WO2023058469A1 - Cosmetic composition - Google Patents

Abstract

This cosmetic composition contains (A) at least 46 mass% of a first oily component consisting of a phenyl-modified silicone, (B) a second oily component containing a liquid hydrocarbon, (C) 15 mass% or less of a third oily component for adjusting the compatibility between component (A) and component (B), (D) a fourth oily component consisting of wax, and (E) a colorant. Component (A) and component (B) have compatibility such that the two components are immiscible when mixed at a mass ratio of 1:1 at 25°C. Component (B) contains at least 40 mass% of the liquid hydrocarbon with respect to the mass of component (B). Component (E) is at least partially treated with at least one selected from the group consisting of metal soaps and organometallic alkoxides.

Description

cosmetic composition Related application

The present invention is based on the priority claim of Japanese Patent Application: Japanese Patent Application No. 2021-165877 (filed on October 8, 2021), and the entire description of the application is incorporated herein by reference. shall be

The present disclosure relates to cosmetic compositions. For example, the present disclosure relates to lip cosmetic compositions.

When makeup comes into contact with dishes or clothes, the color of the makeup is reflected on the contact object, which is called secondary adhesion. Secondary adhesion not only stains the contacting object with the color of the makeup, but also causes the makeup to come off. In particular, lipstick is prone to secondary adhesion because lips often come into contact with dishes. Therefore, cosmetics having a so-called secondary adhesion-less effect have been developed in which color transfer due to secondary adhesion is suppressed (see, for example, Patent Documents 1 to 3).

For example, the solid cosmetic for lips described in Patent Document 1 contains (a) 35 to 50% by mass of hydrogenated polyisobutene, and (b) one or more kinds of methyl that separates when mixed with (a) at 25°C. 20 to 60% by mass of phenyl silicone, (c) 1 to 20% by mass of neopentyl glycol dicaprate as a compatibility modifier for adjusting the compatibility of components (a) and (b), and (d) wax 3 to 12% by mass. The solid cosmetic for lips can further contain (e) a coloring material, and the (e) component is dispersed in the (a) component.

Japanese Patent No. 6242958 Japanese Patent No. 5280490 Japanese Patent No. 5926896

The following analysis is given in light of this disclosure.

In the lip cosmetics having a secondary adhesion-less effect as described in Patent Documents 1 to 3, each component is uniformly mixed in the product before use. When the cosmetic is applied to the lips, the liquid hydrocarbon oil/ester oil-based component and the silicone oil-based component separate on the lips due to the shearing force and/or pressure during application and rubbing of the lips. Due to the separation, the liquid hydrocarbon oil/ester oil component adheres to the skin (lips). On the other hand, the silicone oil-based component coats the liquid hydrocarbon oil/ester oil-based component that adheres to the skin. The coloring material is hardly present in the silicone oil-based component, and is present in the liquid hydrocarbon oil/ester oil-based component. That is, the silicone oil-based component is in a colorless and transparent state. For this reason, even if the lips with lipstick touch the tableware, the colorless and transparent silicone oil-based component adheres to the tableware, and the liquid hydrocarbon oil and ester oil-based component containing the colorant is suppressed from adhering to the tableware. It is possible to suppress the color transfer.

In such cosmetics, increasing the blending amount of the silicone oil-based component in the cosmetic can be considered as a means of enhancing the effect of preventing secondary adhesion. However, when the ratio of the silicone oil-based component increases, the ratio of the liquid hydrocarbon oil/ester oil-based component relatively decreases. Since the colorant is dispersed in the liquid hydrocarbon oil/ester oil component, the dispersibility of the colorant in the cosmetic is lowered. When the dispersibility of the coloring material is lowered, the vividness of the color developed when the cosmetic is applied to the skin is lowered. Therefore, in the cosmetics as described above, there is a trade-off relationship between the effect of preventing secondary adhesion and the vividness of color development.

Therefore, there is a demand for a cosmetic composition that maintains a high secondary adhesion-free effect while providing bright colors.

According to the first aspect of the present disclosure, (A) a first oily component of 46% by mass or more composed of a phenyl-modified silicone, (B) a second oily component containing a liquid hydrocarbon, and (C) a component Cosmetics containing 15% by mass or less of a third oily component for adjusting compatibility between (A) and component (B), (D) a fourth oily component consisting of wax, and (E) a coloring material A food composition is provided. Component (A) and component (B) have compatibility such that they separate when mixed at a mass ratio of 1:1 at 25°C. Component (B) contains 40% by weight or more of liquid hydrocarbons based on the weight of component (B). At least part of component (E) is treated with at least one selected from the group consisting of metal soaps and organometallic alkoxides.

The cosmetic composition of the present disclosure has a high secondary adhesion resistance effect. The cosmetic composition of the present disclosure can exhibit vivid color development on the skin.

The preferred form of each of the above viewpoints is described below.

According to a preferred embodiment of the first aspect, the metal soap is magnesium stearate, calcium stearate, zinc stearate, calcium laurate, zinc laurate, calcium ricinoleate, zinc ricinoleate, zinc octylate, aluminum myristate, and lauroyl asparagine. sodium stearoyl-L-glutamate, sodium lysine dilauroyl glutamate, sodium palmitoyl sarcosinate, and magnesium palmitoyl sarcosinate.

According to a preferred embodiment of the first aspect, the organometallic alkoxide includes isopropyl titanium triisostearate, tetraisopropyl titanate, tetrabutyl orthotitanate, butyl titanate dimer, tetraoctyl titanate, aluminum sec-butoxide, normal propyl zirconate, and It is at least one selected from the group consisting of normal butyl zirconate.

According to the preferred embodiment of the first aspect, the component (B) further contains a liquid ester oil.

According to the preferred embodiment of the first aspect, the liquid ester oil is glyceryl monoisostearate, isostearyl glyceryl ether, polyglyceryl polyisostearate, tetra(ethylhexanoic acid/benzoic acid) pentaerythrityl, tetra(behenic acid/benzoic acid at least one selected from the group consisting of acid/ethylhexanoic acid) pentaerythritol, dimer dilinoleate, and dipentaerythrityl hexahydroxystearate.

