JP2013103885A - Unevenness-correcting cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a cosmetic which is excellent in an unevenness-correcting effect and its sustainability, is good in the fitness of the cosmetic to skins, and gives soft cosmetic films.SOLUTION: The unevenness-correcting cosmetic which is excellent in the unevenness-correcting effect and its sustainability, is good in the fitness of the cosmetic to skins, and gives soft cosmetic films is characterized by compounding the following ingredients (a)-(c): (a) a partially cross-linked organopolysiloxane polymer containing phenyl groups; (b) a film-forming silicone resin; and (c) a powdery material having a refractive index of 1.4-1.8.

Description

  The present invention relates to a concavo-convex correction cosmetic containing a phenyl group-containing partially crosslinked organopolysiloxane polymer, a film-forming silicone resin, and a powder having a refractive index of 1.4 to 1.8. The composition relates to a cosmetic that is excellent in the unevenness correction effect and its sustainability, has a good fit on the skin, and has a soft cosmetic film.

Conventionally, in order to make the skin look beautiful, the skin surface has been smoothed with cosmetics and the skin color has been uniformly adjusted. The surface of the skin is uneven due to pores and skin grooves, and the makeup film collects in the concave portions of the skin over time, and the cosmetics are localized, so that pores and wrinkles are conspicuous, thereby making the skin color uneven and causing the skin to become uneven The effect that makes it look beautiful could not be obtained. Accordingly, cosmetics have been developed for the purpose of correcting unevenness.
As a method for correcting irregularities, a method using a low refractive index powder to blur pores and skin grooves by diffusing light, or filling the pores and skin grooves with powder to physically smooth the skin surface There was a way.
Although these methods are effective immediately after application, the cosmetic film may be destroyed due to changes in facial expression or sebum.
Therefore, by using a specific size organopolysiloxane elastomer spherical powder, volatile silicone, and a silicone resin that forms a film, or by using specific size spherical particles and an oil agent, A method for making the above inconspicuous has been studied. (For example, see Patent Documents 1 and 2)

JP 09-175940 A JP 2005-281295 A

  However, although the silicone resin that forms the film firmly forms the decorative film, it becomes a hard film, cannot follow the movement of the skin, and may not have the expected effect. Further, in addition to spherical particles, when a partially crosslinked organopolysiloxane polymer is used to obtain further effects, the adhesion of the cosmetic to the skin is poor and does not fit into the skin. There is a case where the unevenness correction effect cannot be sufficiently exhibited because the fit is poor and the decorative film cannot be made uniform.

  Therefore, it has been desired to develop a cosmetic that is excellent in the unevenness correction effect and its sustainability, has a good fit on the skin of the cosmetic, and can provide a soft cosmetic film.

  As a result of diligent research in view of the above problems, the present inventor further improved the unevenness correction effect by combining a powder with a low refractive index and a partially crosslinked organopolysiloxane polymer, and further formed a film. It was thought that by adding a silicone resin, a decorative film could be firmly formed and the sustainability could be improved. As a result, the number of cosmetics that were not smooth and unfit to the skin was reduced, and the cosmetics were better fitted to the skin, but the softness of the cosmetic film could not be realized. Therefore, when a phenyl group-containing partially cross-linked organopolysiloxane polymer is used, the adhesion of the cosmetic is further increased, the cosmetic is better fit on the skin, the cosmetic film itself is softened, and the low refractive index is reduced. It was found that the powder was uniformly applied and the unevenness correction effect was improved, and the present invention was completed.

That is, the present invention
The following components (a) to (c);
(A) a phenyl group-containing partially crosslinked organopolysiloxane polymer (b) a film-forming silicone resin (c) an unevenness-correcting cosmetic comprising a powder having a refractive index of 1.4 to 1.8 It is to provide.

  The present invention relates to an unevenness-correcting cosmetic comprising the phenyl group-containing partially crosslinked organopolysiloxane polymer, a film-forming silicone resin, and a powder having a refractive index of 1.4 to 1.8. Relates to a cosmetic that is excellent in the unevenness correction effect and its sustainability, has a good fit on the skin, and has a soft cosmetic film.

Details of the present invention will be described below.
The irregularity-corrected cosmetic of the present invention is a special-purpose cosmetic that obscure undesirable fine irregularities such as small wrinkles and pores on the skin before and after the makeup cosmetic, and undesirably fine irregularities are not noticeable Cosmetics with added functions.

  The component (a) phenyl group-containing partially crosslinked organopolysiloxane polymer used in the present invention is not particularly limited as long as it is a compound having a phenyl group in a silicone elastomer having a three-dimensional structure partially having a crosslinking bond.

Component (a) Phenyl group-containing partially crosslinked organopolysiloxane polymer is, for example, SiO ₂ unit, HSiO _1.5 unit, RSiO _1.5 unit, RHSiO unit, R ₂ SiO unit, R ₃ SiO _0.5 unit. And R ₂ HSiO _0.5 unit (wherein R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding an aliphatic unsaturated group. The monovalent hydrocarbon group is a methyl group, Alkyl group such as ethyl group, propyl group, aryl group such as phenyl group, tolyl group, aliphatic unsaturated group such as vinyl group, hydrogen atom such as methyl group, ethyl group, propyl group, phenyl group, tolyl group, etc. An aralkyl group substituted with an aryl group, a cycloalkyl group such as a cyclohexyl group, a halogenated hydrocarbon group containing a fluoro group, a hydrocarbon group containing an ethylene oxide group, etc. ) Composed of at least one structural unit selected from the group consisting of, an organohydrogenpolysiloxane containing in 1.5 or more molecules of hydrogen atoms bonded to silicon atoms on average, SiO ₂ units, ( CH ₂ ═CH) SiO _1.5 units, RSiO _1.5 units, R (CH ₂ ═CH) SiO units, R ₂ SiO units, R ₃ SiO _0.5 units, R ₂ (CH ₂ ═CH) SiO _{0 0.5} unit (where R is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding an aliphatic unsaturated group. Examples of the monovalent hydrocarbon group include a methyl group, an ethyl group, and a propyl group. Substituted alkyl groups such as phenyl groups, aryl groups such as phenyl groups and tolyl groups, aliphatic unsaturated groups such as vinyl groups, methyl groups, ethyl groups, propyl groups and other hydrogen atoms with aryl groups such as phenyl groups and tolyl groups Was A aralkyl group, a cyclohexyl group, a halogenated hydrocarbon group containing a fluoro group, a hydrocarbon group containing an ethylene oxide group, etc.). unsaturated represented by a vinyl group-containing organopolysiloxane and / or _{C m H 2m-1 (CH} 2) x C m H 2m-1 containing a vinyl group bonded to a silicon atom average 1.5 or more in It can be obtained by addition polymerization with a hydrocarbon (where m is 2 to 6 and x is an integer of 1 or more).

