene were placed in a stirred autoclave, and the inside of the autoclave was purged with nitrogen, and then Grubbs First-generation catalyst [benzylidene-bis (tricyclohexylphosphine) dichlororuthenium] 0.7 g and hydrogenation catalyst solution in which 1.5 g of ethyl vinyl ether was dissolved in 5 ml of toluene were added, and hydrogen was added at 0.8 MPa at 160 ° C. Time hydrogenation was performed. The obtained reaction liquid was poured into a large amount of methanol, and the deposited one was dried under reduced pressure to obtain a solid. This was designated as Polymer D. ^{From 1} H-NMR, it was confirmed that 93% of the main chain carbon-carbon double bond of polymer A was hydrogenated. A part of the polymer D was sampled and subjected to gel permeation chromatography (measurement device HLC-8220 manufactured by Tosoh Corporation), and the molecular weight was examined using polystyrene as a standard. Mn = 165,000, Mw / Mn = 1.79.

Decamethylcyclopentasiloxane (D5) dissolved product of polymer A 40 g of polymer A and 93.5 g of D5 were placed in a separable flask purged with nitrogen. Polymers A and D5 were uniformly dissolved with a glass stirrer at 80 ° C. to prepare a 30% solution.

Methyltrimethicone (M3T) dissolved product of polymer A A dissolved product was produced in the same manner except that the solvent was changed from D5 to M3T.

Isododecane dissolved product of polymer A A dissolved product was produced in the same manner except that the solvent was changed to isododecane.

M3T dissolved product of polymer B 40 g of polymer B and 93.5 g of M3T were placed in a separable flask purged with nitrogen. Polymer A and M3T were uniformly dissolved with a glass stirrer at 80 ° C. to prepare a 30% solution.

D5 dissolved product of polymer D 40 g of polymer D and 93.5 g of D5 were placed in a separable flask purged with nitrogen. Polymers D and D5 were uniformly dissolved at 80 ° C. with a glass stirrer so that a 30% dissolved product was obtained.

Examples of preparing cosmetics using the obtained polymers or their solutions are shown below.
Example 1, Comparative Examples 1 and 2
An emulsified cream foundation having the composition shown in Table 1 was prepared.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０１７
（注４）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注５）信越化学工業（株）製：ＫＦ−９９０９処理
（注６）信越化学工業（株）製：ＫＦ−７３１２Ｊ （シリコーンレジン５０％のＤ５溶解品）
（注７）信越化学工業（株）製：ＫＰ−５４５ （シリコーン変性アクリルポリマー３０％のＤ５溶解品）

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6017
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 5) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 6) Shin-Etsu Chemical Co., Ltd .: KF-7312J (D5 dissolved product of 50% silicone resin)
(Note 7) Shin-Etsu Chemical Co., Ltd .: KP-545 (D5 dissolved product of 30% silicone-modified acrylic polymer)

<Preparation of cosmetics>
Components (1) to (8), (19) and (20) were stirred and mixed so as to be uniform. Separately, components (9) and (10), which were separately dissolved in component (11), were gently added and emulsified. To this emulsion, components (12) to (18) and (21) separately roller-treated were added and mixed. This was filled in a predetermined container to prepare an emulsified cream foundation. The following evaluation was performed about the obtained emulsion type cream foundation.

<Usability evaluation>
The emulsified cream foundation obtained was evaluated by the following criteria for 50 female panelists in terms of spreading (spreadability), stickiness, uneven finish, transparent finish, and long-lasting makeup (durability). did.
<Secondary adhesion prevention effect>
The cosmetics of Example 1, Comparative Example 1 and Comparative Example 2 were applied to the forehead part of the specialized panel according to the same operation, respectively, and when 10 minutes passed after application, tissue paper was pressed against the application part, The secondary adhesion prevention effect of cosmetics was evaluated according to the following criteria. The average of the evaluation results was taken.
<Evaluation criteria>

The results are shown in Table 3. In the table, each symbol is as follows.

As is apparent from Table 3, the cosmetic of the present invention has a makeup and remarkably superior secondary adhesion preventing property as compared with Comparative Examples 1 and 2, and also has good usability.

（注１）信越化学工業（株）製：ＫＦ−９９０９処理
（注２）信越化学工業（株）製：ＫＳＧ−１６
（注３）信越化学工業（株）製：ＫＰ−５６２Ｐ
＜化粧料の調製＞
Ａ：成分１〜８を混合して均一に粉砕した。
Ｂ：成分９〜１２を均一混合した。
Ｃ：ＢをＡに加えて均一にし、金型にプレス成型してパウダーファンデーションを得た。
得られたパウダーファンデーションは、軽く延び、化粧持続性が良く、２次付着もなかった。 Hereinafter, formulation examples of cosmetics are shown. In the following, the extension, makeup holding, and foundation were evaluated with respect to secondary adhesion prevention performance based on the same criteria as described above.
Example 2: Powder foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 3) Shin-Etsu Chemical Co., Ltd .: KP-562P
<Preparation of cosmetics>
A: Components 1 to 8 were mixed and ground uniformly.
B: Components 9 to 12 were uniformly mixed.
C: B was added to A to make it uniform, and pressed into a mold to obtain a powder foundation.
The obtained powder foundation was lightly stretched, had good makeup persistence, and had no secondary adhesion.

（注１）信越化学工業（株）製：ＡＥＳ−３０８３処理
（注２）信越化学工業（株）製：ＫＦ−９９０９処理
（注３）信越化学工業（株）製：ＫＳＰ−３００
（注４）信越化学工業（株）製：ＫＭＰ−５９０
＜化粧料の調製＞
Ａ：成分１〜９を混合して均一に粉砕した。
Ｂ：成分１１〜１４を均一混合し、Ａに加えて均一にした。
Ｃ：Ｂに成分１０を添加し、金型にプレス成型してパウダーファンデーションを得た。
得られたパウダーファンデーションは、軽く延び、化粧持続性に優れ、２次付着もなかった。 Example 3: Powder foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: AES-3083 treatment (Note 2) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-300
(Note 4) Shin-Etsu Chemical Co., Ltd .: KMP-590
<Preparation of cosmetics>
A: Components 1 to 9 were mixed and ground uniformly.
B: Components 11 to 14 were uniformly mixed and added to A to make it uniform.
C: Component 10 was added to B and pressed into a mold to obtain a powder foundation.
The obtained powder foundation extended lightly, was excellent in makeup persistence, and did not have secondary adhesion.