According to the preferred embodiment of the first aspect, the liquid hydrocarbon is at least one selected from the group consisting of hydrogenated polyisobutene, heavy liquid isoparaffin, liquid paraffin, polybutene, polyisobutene, and hydrogenated polydecene.

According to the preferred embodiment of the first aspect, component (A) is at least one selected from the group consisting of trimethylpentaphenyltrisiloxane, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, and phenyltrimethicone.

According to a preferred embodiment of the first aspect, component (C) comprises neopentyl glycol dicaprate, olefin oligomer, glyceryl tri-2-ethylhexanoate, sorbitan sesquiisostearate, propylene glycol monostearate, cetyl PEG/PPG. - 10/1 dimethicone, diglyceryl diisostearate, pentaerythrityl tetraethylhexanoate, squalane, liquid paraffin, trimethylolpropane triisostearate, trimethylolpropane triethylhexanoate, diisostearyl malate, and cetyl ethylhexanoate At least one selected from the group.

According to the preferred embodiment of the first aspect, the component (A) is 46% by mass to 80% by mass with respect to the mass of the cosmetic composition. Component (B) is 5% by mass to 50% by mass. Component (C) is 0.5% by mass to 15% by mass. Component (D) is 3% by mass to 20% by mass. Component (E) is 0.1% by mass to 10% by mass.

According to a preferred embodiment of the first aspect, component (E) is at least one selected from the group consisting of Red No. 102, Red No. 201, Red No. 202, Yellow No. 4, Yellow No. 5, and Blue No. 1. is one.

According to the preferred embodiment of the first aspect, the cosmetic composition is a uniform solid composition at 25°C under atmospheric pressure.

According to the preferred embodiment of the first aspect, when the cosmetic composition is applied to the skin, component (B) migrates to the skin side. Component (A) migrates outside component (B). Component (E) is present in greater amounts in component (B) than in component (A).

According to the preferred embodiment of the first aspect, the cosmetic composition is applied to the lips.

In the following explanation, POE is an abbreviation for polyoxyethylene, POP is an abbreviation for polyoxypropylene, and the number in parentheses after POE or POP represents the average number of added moles of POE or POP groups in the compound.

In the present disclosure, the term "substantial amount" refers to the amount in which the addition of the compound can produce an effect.

"Solid" in the present disclosure refers to a material that can maintain a solid state at 25°C under atmospheric pressure. In the present disclosure, the term “liquid” means fluid (liquid) at 25° C. under atmospheric pressure. A liquid state may also include a semi-solid state.

The cosmetic composition of the present disclosure will be explained. The cosmetic composition of the present disclosure includes (A) a first oily component, (B) a second oily component, (C) a third oily component, (D) a fourth oily component, ( E) an organic colorant. The cosmetic composition of the present disclosure is solid at 25° C. under atmospheric pressure. Before use, in the cosmetic composition of the present disclosure, each component is stably and uniformly dispersed in the solid at 25° C. under atmospheric pressure.

[(A) First oily component (phenyl-modified silicone)]
(A) The first oily component is a component that forms a coating layer when the cosmetic composition of the present disclosure is applied to the skin. (A) The first oily component consists of phenyl-modified silicone. A phenyl-modified silicone is, for example, a siloxane compound into which a phenyl group is introduced at least partially. Phenyl-modified silicone is liquid at 25° C. under atmospheric pressure. Examples of phenyl-modified silicones include trimethylpentaphenyltrisiloxane, diphenylsiloxyphenyltrimethicone, trimethylsiloxyphenyldimethicone, diphenyldimethicone, phenyltrimethicone, and bisphenylpropyldimethicone.

The component (A) may be of one type, or may be a mixture of two or more types.

The content of component (A) is preferably 46% by mass or more, more preferably 50% by mass or more, relative to the mass of the cosmetic composition. Component (A) can be 55% by mass or more, or 60% by mass or more, relative to the mass of the cosmetic composition. If the component (A) is less than 46% by mass, the secondary adhesion resistance effect will be reduced. Component (A) is preferably 80% by mass or less with respect to the mass of the cosmetic composition. Component (A) can be 75% by mass or less, 70% by mass or less, or 65% by mass or less with respect to the mass of the cosmetic composition. If the component (A) exceeds 80% by mass, other components are relatively decreased, resulting in a decrease in color developability.

[(B) Second oily component (hydrocarbon/ester oil)]

(B) The second oily component is a component (adherence layer) that adheres to the skin when the cosmetic composition of the present disclosure is applied to the skin. (B) The second oily component contains liquid hydrocarbons. Component (B) can further comprise a liquid ester oil. Liquid hydrocarbons are preferably at least 40% by mass relative to the mass of component (B). The liquid hydrocarbon can be 50% by weight or more, 60% by weight or more, 70% by weight or more, 80% by weight or more, 90% by weight or more, or 100% by weight based on the weight of component (B). If the amount of liquid hydrocarbon is less than 40% by mass with respect to the mass of component (B), it becomes difficult to have compatibility as described later. Component (B) is liquid at 25° C. under atmospheric pressure.

Components (A) and (B) have the following compatibility: (1) Components (A) and (B) are stirred and mixed at a mass ratio of 1:1 at 90°C. (2) Allow the mixture to stand in an environment at 25°C. (3) Components (A) and (B) separate such that a boundary exists between components (A) and (B) when the temperature of the mixture reaches 25°C.

Liquid hydrocarbons include linear or branched hydrocarbon oils such as hydrogenated polyisobutene, heavy liquid isoparaffin, liquid paraffin (synthetic wax, solid paraffin), polybutene, polyisobutene, and hydrogenated polydecene. Among these, component (B) preferably contains hydrogenated polyisobutene having an average molecular weight of 1,000 to 2,650 because it feels soft when applied to the lips and fits well on the lips. Component (B) does not include component (D) in this disclosure.

Liquid ester oils include glyceryl monoisostearate, isostearyl glyceryl ether, polyglyceryl polyisostearate, tetra(ethylhexanoic acid/benzoic acid) pentaerythrityl, tetra(behenic acid/benzoic acid/ethylhexanoic acid) pentaerythrityl, Examples include dimer dilinoleate, dipentaerythrityl hexahydroxystearate, and the like. Examples of polyglyceryl polyisostearate include polyglyceryl isostearate, polyglyceryl diisostearate, polyglyceryl triisostearate, and polyglyceryl tetraisostearate. Examples of dimer dilinoleic acid esters include dimer dilinoleic acid (phytosteryl/behenyl) and the like.

