JP2017193529A - Cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic comprising an impregnation body in which a liquid cosmetic, which has appropriate thixotropic properties capable of being stably held in an impregnation body and appropriate shear-thinning properties capable of being easily taken using fingers or an applicator and can obtain an effect of correcting irregularities and a smooth sense of use after applying to the skin, is impregnated.SOLUTION: There is provided a cosmetic in which a liquid cosmetic, which comprises (A) 1 to 8 mass% of a non-emulsifiable crosslinking type silicone, (B) 1 to 40 mass% of a spherical silicone resin powder and (C) an oil component, wherein the mass ratio (A)/(C) of the component (A) to the component (C) is 0.01 to 0.12 and the mass ratio (B)/(C) of the component (B) to the component (C) is 0.01 to 0.68, is impregnated in an impregnation body and the liquid cosmetic is taken out from the impregnation body using fingers or an applicator to apply to the skin.SELECTED DRAWING: None

Description

  The present invention relates to a cosmetic for impregnating an impregnated body with a liquid cosmetic containing a predetermined component, and applying the liquid cosmetic from the impregnated body to the skin.

  Conventionally, bottles and tubes are generally used as containers for storing liquid cosmetics. However, since bottles and tubes are difficult to carry when going out, and it is difficult to carry out cosmetic acts easily, in recent years, liquid cosmetics are impregnated in an impregnated body such as a sponge built in a compact container. In use, cosmetics in the form of containers that can be applied to the skin using a finger or an applicator have been developed.

  However, when the liquid cosmetic is impregnated into the impregnated body, it is necessary to increase the viscosity of the liquid cosmetic in order to stably maintain the liquid cosmetic without falling off the impregnated body. If it is increased, it is difficult to impregnate during production, and it becomes difficult to remove the liquid cosmetic from the impregnated body during use, so that it is difficult to apply a sufficient amount to the skin. In addition, a liquid cosmetic with a high viscosity cannot be uniformly applied to the skin, and the feeling of use is inferior, such as stickiness after application.

  For this reason, in the development of cosmetics in which liquid cosmetics are impregnated into an impregnated body, and the liquid cosmetics are applied to the skin by applying a finger or an applicator from the impregnated body, the rheological properties of the liquid cosmetic impregnated in the impregnated body are Makeup that corrects unevenness of skin after applying it to the skin, with appropriate thixotropy that can be stably held in the impregnated body and appropriate shearing that can be easily taken using fingers and applicators. It is important to design so as to obtain an effect and a good feeling of use.

Special table 2015-512933 gazette

  The present invention has an appropriate thixotropy that can be stably held in an impregnated body and an appropriate shearing that can be easily taken using a finger or an applicator. It is an object of the present invention to provide a new cosmetic provided with an impregnated body impregnated with a liquid cosmetic material capable of obtaining a cosmetic effect for correcting the above and a smooth use feeling.

  As a result of investigations by the present inventor to solve the above problems, liquid cosmetics for impregnating impregnated bodies include (A) non-emulsifiable cross-linked silicone, (B) spherical silicone resin powder, C) By blending a predetermined amount of oil, it has been found that it has both appropriate thixotropy and shearing, and can provide an unevenness correction effect on the skin after application and a smooth feeling of use. It came to do.

  That is, this invention contains (A) 1-8 mass% of non-emulsifiable bridge | crosslinking silicone, (B) 1-40 mass% of spherical silicone resin powder, and (C) oil component, and with respect to a component (C). The mass ratio (A) / (C) of the component (A) is 0.01 to 0.12, and the mass ratio (B) / (C) of the component (B) to the component (C) is 0.01 to 0.68. The liquid cosmetic is impregnated into an impregnated body, and the liquid cosmetic is removed from the impregnated body with a finger or an applicator and applied to the skin.

