JP5660702B2 - Aerosol makeup cosmetics - Google Patents

Description

  The present invention relates to an aerosol makeup cosmetic. More specifically, the present invention relates to an aerosol-type water-in-oil emulsion makeup cosmetic that is excellent in redispersibility (difficult to gel), usability (no sliminess, elongation), and emulsion stability.

  In makeup cosmetics such as makeup bases and foundations, water-in-oil type emulsions are frequently used from the viewpoints of sweat resistance, water resistance, makeup feeling, and the like. In recent years, these makeup cosmetics, especially base makeup cosmetics such as makeup bases, tend to be preferred because they are not sticky and light. There is also an increasing demand for easy-to-use spray cosmetics.

  In general, aerosol-type spray cosmetics are used by filling a container with a stock solution and a propellant (for example, LPG, DME, etc.) and pressing a discharge nozzle to spray the contents. By appropriately selecting the propellant gas, it is possible to create a cooling feeling or the like by the heat of gas evaporation.

  However, in the prescription of a makeup-type cosmetic for water-in-oil emulsified spray type, since many oils and powders are blended, a sticky feeling or a feeling of use tends to increase. Also, in terms of dispersion stability, the emulsion (contents) tends to gel and remain in the container, so that the entire capacity cannot be used up, or due to powder agglomerates near the discharge nozzle in the container. There is concern about spray clogging. Therefore, development of a product that solves these problems and has excellent usability is desired.

  As conventional techniques close to the cosmetic of the present invention, for example, the cosmetics described in Patent Documents 1 and 2 below can be mentioned.

  That is, Patent Document 1 describes an oily cosmetic containing a long-chain alkyl group-containing polyglycerin-modified silicone compound. However, Patent Document 1 discloses that cosmetics are applied to aerosol dosage forms, problems inherent to aerosol dosage forms (for example, concerns about clogging due to powder agglomeration and gelation of contents), and good elongation. There is no description or suggestion about improvement of usability, emulsification stability, etc. Further, Document 1 does not describe or suggest a silicone compound having a structure having a branched silicone chain.

  Patent Document 2 describes an aerosol composition comprising a water-in-oil emulsion containing EO / PO graft polyether-modified silicone as an activator as a stock solution and the stock solution and a propellant. And about this aerosol composition, although effects, such as redispersibility and usability, are discussed, the effect is not fully satisfied with the said active agent. Reference 2 does not describe or suggest a silicone compound having a structure having a branched silicone chain.

International Publication No. 03/075864 Pamphlet JP 2000-80017 A

The present invention has been made in view of the above circumstances, and is an aerosol-type water-in-oil emulsion makeup makeup that is not gelled, has excellent redispersibility, has good elongation, is not slimy, and has excellent emulsion stability. The purpose is to provide a fee.

  In order to solve the above problems, the present invention is an aerosol makeup cosmetic comprising a container filled with a stock solution comprising a water-in-oil emulsion composition and a propellant, wherein the stock solution is used as an emulsifier. An aerosol makeup cosmetic containing a polyether-modified silicone having a branched silicone chain (however, the silicone may have a long-chain alkyl-modified moiety) is provided.

  The present invention also provides the above-mentioned aerosol makeup cosmetic, wherein the long-chain alkyl-modified moiety is a co-modified alkyl group having 8 to 20 carbon atoms.

  The present invention also provides the above-mentioned aerosol makeup cosmetic, wherein the polyether-modified silicone is contained in an amount of 0.1 to 4% by mass in the stock solution.

  The present invention also provides the above-mentioned aerosol makeup cosmetic, which contains the stock solution and the propellant in a ratio of 1:99 to 99: 1 (mass ratio).

  The aerosol-type water-in-oil emulsified makeup cosmetic of the present invention has the effects of not being gelled and excellent in redispersibility, having good elongation, no sliminess, and excellent emulsion stability.