For example, when component (A) is trimethylpentaphenyltrisiloxane, component (B) can be hydrogenated polyisobutene.

The content of component (B) is preferably 5% by mass or more, more preferably 8% by mass or more, relative to the mass of the cosmetic composition. Component (B) can be 10% by mass or more, 15% by mass or more, or 20% by mass or more relative to the mass of the cosmetic composition. If the component (B) is less than 5% by mass, it will be difficult to achieve vivid color development. Component (B) is preferably 50% by mass or less, more preferably 45% by mass or less, relative to the mass of the cosmetic composition. Component (B) can be 45% by mass or less, 40% by mass or less, or 35% by mass or less relative to the mass of the cosmetic composition. If the component (B) exceeds 50% by mass, the component (A) is relatively decreased, resulting in a decrease in the secondary adhesion resistance effect.

[(C) Third Oil Component (Compatibilizer)]
(C) The third oily component acts as a compatibilizer that adjusts the compatibility between the component (A) and the component (B). Component (C) acts as a binder between component (A) and component (B) when manufacturing the cosmetic composition. Component (C) preferably has the following compatibility-adjusting action: (1) When component (A), component (B) and component (C) are mixed at a mass ratio of 3:4:1 at 90°C, , component (C) can make component (A) and component (B) compatible. (2) When the mixture at 90 ° C. is left in an environment of 25 ° C. and reaches 25 ° C., the component (C) is added so that there is a boundary between the component (A) and the component (B) , component (A) and component (B) can be separated.

Component (C) is, for example, neopentyl glycol dicaprate, olefin oligomer, glyceryl tri-2-ethylhexanoate, sorbitan sesquiisostearate, propylene glycol monostearate, cetyl PEG/PPG-10/1 dimethicone, diisostearate At least one selected from the group consisting of glyceryl, pentaerythrityl tetraethylhexanoate, squalane, liquid paraffin, trimethylolpropane triisostearate, trimethylolpropane triethylhexanoate, diisostearyl malate, and cetyl ethylhexanoate be able to.

The content of component (C) is preferably 0.5% by mass or more, more preferably 1% by mass or more, relative to the mass of the cosmetic composition. Component (C) can be 2% by mass or more, 3% by mass or more, or 5% by mass or more relative to the mass of the cosmetic composition. If the component (C) is less than 0.5% by mass, it becomes difficult to produce a uniform cosmetic composition. Component (C) is preferably 15% by mass or less, more preferably 12% by mass or less, relative to the mass of the cosmetic composition. Component (C) can be 10% by mass or less, 8% by mass or less, or 6% by mass or less with respect to the mass of the cosmetic composition. If the component (C) exceeds 15% by mass, the component (A) or the component (B) becomes relatively small, and the secondary adhesion resistance effect is lowered, or vivid color development cannot be obtained.

[(D) Fourth oil component (wax)]
(D) The fourth oily component consists of wax. Component (D) has the effect of solidifying component (A) and component (B), which have been dissolved at high temperature, while maintaining a compatible state even at room temperature.

Examples of component (D) include microcrystalline wax, polyethylene wax, carnauba wax, candelilla wax, beeswax, ceresin, and Japanese wax. Component (D) is not included in component (B) in the present disclosure.

The content of component (D) is preferably 3% by mass or more, more preferably 4% by mass or more, relative to the mass of the cosmetic composition. Component (D) can be 5% by mass or more, or 7% by mass or more, relative to the mass of the cosmetic composition. If component (D) is less than 3% by mass, the effect of hardening component (A) and component (B) is reduced. Component (D) is preferably 20% by mass or less, more preferably 15% by mass or less, relative to the mass of the cosmetic composition. Component (D) can be 12% by mass or less, 10% by mass or less, or 8% by mass or less with respect to the mass of the cosmetic composition. If component (D) exceeds 20% by mass, component (A) or component (B) will be relatively small, resulting in reduced secondary adhesion resistance effect or failure to obtain vivid color development.

[(E) Colorant]
The coloring material has the effect of coloring the cosmetic composition. The colorant is preferably dispersible in component (B) rather than component (A). The colorant is preferably an organic pigment. The colorant is preferably an organic pigment that is insoluble in component (A) and component (B). At least part of the coloring material is treated with a treatment agent. The treating agent is believed to have the effect of enhancing the dispersibility of the organic pigment in component (B). The treating agent is at least one selected from the group consisting of metal soaps and organic metal alkoxides. The treatment referred to in the present disclosure means coating at least part of the surface of the coloring material particles with a treating agent or physically and/or chemically adsorbing the treating agent to the coloring material particles. The treatment with the treatment agent may be either wet treatment or dry treatment.

The metal soaps referred to in the present disclosure also include alkaline soaps such as sodium salts and potassium salts. Examples of metal soaps include magnesium stearate, calcium stearate, zinc stearate, calcium laurate, zinc laurate, calcium ricinoleate, zinc ricinoleate, zinc octylate, aluminum myristate, sodium lauroyl aspartate, stearoyl-L- sodium glutamate, sodium lysine dilauroyl glutamate, sodium palmitoyl sarcosinate, magnesium palmitoyl sarcosine and the like.

Examples of organic metal alkoxides include isopropyl titanium triisostearate, tetraisopropyl titanate, tetrabutyl orthotitanate, butyl titanate dimer, tetraoctyl titanate, aluminum sec-butoxide, normal propyl zirconate, normal butyl zirconate and the like. .

The processing agent is preferably 0.5% by mass or more, more preferably 1% by mass or more, and 2% by mass or more, based on the mass of the coloring material, that is, the total mass of the organic pigment and the processing agent. and more preferred. The processing agent can be 3% by mass or more with respect to the mass of the coloring material. If the amount of the treating agent is less than 0.5% by mass, it becomes difficult to obtain vivid color development. The processing agent can be 15% by mass or less, 12% by mass or less, 10% by mass or less, 7% by mass or less, 5% by mass or less, or 3% by mass or less with respect to the mass of the coloring material.