（注１）信越化学工業（株）製：ＫＳＧ−７１０
（注２）信越化学工業（株）製：ＫＦ−６１０５
（注３）信越化学工業（株）製：ＫＭＰ−５９０
（注４）信越化学工業（株）製：ＫＦ−９９０９処理
（注５）信越化学工業（株）製：ＫＦ−９９０９処理
＜化粧料の調製＞
Ａ：成分１〜９を加熱溶解して均一にした。
Ｂ：成分１０〜１３及び１４の一部を混合し、ローラーで分散処理した。
Ｃ：成分１４の残部、１５及び１７を均一溶解し、これをＢに加えて、加熱下、均一分散させた。
Ｄ：加熱攪拌下、ＡにＣを加えて乳化し、これに成分１６を加えて、気密性の高い所定の容器に充填してスティック状Ｗ／Ｏファンデーションを得た。
得られたスティック状Ｗ／Ｏファンデーションは、軽く延び、化粧持続性に優れ、２次付着もなかった。 Example 4: Stick-like W / O foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-710
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6105
(Note 3) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 5) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment <Preparation of cosmetics>
A: Components 1 to 9 were heated and dissolved to be uniform.
B: A part of components 10 to 13 and 14 were mixed and dispersed with a roller.
C: The remainders of component 14, 15 and 17 were uniformly dissolved, added to B, and uniformly dispersed under heating.
D: Under heating and stirring, C was added to A to emulsify, component 16 was added thereto, and the mixture was filled in a predetermined highly airtight container to obtain a stick-like W / O foundation.
The obtained stick-like W / O foundation was lightly stretched, excellent in makeup persistence, and had no secondary adhesion.

（注１）信越化学工業（株）製：ＫＦ−６１００
＜化粧料の調製＞
Ａ：成分１〜１０を加えて均一に混合し、メイク落としを得た。
以上のようにして得られたメイク落としを用いて、ファンデーションを落としたところ、化粧料や皮脂汚れとのなじみが良く、汚れ落ちが非常に良好で、使用後のべたつきもなかった。 Example 5: Makeup removal

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6100
<Preparation of cosmetics>
A: Components 1 to 10 were added and mixed uniformly to obtain a makeup remover.
When the foundation was removed using the makeup remover obtained as described above, the familiarity with cosmetics and sebum stains was good, the stain removal was very good, and there was no stickiness after use.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０２８
＜化粧料の調製＞
Ａ：成分１〜７及び９を加えて均一に混合した。
Ｂ：成分８及び１０を混合した。
Ｃ：ＢをＡに加えて均一に乳化し、クリームを得た。
以上のようにして得られた油中多価アルコール乳化クリームは、のび広がりが軽くて、べたつきや油っぽさもなく、しっとり感があった。 Example 6: Polyhydric alcohol emulsified cream in oil

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028
<Preparation of cosmetics>
A: Components 1 to 7 and 9 were added and mixed uniformly.
B: Components 8 and 10 were mixed.
C: B was added to A and uniformly emulsified to obtain a cream.
The polyhydric alcohol emulsified cream in oil obtained as described above had a light spread, no stickiness or oiliness, and a moist feeling.

（注１）信越化学工業（株）製：ＫＳＧ−７１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＳＧ−１６１０
（注４）信越化学工業（株）製：ＫＦ−６１０４
（注５）信越化学工業（株）製：ＫＳＰ−３００
＜化粧料の調製＞
Ａ：成分１〜７及び９を加えて均一に混合した。
Ｂ：成分８及び１０、１１を混合した。
Ｃ：ＢをＡに加えて均一に乳化し、クリームを得た。
以上のようにして得られた油中多価アルコール乳化クリームは、のび広がりが軽くて、べたつきや油っぽさもなく、しっとり感があった。
Example 7: Polyhydric alcohol emulsified cream in oil

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-710
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSG-1610
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6104
(Note 5) Shin-Etsu Chemical Co., Ltd .: KSP-300
<Preparation of cosmetics>
A: Components 1 to 7 and 9 were added and mixed uniformly.
B: Components 8 and 10, 11 were mixed.
C: B was added to A and uniformly emulsified to obtain a cream.
The polyhydric alcohol emulsified cream in oil obtained as described above had a light spread, no stickiness or oiliness, and a moist feeling.

（注１）信越化学工業（株）製：ＫＳＧ−７１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＰ−５６２Ｐ
（注４）信越化学工業（株）製：ＫＰ−５７４処理
＜化粧料の調製＞
Ａ：成分１〜９及び１２を８０℃に加熱し、均一に混合した。
Ｂ：成分１０をＡに添加し、均一に分散した。
Ｃ：成分１１、１３を混合し、８０℃に加熱後、Ｂに加えて乳化し、金皿に流し込んで冷却し、固形状ホホ紅を得た。
以上のようにして得られた固形状油中多価アルコール乳化ホホ紅は、のび広がりが軽くて、べたつきや油っぽさもなかった。 Example 8: Polyhydric alcohol emulsified hoho red in solid oil

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-710
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KP-562P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment <Preparation of cosmetics>
A: Components 1 to 9 and 12 were heated to 80 ° C. and mixed uniformly.
B: Component 10 was added to A and dispersed uniformly.
C: Ingredients 11 and 13 were mixed, heated to 80 ° C., emulsified in addition to B, poured into a metal pan and cooled to obtain a solid cheek red.
The polyhydric alcohol emulsified cheek red in solid oil obtained as described above was lightly spread and neither sticky nor oily.

（注１）千葉製粉（株）製：レオパールＴＴ
（注２）信越化学工業（株）製：ＫＳＧ−４３
（注３）信越化学工業（株）製：ＫＦ−６１０５
＜化粧料の調製＞
Ａ：成分１、２の一部及び３〜６を加熱し、均一に混合した。
Ｂ：成分２の残部に、９を混合しローラーにて分散し、Ａに添加して均一に混合した。
Ｃ：成分７、８を混合し加温、Ｂに加えて乳化した。
Ｄ：成分１０、１１をＣに添加し、クリーム状口紅を得た。
以上のようにして得られたクリーム状口紅は、のびが軽くて唇に伸ばしやすく、べたつきや油っぽさもなく、持ちもよかった。 Example 9: Creamy lipstick

(Note 1) Chiba Flour Milling Co., Ltd .: Leopard TT
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-43
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6105
<Preparation of cosmetics>
A: A part of components 1 and 2 and 3 to 6 were heated and mixed uniformly.
B: 9 was mixed with the remainder of component 2 and dispersed with a roller, and added to A and mixed uniformly.
C: Components 7 and 8 were mixed, warmed, added to B and emulsified.
D: Components 10 and 11 were added to C to obtain creamy lipstick.
The cream-like lipstick obtained as described above was light and easy to extend to the lips, had no stickiness or oiliness, and had a good hold.

