JP2023097497A - Cosmetic - Google Patents

Abstract

To provide a cosmetic that has a skin tone correcting effect without paleness, yet has a luster without glare, and can quickly create a uniform makeup film without user intervention.SOLUTION: The cosmetic according to the present invention contains: plate-like powders of a specific color tone, containing iron and coated with titanium oxide, with an average particle size of 3 to 30 μm; an oil solution with a refractive index of 1.455 or higher; and one or more selected from phospholipids, 2-methacryloyloxyethylphosphorylcholine (MPC) group-containing polymers, ceramides, and N-acylamino acids and salts thereof.SELECTED DRAWING: None

Description

TECHNICAL FIELD The present invention relates to liquid cosmetics.

BACKGROUND ART Conventionally, make-up cosmetics have been used mainly for the main purposes of concealing skin surface irregularities such as skin pores and wrinkles and color unevenness, as well as imparting luster to make the skin look beautiful. In the past, high-brightness plate-like powders and oils that reflected strong light were used to make the skin look even and shiny. Cosmetics containing a large amount of them have the effect of imparting luster to the skin, but have the drawback of giving an unnatural impression in a technically and angle-dependent manner.
In order to solve such an unnatural finish problem, for example, a complementary color or A composition for adjusting skin color has been proposed, which is characterized by containing a substance having a color gamut near complementary colors as transmitted interference light (see, for example, Patent Document 1). According to this method, it is possible to improve color tone problems without dulling the skin.
On the other hand, by heat-treating iron-containing synthetic mica at a specific temperature as a powder with a color close to the natural skin color, it is possible to achieve a bright red appearance with lightfastness that has never been seen in conventional synthetic mica. In addition, it has been found that a novel synthetic mica can be obtained that exhibits excellent UV-blocking ability. 2).
In addition to this, there have been proposed skin cosmetics containing a specific powder whose color changes little depending on the observation direction of the reflected light of the interference color and an iron oxide/titanium oxide sintered colored pigment (for example, See Patent Document 3). According to this method, it is proposed that a cosmetic can be obtained in which the hue of the skin can be changed depending on the combination while imparting a sense of transparency, and at the same time, the makeup does not deteriorate due to sebum.
Incorporating powder into cosmetics poses the problem of feeling sticky or heavy when applied, but in order to solve such problems, synthetic phlogopite, synthetic phlogopite iron, and an oil agent with a specific structure are used. A proposal has been made to give a smooth touch by combining them. (See Patent Document 4, for example)

JP-A-8-081332 JP-A-6-009210 JP-A-11-43414 JP 2013-234133 A

However, in the technique of Patent Document 1, since the surface has gloss, the covering effect becomes unnatural, and the glossy feeling is technically unfavorable in some cases. In addition, in the technique of Patent Document 2, the glossiness is high, and the angle-dependent difference in glossiness may give an unnatural impression. Furthermore, in the technique of Patent Document 3, the cohesiveness of the powder is high, and in Patent Document 4, the oil agent slides over the skin, making it difficult to quickly finish a uniform cosmetic film on the skin in some cases. .
As described above, in the prior art, it is not possible to cover color unevenness with reflected light that approximates the natural luster of the skin. However, the present inventors attempted to provide a cosmetic that satisfies these effects at the same time.
The present invention has been made in view of the above circumstances, and its main purpose is to have the effect of correcting the skin color with a moderate gloss without glare, without the feeling of a pale white film concealing, regardless of the user. To provide a cosmetic capable of quickly forming a uniform cosmetic film.

As a result of intensive studies to solve the above problems, the present inventors have found that the color tone is adjusted with iron oxide, and plate-like powder coated with titanium oxide, an oil agent with a high refractive index, and a biosimilar component with high affinity for the skin. By containing, the above problem is solved by being able to quickly and uniformly finish the cosmetic film while exhibiting a color unevenness correcting effect without a feeling of hiding a pale white film, while giving an appropriate gloss without a sense of skill. and completed the present invention.

That is, the present invention is as follows.
[1] the following components (A) to (C);
(A) Plate-like powder containing iron and coated with titanium oxide and having an average particle size of 3 to 30 μm (B) Oil agent having a refractive index of 1.455 or more at 24° C. (C) Phospholipid, 2-methacryloyloxy containing one or more selected from ethylphosphorylcholine (MPC) group-containing polymers, ceramides, and N-acylamino acids and salts thereof, and
The component (A) has luster and is measured using a spectrocolorimeter at an incident angle of −45° and an acceptance angle of 0°, and is a colorimetric value defined by the CIE1976L*a*b* color system. L* (lightness), C* (chroma), and h (hue) are cosmetics having 60<L*<83, 12<C*<32, and 40<h<76.
[2] 0.05 g of the component (A) is applied per unit area of [5 × 8] cm ² to the adhesive surface of the transparent adhesive tape, and the angle of incidence is -45 using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a black non-reflective background at a wavelength of 450 nm and 650 nm, the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity at a light receiving angle of 0 degrees [I (O) ] ratio [I(45)]/[I(O)] is 1 to 4 in all cases.
[3] The cosmetic according to [1] or [2], wherein the coating amount of titanium oxide in component (A) is 5 to 20% by mass.
[4] The cosmetic according to any one of [1] to [3], wherein the component (A) is synthetic phlogopite.
[5] The cosmetic according to any one of [1] to [4], wherein the component (B) is one or more selected from ultraviolet absorbers, phenyl-modified silicones, and tridecyl trimellitate. is the fee.
[6] The cosmetic composition according to any one of [1] to [5], further comprising, as a component (D), hydrophobized fine metal oxide particles.
[7] The cosmetic according to any one of [1] to [6], further comprising silica as component (E).
[8] The cosmetic according to any one of [1] to [7], wherein the mass content ratio of the components (A) and (C) is (A)/(C) = 0.5 to 100. is.
[9] 0.05 g of the component (A) is applied per unit area of [5 × 8] cm ² to the adhesive surface of the transparent adhesive tape, and the incident angle is -45 using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a black non-reflective background at 45 degrees, the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is [I (45)] (450 nm ): The cosmetic according to any one of [1] to [8], wherein [I(45)](650 nm)=1.5:1 to 1:3.
[10] The cosmetic according to any one of [1] to [9], wherein the cosmetic is an emulsified cosmetic.

The cosmetic of the present invention comprises iron-containing plate-like powder coated with titanium oxide and having an average particle size of 5 to 15 μm, an oil having a refractive index of 1.460 or more, a phospholipid, and 2 - By containing one or more selected from methacryloyloxyethylphosphorylcholine (MPC) group-containing polymers, ceramides, and N-acylamino acids and salts thereof, while having a skin color correction effect without paleness, To provide a cosmetic having glossiness without glare, and capable of uniformly finishing a cosmetic film at a high speed.

0.05 g of component (A) per unit area of [5 × 8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and blackened at an incident angle of -45 degrees using a goniospectrophotometer D65 light source. Explanation of the angles of the reflection intensity [I(45)] at a light receiving angle of 45 degrees and the reflection intensity [I(O)] at a light receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm when the reflection intensity is measured using a non-reflective background Component (A) Titanium oxide coating Synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide 11-14%, tin oxide coating) Reflection intensity comparison at light receiving angles of 0° and 45° Component (A) Titanium oxide, iron oxide coating mica: (*1) RELIEF COLOR BEIGE (manufactured by JGC Catalysts and Chemicals) (titanium oxide content 14.5-17.5%, iron oxide content 1.5-5.5%, silica content 7-10%) Reflection intensity comparison between 0° and 45° acceptance angles Titanium oxide coating Synthetic phlogopite (*2) HELIOS R10R (manufactured by Topy Industries) (average particle size 11-16 μm, titanium oxide 40-55%, tin oxide coating) Reflection intensity comparison between 0° and 45° light receiving angles Titanium oxide 25-40% Iron oxide 2-7% Coated mica (*3) Blondiee Metallic Gold N-2000S (manufactured by CQV) (average particle size 9-45μm) Reflection intensity comparison between 0° and 45° acceptance angles Mica coated with 25-40% iron oxide (*4) BLONDIEE SUPER BRONZE N-2220S (manufactured by CQV) (average particle size 9-45μm) Reflection intensity comparison between 0° and 45° acceptance angles

Preferred embodiments of the present invention are described in detail below. However, the present invention is not limited to the following preferred embodiments, and can be freely modified within the scope of the present invention. In this specification, percentages are indicated by mass (mass/mass %) unless otherwise specified. Moreover, the upper limit (or less) and lower limit (or more) of each numerical range (to) can be arbitrarily combined as desired. Furthermore, the "average particle size" in this specification is measured by observing the surface state using a scanning electron microscope (manufactured by JEOL, JSM-7800prime) and using an image analyzer (Luzex AP, manufactured by Nireco). It is the value (median diameter D50) obtained by , and indicates the major diameter of the particles.