Examples of organic pigments include Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Red No. 201, Red No. 202, Red No. 203, Red No. 204, and Red No. 205. Red No. 206, Red No. 207, Red No. 208, Red No. 213, Red No. 214, Red No. 215, Red No. 218, Red No. 219, Red No. 220, Red No. 221, Red No. 223, Red No. 225, Red No. 226, Red No. 227, Red No. 228, Red No. 230 (1), Red No. 230 (2), Red No. 231, Red No. 232, Orange No. 201, Orange No. 203, Orange No. 204 , Orange No. 205, Orange No. 206, Orange No. 207, Yellow No. 4, Yellow No. 5, Yellow No. 201, Yellow No. 202 (1), Yellow No. 202 (2), Yellow No. 203, Yellow 204 No., Yellow No. 205, Green No. 3, Green No. 201, Green No. 202, Green No. 204, Green No. 205, Blue No. 1, Blue No. 2, Blue No. 201, Blue No. 202, Blue No. 203, Blue No. 204, It can be at least one selected from the group consisting of Blue No. 205, Brown No. 201, and Purple No. 201. When the cosmetic composition is lipstick, the organic pigment is at least one selected from the group consisting of Red No. 104, Red No. 201, Red No. 202, Yellow No. 4, Yellow No. 5, and Blue No. 1. and preferred. In particular, it is preferable that the coloring material includes Red No. 202.

The content of component (E) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, relative to the mass of the cosmetic composition. Component (E) can be 1% by mass or more, 1.5% by mass or more, or 2% by mass or more relative to the mass of the cosmetic composition. If the component (E) is less than 0.1% by mass, the color of the cosmetic composition becomes too light. Component (E) is preferably 10% by mass or less, more preferably 8% by mass or less, relative to the mass of the cosmetic composition. Component (E) can be 6% by mass or less, 4% by mass or less, or 3% by mass or less relative to the mass of the cosmetic composition. If the component (E) exceeds 10% by mass, the colorant aggregates.

[(F) Fifth oil component (silicone oil)]
The cosmetic composition of the present disclosure can further contain dimethylpolysiloxane (dimethicone). Component (F) is a component that forms a third layer separated from component (A) and component (B) when the cosmetic composition of the present disclosure is applied to the skin. Component (F) is not included in component (A) in this disclosure.

Component (A), component (B) and component (F) preferably have the following compatibility: (1) component (A), component (B) and component (F) at a mass ratio of 1; : Stir mix 1:1 at 90°C. (2) Allow the mixture to stand in an environment at 25°C. (3) component (A), component (B) and component (B) such that a boundary exists between component (A), component (B) and component (F) when the temperature of the mixture reaches 25°C; Separate from component (F).

When the cosmetic composition of the present disclosure contains component (F), component (C) acts as a compatibilizer that adjusts the compatibility of component (A), component (B) and component (F).

The content of component (F) is preferably 2% by mass or more, more preferably 4% by mass or more, relative to the mass of the cosmetic composition. Component (F) can be 6% by mass or more, or 8% by mass or more, relative to the mass of the cosmetic composition. If the component (F) is less than 2% by mass, a sufficient secondary adhesion resistance effect cannot be obtained. Component (F) is preferably 20% by mass or less, more preferably 15% by mass or less, relative to the mass of the cosmetic composition. Component (F) can be 12% by mass or less, 10% by mass or less, or 8% by mass or less with respect to the mass of the cosmetic composition. If component (F) exceeds 20% by mass, other components are relatively decreased.

[(G) Others]
The cosmetic composition of the present disclosure contains other components such as water, water-soluble alcohol, oil components other than the above, powders, anionic surfactants, and cationic surfactants, as long as the effects of the present disclosure are not impaired. , amphoteric surfactant, hydrophilic nonionic surfactant, lipophilic nonionic surfactant, thickener, moisturizing agent, film-forming agent, oil-soluble UV absorber, water-soluble UV absorber, sequestering agent , amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, fragrances and the like can be appropriately contained as necessary.

As water, water used for cosmetics, quasi-drugs, etc. can be used, for example, purified water, ion-exchanged water, tap water, etc. can be used.

Water is 5% by mass or less, preferably 3% by mass or less, more preferably 1% by mass or less, relative to the mass of the cosmetic composition. More preferably, the cosmetic composition contains no substantial amount of water.

Examples of water-soluble alcohols include lower alcohols, polyhydric alcohols, polyhydric alcohol polymers, dihydric alcohol alkyl ethers, dihydric alcohol alkyl ethers, dihydric alcohol ether esters, glycerin monoalkyl ethers, sugar alcohols, At least one selected from monosaccharides, oligosaccharides, polysaccharides, derivatives thereof, and the like can be mentioned.

Examples of lower alcohols include ethanol, propanol, and isopropanol.

Polyhydric alcohols include, for example, dihydric alcohols (e.g., ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, 1,2-hexanediol, etc.); trihydric alcohols (e.g., glycerin, trimethylolpropane, etc.); tetrahydric alcohols ( For example, pentaerythritol such as 1,2,6-hexanetriol); pentahydric alcohol (e.g., xylitol, etc.); hexahydric alcohol (e.g., sorbitol, mannitol, etc.); polyhydric alcohol polymer (e.g., diethylene glycol, di propylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); sugar alcohols (e.g., sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, amylolytic sugar, maltose, xylitol, amylolytic sugar reducing alcohol, etc.); glycolide; tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether; Propylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphate; POP/POE-pentaneerythritol ether, polyglycerin and the like.

Examples of oligosaccharides include at least one selected from sucrose, guntianose, umbelliferose, lactose, planteose, isoliquinoses, α,α-trehalose, raffinose, lignoses, umbilicine, stachyose, verbascoses, and the like. can be mentioned.

Examples of polysaccharides include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, and keratosulfate. , locust bean gum, succinoglucan, caroninic acid and the like.

Examples of other polyols include at least one selected from polyoxyethylene methyl glucoside (glucum E-10), polyoxypropylene methyl glucoside (glucum P-10), and the like.