（注１）信越化学工業（株）製：ＴＭＦ−１．５
（注２）信越化学工業（株）製：ＫＦ−６０１７
（注３）信越化学工業（株）製：ＫＦ−７３１２Ｔ
（注４）信越化学工業（株）製：ＫＦ−９９０１処理
＜化粧料の調製＞
Ａ：成分１〜５を混合し、成分６を加えて均一に混合、分散した。
Ｂ：成分７〜１０を混合した。
Ｃ：ＢをＡに添加して乳化し、アイライナーを得た。
以上のようにして得られたアイライナーは、のびが軽くてアイラインに描きやすく、さっぱりとた使用感である上、化粧持ちも非常に良いことが確認された。 Example 10: Eyeliner

(Note 1) Shin-Etsu Chemical Co., Ltd .: TMF-1.5
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6017
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-7312T
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9901 treatment <Preparation of cosmetics>
A: Components 1 to 5 were mixed, and component 6 was added and mixed and dispersed uniformly.
B: Components 7 to 10 were mixed.
C: B was added to A and emulsified to obtain an eyeliner.
It was confirmed that the eyeliner obtained as described above is light and easy to draw on the eyeline, has a refreshing feeling of use, and has a very long makeup.

（注１）千葉製粉（株）製：レオパールＴＴ
（注２）信越化学工業（株）製：ＫＰ−５６２Ｐ
（注３）信越化学工業（株）製：ＫＦ−９９０９処理
（注４）信越化学工業（株）製：ＫＦ−６０２８
＜化粧料の調製＞
Ａ：成分７、１３を成分９に添加し、加温、均一に混合した。
Ｂ：成分１〜６及び８をＡに添加し、均一に混合した。
Ｃ：成分１０、１１、及び１２をＢに添加し、ローラーで均一にすし、マスカラを得た。
以上のようにして得られたマスカラは、のびが軽くて睫に描きやすく、べたつきがない使用感である上、化粧持ちも非常に良いことが確認された。 Example 11: Mascara

(Note 1) Chiba Flour Milling Co., Ltd .: Leopard TT
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-562P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6028
<Preparation of cosmetics>
A: Ingredients 7 and 13 were added to ingredient 9, warmed and mixed uniformly.
B: Components 1 to 6 and 8 were added to A and mixed uniformly.
C: Ingredients 10, 11, and 12 were added to B, and the mixture was uniformly squeezed with a roller to obtain a mascara.
It was confirmed that the mascara obtained as described above is light and easy to draw on the eyelids, has no stickiness, and has a very long makeup.

（注１）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注２）信越化学工業（株）製：ＫＰ−５７４処理
＜化粧料の調製＞
Ａ：成分１〜４を混合し、成分５を加えて均一に混合、分散した。
Ｂ：成分６〜９を混合した。
Ｃ：ＢをＡに添加して乳化し、クリームアイシャドウを得た。
以上のようにして得られたクリームアイシャドウは、のび広がりが軽くて油っぽさや粉っぽさがなく、持ちもよかった。 Example 12: Cream eye shadow

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment <Preparation of cosmetics>
A: Components 1 to 4 were mixed, and component 5 was added and mixed and dispersed uniformly.
B: Components 6 to 9 were mixed.
C: B was added to A and emulsified to obtain a cream eye shadow.
The cream eye shadow obtained as described above had a light spread and was neither oily nor powdery, and was good to hold.

（注１）信越化学工業（株）製：ＫＰ−５４５
（注２）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注３）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注４）信越化学工業（株）製：ＫＰ−５７４処理
＜化粧料の調製＞
Ａ：成分１〜６を混合し、成分７〜９を加えて均一に混合、分散した。
Ｂ：成分１０〜１１を混合した。
Ｃ：ＢをＡに添加して乳化し、クリームアイシャドウを得た。
以上のようにして得られたクリームアイシャドウは、のび広がりが軽くて油っぽさや粉っぽさがなく、みずみずしく、持ちも良かった。 Example 13: Cream eye shadow

(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-545
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment <Preparation of cosmetics>
A: Components 1 to 6 were mixed, and components 7 to 9 were added and mixed and dispersed uniformly.
B: Components 10 to 11 were mixed.
C: B was added to A and emulsified to obtain a cream eye shadow.
The cream eye shadow obtained as described above had a light spread, no oiliness or powderiness, freshness and good holding.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注４）信越化学工業（株）製：ＳＰＤ−Ｔ５
（注５）信越化学工業（株）製：ＳＰＤ−Ｚ５
＜化粧料の調製＞
Ａ：成分１〜６を均一に混合した。
Ｂ：成分９〜１２を混合した。
Ｃ：ＢをＡに添加して乳化し、成分７及び８を加えてサンカット乳液を得た。
以上のようにして得られたサンカット乳液は、のび広がりが軽く、べたつきや油っぽさがなく、耐汗性が良好であった。 Example 14: Suncut emulsion

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: SPD-T5
(Note 5) Shin-Etsu Chemical Co., Ltd .: SPD-Z5
<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 9 to 12 were mixed.
C: B was added to A and emulsified, and components 7 and 8 were added to obtain a suncut emulsion.
The suncut emulsion obtained as described above had a light spread, no stickiness or oiliness, and good sweat resistance.

（注１）信越化学工業（株）製：ＫＳＧ−２４０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０３８
（注４）信越化学工業（株）製：ＫＰ−５７５
（注５）信越化学工業（株）製：ＡＥＳ−３０８３処理
＜化粧料の調製＞
Ａ：成分５の一部に成分７を加えて均一にし、成分８を添加してビーズミルにて分散した。
Ｂ：成分１〜４及び成分５の残部、６を均一に混合した。
Ｃ：成分９〜１１、及び成分１３を混合して、均一にした。
Ｄ：ＣをＢに添加して乳化し、Ａ及び成分１２を加えてサンカットクリームを得た。
以上のようにして得られたサンカットクリームは、べたつきがなくのび広がりが軽く、油っぽさがなくてさっぱりとした使用感を与えると共に、持ちも良好であった。 Example 15: Sun cut cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-240
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-575
(Note 5) Shin-Etsu Chemical Co., Ltd .: AES-3083 treatment <Preparation of cosmetics>
A: Component 7 was added to a part of component 5 to make it uniform, and component 8 was added and dispersed by a bead mill.
B: Components 1-4 and the remainder of component 5, 6 were mixed uniformly.
C: Components 9 to 11 and Component 13 were mixed and made uniform.
D: C was added to B to emulsify, and A and component 12 were added to obtain a sun cut cream.
The suncut cream obtained as described above had no stickiness, light spread, light oiliness, a refreshing feeling of use and good holding.