<Component (A)>
Component (A) used in the present invention is plate-like powder containing iron and coated with titanium oxide and having an average particle size of 3 to 30 μm. The surface of a plate-like powder base is coated with titanium oxide, and the base plate-like powder is not particularly limited. For example, mica, sericite, synthetic mica such as (fluoride/hydroxide/oxidation)/(Mg/K/silicon), calcined sericite, talc, calcined talc, aluminum silicate, magnesium silicate, Aluminum magnesium silicate, glass powder, cleaved talc, silicic anhydride, aluminum oxide, kaolin, boron nitride, barium sulfate, aluminum oxide, bismuth oxychloride, inorganic powder such as fish scale foil, cellulose, polyethylene terephthalate/aluminum/epoxy lamination powder, polyethylene terephthalate/polyolefin laminated film powder, polyethylene terephthalate/polymethyl methacrylate laminated film powder, and the like, and these may be used alone or in combination of two or more. Brilliance is to impart a good feeling of brilliance to the skin after use, and is not angle dependent at all. It gives a glossy feeling. Appropriate luster is required, unlike the matte finish of the particulate composite powder of similar composition for the purpose of blocking ultraviolet rays.
The plate-like powder containing iron and coated with titanium oxide includes the plate-like powder of the base material coated with titanium oxide and iron oxide and/or iron hydroxide, or the plate-like powder to which iron and titanium are added. It is particularly limited to those precipitated as iron oxide and/or iron hydroxide and titanium oxide on the surface of the plate-like powder of the base, or to the plate-like powder containing iron in the base coated with titanium oxide. do not. Specifically, iron oxide-coated mica titanium, titanium oxide-iron oxide-coated synthetic mica, titanium oxide-coated synthetic phlogopite iron oxide, titanium oxide-iron oxide-coated silica, titanium oxide-iron oxide-coated glass powder, titanium oxide-iron oxide-coated tabular sulfuric acid barium, titanium oxide, iron oxide coated plate-like aluminum oxide, and the like. Among them, the matrix is preferably mica, sericite, synthetic phlogopite, or talc, more preferably synthetic phlogopite, and still more preferably synthetic phlogopite iron. This base is preferred because it is more excellent in glossiness without glare and in the speed at which the cosmetic film is uniformly finished.
Furthermore, among them, a composite powder coated with a colored layer having a refractive index of 2 or more as a plate-like coating layer, wherein the refractive index is 1.30 to 1.99 between the colored layers or in the outermost layer It may be a powder having an inorganic layer of The inorganic layer is preferably made of one or more selected from silicic anhydride, aluminum oxide, and tin oxide.

The component (A) used in the present invention may be coated with titanium oxide by a known coating method. For example, the base powder is suspended in a dilute titanic acid aqueous solution and heated to 70 to 100° C. to hydrolyze the titanium salt to precipitate hydrated titanium oxide particles on the powder. It can be produced by firing at a high temperature of 1000°C. The surface may be coated with an acid before the reaction. The amount of surface treatment of each metal contained in the sample (powder) was determined by ICP (Inductively Coupled Plasma; ARCOS (Germany Spectro)) emission analysis of a sample prepared using a general method. It can be obtained by measurement. When coating titanium oxide, it is more preferable to coat with tin oxide as a binder for titanium oxide. Although the amount of tin oxide is not particularly limited, a preferable example is one coated with 0.5 to 2.0%.
A known coating method may be used for coating the iron oxide of the component (A) used in the present invention. For example, as an example, a caustic soda aqueous solution is heated to 30 to 35° C. to disperse powder particles, an aqueous solution containing ferric sulfate is added and stirred, and reacted at 90° C. for about 2 hours. The obtained powder is washed with water, neutralized and dried. After pulverizing, it can be obtained by firing the raw material particles and iron oxide or hydroxide (for example, about 750 to 900° C. for about 1 to 3 hours).
The synthetic mica powder containing the iron element in the crystal structure of the component (A) powder can be produced by a melt synthesis method, or a known melt synthesis method. In order to produce synthetic mica containing elemental iron by a melt synthesis method, raw materials such as potassium silicofluoride, magnesium oxide, aluminum oxide, silicon dioxide and iron oxide are mixed in a predetermined number of moles and heated at 1400°C to 1600°C. After being melted, it is cooled and crystallized, and the resulting crystal mass is pulverized by a known pulverization method, treated with stirring in an acid aqueous solution, and then dehydrated, washed and dried. This dry powder can be heat-treated at 700 to 1200° C. to obtain a synthetic phlogopite iron powder containing an iron element in the crystal structure. Component (A) includes those in which the synthetic phlogopite iron powder is further coated with a metal oxide such as titanium oxide.

The component (A) used in the present invention preferably provides both specular reflected light and diffuse reflected light and has a small difference in reflection intensity. In that case, it is preferable because it does not exhibit excessive luster that may be perceived as glare. 0.05 g of component (A) per unit area of [5 × 8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and blackened at an incident angle of -45 degrees using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a non-reflective background, the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity [I (O)] at a light receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm Both [I(45)]/[I(O)] are preferably in the range of 1-5, more preferably in the range of 1-3. This range is more preferable because it is excellent in luster without excessive luster and glare, and is excellent in the speed at which the cosmetic film is uniformly finished. Furthermore, the ratio of the reflection intensity [I (45)] at the light receiving angle of 45 degrees at the wavelengths of 450 nm and 650 nm is [I (45)] (450 nm): [I (45)] (650 nm) = 3: 2 to 1: 3 is preferred, 1:1 to 2:5 is more preferred, and 1:1 to 1:2 is even more preferred. Within this range, the effect of correcting skin color without bluishness is more excellent, which is more preferable. Such a component (A) is a commercially available product, for example, a glittering powder obtained by coating red iron oxide and titanium oxide on a mica matrix is RELIEF COLOR BEIGE, RELIEF COLOR PINK (manufactured by Nikki Shokubai Kasei Co., Ltd.). , DUOCROME YR (manufactured by BASF) and the like. Further, as a developed product, as shown in FIG. 2, a titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide 11-14%, tin oxide coating) can be mentioned more preferably.

The average particle size of component (A) used in the present invention is 3 to 30 μm. 5 to 25 μm is preferred, 5 to 20 μm is more preferred, and 5 to 15 μm is even more preferred. Within this range, it spreads evenly and selectively on the skin hillocks, does not emphasize unevenness, has a high skin color correction effect without paleness, and imparts a glossy feeling without glare in a well-balanced manner. It is more preferable because it can

The color tone of the component (A) used in the present invention is the colorimetric value L defined by the CIE1976L*a*b* color system when measured using a spectrocolorimeter at an incident angle of -45° and a light receiving angle of 0°. * (lightness), C* (chroma), and h (hue) are 60<L*<83, 12<C*<32, and 40<h<76. Preferably, 60<L*<75, 17<C*<25, 50<h<70, more preferably 68<L*<75, 18<C*<25, 55<h<70. is. When the component (A) falls within these color tones, it is more preferable because it has an excellent effect of correcting skin color without paleness, and provides a color tone that is suitable for the standard skin color of yellow people.

Titanium oxide in the component (A) used in the present invention is not particularly limited, but is preferably 5 to 25%, more preferably 5 to 22%, and still more preferably 5 to 20%. can give
The content of iron in the component (A) used in the present invention is not particularly limited as long as it falls within the specified hue. In the case of synthetic phlogopite iron in which titanium oxide is coated on a plate-like powder containing iron in the matrix, the preferable lower limit in terms of iron oxide Fe ₂ O ₃ is preferably 8% or more. % or more, more preferably 10% or more, and a suitable upper limit is preferably 25% or less, more preferably 20% or less, more preferably 17% or less, more preferably 15% or less, and 14% or less. is more preferred. A specific commercially available product is PDM-FE (manufactured by Topy Industries, Ltd.).
Titanium oxide and iron oxide respectively coated on the surface of the plate-like powder of the base, iron and titanium are added to the surface of the plate-like powder of the base and iron oxide and/or iron hydroxide, titanium oxide or a mixture thereof However, in any case, the iron oxide Fe ₂ O ₃ equivalent content in the component (A) is set to a preferable amount with respect to the amount of titanium oxide. , Iron oxide mass/titanium oxide mass=0.05 to 2.0 is preferable, and there is no particular limitation as long as the color tone is within the specified range.

Since the component (A) used in the present invention has the spectral reflection characteristics, the reflection intensity does not change depending on the angle, and it does not give an impression of skill, and can impart a skin color correction effect. In addition, a blue light cut effect can be imparted by the properties of the contained titanium oxide.

The content of component (A) used in the present invention is not particularly limited, but the lower limit is preferably 0.2% or more, more preferably 1% or more. The upper limit is preferably 20% or less, more preferably 15% or less, still more preferably 10% or less, and even more preferably 5% or less. The range is preferably 0.2 to 10%, more preferably 1 to 8%, even more preferably 1 to 5%. Within this range, it is possible to obtain an appropriate effect of correcting color unevenness and an effect of quickly finishing a uniform film without agglomeration.

<Component B>
The component (B) oil used in the present invention has a refractive index of 1.455 or more at 24°C. As long as it satisfies this condition and is usually used in cosmetics, it can be used without particular restrictions regardless of its origin, such as animal oil, vegetable oil, or synthetic oil. Those that are liquid or pasty at 25° C. are preferred.

The refractive index of component (B) used in the present invention is not particularly limited as long as it is measured using a commercially available refractometer. For example, a handheld refractometer R-5000 (manufactured by Atago Co.) can be used. The measurement method may be carried out according to the description of the handheld refractometer R-5000 or the like. That is, a measurement sample is filled into a glass bottle having an outer diameter of 45 mm, an inner diameter of 38 mm, and a height of 82 mm so as not to create an air space, and the bottle is covered and left in a constant temperature bath at 24° C. overnight. The next day, the refractive index can be obtained by reading the measured value with a refractometer.