  Hereinafter, the present invention will be described in detail.

[Undiluted solution]
The stock solution is a water-in-oil emulsion composition. In the present invention, a polyether-modified silicone having a branched silicone chain (however, the silicone may have a long-chain alkyl-modified moiety) is used as an emulsifier.

  A polyether-modified silicone having a branched silicone chain refers to a structure in which a polyether-modified siloxane having a straight chain structure is used as a main chain and the siloxane chain is branched, and a long-chain alkyl group is co-modified in the siloxane main chain. It may have a portion that has been changed. As the long-chain alkyl group, an alkyl group having 8 to 20 carbon atoms, particularly 10 to 18 carbon atoms is preferable. The polyether modification is preferably modification only with polyethylene oxide (= polyethylene glycol modification).

  Specific examples of the polyether-modified silicone having a branched silicone chain include PEG-9 polydimethylsiloxyethyl dimethicone [commercially available product such as “KF-6028” (manufactured by Shin-Etsu Chemical Co., Ltd.)], lauryl PEG-9. Examples include polydimethylsiloxyethyl dimethicone [commercially available products such as “KF-6038” (manufactured by Shin-Etsu Chemical Co., Ltd.)], cetyl PEG-9 polydimethylsiloxyethyl dimethicone, and the like. However, it is not limited to these examples. Among them, those having an alkyl co-modified moiety are preferable, and lauryl PEG-9 polydimethylsiloxyethyl dimethicone is particularly preferably used. 1 type (s) or 2 or more types can be used for this modified silicone.

  The blending amount of the modified silicone is not particularly limited as long as it is an amount sufficient to emulsify the water-in-oil emulsion composition which is a stock solution, but it is blended in an amount of 0.1 to 4% by mass in the stock solution. More preferably, it is 0.3-4 mass%, Most preferably, it is 0.4-3 mass%.

  In the water-in-oil type emulsion stock solution of the cosmetic of the present invention, an oily component, an aqueous component, a powder component and the like that can be usually blended in a makeup cosmetic are blended.

  The oily component that can be blended in the stock solution of the cosmetic of the present invention is not particularly limited as long as it is an oily component that can be blended in a normal cosmetic. For example, oils and fats, waxes, hydrocarbon oils, higher fatty acids, higher Examples include alcohol, synthetic ester oil, and silicone oil.

  As fats and oils, avocado oil, camellia oil, evening primrose oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, trioctanoic acid glycerin, triisopalmitic acid Liquid fats such as glycerin; cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cow leg Examples thereof include solid fats and oils such as fat, mole, and hardened castor oil.

  The waxes include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauryl hexyl, reduced lanolin, jojojo Examples include a wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like.

  Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalene, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.

  Higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA) and the like are exemplified.

  As higher alcohols, linear alcohols such as lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol; monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, Examples thereof include branched chain alcohols such as cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, and octyldodecanol.

Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearylate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, monoisostearic acid N-alkyl glycol, dicapric acid neopentyl glycol, malic acid Diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexyl trimethylolpropane, Trimethylolpropane phosphate, pentane erythritol tetra-2-ethylhexylate, glycerin triethyl-2-ethylhexylate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri- 2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic oil, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, adipic acid di- 2-heptylundecyl, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyl adipate Decyl, sebacic acid diisopropyl, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, crotamiton (C ₁₃ H ₁₇ NO) and the like are exemplified.

  Examples of the silicone oil include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane; cyclic polysiloxanes such as decamethylpolysiloxane, dodecamethylpolysiloxane, and tetramethyltetrahydrogenpolysiloxane; 3 Examples thereof include silicone resin and silicone rubber forming a three-dimensional network structure.

  These oily components (oil phase) are preferably 10 to 70% by mass, more preferably 10 to 50% by mass in the stock solution of the cosmetic of the present invention.