（注１）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注２）信越化学工業（株）製：ＫＳＰ−１０５
（注３）信越化学工業（株）製：ＳＰＤ−Ｚ６
＜化粧料の調製＞
Ａ：成分１〜７を均一に混合した。
Ｂ：成分９〜１３を混合した。
Ｃ：ＢをＡに添加して乳化し、成分８を加えてシェイキングタイプのサンカットローションを得た。
以上のようにして得られたサンカットローションは、のび広がりが軽く、べたつきや油っぽさがなく、持ちも非常に優れていた。 Example 16: Sun cut lotion (shaking type)

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSP-105
(Note 3) Shin-Etsu Chemical Co., Ltd .: SPD-Z6
<Preparation of cosmetics>
A: Components 1 to 7 were mixed uniformly.
B: Components 9 to 13 were mixed.
C: B was added to A to emulsify, and component 8 was added to obtain a shaking type sun cut lotion.
The sun cut lotion obtained as described above had a light spread, no stickiness or oiliness, and was very excellent in holding.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注４）信越化学工業（株）製：ＳＰＤ−Ｔ６
（注５）信越化学工業（株）製：ＳＰＤ−Ｚ６
＜化粧料の調製＞
Ａ：成分１〜８を均一に混合した。
Ｂ：成分９〜１２を混合した。
Ｃ：ＢをＡに添加して乳化し、サンカットクリームを得た。
以上のようにして得られたサンカットクリームは、べたつきがなく、のび広がりが軽く、油っぽさがなくて、持ちもよかった。 Example 17: Sun cut cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: SPD-T6
(Note 5) Shin-Etsu Chemical Co., Ltd .: SPD-Z6
<Preparation of cosmetics>
A: Components 1 to 8 were mixed uniformly.
B: Components 9 to 12 were mixed.
C: B was added to A and emulsified to obtain a sun cut cream.
The sun cut cream obtained as described above had no stickiness, light spread, no oiliness, and good holding.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０１７
＜化粧料の調製＞
Ａ：成分１〜６を均一に混合した。
Ｂ：成分７〜１３、及び成分１５を混合した。
Ｃ：ＢをＡに添加して乳化し、成分１４を添加してサンタン乳液を得た。
以上のようにして得られたサンタン乳液は、べたつきがなく、のび広がりが軽く、油っぽさがなくてさっぱりとした使用感を与えた。 Example 18: Suntan emulsion

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6017
<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 7 to 13 and Component 15 were mixed.
C: B was added to A to emulsify, and component 14 was added to obtain a suntan emulsion.
The suntan emulsion obtained as described above had no stickiness, light spreading, light oiliness and a refreshing feeling.

（注１）信越化学工業（株）製：ＫＳＧ−３２０
（注２）信越化学工業（株）製：ＫＳＧ−４２
（注３）信越化学工業（株）製：ＫＦ−６０３８
（注４）信越化学工業（株）製：ＫＰ−５６１Ｐ
＜化粧料の調製＞
Ａ：成分１〜８及び１７、１８を加熱混合した。
Ｂ：成分１２及び２０の一部を加熱攪拌後、成分９〜１１を添加し分散処理した。
Ｃ：成分１３〜１６及び２０の残部を均一溶解し、Ｂと混合した。
Ｄ：攪拌下、ＡにＣを徐添して乳化し、冷却して成分１９を添加しサンタンクリームを得た。
以上のようにして得られたサンタンクリームは、キメが細かく、のび広がりが軽くてべたつきや油っぽさがなく、さっぱりとした使用感を与えると共に、持ちも良かった。 Example 19: Suntan cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-320
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-42
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-561P
<Preparation of cosmetics>
A: Components 1 to 8, 17 and 18 were heated and mixed.
B: After heating and stirring a part of components 12 and 20, components 9 to 11 were added and dispersed.
C: The remaining components 13 to 16 and 20 were uniformly dissolved and mixed with B.
D: While stirring, C was gradually added to A to emulsify, and after cooling, component 19 was added to obtain a suntan cream.
The suntan cream obtained as described above was fine in texture, lightly spread, free of stickiness and oiliness, gave a refreshing feeling of use and was also good.

（注１）信越化学工業（株）製：ＫＦ−６０３８
（注２）信越化学工業（株）製：ＦＬ−５
（注３）信越化学工業（株）製：ＫＭＰ−５９０
（注４）パーフルオロアルキルエチルリン酸ジエタノールアミン塩にて５％被覆したもの
（注５）信越化学工業（株）製：ＫＦ−９９０９処理
（注６）信越化学工業（株）製：ＫＦ−６１０５
＜化粧料の調製＞
Ａ：成分１の一部、成分１１、１２及び２０の一部を混合し、均一に分散した。
Ｂ：成分８〜１０を均一に混合した。
Ｃ：成分１の残部、２〜７を混合し、Ｂを加えて均一に分散混合した。
Ｄ：成分１３〜１８及び２０の残部を混合し、均一にした。
Ｅ：攪拌下、ＣにＤを徐添して乳化し、Ａ及び成分１９を添加しＷ／Ｏファンデーションを得た。
以上のようにして得られたＷ／Ｏファンデーションは、べたつきがなくサラッとしており、のび広がりが軽くて油っぽさがなく、化粧持ちも良く、また、２次付着もなかった。 Example 20: Liquid W / O foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 2) Shin-Etsu Chemical Co., Ltd .: FL-5
(Note 3) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 4) 5% coated with perfluoroalkylethyl phosphate diethanolamine salt (Note 5) Shin-Etsu Chemical Co., Ltd .: KF-9909 treated (Note 6) Shin-Etsu Chemical Co., Ltd .: KF-6105
<Preparation of cosmetics>
A: A part of component 1 and a part of components 11, 12, and 20 were mixed and dispersed uniformly.
B: Components 8 to 10 were mixed uniformly.
C: The remainder of component 1 and 2 to 7 were mixed, and B was added and dispersed and mixed uniformly.
D: The remaining components 13 to 18 and 20 were mixed and made uniform.
E: While stirring, D was gradually added to C to emulsify, and A and component 19 were added to obtain a W / O foundation.
The W / O foundation obtained as described above had no stickiness and was smooth, lightly spreading, light and oily, having good makeup, and having no secondary adhesion.

（注１）信越化学工業（株）製：ＫＦ−５４
（注２）信越化学工業（株）製：ＫＦ−７３１２J
（注３）信越化学工業（株）製：ＫＦ−６０３８
＜化粧料の調製＞
Ａ：成分１〜７、成分１２〜１４を均一に混合した。
Ｂ：成分８〜１１、及び１６を均一に混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、成分１５を添加し、ヘアクリームを得た。
以上のようにして得られたヘアクリームは、油っぽさがなく、のび広がりが軽く、耐水性、撥水性、耐汗性があり持ちも良かった。 Example 21: Hair cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-7312J
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
<Preparation of cosmetics>
A: Components 1 to 7 and Components 12 to 14 were mixed uniformly.
B: Components 8 to 11 and 16 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 15 was added to obtain a hair cream.
The hair cream obtained as described above was not oily, spread lightly, had water resistance, water repellency and sweat resistance, and had good durability.