The lower limit of the refractive index of the component (B) used in the present invention is 1.455 or more, preferably 1.458 or more, and 1.47 or more from the viewpoint of imparting an appropriate gloss without becoming technical. More preferably, 1.550 or less is preferable.

Examples of the component (B) oil agent used in the present invention that satisfy the above conditions include polybutene, heavy liquid isoparaffin, liquid lanolin acetate, diphenyl dimethicone, diphenyldisiloxyphenyl trimethicone, tridecyl trimellitate, dimer acid ester, and methoxysilica. Ethylhexyl formate, diglyceryl triisostearate, trimethylolpropane triisostearate and the like can be mentioned. These commercially available products include purified polybutene HV-100F (SB) (manufactured by Japan Natural Products Co., Ltd.) (refractive index 1.492), polybutene 35R (refractive index 1.489), polybutene 2000H (refractive index 1.503) ( Idemitsu Kosan Co., Ltd.), Pearl Ream 18 (refractive index 1.491), Pearl Ream 24 (refractive index 1.496), Pearl Ream 46 (refractive index 1.502) (manufactured by NOF Corporation), ACELAN SP (refractive index 1.485) (manufactured by Croda Japan), KF-54 (refractive index 1.502), KF-56 (refractive index 1.455) (manufactured by Shin-Etsu Chemical Co., Ltd.), LIPONATE TDTM (refractive index 1.480) ( LIPO CHEMICALS INC.), LUSPLAN DA-DD-IS (refractive index 1.472), PLANDOOR-S (refractive index 1.479) (manufactured by Nippon Fine Chemical Co., Ltd.), ethylhexyl methoxycinnamate (refractive index 1.508 ) (BASF) Eldew PS-203 (refractive index 1.479), Eldew PS-306 (refractive index 1.480) (manufactured by Ajinomoto Co.), refined olive oil (refractive index 1.465), macadamia nut oil (refractive index 1 .465), Saracos 6318V (refractive index 1.463), Cosmol 222 (refractive index 1.458), Cosmol 43V (refractive index 1.463) (manufactured by Nisshin OilliO Co., Ltd.), and the like.

The structure of the oil (B) used in the present invention is preferably ethylhexyl methoxycinnamate, diphenyl dimethicone, diphenyldisiloxyphenyl trimethicone, tridecyl trimellitate, and ethylhexyl methoxycinnamate, diphenyl dimethicone, diphenyldisiloxyphenyl trimethicone. Methicone is more preferred. The component (B) used in the present invention can impart a uniform moist gloss of the component (B) to the surface of the uniform cosmetic film of the component (A) with a glossy feeling without glare. It is more preferable because it helps to quickly finish a uniform film without skidding.

The content of the component (B) used in the present invention is preferably 1 to 20%, more preferably 2 to 17%, even more preferably 2 to 15%, from the viewpoint of imparting an appropriate gloss and quickly finishing a uniform film. .

<Component C>
Component (C) used in the present invention is one or more selected from phospholipids, 2-methacryloyloxyethylphosphorylcholine (MPC) group-containing polymers, ceramides, N-acylamino acids and salts thereof.
The phospholipid used as the component (C) in the present invention is a lipid having a phosphate group regardless of animal, vegetable, hydrogenated, non-hydrogenated, PC (phosphatidylcholine) purity, and the like. Although the composition is not particularly limited, examples include those containing phosphatidylcholine (PC), phosphatidylinositol (PI), phosphatidylethanolamine (PE), phosphatidic acid, phosphatidylserine, phosphatidylglycerol, sphingomyelin, and lysophosphatidylcholine. . In particular, one containing phosphatidylcholine (PC) is preferable, but it is not particularly limited. Specifically, commercial products such as Ajinomoto lecithin (manufactured by Ajinomoto Co., Inc.), which is a soybean phospholipid, and Recinol S-10 and S-10E (both manufactured by Nikko Chemicals Co., Ltd.), which are hydrogenated soybean lecithins, can be mentioned. can.
The 2-methacryloyloxyethylphosphorylcholine (MPC) group-containing polymer as the component (C) used in the present invention is one or more selected from homopolymers of MPC and copolymers of MPC and hydrophobic monomers. is. The molecular weight is 5000 or more, more preferably 10000 or more, and in the case of a copolymer with a hydrophobic monomer, the type of the hydrophobic monomer is not particularly limited, but is styrene, acrylic acid ester, or methacrylic acid ester. The molar ratio of MPC to hydrophobic monomer is preferably in the range of 50:50 to 97:3 from the viewpoint of non-stickiness. More specific examples of the MPC homopolymer and the copolymer of MPC and a hydrophobic monomer, which are the component (C) used in the present invention, include Lipidure-HM and Lipidure-HM as MPC homopolymers. -500, (all manufactured by NOF Corporation), as copolymers of MPC and butyl methacrylate, Lipidure-PMB, Lipidure-A, Lipidure-B, Lipidure-NA, Lipidure-NR (all NOF stock manufactured by a company).
In the N-acylated amino acid and its salt as the component (C) used in the present invention, the hydrogen atom of the amino group of the amino acid is substituted with an acyl group, and the acyl group has 1 to 20 carbon atoms and is saturated or unsaturated. are linear or cyclic. Examples include N-acetylglutamic acid, N-lauroylglutamic acid, N-myristylalanine, NN-oleylthreonine, N-cinnamoylglycine, N-nicotinoylglutamic acid and the like. Salts include sodium salts, potassium salts, and triethanolamine salts.
Ceramides as component (C) used in the present invention include ceramides and derivatives thereof, and may be natural extracts or synthetic products. Generally, it is not limited as long as it can be used in cosmetics, but for example, one or more long-chain linear and/or branched alkyl or alkenyl groups in the molecule, at least two or more hydroxyl groups, and one or more or a derivative in which a phosphatidylcholine residue or sugar residue is bound to the hydroxyl group of the nonionic amphiphilic substance having an amide group (and/or amino group) of A series of ceramides that Specifically, natural ceramides such as sphingosine, phytosphingosine and their long-chain fatty acid amides such as ceramide 1, ceramide 2, ceramide 3, ceramide 3B, ceramide 4, ceramide 5, ceramide 6, ceramide 6I, and ceramide 6II; Sphingophospholipids such as sphingosine, sphingomyelin which is a phospholipid derivative of phytosphingosine, and phytosphingomyelin; glycosphingolipids such as cerebrosides and gangliosides which are glycosides thereof; and glycosphingolipids such as phytosphingolipids.
Among these, phospholipids and ceramides are more preferred, and phospholipids are even more preferred, in terms of glossiness without glare and the speed at which the cosmetic film is uniformly finished.

The content of component (C) used in the present invention is preferably 0.01 to 8%, more preferably 0.1 to 7%, still more preferably 0.1 to 6%. Within this range, it is possible to enhance the speed at which the cosmetic film is uniformly finished while making the most of the non-glare luster of the component (A), which is more preferable.

The mass content ratio of the component (A) and the component (C) from the point that the stickiness can be suppressed while increasing the speed at which the cosmetic film of the component (A) is uniformly finished by the component (C) used in the present invention. is preferably (A) / (C) = 0.5 to 100, more preferably (A) / (C) = 0.5 to 50.0, still more preferably (A) / (C) = 0.5 ~30.0, more preferably (A)/(C) = 1.0 to 10.0, most preferably (A)/(C) = 1.0 to 6.0.

<Component D>
The present invention preferably further contains the component (D), a hydrophobized fine particle metal oxide. Examples of fine metal oxides include ultraviolet blockers such as zinc oxide, titanium oxide, cerium oxide, and iron oxide, and these can be used alone or in combination of two or more. However, there are no particular restrictions on the shape, such as spherical, plate-like, needle-like, or spindle-like, and the particle structure such as porous or non-porous. Also, the average particle size is not particularly limited, but an average particle size of 0.01 to 10 μm can be mentioned. In particular, fine particle titanium oxide, fine particle zinc oxide and fine particle cerium oxide are preferred, fine particle titanium oxide and fine particle zinc oxide are more preferred, and fine particle titanium oxide is still more preferred. Alternatively, it may be in the form of a composite powder in which the component (D) is adsorbed on the surface of a matrix such as mica, synthetic mica, glass, silica, alumina, or the like.

Specific commercial products include, for example, MP-1133, MP-701, MP-40, MP-100, MT-500SAS (manufactured by Tayca); XZ-100F, XZ-300F, XZ-3000, STR-100C -LF (manufactured by Sakai Chemical Industry Co., Ltd.); ZnO-610Si(4)G (manufactured by Sumitomo Osaka Cement Co., Ltd.); ST-461EC, ST-710EC (manufactured by Titan Kogyo Co., Ltd.) and the like. Cerium oxide includes CERIGUARD W-500 (manufactured by Daito Kasei Co., Ltd., average particle size 1800 nm). For iron oxide, TAROX series (manufactured by Titan Kogyo Co., Ltd., P or HP or CS grades: R-516P, YP1200P, BL-100P, R-516CS, LL-100CS, ABL-205CS, etc., or composite powders thereof ), FESOIE series (manufactured by Titan Kogyo Co., Ltd.), SUN PURO series (C33-8001, C33-9001, C33-7001 (manufactured by Sun Chemical), UNIPURE series (manufactured by SENSIENT), etc. In addition, the component (D ) may be produced by a known production method, and is not particularly limited.

