JP4205844B2 - Skin cosmetics - Google Patents
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【０００１】
【発明の属する技術分野】
本発明は、特定の光学特性を有する複合無機粉体と微粒子酸化亜鉛とを含有することにより、十分なカバー力がありながらも透明感があり、自然な仕上がりで毛穴やシミ、ソバカスが目立たず、かつ経時で仕上がりが変化せず長時間塗布直後のきめ細かな仕上がりが持続する皮膚化粧料に関する。
【０００２】
【従来の技術】
マイカ、タルク、セリサイト等の鱗片状粉体はパウダーファンデーション等のメイクアップ用化粧料に配合されている。これらの粉体は、肌に対する延展性、付着性、滑らかさ等の使用感を向上させ、カバー力やしっとり感等の仕上がり感を高める特性を有するが、これらの粉体は屈折率が１．７以下であるため皮脂や汗に濡れると色変化（色くすみ）が大きいという欠点がある。そのため、例えばマイカに屈折率の高い酸化チタンを被覆させたパール顔料（特公昭４３−２５６４４号参照）が用いられているが、この場合マイカ表面の二酸化チタン薄膜による光干渉により銀白色、金色等の真珠光沢が生じる。そのため粉体の表面反射光が大きくなり、化粧料に配合した場合ぎらついた仕上がりになるため好ましくない。
【０００３】
特開昭５８−１４９９５９号公報では、雲母上に金属酸化物層として、二酸化チタンに加えて二酸化ケイ素及び酸化アルミニウムの均質混合層が形成された粉体を用いているが、これらの粉体は青色等の干渉色が生じる。更に、粉体の表面反射光も大きくなり、配合すると不自然な仕上がりとなるため好ましくない。
特開昭６３−２５４１６９号公報では、鱗片状無機粉体の粒子表面に二酸化チタンを被覆し、更にその上に酸化アルミニウムを被覆した粉体を用いているが、二酸化チタンと酸化アルミニウムの重量比率が３０：７０〜７０：３０と、二酸化チタンの比率が多いため反射光が高くなり、配合すると白っぽく不自然な仕上がりとなるため好ましくない。
【０００４】
また、特開平６−５６６２８号公報及び特開平８−１８８７２３号公報では、シミ、ソバカス等をカバーしながらも透明な素肌感の化粧仕上がりを有する化粧料が提案されている。これらの基材として雲母等の薄片状体質顔料をまず二酸化チタン又は有色顔料二酸化チタンで被覆し、その上からシリカ層又は光を拡散反射する粉体で被覆したものを用いているが、シリカの層で被覆した場合は二酸化チタンとシリカの屈折率の差が大きく、この両層の境界面で強い光の反射があるため、十分な透明感が得られない。
【０００５】
また透明感がある仕上がりを得ることが可能な化粧料においても、皮脂等によって化粧くずれが生じると、透明感を維持することができなくなる。そこで、近年、皮脂による化粧くずれを防止する目的で、粉体表面をフッ素化合物で処理して撥水・撥油性を付与することが提案されている（特開昭５５−１６７２０９号公報、特開昭６２−２５００７４号公報、特開平１−１８０８１１号公報、米国特許第３６３２７４４号明細書等）。しかしながら、このようなフッ素処理粉体を特にメーキャップ化粧料に多用した場合には、はじき出された油、皮脂等が点在して目立ってしまうという問題がある。
【０００６】
【発明が解決しようとする課題】
本発明の目的は、使用感（のび、つき等）、仕上がり（自然な仕上がり、透明感のある仕上がり、毛穴やシミ、ソバカスが目立たない等）が共に優れ、かつ長時間経過後も皮脂によるくずれやべたつきがなく、塗布直後の自然な、透明感のある仕上がりを長時間維持することができる皮膚化粧料を提供することにある。
【０００７】
【課題を解決するための手段】
本発明者は、特定の光学特性を有する複合無機粉体（Ａ）と微粒子酸化亜鉛（Ｂ）を併用すると、十分なカバー力がありながらも透明感があり、自然な仕上がりで、毛穴やシミ、ソバカスが目立たなくなると共に、皮脂による化粧くずれが生じず、仕上がりの非常にきめ細かい皮膚化粧料が得られ、その仕上がりが長時間持続することを見出した。
【０００８】
本発明は、（Ａ）複合無機粉体とタルク及びスクワランの混合物（重量比 ４７：４７：６）１０ｍｇを黒色人工皮革表面の１０ｃｍ×５ｃｍの部分に均一に塗布した試料について、入射光側と受光側にそれぞれＳ偏光板又はＰ偏光板を装着した変角分光測色計を用いて、Ｃ光による２°視野の受光条件における表面反射光量及び粉体層反射光量を測定したとき、入射光角４５°及び受光角４５°の条件下と、入射光角４５°及び受光角０°の条件下で測定されたそれぞれの表面反射光量の差が７〜１５で、かつ入射光角４５°及び受光角０°で測定された表面反射光量と粉体層反射光量の差が−３〜３である複合無機粉体、及び（Ｂ）微粒子酸化亜鉛を含有する皮膚化粧料を提供するものである。
【０００９】
【発明の実施の形態】
本発明においては、（Ａ）成分の複合無機粉体の光学特性を評価するために、当該複合無機粉体とタルク及びスクワランの混合物を人工皮革上に塗布した試料について、以下に詳述するように反射光量を測定する。
【００１０】