  However, R of the organohydrogenpolysiloxane and vinyl group-containing organopolysiloxane as the structural unit represents a substituted or unsubstituted monovalent hydrocarbon group having 1 to 30 carbon atoms excluding a fatty acid unsaturated group. A part of R is a phenyl group.

  As such a partially crosslinked organosiloxane polymer containing a phenyl group, for example, (diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane) crosspolymer may be mentioned under the component designation name. Examples of commercially available products include silicone gels in which hydrocarbon oils or ester oils are blended with partially crosslinked organosiloxane polymers containing phenyl groups. Examples of commercially available products include KSG-18 (15% diphenylsiloxyphenyl). A trimethicone solution (manufactured by Shin-Etsu Chemical Co., Ltd.) can be specifically mentioned.

  Although the compounding quantity of the component (a) used by this invention is not specifically limited, 0.05-10 mass% (henceforth only showing "%") in cosmetics is preferable, More preferably, it is 0.1-6. %. If it is this range, the uneven | corrugated correction | amendment cosmetics excellent in the unevenness | corrugation correction effect and its sustainability, the goodness of the cosmetics to the skin, and the softness of the cosmetic film can be obtained.

  The film-forming silicone resin of component (b) used in the unevenness correction cosmetic of the present invention is not particularly limited as long as it has an organopolysiloxane skeleton and forms a film, but in the present invention, film formation is A solution in which 40% of a silicone resin is dissolved in a soluble solvent is applied to a glass plate with a 400 μm-thick applicator and dried for 24 hours at room temperature. It is a component used. Specific examples include trimethylsiloxysilicic acid, polymethylsilsesquioxane, and acrylic-silicone graft copolymers, and one or more of these can be used.

Trimethylsiloxysilicic acid is a compound having a crosslinked structure having a siloxane structure as a main skeleton, and represented by [(CH ₃ ) ₃ SiO _1/2 ] x [SiO ₂ ] y (X is 1 to 3, Y is 0.5-8) and the like, and a solution dissolved with silicone oil can also be used. Commercially available products include silicon X-21-5250 (50% decamethylcyclopentasiloxane solution), KF-7312T (60% methyltrimethicone solution), KF-7312J (50% decamethylcyclopentasiloxane solution), KF- 7312K (60% dimethicone solution), KF-9021 (50% decamethylcyclopentasiloxane solution) (all manufactured by Shin-Etsu Chemical Co., Ltd.), SR1000 (made by Momentive Performance Materials Japan), etc. it can.

Polymethylsilsesquioxane is composed of R ¹ SiO _1.5 units and R ² ₃ SiO _0.5 units (wherein R ¹ and R ² represent substituted or unsubstituted monovalent hydrocarbon groups). It is a silicone resin, and as a commercial product, SILFORM
FLEXIBLE RESIN (made by Momentive Performance Materials), etc. are mentioned.

  The acrylic-silicone graft copolymer is a radical of an organopolysiloxane compound (I) having a radical polymerizable group at one end of a molecular chain and a radical polymerizable monomer (II) mainly composed of acrylate and / or methacrylate. Examples of the polymer include those described in JP-A-2-25411 and JP-A-2-132141. Further, (III) acrylic acid and / or methacrylic acid can be further polymerized as monomers.

  Examples of the organopolysiloxane compound (I) having radical polymerizability at one end of the molecular chain include those represented by the following general formula (1).

R ¹ : a methyl group or a hydrogen atom R ² : a divalent saturated hydrocarbon having 1 to 10 carbon atoms having a linear or branched carbon chain, optionally blocked by one or two ether bonds Group R ³ : may be the same or different, and is selected from a methyl group, a butyl group, and —OSi (CH ₃ ) ₃ : 1 to 300

  The radical polymerizable monomer (b) mainly composed of acrylate and / or methacrylate means a compound having one radical polymerizable unsaturated bond in the molecule, and the acrylate and / or methacrylate used is methyl (meta). ) Acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, alkyl (meth) acrylate such as 2-ethylhexyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, etc. Hydroxyalkyl (meth) acrylate, perfluoroalkyl (meth) acrylate having 1 to 10 fluorocarbon chains, and the like.

  Copolymerization of the dimethylpolysiloxane compound (I) having a radical polymerizable group at one end of the molecular chain with the radical copolymerizable monomer (II) mainly composed of acrylate and / or methacrylate is carried out by polymerization ratio ((I) / (II)): In the range of 1/19 to 2/1, it is carried out in the presence of a normal radical polymerization initiator such as benzoyl peroxide, lauroyl peroxide, azobisisobutyronitrile, solution polymerization method, Any of an emulsion polymerization method, a suspension polymerization method, and a bulk polymerization method can be applied.

Such an acrylic-silicone-based graft copolymer has a component designation name, for example, an (alkyl acrylate / dimethicone) copolymer. Examples of commercially available products include KP-541 (60% isopropanol solution), KP-545 (30% cyclopentasiloxane solution), KP-549 (40% methyltrimethicone solution), and KP-550 (40% isododecane solution). Etc.
Further, an organopolysiloxane compound (I) having a radical polymerizable group at one end of a molecular chain, a radical copolymerizable monomer (II) mainly composed of acrylate and / or methacrylate, and (III) acrylic acid and / or methacrylic acid The copolymer may be, for example, a component designation name, and a component designation name, for example, (acrylates / tris (trimethylsiloxy) silylpropyl methacrylate) copolymer.

  In the present invention, the component (b) can be used alone or in combination of two or more thereof, and the blending amount thereof is not particularly limited, but is preferably 0.1 to 10% in the cosmetic, more preferably 0. .5-5%. Within this range, the film feel is not strong, there is no burden on the skin, the unevenness correction effect and its sustainability are excellent, the cosmetics have good fit on the skin, and the unevenness is excellent in the softness of the makeup film A corrected cosmetic can be obtained.

The powder of the component (c) used in the present invention is a powder having a refractive index in the range of 1.4 to 1.8, and in the unevenness correction cosmetic of the present invention, the pores and skin grooves are blurred. , Make the unevenness of the skin inconspicuous. The refractive index is a value measured by a liquid immersion method. Specifically, polyamide, polymethylsilsesquioxane, silicone elastomer, crosslinked silicone / network silicone copolymer, polystyrene, polyurethane, polyethylene, crystalline cellulose, polymethacrylic ester, polyacrylic ester, silicic anhydride , Calcium carbonate, magnesium carbonate, barium sulfate, alumina, aluminum hydroxide, boron nitride, and the like, and one or more of these can be used.
Moreover, the particle size of a component (c) is although it does not specifically limit, 1-50 micrometers is preferable from a viewpoint which makes the unevenness | corrugation of skin inconspicuous. In the present invention, the average particle diameter is a value obtained by a laser diffraction particle size distribution analyzer. In the unevenness correcting cosmetic composition of the present invention, when a powder having a refractive index of less than 1.4 is used instead of the component (c), the transparency of the decorative film is increased, and it is difficult to obtain the effect of blurring small wrinkles and pores. For this reason, it is not preferable to use a powder having a refractive index of more than 1.8, because the decorative film becomes opaque and unnaturally finished.