As the oily component, for example, hydrocarbon oil, wax, liquid oil, solid oil, wax, synthetic ester oil, higher fatty acid, higher alcohol, silicone oil, etc. can be used.

Examples of hydrocarbon oils include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, isododecane, isohexadecane, hydrogenated polydecene, and mineral oil.

Waxes include, for example, beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, privet wax, montan wax, bran wax, kapok wax, sugarcane wax, hexyl laurate, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE cholesterol ether, POE. Hydrogenated lanolin alcohol ethers such as liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, microcrystalline wax, Fischer-Tropsch wax and the like.

Examples of liquid oils include avocado oil, camellia oil, macadamia nut oil, corn oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, and cottonseed oil. , Eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, sinagiri oil, Japanese pear oil, jojoba oil, germ oil, triglycerin and the like.

Examples of solid fats and oils include cacao butter, coconut oil, hydrogenated coconut oil, palm oil, palm kernel oil, Japanese magnolia kernel oil, hydrogenated oil, Japanese magnolia kernel oil, hydrogenated oil, Japanese magnolia, and hydrogenated castor oil.

Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate, cetyl lactate, and myristyl lactate. , lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, apple diisostearyl acid, glyceryl di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, glyceryl tri-2-ethylhexanoate , glyceryl trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptyl undecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid 2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, sebacin di-2-ethylhexyl acid, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate and the like.

Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toric acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.

Higher alcohols include, for example, straight-chain alcohols (e.g., lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); branched-chain alcohols (e.g., monostearyl glycerin ether (bacyl alcohol ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol, etc.) can be used.

Examples of silicone oils include dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, stearoxymethylpolysiloxane, polyether-modified organopolysiloxane, fluoroalkyl/polyoxyalkylene co-modified organopolysiloxane, and alkyl-modified organopolysiloxane. , terminal-modified organopolysiloxane, fluorine-modified organopolysiloxane, amino-modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicate, silicone RTV rubber, and silicone compounds such as cyclopentasiloxane.

The powder is not particularly limited as long as it can be used in general, such as for cosmetics. Powders include, for example, inorganic powders (e.g., talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, red mica, biotite, slithiamite, calcined mica, calcined talc, vermiculite, Magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, fumed silica, zeolite, glass, barium sulfate, calcined calcium sulfate ( Calcined gypsum), calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc.); organic powder (e.g. polyamide resin powder (nylon powder) , polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, silicone resin powder, silk powder, wool powder, urethane powder etc.); inorganic white pigments (e.g., titanium dioxide, zinc oxide, etc.); inorganic red pigments (e.g., iron oxide (red iron oxide), iron titanate, etc.); inorganic brown pigments (γ-iron oxide, etc.), inorganic yellow system pigments (yellow iron oxide, ocher, etc.), inorganic black pigments (black iron oxide, carbon black, low order titanium oxide, etc.), inorganic purple pigments (e.g., manganese violet, cobalt violet, etc.); inorganic green pigments ( For example, chromium oxide, chromium hydroxide, cobalt titanate, etc.); Inorganic blue pigments (for example, ultramarine blue, Prussian blue, etc.); colored titanium oxide-coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigments (e.g., aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium, or aluminum lakes (e.g., Red No. 201, Red No. 202, Organic pigments such as Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, and Blue No. 404, red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1, etc.); Natural pigments (e.g., chlorophyll, β-carotene, etc.); Wax powder (e.g., carnauba wax powder, etc.); Starch powder (e.g., corn starch powder, rice starch powder, etc.), etc. can be done.

Examples of anionic surfactants include fatty acid soaps (e.g., sodium laurate, sodium palmitate, etc.); higher alkyl sulfate salts (e.g., sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (e.g., , POE-lauryl ether sulfate triethanolamine, POE-sodium lauryl ether sulfate, sodium laureth sulfate, etc.); N-acylsarcosic acid (e.g., sodium lauroyl sarcosinate, etc.); sodium N-methyltaurate, sodium N-myristoyl-N-methyltaurate, sodium cocoyl methyltaurate, sodium lauryl methyl tauride, etc.); phosphate ester salts (POE-sodium oleyl ether phosphate, POE-stearyl ether phosphate, etc.) sulfosuccinates (e.g. sodium di-2-ethylhexyl sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, lauryl polypropylene glycol sodium sulfosuccinate, etc.); alkylbenzene sulfonates (e.g. sodium linadodecylbenzene sulfonate); , linadodecylbenzenesulfonic acid triethanolamine, linadodecylbenzenesulfonic acid, etc.); higher fatty acid ester sulfate salts (e.g., hydrogenated coconut oil fatty acid sodium glycerol sulfate, etc.); sodium, disodium N-stearoyl glutamate, monosodium N-myristoyl-L-glutamate, etc.); sulfated oil (e.g., funnel oil, etc.); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether carboxylate; Olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate; higher fatty acid alkylolamide sulfate; sodium lauroyl monoethanolamide succinate; N-palmitoyl aspartic acid ditriethanolamine; sodium caseinate, etc. can do.

Cationic surfactants include, for example, alkyltrimethylammonium salts (e.g., stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (e.g., cetylpyridinium chloride, etc.); dialkyldimethylammonium salts (e.g., distearyl chloride dimethylammonium); poly(N,N'-dimethyl-3,5-methylenepiperidinium) chloride; alkyl quaternary ammonium salts; alkyldimethylbenzylammonium salts; alkylisoquinolinium salts; - alkylamine; alkylamine salt; polyamine fatty acid derivative; amyl alcohol fatty acid derivative; benzalkonium chloride;

Amphoteric surfactants include, for example, imidazoline-based amphoteric surfactants (e.g., 2-undecyl-N,N,N-(hydroxyethylcarboxymethyl)-2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide side-1-carboxyethyloxy disodium salt, etc.); betaine-based surfactants (e.g., 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amidobetaine , sulfobetaine, etc.) and the like.

