JP2009143834A - Water-in-oil type emulsion cosmetic - Google Patents
Water-in-oil type emulsion cosmetic Download PDFInfo
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本発明は油中水型乳化化粧料に関する。さらに詳しくは、べたつきがなく、しっとりとした保湿性に優れ、伸び広がりが良好で、且つ、保存安定性に優れた油中水型乳化化粧料に関する。 The present invention relates to a water-in-oil emulsified cosmetic. More particularly, the present invention relates to a water-in-oil emulsified cosmetic that has no stickiness, is excellent in moisturizing and moisturizing properties, has a good spread, and has excellent storage stability.
従来、油中水型乳化化粧料は、油相が連続相であるという構造特性から、皮膚表面上に水分透過性の低い油膜を残し、長時間にわたって肌を乾燥から保護するとともに、化粧持続性が良好であることが知られている。しかしながら、油中水型乳化化粧料は、保存安定性の面から内水相の配合量に制約があり、また、外油相となる油系にワックスを多量に配合したり、油性高分子や界面活性剤を多量に用いて系の安定性を図る必要があった。その結果、肌に塗布した際に、べたつき感や油性感を生じたり、伸び広がりが悪くなる等して、水相を連続相とする水中油型乳化化粧料と比較した場合、良好な使用感を得ることが困難であった。この問題を解決するためにこれまでに数多くの検討がなされてきた。 Conventionally, water-in-oil emulsified cosmetics have a structural characteristic that the oil phase is a continuous phase, leaving an oil film with low moisture permeability on the skin surface, protecting the skin from drying over a long period of time, and maintaining makeup durability. Is known to be good. However, water-in-oil emulsified cosmetics have restrictions on the amount of the inner aqueous phase in terms of storage stability, and a large amount of wax is added to the oil system that becomes the outer oil phase, It was necessary to increase the stability of the system by using a large amount of surfactant. As a result, when applied to the skin, when it is compared with an oil-in-water emulsified cosmetic having an aqueous phase as a continuous phase, such as when it is applied to the skin, it becomes sticky or oily, or the spread of spread is worsened. It was difficult to get. Many studies have been made so far to solve this problem.
例えば、特定のノニオン界面活性剤と特定の混合油を含有する油中水型乳化化粧料(特許文献1参照)、オルガノポリシロキサンエラストマー球状粉体とポリエーテル系シリコーン活性剤を含有する油中水型乳化化粧料(特許文献2参照)、高分子量ポリジメチルシロキサンを含有する油中水型乳化化粧料(特許文献3参照)、ポリオキシアルキレン変性オルガノポリシロキサンと水膨潤性粘土鉱物を含有する油中水型乳化化粧料(特許文献4参照)等が開示されている。 For example, water-in-oil emulsified cosmetics containing a specific nonionic surfactant and a specific mixed oil (see Patent Document 1), water-in-oil containing an organopolysiloxane elastomer spherical powder and a polyether silicone active agent Emulsified cosmetic (see Patent Document 2), water-in-oil emulsified cosmetic containing high molecular weight polydimethylsiloxane (see Patent Document 3), oil containing polyoxyalkylene-modified organopolysiloxane and water-swellable clay mineral A water-in-water emulsified cosmetic (see Patent Document 4) and the like are disclosed.
これまでに様々な油中水型乳化化粧料の検討がなされてきたが、使用感、保存安定性の面で必ずしも十分ではなかった。そこで、本発明の目的は、べたつきがなく、しっとりとした保湿性に優れ、伸び広がりが良好で、且つ、保存安定性に優れた油中水型乳化化粧料を提供することにある。 Various water-in-oil emulsified cosmetics have been studied so far, but they are not always sufficient in terms of usability and storage stability. Accordingly, an object of the present invention is to provide a water-in-oil emulsified cosmetic that has no stickiness, is excellent in moisturizing and moisturizing properties, has good elongation spread, and has excellent storage stability.