  Further, in the present invention, (A) the non-emulsifiable cross-linkable silicone is selected from the group consisting of a dimethicone cross polymer, a (dimethicone / vinyl dimethicone) cross polymer, and a (dimethicone / phenylvinyl dimethicone) cross polymer. It is a cosmetic characterized by being 2 or more types.

  Furthermore, this invention is cosmetics characterized by mass ratio (A) / (C) of the component (A) with respect to the said component (C) being 0.015-0.07.

  Furthermore, this invention is cosmetics characterized by mass ratio (B) / (C) of the component (B) with respect to the said component (C) being 0.1-0.5.

  Furthermore, the present invention is a cosmetic characterized in that the liquid cosmetic is an oily cosmetic or a water-in-oil emulsified cosmetic.

  Furthermore, the present invention is a cosmetic characterized in that the impregnated body is a fibrous body, a foamed body or a porous body.

  Furthermore, the present invention is a cosmetic characterized in that the impregnated body impregnated with the liquid cosmetic is incorporated in a compact container having airtightness.

  The liquid cosmetic for impregnating the impregnated body has appropriate thixotropy and shearing as its rheological properties, so it can be held stably without falling off the impregnated body, and fingers and applicators can be held A sufficient amount can be applied to the skin because it can be easily taken using.

  Moreover, after apply | coating liquid cosmetics to skin, the cosmetic effect which correct | amends the unevenness | corrugation of skin, and the smooth use feeling can be acquired.

  The cosmetic of the present invention contains (A) 1 to 8% by mass of a non-emulsifiable cross-linked silicone, (B) 1 to 40% by mass of spherical silicone resin powder, and (C) an oil component, and component (C). The mass ratio (A) / (C) of the component (A) to 0.01 to 0.12, and the mass ratio (B) / (C) of the component (B) to the component (C) is 0.01 to 0.00. 68 liquid cosmetics are impregnated into an impregnated body, and the liquid cosmetic is taken from the impregnated body with a finger or an applicator and applied to the skin.

  Here, the act of removing the liquid cosmetic from the impregnated body with a finger or an applicator includes the act of transferring the puff etc. onto the impregnated body and taking it out, or scooping it off.

  The (A) non-emulsifying cross-linked silicone used in the present invention is commercially available in the form of a liquid oil swelling product. In the present invention, a commercially available product can be used, and examples of the commercially available product include the following.

As a swelling product of INCI name dimethicone / vinyl dimethicone crosspolymer or poly-silicone-11, KSG-15 ((dimethicone / vinyl dimethicone) crosspolymer, a mixture of cyclopentasiloxane and about 5% cross-linked product), KSG -16 ((dimethicone / vinyl dimethicone) cross-polymer, mixture of dimethicone 6 mPa · s, about 25% crosslinked), KSG-18 ((dimethicone / vinyl dimethicone) cross-polymer, phenyl trimethicone mixture, about 15%) (Shin-Etsu Chemical Co., Ltd.), GRANSIL GCM (polysilicone-11 and octamethylcyclotetrasiloxane is a mixture of about 6% cross-linked product), GRANSIL GCM-5 (polysilicone-11 and decamethyl) Mixing cyclopentasiloxane The cross-linked product is about 6%), GRANSIL IDS (polysilicone-11 and isodecane is about 7% cross-linked product), GRANSIL DMG-6 (polysilicone-11 and dimethicone 6 mPa · s is about cross-linked product) 18%), GRANSIL DMG-20 (a mixture of poly-silicone-11 and dimethicone 20 mPa · s is about 25%), GRANSIL DMG-50 (a mixture of poly-silicone-11 and dimethicone 50 mPa · s is about 26%), GRANSIL PM (polysilicone-11 and phenyltrimethicone mixture is about 20% cross-linked), GRANSILIN (polysilicone-11 and isononyl isononanoyl is about 15% cross-linked) (above, GRANT Etc.).