（注１）信越化学工業（株）製：ＫＦ−９０２８
（注２）信越化学工業（株）製：ＫＦ−７３１２J
（注３）信越化学工業（株）製：ＫＦ−６０１１
（注４）ノベオン社製：ペミュレンＴＲ−１
＜化粧料の調製＞
Ａ：成分１〜１０、及び成分１４を加熱溶解した。
Ｂ：成分１１〜１３、及び１６を混合し、加熱した。
Ｃ：攪拌下、ＢにＡを徐添して乳化し、冷却後、成分１５を添加してヘアクリームを得た。
以上のようにして得られたヘアクリームは、のび広がりが軽く、毛髪に光沢と滑らかさを与え、毛髪に対した優れたセット効果を有したと共に、耐水性、耐汗性があり持ちも良かった。 Example 22: Hair cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-9028
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-7312J
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 4) Noveon: Pemulen TR-1
<Preparation of cosmetics>
A: Components 1 to 10 and Component 14 were dissolved by heating.
B: Components 11 to 13 and 16 were mixed and heated.
C: While stirring, A was gradually added to B to emulsify, and after cooling, component 15 was added to obtain a hair cream.
The hair cream obtained as described above has a light spread, gives gloss and smoothness to the hair, has an excellent setting effect on the hair, and is water-resistant and sweat-resistant and has good durability. It was.

（注１）信越化学工業（株）製：ＫＦ−７００２
（注２）信越化学工業（株）製：ＫＦ−６０１１Ｐ
（注３）信越化学工業（株）製：ＫＭＰ−５９０
（注４）セピック製：セピゲル３０５
＜化粧料の調製＞
Ａ：成分１〜９、成分１４を均一に混合した。
Ｂ：成分１０〜１３、及び１６を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して乳化し、成分１５を添加し、保湿Ｏ／Ｗクリームを得た。
以上のようにして得られた保湿Ｏ／Ｗクリームは、のび広がりが軽く、さっぱりとした使用感を与え、保湿効果が持続した。 Example 23: Moisturizing O / W cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-7002
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6011P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KMP-590
(Note 4) Sepic: Sepigel 305
<Preparation of cosmetics>
A: Components 1 to 9 and Component 14 were mixed uniformly.
B: Components 10 to 13 and 16 were mixed uniformly.
C: While stirring, A was gradually added to B to emulsify, and component 15 was added to obtain a moisturizing O / W cream.
The moisturizing O / W cream obtained as described above spreads lightly, gives a refreshing feeling of use, and maintains the moisturizing effect.

（注１）信越化学工業（株）製：ＫＳＧ−１５
（注２）信越化学工業（株）製：ＫＳＧ−１６
（注３）信越化学工業（株）製：ＫＦ−６１０４
（注４）信越化学工業（株）製：ＫＦ−６１００
（注５）セピック社製：シムルゲル６００
（注６）クラリアント社製：アリストフレックスＡＶＣ
＜化粧料の調製＞
Ａ：成分１〜４を均一に混合した。
Ｂ：成分５〜１１を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して混合し、Ｏ／Ｗエモリエントクリームを得た。
以上のようにして得られたＯ／Ｗエモリエントクリームは、油っぽさがなくサラサラッとしており、のび広がりが軽く、肌を守る効果が持続した。 Example 24: O / W emollient cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6104
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6100
(Note 5) manufactured by Sepic Corporation: Shimurugel 600
(Note 6) Made by Clariant: Aristoflex AVC
<Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 11 were mixed uniformly.
C: While stirring, A was gradually added to B and mixed to obtain an O / W emollient cream.
The O / W emollient cream obtained as described above has no oiliness and is smooth, spreads lightly, and maintains the effect of protecting the skin.

（注１）信越化学工業（株）製：ＫＦ−８１０８
（注２）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注３）信越化学工業（株）製：ＫＳＰ−１０２
＜化粧料の調製＞
Ａ：成分１〜８、成分１２を均一に混合した。
Ｂ：成分９〜１１、及び１４を均一に混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、成分１３を添加し、ハンドクリームを得た。
以上のようにして得られたハンドクリームは、油っぽさがなくサラサラッとしており、のび広がりが軽く、肌を守る効果が持続した。 Example 25: Hand cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-8108
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-102
<Preparation of cosmetics>
A: Components 1 to 8 and Component 12 were mixed uniformly.
B: Components 9 to 11 and 14 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 13 was added to obtain a hand cream.
The hand cream obtained as described above is not oily and smooth, spreads lightly and maintains the effect of protecting the skin.

（注１）信越化学工業（株）製：ＫＰ−５６１Ｐ
＜化粧料の調製＞
Ａ：成分１〜９を加熱混合した。
Ｂ：成分１０〜１２、及び１４を混合、加熱した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、冷却後、成分１３を添加し、Ｏ／Ｗクリームを得た。
以上のようにして得られたＯ／Ｗクリームは、べたつきや油っぽさがなくサラッとしており、のび広がりが軽く、さっぱりとした使用感を有していることが確認された。 Example 26: O / W cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-561P
<Preparation of cosmetics>
A: Components 1 to 9 were heated and mixed.
B: Components 10 to 12 and 14 were mixed and heated.
C: While stirring, B was gradually added to A to emulsify, and after cooling, Component 13 was added to obtain an O / W cream.
It was confirmed that the O / W cream obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and has a refreshing feeling.

（注１）信越化学工業（株）製：ＫＳＧ−１６
（注２）ノベオン社製：ペミュレンＴＲ−１
＜化粧料の調製＞
Ａ：成分１〜７を加熱し、均一に混合した。
Ｂ：成分８〜１２、及び１４を混合、加熱した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、冷却後、成分１３を添加し、Ｏ／Ｗクリームを得た。
以上のようにして得られたＯ／Ｗクリームは、べたつきや油っぽさがなくサラッとしており、のび広がりが軽く、肌のみずみずしさを持続することが確認された。 Example 27: O / W cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 2) Noveon: Pemulen TR-1
<Preparation of cosmetics>
A: Components 1 to 7 were heated and mixed uniformly.
B: Components 8 to 12 and 14 were mixed and heated.
C: While stirring, B was gradually added to A to emulsify, and after cooling, Component 13 was added to obtain an O / W cream.
It was confirmed that the O / W cream obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and maintains a freshness of the skin.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＳＧ−１６１０
（注４）信越化学工業（株）製：ＫＦ−６０１７
＜化粧料の調製＞
Ａ：成分１〜７を均一に混合した。
Ｂ：成分８〜１３を均一に混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、透明Ｗ／Ｏ美容液を得た。
以上のようにして得られた透明Ｗ／Ｏ美容液は、べたつきや油っぽさがなく、肌のみずみずしさを持続することが確認された。 Example 28: Transparent W / O serum

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSG-1610
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6017
<Preparation of cosmetics>
A: Components 1 to 7 were mixed uniformly.
B: Components 8 to 13 were mixed uniformly.
C: While stirring, B was gradually added to A and emulsified to obtain a transparent W / O serum.
It was confirmed that the transparent W / O serum obtained as described above has no stickiness or oiliness and maintains the freshness of the skin.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
＜化粧料の調製＞
Ａ：成分１〜３を均一に混合した。
Ｂ：成分４〜７を均一に混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、制汗剤を得た。
以上のようにして得られた制汗剤は、のび広がりが軽く、皮膚を白くせず、制汗効果の持ちが良いことが確認された。 Example 29: Antiperspirant

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
<Preparation of cosmetics>
A: Components 1 to 3 were mixed uniformly.
B: Components 4 to 7 were mixed uniformly.
C: Under stirring, B was gradually added to A and emulsified to obtain an antiperspirant.
It was confirmed that the antiperspirant obtained as described above spreads lightly, does not whiten the skin, and has a good antiperspirant effect.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＳＰ−１０１
（注４）信越化学工業（株）製：ＫＦ−９０２８
＜化粧料の調製＞
Ａ：成分１〜６を均一に混合し、リンクルコンシーラーを得た。
以上のようにして得られたリンクルコンシーラーは、べたつきや油っぽさがなくサラッとしており、のび広がりが軽く、シーリング効果を持続できることが確認された。 Example 30: Wrinkle concealer

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-101
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9028
<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly to obtain a wrinkle concealer.
It was confirmed that the wrinkle concealer obtained as described above has no stickiness or oiliness and is smooth, has a light spread, and can maintain the sealing effect.

