JP2023098186A - Powder cosmetic - Google Patents

Abstract

To provide powder cosmetics that has a natural skin-correcting effect, high covering effect for uneven color and unevenness, and excellent makeup retention effect.SOLUTION: Provided is a powder cosmetic that contains: synthetic phlogopite coated with titanium oxide and tin oxide and having an average particle size of 5 to 16 μm; one or more fine particle metal oxides selected from other titanium oxide and zinc oxide; and one or more substantially spherical powders selected from naturally occurring water-insoluble polymers and silicic anhydride.SELECTED DRAWING: None

Description

The present invention relates to powder cosmetics

Powdered cosmetics such as foundations and white powders are composed mainly of powders, and while providing a matte finish, they even out the color of the skin and smooth out uneven skin such as spots and freckles, as well as irregularities on the skin surface such as pores and wrinkles. Its main purpose is to make the skin look beautiful by hiding it. In order to cover such troubles with powder cosmetics, conventionally, titanium oxide or the like, which has high concealability, has mainly been used. Powdered cosmetics with a high content of them are effective against color tone problems such as spots and freckles, but the finish is white, thick and unnatural with no transparency, and unevenness is rather conspicuous. It had its shortcomings. In addition, powder cosmetics are likely to cause makeup deterioration such as color fading and smearing of the makeup film over time due to sebum and perspiration, so products with long lasting makeup are required.

In order to solve such an unnatural finish and poor cosmetic durability over time, for example, a method of combining synthetic phlogopite and organic plate-like powder, boron nitride, spherical powder and liquid oil has been proposed. (See Patent Document 1, for example). The powder foundation obtained by this method has high adhesion to the skin, and it is possible to make irregularities such as pores inconspicuous with a cosmetic film with a natural finish.

In addition to this, there have been proposed skin cosmetics containing a specific powder whose color changes little depending on the observation direction of the reflected light of the interference color and an iron oxide/titanium oxide sintered colored pigment (for example, See Patent Document 2). According to this method, it is proposed that a cosmetic can be obtained in which the hue of the skin can be changed depending on the combination while imparting a sense of transparency, and at the same time, the makeup does not deteriorate due to sebum.

On the other hand, by heat-treating iron-containing synthetic mica at a specific temperature as a powder with a color close to the natural skin color, it is possible to achieve a bright red appearance with lightfastness that has never been seen in conventional synthetic mica. In addition, it has been found that a novel synthetic mica can be obtained that exhibits excellent UV-blocking ability. 3). Furthermore, a composite mica powder is proposed in which a synthetic mica powder containing an iron element is coated with an oxide (see, for example, Patent Document 4). Attempts have been made to provide a composite mica powder that is almost white when dry, but changes to a skin color when wet with a liquid, and that exhibits a pearly feel with an unprecedented color.

JP 2013-209346 A JP-A-11-43414 JP-A-6-9210 JP-A-7-258031

However, with the techniques of Patent Documents 1 and 2, it is difficult to achieve both a natural skin correcting effect and a high covering effect, and furthermore, when the skin is wet with sebum or sweat, color fading is likely to occur, and makeup collapse cannot be prevented. was there. In the techniques of Patent Documents 3 and 4, it is necessary to improve the tendency of unevenness to be conspicuous in the case of a large shape with high glossiness, and there may be a problem in longevity of makeup due to a large color change when wet with sebum. rice field.

As described above, in the prior art, the problem was that it was not possible to obtain a satisfactory effect of a powder cosmetic composition that does not easily cause makeup deterioration while achieving both a natural skin correcting effect and a high covering effect. attempted to provide a powdery cosmetic that satisfies these effects at the same time.

The present invention has been made in view of the above circumstances, and its main purpose is to obtain a cosmetic film that is naturally corrected without the feeling of a white film, while having a high covering effect on color unevenness and unevenness. and to provide a powdery cosmetic which is resistant to sebum and sweat and has a high makeup lasting effect.

In order to solve the above problems, the present inventors have made intensive studies and found that iron oxide-coated synthetic iron phlogopite, titanium oxide, and zinc oxide, a naturally-derived water-insoluble polymer, and silicic anhydride are included. By doing so, surprisingly, while synthetic phlogopite gives a glossy feeling and naturally covers the color, titanium oxide and zinc oxide make it possible to achieve a pore-covering effect. The present inventors have found that the combined use of a water-insoluble polymer and silicic anhydride provides a cosmetic film that is less likely to cause makeup deterioration, thereby solving the above-described problems, thereby completing the present invention.

That is, the present invention is as follows.
[1] the following components (A) to (C);
(A) Titanium oxide and synthetic phlogopite coated with tin oxide and having an average particle size of 5 to 16 μm (B) One or more fine particles of metal oxide selected from titanium oxide and zinc oxide other than component (A) Product (C) A powder cosmetic containing one or more substantially spherical powders selected from naturally-derived water-insoluble polymers and silicic anhydride, wherein the component (A) is a glittering powder. be.
[2] Apply 0.05 g of the component (A) to the adhesive surface of the transparent adhesive tape per unit area of [5×8] cm ² , and measure the incident angle at -45 using a goniospectrophotometer D65 light source. When the reflection intensity was measured using a black non-reflective background at 450 nm and 650 nm, the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity at a light receiving angle of 0 degrees [I (O )] ratio [I(45)]/[I(O)] is 1.1 to 2.5.
[3] The cosmetic powder according to [1] or [2], wherein the coating amount of titanium oxide of component (A) is 5 to 20% by mass.
[4] The cosmetic powder according to any one of [1] to [3], wherein the synthetic phlogopite of component (A) is synthetic phlogopite iron.
[5] The cosmetic powder according to any one of [1] to [4], wherein the component (B) is coated with iron oxide.
[6] The cosmetic powder according to any one of [1] to [5], wherein the component (C) is a powder coated with a metal oxide.
[7] The cosmetic powder according to any one of [1] to [6], further comprising, as component (D), a silicone oil having a kinematic viscosity at 25°C of 6 to 100 mm ² /s.
[8] The mass ratio of the component (A) and the total mass of components (A) and (B) [(A) + (B)] is (A) / [(A) + (B)] = 0 0.05 to 1.0, the powder cosmetic according to any one of [1] to [7].
[9] The cosmetic powder according to any one of [1] to [8], wherein the component (A) is a blue light-cutting agent.

Furthermore, the following invention can also be added.
[10] The component (A) has a colorimetric value L* defined by the CIE1976L*a*b* color system when measured using a spectral colorimeter at an incident angle of −45° and an acceptance angle of 0°, The cosmetic powder according to any one of [1] to [9], wherein C* and h are 68<L*<75, 18<C*<25, and 55<h<70.

The cosmetic powder of the present invention comprises synthetic phlogopite coated with titanium oxide and tin oxide and having an average particle size of 5 to 16 μm, one or more selected from titanium oxide and zinc oxide, and a specific substantially spherical To provide a powdery cosmetic having a natural skin correcting effect and a high covering effect for color unevenness and unevenness, and having an excellent make-up lasting effect by containing powder.