Further, it is preferable that the surface of the metal oxide other than the iron oxide of the component (D) used in the present invention is further coated with an iron oxide or hydroxide. The component (D) used in the present invention may be coated with an oxide or hydroxide of iron, an oxide or hydroxide of silicon, or an oxide or hydroxide of aluminum as each layer.
When the component (D) is further coated with iron oxide, the amount of coating is not particularly limited, but from the viewpoint of natural covering power, the amount of iron oxide coated metal oxide (preferably iron oxide coated titanium dioxide or iron-coated zinc oxide), the preferred lower limit is 0.5% or more, more preferably 0.6% or more, still more preferably 0.7% or more, and the preferred upper limit is 5% or less. is preferred, more preferably 3.5% or less, and still more preferably 3%. 9-3% is more preferred. In the present invention, component (D) can be used alone or in combination of two or more, if necessary.

The component (D) hydrophobizing agent used in the present invention is not particularly limited as long as it is a hydrophobizing agent that is commonly used in cosmetics, quasi-drugs, pharmaceuticals, etc. Examples include silicone treatment agents and fluorine treatment. agents, organic titanate treating agents, metallic soap treating agents, phospholipid treating agents, acylated amino acid treating agents and the like. In terms of emulsified state immediately after production, emulsion stability over time at high temperature, SPF effect, and water resistance, silicone treatment, organic titanate treatment, metallic soap treatment, and acylated amino acid treatment are preferred, and component (C) is replaced with component ( It may be used as a hydrophobizing agent of D).
Specifically, the silicone treatment agent includes chain silicones such as low polymerization degree dimethylpolysiloxane, high polymerization degree dimethylpolysiloxane, and methylphenylpolysiloxane; Examples include silicones, silicone resins such as trimethylsiloxysilicate and acrylic-silicone graft copolymers, silicone rubbers, partially or fully crosslinked organopolysiloxanes, silylating agents, silane coupling agents, and the like. 1 type or 2 types or more can be used.
Among the silane coupling agents, trialkoxyalkylsilanes are preferred. A trialkoxyalkylsilane is a compound in which three alkoxy groups and one alkyl group are bonded to a silicon atom, and the alkoxy groups chemically modify the powder surface by reacting with hydroxyl groups on the powder surface. is a compound.
The alkoxy group in the trialkoxyalkylsilane is preferably an alkoxy group having 1 to 3 carbon atoms such as methoxy, ethoxy and propoxy. The alkyl group in the trialkoxyalkylsilane is preferably an alkyl group having 6 to 18 carbon atoms such as hexyl group, octyl group, decyl group, octadecyl group and the like. Such trialkoxyalkylsilanes are, for example, trimethoxyhexylsilane, trimethoxyoctylsilane, trimethoxydecylsilane, trimethoxyoctadecylsilane, triethoxyhexylsilane, triethoxyoctylsilane (OTS), triethoxydecylsilane, tri and ethoxyoctadecylsilane. Among these, trimethoxyoctylsilane and triethoxyoctylsilane (OTS) are more preferable from the viewpoint of emulsified state immediately after production, emulsion stability over time at high temperature, SPF effect, and water resistance.
Examples of organic titanate treating agents include long-chain carboxylic acid-type, pyrophosphate-type, phosphorous acid-type, amino acid-type alkyl titanates and the like, and alkyl titanates having an alkyl group of 8 to 24 carbon atoms are preferred. Specifically, the alkyl titanates are long-chain carboxylic acid type alkyl titanates such as isopropyl triisostearoyl titanate (ITT), isopropyl trioctanoyl titanate, isopropyl dimethacryl isostearoyl titanate, isopropyl isostearoyl diacryl titanate, di isostearoyl ethylene titanate and the like, and pyrophosphate type alkyl titanates such as tetraisopropylbis(dioctylphosphite)titanate, tetraoctylbis(ditridecylphosphite)titanate, tetra(2,2-diallyloxymethyl-1-butyl ) bis(ditridecylphosphite) titanate and the like, and examples of phosphorous acid-type alkyl titanates include isopropyl tri(dioctylpyrophosphate) titanate, bis(dioctylpyrophosphate)oxyacetate titanate, bis(dioctylpyrophosphate)ethylene titanate, and the like. and examples of amino acid type alkyl titanates include isopropyl tri(N-amidoethyl/aminoethyl) titanate.
In the present invention, among these alkyl titanates, a long-chain carboxylic acid type alkyl titanate is preferable from the viewpoint of the emulsified state immediately after production, the emulsion stability over time at high temperatures, the SPF effect, and the water resistance, and isopropyl triisostearoyl titanate. (ITT) is more preferred.
Examples of the metal soap treatment agent include fatty acids and metal salts thereof, and fatty acids having 12 to 18 carbon atoms are preferred. Examples of salts thereof include calcium, magnesium, zinc, and aluminum. Aluminum salts are particularly preferred. As metal soap treatment agents, aluminum stearate, aluminum isostearate, aluminum distearate, and aluminum oleate are selected from the viewpoints of emulsified state immediately after production, emulsion stability over time at high temperature, lack of stickiness, SPF effect, and water resistance. , aluminum palmitate, aluminum laurate, aluminum myristate and aluminum dimiritate, preferably one or more selected from the group consisting of aluminum stearate and aluminum isostearate, more preferably one or more selected from the group consisting of aluminum stearate and aluminum isostearate. Aluminum stearate is more preferable from the viewpoint of emulsion stability over time and water resistance.
Amino acids for acylamino acid treatment include, for example, proline, hydroxyproline, alanine, glycine, sarcosine, lysine, aspartic acid, glutamic acid, and salts thereof. Specifically, the fatty acid constituting the acyl group for the acylated amino acid treatment is preferably a fatty acid having 1 to 23 carbon atoms, more preferably a fatty acid having 8 to 20 carbon atoms. One or more selected from the group consisting of dilauroyl glutamic acid lysine and lauroyl lysine are more preferable. These salts include Na, Ca, Al, Mg, Zn, Zr, Ti salts. As the acylated amino acid treatment, lauroyl lysine is preferable from the viewpoints of emulsified state immediately after production, emulsion stability over time at high temperature, SPF effect, and water resistance.

The average particle size of the component (D) used in the present invention is preferably 10 nm or more, more preferably 15 nm or more, still more preferably 20 nm or more, as a suitable lower limit, and preferably 100 nm or less as a suitable upper limit. 80 nm or less is more preferable, and 50 nm or less is even more preferable. This range is preferable from the viewpoint of improving the continuity of the film by filling the gaps between the powders and quickly finishing a uniform film.

The content of the component (D) in the cosmetic of the present invention is not particularly limited, but the preferred lower limit is preferably 1% or more, more preferably 3% or more, and still more preferably 5% or more. A suitable upper limit is preferably 20% or less, more preferably 15% or less, still more preferably 12% or less, and the preferable numerical range is preferably 1 to 20%, more preferably 3 to 15%, ~12% is more preferred. This range is preferable because the powder spreads over the skin without agglomeration, so that the film is uniformly and quickly finished.

<Component E>
In the present invention, it is also preferred to use silica as component (E). As long as it is used in ordinary cosmetics, it can be used regardless of whether it has a spherical shape or an irregular shape, whether it has pores, whether it has surface treatment, or the like. Although the size is not particularly limited, it is preferably 0.005 to 40 μm, more preferably 0.01 to 30 μm. A preferable size may be appropriately set according to the formulation of the cosmetic, and the oily formulation is preferably 0.005 to 0.5 μm and/or 10 to 40 μm. 1 to 20 μm is preferred. This range is preferable because it does not impair the skin color correction effect without paleness and the glossy feeling without glare. Furthermore, among them, spherical silica is preferable in that it can give a smooth finished feeling and reduce stickiness. In addition, it is more preferable to use one that has been subjected to a hydrophobic treatment in terms of stability over time. Examples include anhydrous silica, hydrated silica, silylated silica, dimethylsilylated silica, etc. Commercially available products include Silysia 770 (average particle size 6.9 μm, amorphous, porous), 550 (average particle size 3.9 μm, irregular). Regular, porous), 320 (3.2 μm, irregular, porous) (manufactured by Fuji Silysia Chemical Co., Ltd.), AEROSIL 200 (average particle size 12 nm, amorphous, fumed, nonporous), 300 (same 7 nm, amorphous fumes, nonporous), 380S (6 nm, amorphous fumes, nonporous), R972 (16 nm, amorphous fumes, nonporous), R974 (12 nm, amorphous fumes, nonporous) , non-porous), R976S (same 7 nm, amorphous fumes, non-porous), RX300 (same 7 nm, amorphous fumes, non-porous) (manufactured by Nippon Aerosil Co., Ltd.), Sunsphere NP-30 ( NP-100 (average particle size 4 μm, spherical, nonporous), NP-100 (average particle size 10 μm, spherical, nonporous), NP-200 (average particle size 20 μm, spherical, nonporous) (manufactured by AGC Si Tech), God Ball D11-796C (average particle size 3.5 μm, spherical, porous), E2-824C (average particle size 1 μm, spherical, porous) (manufactured by Suzuki Yushi Kogyo Co., Ltd.).