Commercially available products include cross-linked silicone / network-type silicone copolymers such as “KSP-102 (manufactured by Shin-Etsu Chemical Co., Ltd.)”, “Gantz Pearl GM-2800 (manufactured by Gantz Kasei)”, and polystyrene as Gantz Pearl. GS-0605 (manufactured by Gantz Kasei Co., Ltd.), and poly (meth) acrylate alkyls include Matsumoto Microsphere M-305, M-306, M-503, M-600, M-311 (Matsumoto Yushi) As the polyamide, Gantz Pearl GPA-550 (manufactured by Gantz Kasei), Orgasol 2002D, 2002EXD (above, manufactured by Atofina Japan), Toray nylon powder SP-500 (manufactured by Toray Industries, Inc.) and the like can be mentioned. It is done. These powders may be subjected to a surface treatment by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a wax, a surfactant, an oil, a hydrocarbon, or the like.

  Although the compounding quantity of the component (c) in the uneven | corrugated correction cosmetics of this invention is not specifically limited, 1 to 40% is preferable and 3 to 20% is still more preferable. When the blending amount of the component (c) is within this range, it is possible to obtain an unevenness-correcting cosmetic excellent in the effect of making the unevenness of the skin inconspicuous and excellent in sustainability over time.

In addition to the above components (a) to (c), the unevenness correcting cosmetic of the present invention improves the fit of the cosmetic on the skin, in particular, by blending the component (d) phenyl group-containing non-crosslinked organopolysiloxane. To do.
Unlike the component (a), the component (d) phenyl group-containing non-crosslinked organopolysiloxane can be used as long as it does not have a crosslinked structure and contains a phenyl group. Specific examples of component names include diphenyl dimethicone, diphenylsiloxyphenyl trimethicone, trimethylpentaphenyl trisiloxane, phenyl trimethicone, phenyl methicone, and the like, using one or more of them. Can do.

  Although the compounding quantity of the component (d) in the uneven | corrugated correction cosmetics of this invention is not specifically limited, 0.05-20% is preferable and 0.1-10% is still more preferable. When the content of the component (d) is within this range, it is possible to obtain an unevenness-correcting cosmetic material that has an effect of making the unevenness of the skin inconspicuous and that the cosmetic material fits on the skin.

In addition to the components (a) to (c), the unevenness correcting cosmetic of the present invention further improves the dispersibility of the component (b) and the sustainability of the unevenness correction effect by using the volatile oil agent of the component (e). can do. The component (e) volatile oil is volatile at 1 atmosphere and 25 ° C., and specifically has a boiling point of 260 ° C. or less at normal pressure. Light liquid isoparaffin, hydrocarbon, hexamethyldisiloxane , Decamethyltetrasiloxane, dodecamethylcyclopentasiloxane, methyltrimethicone, ethyltrisiloxane, and other low molecular chain polysiloxanes, low polymerization dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohex Examples thereof include low molecular cyclic silicone oils such as sasiloxane.
Commercially available light isoparaffins such as Isopar H (Esso Chemical), Isododecane (Bayer), Isohexadecane (Uniquema), IP Solvent 1620MU, IP Solvent 2028MU, IP Solvent 2835 (above, Idemitsu Kosan Co., Ltd.) ), Decamethylcyclopentasiloxane as TFS405 (manufactured by Toshiba Silicone), SH245, DC345 (manufactured by Dow Corning Toray), KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.), and methyltrimethicone as silicone TMF- 1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.) as methylpolysiloxane, KF-96L-1.5CS (manufactured by Shin-Etsu Chemical Co., Ltd.) as decamethyltetrasiloxane, SILSO as ethyltrisiloxane T ETS (manufactured by Momentive Performance Materials, Inc.), and the like.

  Although the compounding quantity of the volatile oil agent of a component (e) is not specifically limited, 0.5 to 40% is preferable, More preferably, it is 1 to 30%. If it is this range, the dispersibility of a component (b) can be improved and the uneven | corrugated correction | amendment cosmetics excellent in the persistence of the uneven | corrugated correction effect can be obtained.

In addition to the components (a) to (c) described above, the irregularity-corrected cosmetic of the present invention uses the paste oil of component (f) to increase the adhesion to the skin and improve the fit of the cosmetic on the skin. be able to.
The paste oil of component (f) is an oil agent that takes a paste form at room temperature, and the paste form has a viscosity at 30 ° C. of 5000 to 100,000 mPa · s. In the present invention, the viscosity was measured using a single cylindrical rotational viscometer bismetron type VS-A1 (manufactured by Shibaura System Co., Ltd.) after allowing the sample to stand at 30 ° C. for one day.
For example, hydrocarbons, animal oils, vegetable oils, mineral oils, higher fatty acid esters, cross-linked silicone oils, fluorine-based oils and the like can be used. Specifically, petroleum jelly, hardened oil of palm oil, hardened oil of palm oil, monostearic acid hardened castor oil, lanolin, cholesteryl hydroxystearate, cholesterol fatty acid ester, phytosterol fatty acid ester, dipentaerythritol fatty acid ester, cross-linked type Examples thereof include methylpolysiloxane, cross-linked methylphenylpolysiloxane, highly polymerized methylpolysiloxane, and the like, and these can be used alone or in combination. Commercially available products include petrolatum pen reco snow (manufactured by Pen Reco), polybutene 35R, polybutene 100R, polybutene 300R (all manufactured by Idemitsu Petrochemical Co., Ltd.), Saracos HS, Cosmol 168 series, and NOMCOAT LAH (all manufactured by Nisshin Oil Etc.).

  Although the compounding quantity of the paste oil of a component (f) is not specifically limited, 0.05-20% is preferable, More preferably, it is 0.1-15%. If it is this range, the uneven | corrugated correction | amendment cosmetics which improved the adhesion to skin and were excellent in the fit of the cosmetics to the skin can be obtained.

In the unevenness correcting cosmetic composition of the present invention, if necessary, components that can be blended with ordinary cosmetic compositions can be blended as appropriate.
For example, oils other than components (a), (b), (d), (e) and (f), surfactants, alcohols, water, powders other than component (c), UV absorbers, gelling agents And thickeners, moisturizers, antiseptics, antibacterial agents, antioxidants, beauty ingredients (whitening agents, cell activators, anti-inflammatory agents, blood circulation promoters, skin astringents, antiseborrheic agents, vitamins, amino acids Etc.) can be blended.