Transmittance measurement at each wavelength of component (A) and comparative product Blue light cut function (380-500nm hiding rate) 0.05 g of component (A) per unit area of [5 × 8] cm2 was applied to the adhesive surface of the transparent adhesive tape, and a goniospectrophotometer D65 light source was used to detect black at an incident angle of -45 degrees. Explanation of the angles of the reflection intensity [I(45)] at a light receiving angle of 45 degrees and the reflection intensity [I(O)] at a light receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm when the reflection intensity is measured using a reflective background. Component (A) Titanium oxide coating Synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide 11-14%, tin oxide coating) Reflection intensity comparison at light receiving angles of 0° and 45° Component (A) Titanium oxide coating Synthetic phlogopite (*1) HELIOS R10R (manufactured by Topy Industries, Ltd.) (average particle size 11-16 μm, titanium oxide 40-55%, tin oxide coating) Reflection at light-receiving angles of 0° and 45° Strength comparison Titanium oxide, iron oxide coated mica (*3) RELIEF COLOR BEIGE (manufactured by Nikki Shokubai Kasei Co., Ltd.) (titanium oxide content: 14.5-17.5%, iron oxide content: 1.5-5.5%, silica content: 7-10%) Light-receiving angle: 0° 45° reflection intensity comparison

Preferred embodiments of the present invention are described in detail below. However, the present invention is not limited to the following preferred embodiments, and can be freely modified within the scope of the present invention. In this specification, percentages are indicated by mass (mass/mass %) unless otherwise specified. Moreover, the upper limit (or less) and lower limit (or more) of each numerical range (to) can be arbitrarily combined as desired. Furthermore, the "average particle size" in this specification is measured by observing the surface state using a scanning electron microscope (manufactured by JEOL, JSM-7800prime) and using an image analyzer (Luzex AP, manufactured by Nireco). It is the value (median diameter D50) obtained by , and indicates the major diameter of the particles.

<Component (A)>
Component (A) used in the present invention is synthetic phlogopite coated with titanium oxide and tin oxide and having an average particle size of 5 to 16 μm. Synthetic phlogopite is a hydroxy group (hydroxy group ) is fluorine-substituted synthetic fluorphlogopite (synthetic mineral), and synthetic mica. Brilliance is to impart a good feeling of brilliance to the skin, and the intensity of reflection varies depending on the angle of reflection, giving a feeling of luster.
Component (A) is a coating of titanium oxide and tin oxide, and tin oxide is used to stabilize the titanium oxide coating. There is no particular limitation on the amount of any coating. Component (A) may be further provided with another metal oxide coating and/or surface treatment. Among them, those containing iron are more preferable. In that case, it is not particularly limited whether it is coated with iron oxide or contains iron inside the matrix, but synthetic phlogopite iron containing iron in synthetic phlogopite as the matrix is more preferable. This matrix is more preferable because it is a flaky powder, which improves smooth spreadability and, after application, is superior in natural skin correction effect and high covering effect against color unevenness.

The synthetic mica powder containing an iron element in the crystal structure of the component (A) powder used in the present invention can be produced by a melt synthesis method, or a known melt synthesis method. . In order to produce synthetic mica containing iron element by a melt synthesis method, raw materials such as potassium silicofluoride, magnesium oxide, aluminum oxide, silicon dioxide, and optionally iron oxide are mixed in a predetermined number of moles, and heated to 1400°C. After being melted at ~1600°C, it is cooled and crystallized. The obtained crystal mass is pulverized by a known pulverization method, treated with stirring in an aqueous acid solution, dehydrated, washed and dried. This dry powder can be heat-treated at 700 to 1200° C. to obtain a synthetic phlogopite iron powder.
Component (A) used in the present invention is preferably titanium oxide-coated synthetic phlogopite iron coated with titanium oxide. The composite powder of component (A) coated with titanium oxide is particularly preferable because it has a high natural skin correction effect in terms of color. When the composition according to the present invention is applied, since the surface is coated with titanium oxide, the effect of covering the uneven color is further enhanced, and in addition to the glossy finish, the color change when it is wet with sebum from a dry state is reduced. , is preferred because it also enhances the makeup lasting effect. Furthermore, the composite powder of the component (A) coated with titanium oxide is more preferable because it has an excellent blue light cut effect and an ultraviolet shielding effect. As a specific example, synthetic phlogopite iron coated with 11 to 14% titanium oxide is preferable, and tin oxide coated as a binder for titanium oxide is more preferable due to the coating stability of titanium oxide. Although the amount of tin oxide is not particularly limited, a preferred example is one coated with 0.5 to 2.0%, and the crystal system of titanium oxide is preferably rutile type.

In the component (A) used in the present invention, the synthetic phlogopite powder may be further coated with titanium oxide by a known coating method. For example, synthetic mica powder containing elemental iron is suspended in a dilute aqueous solution of titanic acid, heated to 70 to 100° C., and the titanium salt is hydrolyzed onto the synthetic mica powder containing elemental iron. It can be produced by precipitating hydrated titanium oxide particles and then firing them at a high temperature of 700 to 1000°C. The surface may be coated with an acid before the reaction. By such a known coating method, the titanium oxide-coated synthetic phlogopite iron used in Examples below can be produced. The amount of surface treatment of each metal contained in the sample (powder) was determined by ICP (Inductively Coupled Plasma; ARCOS (Germany Spectro)) emission analysis of a sample prepared using a general method. It can be obtained by measurement.

The component (A) used in the present invention preferably provides both specular reflected light and diffuse reflected light and has a small difference in reflection intensity. In that case, it is preferable because it does not exhibit excessive luster that may be perceived as glare. 0.05 g of component (A) per unit area of [5 × 8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and blackened at an incident angle of -45 degrees using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a non-reflective background, the ratio of the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity [I (O)] at a light receiving angle of 0 degrees at wavelengths of 450 nm and 650 nm [I (45)] / [I (O)] are both preferably in the range of 1 to 5, more preferably in the range of 1.1 to 3, and 1.3 to 2.5 Ranges are more preferred. This range is more preferable because it is excellent in luster without excessive luster and glare, and is excellent in the speed at which the cosmetic film is uniformly finished. Furthermore, the ratio of the reflection intensity [I (45)] at the light receiving angle of 45 degrees at the wavelengths of 450 nm and 650 nm is [I (45)] (450 nm): [I (45)] (650 nm) = 3: 2 to 1: 3 is preferred, and 1:1 to 1:2 is more preferred. Within this range, it is more preferable because it provides a natural skin correcting effect and an excellent color unevenness covering effect while maintaining a suitable lustrous feeling. Such component (A) is commercially available, for example, as shown in FIG. can be done. The surface of these powders may be further coated with iron oxide and/or iron hydroxide, an organic pigment, or the like. Further, as a developed product, as shown in FIG. 4, titanium oxide-coated synthetic phlogopite iron (average particle size: 5-11 μm, titanium oxide: 11-14%, tin oxide coating) is more preferable.

The color tone of the component (A) used in the present invention is not particularly limited, but can be represented by the CIE1976L*a*b* color system, and the measured values of the CIE1976L*a*b* color system are known. It can be performed using a CIE1976L*a*b* color system measuring instrument. The color tone of the component (A) in the CIE1976L*a*b* color system is measured using a spectral colorimeter (for example, a spectral colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.)) at an incident angle of -45° and a light receiving angle. In the measurement at 0°, when the component (A) was tapped on the cell 20 times and measured, the colorimetric values L* (lightness) and C* (chroma) specified in the CIE1976L*a*b* color system were obtained. ) and h (hue) are preferably in the ranges of 63<L*<83, 12<C*<32, and 50<h<76. More preferable ranges are 63<L*<75, 18<C*<25, and 50<h<70. In particular, the range of 68<L*<75, 18<C*<25, 55<h<70 is more preferable, and as a specific example, for example, 11 to 14% titanium oxide having an average particle size of 5 to 11 μm is coated. is a synthetic phlogopite iron coated with tin oxide as a binder for titanium oxide. Containing this component (A) improves smooth spreadability, does not give a feeling of glare after application, provides a natural skin correction effect and an uneven color cover effect, and in particular eliminates color unevenness, spots, dark circles, etc. It is effective for application to areas with color tone troubles, and has excellent make-up durability.