本発明者らは、鋭意研究の結果、次の油中水型乳化化粧料が上記の目的を達成することを確認し本発明を完成するに至った。 As a result of intensive studies, the present inventors have confirmed that the following water-in-oil type emulsified cosmetics achieve the above object, and have completed the present invention.
すなわち、本発明は、
次の成分(A)〜(F):
(A)下記一般式(1)で示される特定のシリコーン化合物3〜7質量%
R1 aR2 bR3 cSiO(4−a−b−c)/2(1)
[式中、R1は炭素数1〜30のアルキル基、アリール基、アラルキル基、フッ素置換アルキル基、あるいは、−CmH2m−O−(C2H4O)d(C3H6O)eR4で表される有機基から選択される同種又は異種の有機基であり、R2は−CmH2m−O−(C2H4O)f(C3H6O)g−R5で表されるポリオキシアルキレン基、R3は下記一般式(2)
That is, the present invention
The following components (A) to (F):
(A) 3 to 7% by mass of a specific silicone compound represented by the following general formula (1)
R 1 a R 2 b R 3 c SiO (4-a-b-c) / 2 (1)
[Wherein, R 1 represents an alkyl group having 1 to 30 carbon atoms, an aryl group, an aralkyl group, a fluorine-substituted alkyl group, or —C m H 2m —O— (C 2 H 4 O) d (C 3 H 6 O) e R 4 is the same or different organic group selected from organic groups represented by R 4 , and R 2 is —C m H 2m —O— (C 2 H 4 O) f (C 3 H 6 O). The polyoxyalkylene group represented by g- R 5 , R 3 represents the following general formula (2)
で表されるオルガノシロキサンであって、R4は炭素数4〜30の炭化水素基又はR6−(CO)−で示される有機基、R5は水素原子若しくは炭素数1〜30の炭化水素基又はR6−(CO)−で示される有機基、R6は炭素数1〜30の炭化水素基である。a、b、cはそれぞれ1.0≦a≦2.5、0.001≦b≦1.5、0.001≦c≦1.5であり、d、eはそれぞれ0≦d≦50、0≦e≦50の整数であり、f、gはそれぞれ2≦f≦200、0≦g≦200、かつf+gが3〜200の整数である。また、mは0≦m≦15の整数、hは0≦h≦500の整数であり、nは1≦n≦5の整数である。]
(B)環状シリコーン4〜6量体から選択される一種又は二種以上10〜20質量%
(C)メチルフェニルポリシロキサン4〜8質量%
(D)炭化水素油5〜10質量%
(E)有機変性粘土鉱物0.5〜2質量%
(F)酸化チタン5〜20質量%
を含有することを特徴とする油中水型乳化化粧料に関する。
R 4 is a hydrocarbon group having 4 to 30 carbon atoms or an organic group represented by R 6- (CO)-, R 5 is a hydrogen atom or a hydrocarbon having 1 to 30 carbon atoms A group or an organic group represented by R 6 — (CO) —, R 6 is a hydrocarbon group having 1 to 30 carbon atoms. a, b and c are 1.0 ≦ a ≦ 2.5, 0.001 ≦ b ≦ 1.5 and 0.001 ≦ c ≦ 1.5, respectively, d and e are 0 ≦ d ≦ 50, An integer of 0 ≦ e ≦ 50, f and g are integers of 2 ≦ f ≦ 200, 0 ≦ g ≦ 200, and f + g is 3 to 200, respectively. M is an integer of 0 ≦ m ≦ 15, h is an integer of 0 ≦ h ≦ 500, and n is an integer of 1 ≦ n ≦ 5. ]
(B) One or more types selected from cyclic silicone tetramer to hexamer 10 to 20% by mass
(C) Methylphenylpolysiloxane 4-8% by mass
(D) 5-10% by mass of hydrocarbon oil
(E) Organically modified clay mineral 0.5-2% by mass
(F) Titanium oxide 5-20% by mass
The present invention relates to a water-in-oil type emulsified cosmetic comprising:
本発明によれば、べたつきがなく、しっとりとした保湿性に優れ、伸び広がりが良好で、且つ、保存安定性に優れた油中水型乳化化粧料を提供することができる。 According to the present invention, it is possible to provide a water-in-oil emulsified cosmetic that has no stickiness, is excellent in moisturizing moisture, has good elongation spread, and has excellent storage stability.