Examples of the oil agent include solid oils, liquid oils and the like, and natural animal and vegetable oils and semi-synthetic oils, hydrocarbon oils, ester oils, glyceride oils, silicone oils, higher alcohols, higher fatty acids, organic solvents and the like are exemplified.
Solid oils include carnauba wax, candelilla wax, cotton wax, shellac wax, natural waxes such as hardened oil, mineral waxes such as ozokerite, ceresin, paraffin wax, microcrystalline wax, polyethylene wax, Fischer-Tropsch wax, ethylene propylene copolymer And the like, synthetic alcohols such as behenyl alcohol, cetyl alcohol, stearyl alcohol, cholesterol and phytosterols, higher fatty acids such as stearic acid and behenic acid, and the like.
Liquid oils, including natural animal and vegetable oils and semi-synthetic oils, specifically avocado oil, linseed oil, almond oil, ibotarou, eno oil, olive oil, kaya oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil , Rice bran oil, sasanqua oil, safflower oil, cinnamon oil, cinnamon oil, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, nukarou, germ oil, persic oil , Palm oil, palm kernel oil, castor oil, sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, palm oil, tricoconut oil fatty acid glyceride, peanut oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid Isopropyl, POE lanolin alcohol ether, POE lanolin alcohol acetate, lanoli Fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, yolk oil, and the like.
Examples of the hydrocarbon oil include squalane, squalene, liquid paraffin, and pristane.
Examples of ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, 2-ethylhexanoic acid Cetyl, ethylene glycol di-2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octoate, octyldodecyl Gum ester, oleyl oleate, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate Butyl acetate, isocetyl stearate, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, cetyl lactate, myristyl lactate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, palmitic acid 2 -Heptylundecyl, isopropyl myristate, 2-octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, hexyldecyl dimethyloctanoate, ethyl laurate, hexyl laurate, N-lauroyl-L-glutamic acid-2 -Octyldodecyl ester, diisostearyl malate and the like.
As glyceride oil, acetoglyceride, triisooctanoic acid glyceride, triisostearic acid glyceride, triisostearic acid diglyceride, tetraisostearic acid diglyceride, triisopalmitic acid glyceride, tri-2-ethylhexanoic acid glyceride, monostearic acid glyceride, di- Examples include 2-heptylundecanoic acid glyceride and trimyristic acid glyceride.
Examples of the silicone oil include dimethylpolysiloxane, methylhydrogenpolysiloxane, tetramethyltetrahydrogencyclotetrasiloxane, and alkyl-modified silicone.
Examples of the higher alcohol include oleyl alcohol, lauryl alcohol, stearyl alcohol, isostearyl alcohol, and 2-octyldodecanol.
Examples of higher fatty acids include oleic acid, palmitic acid, myristic acid, stearic acid, and isostearic acid.

The surfactant is not particularly limited as long as it is usually used in cosmetics, and any surfactant can be used. Examples of the surfactant include an anionic surfactant, a cationic surfactant, a nonionic surfactant, and an amphoteric surfactant. These may be used alone or in combination of two or more as required. be able to.
Specific examples of anionic surfactants include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, carboxylates such as condensation of amino acids and fatty acids, alkyl sulfonic acids, and alkene sulfones. Acid salts, sulfonates of fatty acid esters, sulfonates of fatty acid amides, sulfonates of alkyl sulfonates and their formalin condensates, alkyl sulfate esters, secondary higher alcohol sulfates, alkyl and allyl ether sulfates Ester salts, fatty acid ester sulfates, fatty acid alkylolamide sulfates, polyoxyethylene alkyl sulfates, sulfate salts such as funnel oil, alkyl phosphates, ether phosphates, alkyl allyl ether phosphates A Dorin salts, such as N- acylamino acid-based active agents.
Cationic surfactants include long chain alkyltrimethylammonium salts, dilong chain alkyldimethylammonium salts, long chain alkyldimethylbenzylammonium salts, dipolyoxyethylene alkylmethylammonium salts, dipolyoxyethylene alkyl ether dimethylammonium salts, poly Alkyl quaternary ammonium salts such as oxypropylene methyl diethyl ammonium salt and aromatic quaternary ammonium salts, pyridinium salts such as alkyl pyridinium salts, imidazoline salts such as alkyl dihydroxyethyl imidazoline salts, N-acyl basic amino acid lower alkyl esters And amine salts such as alkylamine salts, polyamines, amino alcohol fatty acid derivatives and the like.
Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxy Ethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene cured Castor oil, polyoxyethylene hydrogenated castor oil fatty acid ester, polyoxyethylene Phytostanol ether, polyoxyethylene phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyethylene methylpolysiloxane copolymer, methylpolysiloxane cetylmethylpolysiloxane poly (oxyethylene oxy Propylene) methylpolysiloxane copolymer, poly (oxyethylene-oxypropylene) methylpolysiloxane copolymer, PEG-9 polydimethylsiloxyethyl dimethicone, lauryl PEG-9 polydimethylsiloxyethyl dimethicone, polyoxyethylene methylsiloxane poly Oxypropylene oleylmethylsiloxane / dimethylsiloxane copolymer, polyglycerin-modified organopolysiloxane alkanolamine , Sugar ethers, and sugar amides.
Examples of amphoteric surfactants include carbobetaine-type amphoteric surfactants such as alkyldimethylaminoacetic acid betaine, fatty acid amidopropyldimethylaminoacetic acid betaine, alkyldihydroxyethylaminoacetic acid betaine, and sulfobetaine-type amphoteric surfactants such as alkylsulfobetaine, N -Amidoamine type (imidazoline type) amphoteric surfactants such as fatty acid acyl-N-carboxymethyl-N-hydroxyethylethylenediamine salt, N-fatty acid acyl-N-carboxymethoxyethyl-N-carboxymethylethylenediamine di-salt, N- [ Amino acid type amphoteric surfactants such as 3-alkyloxy-2-hydroxypropyl] arginine salt, and alkyliminodicarboxylate type amphoteric surfactants.

  Organic ultraviolet absorbers include salicylic acid series such as homomenthyl salicylate, octyl salicylate, triethanolamine salicylate; paraaminobenzoic acid, ethyldihydroxypropylparaaminobenzoic acid, glycerylparaaminobenzoic acid, octyldimethylparaaminobenzoic acid, amyl paradimethylaminobenzoate PABA type such as 2-ethylhexyl paradimethylaminobenzoate; 4- (2-β-glucopyranosyloxy) propoxy-2-hydroxybenzophenone, dihydroxydimethoxybenzophenone, dihydroxydimethoxybenzophenone sodium disulfonate, 2-hydroxy- 4-methoxybenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfate, 2,2′-dihydroxy-4-methoxybenzopheno 2,4-dihydroxybenzophenone, 2,2′4,4′-tetrahydroxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2-hydroxy-4-N-octoxybenzophenone, and other benzophenones System: 2-ethylhexyl paramethoxycinnamate (also known as octyl paramethoxycinnamate), glyceryl mono-2-ethylhexanoate diparamethoxycinnamate, methyl 2,5-diisopropylcinnamate, 2,4,4 6-tris [4- (2-ethylhexyloxycarbonyl) anilino] -1,3,5-triazine, methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate, isopropyl dimethoxycinnamate paramethoxy cinnamate Acid ester mixture, p-methoxyhydrocinnamic acid di Cinnamic acid systems such as ethanolamine salts; benzoylmethane systems such as 2-phenyl-benzimidazole-5-sulfate, 4-isopropyldibenzoylmethane, 4-tert-butyl-4′-methoxydibenzoylmethane; 2-cyano -3,3-diphenylpropane-2-enoic acid 2-ethylhexyl ester (also known as octocrylene), dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, 1- (3,4-dimethoxyphenyl) -4,4 -Dimethyl-1,3-pentanedione, sinoxate, methyl-O-aminobenzoate, 2-ethylhexyl-2-cyano-3,3-diphenyl acrylate, 3- (4-methylbenzylidene) camphor, octyltriazone, 4- (3,4-dimethoxyphenylmethylene) -2, - dioxo-1-imidazolidine-propionic acid 2-ethylhexyl, these polymeric derivatives and silane derivatives and the like, may be blended singly or in combination depending on the purpose.