The component (A) blue light cut agent used in the present invention has a blue light cut effect with a wavelength of 380 to 500 nm. In particular, the component (A) uniformly containing iron oxide is more preferable. The blue light cut function (380 to 500 nm shielding rate) has a suitable lower limit of preferably 30% or more, more preferably 35% or more, more preferably 40% or more, more preferably 45% or more, more preferably 50% or more are. As the component (A) used for the purpose of cutting blue light, titanium oxide-coated synthetic phlogopite iron is more preferable, and a blue light cutting function (380 to 500 nm shielding rate) of 40% or more is preferable. . More preferably, titanium oxide and tin oxide coated synthetic phlogopite iron composites are suitable. When tin oxide is used in combination, the crystal structure of the coated titanium oxide tends to be of the rutile type, which is preferable in terms of the stability of the coated titanium oxide. The evaluation of the blue light cut effect and the confirmation test of the evaluation of the effect will be described later in [Examples].

The coating amount of titanium oxide in the component (A) used in the present invention is not particularly limited, but when the component (A) is converted to 100%, the coating amount is preferably 1% or more as a suitable lower limit , More preferably 5% or more, still more preferably 9% or more, and a suitable upper limit is preferably 25% or less, more preferably 18% or less, and still more preferably 14% or less. The range is preferably 1-25%, more preferably 5-18%, most preferably 9-14%. Within this range, a natural skin correcting effect, a high covering effect for color unevenness, an excellent makeup lasting effect, and a blue light cutting effect can be obtained, which is more preferable.

Further, the component (A) used in the present invention is preferably subjected to a surface treatment with a surface treatment agent (preferably a treatment agent (hydrophobizing agent) for making powder water-repellent). A known surface treating agent can be used as the surface treating agent, and among these surface treating agents, those surface-treated with silicone compounds (also referred to as silicones), acylated amino acids, metallic soaps, and fatty acids are preferred. . Among them, a dimethicone-treated synthetic phlogopite iron powder or a dimethicone-treated titanium oxide-coated synthetic phlogopite iron powder is preferable. The method for surface-treating the powder such as the synthetic phlogopite-iron powder or the titanium oxide-coated synthetic phlogopite-iron composite with the surface-treating agent is not particularly limited, and a generally known method can be used. At this time, the content of the surface treatment compound in the powder is not particularly limited, but is preferably 0.1 to 10%, more preferably 0.2 to 5%, even more preferably 0.5 to 3%. As for the surface treatment, the surface treatment methods for components (A) and (B), which will be described later, can also be employed as appropriate.

Component (A) used in the present invention has an average particle size of 5 to 16 μm. Within this range, there is no unpleasant glare that emphasizes unevenness, and the effect of covering unevenness on the skin surface (for example, pores, wrinkles, etc.) is excellent, and natural skin correction effects, color unevenness and unevenness are achieved. It is more preferable because it has a high covering effect on the skin and an excellent makeup lasting effect.
Specific examples of synthetic phlogopite coated with titanium oxide and tin oxide and having an average particle size of 5 to 16 μm include the HELIOS R10 series (manufactured by Topy Industries, Ltd.), particularly flesh colors such as R10R and R10Y. Interfering light close to is preferred. However, the component (A) of interference light such as blue, green, purple, and silver may be used together by correcting the hue of the light, and there is no particular limitation. Further, as the synthetic phlogopite iron as the matrix, for example, PDM-FE (manufactured by Topy Industries, Ltd.) is used to coat titanium oxide and tin oxide. When the synthetic phlogopite of the component (A) is synthetic phlogopite iron, the content in terms of iron oxide in the synthetic phlogopite iron is not particularly limited, but a suitable lower limit is preferably 8% or more. % or more, more preferably 10% or more, and a suitable upper limit is preferably 15% or less, more preferably 14% or less, and more preferably 13% or less. Within this range, it is easier to achieve both smoothness and a natural covering effect when using cosmetics, maintain the smooth shape of the synthetic phlogopite iron, and easily achieve an optimum color that is close to the skin color of yellow people. Become.

The content of the component (A) in the powder cosmetic of the present invention is not particularly limited, but as a suitable lower limit, it is preferably 0.02% or more, more preferably 0.5% or more, and still more preferably 1% or more. , More preferably 3% or more, more preferably 5% or more, and a suitable upper limit is preferably 25% or less, more preferably 20% or less, more preferably 18% or less, and more preferably 15% or less. Preferably, 12% or less is more preferable. Within this range, the natural skin correcting effect, the high covering effect for color unevenness, and the long-lasting effect of makeup are superior, which is more preferable.

<Component (B)>
The powder cosmetic of the present invention further contains, as a component (B), one or more fine-particle metal oxides selected from titanium oxide and zinc oxide other than the component (A), and the shape of the metal oxide is Powder is preferred. In a more preferred embodiment, component (B) may contain one or more metal oxides selected from titanium oxide and zinc oxide having an average particle size of 0.01 to 4.0 μm. When the average particle size is within this range, it is more preferable because it facilitates adjustment of a smooth feeling during application, a high covering effect for natural color unevenness and irregularities, and is excellent in makeup lasting effect. The shape of the titanium oxide and zinc oxide is not particularly limited, such as spherical, plate-like, needle-like, or spindle-like, and the particle structure such as porous or non-porous.
Specific commercial products that can be used as component (B) include, for example, MP-18, MP-701, MP-1133, MP-40, MP-100, MT-01, MT-05 and MT100 series. , MT500 series, MT700 series, MZ-300 series, MZ-500 series, etc. or composite powder thereof (manufactured by Tayca), XZ-300F, XZ-1000F, XZ-3000F, MKR-1, FINEX-20-LP , FINEX-30-LP2, STR-100 series, etc. (manufactured by Sakai Chemical Industry Co., Ltd.), SYMPHOLIGHT series (manufactured by Nikki Shokubai Kasei Co., Ltd.), RONAELAIR BLANCSEALER (manufactured by Merck Performance Materials Co., Ltd.), ZnO-CX (manufactured by Sumitomo Osaka Cement Co., Ltd.) ), ST series (manufactured by Titan Kogyo Co., Ltd.), and Solabel XTP-1 (manufactured by Croda Japan Co., Ltd.), but are not limited thereto. Moreover, component (B) may be produced by a known production method, and is not particularly limited.
Further, it is preferable that the surface of the component (B) used in the present invention is further coated with an iron oxide or hydroxide. The component (B) used in the present invention may be coated with oxides or hydroxides of iron, oxides or hydroxides of silicon, oxides or hydroxides of aluminum as respective layers. In the case where the component (B) is further coated with iron oxide, the coating amount is not particularly limited. (in iron oxide-coated titanium dioxide or iron oxide-coated zinc oxide), the preferred lower limit is 0.5% or more, more preferably 0.6% or more, still more preferably 0.7% or more. The upper limit is preferably 5% or less, more preferably 3.5% or less, still more preferably 3%, and the preferred numerical range is preferably 0.5 to 5%, 0.7 to 3.5 % is more preferred, and 0.9 to 3% is even more preferred. This range is more preferable because it provides a more natural skin correction effect. In the present invention, component (B) can be used alone or in combination of two or more, if necessary.