Hydrophilic nonionic surfactants include, for example, POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE-sorbitol fatty acid esters (eg, POE-sorbitol monolaurate, POE-sorbitol monooleate, POE-sorbitol pentaoleate, POE-sorbitol monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerol mono stearate, POE-monooleate such as POE-glycerin monoisostearate, POE-glycerin triisostearate, etc.); POE-fatty acid esters (e.g., POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); Alkyl ethers (eg, POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic types (eg, Pluronic, etc.); POE/POP-alkyl ether (e.g., POE/POP-cetyl ether, POE/POP-2-decyltetradecyl ether, POE/POP-monobutyl ether, POE/POP-hydrogenated lanolin, POE/POP-glycerin ether, etc.) tetra-POE/tetra-POP-ethylenediamine condensates (e.g., Tetronic, etc.); POE-castor oil hydrogenated castor oil derivatives (e.g., POE-castor oil, POE-hydrogenated castor oil, POE-hydrogenated castor oil monoisostearate, POE-hydrogenated castor oil triisostearate, POE-hydrogenated castor oil monopyroglutamic acid monoisostearate diester, POE-hydrogenated castor oil maleic acid, etc.); amides (eg, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid esters; POE-alkylamines; POE-fatty acid amides; sucrose fatty acid esters; trioleyl phosphate and the like.

Lipophilic nonionic surfactants include, for example, sorbitan fatty acid esters (e.g., sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate, etc.); , α,α'-glycerol pyroglutamate, glyceryl monostearate, malic acid, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate, etc.); hydrogenated castor oil derivatives;

Examples of natural water-soluble polymers include plant-based polymers (e.g., gum arabic, tragacanth gum, galactan, guar gum, carob gum, karaya gum, carrageenan, pectin, agar, quince seed (quince), algecolloid (cassou extract), starch ( rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, pullulan, etc.)

Examples of semi-synthetic water-soluble polymers include starch-based polymers (e.g., carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose-based polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder, etc.); alginate-based polymers (eg, sodium alginate, propylene glycol alginate, etc.);

Thickeners include, for example, gum arabic, carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, carboxymethylcellulose (CMC), and hydroxyethylcellulose. , hydroxypropylcellulose, polyvinyl alcohol (PVA), polyvinyl methyl ether (PVM), PVP (polyvinylpyrrolidone), sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium cellulose sulfate, xanthan gum, silica Examples include magnesium aluminum oxide, bentonite, hectorite, magnesium aluminum silicate (Vegum), laponite, silicic anhydride, taurate-based synthetic polymer, and acrylate-based synthetic polymer.

Moisturizers include, for example, polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, diglycerin (EO) PO adducts, rose rose extract, yarrow extract, and melilot extract. etc.

Examples of coating agents include polymer silicone, silicone resin, trimethylsiloxysilicate, etc.).

Examples of vitamins include vitamins A, B1, B2, B6, C, E and their derivatives, pantothenic acid and its derivatives, biotin, and the like.

Examples of antioxidants include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, and gallic acid esters.

Examples of antioxidant aids include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, cephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

Other ingredients that can be blended include, for example, preservatives (ethylparaben, butylparaben, chlorphenesin, phenoxyethanol, etc.); ); whitening agent (e.g., placenta extract, saxifrage extract, arbutin, etc.); , coix seed, loofah, lily, saffron, cnidium, ginger, hypericum, ononis, garlic, red pepper, chimp, angelica, seaweed, etc.), activator (e.g., royal jelly, photosensitizer, cholesterol derivative, etc.); blood circulation promoter (e.g., , Nonylic Acid Vanillylamide, Nicotinic Acid Benzyl Ester, Nicotinic Acid β-Butoxyethyl Ester, Capsaicin, Zingerone, Cantharis Tincture, Ictamol, Tannic Acid, α-Borneol, Tocopherol Nicotinate, Inositol Hexanicotinate, Cyclanderate, Cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.), and the like.

Furthermore, the composition of the present disclosure contains caffeine, tannin, verapamil, tranexamic acid and its derivatives, various crude drug extracts such as licorice, Chinese quince, and Ichiyakuso, tocopheryl acetate, glycyrrhizic acid, glycyrrhizic acid and its derivatives or salts thereof, and the like. Pharmaceutical agents, whitening agents such as vitamin C, magnesium ascorbate phosphate, glucoside ascorbate, arbutin and kojic acid, amino acids and derivatives thereof such as arginine and lysine, and glucoxyl hesperidin can also be contained as appropriate.

[Production method]
A method for producing the cosmetic composition of the present disclosure will be described. The cosmetic composition of the present disclosure can be produced by known methods. For example, first, each component is mixed and heated to a temperature at which each component melts (for example, 80° C. or higher). After melting, the mixture is mixed so that each component is uniform. After mixing, the mixture can be cooled to room temperature and solidified while maintaining a uniform component state to produce a solid cosmetic composition.

[how to use]
A method for using the cosmetic composition of the present disclosure will be described. The cosmetic composition of the present disclosure can be used by applying it to the skin. When the cosmetic composition is lipstick, it can be used by directly applying it to the lips. Component (A) and component (B) separate on the skin due to shear and/or pressure during application and/or lip rubbing. When separated, component (B) moves to the skin side and adheres to the skin. Component (E) is dispersed in component (B). Component (A) migrates to cover component (B). Thereby, component (A) acts as a protective film for component (B) and component (E). Even if the part to which the cosmetic composition is applied touches an object, the colorless and transparent component (A) adheres to the contact object and suppresses the adhesion of the component (B) containing the component (E), thereby preventing color transfer. can be suppressed.

In the cosmetic composition of the present disclosure, it may be impossible or almost impractical to directly specify the phase structure by composition. In such cases, the cosmetic composition of the present disclosure should be allowed to be identified by its manufacturing method.

The cosmetic composition of the present disclosure can be applied to, for example, moisturizers, cosmetics, and the like. For example, the cosmetic composition of the present disclosure can be applied to lip moisturizers (lip balms), skin moisturizers (balms), lipsticks, lip glosses, and the like.

The cosmetic composition of the present disclosure suppresses color transfer due to secondary adhesion. The cosmetic composition of the present disclosure enhances vividness of color development by the coloring material when applied to the skin.

The cosmetic composition of the present disclosure will be described below with examples. However, the cosmetic composition of the present disclosure is not limited to the examples below. In the following examples, examples applied to lipsticks of each test example will be described, but the compositions of the present disclosure are not limited to lipsticks. The unit of the content of each component shown in each table is % by mass.