  Specific examples of alcohols include lower alcohols such as ethanol and isopropanol, glycerin, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, 1,3-butylene glycol, and erythritol. Examples include monohydric alcohols, sugar alcohols such as sorbitol, maltose, xylitol, maltitol, benzyl alcohol, and the like.

Examples of powders include inorganic powders, organic powders, metal soap powders, colored pigments, pearl pigments, metal powders, tar dyes, natural dyes, etc., and their particle shapes (spherical, needle-like, plate-like, etc.) Regardless of particle diameter (smoke, fine particles, pigment grade, etc.) and particle structure (porous, non-porous, etc.), any one can be used.
Specific examples of inorganic powders include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, calcium sulfate, magnesium sulfate, talc, mica, kaolin, sericite, muscovite, synthetic mica, phlogopite. , Mica, biotite, lithia mica, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, metal tungstate, hydroxyapatite, vermiculite, hydrite, bentonite, Examples include montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate and the like.
Organic powders include polyester powder, polypropylene powder, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, silk powder, divinylbenzene / styrene copolymer powder, vinyl resin powder, urea resin powder, phenol resin powder, fluorine Resin powder, acrylic resin powder, melamine resin powder, epoxy resin powder, polycarbonate resin powder, microcrystalline fiber powder powder, rice starch, lauroyl lysine and the like.
Examples of metal soap powder (surfactant metal salt powder) include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, and sodium zinc cetyl phosphate. Each powder is mentioned.
As colored pigments, inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, black iron oxide, carbon black, etc. Lake inorganic black pigments, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue, and tar dyes And those obtained by lacquering natural pigments and composite powders obtained by combining these powders.
Examples of the pearl pigment include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, titanium oxide-coated glass powder, and titanium oxide-coated colored mica. Examples of the metal powder include aluminum powder, copper powder, and stainless steel powder.
As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red 230, Red 401, Red 505, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Yellow 204, Yellow 401, Blue 1, Blue 2, Blue 201, Blue 404 , Green No. 3, Green No. 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, Orange No. 207 and the like. , Calsamine, bradylin, crocin and the like.
These powders may be used as they are, but these powders may be combined, or may be used after coating with a known surface treatment agent.
The said powder can be used 1 type or in combination of 2 or more type as needed.

  Examples of oil gelling agents include metal soaps such as aluminum stearate, magnesium stearate, zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, dextrin palmitate, Dextrin fatty acid esters such as dextrin stearic acid ester, dextrin 2-ethylhexanoic acid palmitic acid ester, sucrose fatty acid esters such as sucrose palmitic acid ester, sucrose stearic acid ester, benzylidene of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol Examples thereof include organically modified clay minerals such as derivatives, dimethylbenzyl dodecyl ammonium montmorillonite clay, and dimethyl dioctadecyl ammonium montmorillonite clay.

  Water-based thickeners and gelling agents include gum arabic, gum tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), starch (rice, corn, potato, wheat), alge colloid, tolanto gum Plant polymers such as locust bean gum, microbial polymers such as xanthan gum, dextran, succinoglucan, pullulan, animal polymers such as collagen, casein, albumin, gelatin, carboxymethyl starch, methylhydroxypropyl starch, etc. Starch-based polymers, methylcellulose, ethylcellulose, hydroxypropylmethylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, nito Cellulose, cellulose sulfate sodium, sodium carboxymethyl cellulose, crystalline cellulose, cellulose-based cellulose polymer, alginic acid-based polymers such as sodium alginate, propylene glycol alginate, polyvinyl methyl ether, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, etc. Vinyl polymer, polyoxyethylene polymer, polyoxyethylene polyoxypropylene copolymer polymer, acrylic polymer such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, bentonite, magnesium aluminum silicate, laponite Inorganic thickeners such as hectorite and silicic anhydride, polyethyleneimine, and cationic polymers. Also included are film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone.

Examples of the humectant include urea, hyaluronic acid, chondroitin sulfate, pyrrolidone carboxylate, and the like.
As preservatives and antibacterial agents, paraoxybenzoic acid esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, salicylic acid, coalic acid, sorbic acid, parachlorometacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride , Trichlorocarbanilide, photosensitizer, isopropylmethylphenol and the like.

  Antioxidants include tocopherol, butylhydroxyanisole, dibutylhydroxytoluene, and pH adjusters include lactic acid, lactate, citric acid, citrate, glycolic acid, succinic acid, tartaric acid, malic acid, potassium carbonate, hydrogen carbonate Sodium, ammonium bicarbonate, etc., chelating agents such as alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphate, hydroxyethane diphosphone, etc., and refreshing agents such as L-menthol, camphor, light cargo oil, peppermint Examples of anti-inflammatory agents such as oil and eucalyptus oil include allantoin, glycyrrhetinate, glycyrrhetin derivatives, tranexamic acid, and azulene.

  Beauty ingredients include whitening agents such as arbutin, glutathione, and yukinoshita extract, royal jelly, photosensitizer, cholesterol derivatives, cell activators such as calf blood extract, rough skin improver, nonyl acid wallenyl amide, nicotinic acid benzyl ester, Nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin , Blood circulation promoters such as γ-oryzanol, skin astringents such as zinc oxide and tannic acid, and antiseborrheic agents such as sulfur and thianthol.

  Vitamins such as vitamin A oil, retinol, retinol acetate, retinol palmitate, vitamin B2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, vitamin B6 such as pyridoxine hydrochloride, pyridoxine dioctanoate Vitamin C such as L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, dl-α-tocopherol-L-ascorbic acid diester dipotassium, calcium pantothenate, D -Pantothenic alcohols, pantothenyl ethyl ether, pantothenic acids such as acetyl pantothenyl ethyl ether, vitamin Ds such as ergocalciferol, cholecalciferol, nicotinic acid, benzyl nicotinate, Nicotinic acids such as succinic acid amide, dl-α-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, vitamin E such as dl-α-tocopherol succinate, vitamin P, biotin, etc. .