The average particle size of component (B) in the present invention is not particularly limited, but in the case of a single particle, the preferred lower limit is preferably 0.010 μm or more, more preferably 0.035 μm or more, and 0.01 μm or more. 1 μm or more is more preferable, and the preferable upper limit is preferably 4.0 μm or less, more preferably 3.0 μm or less, and even more preferably 1.0 μm or less. Within this range, the effect of covering the skin bumps naturally is superior. As for the range, an average particle size of 0.035 to 3.0 μm is more preferable because the natural covering effect can be easily adjusted. The component (B) used in the present invention is particularly preferably in the form of a plate, and the component (B) itself may be in the form of a plate, or a plate of mica, synthetic mica, glass, silica, alumina, or the like. More preferably, it is in the form of a composite plate-like powder in which the component (B) is adsorbed on the surface of the matrix. The component (A) may be included in the plate-like powder matrix. In this case, the lower limit of the thickness of component (B) itself is preferably 0.010 µm or more, more preferably 0.035 µm or more, even more preferably 0.1 µm or more, and the upper limit is preferably 1.0 µm or less. Within this range, the natural skin correction effect and the high covering effect for color unevenness are excellent, which is preferable.

The content of component (B) in the powder cosmetic of the present invention is not particularly limited, but the preferred lower limit is preferably 1% or more, more preferably 5% or more, based on the total amount (100% by mass) of the cosmetic. It is more preferably 7% or more, and a suitable upper limit is preferably 20% or less, more preferably 15% or less, and still more preferably 12% or less. Preferably, 5 to 15% is more preferable, and 7 to 12% is even more preferable. Within this range, the natural skin correction effect and the high covering effect for color unevenness are excellent, which is preferable.

<Surface treatment method for component (A) or (B)>
Component (A) and component (B) used in the present invention are each further surface-treated with a generally known surface-treating agent such as a silicone compound, an acylated amino acid or its salt, a metal soap, a fatty acid, a surfactant, or the like. is preferably applied. Among them, the use of those surface-treated with a hydrophobizing surface treatment agent improves the dispersibility of the metal oxide in the cosmetic, increases the adhesion to the skin, and provides a high covering effect for color unevenness and unevenness. It is preferable in that it can improve durability. In the powder cosmetic of the present invention, for example, component (A) and/or treated with a silicone compound and/or a surface treatment agent having a fatty group having 16 to 24 carbon atoms (also referred to as a surface treatment compound) Component (B) is preferably used.
More specifically, the silicone compounds include dimethicone, methicone, hydrogen dimethicone, triethoxysilylethylpolydimethylsiloxyethyldimethicone, and triethoxysilylethylpolydimethylsiloxyethylhexyl, as represented by INCI names (International Nomenclature Cosmetic Ingredient labeling names). Examples thereof include dimethicone, (acrylates/tridecyl acrylate/triethoxysilylpropyl methacrylate/dimethicone methacrylate) copolymer, triethoxycaprylylsilane, etc., and one or more selected from these can be used. Among surface treatments with silicone compounds, dimethicone treatment is more preferable in terms of spreadability and make-up lasting.
Among the surface treatment agents (also referred to as surface treatment compounds) having an aliphatic group having 16 to 24 carbon atoms, specific examples include surface treatment agents having nitrogen sources such as acylated amino acids, phospholipids and sphingolipids, More preferably, one or more selected from oil agents having an ester group, fatty acids (salts), higher alcohols, ethoxysilane surface treating agents, and alkyl titanate surface treating agents.
In particular, when a surface treatment agent having a highly crystalline saturated straight-chain fatty group is used as the fatty group, a high covering effect for color unevenness and unevenness is likely to be obtained, so the dosage form has good spreadability. , it can be expected to improve the adhesion on the skin. In addition, when a surface treatment agent having an unsaturated fatty group or a branched saturated fatty group is used, a smooth feeling of use can be obtained, especially in the case where the continuous layer is air or in a dosage form that does not spread easily. may be effective. All of them have a fatty group with 16 to 24 carbon atoms, so that the adhesiveness to the skin is enhanced, the effect of covering the skin bumps is maximized with a small amount, and the effect of improving the longevity of the makeup is excellent.
As the surface treatment of component (A), silicone surface treatment or dimethicone surface treatment is preferred. In addition, the surface treatment of component (B) includes silicone surface treatment (e.g. dimethicone surface treatment), acylated amino acid treatment, metal soap treatment, sphingolipid surface treatment (e.g. ceramide NG surface treatment), phospholipid surface treatment (e.g. hydrogenated 1 or 2 or more selected from phospholipid surface treatment, etc. are preferable. The surface treatment agent for surface treatment of the powder used in the present invention is not particularly limited. , high viscosity silicone, crosslinked silicone, fluorine-modified silicone, acryl-silicone graft copolymer, silicone compounds such as silicone resins; anionic surfactants, cationic surfactants, nonionic surfactants and other surfactants, metals Soaps, polyisobutylene, waxes (e.g. beeswax), oils such as higher fatty acids and higher alcohols, amino acid compounds such as N-acyl amino acids, perfluoroalkyl phosphoric acid and its salts, fluorine compounds such as perfluoroalkylsilanes, lecithin , phospholipids such as hydrogenated phospholipids, sphingolipids such as ceramide NG (2), and the like, and one or more selected from these can be used.
The surface treatment agents may be used singly or in combination of two or more, and can be appropriately adjusted according to the dosage form of the cosmetic. In addition, the treatment method includes a wet treatment in which the processing agent and powder are mixed in a solvent in a slurry form, kneaded in a planetary mixer or the like, and then the solvent is removed and the surface is treated. A dry treatment in which the treatment is performed by stirring in a mixing machine such as a mixer can be mainly used, and is preferable in terms of efficient surface treatment and improved dispersibility. The amount of surface treatment is not particularly limited.

(A) / [(A) + (B)], which is the mass ratio of components (A) and [(A) + (B)] used in the present invention, is preferably 0.001 or more, 0.10 or more is more preferable, and 0.20 or more is even more preferable. The upper limit is 1.00 or less, preferably 0.85 or less, and more preferably 0.70 or less. The range is preferably 0.05 to 0.85, more preferably 0.07 to 0.80, even more preferably 0.10 to 0.70. Within this range, it is not only more preferable because it is more excellent in both a natural skin correction effect and a high covering effect for color unevenness and unevenness, but it is also preferable in terms of the balance between effect and cost.

<Component (C)>
The present invention further contains, as component (C), one or more substantially spherical powders selected from naturally occurring water-insoluble polymers and silicic anhydride. A spherical shape includes not only a true spherical shape but also a substantially spherical shape, an ellipsoidal shape, a pseudo-spherical shape, etc., and the ratio of major axis/minor axis is preferably 1.5/1 to 1/1, more preferably 1.2/1. It is in the range of ~1/1. The spherical powder of component (C) may have a smooth surface, may have holes on the surface, or may have fine irregularities on the surface. The powder is not particularly limited as long as it can be used as a powder in cosmetics. Spherical particles with high light scattering properties are particularly preferred in terms of the pore-covering effect.