本発明に用いられる特定のシリコーン化合物(A)の質量平均分子量は特に限定されるものではないが、500〜200,000であることが好ましく、特に1000〜100,000であることが好ましい。市販品としては、信越化学工業社製のKF−6028等が挙げられる。 The mass average molecular weight of the specific silicone compound (A) used in the present invention is not particularly limited, but is preferably 500 to 200,000, and particularly preferably 1000 to 100,000. As a commercial item, Shin-Etsu Chemical Co., Ltd. KF-6028 etc. are mentioned.
成分(A)の配合量は3〜7質量%が好ましい。3質量%未満では保存安定性の低下がみられ、7質量%を超えると優れた使用感が得られない。 As for the compounding quantity of a component (A), 3-7 mass% is preferable. If it is less than 3% by mass, the storage stability is lowered, and if it exceeds 7% by mass, an excellent feeling of use cannot be obtained.
環状シリコーン4〜6量体(B)は、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサンで示され、これらから選択される一種又は二種以上を組み合わせて用いるものである。市販品としては、信越化学工業社製のシリコンKF−995等が挙げられる。 The cyclic silicone tetramer to hexamer (B) is represented by octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and one or a combination of two or more selected from these is used. . Examples of commercially available products include Silicon KF-995 manufactured by Shin-Etsu Chemical Co., Ltd.
本発明に用いられる成分(B)の配合量は、10〜20質量%が好ましい。10質量%未満では優れた使用感が得られず、20%質量%を超えると油性感が高まり、使用感を悪くしてしまう。 As for the compounding quantity of the component (B) used for this invention, 10-20 mass% is preferable. If it is less than 10% by mass, an excellent feeling of use cannot be obtained, and if it exceeds 20% by mass, the oily feeling increases and the feeling of use becomes worse.
メチルフェニルポリシロキサン(C)は、通常、化粧料に用いられるものである。市販品としては、信越化学工業社製のシリコンKF−56等が挙げられる。 Methylphenylpolysiloxane (C) is usually used in cosmetics. Examples of commercially available products include Silicon KF-56 manufactured by Shin-Etsu Chemical Co., Ltd.
成分(C)の配合量は4〜8質量%が好ましい。4質量%未満では優れた使用感が得られず、更に保存安定性の低下もみられる。また、8質量%を超えると優れた使用感が得られない。 As for the compounding quantity of a component (C), 4-8 mass% is preferable. If it is less than 4% by mass, an excellent feeling of use cannot be obtained, and a decrease in storage stability is also observed. Moreover, when it exceeds 8 mass%, the outstanding usability | use_condition cannot be obtained.
本発明で用いられる炭化水素油(D)は、通常、化粧料に用いられるものであり、流動パラフィン、スクワラン等が挙げられる。 The hydrocarbon oil (D) used in the present invention is usually used in cosmetics, and examples thereof include liquid paraffin and squalane.
成分(D)の配合量は5〜10質量%が好ましい。5質量%未満では優れた使用感が得られず、10%質量%を超えると油性感が高まり、使用感を悪くしてしまう。 As for the compounding quantity of a component (D), 5-10 mass% is preferable. If it is less than 5% by mass, an excellent feeling of use cannot be obtained, and if it exceeds 10% by mass, the oily feeling increases and the feeling of use becomes worse.