  Examples of amino acids include arginine, aspartic acid, cystine, cysteine, methionine, serine, leucine, isoleucine, tryptophan, alanine, glycine, proline and the like.

  As a manufacturing method of the unevenness correcting cosmetic of the present invention, it can be manufactured by a generally known method, and any manufacturing device may be used as long as it is a dispersion / emulsification device such as a general dispersion.

Examples of the dosage form of the unevenness correcting cosmetic of the present invention include a water-in-oil type, an oily type, an oil-in-water type, a multiple emulsion, and a powder type, and a water-in-oil type and an oily type are preferable. Examples of the form include liquid, semi-solid, solid and the like, and semi-solid to liquid are preferable. Applications include makeup cosmetics such as foundations, concealers, blushers, white powders, control colors, base materials, BB creams, eye colors, lipsticks, and other cosmetics, emulsions, creams, etc. It can be applied to skin care cosmetics such as serums, day creams and sunscreens.
Hereinafter, the present invention will be described in more detail with reference to examples. Note that these do not limit the present invention.

Examples 1 to 8 and Comparative Examples 1 to 3: Water-in-oil emulsification type concealer The water-in-oil emulsification type concealer having the composition shown in Table 1 below was prepared by the following production method, and the unevenness correction effect and the durability of the unevenness correction effect were maintained. The evaluation items of the goodness of the cosmetic to fit on the skin and the softness of the cosmetic film were evaluated and determined by the following methods, and the results are shown in Table 1.

(Note 1) KSG-18 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 2) KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 3) KF-9021 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 4) KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 5) KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 6) KSP-300 (Shin-Etsu Chemical Co., Ltd.)
(Note 7) KF-56 (Shin-Etsu Chemical Co., Ltd.)
(Note 8) Cosmall 168ARNV (Nisshin Oilio Co., Ltd.)
(Note 9) 3% surface treatment with KF-9901 (Shin-Etsu Chemical Co., Ltd.) (Note 10) KF-6028P (Shin-Etsu Chemical Co., Ltd.)
(Note 11) KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
(1) Components 10 to 14 and 16 are partly mixed with part of 8 with three rollers (2) Components 9 and 18 are heated and dissolved at 70 ° C., and (1) and components 1 to 7 and 8 are mixed. The remainder, 15, 16 and 17-19 are added and mixed uniformly.
(3) Components 20 to 23 are mixed and dissolved uniformly, then added to (2) and emulsified.
(4) (3) was defoamed and filled into a container to obtain a water-in-oil emulsified concealer.

(Evaluation Method 1) “Concavity and convexity correction effect” and “Durability of concave and convexity correction effect”
Applying 0.3 g of the water-in-oil emulsified concealer of the examples and comparative examples to the entire face, and analyzing the digital photographs taken before and after the application and over time (7 hours later) Thus, the number of pores with conspicuous openings was counted. For the measurement, Skin Analyzer
This was performed using a Clinical Suite RSA100 (manufactured by Inforward). The decrease rate of the number of pores is a comparison of the number of pores when the cosmetic is not applied and immediately after the application of the cosmetic. The larger the decrease rate of the number of open pores, the greater the unevenness correction effect. The evaluation of sustainability is a measurement evaluation of the number of pores after 7 hours of daily life after applying cosmetics. The average of the scores obtained from each panel was taken and judged based on the following criteria.
(Criteria)
(Concavity and convexity correction effect: pore reduction rate): (Score)
Reduction rate of the number of pores with noticeable opening is 40% or more: Reduction rate of the number of pores with noticeable opening of 5 points is 30% or more and less than 40%: Reduction rate of the number of pores with noticeable opening of 4 points is 20% or more and less than 30%: 3 Decrease rate of the number of pores with conspicuous open points is 10% or more and less than 20%: Decrease rate of the number of conspicuous pores with 2 open points is less than 10%: 1 point (Criteria)
(Durability of unevenness correction effect): (Score)
Number of pores less than 100% compared to immediately after application: 100% or more and less than 150% compared to immediately after application of 5 points: Number of pores of 150% or more and less than 200% compared to immediately after application of 4 points: 3 The number of pores is 200% or more and less than 250% compared to immediately after point application: The number of pores is 250% or more compared to immediately after application of two points: 1 point (criteria)
(Average score): (Judgment)
4.5 or more: ◎
3.5 or more and less than 4.5: ○
1.5 or more and less than 3.5: △
Less than 1.5: ×

(Evaluation Method 2) “Goodness of cosmetics on skin”, “Softness of cosmetic film”
20 panelists specializing in cosmetic evaluation applied and applied the water-in-oil emulsified concealers of the above-mentioned examples and comparative examples to the nose and lips around the pores and wrinkles. Each of the items of “goodness of fit” and “softness of the decorative film” was evaluated according to the following evaluation criteria, and the average of the scores obtained from each panel was taken and judged based on the following criteria.
[Evaluation criteria]
(Evaluation result): (Grade)
Very good: 6 points Good: 5 points Somewhat good: 4 points Normal: 3 points Somewhat bad: 2 points Bad: 1 point Very bad: 0 points [Criteria]
(Average score): (Judgment)
5.0 or more: ◎ Very good 3.5 or more to less than 5.0: ○ Good 1.5 or more to less than 3.5: △ Normal Less than 1.5: × Defect

(result)
As is apparent from the results in Table 1, the water-in-oil emulsification type concealers of Examples 1 to 8 have the unevenness correction effect, the durability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the cosmetic film. It was excellent.
On the other hand, the water-in-oil emulsified concealer of Comparative Example 1 from which the phenyl group-containing partially crosslinked organopolysiloxane polymer of component (a) is omitted has a decorative film that is hard and has a poor sustainability of the unevenness correction effect. Although there was no sloppy feeling, the effect of the unevenness correction was inferior due to the influence of the expansion and spread. Further, in Comparative Example 2 in which the film-forming silicone resin of component (b) was removed, the cosmetic did not fit well on the skin, and the unevenness correction effect could not be sufficiently obtained. The durability of the effect was inferior. Further, in Comparative Example 3 in which the powder having a refractive index of 1.4 to 1.8 of the component (c) is removed, the unevenness correction effect cannot be sufficiently obtained, and the softness of the decorative film is not sufficient. Furthermore, the sustainability of the unevenness correction effect was also inferior.