（注１）信越化学工業（株）製：ＫＦ−５６
（注２）信越化学工業（株）製：ＫＦ−６０２８
＜化粧料の調製＞
Ａ：成分１〜８を加熱混合した。
Ｂ：成分９〜１１及び１３を加熱混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、冷却後、成分１２を添加し、クレンジングクリームを得た。
以上のようにして得られたクレンジングクリームは、のび広がりが軽く、しっとりとしてみずみずしく、さっぱりとした使用感を与えることが確認された。 Example 31: Cleansing cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-56
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028
<Preparation of cosmetics>
A: Components 1 to 8 were heated and mixed.
B: Components 9 to 11 and 13 were heated and mixed.
C: While stirring, B was gradually added to A to emulsify, and after cooling, component 12 was added to obtain a cleansing cream.
It was confirmed that the cleansing cream obtained as described above has a light spread, moist and fresh, and gives a refreshing feeling.

（注１）信越化学工業（株）製：ＫＦ−６０１１
（注２）信越化学工業（株）製：ＫＦ−６０１３
＜化粧料の調製＞
Ａ：成分１〜４を均一に混合した。
Ｂ：成分５〜１０を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して乳化し、透明クレンジングローションを得た。
以上のようにして得られた透明クレンジングローションは、のび広がりが軽く、しっとりとしてみずみずしい使用感を与え、クレンジング効果も高いことが確認された。 Example 32: Transparent cleansing lotion

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6013
<Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 10 were mixed uniformly.
C: While stirring, A was gradually added to B and emulsified to obtain a transparent cleansing lotion.
It was confirmed that the transparent cleansing lotion obtained as described above is lightly spread, gives a moist and fresh feeling, and has a high cleansing effect.

（注１）信越化学工業（株）製：ＫＦ−６１００
（注２）信越化学工業（株）製：ＫＳＰ−１００
（注３）クラリアント社製：アリストフレックスＡＶＣ
＜化粧料の調製＞
Ａ：成分１〜６を均一に混合した。
Ｂ：成分７〜１０を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して混合し、ボディーローションを得た。
以上のようにして得られたボディーローションは、べたつきや油っぽさがなくサラサラッとしており、のび広がりが軽く、肌のみずみずしさを持続することが確認された。 Example 33: Body lotion

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6100
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSP-100
(Note 3) Made by Clariant: Aristoflex AVC
<Preparation of cosmetics>
A: Components 1 to 6 were mixed uniformly.
B: Components 7 to 10 were mixed uniformly.
C: While stirring, A was gradually added to B and mixed to obtain a body lotion.
It was confirmed that the body lotion obtained as described above had no stickiness or oiliness and was smooth, had a light spread, and kept the skin fresh.

（注１）信越化学工業（株）製：ＫＦ−６０１１Ｐ
（注２）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注３）信越化学工業（株）製：ＫＳＰ−３００
＜化粧料の調製＞
Ａ：成分１〜６を加温し、均一に混合した。
Ｂ：成分７〜１０を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して混合し、トリートメントゲルを得た。
以上のようにして得られたトリートメントゲルは、油っぽさがなくサラサラッとしており、のび広がりが軽く、トリートメント効果にも優れていることが確認された。 Example 34: Treatment gel

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSP-300
<Preparation of cosmetics>
A: Components 1 to 6 were heated and mixed uniformly.
B: Components 7 to 10 were mixed uniformly.
C: While stirring, A was gradually added to B and mixed to obtain a treatment gel.
It was confirmed that the treatment gel obtained as described above had no oiliness and was smooth, lightly spread, and excellent in treatment effect.

（注１）信越化学工業（株）製：ＫＦ−６０１１Ｐ
＜化粧料の調製＞
Ａ：成分１〜３を均一に混合した。
Ｂ：成分５〜１０を均一に混合した後、成分４を添加し、均一にした。
Ｃ：攪拌下、ＢにＡを徐添して混合し、ペースト状の洗い流しタイプパック化粧料を得た。
以上のようにして得られた洗い流しタイプパック化粧料は、のび広がりが軽く、洗浄効果に優れ、洗い流した後は、肌がツルツルした感触になることが確認された。 Example 35: Wash-off type pack

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011P
<Preparation of cosmetics>
A: Components 1 to 3 were mixed uniformly.
B: After ingredients 5 to 10 were uniformly mixed, ingredient 4 was added and made uniform.
C: Under stirring, A was gradually added to B and mixed to obtain a paste-type washout type pack cosmetic.
It was confirmed that the rinse-off type pack cosmetic obtained as described above has a light spread and an excellent cleaning effect, and after washing, the skin feels smooth.

（注１）信越化学工業（株）製：ＫＦ−６１００
＜化粧料の調製＞
Ａ：成分１〜５を均一に混合した。
Ｂ：成分６〜１１を均一に混合した。
Ｃ：攪拌下、ＢにＡを徐添して混合し、脱臭剤を得た。
以上のようにして得られた脱臭剤は、のび広がりが軽くてべたつきや油っぽさがなく、脱臭効果が持続することが確認された。 Example 36: Deodorant

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6100
<Preparation of cosmetics>
A: Components 1 to 5 were mixed uniformly.
B: Components 6 to 11 were mixed uniformly.
C: While stirring, A was gradually added to B and mixed to obtain a deodorizer.
It was confirmed that the deodorizer obtained as described above has a light spread and no stickiness or oiliness, and the deodorizing effect is sustained.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注３）信越化学工業（株）製：ＫＳＧ−４３
＜化粧料の調製＞
Ａ：成分１〜４を均一に混合した。
Ｂ：成分５〜９を加熱混合し、均一にした。
Ｃ：成分１０〜１２を加熱混合した。
Ｄ：攪拌下、ＢにＣを徐添して乳化し、冷却した。
Ｅ：攪拌下、ＡにＤを徐添して乳化し、Ｏ／Ｗ／Ｏ型乳液を得た。
以上のようにして得られたＯ／Ｗ／Ｏ型乳液は、油っぽさがなく、のび広がりが軽く、清涼感を持続することが確認された。 Example 37: O / W / O type emulsion