  Further, as a swelling product of what is called INCI name vinyl dimethicone / lauryl dimethicone cross polymer, KSG-41 (a mixture of (vinyl dimethicone / lauryl dimethicone) cross polymer and liquid paraffin and about 30% cross-linked product), KSG-42 ((Vinyl dimethicone / lauryl dimethicone) cross polymer, light isoparaffin mixture, crosslinked product is about 25%), KSG-43 ((vinyl dimethicone / lauryl dimethicone) cross polymer, crosslinked product of glyceryl tri-2-ethylhexanoate About 30%), KSG-44 ((vinyl dimethicone / lauryl dimethicone) crosspolymer, a mixture of squalane and about 5% cross-linked product) (Shin-Etsu Chemical Co., Ltd.).

  In addition, as a swelling product of what is called an INCI name alkyl (C30-45) cetearyl dimethicone crosspolymer, VELVESIL 125 (a mixture of alkyl (C30-45) cetearyl dimethicone crosspolymer and cyclopentasiloxane is used as a cross-linked product. .5%), VELVESIL Plus (alkyl (C30-45) cetearyl dimethicone cloth polymer, cyclopentasiloxane, PEG / PPG-20 / 23 dimethicone 5 mPa · s, with a crosslinked product of about 20%), cetearyl dimethicone cloth As a swelling material of what is called a polymer, VELVESIL DM (cetearyl dimethicone cross polymer, a mixture of dimethicone 5 mPa · s and about 17% crosslinked product) (above, manufactured by Momentive Performance Materials Co., Ltd.) and the like can be mentioned.

  Furthermore, as a swelling product of what is referred to as INCI name dimethicone cross polymer, “silicone elastomer blend 9045” (a mixture of dimethicone cross polymer and decamethylcyclopentasiloxane is 12.5% cross-linked product (actual content)), “ "Silicone elastomer blend 9041" (16% cross-linked with a mixture of dimethicone cross polymer and dimethicone 5 mPa · s), "Silicone elastomer blend 9040" (cross-linked with a mixture of dimethicone cross polymer and decamethylcyclopentasiloxane) The product (actual content) is 12%) (above, manufactured by Toray Dow Corning Silicone Co., Ltd.).

  (A) The compounding quantity (actual part) of non-emulsifiable crosslinking silicone shall be 1-8 mass% with respect to liquid cosmetics. When the blending amount is less than 1% by mass, it is difficult to stably hold the liquid cosmetic in the impregnated body. On the other hand, if the blending amount exceeds 8% by mass, it may be difficult to remove the liquid cosmetic, or the feeling of use may be inferior, for example, the skin may become distorted when applied.

  (A) The composition of the non-emulsifiable cross-linking silicone increases the viscosity of the oil component as a dispersion medium, suppresses the sedimentation of the spherical silicone resin powder as a dispersoid, and compares with a thickener such as an organically modified clay mineral. In addition, when applying liquid cosmetics, it exhibits the effect of making the unevenness of the skin inconspicuous while giving a smooth and excellent feeling of use. As the non-emulsifying cross-linked silicone exhibiting such an effect, dimethicone cross polymer, (dimethicone / vinyl dimethicone) cross polymer, and (dimethicone / phenyl vinyl dimethicone) cross polymer are particularly preferable.

  (B) Examples of the spherical silicone resin powder include (dimethicone / vinyl dimethicone) crosspolymer (as a commercially available product, for example, “EP9215 cosmetic powder” (manufactured by Toray Industries, Inc.)), (dimethicone / vinyl phenyl dimethicone / silsesquioxane). Sun) cross polymer (commercially available products such as “KSP-300” and the like (manufactured by Shin-Etsu Chemical Co., Ltd.)), (vinyl dimethicone / methicone silsesquioxane) cross polymer (commercially available products such as “KSP-100”) , “KSP-101”, “KSP-102”, “KSP-105” and the like (all manufactured by Shin-Etsu Chemical Co., Ltd.)), spherical silicone resin fine particles [commercially available products such as “Tospearl 120”, “ Tospearl 145A "(all manufactured by Tanac Co., Ltd.)] and the like.