本発明で用いられる有機変性粘土鉱物(E)は、通常、化粧料に用いられるものでありジメチルジステアリルアンモニウムヘクトライト、ジメチルジステアリルアンモニウムベントナイト、ベンジルジメチルステアリルアンモニウムヘクトライト等が知られている。市販品としては、エレメンティスジャパン社製のベントン38VCG(ジメチルジステアリルアンモニウムヘクトライト)等が挙げられる。 The organically modified clay mineral (E) used in the present invention is usually used in cosmetics, and dimethyl distearyl ammonium hectorite, dimethyl distearyl ammonium bentonite, benzyl dimethyl stearyl ammonium hectorite and the like are known. Examples of commercially available products include Benton 38VCG (dimethyl distearyl ammonium hectorite) manufactured by Elementis Japan.
成分(E)の配合量は0.5〜2質量%が好ましい。0.5質量%未満では保存安定性の低下がみられ、2質量%を超えると優れた使用感が得られない。 The blending amount of the component (E) is preferably 0.5 to 2% by mass. When the amount is less than 0.5% by mass, the storage stability is deteriorated, and when it exceeds 2% by mass, an excellent feeling of use cannot be obtained.
本発明に用いられる酸化チタン(F)は、通常、化粧料に用いられるものであり、必要であればアルミナ、シリカ処理されたものやシリコーン等で疎水処理したものが用いられる。 The titanium oxide (F) used in the present invention is usually used in cosmetics, and if necessary, those treated with alumina, silica, or those treated with a silicone or the like are used.
成分(F)の配合量は、5〜20質量%が好ましい。5質量%未満では隠蔽効果が低く、メイクアップ化粧料、日焼け止め化粧料としての目的を達成することができず、20質量%を超えると、感触が重くなってしまう。 As for the compounding quantity of a component (F), 5-20 mass% is preferable. If it is less than 5% by mass, the concealing effect is low, the purpose as a makeup cosmetic or sunscreen cosmetic cannot be achieved, and if it exceeds 20% by mass, the feel becomes heavy.
本発明の油中水型乳化化粧料は、上記必須成分の他に、通常の化粧料に使用される成分、例えば顔料、油性成分、保湿剤、乳化剤、紫外線吸収剤、防腐剤、香料等を本発明の効果を損なわない範囲で配合することができる。 The water-in-oil emulsified cosmetic of the present invention contains, in addition to the above essential components, components used in ordinary cosmetics, such as pigments, oily components, moisturizers, emulsifiers, ultraviolet absorbers, preservatives, and fragrances. It can mix | blend in the range which does not impair the effect of this invention.
本発明の油中水型乳化化粧料の用途は特に限定されず、乳化ファンデーション、メイクアップベース等のメイクアップ化粧料、サンスクリーン等の日焼け止め化粧料等として適用することができる。 The use of the water-in-oil emulsified cosmetic of the present invention is not particularly limited, and can be applied as a makeup cosmetic such as an emulsified foundation and a makeup base, and a sunscreen cosmetic such as a sunscreen.
また剤型としては、乳液類、クリーム類等に適用することができる。 The dosage form can be applied to emulsions, creams and the like.
以下に実施例を挙げて本発明を更に詳細に説明する。尚、これらは本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.
実施例1〜6及び比較例1〜16の油中水型乳化化粧料を表1、表2、表3に示す。油中水型乳化化粧料を下記の方法により製造し、保存安定性及び使用感評価を下記の方法に従って行った。 Tables 1, 2 and 3 show the water-in-oil emulsified cosmetics of Examples 1 to 6 and Comparative Examples 1 to 16, respectively. A water-in-oil emulsified cosmetic was produced by the following method, and storage stability and usability evaluation were performed according to the following method.
注1:KF−6028(信越化学工業社製)
<製造方法>
(1)から(7)の油相成分を混合し、75℃にて加熱溶解し、これに(8)〜(10)の顔料を加え、ホモミキサーにて均一に分散する。一方、(11)〜(14)の水相成分を混合し、75℃にて加熱溶解後、油相成分に加え乳化を行う。乳化終了後、30℃まで冷却し、油中水型乳化化粧料を得た。
Note 1: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
<Manufacturing method>
The oil phase components (1) to (7) are mixed, dissolved by heating at 75 ° C., the pigments (8) to (10) are added thereto, and the mixture is uniformly dispersed with a homomixer. On the other hand, the water phase components (11) to (14) are mixed, heated and dissolved at 75 ° C., and then added to the oil phase component to emulsify. After the emulsification, the mixture was cooled to 30 ° C. to obtain a water-in-oil emulsified cosmetic.