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSG-43
<Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 9 were heated and mixed to make uniform.
C: Components 10 to 12 were heated and mixed.
D: While stirring, C was gradually added to B, emulsified, and cooled.
E: While stirring, D was gradually added to A and emulsified to obtain an O / W / O type emulsion.
It was confirmed that the O / W / O type emulsion obtained as described above was not oily, lightly spread, and maintained a refreshing feeling.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注３）信越化学工業（株）製：ＫＦ−９９０９処理
＜化粧料の調製＞
Ａ：成分１〜４を均一に混合した。
Ｂ：成分５〜１１を加熱混合し、均一にした。
Ｃ：成分１２〜１４を加熱混合した。
Ｄ：攪拌下、ＢにＣを徐添して乳化し、冷却した。
Ｅ：攪拌下、ＡにＤを徐添して乳化し、Ｏ／Ｗ／Ｏ型リキッドファンデーションを得た。
以上のようにして得られたＯ／Ｗ／Ｏ型リキッドファンデーションは、べたつきや油っぽさがなく、のび広がりが軽く、化粧持ちもよく、２次付着も無いことが確認された。 Example 38: O / W / O type liquid foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment <Preparation of cosmetics>
A: Components 1 to 4 were mixed uniformly.
B: Components 5 to 11 were heated and mixed to be uniform.
C: Components 12 to 14 were heated and mixed.
D: While stirring, C was gradually added to B, emulsified, and cooled.
E: While stirring, D was gradually added to A and emulsified to obtain an O / W / O type liquid foundation.
It was confirmed that the O / W / O type liquid foundation obtained as described above has no stickiness or oiliness, light spread, light makeup, and no secondary adhesion.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＳＧ−１６
（注４）信越化学工業（株）製：ＫＦ−６０２８Ｐ
＜化粧料の調製＞
Ａ：成分１〜８を均一に混合し、５０℃に暖める。
Ｂ：成分９〜１１、及び成分１３を混合し、均一にした。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、成分１２を加えてＷ／Ｏクリームを得た。
以上のようにして得られたＷ／Ｏクリームは、べたつきや油っぽさがなく、のび広がりが軽く、肌のしっとり感を持続できることが確認された。 Example 39: W / O cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KSG-16
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-6028P
<Preparation of cosmetics>
A: Components 1 to 8 are mixed uniformly and warmed to 50 ° C.
B: Components 9 to 11 and Component 13 were mixed and made uniform.
C: Under stirring, B was gradually added to A to emulsify, and component 12 was added to obtain a W / O cream.
It was confirmed that the W / O cream obtained as described above has no stickiness or oiliness, spreads lightly, and can maintain the moist feeling of the skin.

（注１）信越化学工業（株）製：ＫＰ−５４５
（注２）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注３）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注４）信越化学工業（株）製：ＫＰ−５７４処理
＜化粧料の調製＞
Ａ：成分１〜７を加温混合した。
Ｂ：成分８〜１０、及び成分１２を均一に混ぜ、Ａと混合した。
Ｃ：成分１１、１３を混合した。
Ｄ：攪拌下、ＢにＣを徐添して乳化し、Ｗ／Ｏホホ紅を得た。
以上のようにして得られたＷ／Ｏホホ紅は、べたつきや油っぽさがなく、のび広がりが軽く、密着性に優れ、化粧持ちもよかった。 Example 40: W / O cheek red

(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-545
(Note 2) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KP-574 treatment <Preparation of cosmetics>
A: Components 1 to 7 were heated and mixed.
B: Components 8 to 10 and Component 12 were mixed uniformly and mixed with A.
C: Components 11 and 13 were mixed.
D: While stirring, C was gradually added to B and emulsified to obtain W / O red.
The W / O hoho red so obtained was free from stickiness and oiliness, spreads lightly, has excellent adhesion, and has good makeup.

（注１）信越化学工業（株）製：ＫＳＧ−２１０
（注２）信越化学工業（株）製：ＫＳＧ−１５
（注３）信越化学工業（株）製：ＫＦ−６０２８Ｐ
（注４）信越化学工業（株）製：ＫＦ−９９０９処理
（注５）信越化学工業（株）製：ＫＰ−５７５
＜化粧料の調製＞
Ａ：成分４の一部と成分９を混合し、成分８を均一に分散した。
Ｂ：成分１〜３、４の残部、及び成分５〜７を均一に混合した。
Ｃ：成分１０〜１４、及び成分１６を均一に混合した。
Ｄ：攪拌下、ＢにＣを徐添して乳化し、Ａ及び成分１５を添加してＷ／Ｏリキッドファンデーションを得た。
以上のようにして得られたＷ／Ｏリキッドファンデーションは、べたつきや油っぽさがなく、のび広がりが軽く、化粧持ちもよく、２次付着も無かった。 Example 41: W / O liquid foundation

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-210
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-15
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6028P
(Note 4) Shin-Etsu Chemical Co., Ltd .: KF-9909 treatment (Note 5) Shin-Etsu Chemical Co., Ltd .: KP-575
<Preparation of cosmetics>
A: A part of component 4 and component 9 were mixed, and component 8 was uniformly dispersed.
B: The remaining components 1 to 4 and components 5 to 7 were mixed uniformly.
C: Components 10 to 14 and Component 16 were mixed uniformly.
D: While stirring, C was gradually added to B and emulsified, and A and component 15 were added to obtain a W / O liquid foundation.
The W / O liquid foundation obtained as described above had no stickiness or oiliness, light spread, light makeup, and no secondary adhesion.

（注１）信越化学工業（株）製：ＫＳＧ−３４０
（注２）信越化学工業（株）製：ＫＳＧ−４４
（注３）信越化学工業（株）製：ＫＦ−６０３８
（注４）信越化学工業（株）製：ＫＳＰ−１００
＜化粧料の調製＞
Ａ：成分１〜８を均一に混合した。
Ｂ：成分９〜１３、及び成分１５を均一に混合した。
Ｃ：攪拌下、ＡにＢを徐添して乳化し、成分１４を添加してＷ／Ｏクリームを得た。
以上のようにして得られたＷ／Ｏクリームは、べたつきや油っぽさがなく、肌のしっとり感を持続することが確認された。 Example 42: W / O type cream

(Note 1) Shin-Etsu Chemical Co., Ltd .: KSG-340
(Note 2) Shin-Etsu Chemical Co., Ltd .: KSG-44
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6038
(Note 4) Shin-Etsu Chemical Co., Ltd .: KSP-100
<Preparation of cosmetics>
A: Components 1 to 8 were mixed uniformly.
B: Components 9 to 13 and Component 15 were mixed uniformly.
C: While stirring, B was gradually added to A to emulsify, and component 14 was added to obtain a W / O cream.
It was confirmed that the W / O cream obtained as described above has no stickiness or oiliness and maintains a moist feeling on the skin.