  The hardness of the spherical silicone resin powder is not particularly limited, but a type A durometer hardness of 40 (dimethicone / vinyl dimethicone) crosspolymer (for example, “EP9215 manufactured by Toray Industries, Inc.” defined in JIS K 6253 “Cosmetic powder”) is less likely to swell in oil, so increasing the blending amount has little effect on the viscosity of liquid cosmetics, and is preferable because it has a smooth feel when applied to the skin. .

  (B) 1-40 mass% is preferable with respect to liquid cosmetics, and, as for the compounding quantity of spherical silicone resin powder, 10-35 mass% is more preferable. If the blending amount is less than 1% by mass, the effect of correcting the dry feel and the unevenness of the skin cannot be obtained sufficiently, and even if blending over 40% by mass, the improvement of the effect corresponding to it Rather, problems such as difficulty in filling the impregnated body with the liquid cosmetic material occur.

  (C) The oil component is not particularly limited as long as it is an oily component that can be usually blended in cosmetics. For example, silicone oil, synthetic ester oil, hydrocarbon oil, higher fatty acid, higher alcohol, oil and fat, waxes, etc. Is mentioned.

  Examples of the silicone oil include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; cyclic polysiloxanes such as decamethylpolysiloxane, dodecamethylpolysiloxane, and tetramethyltetrahydrogenpolysiloxane; 3 Examples thereof include silicone resin and silicone rubber forming a three-dimensional network structure.

  Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, monoisostearic acid N-alkyl glycol, dicapric acid neopentyl glycol, malic acid Diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexyl trimethylolpropane, Trimethylolpropane phosphate, pentane erythritol tetra-2-ethylhexylate, glycerin triethyl-2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri- 2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic oil, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, adipic acid di- 2-heptylundecyl, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyl adipate Decyl, sebacic acid diisopropyl, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, etc. crotamiton (C13H17NO) are exemplified.

  Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalene, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.

  Higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) and the like are exemplified.

  As higher alcohols, linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol; monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, Examples thereof include branched chain alcohols such as cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, and octyldodecanol.

  As fats and oils, avocado oil, camellia oil, evening primrose oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, triisopalmitic acid Liquid fats such as glycerin; cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cow leg Examples thereof include solid fats and oils such as fat, mole, and hardened castor oil.

  The waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauryl hexyl, reduced lanolin, jojojo Examples include a wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like.

  (C) Mass ratio (A) / (C) of (A) non-emulsifiable cross-linked silicone to oil component is 0.01 to 0.12, and (C) Mass ratio of (B) spherical silicone resin powder to oil component ( B) / (C) is set to 0.01 to 0.68. As a result, it has both appropriate thixotropy that can be stably held in the impregnated body and appropriate shearing that can be easily taken using a finger or an applicator. It is possible to obtain a liquid cosmetic that provides a cosmetic effect to be corrected and a smooth feeling of use. If the mass ratio (A) / (C) is less than 0.01, the liquid cosmetic is difficult to be held in the impregnated body, and if the mass ratio (A) / (C) is greater than 0.12, it is difficult to fill the impregnated body. Moreover, when it is applied to the skin, it becomes easy to cause kinking. On the other hand, if the mass ratio (B) / (C) is less than 0.01, the feeling of smooth use is inferior, and the liquid cosmetic is difficult to be stably held in the impregnated body, and the mass ratio (B) / (C) is When it is larger than 0.68, it becomes difficult to fill the impregnated body, and when it is applied to the skin, there is a tendency to twist and it is difficult to apply uniformly. In order to utilize such characteristics of liquid cosmetics and enable more stable retention and impregnation and uniform application, the mass ratio (A) / (C) is 0.015. It is particularly preferable that the mass ratio (B) / (C) is 0.1 to 0.5 in order to obtain a smooth and excellent usability when applied to the skin. It is particularly preferred. If the mass ratio (A) / (C) and the mass ratio (B) / (C) are both within the predetermined range, the amount of the (C) oil component is not particularly limited. , More than 30% by mass can be blended.