<保存安定性の評価>
得られた試料を、5℃、25℃、50℃の各恒温槽内に静置し、30日後の保存安定性を下記の基準に従って判定した。
[判定]
○:変化なし
△:やや分離傾向
×:明らかに分離
<使用感の評価>
専門評価パネル10名により、べたつき感、保湿感、伸び広がり感について5段階評価し、その平均点から下記の基準に従って判定した。
[評価点]
5点:非常に良好
4点:良好
3点:普通
2点:やや不良
1点:不良
[判定]
○:平均点4.0以上
△:平均点2.0以上4.0未満
×:平均点2.0未満
上記評価方法により得られた結果を、表1、表2、表3に併せて示す。
<Evaluation of storage stability>
The obtained sample was left still in each thermostat of 5 degreeC, 25 degreeC, and 50 degreeC, and the storage stability after 30 days was determined in accordance with the following reference | standard.
[Judgment]
○: No change △: Slight separation tendency ×: Clearly separated <Evaluation of feeling of use>
Ten professional evaluation panels evaluated the sticky feeling, moisturizing feeling, and stretch feeling in five levels, and determined from the average points according to the following criteria.
[Evaluation points]
5 points: very good 4 points: good 3 points: normal 2 points: slightly bad 1 point: bad [determination]
◯: Average score of 4.0 or more Δ: Average score of 2.0 or more and less than 4.0 ×: Average score of less than 2.0 .
表1、表2、表3の結果から明らかなように、本発明に係る実施例1〜6は、比較例1〜16に比べ、保存安定性、使用感共に優れるものであった。 As is clear from the results of Tables 1, 2 and 3, Examples 1 to 6 according to the present invention were superior in both storage stability and usability compared to Comparative Examples 1 to 16.
[実施例7]油中水型乳化化粧料(乳化ファンデーッション1)
(1) シリコーン化合物(注1) 5.0(質量%)
(2) オクタメチルシクロテトラシロキサン 15.0
(3) メチルフェニルポリシロキサン 6.0
(4) スクワラン 7.0
(5) 有機変性粘土鉱物(注2) 1.0
(6) 酸化チタン 10.0
(7) ベンガラ 0.5
(8) 黄酸化鉄 1.5
(9) 黒酸化鉄 0.2
(10)タルク 5.0
(11)1,3−ブチレングリコール 5.0
(12)パラオキシ安息香酸メチル 0.2
(13)塩化ナトリウム 1.0
(14)精製水 100とする残部
注1:KF−6028(信越化学工業社製)
注2:ベントン38VCG(エレメンティスジャパン社製)
製法:(1)から(5)の油相成分を混合し、75℃にて加熱溶解し、これに(6)〜(10)の顔料を加え、ホモミキサーにて均一に分散する。一方、(11)〜(14)の水相成分を混合し、75℃にて加熱溶解後、油相成分に加え乳化を行う。乳化終了後、30℃まで冷却し、油中水型乳化化粧料を得た。
[Example 7] Water-in-oil emulsified cosmetic (emulsion foundation 1)
(1) Silicone compound (Note 1) 5.0 (mass%)
(2) Octamethylcyclotetrasiloxane 15.0
(3) Methylphenylpolysiloxane 6.0
(4) Squalane 7.0
(5) Organically modified clay mineral (Note 2) 1.0
(6) Titanium oxide 10.0
(7) Bengala 0.5
(8) Yellow iron oxide 1.5
(9) Black iron oxide 0.2
(10) Talc 5.0
(11) 1,3-butylene glycol 5.0
(12) Methyl paraoxybenzoate 0.2
(13) Sodium chloride 1.0
(14) The balance of purified water 100 Note 1: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 2: Benton 38VCG (made by Elementis Japan)
Production method: The oil phase components (1) to (5) are mixed, dissolved by heating at 75 ° C., the pigments (6) to (10) are added thereto, and the mixture is uniformly dispersed with a homomixer. On the other hand, the water phase components (11) to (14) are mixed, heated and dissolved at 75 ° C., and then added to the oil phase component to emulsify. After the emulsification, the mixture was cooled to 30 ° C. to obtain a water-in-oil emulsified cosmetic.