[Test Examples 1 to 37]
Cosmetic compositions according to Test Examples 1 to 37 shown in Tables 1 to 9 were prepared. The prepared cosmetic composition was a solid lipstick at 25° C., and each component was uniformly dispersed. Each composition was tested for the secondary adhesion-less effect and vividness of color development. Evaluation criteria for each test item are shown below.

The percentage of the processing colorant is the ratio of the processing agent to the mass of the processing colorant. For example, 5% magnesium stearate treated Red No. 202 indicates that Red No. 202 was treated with 5% by weight of magnesium stearate relative to the total weight of colorant Red No. 202 and treating agent magnesium stearate.

[Secondary adhesion-less effect]
The cosmetic composition of each test example was applied to the lips as lipstick. The cup was touched once with the lips as if drinking a drink, and whether the cup was colored by the coloring material was evaluated.
A: There was no coloring in the cup;
B: The cup was slightly colored;
C: The cup was slightly colored;
D: The cup was clearly colored.

[Vividness of coloring]
A panel of 10 experts applied the cosmetic composition of each test example to the lips as lipstick, and evaluated whether the color of the lipstick was vivid. It was rated by the number of people who evaluated it on a specialized panel.
A: 8 or more expert panels evaluated that the color development was vivid;
B: 6 to 7 panelists evaluated that the coloring was vivid;
C: 3 to 5 expert panels evaluated that the color development was vivid;
D: Not more than 2 panelists evaluated that the coloring was vivid.

[Test Examples 1 to 4]
Cosmetic compositions with different coloring material treatments were prepared. Table 1 shows the composition and evaluation of each cosmetic composition.

In Test Example 1 using an untreated coloring material, vivid color development was not obtained. In Test Example 2 using the colorant treated with the organic silane compound, the colorant also migrated to the silicone oil, so a sufficient effect of preventing secondary adhesion could not be obtained. On the other hand, in Test Example 3, in which the coloring material treated with metal soap was added, and in Test Example 4, in which the coloring material treated with organometallic alkoxide was added, high evaluations were obtained for both the effect of preventing secondary adhesion and vividness of color development. was taken. From this, by using a coloring material treated with a metal soap and a coloring material treated with an organometallic alkoxide, the content of the phenyl-modified silicone can be increased, and almost no coloring material migrates to the phenyl-modified silicone. Therefore, it was possible to enhance the secondary adhesion resistance effect. Even with a low content of hydrocarbons in which coloring materials are dispersed, vivid colors could be achieved.

[Test Examples 5 to 10]
Cosmetic compositions with varying contents of phenyl-modified silicone were prepared. Table 2 shows the composition and evaluation of each cosmetic composition.

In Test Examples 6 to 10, in which the content of phenyl-modified silicone was low, the evaluation of the secondary adhesion resistance effect was low. Therefore, considering the test examples described later, it is considered that the content of phenyl-modified silicone is preferably 46% by mass or more.

[Test Examples 11 to 15]
A cosmetic composition containing a coloring material with varying amounts of the treating agent and a cosmetic composition with varying content of the compatibilizer were prepared. Table 3 shows the composition and evaluation of each cosmetic composition.

A good evaluation was also obtained in Test Example 11 in which the amount of processing agent for processing the coloring material was reduced. Good evaluations were also obtained in Test Examples 12 and 13 in which the compatibilizer content was low, and Test Example 14 in which one type of compatibilizer was used. It is considered that the content of the compatibilizing agent is preferably 0.5% by mass or more. It is considered that the content of the compatibilizing agent is preferably 15% by mass or less.

[Test Examples 16 to 19]
Cosmetic compositions were prepared with varying amounts of hydrocarbon and ester oil. Table 4 shows the composition and evaluation of each cosmetic composition.

Secondary adhesion occurred in Test Examples 16 to 18, in which the component (B) did not contain a liquid hydrocarbon and consisted of an ester oil. On the other hand, in Test Example 19 in which 50% by mass of component (B) was liquid hydrocarbon, secondary adhesion resistance was improved. From this, it is considered preferable that 40% by mass or more of component (B) is liquid hydrocarbon.

In Test Examples 16 to 18 using untreated coloring materials, like Test Example 1, vivid color development was not obtained.

[Test Examples 20 to 23]
A cosmetic composition having no secondary adhesion-less effect, that is, a one-layer cosmetic composition that does not separate into two layers after application was prepared. Table 5 shows the composition and evaluation of each cosmetic composition.

In Test Example 1, when the untreated coloring material was used, vividness of color development was not obtained. However, in Test Example 20, vivid color development could be obtained even with the untreated colorant. From this, it was found that the problem of not being able to obtain vivid color development and having a dull appearance is a problem peculiar to a two-layer separated cosmetic composition containing a silicone oil as a coating layer. In addition, it was found that the coloring materials treated with metal soaps and organometallic alkoxides are useful for color development of two-layer separation cosmetic compositions.

[Test Examples 24 to 33]
Cosmetic compositions with different types of organic pigments were prepared. Tables 6 and 7 show the composition and evaluation of each cosmetic composition.

In Test Examples 25 to 28, a coloring material other than Red No. 202 was used as the coloring material. Also in Test Examples 25 to 28, vivid colors similar to those in Test Example 24 using Red No. 202 were obtained. Also, a good secondary adhesion-less effect was obtained. On the other hand, in Test Examples 29 to 33 in which the surface treatment of the coloring material was not performed, as in Test Example 1, vivid color development was not obtained. From this, it is considered that the processing of the present disclosure does not matter what type of color material is used. In addition, it was possible to reconfirm the effectiveness of the surface treatment of the coloring material particles in improving the vividness of the color development.

[Test Examples 34-35]
Cosmetic compositions were prepared in which the colorant content was varied. Table 8 shows the composition and evaluation of each cosmetic composition.

Even with a coloring material content of 0.3% by mass, a secondary adhesion-less effect and vivid coloring could be achieved. In addition, the use of the surface treatment coloring material not only improved the vividness of the color development, but also improved the effect of preventing secondary adhesion.