The content of component (E) used in the present invention is preferably 1 to 15%, more preferably 1 to 12%, even more preferably 1 to 10%. This range is preferable because it does not impair the effect of correcting the skin color without paleness and the glossy feeling without glare.

<Components other than components (A) to (E)>
In addition to the above components, the cosmetic composition of the present invention contains an aqueous component, a water-soluble polymer, an ultraviolet absorber, a paraoxybenzoic acid derivative, a preservative such as phenoxyethanol, vitamins, a cosmetic component, a moisturizer, a surfactant, and a cross-linking agent. Optional ingredients such as emulsifiable silicone elastomer and powders other than the above components (A) to (D) and (E) can be contained as appropriate within a range that does not impair the effects of the present invention. The cosmetic of the present invention can be obtained by appropriately adopting known production methods such as inclusion, mixing, emulsification, etc. using the above-described components (A) to (D) and (E), etc., to obtain the desired cosmetic. Types and forms can be prepared.

<About dosage form>
The form of the cosmetic of the present invention is not particularly limited, but may be any of powder, liquid, paste, milky lotion, cream, gel, solid, etc., and one or more of these may be used. can be selected. Emulsified cosmetics, oil-based cosmetics, powdered cosmetics, and powdered solid cosmetics are preferable for exerting the effect, and emulsified cosmetics that exhibit glossiness are particularly preferable.

<Cosmetics>
The cosmetic of the present invention can be applied to make-up cosmetics such as eye color, eyebrow, foundation, blush, white powder, and foundation, skin care cosmetics such as emulsion, cream, serum, and body powder, sunscreen cosmetics, and the like. It is possible, and one or two or more can be selected from these. In addition, the cosmetic of the present invention may be a composition or may be used as an external preparation for skin.

In addition, as another aspect of the present invention, the cosmetic of the present invention is used to cover irregularities on the skin surface (pores, wrinkles, etc.) and to naturally cover color tone troubles (spots, freckles, uneven color, etc.) on the skin mounds. It may be a cosmetic for use to

The present invention will be described in detail with reference to the following examples. It should be noted that these do not limit the present invention in any way.

The color tone measurement CIE1976 L*a*b* color system measurement test method and the reflection intensity test method using a gonio-color difference meter for component (A) are shown below, and the results are shown in Table 1.
<CIE1976L*a*b* color system measurement test>
Spectral colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.) was used to measure the incident angle of -45 ° and the acceptance angle of 0 °, and the component (A) was tapped 20 times in the cell to measure CIE1976L *. Colorimetric values L* (lightness), C* (chroma), and h (hue) of color values defined by the a*b* color system were obtained. The results are shown in Table 1 below.
<Reflection intensity test by gonio-color difference meter>
0.05 g of component (A) per unit area of [5 × 8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and the goniospectrophotometric colorimetry system GCMS-3B type (manufactured by Murakami Color Research Institute Co., Ltd.) was applied. ) Reflection intensity was measured using a D65 illuminant and a black non-reflective background at an angle of incidence of -45 degrees.
An explanation of the evaluation angle is shown in FIG. 1, and the results are shown in FIGS. (O)] ratio [I (45)] / [I (O)] and the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm, [I (45)] (450 nm): [I(45)] (650 nm) was measured and calculated.

※１：ＲＥＬＩＥＦ ＣＯＬＯＲ ＢＥＩＧＥ（日揮触媒化成社製）
※２：ＨＥＬＩＯＲＳ Ｒ１０Ｒ（トピー工業社製）
※３：ＢＬＯＮＤＩＥＥ Ｍｅｔａｌｌｉｃ ＧＯＬＤ Ｎ－２０００Ｓ（ＣＱＶ社製）
※４：ＢＬＯＮＤＩＥＥ ＳＵＰＥＲ ＢＲＯＮＺＥ Ｎ－２２２０Ｓ（ＣＱＶ社製）
※５：ＰＤＭ－ＦＥ（トピー工業社製）

*1: RELIEF COLOR BEIGE (manufactured by Nikki Shokubai Kasei Co., Ltd.)
*2: HELIORS R10R (manufactured by Topy Industries, Ltd.)
*3: BLONDIEE Metallic GOLD N-2000S (manufactured by CQV)
*4: BLONDIEE SUPER BRONZE N-2220S (manufactured by CQV)
*5: PDM-FE (manufactured by Topy Industries, Ltd.)

The color tones of the three samples of component (A) ranged from 60<L*<75, 12<C*<25, 40<h<70. <L*<75, 18<C*<25, 55<h<70.
In addition, according to the results of the reflection intensity test at each wavelength with a goniochromatometer, the component (A) has a reflection intensity [I (45)] at a light receiving angle of 45 degrees and a light receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm in each result. The ratio [I(45)]/[I(O)] of the reflection intensity [I(O)] was in the range of 1-5. Furthermore, the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is [I (45)] (450 nm): [I (45)] (650 nm) = 1: 1 to 1: 2 range.

<<Examples 1 to 21 and Comparative Examples 1 to 8: Oil-in-water emulsified cosmetic (foundation)>>
The oil-in-water emulsified cosmetics (foundation) shown in Tables 2 to 4 were prepared, and the following evaluations were performed for skin color correction effect without paleness, glossy feeling without glare, and speed of uniformly finishing the cosmetic film. Judgment was made according to the judgment criteria. The results are also shown.

※６：ＭＰ－１１３３（テイカ社製）
※７：ＣＲ－５０（石原産業社製）
※８：Ｒ－５１６ＣＳ（チタン工業社製）
※９：ＬＬ－１００ＣＳ（チタン工業社製）
※１０：ＡＢＬ－２０５ＣＳ（チタン工業社製）
※１１：ＳＴＲ－１００Ａ－ＬＰ（堺化学工業社製）
※１２：ＮＩＫＫＯＬレシノールＳ－１０ＥＲ（日光ケミカルズ社製）
※１６：ＳＨ－５５６（東レ・ダウコーニング社製）
※１７：ＫＦ－５６（信越化学工業社製）
※１８：ＬＩＰＯＮＡＴＥ ＴＤＴＭ（ＬＩＰＯ ＣＨＥＭＩＣＡＬＳ ＩＮＣ社製）
※１９：ＮＥＯ ＨＥＬＩＯＰＡＮ ＯＳ（シムライズ社製）
※２０：ＣＡＲＮＡＴＩＯＮ（ＳＯＮＮＥＢＯＲＮ，ＬＬＣ社製）
※２１：Ｋ２２－Ｍ４０（４０％水分散物）（大日本化成社製）の固形分

*6: MP-1133 (manufactured by Tayca)
*7: CR-50 (manufactured by Ishihara Sangyo Co., Ltd.)
*8: R-516CS (manufactured by Titan Kogyo Co., Ltd.)
*9: LL-100CS (manufactured by Titan Kogyo Co., Ltd.)
*10: ABL-205CS (manufactured by Titan Kogyo Co., Ltd.)
* 11: STR-100A-LP (manufactured by Sakai Chemical Industry Co., Ltd.)
*12: NIKKOL Resinol S-10ER (manufactured by Nikko Chemicals)
*16: SH-556 (manufactured by Dow Corning Toray)
*17: KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)
*18: LIPONATE TDTM (manufactured by LIPO CHEMICALS INC.)
*19: NEO HELIOPAN OS (manufactured by Simrise)
*20: CARNATION (manufactured by SONNEBORN, LLC)
*21: Solid content of K22-M40 (40% aqueous dispersion) (manufactured by Dainippon Kasei Co., Ltd.)

※１３：レシチンＣＬＯ（味の素社製）
※１４：セラミドＴＩＣ－００１（高砂香料社製）
※１５：アミソフトＨＡ－Ｐ（味の素社製）
※２２：ＳＩＭＵＬＧＥＬ ＥＧ ＱＤ（３７．５％分散物）（ＳＥＰＰＩＣ社製）の固形分

*13: Lecithin CLO (manufactured by Ajinomoto Co., Inc.)
* 14: Ceramide TIC-001 (manufactured by Takasago International Corporation)
*15: Amisoft HA-P (manufactured by Ajinomoto Co., Inc.)
*22: Solid content of SIMULGEL EG QD (37.5% dispersion) (manufactured by SEPPIC)

(Manufacturing method) (Tables 2 to 4: Ingredients not contained shall not be blended.)
A. Disperse ingredients 1-15.
B. Ingredients 16-33 are mixed uniformly.
C. Ingredients 34-44 are uniformly mixed.
D. Add B to C and emulsify.
E. A was added to D and defoamed after mixing to obtain a foundation.