実施例7はべたつきがなく、しっとりとした保湿性に優れ、伸び広がりが良好で、且つ、保存安定性に優れた油中水型乳化化粧料であった。 Example 7 was a water-in-oil emulsified cosmetic with no stickiness, excellent moisturizing and moisturizing properties, good elongation spread, and excellent storage stability.
[実施例8]油中水型乳化化粧料(乳化ファンデーション2)
(1) シリコーン化合物(注1) 5.0(質量%)
(2) ドデカメチルシクロヘキサシロキサン 15.0
(3) メチルフェニルポリシロキサン 6.0
(4) スクワラン 7.0
(5) 有機変性粘土鉱物(注2) 1.0
(6) 酸化チタン 10.0
(7) ベンガラ 0.5
(8) 黄酸化鉄 1.5
(9) 黒酸化鉄 0.2
(10)タルク 5.0
(11)1,3−ブチレングリコール 5.0
(12)パラオキシ安息香酸メチル 0.2
(13)塩化ナトリウム 1.0
(14)精製水 100とする残部
注1:KF−6028(信越化学工業社製)
注2:ベントン38VCG(エレメンティスジャパン社製)
製法:(1)から(5)の油相成分を混合し、75℃にて加熱溶解し、これに(6)〜(10)の顔料を加え、ホモミキサーにて均一に分散する。一方、(11)〜(14)の水相成分を混合し、75℃にて加熱溶解後、油相成分に加え乳化を行う。乳化終了後、30℃まで冷却し、油中水型乳化化粧料を得た。
[Example 8] Water-in-oil emulsified cosmetic (emulsification foundation 2)
(1) Silicone compound (Note 1) 5.0 (mass%)
(2) Dodecamethylcyclohexasiloxane 15.0
(3) Methylphenylpolysiloxane 6.0
(4) Squalane 7.0
(5) Organically modified clay mineral (Note 2) 1.0
(6) Titanium oxide 10.0
(7) Bengala 0.5
(8) Yellow iron oxide 1.5
(9) Black iron oxide 0.2
(10) Talc 5.0
(11) 1,3-butylene glycol 5.0
(12) Methyl paraoxybenzoate 0.2
(13) Sodium chloride 1.0
(14) The balance of purified water 100 Note 1: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
Note 2: Benton 38VCG (made by Elementis Japan)
Production method: The oil phase components (1) to (5) are mixed, dissolved by heating at 75 ° C., the pigments (6) to (10) are added thereto, and the mixture is uniformly dispersed with a homomixer. On the other hand, the water phase components (11) to (14) are mixed, heated and dissolved at 75 ° C., and then added to the oil phase component to emulsify. After the emulsification, the mixture was cooled to 30 ° C. to obtain a water-in-oil emulsified cosmetic.
実施例8はべたつきがなく、しっとりとした保湿性に優れ、伸び広がりが良好で、且つ、保存安定性に優れた油中水型乳化化粧料であった。 Example 8 was a water-in-oil emulsified cosmetic with no stickiness, excellent moisturizing and moisturizing properties, good elongation spread, and excellent storage stability.