[Example 9]
Water-in-oil foundation (component) (%)
1. (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 3.0
2. (Dimethicone / vinyl dimethicone) 15% cross polymer
Cyclomethicone solution (Note 12) 5.0
3. Trimethylsiloxysilicate 50% cyclomethicone solution (Note 13) 3.0
4). Polyamide powder (average particle size 14μ) 2.0
5. Spherical methyl methacrylate cross-polymer powder (average particle size 30μ) 5.0
6). Diphenylsiloxyphenyl dimethicone (Note 7) 2.0
7). Methyltrimethicone 20.0
8). Cholesteryl hydroxystearate 5.0
9. Dimethicone-treated titanium oxide (Note 9) 10.0
10. Dimethicone-treated iron oxide (Note 9) 2.5
11. Mica 3.0
12 Distearyldimonium hectorite 1.0
13. Polysilicone-13 (Note 14) 1.5
14 Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Note 11) 2.5
15. Isotridecyl isononanoate 3.0
16. Glyceryl tri-2-ethylhexanoate 2.0
17. 2-ethylhexyl methoxycinnamate 5.0
18. Methyl paraoxybenzoate 0.2
19.1,3-Butylene glycol 5.0
20. Sodium chloride 0.3
21. Purified water remaining amount 22. Perfume appropriate amount (Note 12) KSG-15 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 13) KF-7712J (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 14) DOW CORNING TORAY FZ-2233 (Toray Dow Corning)

(Production method)
(1) A part of components 9 to 11 and 7 and a part of 14 are processed with three rollers.
(2) The component 12 is swollen by a part of 7 and a part of 14.
(3) Components 8 and 15 are heated and melted at 60 ° C., (1) and (2), the remainder of components 1 to 6 and 7, the remainder of 14 and 16 to 17 and 22 are added and mixed uniformly. .
(4) Components 18 to 21 are mixed and dissolved uniformly, then added to (3) and emulsified.
(5) (4) was defoamed and filled into a container to obtain a water-in-oil foundation.

(result)
The water-in-oil foundation of Example 9 was excellent in the unevenness correction effect, the durability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the cosmetic film.

[Example 10]
Water-in-oil base material (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 8.0
2. (Vinyl Dimethicone / Lauryl Dimethicone) Cross Polymer 30%
Triethylhexanoin solution (Note 15) 3.0
3. Trimethylsiloxysilicate 50% cyclomethicone solution (Note 3) 2.0
4). Lauroyl lysine 1.0
5. Polyalkyl acrylate powder (average particle size 10μ) 5.0
6). Diphenyl dimethicone (Note 16) 2.0
7). Spherical polyamide powder (average particle size 8μ) 5.0
8). Decamethylcyclopentasiloxane 20.0
9. Vaseline 2.0
10. Dimethicone-treated titanium oxide (Note 9) 5.0
11. Dimethicone-treated iron oxide (Note 9) 1.0
12 Synthetic phlogopite 3.0
13. Distearyldimonium hectorite 1.0
14 PEG-9 polydimethylsiloxyethyl dimethicone (Note 10) 1.5
15. Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Note 11) 2.5
16. Isotridecyl isononanoate 3.0
17. Glyceryl tri-2-ethylhexanoate 2.0
18. 2-ethylhexyl methoxycinnamate 5.0
19. Diethylaminohydroxybenzoyl hexyl benzoate 1.0
20. Methyl paraoxybenzoate 0.2
21. Glycerin 5.0
22. Sodium chloride 0.3
23. Purified water remaining amount 24. Perfume appropriate amount (Note 15) KSG-43 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Note 16) KF-54 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
(1) A part of components 10 to 12 and 8 and a part of 14 are processed with three rollers.
(2) Components 9 and 16 are heated and melted at 60 ° C., (1), the remainder of components 1 to 7 and 8, the remainder of 13, 14 and 15, 17 to 19 and 24 are added and mixed uniformly. .
(3) Components 20 to 23 are mixed and dissolved uniformly, then added to (2) and emulsified.
(4) (3) was degassed and filled into a container to obtain a water-in-oil base material.

(result)
The water-in-oil emulsion type base material of Example 10 was excellent in the unevenness correction effect, the sustainability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the cosmetic film.

[Example 11]
Water-in-oil BB cream (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 3.0
2. (Dimethicone / vinyl dimethicone) 15% cross polymer
Cyclomethicone solution (Note 12) 5.0
3. Trimethylsiloxysilicate 50% cyclomethicone solution (Note 3) 6.0
4). Spherical silica powder (average particle size 5μ) 1.0
5. Spherical polymethylsilsesquioxane powder (average particle size 6μ) 5.0
6). Diphenylsiloxyphenyl dimethicone (Note 7) 2.0
7). Spherical polyurethane powder (average particle size 15μ) 5.0
8). Isododecane 10.0
9. Decamethylcyclopentasiloxane 10.0
10. Macadamia nut fatty acid phytosteryl 2.0
11. Dimethicone-treated titanium oxide (Note 9) 8.0
12 Dimethicone-treated iron oxide (Note 9) 2.0
13. Sericite 3.0
14 Distearyldimonium hectorite 0.5
15. Stearalkonium hectorite 0.5
16. Lecithin 0.2
17. Sorisotan sesquiisothrea phosphate 0.5
18. Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Note 11) 2.5
19. Dimethylpolysiloxane (6 mm ² / s: 25 ° C.) 3.0
20. Mineral oil 2.0
21. Dextrin palmitate 1.0
22. 2-ethylhexyl methoxycinnamate 5.0
23. Octyl palmitate 2.0
24. Methyl paraoxybenzoate 0.2
25. Ethanol 5.0
26. Sodium chloride 0.3
27. Purified water remaining amount 28. Perfume

(Production method)
(1) A part of the component 9, a part of the parts 11 to 13, 16 to 17, and 18 are processed with three rollers.
(2) Components 10 and 20 to 21 are heated and melted at 60 ° C., and (1), the remainder of components 1 to 8 and 9 are added, the remainder of 14 to 15 and 18 are added, and 19 to 22 and 28 are added uniformly. To mix.
(3) Components 24 to 27 are uniformly mixed and dissolved, and then added to (2) and emulsified.
(4) (3) was defoamed and filled into a container to obtain a water-in-oil BB cream.

(result)
The water-in-oil emulsification type BB cream of Example 11 was excellent in the unevenness correction effect, the sustainability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the cosmetic film.

[Example 12]
Water-in-oil sunscreen (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 3.0
2. (Dimethicone / vinyl dimethicone) 15% cross polymer
Cyclomethicone solution (Note 12) 2.0
3. Trimethylsiloxysilicate 50% cyclomethicone solution (Note 13) 3.0
4). Spherical (styrene / DVB) copolymer powder (average particle size 6 μ) 1.0
5. Spherical polystyrene powder (average particle size 6μ) 5.0
6). Diphenylsiloxyphenyl dimethicone (Note 7) 2.0
7). Dimethylpolysiloxane (2 mm ² / s: 25 ° C.) 20.0
8). Dimer linoleic acid (phytosteryl / isostearyl /
Cetyl / stearyl / behenyl) 1.0
9. Dimethicone-treated titanium oxide (Note 9) 5.0
10. Dimethicone-treated zinc oxide (Note 9) 5.5
11. Sericite 3.0
12 Distearyldimonium hectorite 1.0
13. PEG-9 polydimethylsiloxyethyl dimethicone (Note 10) 1.5
14 Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (Note 11) 2.5
15. Isotridecyl isononanoate 3.0
16. Tri (Capryl / Capric Acid) Glyceryl 2.0
17. 2-Ethylhexyl paramethoxycinnamate 5.0
18. Diethylaminohydroxybenzoyl hexyl benzoate 2.0
19. Phenylbenzimidazolesulfonic acid 2.0
20. Triethanolamine 1.7
21. Phenoxyethanol 0.2
22. Dipropylene glycol 5.0
23. Sodium chloride 0.3
24. Purified water remaining amount 25. Perfume

(Production method)
(1) A part of components 9 to 11 and 7 and a part of 13 are processed with three rollers.
(2) Components 8 and 15 are heated and melted at 70 ° C., (1), the remainder of components 1 to 6 and 7, the remainder of 12, 13 and 14, 16 to 18, 25 are added and mixed uniformly. .
(3) Components 19 to 24 are uniformly mixed and dissolved, then added to (2) and emulsified.
(4) (3) was defoamed and filled into a container to obtain a water-in-oil sunscreen.