[Test Examples 36-37]
In the above Test Examples, the cosmetic composition separated into two layers after application, but in Test Examples 36 and 37, cosmetic compositions that separated into three layers after application were prepared. Table 8 shows the composition and evaluation of each cosmetic composition.

In Test Examples 36 and 37, when applied to the skin, it separated into three layers: component (A) phenyl-modified silicone, component (F) dimethicone, and component (B) hydrocarbon oil. In Test Example 37, vivid color development could be obtained by surface-treating the coloring material even in the case of a cosmetic that separates into three layers. In addition, Test Example 37 exhibited a higher secondary adhesion resistance effect.

The cosmetic composition of the present invention has been described based on the above embodiments and examples, but is not limited to the above embodiments and examples. Various modifications, changes and improvements can be made to each disclosed element (including the elements described in the claims, specification and drawings) based on the technical concept. Moreover, various combinations, replacements, or selections of each disclosed element are possible within the scope of the claims of the present invention.

Further problems, objects, and forms (including modifications) of the present invention will be made clear from the entire disclosure of the present invention, including the scope of claims.

Regarding the numerical ranges described in this document, it should be interpreted that any numerical value or range included within the range is specifically described in this document, even if there is no particular description.

Some or all of the above embodiments may be described in the following supplementary remarks, but are not limited to the following description. Each appendix can also be combined with each claim listed in the claims.
[Appendix 1]
A method of using a cosmetic composition, wherein the cosmetic composition of the present disclosure is used as a moisturizer.
[Appendix 2]
A method of using the cosmetic composition of the present disclosure as a lipstick.
[Appendix 3]
A method of using a cosmetic composition comprising applying the cosmetic composition of the present disclosure to the lips.

The cosmetic composition of the present disclosure can be applied, for example, to cosmetics applied to the skin. For example, the cosmetic composition of the present disclosure can be applied to base cosmetics, top cosmetics, makeup cosmetics, antiperspirants, deodorants, sunscreen cosmetics, skin care agents, and the like.

Claims (13)

1. (A) 46% by mass or more of a first oily component made of phenyl-modified silicone;
   (B) a second oily component containing a liquid hydrocarbon;
   (C) a third oily component of 15% by mass or less that adjusts the compatibility between the component (A) and the component (B);
   (D) a fourth oily component made of wax;
   (E) a coloring material,
   The component (A) and the component (B) have compatibility such that they separate when mixed at a mass ratio of 1:1 at 25 ° C.,
   The component (B) contains 40% by mass or more of the liquid hydrocarbon relative to the mass of the component (B),
   A cosmetic composition, wherein at least part of the component (E) is treated with at least one selected from the group consisting of metallic soaps and organometallic alkoxides.
2. The metal soap includes magnesium stearate, calcium stearate, zinc stearate, calcium laurate, zinc laurate, calcium ricinoleate, zinc ricinoleate, zinc octoate, aluminum myristate, sodium lauroyl aspartate, sodium stearoyl-L-glutamate, 2. The cosmetic composition according to claim 1, which is at least one selected from the group consisting of sodium lysine dilauroyl glutamate, sodium palmitoyl sarcosinate, and magnesium palmitoyl sarcosine.
3. The organometallic alkoxide is selected from the group consisting of isopropyl titanium triisostearate, tetraisopropyl titanate, tetrabutyl orthotitanate, butyl titanate dimer, tetraoctyl titanate, aluminum sec-butoxide, normal propyl zirconate, and normal butyl zirconate. The cosmetic composition according to claim 1 or 2, which is at least one.
4. The cosmetic composition according to any one of claims 1 to 3, wherein the component (B) further contains a liquid ester oil.
5. The liquid ester oils include glyceryl monoisostearate, isostearyl glyceryl ether, polyglyceryl polyisostearate, tetra(ethylhexanoic acid/benzoic acid) pentaerythrityl, tetra(behenic acid/benzoic acid/ethylhexanoic acid) pentaerythrityl, 5. The cosmetic composition according to claim 4, which is at least one selected from the group consisting of dimer dilinoleate and dipentaerythrityl hexahydroxystearate.
6. The liquid hydrocarbon is at least one selected from the group consisting of hydrogenated polyisobutene, heavy liquid isoparaffin, liquid paraffin, polybutene, polyisobutene, and hydrogenated polydecene, according to any one of claims 1 to 5. Cosmetic composition as described.
7. The component (A) according to any one of claims 1 to 6, wherein said component (A) is at least one selected from the group consisting of trimethylpentaphenyltrisiloxane, diphenyldimethicone, diphenylsiloxyphenyltrimethicone, and phenyltrimethicone. Cosmetic composition as described.
8. Component (C) includes neopentyl glycol dicaprate, olefin oligomer, glyceryl tri-2-ethylhexanoate, sorbitan sesquiisostearate, propylene glycol monostearate, cetyl PEG/PPG-10/1 dimethicone, and diglyceryl diisostearate. , pentaerythrityl tetraethylhexanoate, squalane, liquid paraffin, trimethylolpropane triisostearate, trimethylolpropane triethylhexanoate, diisostearyl malate, and cetyl ethylhexanoate. , The cosmetic composition according to any one of claims 1 to 7.
9. For the mass of the cosmetic composition,
   The component (A) is 46% by mass to 80% by mass,
   The component (B) is 5% by mass to 50% by mass,
   The component (C) is 0.5% by mass to 15% by mass,
   The component (D) is 3% by mass to 20% by mass,
   The cosmetic composition according to any one of claims 1 to 8, wherein the component (E) is 0.1% by mass to 10% by mass.
10. Claims 1 to 9, wherein the component (E) is at least one selected from the group consisting of Red No. 102, Red No. 201, Red No. 202, Yellow No. 4, Yellow No. 5, and Blue No. 1. A cosmetic composition according to any one of claims 1 to 3.
11. The cosmetic composition according to any one of claims 1 to 10, which is a uniform solid composition at 25°C under atmospheric pressure.
12. When the cosmetic composition according to claim is applied to the skin, the component (B) migrates to the skin side, the component (A) migrates to the outside of the component (B),
    The cosmetic composition according to any one of claims 1 to 11, wherein said component (E) is present in said component (B) more than said component (A).
13. The cosmetic composition according to any one of claims 1 to 12, which is applied to the lips.