The naturally-derived water-insoluble polymer of the component (C) used in the present invention includes a polymer whose starting material is an animal-derived or plant-derived polymer. Addition of 0.0% lowers the transparency of the aqueous solution. In addition, among component (C), for example, one or two selected from cellulose powder and starch powder, which are naturally-originated or plant-derived organic powders (preferably polysaccharide powders), and silica, which is an inorganic powder. The above are more preferable in terms of the pore-covering effect. Among cellulose powders, crystalline cellulose powder is preferred. Among starch powders, crosslinked or non-crosslinked corn-derived starch powder, wheat-derived starch powder, rice-derived starch powder, and powders of chemically modified products having these skeletons (e.g., hydroxypropyl starch, octenyl succinic acid corn starch salts, etc.); metal oxide-coated starches (for example, titanium oxide-coated cornstarch, etc.) powders; In addition, the hydrophobized component (C) treated with the surface treating agent described as the surface treating agent for component (A) and/or component (B) is more preferable.

The average particle size of the component (C) used in the present invention is not particularly limited, but the preferred lower limit is preferably 0.5 μm or more, more preferably 4.0 μm or more, and the preferred upper limit is 40 μm or less. It is preferably 30 μm or less, more preferably 30 μm or less. Within this range, the effect of making unevenness of the skin less conspicuous can be expected.

The content of the component (C) in the powder cosmetic of the present invention is not particularly limited, but the preferred lower limit is preferably 5% or more, more preferably 8% or more, in the total amount of the cosmetic (100% by mass). 10% or more is more preferable, and a suitable upper limit is preferably 50% or less, more preferably 40% or less, even more preferably 30% or less, and more preferably 20% or less. When the component (C) is contained in this range, it is preferable because it is excellent in the effect of improving the smooth feeling of use and making unevenness of the skin less noticeable. The effect of the component (B) can be supplemented, and at the same time, the texture of the overall finish of the cosmetic can be adjusted.

The ratio of component (A) to component (C) in the powder cosmetic of the present invention, (A)/(C), is not particularly limited, but is particularly important for achieving both uneven color and a high covering effect for unevenness. . As a lower limit, 0.001 or more is preferable, 0.05 or more is more preferable, and 0.1 or more is more preferable.
The upper limit is preferably 8.0 or less, more preferably 2.0 or less, and even more preferably 1.0 or less. The range is preferably 0.05 to 5.0, more preferably 0.07 to 3.0, even more preferably 0.1 to 2.0. Within this range, it is more preferable because it is more excellent in achieving both a natural skin correcting effect and a high covering effect for color unevenness and unevenness.

<Component (D)>
The powder cosmetic of the present invention further contains a silicone oil having a kinematic viscosity at 25° C. of 6 to 100 mm ² /s as component (D). Although the structure of the silicone oil is not particularly limited, it is a non-volatile oil that has a polysiloxane skeleton and does not have a volatility of 50% or more at 25° C. and normal pressure. Specifically, for example, silicone oils include dimethylpolysiloxane, phenyl-modified polysiloxane (e.g., methylphenylpolysiloxane), alkyl-modified silicone, cyclic siloxane (e.g., octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.). ), methyl trimethicone, and the like, but are not limited thereto. One or two or more of these can be appropriately selected and used. In addition, it is preferable that the kinematic viscosity is within this range because the dispersibility of the component (A) is improved, and the high effect of covering uneven color and the long-lasting effect of makeup are excellent.

Component (D) used in the present invention is preferably dimethylpolysiloxane and/or phenyl-modified polysiloxane.
Commercial products of dimethylpolysiloxane include KF-96A-6CS (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-96-10CS (manufactured by Shin-Etsu Chemical Co., Ltd.), SH200C FLUID 6CS (manufactured by Toray Industries, Inc.), phenyl-modified poly Commercial products of siloxane include, for example, triphenyldimethylvinyldisiloxane (eg, commercial product: SILSHINE VP), diphenylsiloxyphenyl trimethicone (eg, commercial product: KF-56 (methylphenylpolysiloxane), etc.), trimethylpentaphenyl Trisiloxane, diphenyl dimethicone (eg, commercially available product: Silicon KF-54 (methylphenylpolysiloxane), etc.), trimethylsiloxyphenyl dimethicone (eg, commercially available product: BELSIL PDM1000, etc.), but not limited thereto. Alternatively, it may be produced by a known production method. These 1 type(s) or 2 or more types can be used.

The content of the component (D) used in the present invention is not particularly limited as long as it exhibits the effect of the present invention, but the lower limit is preferably 0.1% or more, and 1% or more. is more preferable, and 2% or more is even more preferable. The upper limit is preferably 30% or less, more preferably 15% or less, and even more preferably 5% or less. The range is preferably 1-10%, more preferably 2-5%. Within this range, the dispersibility of the component (A) is improved, and a high covering effect for color unevenness and an excellent makeup lasting effect are obtained, which is preferable.

<Components other than components (A) to (D)>
In addition to the above ingredients, the powder cosmetic of the present invention contains water-soluble polymers, ultraviolet absorbers, paraoxybenzoic acid derivatives, preservatives such as phenoxyethanol, vitamins, cosmetic ingredients, moisturizers, surfactants, and cross-linked emulsifiers. Optional components such as a flexible silicone elastomer and powders other than the above components (A), (C) and (D) can be appropriately contained within a range that does not impair the effects of the present invention. The powdery cosmetic of the present invention can be produced by appropriately adopting known production methods such as blending, mixing, emulsifying, etc. using the above-described components (A) and (B), etc., to obtain the type and form of the desired cosmetic. can be prepared.

Although the method for producing the powder cosmetic of the present invention is not particularly limited, a known powder cosmetic production method can be applied. Among the methods for producing the powdery cosmetic of the present invention, it is preferable to use the dry molding method and the wet molding method for the solid powdery cosmetic. The dry molding method is, specifically, a method of mixing powder and an oil solution and compressing and molding the mixture into a container. The wet molding method is a wet molding method including mixing powder, oil and solvent in any order. The solvent can be added at any time, is a component that can be used in the production of powdered solid cosmetics, and can be either volatile or non-volatile. If it is volatile, it is preferable to evaporate it after molding, and if it is non-volatile, when the molding surface is rubbed at the time of use, an appropriate amount that can be applied to the skin can be obtained. It may be molded as it is or either. Among the methods for producing powdered cosmetics of the present invention, in the case of powdered cosmetics, steps such as mixing and/or pulverization can be used.

<Cosmetics>
The powdery cosmetic composition of the present invention can be applied to make-up cosmetics such as eye color, eyebrow, foundation, blusher, white powder, and foundation, skin care cosmetics such as body powder, sunscreen cosmetics, and the like. One type or two or more types can be selected. Moreover, the powder cosmetic of the present invention may be a composition or may be used as an external skin preparation.

The form of the powdery cosmetic of the present invention is not particularly limited, but may be either powdery or powdery solid, and one or more of these may be selected. In particular, powdery solid cosmetics are preferred in terms of exhibiting a natural concealing effect.

The present invention will be further described with reference to Examples and the like below. In addition, these do not limit this invention at all.