（注１）信越化学工業（株）製：ＫＰ−５６１Ｐ
（注２）信越化学工業（株）製：ＫＦ−５４
（注３）信越化学工業（株）製：ＫＦ−６１０５
＜化粧料の調製＞
Ａ：成分１〜１２を加熱し、均一に混合した。
Ｂ：加熱下、成分１３及び１４をＡに加えて均一に混合し、気密性の高い所定の容器に充填して、リップスティックを得た。
以上のようにして得られたリップスティックは、べたつきや油っぽさがなく、にじみ等もなく、化粧持ちもよいことが確認された。 Example 43: Lipstick

(Note 1) Shin-Etsu Chemical Co., Ltd .: KP-561P
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6105
<Preparation of cosmetics>
A: Components 1 to 12 were heated and mixed uniformly.
B: Under heating, components 13 and 14 were added to A, mixed uniformly, and filled into a predetermined highly airtight container to obtain a lipstick.
It was confirmed that the lipstick obtained as described above has no stickiness or oiliness, no bleeding, and good makeup.

（注１）信越化学工業（株）製：ＫＦ−６０１１
（注２）信越化学工業（株）製：ＫＦ−６０１３
（注３）信越化学工業（株）製：ＫＦ−９０２８
＜化粧料の調製＞
Ａ：成分１〜３及び７〜１０を均一に混合しした。
Ｂ：成分４〜６を均一に混合しした。
Ｃ：攪拌下、ＡにＢを加え乳化し、キューティクルコートを得た。
以上のようにして得られたキューティクルコートは、のび広がりが軽く、毛髪のぱさつきを抑え、光沢と滑らかさを与えることが確認された。 Example 44: Cuticle coat

(Note 1) Shin-Etsu Chemical Co., Ltd .: KF-6011
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-6013
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-9028
<Preparation of cosmetics>
A: Components 1 to 3 and 7 to 10 were mixed uniformly.
B: Components 4 to 6 were mixed uniformly.
C: Under stirring, B was added to A and emulsified to obtain a cuticle coat.
It was confirmed that the cuticle coat obtained as described above spreads lightly, suppresses hairiness, and gives gloss and smoothness.

（注１）信越化学工業（株）製：ＭＫ−１５Ｈ
（注２）信越化学工業（株）製：ＫＦ−５４
（注３）信越化学工業（株）製：ＫＦ−６０１３
＜化粧料の調製＞
Ａ：成分１〜８を加熱溶解した。
Ｂ：成分１１〜１５を加熱溶解した。
Ｃ：攪拌下、ＡにＢを添加して乳化し、さらに、これに成分８及び９を加えてヘアトリートメントを得た。
以上のようにして得られたヘアトリートメントは、のび広がりが軽く、毛髪に光沢と滑らかさを与えることが確認された。 Example 45: Hair treatment

(Note 1) Shin-Etsu Chemical Co., Ltd .: MK-15H
(Note 2) Shin-Etsu Chemical Co., Ltd .: KF-54
(Note 3) Shin-Etsu Chemical Co., Ltd .: KF-6013
<Preparation of cosmetics>
A: Components 1 to 8 were dissolved by heating.
B: Components 11 to 15 were dissolved by heating.
C: Under stirring, B was added to A to emulsify, and components 8 and 9 were further added thereto to obtain a hair treatment.
It was confirmed that the hair treatment obtained as described above spreads lightly and gives the hair gloss and smoothness.

（注１）信越化学工業（株）製：ＴＭＦ−１．５
＜化粧料の調製＞
Ａ：成分７〜９を混合し、成分４〜６を添加して均一に混合した。
Ｂ：Ａに成分１〜３を添加して混合した。
Ｃ：Ｂに成分１０を添加混合して、ネイルエナメルを得た。
以上のようにして得られたネイルエナメルは、のび広がりが軽く、爪に光沢を与え、持ちも優れていることが確認された。 Example 46: Nail enamel

(Note 1) Shin-Etsu Chemical Co., Ltd .: TMF-1.5
<Preparation of cosmetics>
A: Components 7 to 9 were mixed, and components 4 to 6 were added and mixed uniformly.
B: Components 1 to 3 were added to A and mixed.
C: Component 10 was added to B and mixed to obtain a nail enamel.
It was confirmed that the nail enamel obtained as described above has a light spreading, gives gloss to the nails and is excellent in holding.

＜化粧料の調製＞
Ａ：成分５〜９を混合し、成分４を添加して均一に混合した。
Ｂ：Ａに成分１〜３を添加して混合して、ネイルエナメルオーバーコートを得た。
以上のようにして得られたエナメルオーバーコートは、のび広がりが軽く、エナメルの光沢を増し、持ちもよいことが確認された。 Example 47: Nail enamel overcoat

<Preparation of cosmetics>
A: Components 5 to 9 were mixed, and component 4 was added and mixed uniformly.
B: Components 1 to 3 were added to A and mixed to obtain a nail enamel overcoat.
It was confirmed that the enamel overcoat obtained as described above spreads lightly, increases the gloss of the enamel, and has good holding properties.

  The cosmetic of the present invention is excellent in the feeling of use at the time of application, elongation on the skin and hair. The applied makeup maintains its effect and has no secondary adhesion to clothes or the like.

Claims (8)

A cosmetic comprising a polymer having a repeating unit of the following formula (1), wherein a carbon-carbon double bond of the polymer main chain may be partially hydrogenated.

(In the formula, ^{R 1} is a methyl group, X is a group represented by the following formula (i), a is an integer of 1 to 3, b is an integer of 0 to 2)

^{(R 2} is a methyl group, d is an integer of 1-5.) The cosmetic according to claim 1, wherein the polymer further has a repeating unit represented by the following formula (2).

[Wherein R ^3, independently of one another, a hydrogen atom, a perfluorobutyl group,及 Beauty hydroxymethyl group or al chosen groups, b is an integer of 0-2. ) The cosmetic according to claim 1 or 2, wherein the polymer has a polystyrene-equivalent number average molecular weight (Mn) measured by GPC of 300 to 1,000,000 .   The cosmetic according to any one of claims 1 to 3, wherein 50 to 100% of the carbon-carbon double bonds of the polymer main chain are hydrogenated.   The cosmetic according to any one of claims 1 to 4, wherein the polymer is a powder cosmetic containing 0.1 to 10% by weight of the cosmetic weight. The cosmetic according to any one of claims 1 to 4, wherein the polymer is a liquid cosmetic contained in an amount of 0.1 to 7.5% by weight of the cosmetic. The linear, branched, or cyclic volatile silicone oil at 25 ° C. is further included in a weight ratio of 1: 2 to 100: 1 with respect to the polymer. Cosmetics described in 1. The silicone oil is at least one selected from the group consisting of octamethyltrisiloxane, decamethyltetrasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tristrimethylsiloxymethylsilane, and tetrakistrimethylsiloxysilane. Item 7. A cosmetic material according to Item 7.