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
stomach. Skin color correction effect without paleness b. Glossy feeling without glare c. The speed at which the makeup film is evenly finished

(Evaluation method 1)
A use test was conducted by 20 professional evaluation panels for the foundation, and each panelist evaluated the skin color correction effect without paleness, glossiness without glare, and the speed at which the makeup film was evenly finished in the following absolute evaluation in 5 stages. A score was given, and the average value was calculated from the total score of all the panel members for each sample, and judged according to the following 4-step judgment criteria. In addition, the “skin color correction effect without paleness” is whether there is an unnatural bluish white film immediately after application, and the “glossiness without glare” is unnatural from any angle immediately after application. The “speed at which the makeup film is evenly finished” is the speed at which the powder or liquid ingredient adheres immediately after application without slipping on the skin, and the makeup film subsides. evaluated whether

<Absolute evaluation criteria>
(Rating): (Evaluation)
5: Very good 4: Good 3: Normal 2: Poor 1: Very bad <judgment criteria>
(Judgment): (Average score)
AA: 4.5 points or more: Very good A: More than 4 points and 4.5 points or less: Good B: More than 3 points and 4 points or less: Fairly good C: 3 points or less than 2 points: Somewhat poor D: 2 points or less: Poor

As is clear from the results in Tables 2 and 3, the foundations of Examples 1 to 21, which are the products of the present invention, have a skin color correcting effect without paleness, a glossy feeling without glare, and a uniform finish speed of the cosmetic film. It was an oil-in-water emulsified liquid cosmetic that was excellent in all items. On the other hand, as shown in the results of Table 4, Comparative Examples 1 to 4, which do not contain component (A), are not satisfactory in skin correcting effect without paleness and luster without glare due to some large pearlescent agents. rice field. Further, Comparative Examples 5 to 7, which did not contain the component (B), had a low glossy feeling without glare, and the uniform finishing speed of the cosmetic film was not sufficient. In Comparative Example 8, which contained stearic acid instead of component (C), the speed at which the cosmetic film was uniformly finished was not sufficient.

Example 22: Powder foundation (powder solid cosmetic)
A powder foundation was produced by a slurry method according to the following formulation and production method.
(Component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
5.0
2. Ceramide-treated titanium oxide*23 10.0
3. Fine zinc oxide *24 5.0
4. Boron nitride *25 8.0
5. Bismuth oxychloride *26 5.0
6. Red iron oxide *8 0.5
7. Yellow iron oxide *9 1.7
8. Black iron oxide *10 0.15
9. Talc *27 Remaining amount 10. Spherical silica *28 10.0
11. Lauroyllysine *29 4.0
12. Silicone treated mica *30 10.0
13. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 2.0
14. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455)
8.0
15. Isotridecyl isononanoate *31 (refractive index 1.445) 5.0
16. Diisostearyl malate *32 (refractive index 1.460) 2.0
17. Chlorphenesin 0.2
18. Lemon extract 0.001
19. Pearl barley extract 0.001
20. Green tea extract 0.001
21. Fermented rice extract 0.001
22. Rice bran extract 0.001
23. Hyaluronic acid Na 0.001
24. Hydrolyzed collagen 0.001
25. Proteoglycan 0.001
26. Scutellaria root extract 0.001
27. Hydrolyzed soybean extract 0.001
28. Astaxanthin 0.001
29. Rose honey 0.001
30. Shea butter 0.001
31. Ceramide NG 0.001
32. Hummus extract 0.001
33. Keiketto extract 0.001
34. Theanine 0.001
35. Alum 0.001
36. Aluminum chlorohydroxyl 0.001
*23: MP-1133 (manufactured by Tayca, average particle size 0.27 μm) 94.4%
Al hydroxide 2.6% treatment, (palmitic acid / ethylhexanoic acid) dextrin 2.7% treatment Ceramide NG 0.3% treatment * 24: MZ-500 (manufactured by Tayka, average particle size 25 nm)
*25: SHP-3 (manufactured by Mizushima Ferroalloy Co., Ltd., average particle size: 6 μm, aspect ratio: 10)
*26: PEARL-GLO UVR (manufactured by ENGELHARD)
*27: JA-46R (manufactured by Asada Flour Milling Co., Ltd., average particle size 9 μm, aspect ratio 50)
*28: Sunsphere NP-30 (manufactured by AGC Si Tech, average particle size 4 μm)
*29: Amihope LL (manufactured by Ajinomoto Co., Inc.)
*30: Y-3000 (manufactured by Yamaguchi Mica, average particle diameter 23 μm, aspect ratio 70)
2% dimethicone treatment * 31: Salacos 913 (manufactured by Nisshin OilliO Co., Ltd.)
*32: Himalate DIS (manufactured by KOKYU ALCOHOL KOGYO CO., LTD.)

(Production method)
A. Mix 1 to 12 evenly with a super mixer.
B. A homogeneous mixture of components 13 to 36 was added to A, dispersed uniformly, and pulverized to obtain a cosmetic base.
C. 50 parts of a solvent (isododecane) was added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture.
D. 11 g of the mixture was filled in a round metal plate (5.5 cm in diameter) and compressed four times under the conditions of a press pressure of 2.0 kgf/cm ² , a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. . Then, it was dried at 70° C. for a whole day and night to remove the solvent to obtain a foundation.

The obtained powder foundation (powder solid cosmetic) was a powder foundation excellent in skin color correcting effect without paleness, glossy feeling without glare, and quickness of uniformly finishing a cosmetic film.

Example 23: Foundation (property between solid powder and oily solid)
A foundation having properties between a solid powder and an oily solid was manufactured according to the formulation and manufacturing method described below.
(Component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
6.0
2. Silicone treatment Aluminum hydroxide/hydrous silicic acid treatment
Fine particles of titanium oxide *11 2.0
3. Ceramide-treated titanium oxide *23 8.0
4. Zinc oxide *24 1.0
5. Boron nitride *33 5.0
6. Synthetic phlogopite *34 Remainder 7. Red iron oxide *8 0.5
8. Yellow iron oxide *9 1.7
9. Black iron oxide *10 0.15
10. Spherical silica *35 5.0
11. Silica dimethyl silylate *36 0.2
12. Spherical cellulose powder *37 0.5
13. (dimer dilinoleic acid (phytosteryl/isostearyl/cetyl
/stearyl/behenyl) (refractive index 1.487) *38 5.0
14. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455)
15.0
15. Triisostearin *39 (refractive index 1.458) 1.0
16. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 15.0
17. Hydrogenated phospholipid *12 0.5
18. Isododecane 5.0
*33: BORON NITRADE POWDER CCS-102 (manufactured by Momentive)
* 34: Micromica MK-200K (manufactured by Katakura Co-op Aguri, average particle size 7 μm, aspect ratio 60)
*35: CHIFFONSIL P-3R (manufactured by Nikki Shokubai Kasei Co., Ltd., average particle size 6 μm)
* 36: AEROSIL R-976S (manufactured by Nippon Aerosil Co., Ltd.)
* 37: CELLULOBEADS D-30 (manufactured by Daito Kasei Kogyo Co., Ltd.)
* 38: PLANDOOL-S (manufactured by Nippon Fine Chemical Co., Ltd.)
*39: Saracos 3318 (manufactured by Nisshin OilliO Co., Ltd.)

(Production method)
A: Components 7 to 17 are dispersed and swollen with a three-roller.
B: Components 1 to 6 and 18 are added to A and kneaded in a planetary mixer while reducing pressure.
C: B was filled in a container to obtain a foundation with properties between solid powder and oily solid.

The obtained foundation was excellent in the effect of correcting the skin color without paleness, the glossy feeling without glare, and the speed at which the cosmetic film was uniformly finished.

Example 24: O/W emulsified liquid base An oil-in-water type liquid makeup base was produced according to the following formulation and production method.
(Component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
6.0
2. Phospholipid-treated titanium oxide *40 2.0
3. Talc *27 1.0
4. Silicone treatment Aluminum hydroxide/hydrous silicic acid treatment
Fine particles of titanium oxide *11 4.0
5. Red iron oxide *8 0.1
6. Yellow iron oxide *9 0.1
7. Black iron oxide *10 0.01
8. Amodimethicone/distearyldimonium chloride treatment
Spherical silica*41 3.0
9. Titanium oxide coated synthetic phlogopite 4.0
10. Lauroyllysine *29 1.0
11. BG20.0
12. Ethanol 2.0
13. (Acrylates/alkyl acrylate (C10-30))
Crosspolymer 10.0
14. Carbomer 5.0
15. Remaining purified water 16. Ethylhexyl methoxycinnamate 8.0
17. Diethylaminohydroxybenzoyl hexyl benzoate 1.0
18. methylenebisbenzotriazolyltetramethylbutylphenol 0.5
19. Polyglyceryl-10 laurate 0.1
20. Hydrogenated phospholipid *12 0.5
21. Sodium stearoyl glutamate *42 0.1
22. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 4.0
23. Triethylhexanoin *43 0.5
24. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455)
1.0
25. PG dicaprate *44 1.0
26. Polysorbate 80 *45 0.5
27. Behenyl alcohol *46 0.5
* 40: CR-50 (manufactured by Ishihara Sangyo Co., Ltd., average particle size 0.25 μm) 99.46%
Phospholipid 0.54%
*41: TMS-05DCA (manufactured by Tayca, average particle size 5 μm)
*42: Amisoft HS-11P (F) (manufactured by Ajinomoto Co., Inc.)
*43: MYRITOL GTEH (manufactured by BASF)
* 44: NIKKOL PDD (manufactured by Nippon Surfactant Industry Co., Ltd.)
*45: Polysorbate 80 (manufactured by Kao Corporation)
*46: Conor 2265 (manufactured by Shin Nippon Rika Co., Ltd.)

(Production method)
A: Components 1 to 15 are dispersed and swollen.
B: Add ingredients 16 to 27 to A and emulsify.
C:B was filled in a tube container to obtain an O/W emulsified liquid base.