(result)
The water-in-oil type sunscreen of Example 12 is a water-in-oil type sunscreen excellent in unevenness correction effect, durability of the unevenness correction effect, good fit of the cosmetic on the skin, and softness of the cosmetic film. there were.

[Example 13]
Oily solid blusher (ingredient) (%)
1. (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 3.0
2. (Dimethicone / vinyl dimethicone) 15% cross polymer
Cyclomethicone solution (Note 12) 5.0
3. Trimethylsiloxysilicic acid (Note 17) 3.0
4). Barium sulfate 2.0
5. Acrylates Copolymer Solution (Note 18) 5.0
6). Diphenylsiloxyphenyl dimethicone (Note 7) 2.0
7). Light isoparaffin 10.0
8). Vaseline 5.0
9. Dimethicone-treated iron oxide (Note 9) 1.5
10. Red 226 0.5
11. Bismuth oxychloride 5.0
12 Polyethylene wax 3.0
13. Candelilla Row 1.0
14 Propylene glycol dicaprate 15.0
15. Polyglyceryl-2 triisostearate 7.0
16. 2-ethylhexyl methoxycinnamate 7.0
17. Dimethylyl polysiloxane (10 mm ² / s: 25 ° C.) 10.0
18. Haze-like dimethylsilylated silica powder (average particle size 7 nm) 0.1
19. Phenoxyethanol 0.2
20. Perfume appropriate amount (Note 17) SR1000
(Note 18) KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production method)
(1) A part of components 8, 12 to 13, 14 and part of 17 are uniformly mixed and dissolved at 100 ° C.,
Ingredients 9 to 10 and 19 are added and mixed, and the mixture is processed with three rollers.
(2) Dissolve component 3 in 7 at room temperature.
(3) The remaining parts of (1) and (2), components 1-2, 4-6, and 14, 15 to 16, and 17 and 18 and 20 are uniformly mixed and dissolved at 90 ° C.
(4) (3) was defoamed and filled into a dish-like container to obtain an oily solid blusher.

(result)
The oil-based solid blusher of Example 13 was excellent in the unevenness correction effect, the durability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the cosmetic film.

[Example 14]
Oil-based solid base for eyes (component) (%)
1. (Dimethicone / Phenyl vinyl dimethicone) Cross polymer 15%
Diphenylsiloxyphenyl trimethicone solution (Note 1) 3.0
2. (Dimethicone / vinyl dimethicone) 15% cross polymer
Cyclomethicone solution (Note 12) 5.0
3. Trimethylsiloxysilicate 50% cyclomethicone solution (Note 13) 1.0
4). Acrylates Copolymer (Note 18) 5.0
5. Diphenylsiloxyphenyl dimethicone (Note 7) 2.0
6). Methyltrimethicone 20.0
7). Stearic acid hydrogenated castor oil 2.0
8). Dimethicone-treated titanium oxide (Note 9) 1.5
9. Dimethicone-treated iron oxide (Note 9) 0.5
10. Boron nitride 5.0
11. Polyethylene wax 3.0
12 Candelilla Row 1.0
13. Carnauba 1.0
14 Propylene glycol dicaprate 10.0
15. Liquid paraffin 7.0
16. 2-ethylhexyl methoxycinnamate 7.0
17. Dimethylyl polysiloxane (20 mm ² / s: 25 ° C.) 10.0
18. Dimethylsilylated silica 0.1
19. Methyl paraoxybenzoate 0.2
20. Perfume

(Production method)
(1) A part of components 7, 11 to 13 and 14 and a part of 17 are uniformly mixed and dissolved at 100 ° C., components 8 to 9 and 19 are added and mixed, and the mixture is processed with three rollers.
(2) (1), the remainder of components 1-6, 10, 14, and the remainder of 15-16, 17 and 20 are uniformly mixed and dissolved at 90 ° C.
(3) (2) was defoamed and filled in a jar container to obtain an oily solid mold base.

(result)
The base for the oil-based solid eye of Example 14 was excellent in the unevenness correction effect, the durability of the unevenness correction effect, the good fit of the cosmetic on the skin, and the softness of the decorative film.

Claims (9)

The following components (a) to (c);
(A) A phenyl group-containing partially crosslinked organopolysiloxane polymer (b) a film-forming silicone resin (c) a powder having a refractive index of 1.4 to 1.8 is blended.   Furthermore, the uneven | corrugated correction | amendment cosmetics of Claim 1 which mix | blend a phenyl group containing non-crosslinked organopolysiloxane as a component (d).   Furthermore, a volatile oil agent is mix | blended as a component (e), The uneven | corrugated correction | amendment cosmetics of Claim 1 or 2 characterized by the above-mentioned.   The component (b) film-forming silicone resin is one or more selected from trimethylsiloxysilicic acid and an acrylic-silicone graft copolymer. The uneven | corrugated correction cosmetics as described.   The component (d) phenyl group-containing non-crosslinked organopolysiloxane is one or more selected from diphenyldimethicone, diphenylsiloxyphenyltrimethicone, trimethylpentaphenyltrisiloxane, phenyltrimethicone and phenylmethicone. The unevenness correction cosmetic according to any one of claims 1 to 4.   6. The unevenness-correcting cosmetic according to claim 1, wherein the powder of component (c) having a refractive index of 1.4 to 1.8 has an average particle diameter of 1 to 50 [mu] m.   The powder of component (c) having a refractive index of 1.4 to 1.8 is polyamide, polymethylsilsesquioxane, silicone elastomer, cross-linked silicone / network silicone copolymer, polystyrene, polyurethane, polyethylene, crystalline cellulose The unevenness correcting cosmetic composition according to claim 1, wherein the cosmetic composition is one or more selected from polymethacrylic acid ester and polyacrylic acid ester.   Furthermore, paste oil is mix | blended as a component (f), The uneven | corrugated correction cosmetics in any one of Claims 1-7 characterized by the above-mentioned.   The unevenness correction cosmetic according to claim 1, wherein the unevenness correction cosmetic has an oily type or a water-in-oil type.