Claims (1)
(A)下記一般式(1)で示される特定のシリコーン化合物 3〜7質量%
R1 aR2 bR3 cSiO(4−a−b−c)/2 (1)
[式中、R1は炭素数1〜30のアルキル基、アリール基、アラルキル基、フッ素置換アルキル基、あるいは、−CmH2m−O−(C2H4O)d(C3H6O)eR4で表される有機基から選択される同種又は異種の有機基であり、R2は−CmH2m−O−(C2H4O)f(C3H6O)g−R5で表されるポリオキシアルキレン基、R3は下記一般式(2)
(B)環状シリコーン4〜6量体から選択される一種又は二種以上10〜20質量%
(C)メチルフェニルポリシロキサン4〜8質量%
(D)炭化水素油5〜10質量%
(E)有機変性粘土鉱物0.5〜2質量%
(F)酸化チタン5〜20質量%
を含有することを特徴とする油中水型乳化化粧料。 The following components (A) to (F):
(A) 3-7% by mass of a specific silicone compound represented by the following general formula (1)
R 1 a R 2 b R 3 c SiO (4-a-b-c) / 2 (1)
[Wherein, R 1 represents an alkyl group having 1 to 30 carbon atoms, an aryl group, an aralkyl group, a fluorine-substituted alkyl group, or —C m H 2m —O— (C 2 H 4 O) d (C 3 H 6 O) e R 4 is the same or different organic group selected from organic groups represented by R 4 , and R 2 is —C m H 2m —O— (C 2 H 4 O) f (C 3 H 6 O). The polyoxyalkylene group represented by g- R 5 , R 3 represents the following general formula (2)
(B) One or more types selected from cyclic silicone tetramer to hexamer 10 to 20% by mass
(C) Methylphenylpolysiloxane 4-8% by mass
(D) 5-10% by mass of hydrocarbon oil
(E) Organically modified clay mineral 0.5-2% by mass
(F) Titanium oxide 5-20% by mass
A water-in-oil type emulsified cosmetic comprising:
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011037123A1 (en) * | 2009-09-25 | 2011-03-31 | 株式会社 資生堂 | Water-in-oil-type emulsion skin cosmetic |
JP2011148757A (en) * | 2009-12-22 | 2011-08-04 | Shiseido Co Ltd | Aerosol-type cosmetic for makeup use |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001039819A (en) * | 1999-07-30 | 2001-02-13 | Shin Etsu Chem Co Ltd | New silicone compound and cosmetic containing the same |
JP2003292415A (en) * | 2002-04-01 | 2003-10-15 | Shin Etsu Chem Co Ltd | Cosmetic |
JP2004161698A (en) * | 2002-11-14 | 2004-06-10 | Kose Corp | Water-in-oil type emulsion cosmetic |
-
2007
- 2007-12-13 JP JP2007321534A patent/JP2009143834A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001039819A (en) * | 1999-07-30 | 2001-02-13 | Shin Etsu Chem Co Ltd | New silicone compound and cosmetic containing the same |
JP2003292415A (en) * | 2002-04-01 | 2003-10-15 | Shin Etsu Chem Co Ltd | Cosmetic |
JP2004161698A (en) * | 2002-11-14 | 2004-06-10 | Kose Corp | Water-in-oil type emulsion cosmetic |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011037123A1 (en) * | 2009-09-25 | 2011-03-31 | 株式会社 資生堂 | Water-in-oil-type emulsion skin cosmetic |
JP2011068598A (en) * | 2009-09-25 | 2011-04-07 | Shiseido Co Ltd | Water-in-oil type emulsion skin cosmetic |
CN102573783A (en) * | 2009-09-25 | 2012-07-11 | 株式会社资生堂 | Water-in-oil-type emulsion skin cosmetic |
CN102573783B (en) * | 2009-09-25 | 2013-08-28 | 株式会社资生堂 | Water-in-oil-type emulsion skin cosmetic |
US8815958B2 (en) | 2009-09-25 | 2014-08-26 | Shiseido Company, Ltd. | Water-in-oil type emulsion skin cosmetic |
JP2011148757A (en) * | 2009-12-22 | 2011-08-04 | Shiseido Co Ltd | Aerosol-type cosmetic for makeup use |
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