The resulting O/W emulsified liquid base was excellent in skin color correcting effect without paleness, glossy feeling without glare, and speed of uniformly finishing the cosmetic film.

Example 25: W/O Emulsified Liquid Foundation A water-in-oil liquid foundation was developed according to the formulation and manufacturing method described below.
(Component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
5.0
2. Silicone treatment Aluminum hydroxide/hydrous silicic acid treatment
Fine particles of titanium oxide *11 4.0
3. Silica-coated/silicone treated fine zinc oxide *47 2.0
4. Dimethicone treated red iron oxide 0.3
5. Dimethicone treated yellow iron oxide 1.2
6. Dimethicone-treated black iron oxide 0.1
7. Boron nitride *25 1.0
8. Spherical silica *48 2.0
9. Dimethicone crosspolymer *49 1.0
10. Synthetic phlogopite *34 1.0
11. Bis(PEG/PPG-14/14) dimethicone *50 1.0
12. Isotridecyl isononanoate *31 2.5
13. Alkyl benzoate (C12-15) 1.5
14. Ethylhexyl methoxycinnamate 3.0
15. Diisostearyl malate *32 (refractive index 1.460) 0.5
16. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 10.0
17. (Acrylates/Dimethicone) Copolymer *51 4.0
18. Remaining purified water 19. Tremella fungus polysaccharide *52 4.0
20. Ethanol 4.0
21. Ethylhexylglycerin *53 0.1
22. Phenoxyethanol 0.3
*47: MZ-510HPSX (manufactured by Tayca, average particle size 25 nm)
*48: TMS-10 (Taika, average particle size 10 μm)
* 49: DOWSIL 9040 SILICONE ELASTOMER BLEND (manufactured by Dow Corning) (solid content: dimethicone crosspolymer 12.6%, solvent cyclomethicone 87.4%)
*50: ABIL EM 97S (manufactured by Evonik Industries)
*51: KP-545 (manufactured by Shin-Etsu Chemical Co., Ltd.)
*52: TREMOIST-TP (manufactured by Nippon Fine Chemical Co., Ltd.)
*53: ADEKA NOL GE-RF (manufactured by ADEKA)

(Production method)
A: Components 1 to 14 are dispersed with a three-roller.
B: Components 15 to 17 are added to A and dispersed.
C: Add ingredients 18 to 22 to B and emulsify.
D: A tube container was filled with C to obtain a W/O emulsified liquid foundation.

The obtained W/O emulsified liquid foundation was excellent in skin color correcting effect without paleness, glossy feeling without glare, and speed of uniform finishing of the cosmetic film.

Example 26: Powder Foundation A powder foundation was developed according to the following formulation and manufacturing method.
(Component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
4.0
2. Dimethicone-treated zinc oxide (average particle size 3.0 μm, hexagonal plate shape) 6.0
3. Phospholipid-treated titanium oxide *40 4.0
4. Silicone treated mica *30 Remainder 5. Lauroyllysine *29 3.0
6. Boron nitride *33 10.0
7. Barium sulfate (plate-like, average particle size 15 μm) 1.0
8. Spherical silica *41 2.0
9. Red iron oxide *8 1.5
10. Yellow iron oxide *9 1.0
11. Black iron oxide *10 0.5
12. Ethylhexyl methoxycinnamate 6.0
13. (Acrylates/Stearyl Acrylate/Dimethicone Methacrylate)
Copolymer *54 0.5
14. Sorbitan sesquistearate *55 1.0
15, isotridecyl isononanoate *31 0.5
16. Chlorphenesin 0.1
17. Ethanol 0.5
*54: KP-561P (manufactured by Shin-Etsu Chemical Co., Ltd.)
*55: NIKKOL SS-15V (manufactured by Nippon Surfactant Industry Co., Ltd.)

(Production method)
A: Components (1) to (11) were mixed and dispersed.
B: Components (12) to (17) dispersed in A were added and pulverized with a pulverizer.
C: A powder foundation was obtained by compression molding in a metal plate container. Component (17) was then evaporated.

The obtained powder foundation was excellent in the effect of correcting the skin color without paleness, the glossy feeling without glare, and the speed at which the cosmetic film was uniformly finished.

Example 27: Oily blush (ingredient) (%)
1. Dextrin palmitate *56 10.0
2. Microclusterin wax (melting point 77-82°C) 4.0
3. Trimethylsiloxysilicate *57 6.0
4. Diglyceryl triisostearate (refractive index 1.463) 15.0
5.2-Cetyl ethylhexanoate (refractive index 1.443) 35.0
6. Dimethylpolysiloxane (25°C, same viscosity 6CS) 2.0
7. dimer dilinoleic acid (phytosteryl/isostearyl/cetyl
/stearyl/behenyl) (refractive index 1.487) *38 2.0
8. Sorbitan sesquioleate 2
9. Hydrogenated phospholipid *12 0.5
10. Red No. 202 0.5
11. Yellow No. 4 0.5
12. Black iron oxide *10 0.1
13. Talc *27 Remaining amount 14. Silica dimethyl silylate *36 2.0
15. Spherical cellulose powder *37 3.0
16. Polyethylene powder *58 0.2
17. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
2.0
18. Silica-coated/silicone treated fine zinc oxide *47 1.0
*56: Rheopearl TL2 (manufactured by Chiba Flour Mills)
* 57: KF-9021 (50% solid content decamethylcyclopentasiloxane solution) (manufactured by Shin-Etsu Chemical Co., Ltd.)
*58: Mipelon PM-200 (manufactured by Mitsui Chemicals, Inc.)
Red No. 202 (generic name: Lithol Rubine BCA.) and Yellow No. 4 (generic name: Tartrazine).

(Production method)
A. Components (1) to (8) are heated and uniformly dissolved.
B. Components (9) to (18) are added to A and dispersed uniformly.
C. B was poured into a gold plate and solidified by cooling to obtain an oily blush.

The obtained oily blusher was excellent in skin color correcting effect without paleness, glossy feeling without glare, and speed of uniform finishing of the cosmetic film.

Example 28: Powder solid blush (ingredients) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
20.0
2. Silicone treated mica *30 Remainder 3. Synthetic phlogopite *34 10.0
4. Triethoxycaprylylsilane-treated red iron oxide 0.2
5. Red No. 226 0.5
6. Talc*27 5.0
7. Silica-coated/silicone treated fine zinc oxide *47 2.0
8. Spherical cellulose powder *37 2.0
9. Spherical silica *28 1.0
10. Chlorphenesin 0.2
11. Diglyceryl triisostearate (refractive index 1.463) 1.0
12. Diisostearyl malate *32 (refractive index 1.460) 1.0
13. Heavy liquid isoparaffin (refractive index 1.491) 0.5
14. Squalane (refractive index 1.457) 1.0
15. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 7.0
16. ((Dimer Dilinoleic Acid (Phytosteryl/Isostearyl/Cetyl
/stearyl/behenyl) (refractive index 1.487) *38 1.0
17. Rosemary leaf extract 0.1
18. Glycerin 0.5
19. Avocado oil 0.1
20. mineral oil 0.2
21. Tocopherol 0.01

(Production method)
A. Ingredients (1) to (10) are uniformly mixed.
B. A uniformly mixed component (11) to (21) was added to A, dispersed uniformly, and pulverized to obtain a cosmetic base.
C. This was compressed and filled into an airtight resin container to obtain a blush.

The resulting powdery solid blusher was excellent in skin color correcting effect without paleness, glossy feeling without glare, and speed of uniform finishing of the cosmetic film.

Example 29: White powder (component) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
10.0
2. Dimethicone-treated synthetic phlogopite *5 15.0
3. Talc *27 Remaining amount 4. Titanium mica *59 10.0
5. Silica-coated/silicone treated fine zinc oxide *47 8.0
6. Boron nitride *25 5.0
7. Spherical polyethylene powder *58 5.0
8. Spherical cellulose powder *37 10.0
9. Calcium carbonate *60 1.0
10. Spherical silica *48 2.0
11. Bengara 1.0
12. Yellow iron oxide *9 2.0
13. Black iron oxide *10 0.3
14. Methyl paraoxybenzoate 0.2
15. Ethylhexyl methoxycinnamate 2.0
16. Pentaerythrityl tetraisostearate (refractive index 1.467) 0.5
17. Octyldodecyl stearoyloxystearate 0.5
18. Triethylhexanoin (refractive index 1.443) 3.0
19. (VP/hexadecene) copolymer *61 0.5
20. Squalane (refractive index 1.452) 0.2
21. Stearanium Hectorite *62 1.0
22. 2% aqueous solution of cellulose nanofiber *63 0.2
23. Rice bran glycosphingolipid 0.1
24. Dutch mustard extract 0.1
25. Hydrogenated phospholipid *12 0.2
*59: TIMIRON STARLUSTER MP-115
(manufactured by Merck, average particle size 20 μm, aspect ratio 300)
*60: PC chalk (manufactured by Shiraishi Kogyo Co., Ltd., average particle size 1 μm)
*61: ANTARON V-216 (Ashland Japan Co., Ltd.)
*62: BENTONE 27V (manufactured by Elementis)
*63: Rheocrysta C-2SP (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.)