  Examples of the aqueous component that can be blended in the stock solution of the cosmetic of the present invention include water and water-soluble components. Examples of the water-soluble component include lower alcohols, humectants, water-soluble polymers (natural, semi-synthetic, synthetic, inorganic) and the like.

  Examples of lower alcohols include ethanol, propanol, butanol, pentanol, hexanol and the like.

  As the humectant, glycerin, diethylene glycol, butylene glycol, polyethylene glycol, hexylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, elastin, amino acid, nucleic acid, cholesteryl-12 Examples include hydroxystearate, sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiyobara extract, Atlantic licorice extract, merirot extract, etc. The

  Natural water-soluble polymers include arabia gum, tragacanth gum, galactan, guar gum, locust bean gum, tamarind gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (gypsum extract), starch (rice, corn) , Potato, wheat), plant water-soluble polymers such as glycyrrhizic acid; microbial water-soluble polymers such as xanthan gum, dextran, succinoglycan, and bullulan; animal water-soluble polymers such as collagen, casein, albumin, and gelatin Etc. are exemplified.

  Semi-synthetic water-soluble polymers include starch-based water-soluble polymers such as carboxymethyl starch and methylhydroxypropyl starch; methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxy Examples thereof include cellulose water-soluble polymers such as methyl cellulose (CMC), crystalline cellulose, and cellulose powder; and alginic acid water-soluble polymers such as sodium alginate and propylene glycol alginate.

  Synthetic water-soluble polymers include vinyl water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol); polyethylene glycol 20,000, 4,000,000, and 600, Polyoxyethylene water-soluble polymers such as 000; copolymer water-soluble polymers such as polyoxyethylene polyoxypropylene copolymers; acrylic water-soluble polymers such as sodium polyacrylate, polyethyl acrylate, and polyacrylamide In addition, polyethyleneimine, cationic polymer and the like are exemplified.

  Examples of the inorganic water-soluble polymer include bentonite, silicate AlMg (beegum), laponite, hectorite, and silicic anhydride.

  These aqueous components (aqueous phase) are preferably 20 to 89% by mass, more preferably 40 to 89% by mass, in the stock solution of the cosmetic of the present invention.

  In addition, it is preferable that the mixing ratio of the water phase and the oil phase in the cosmetic composition of the present invention is approximately 2 to 8 in terms of the water phase / oil phase (mass ratio) from the viewpoint of increasing the effect of the present invention in a balanced manner. More preferably, it is 2-6.

  As a powder component that can be blended in the stock solution of the cosmetic of the present invention, either a hydrophobic powder or a hydrophilic powder can be used, but a hydrophobic powder is preferred. The hydrophobic powder includes not only a hydrophobic powder itself but also a hydrophobized powder obtained by hydrophobizing the powder surface even if the powder is a hydrophilic powder or the like.

  Specific examples of the hydrophobic powder include polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder. Examples thereof include organic powders such as ethylene powder and cellulose powder, and silicone powders such as trimethylsilsesquioxane powder.