  Examples of impregnated bodies for impregnating liquid cosmetics include nonwoven fabrics made of single or mixed materials such as resin, pulp, and cotton, fiber bodies processed with resin, foams such as sponge, porous bodies equipped with a continuous mechanism, etc. Is mentioned. As materials, NBR (acrylonitrile butadiene rubber), SBR (styrene butadiene rubber), NR (natural rubber), urethane, nylon, polyolefin, polyester, EVA (ethylene vinyl acetate), PVA (polyvinyl alcohol), silicon, elastomer, However, the material is not limited to these materials as long as the impregnated body can contain the contents.

  Examples of the applicator for taking the liquid cosmetic from the impregnated body and applying it to the skin include sponges, puffs, chips, and the like that are usually used when the liquid cosmetic is applied to the skin.

  Liquid cosmetics can be made into water-in-oil emulsified cosmetics by blending aqueous components as well as oily cosmetics in which powder components and the like are blended with liquid oil.

  Moreover, the emulsifier which can generally be mix | blended with the emulsification composition of a water-in-oil type can be mix | blended with an emulsifier. As such an emulsifier, a hydrophobic (HLB7 or less) emulsifier is preferably used. For example, sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan monooleate, sorbitan monoisostearate, sorbitan tristearate; glycerol Glycerol fatty acid esters such as monostearate, glycerol monooleate, glycerol isostearate, diglycerol diisostearate, decaglyceryl pentaisostearate; POE (5), POE (7.5), POE (10) hydrogenated castor oil Polyoxyethylene hydrogenated castor oil such as: dipolyhydroxystearate esters: polyglyceryl-2 dipolyhydroxystearate (manufactured by Cognis: PGPH), PEG30 dipolyhydroxystearate ( High molecular weight lipophilic activators such as Nikema Alaser P135); cetyl dimethicone copolyol [eg “ABIL EM90” (manufactured by Goldschmidt)], polyether-modified silicone [eg “KF6017” (Shin-Etsu Chemical Co., Ltd.) And the like); polyglycerin-modified silicones, polyglycerin-based silicones such as alkyl co-modified polyglycerin-modified silicones; and the like. In the present invention, one or two or more emulsifiers having an HLB of 7 or less can be used.

  Examples of the aqueous component include water and water-soluble components. Examples of the water-soluble component include lower alcohols, humectants, water-soluble polymers (natural, semi-synthetic, synthetic, inorganic) and the like.

  Examples of lower alcohols include ethanol, propanol, butanol, pentanol, hexanol and the like.

  As the humectant, glycerin, diethylene glycol, butylene glycol, polyethylene glycol, hexylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, elastin, amino acid, nucleic acid, cholesteryl-12 Examples include hydroxystearate, sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiyobara extract, Atlantic licorice extract, merirot extract, etc. The

  Natural water-soluble polymers include arabia gum, tragacanth gum, galactan, guar gum, locust bean gum, tamarind gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (gypsum extract), starch (rice, corn) , Potato, wheat), plant water-soluble polymers such as glycyrrhizic acid; microbial water-soluble polymers such as xanthan gum, dextran, succinoglycan, and bullulan; animal water-soluble polymers such as collagen, casein, albumin, and gelatin Etc. are exemplified.

  Semi-synthetic water-soluble polymers include starch-based water-soluble polymers such as carboxymethyl starch and methylhydroxypropyl starch; methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxy Examples thereof include cellulose water-soluble polymers such as methyl cellulose (CMC), crystalline cellulose, and cellulose powder; and alginic acid water-soluble polymers such as sodium alginate and propylene glycol alginate.