<Blue light cut effect evaluation of component (A) used in the present invention> (see FIGS. 1 and 2)
The blue light cut effect of the component (A) used in the present invention was evaluated as follows.
FIG. 1 shows the measured transmittance (100%-transmittance=shielding rate) for each wavelength of the component (A) used in the present invention and a comparative product. From the transmittance, the blue light cut function (blocking rate of 380 to 500 nm) was calculated and shown in FIG.
The samples were composed of component (A) titanium oxide, tin oxide-coated synthetic phlogopite iron (average particle size 5-11 μm, titanium oxide coating amount 11-14%), titanium oxide, tin oxide-coated synthetic phlogopite (average particle size 11 ~ 15 μm, titanium oxide coating amount 46%) * 1, synthetic phlogopite (average particle size 5 μm, PDM-5L: manufactured by Topy Industries)), synthetic phlogopite iron (average particle size 5 to 11 μm, PDM -FE: manufactured by Topy Industries, Ltd.)). The sample was suspended in IPA (isopropyl alcohol) to a concentration of 20% and dispersed by Despa. A coating film was drawn on a quartz plate with a 12.5 μm doctor blade, and after drying, the transmittance was measured using an integrating sphere UV-2600 (UV-VIS SPECTROPHOTOMETER) (manufactured by Shimadzu Corporation).

As a result, the blue light cut effect of the component (A) used in the present invention is the highest for titanium oxide-coated synthetic phlogopite iron (average particle size 5 to 11 μm, titanium oxide coating amount 11 to 14%, tin oxide coating). , Titanium oxide, tin oxide-coated synthetic phlogopite (average particle size 11-15 μm, titanium oxide coating amount 46%)*1, or synthetic phlogopite iron (average particle size 5-11 μm) can be seen to some extent, and synthetic phlogopite ( No effect was observed with respect to the average particle size of 5 μm).

<CIE1976L*a*b* color system measurement test of component (A) used in the present invention> (see Table 1)
Spectral colorimeter SE7700 (manufactured by Nippon Denshoku Industries Co., Ltd.) was used to measure the incident angle of -45 ° and the acceptance angle of 0 °, and the component (A) was tapped 20 times in the cell to measure CIE1976L *. Colorimetric values L* (lightness), C* (chroma), and h (hue) of color values defined by the a*b* color system were determined. The results are shown in Table 1 below.

<Reflection intensity test of component (A) used in the present invention by a gonio-colorimeter> (see Table 1 and FIGS. 3 to 6)
0.05 g of the component (A) used in the present invention is applied to the adhesive surface of the transparent adhesive tape per unit area of [5×8] cm ² , and the goniospectrophotometric system GCMS-3B (Murakami Co., Ltd.) is used. Using a D65 light source (manufactured by Shiki Gijutsu Kenkyusho Co., Ltd.), the reflection intensity was measured at an incident angle of -45 degrees with a black non-reflective background.
An explanation of the evaluation angle is shown in FIG. 3, and the results are shown in FIGS. (O)] ratio [I(45)]/[I(O)] and the values of the reflection intensity [I(45)] at a light receiving angle of 45 degrees at wavelengths of 450 nm and 650 nm are shown together with the color values. 1.

Of the component (A), the color tone of the titanium oxide-coated synthetic phlogopite iron is in the range of 63<L*<75, 18<C*<25, 50<h<70, and is the general skin color of yellow people. was close to Further, component (A) is the ratio [I(45)]/ It was suggested that [I(O)] is small, the angle dependence is low, and the reflectivity has reflection characteristics in which the difference in reflection intensity depending on the wavelength falls within a specific range.

<Tables 2-3: Examples 1-24, Table 4: Comparative Examples 1-6, powder foundation (dry process)>
Using the component (A) described above and a comparative product, a powder foundation was prepared with the following composition.

※１：ＨＥＬＩＯＳ Ｒ１０Ｒ（トピー工業社製）
※２：ＰＤＭ－ＦＥ（ＴＳ）（トピー工業社製）
※８：シリカマイクロビードＰ－１５０５（日揮触媒化成社製)の（ジメチコン／ビニルジメチコン）クロスポリマー０．５％処理品
※１２：ブラウン酸化鉄ＢＢＲ－２１３ＨＰ（チタン工業社製）のジメチコン処理品
※１３：ＡＢＬ－２０５ＣＳ（チタン工業社製）のジメチコン処理品
※１４：ＳＡ－タルクＪＡ－４６Ｒ（三好化成工業社製）
※１５：ＳＡ－ＰＤＭ－１０Ｌ（三好化成工業社製）
※１６：Ｒｏｎａ Ｆｌａｉｒ ＬＦ－２０００（メイクパフォーマンスマテリアルズ社製）
※１７：ＫＦ－５６（信越化学工業社製)
※１８：ＣＲＯＤＡＭＯＬ ＯＳＵ（クローダジャパン社製）
※１９：ニッコール レシノールＳ－１０（日光ケミカルズ社製）

*1: HELIOS R10R (manufactured by Topy Industries)
*2: PDM-FE (TS) (manufactured by Topy Industries, Ltd.)
*8: Silica microbead P-1505 (manufactured by Nikki Shokubai Kasei Co., Ltd.) (dimethicone/vinyl dimethicone) crosspolymer 0.5% treated product *12: Brown iron oxide BBR-213HP (manufactured by Titan Kogyo Co., Ltd.) dimethicone treated product *13: Dimethicone-treated product of ABL-205CS (manufactured by Titan Kogyo Co., Ltd.) *14: SA-talc JA-46R (manufactured by Miyoshi Kasei Co., Ltd.)
*15: SA-PDM-10L (manufactured by Miyoshi Kasei Co., Ltd.)
*16: Rona Flair LF-2000 (manufactured by Make Performance Materials)
*17: KF-56 (manufactured by Shin-Etsu Chemical Co., Ltd.)
*18: CRODAMOL OSU (manufactured by Croda Japan)
*19: Nikkor Resinol S-10 (manufactured by Nikko Chemicals)

※５：ＸＺ－３００Ｆ－ＬＰ（堺化学工業社製）
※６：ＭＰ－４０（テイカ社製）のジメチコン０．３％処理品
※７：ＭＰ－７０１（テイカ社製）のジメチコン０．３％処理品
※９：サンスフェア ＮＰ－３０（ＡＧＣエスアイティック社製)のシリコーンＫＦ－５０ＣＳ １％処理品
※１０：Ｃｅｌｌｕｌｏｂｅａｄｓ Ｄ－５ （大東化成工業社製）のトリイソステアリン酸イソプロピルチタン処理品

*5: XZ-300F-LP (manufactured by Sakai Chemical Industry Co., Ltd.)
*6: MP-40 (manufactured by Tayca) processed with 0.3% dimethicone *7: MP-701 (manufactured by Tayca) processed with 0.3% dimethicone *9: Sunsphere NP-30 (AGC S.I.Tic) (manufactured by Daito Kasei Kogyo Co., Ltd.) silicone KF-50CS 1% treated product *10: Cellulobeads D-5 (manufactured by Daito Kasei Kogyo Co., Ltd.) treated with isopropyl titanium triisostearate

※３：ＲＥＬＩＥＦ ＣＯＬＯＲ ＢＥＩＧＥ（日揮触媒化成社製）
※４：ＣＯＳＭＥＴＩＣＡ ＦＩＮＥ ＷＨＩＴＥ Ｎ－８０００Ｄ（ＣＱＶ社製）（平均粒子径４～２５μｍ）
※１１：ＫＳＰ－１００（信越化学工業社製)

*3: RELIEF COLOR BEIGE (manufactured by Nikki Shokubai Kasei Co., Ltd.)
*4: COSMETICA FINE WHITE N-8000D (manufactured by CQV) (average particle size 4-25 μm)
*11: KSP-100 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Manufacturing method: manufactured by containing only the components listed in Tables 2 to 4)
A. 1 to 26 are uniformly mixed with a super mixer.
B. 27 to 33 are uniformly mixed and dissolved.
C. Add B to A and mix uniformly.
D. C was pulverized, filled in a container, and compression-molded to obtain a powder foundation.