  Examples of the powder component of the hydrophobized powder include talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, safmica, biotite, lithia mica, permiculite, magnesium carbonate, calcium carbonate, Aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, Ceramic powders, metal soaps (zinc myristate, calcium palmitate, aluminum stearate, etc.), inorganic powders such as boron nitride; inorganic white pigments such as titanium dioxide and zinc oxide; inorganics such as iron oxide (Bengara) and iron titanate Red pigment Inorganic brown pigments such as γ-iron oxide; Inorganic yellow pigments such as yellow iron oxide and ocher; Inorganic black pigments such as black iron oxide, carbon black, low-order titanium dioxide; Inorganic purple pigments such as mango violet and Baltic violet Pigments; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; inorganic blue pigments such as ultramarine and bitumen; titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, titanium dioxide coated talc, colored titanium dioxide Examples thereof include pearl pigments such as coated mica, bismuth oxychloride and fish scale foil; metal powder pigments such as aluminum powder and copper powder. As a method for hydrophobizing these powder components, any method can be used as long as it can impart water repellency, and any method can be used. For example, a gas phase method, a liquid phase method, and an autoclave. A normal surface treatment method such as a method or a mechanochemical method can be used. Although it does not specifically limit as a hydrophobizing agent, Fatty acid dextrin processing powder, trimethylsiloxysilicic acid processing powder, fluorine-modified trimethylsiloxysilicic acid processing powder, methylphenylsiloxysilicic acid processing powder, fluorine-modified methylphenylsiloxysilicic acid processing powder Low viscosity to high viscosity oily polysiloxane treated powder such as dimethylpolysiloxane, diphenylpolysiloxane, methylphenylpolysiloxane, gum-like polysiloxane treated powder, methylhydrogenpolysiloxane treated powder, fluorine-modified methylhydrogenpolysiloxane treated powder , Methyltrichlorosilane, methyltrialkoxysilane, hexamethyldisilane, dimethyldichlorosilane, dimethyldialkoxysilane, trimethylchlorosilane, trimethylalkoxysilane, etc. Treatment powder with organic silyl compounds or their fluorine-substituted products, ethyltrichlorosilane, ethyltrialkoxysilane, propyltrichlorosilane, propyltrialkoxysilane, hexyltrichlorosilane, hexyltrialkoxysilane, long-chain alkyltrichlorosilane, long-chain alkyltri Examples thereof include treatment powders with organically modified silanes such as ethoxysilane or fluorine-substituted products thereof, amino-modified polysiloxane-treated powders, fluorine-modified polysiloxane-treated powders, and fluorinated alkyl phosphoric acid-treated powders.

  Hydrophobic powder has strong water repellency, and even when actually applied to an emulsion, it is resistant to water and sweat, and is most resistant to makeup, so it has excellent durability. Also, the emulsified particles are dense and have the longest stability.

  The blending amount of the powder component is not generally unambiguous for the use of the cosmetic of the present invention (for foundation, for makeup, etc.), but is preferably 1 to 20% by mass in the stock solution of the cosmetic of the present invention. More preferably, it is 1-10 mass%. If the amount is too small, the concealability (covering power) is lowered, which is unsuitable as a cosmetic for makeup. On the other hand, if the amount is too large, the powderyness tends to be remarkable and the stability tends to deteriorate. It is. In makeup cosmetics, powder components are blended in this way, but in the present invention, the contents in the container are difficult to gel, have excellent redispersibility, and do not cause nozzle clogging. .

  Examples of other components other than those exemplified above include preservatives (ethyl paraben, butyl paraben, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.) ); Whitening agent (for example, Yukinosita extract, arbutin, etc.); various extracts (for example, agate, auren, sicon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokinein, loofah) , Lily, saffron, nematode, ginger, hypericum, onionis, garlic, red pepper, chimpi, red snapper, seaweed, etc.), activator (eg, royal jelly, photosensitizer, cholesterol derivative, etc.); blood circulation promoter (eg, nonenyl acid wallenylamide) , D Benzyltinate, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil , Cephalanthin, γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.); ultraviolet absorbers, etc. However, it is not limited to these examples.

[Propellant]
The propellant is not particularly limited as long as it can be used for aerosol cosmetics and the like. In the present invention, for example, dichlorodifluoromethane, difluoromonochloroethane, monochlorodifluoromethane, dichlorotetrafluoroethane, tetrafluoroethane. Dimethyl ether (DME), propane, isobutane, n-butane, liquefied petroleum gas (LPG; propane, isobutane, n-butane as a main component) or a mixture thereof. 1 type (s) or 2 or more types can be used for a propellant. Of these, liquefied petroleum gas (LPG), dimethyl ether (DME) and the like are preferably used.