  Synthetic water-soluble polymers include vinyl water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol); polyethylene glycol 20,000, 4,000,000, and 600, Polyoxyethylene water-soluble polymers such as 000; copolymer water-soluble polymers such as polyoxyethylene polyoxypropylene copolymers; acrylic water-soluble polymers such as sodium polyacrylate, polyethyl acrylate, and polyacrylamide In addition, polyethyleneimine, cationic polymer and the like are exemplified.

  Examples of the inorganic water-soluble polymer include bentonite, silicate AlMg (beegum), laponite, hectorite, and silicic anhydride. As the powder component, either a hydrophobic powder or a hydrophilic powder can be used, but a hydrophobic powder is preferred. The hydrophobic powder includes not only a hydrophobic powder itself but also a hydrophobized powder obtained by hydrophobizing the powder surface even if the powder is a hydrophilic powder or the like.

  Specific examples of the hydrophobic powder include polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder. Examples thereof include organic powders such as ethylene powder and cellulose powder.

  Examples of the powder component of the hydrophobized powder include talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, safmica, biotite, lithia mica, permiculite, magnesium carbonate, calcium carbonate, Aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, Ceramic powders, metal soaps (zinc myristate, calcium palmitate, aluminum stearate, etc.), inorganic powders such as boron nitride; inorganic white pigments such as titanium dioxide and zinc oxide; inorganics such as iron oxide (Bengara) and iron titanate Red pigment Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Inorganic black pigments such as black iron oxide, carbon black, low-order titanium dioxide; Inorganic purple pigments such as mango violet and Baltic violet Pigments; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, titanium dioxide coated talc, colored titanium dioxide Examples thereof include pearl pigments such as coated mica, bismuth oxychloride and fish scale foil; metal powder pigments such as aluminum powder and copper powder. As a method for hydrophobizing these powder components, any method can be used as long as it can impart water repellency, and any method can be used. For example, a gas phase method, a liquid phase method, and an autoclave. A normal surface treatment method such as a method or a mechanochemical method can be used. Although it does not specifically limit as a hydrophobizing agent, Fatty acid dextrin processing powder, trimethylsiloxysilicic acid processing powder, fluorine-modified trimethylsiloxysilicic acid processing powder, methylphenylsiloxysilicic acid processing powder, fluorine-modified methylphenylsiloxysilicic acid processing powder Low viscosity to high viscosity oily polysiloxane treated powder such as dimethylpolysiloxane, diphenylpolysiloxane, methylphenylpolysiloxane, gum-like polysiloxane treated powder, methylhydrogenpolysiloxane treated powder, fluorine-modified methylhydrogenpolysiloxane treated powder , Methyltrichlorosilane, methyltrialkoxysilane, hexamethyldisilane, dimethyldichlorosilane, dimethyldialkoxysilane, trimethylchlorosilane, trimethylalkoxysilane, etc. Powders treated with silyl compounds or their fluorine-substituted compounds, ethyltrichlorosilane, ethyltrialkoxysilane, propyltrichlorosilane, propyltrialkoxysilane, hexyltrichlorosilane, hexyltrialkoxysilane, long-chain alkyltrichlorosilane, long-chain alkyltri Examples thereof include treatment powders with organically modified silanes such as ethoxysilane or fluorine-substituted products thereof, amino-modified polysiloxane-treated powders, fluorine-modified polysiloxane-treated powders, and fluorinated alkyl phosphoric acid-treated powders.

  Examples of other components other than those exemplified above include preservatives (ethyl paraben, butyl paraben, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.) ); Whitening agent (for example, Yukinosita extract, arbutin, etc.); various extracts (for example, agate, auren, sicon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokinein, loofah) , Lily, saffron, nematode, ginger, hypericum, onionis, garlic, red pepper, chimpi, red snapper, seaweed, etc.), activator (eg, royal jelly, photosensitizer, cholesterol derivative, etc.); blood circulation promoter (eg, nonenyl acid wallenylamide) , D Benzyltinate, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil , Cephalanthin, γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.); ultraviolet absorbers, etc. However, it is not limited to these examples.