(Evaluation method)
The following evaluation items (a) to (c) were evaluated by the following methods.
(Evaluation item)
stomach. Natural skin correction effect b. High cover effect for color unevenness and unevenness c. makeup lasting effect

Each sample was applied by 20 specialist panels using a cosmetic puff, and each item from A to C was evaluated in 5 stages according to the following absolute evaluation criteria, and each sample was scored. The average score of all panels was determined according to the following criteria. In addition, the “natural skin correction effect” is whether there is an unnatural white film feeling immediately after application, whether it feels like the skin is naturally corrected without a technical gloss, or “color unevenness and unevenness”. Regarding "high coverage effect", immediately after application, whether color unevenness such as spots and freckles, uneven unevenness such as pores and wrinkles were hidden, and "makeup lasting effect" was compared immediately after 8 hours after application. It was evaluated whether or not the initial state was maintained without deterioration of the cosmetic film.

<Absolute evaluation criteria>
(Rating): (Evaluation)
5: very good 4: good 3: fair 2: bad 1: very bad

(Judgment): (Average score)
AA: 4.5 points or more: Very good A: More than 4 points and 4.5 points or less: Good B: More than 3 points and 4 points or less: Fairly good C: 3 points or less than 2 points: Somewhat poor D: 2 points or less: Poor

As is clear from the results in Table 1, the powder foundations of Examples 1 to 21, which are the products of the present invention, have a natural skin correction effect, and are excellent in covering color unevenness and unevenness. It was a powder cosmetic that was highly effective and excellent in all items. On the other hand, Comparative Example 1 having a large particle size glittering powder not containing the component (A), Comparative Example 2 using only synthetic phlogopite iron, and Comparative Example 3 containing a mica-based glittering powder were all mainly used. However, the natural skin correction effect was not satisfactory, and depending on the type, the blue light cut effect was also unsatisfactory. In particular, when synthetic iron phlogopite was used alone, the makeup lasting effect was inferior in that the color tended to fade. In addition, Comparative Example 4, which does not contain component (B), has a high covering effect on color unevenness and irregularities and a low blue light cutting effect, and Comparative Example 5, which contains substantially spherical powder of a synthetic polymer instead of component (C). In addition, in Comparative Example 6, which does not contain component (C), the long-lasting effect was not satisfactory.

Example 25: Powder foundation (slurry)
A powder foundation was produced by a slurry method according to the following formulation and production method.
(Component) (%)
1. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron described in FIG. 4 5.0
2. Iron oxide-coated titanium dioxide (average particle size 400 nm) 10.0
3. Siliconized zinc oxide (average particle size 25 nm) 5.0
4. Boron nitride 8.0
5. Bismuth oxychloride 5.0
6. Red iron oxide 0.5
7. Yellow iron oxide 1.7
8. Black iron oxide 0.15
9. Talc Remaining amount 10. Spherical silica (average particle size 8 μm) 10.0
11. Lauroyllysine 4.0
12. Mica (average particle size μm) 10.0
13. Dimethicone 0.5
14. Diphenylsiloxyphenyl trimethicone 8.0
15. Isotridecyl isononanoate 5.0
16. Dimethylpolysiloxane 2.0
17. Chlorphenesin 0.2
18. Lemon extract 0.001
19. Pearl barley extract 0.001
20. Green tea extract 0.001
21. Fermented rice extract 0.001
22. Rice bran extract 0.001
23. Hyaluronic acid Na 0.001
24. Hydrolyzed collagen 0.001
25. Proteoglycan 0.001
26. Scutellaria root extract 0.001
27. Hydrolyzed soybean extract 0.001
28. Astaxanthin 0.001
29. Rose honey 0.001
30. Shea butter 0.001
31. Ceramide NG 0.001
32. Hummus extract 0.001
33. Keiketto extract 0.001
34. Theanine 0.001
35. Alum 0.001
36. Aluminum chlorohydroxyl 0.001

(Production method)
A. Mix 1 to 12 evenly with a super mixer.
B. A homogeneous mixture of components 13 to 36 was added to A, dispersed uniformly, and pulverized to obtain a cosmetic base.
C. 50 parts of a solvent (isododecane) was added to 100 parts of the cosmetic base material and mixed to obtain a slurry-like mixture.
D. 11 g of the mixture was filled in a round metal plate (5.5 cm in diameter) and compressed four times under the conditions of a press pressure of 2.0 kgf/cm ² , a press time of 4 seconds, and 6 sheets of paper to partially remove the solvent. . Then, it was dried at 70° C. for a whole day and night to remove the solvent to obtain a foundation.

The powder foundation (slurry) thus obtained was a powder foundation having a natural skin correcting effect, a high covering effect for color unevenness and irregularities, and a high makeup lasting effect.

Example 26: Foundation (property between solid powder and oily solid)
A foundation having properties between a solid powder and an oily solid was manufactured according to the formulation and manufacturing method described below.
(Component) (%)
1. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron 6.0 described in FIG.
2. Titanium oxide (average particle size 35 nm) 2.0
3. Iron oxide-coated titanium dioxide (average particle size 270 nm) 8.0
4. Zinc oxide (average particle size 25 nm) 1.0
5. Boron nitride (average particle size 3 μm) 5.0
6. Synthetic phlogopite (average particle size 10 μm) 8.0
7. Calcined sericite 14.0
8. Red iron oxide 0.5
9. Yellow iron oxide 1.7
10. Black iron oxide 0.15
11. Sericite remaining amount 12. Spherical porous silica (average particle size 8 μm) 5.0
13. Dimethyl silylated silica 0.2
14. Cellulose 0.5
15. (Dimethicone/vinyl dimethicone) crosspolymer 5.0
16. Diphenylsiloxyphenyl trimethicone 15.0
17. Glyceryl octanoate 5.0
18. Dimethylpolysiloxane 15.0
19. Pentylene glycol 0.2
20. Isododecane 5.0

(Production method)
A: Components 13 to 20 are dispersed and swollen with a three-roller.
B: Components 1 to 12 are added to A, and kneaded in a planetary mixer under reduced pressure.
C: B was filled in a container to obtain a foundation with properties between solid powder and oily solid.

The resulting foundation was a powder foundation that had a natural skin correcting effect, a high covering effect for color unevenness and irregularities, and an excellent makeup lasting effect.