[Filling aerosol containers]
The cosmetic of the present invention is an aerosol makeup cosmetic in the form of a spray. The aerosol makeup cosmetic of the present invention is manufactured by, for example, a method in which the stock solution is stored in a known aerosol pressure vessel, air purged and clinched, and then filled with a propellant. Can do.

  The mixing ratio of the stock solution and the propellant is preferably 1:99 to 99: 1 (mass ratio), more preferably 10:90 to 90:10. If the mixing ratio is out of the above range, uniform application (spraying) becomes impossible, which is not preferable.

  The viscosity of the stock solution is not particularly limited as long as it can be sprayed from an aerosol container, but is preferably 100 to 500,000 mPa · s (30 ° C., B-type viscometer), more preferably 1,000 to 200,000 mPa · s. If the viscosity is too high, spraying may be difficult and gelation may occur. On the other hand, if the viscosity is too low, dripping may occur when sprayed on the skin.

  The cosmetics of the present invention are suitably used as base cosmetics (base makeup cosmetics), liquid foundations, cream foundations, suncare products, and the like.

  Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited thereto. Unless otherwise specified, all the amounts are mass%.

  First, the evaluation method used in the present invention will be described.

[Redispersibility (difficulty of gelation)]
After the stock solution and the propellant (LPG) were filled in a pressure-resistant glass bottle at a ratio of 1: 1 (mass ratio), this was rotated at 1000 rpm for 30 minutes using a centrifuge. Then, the state of the composition at the time of stirring 10 times in the horizontal direction was confirmed.
A: A powder agglomerate or gel composition did not remain and was in a uniform state B: A powder agglomerate or gel composition remained slightly, but there was no practical problem C: Powder agglomerate Almost all gel composition remained

[Emulsification stability]
Each sample of each example and comparative example was allowed to stand at room temperature and 50 ° C. for 1 month, and the state of the composition thereafter was confirmed.
(Evaluation)
A: Both room temperature (25 ° C.) and 50 ° C. were stable (no decrease in viscosity)
B: Although stable at room temperature (25 ° C.), a slight decrease in viscosity was observed at 50 ° C., but there was no practical problem. C: Water was removed at both room temperature (25 ° C.) and 50 ° C.

[No sliminess]
A female panel (10 persons) evaluated each sample of each example and comparative example based on the following evaluation criteria for the lack of sliminess during application.
(Evaluation)
◎: 8 or more responded that they felt slimy ○: 6-7 responded that they felt slimy △: 3-5 responded that they felt slimy ×: 2 or fewer respondents Answer that she felt the lack of sliminess

[Elongation]
A female panel (10 persons) evaluated each sample of each example and comparative example based on the following evaluation criteria for the elongation at the time of application.
(Evaluation)
◎: 8 or more responded that they felt good growth ○: 6-7 responded that they felt good △: 3-5 responded that they felt good × ×: 2 or less Answer that they felt good growth

(Examples 1-4, Comparative Examples 1-3)
A stock solution (water-in-oil emulsified composition) having the composition shown in Table 1 below is produced by a conventional method, and a pressure-resistant glass bottle is filled with these stock cake and propellant (LPG) at a ratio of 1: 1 (mass ratio). Was used as a sample and evaluated for redispersibility (resistance to gelation), emulsification stability, lack of sliminess, and good elongation according to the above evaluation method. The results are shown in Table 1.

  In Table 1, the following compounds were used as the components shown below. The same applies to the following prescription examples.