  The cosmetic of the present invention can be made into a container form suitable for carrying by incorporating an impregnated body impregnated with a liquid cosmetic into a compact container having airtightness.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail along an Example, these Examples do not limit this invention. Numerical values in the table indicate mass% unless otherwise specified. Regarding the evaluation items “smooth feeling” and “smooth”, a use test was conducted by 10 panelists. “Fillability” is evaluated for ease of filling when liquid cosmetic is filled from above the impregnated body, and “impregnated state” is evaluated for resistance to dripping of liquid cosmetic from the impregnated body after filling. did. In addition, the nonwoven fabric made from a polyester fiber was used for the impregnation body. The evaluation criteria of the sample are described as A: very good (pass), B: good (pass), C: slightly good (pass), D: inferior (fail).

  Table 1 shows the evaluation results of “smooth feeling”, “skin”, “fillability”, and “impregnation state” for the liquid cosmetics of each formulation. 1-8 mass% of a component (A), 1-40 mass% of a component (B), and a component (C) are mix | blended, and mass ratio (A) / (C) is 0.01-0.12, and mass. Although Examples 1-14 which made ratio (B) / (C) 0.01-0.68 were able to obtain the pass result of AC determination in any evaluation, component (A) is used. Comparative Examples 1 to 8 in which 0 or 9% by mass and 0 or 50% by mass of component (B) were blended resulted in a D determination in any of the evaluation items.

  Examples 1, 2, and 6 to 10 are A or B determinations in “impregnated state” and “crack”, and in order to obtain a better evaluation in “impregnated state” and “crawl”, It was confirmed that the mass ratio (A) / (C) should be 0.15 to 0.07.

  In addition, Examples 2 to 5 and 9 to 13 are A or B determinations in “free feeling”, and in order to obtain a better evaluation in “free feeling”, the mass ratio (B) / (C ) Should be 0.1-0.5.

  Below, the formulation example of the liquid cosmetics used for the cosmetics of this invention is shown as an Example. All compounding amounts are expressed in mass% with respect to the liquid cosmetic.

  The liquid cosmetic used in the cosmetic of the present invention can be widely used not only as an oily cosmetic as exemplified in Table 1, but also as a water-in-oil emulsified cosmetic as exemplified in Table 2. The amount of water blended in the water-in-oil emulsified cosmetic is preferably 10 to 50% by mass.

Claims (7)

(A) 1-8% by mass of non-emulsifiable cross-linked silicone,
(B) spherical silicone resin powder 1-40% by mass;
(C) oil and
The mass ratio (A) / (C) of the component (A) to the component (C) is 0.01 to 0.12, and the mass ratio (B) / (C of the component (B) to the component (C) ) Is impregnated into the impregnated body with 0.01 to 0.68 liquid cosmetic, and the liquid cosmetic is taken from the impregnated body with a finger or an applicator and applied to the skin.   The (A) non-emulsifiable cross-linking silicone is one or more selected from the group consisting of a dimethicone crosspolymer, a (dimethicone / vinyl dimethicone) crosspolymer, and a (dimethicone / phenylvinyldimethicone) crosspolymer. The cosmetic product according to claim 1.   The cosmetic product according to any one of claims 1 to 3, wherein a mass ratio (A) / (C) of the component (A) to the component (C) is 0.015 to 0.07.   The cosmetic product according to claim 1 or 2, wherein a mass ratio (B) / (C) of the component (B) to the component (C) is 0.1 to 0.5.   The cosmetic according to any one of claims 1 to 4, wherein the liquid cosmetic is an oily cosmetic or a water-in-oil emulsified cosmetic.   The cosmetic product according to any one of claims 1 to 5, wherein the impregnated body is a fibrous body, a foamed body, or a porous body.   The cosmetic according to any one of claims 1 to 6, wherein the impregnated body impregnated with the liquid cosmetic is incorporated in a compact container having airtightness.