(Production method)
A. Ingredients (1) to (14) are uniformly mixed.
B. A uniformly mixed component (15) to (25) was added to A, dispersed uniformly, and pulverized to obtain a cosmetic base.
C. 70 parts of the solvent shown in the table was added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture.
D. 10.0 g of the mixture was placed in a round metal plate container (7 cm in diameter) and compressed twice under the conditions of a press pressure of 2.0 kgf/cm 2 , a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. Then, it was dried at 70° C. for 10 hours to remove the solvent and obtain a white powder.

The obtained white powder was excellent in skin color correcting effect without paleness, glossy feeling without glare, and quickness of uniformly finishing a cosmetic film.

Example 30: Eyebrow (ingredient) (%)
1. Talc *27 20.0
2. Silicone treated mica *30 Remainder 3. Black iron oxide *10 10.0
4. Bengala 4.0
5. Al hydroxide treated titanium oxide (average particle size 1.0 μm) 6.0
6. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
10.0
7. Black iron oxide coated mica titanium 15.0
8. Fine zinc oxide *24 2.0
9. Zinc stearate *64 1.0
10. Spherical silica *28 1.0
11. Red No. 226 0.1
12. Yellow No. 4 0.1
13. Red No. 202 0.1
14. Dimethylpolysiloxane (25°C, kinematic viscosity 6CS) 10.0
15. Phenyl trimethicone *16 (refractive index 1.458) 3.0
16. dimer dilinoleic acid (phytosteryl/isostearyl/cetyl
/stearyl/behenyl) (refractive index 1.487) *38 3.0
17. Carnauba wax 0.5
18. Microcrystalline wax (melting point 77-82°C) 0.5
19. Trimethylsiloxysilicate *57 1.0
20. Paraffin 0.3
21. Beeswax 0.2
22. Dextrin Isostearate 1.0
23. Hydrogenated phospholipid *12 1.0
24. Damask rose flower extract 0.2
25. Lemon fruit extract 0.1
26. Ethanol 0.1
27. Purified water 0.2
* 64: MZ-2 (manufactured by NOF Corporation, average particle size 1.5 μm)

(Production method)
A. Ingredients (1) to (13) are uniformly mixed.
B. A uniformly mixed component (14) to (27) was added to A, dispersed uniformly, and pulverized to obtain a cosmetic base.
C. 40 parts of isododecane solvent was added to 100 parts of the cosmetic base material and mixed to obtain a slurry mixture.
D. 2.0 g of the mixture was placed in a round metal plate container (2 cm in diameter) and compressed twice under the conditions of a press pressure of 2.0 kgf/cm 2 , a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. Then, it was dried at 70° C. for 10 hours to remove the solvent and obtain an eyebrow.

The obtained eyebrows were excellent in glossy feeling without glare and speed in which the cosmetic film was uniformly finished.

Example 31: Solid powder eye shadow (ingredient) (%)
1. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
10.0
2. Talc *27 Remaining amount 3. Titanium oxide treated with 2Na stearoyl glutamic acid *65 15.0
4. Silicone treatment Aluminum hydroxide/hydrous silicic acid treatment
Fine particles of titanium oxide *11 2.0
5. Boron nitride *25 5.0
6. Spherical silica *48 5.0
7. Ultramarine 2.0
8. Red No. 202 0.5
9. Organopolysiloxane elastomer powder *66 1.0
10. Chlorphenesin 0.1
11. Bismuth oxychloride *26 5.0
12. Barium sulfate (plate-like, average particle size: 15 μm) 3.0
13. Macadamia nut oil (refractive index 1.465) 1.0
14. Dimethylpolysiloxane (6CS: 25°C) 7.0
15. Diphenylsiloxyphenyl trimethicone *17 (refractive index 1.455)
2.0
16. Di(phytosteryl/octyldodecyl) lauroyl glutamate *67
(refractive index 1.479) 1.0
17. Hydrogenated phospholipid *12 0.5
18. Refined olive oil (refractive index 1.465) 0.5
19. Perfume 0.01
* 65: NAI-Titanium MP-1133 (manufactured by Miyoshi Kasei Co., Ltd., average particle size 0.27 μm)
* 66: KSP-300 (manufactured by Shin-Etsu Chemical Co., Ltd., average particle size 5 μm)
*67: Eldew PS-203 (manufactured by Ajinomoto Co., Inc.)

(Production method)
A. Components (1) to (12) are uniformly dispersed using a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.).
B. Ingredients (13)-(19) are uniformly mixed.
C. While stirring A with a Henschel mixer, B is added and uniformly dispersed.
D. Pulverize C with a pulverizer.
E. D was filled in a metal plate and compression-molded to obtain a solid powdery eyeshadow.

The obtained eyeshadow was excellent in skin color correcting effect without paleness, glossy feeling without glare, and quickness in finishing the makeup film uniformly.

Example 32: Aerosol type foundation cosmetic (ingredient) (%)
1. Phospholipid-treated aluminum hydroxide-treated titanium oxide (average particle size 0.27 μm) 10.0
2. Triethoxycaprylylsilane-treated red iron oxide 0.8
3. Triethoxycaprylylsilane treated yellow iron oxide powder 1.0
4. Triethoxycaprylylsilane-treated black iron oxide powder 0.5
5. Titanium oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, iron oxide coating amount 11-14%, tin oxide coating: Fig. 2)
10.0
6. Silicone treatment Aluminum hydroxide/hydrous silicic acid treatment
Fine particles of titanium oxide *11 2.0
7. Spherical silica *28 2.0
8. Polyglyceryl-3/polydimethylsiloxyethyl dimethicone 1.0
9. Decamethylcyclopentasiloxane 5.0
10. Dimethylpolysiloxane remaining amount 11. (Trifluoropropyl Dimethicone/Trifluoropropyldivinyl Dimethicone) Crosspolymer 2.0
12. Ethylhexyl methoxycinnamate 8.0
13. (Trifluoroproyldimethylsiloxy/
trimethylsiloxy)silsesquioxane)*68 5.0
14. PEG-9 polydimethylsiloxyethyl dimethicone *69 2.0
15. Mixture of crosslinked organopolysiloxane polymers 2.0
16. Trimethylolpropane triisostearate (refractive index 1.463) 0.5
17.2-Methacryloyloxyethylphosphorylcholine (MPC) group-containing polymer *70
1.0
18. agar 0.1
19. bisethylhexyloxyphenol methoxyphenyl
Triazine Emulsion 2.0
20. Tripropylene glycol 3.0
21. Purified water 15.0
*68: FR-5 (manufactured by Momentive)
* 69: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 70: Lipidure-PMB (manufactured by NOF Corporation)

(Production method)
A. Components (1) to (7) are kneaded with three rollers.
B. A and components (8) to (16) are heated and mixed at 50° C. and dispersed uniformly.
C. Components (17) to (21) were mixed, added to B, and emulsified at room temperature to obtain a stock solution.
D. After filling 9 g of the stock solution obtained in C into an aluminum pressure-resistant container, the valve was fixed, and 10 g of LPG 0.15 and 2 g of dimethyl ether were filled into the pressure-resistant container through the valve to obtain an aerosol type foundation.

The obtained aerosol-type foundation was excellent in the effect of correcting the skin color without paleness, the glossy feeling without glare, and the speed with which the cosmetic film was uniformly finished.

Claims (10)

the following components (A)-(C);
(A) Plate-like powder containing iron and coated with titanium oxide and having an average particle size of 3 to 30 μm (B) Oil agent having a refractive index of 1.455 or more at 24° C. (C) Phospholipid, 2-methacryloyloxy containing one or more selected from ethylphosphorylcholine (MPC) group-containing polymers, ceramides, and N-acylamino acids and salts thereof, and
The component (A) has luster and is measured using a spectrocolorimeter at an incident angle of −45° and an acceptance angle of 0°, and is a colorimetric value defined by the CIE1976L*a*b* color system. A cosmetic having L* (lightness), C* (chroma), and h (hue) of 60<L*<83, 12<C*<32, and 40<h<76. 0.05 g of the component (A) per unit area of [5×8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and the angle of incidence was −45 degrees using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a black non-reflective background, the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity at a light receiving angle of 0 degrees [I (O)] at wavelengths of 450 nm and 650 nm 2. The cosmetic composition according to claim 1, wherein the ratio [I(45)]/[I(O)] is 1-4. 3. The cosmetic according to claim 1, wherein the coating amount of titanium oxide in component (A) is 5 to 20% by mass. The cosmetic according to any one of claims 1 to 3, wherein the plate-like powder of component (A) is based on synthetic phlogopite iron. 5. The cosmetic according to any one of claims 1 to 4, wherein the component (B) is one or more selected from ultraviolet absorbers, phenyl-modified silicones, and tridecyl trimellitate. 6. The cosmetic according to any one of claims 1 to 5, further comprising, as a component (D), a hydrophobized fine particle metal oxide. 7. The cosmetic according to any one of claims 1 to 6, further comprising silica as component (E). The cosmetic according to any one of claims 1 to 7, wherein the mass content ratio of the components (A) and (C) is (A)/(C) = 0.5 to 100. 0.05 g of the component (A) per unit area of [5×8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and the angle of incidence was −45 degrees using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a black non-reflective background, the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm is [I (45)] (450 nm): [ I(45)](650 nm)=1:1 to 1:2, the cosmetic according to any one of claims 1 to 8. The cosmetic according to any one of claims 1 to 9, which is an emulsified cosmetic.

Images