Example 27: Pressed powder A pressed powder was produced according to the following formulation and production method.
(Component) (%)
1. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron described in FIG. 4 10.0
2. Iron oxide-coated titanium dioxide (average particle size 270 nm) 1.0
2. Titanium oxide (average particle size 35 nm) 2.0
3. Remaining talc 4. Mica Titanium 5.0
5. Synthetic phlogopite 8.0
6. Bismuth oxychloride 10.0
7. Calcined sericite 5.0
8. Spherical polyethylene powder (average particle size 10 μm) 4.0
9. spherical methyl methacrylate crosspolymer
(Average particle size 15 μm) 10.0
10. Spherical silica (average particle size 8 μm) 1.0
11. Red iron oxide 0.1
12. Yellow iron oxide 0.2
13. Black iron oxide 0.01
14. Dimethicone 0.5
15. Methyl paraoxybenzoate 0.2
16. 2-ethylhexyl para-methoxycinnamate 2.0
17. Pentaerythrityl tetraisostearate 2.0
18. Octyldodecyl stearoyloxystearate 2.0
19. Dimethylpolysiloxane (6CS) 3.0
20. (Dimethicone/vinyl dimethicone) crosspolymer 1.0
21. Squalane 0.5
22. Aluminum magnesium silicate 1.0

(Production method)
A. Ingredients 1-13 are uniformly mixed.
B. Components 14 to 22 were uniformly mixed with A, dispersed uniformly, and pulverized to obtain a cosmetic base material.
C. 70 parts of water was added to 100 parts of the cosmetic base material, mixed, and kneaded at room temperature.

The obtained pressed powder had a natural skin-correcting effect, was excellent in a high covering effect for color unevenness and unevenness, and had an excellent make-up lasting effect.

Example 28: Loose powder A loose powder was produced according to the following formulation and production method.
(Component) (%)
1. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron described in FIG. 4 5.0
2. Iron oxide-coated titanium dioxide (average particle size 400 nm) 3.0
3. Spherical silica (average particle size 5 μm) 10.0
4. Spherical cellulose acetate (average particle size 7 μm) 5.0
5. Silicone resin spherical powder (average particle size 5 μm) 10.0
6. Red iron oxide 0.2
7. Yellow iron oxide 0.4
8. Black iron oxide 0.05
9. Mica (average particle size 15 µm) Remainder 10. Coated mica (average particle size 20 μm) 10.0
11. Boron nitride (average particle size 6 μm) 10.0
12. Synthetic phlogopite 15.0
13. Ethylhexylglycerin 0.2
14. Liquid paraffin 2.0
15. Perfume 0.5

(Production method)
A. 1 to 11 are uniformly mixed with a super mixer.
B. 12 to 15 are uniformly mixed and dissolved.
C. Add B to A and mix uniformly.
D. A loose powder was obtained by pulverizing C and filling it in a metal plate and a resin plate container.

The obtained loose powder was a loose powder that had a natural skin correcting effect, a high covering effect for color unevenness and irregularities, and an excellent make-up longevity effect.

Example 29: Cheek color A cheek color was produced according to the following formulation and production method.
(Component) (%)
1. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron described in FIG. 4 5.0
2. Iron oxide-coated titanium oxide (average particle size 400 nm) 1.0
3. Boron nitride 10.0
4. N-lauroyl-L-lysine *14 5.0
5. Synthetic phlogopite balance 6. Mica Titanium 5.0
7. Red No. 226 0.5
8. Yellow No. 4 1.0
9. Blue No. 1 0.1
10. Bengara 0.5
11. Yellow iron oxide 0.3
12. Silicic anhydride (average particle size 15 μm) 3.0
13. Cellulose powder (average particle size 15 μm) 5.0
14. Crosslinked silicone/network silicone block copolymer 5.0
15. Vaseline 3.0
16. (Dimethicone/vinyl dimethicone) crosspolymer 2.0
17.2-Glyceryl ethylhexanoate 5.0
18.3-(4-chlorophenoxy)-1,2-propanediol 0.2
19. Ethylhexylglycerin 0.1

(Production method)
A. Components 1 to 14 are uniformly dispersed using a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.).
B. Ingredients 15 to 19 are uniformly mixed and dissolved.
C. While stirring A with a Henschel mixer, B is added and uniformly dispersed.
D. Pulverize C with a pulverizer.
E. D was mixed with an appropriate amount of isododecane to obtain a slurry mixture.
F. E was filled in a metal plate, compression molded, and then dried to remove the solvent to obtain a solid powdery cheek color.

The obtained cheek color had a natural skin correcting effect and an excellent make-up lasting effect.

Example 30: Eye Color An eye color was produced according to the following recipe and method.
(Component) (%)
1. Synthetic phlogopite 10.0
2. Talc Remaining amount3. Titanium oxide coated mica 20.0
4. Boron nitride 5.0
5. Iron oxide coated titanium oxide 5.0
6. No. in Tables 2-4. 1,
Titanium oxide-coated synthetic phlogopite iron described in FIG. 4 5.0
7. Hexagonal tabular zinc oxide (average particle size 300 nm) 3.0
8. Red 202 0.5
9. Cornstarch (average particle size 10 μm) 5.0
10. 1,2-octanediol as appropriate 11. Liquid paraffin 3.0
13. Dimethylpolysiloxane (KF-96-10CS) 5.0
14.2-Glyceryl ethylhexanoate 3.0
15. Perfume 0.1

(Production method)
A. Ingredients 1 to 9 are uniformly dispersed with a Henschel mixer.
B. Mix ingredients 10-15 to uniformity.
C. B was added to A, and after uniform dispersion, the mixture was pulverized to obtain a solid powdery eye color.

The obtained eye color had a natural skin correcting effect, was excellent in a high covering effect for color unevenness and unevenness, and was an eye color excellent in makeup longevity.

Claims (9)

the following components (A)-(C);
(A) Titanium oxide and synthetic phlogopite coated with tin oxide and having an average particle size of 5 to 16 μm (B) One or more fine particles of metal oxide selected from titanium oxide and zinc oxide other than component (A) Item (C) A powder cosmetic containing one or more substantially spherical powders selected from naturally-derived water-insoluble polymers and silicic anhydride, wherein the component (A) is a glittering powder. 0.05 g per unit area of [5×8] cm ² was applied to the adhesive surface of the transparent adhesive tape, and the angle of incidence was -45 degrees using a goniospectrophotometer D65 light source. When the reflection intensity is measured using a black non-reflective background, the reflection intensity [I (45)] at a light receiving angle of 45 degrees and the reflection intensity at a light receiving angle of 0 degrees [I (O)] at wavelengths of 450 nm and 650 nm 2. The cosmetic composition according to claim 1, wherein the ratio [I(45)]/[I(O)] is 1.1 to 2.5. 3. The cosmetic powder according to claim 1, wherein the coating amount of titanium oxide of component (A) is 5 to 20% by mass. The cosmetic powder according to any one of claims 1 to 3, wherein the synthetic phlogopite of the component (A) is synthetic phlogopite iron. The cosmetic powder according to any one of claims 1 to 4, wherein the component (B) is coated with iron oxide. The cosmetic powder according to any one of claims 1 to 5, wherein the component (C) is powder coated with a metal oxide. The cosmetic powder according to any one of Claims 1 to 6, further comprising, as component (D), a silicone oil having a kinematic viscosity at 25°C of 6 to 100 mm ² /s. The mass ratio (A) / [(A) + (B)] of the total mass [(A) + (B)] of the component (A) and the components (A) and (B) is (A) / [ (A)+(B)]=0.05 to 0.85, the powder cosmetic according to any one of claims 1 to 7. The powder cosmetic according to any one of claims 1 to 8, wherein the component (A) is a blue light cut agent.

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