Polyoxyethylene / methylpolysiloxane copolymer ^{(* 1)} : “KF-6017” (manufactured by Shin-Etsu Chemical Co., Ltd.)
PEG-9 polydimethylsiloxyethyl dimethicone ^{(* 2)} : “KF-6028” (manufactured by Shin-Etsu Chemical Co., Ltd.)
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone ^{(* 3)} : “KF-6038” (manufactured by Shin-Etsu Chemical Co., Ltd.)
Poly (oxyethylene / oxypropylene) / butylene / methylpolysiloxane copolymer ^{(* 4)} : “FZ-2233” (manufactured by Toray Dow Corning)
Silicone resin fine particle powder ^{(* 5)} : "Tospearl 145A" (Momentive Performance Materials Japan GK)

  As is clear from the results in Table 1, in Examples 1 to 4 using the polyether-modified silicone having a branched silicone chain of the present invention, redispersibility (hardness of gelation), emulsion stability, and sliminess It was confirmed that the effects of goodness and elongation were achieved in a well-balanced manner. On the other hand, Comparative Examples 1 to 3 using silicone having no branched silicone chain could not have these effects.

Below, the formulation example of the stock solution in this invention is shown.
(Prescription Example 1)
(Mixed component) (mass%)
Decamethylcyclopentapolysiloxane 19
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone ^{(* 3)} 1
Vitamin E acetate 0.02
Lauroylglutamate di (phytosteryl / octyldodecyl) ethyl cetyl hexanoate (“Erudu PS-203”; manufactured by Ajinomoto Co., Inc.) 0.1
Ethylhexyl ethylhexanoate 2
Silicone resin fine particle powder ^{(* 5)} 5
Titanium dioxide 0.01
Tin oxide 0.01
Hydrous silica 0.01
Ion exchange water Residual EDTA-3Na 0.2
Polyethylene glycol (N = 400) 4
1,3-butylene glycol 4
Sodium hyaluronate 0.01
PEG / PPG-14 / 7 dimethyl ether 0.01
Methylparaben 0.15
Synthetic alcohol (95 degrees) 10

(Prescription example 2)
(Mixed component) (mass%)
Decamethylcyclopentapolysiloxane 15
Dodecamethylcyclohexapolysiloxane 3
Dimethicone 2
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone ^{(* 3)} 1
Cetyl ethylhexanoate 0.1
Silicone resin fine particle powder ^{(* 5)} 8
Methyl methacrylate cross polymer 2
Ion exchange water Residual EDTA-3Na 0.2
Polyethylene glycol (N = 400) 4
Dipropylene glycol 4
Sodium hyaluronate 0.01
PEG / PPG-14 / 7 dimethyl ether 0.01
Phenoxyethanol 0.15
Synthetic alcohol (95 degrees) 10

(Prescription Example 3)
(Mixed component) (mass%)
Decamethylcyclopentapolysiloxane 20
Lauryl PEG-9 polydimethylsiloxyethyl dimethicone ^{(* 3)} 1
Cetyl ethylhexanoate 0.1
Silicone resin fine particle powder ^{(* 5)} 4
Methyl methacrylate cross polymer 1
Ion exchange water Residual EDTA-3Na 0.2
Polyethylene glycol (N = 400) 4
Dipropylene glycol 4
Sodium hyaluronate 0.01
PEG / PPG-14 / 7 dimethyl ether 0.01
Phenoxyethanol 0.15
Synthetic alcohol (95 degrees) 10

  The aerosol-type water-in-oil emulsion makeup cosmetic of the present invention is not gelled and excellent in redispersibility, has good elongation, is not slimy, and is excellent in emulsion stability.

Claims (4)

  An aerosol makeup cosmetic comprising a stock solution comprising a water-in-oil emulsion composition and a propellant filled in a container, wherein the stock solution is a polyether-modified silicone having a branched silicone chain as an emulsifier , The silicone may have a long-chain alkyl-modified moiety).   The aerosol makeup cosmetic according to claim 1, wherein the long-chain alkyl-modified moiety is a co-modified alkyl group having 8 to 20 carbon atoms.   The aerosol makeup cosmetic according to claim 1 or 2, wherein the polyether-modified silicone is contained in the stock solution in an amount of 0.1 to 4% by mass.   The aerosol makeup cosmetic composition according to any one of claims 1 to 3, comprising a stock solution and a propellant in a ratio of 1:99 to 99: 1 (mass ratio).