即ち、１０ｃｍ×５ｃｍのポリウレタン製人工皮革（黒色人工皮革；オカモト製ＯＫ−７，白色人工皮革；オカモト製ＯＫ−マット）を用い、各人工皮革に複合無機粉体とタルク及びスクワランの混合物（重量比 ４７：４７：６）を１０ｍｇ塗布し、村上色彩技術研究所製の２次元変角分光測色計ＧＣＭＳ−３を用い、Ｃ光による２°視野の受光条件下で測定する。ここで、タルクは平均粒子径（レーザー回折法で測定）が１５〜２０μｍのもの、例えばＦＫ−３００Ｓ（平均粒子径１７．８μｍ（株）山口雲母工業所社製）、スクワランは化粧品グレードのもの、例えばニッコールスクワラン（日光ケミカル（株）社製）を使用する。かかる塗膜からの反射光には、図１に示すように、表面反射光、粉体層反射光及び基底層反射光が含まれるが、入射光及び受光における偏光モードに応じて、反射光成分がそれぞれ異なる。測定にあたっては、入射光側と受光側にそれぞれＳ偏光板又はＰ偏光板を組合せて装着し、黒色人工皮革で得た測定値と白色人工皮革で得た測定値とから、表面反射光量、粉体層反射光量、基底層反射光量をそれぞれ算出することができる。
【００１１】
黒色人工皮革を用いて、入射光側にＳ偏光板及び受光側にＳ偏光板を置いて測定した値をＢss、入射光側にＳ偏光板及び受光側にＰ偏光板を置いて測定した値をＢsp、入射光側にＰ偏光板及び受光側にＳ偏光板を置いて測定した値をＢps、入射光側にＰ偏光板及び受光側にＰ偏光板を置いて測定した値をＢppとする。同様に白色人工皮革を用いた場合は、それぞれＷss、Ｗsp、Ｗps、Ｗppとする。各測定値には、ＸＹＺ表色系における三刺激値Ｘ，Ｙ，Ｚが含まれ、それぞれ個別の数値として測定することができる。
各測定値から、表面反射光ＳBは、
【００１２】
【数１】
で表される。また、粉体層反射光Ｄfは、
【００１４】
【数２】
で表される。また、基底層反射光Ｄbは、
【００１６】
【数３】
で表される。これらより、表面反射光量Ｙ（ＳB）は、
【００１８】
【数４】
粉体層反射光量Ｙ（Ｄf）は、
【００２０】
【数５】
基底層反射光量Ｙ（Ｄb）は、
【００２２】
【数６】
で表される。ここで、Ｙ（Ｂsp）、Ｙ（Ｂps）等は、それぞれＢsp、ＢpsのＹ値を示す。
【００２４】
使用する光源としては、昼光光源であるＣ光を用い、受光視野は２°とする。
測定は、入射角を４５°で一定にして、受光角を０°〜９０°まで５°刻みで行い、反射光量差が一番大きい入射角４５°／受光角４５°の条件下と、入射角４５°／受光角０°の条件下での測定値に着目する。
【００２５】
本発明の（Ａ）成分は、これらの条件下でのそれぞれの表面反射光量の差が７〜１５であることが第１の要件である。「表面反射光量の差」が１５より大きくなると、つやが出過ぎて顔がてかって見え、一方、７より小さくなると、つやが少なく顔が暗くくすんだように見えてしまう。
【００２６】
更に、表面反射光量と粉体層反射光量の差がわかりやすい、入射角４５°／受光角０°の条件下での測定値から、表面反射光量と粉体層反射光量の差が−３〜３であることが第２の要件である。「表面反射光量と粉体層反射光量の差」が３より大きくなると、つやが出過ぎて顔がてかって見え、−３より小さくなると、白っぽい顔になってしまう。
【００２７】
本発明で用いる（Ａ）成分の複合無機粉体は、鱗片状基材上に他の金属酸化物を複合させてなり、上記の光学特性を有するように設計される。その鱗片状基材は、平均粒子径が２〜２０μｍで、厚みが０．０５〜１μｍであることが好ましい。このような鱗片状基材としては雲母、セリサイト、タルク、カオリン、スメクタイト属粘土鉱物、合成マイカ、合成セリサイト、板状二酸化チタン、板状シリカ、板状酸化アルミニウム、窒化硼素、硫酸バリウム、板状チタニア・シリカ複合酸化物等が挙げられるが、特にタルクが使用感の点で好ましい。
【００２８】
これら鱗片状基材に複合化される金属酸化物としては二酸化チタン（ＴｉＯ2）、酸化鉄（Ｆｅ2Ｏ3）、酸化セリウム（ＣｅＯ2）、酸化亜鉛（ＺｎＯ）、シリカ（ＳｉＯ2）、酸化マグネシウム（ＭｇＯ）、酸化アルミニウム（Ａｌ2Ｏ3）、酸化カルシウム（ＣａＯ）、酸化ジルコニウム（ＺｒＯ2）が挙げられるが、特に二酸化チタン、酸化アルミウニム、シリカが屈折率の点で好ましい。
【００２９】
（Ａ）成分は、前記鱗片状基材に、前記金属酸化物から選択される１〜３種類の屈折率の異なる金属酸化物を、屈折率の高い方から順に被覆することにより調製される。当該金属酸化物は、（Ａ）成分に要求されるカバー力によって選択すればよい。カバー力の高い粉体を得るためには、第１層に屈折率の高い金属酸化物、例えば二酸化チタン等を被覆することが好ましい。他方、カバー力の低い粉体を得るためには、第１層に中程度の屈折率を持つ金属酸化物、例えば、酸化アルミニウム等を被覆することが好ましい。
次いで、必要により第２層以上の層を形成していくが、光の反射を抑制し透明感を出すために、第２層以上は第１層よりも屈折率の小さい金属酸化物であることが望ましい。
【００３０】
金属酸化物の被覆方法は、前記のように選択される金属酸化物の前駆物質である金属塩を所定量加水分解し、あるいは、同様に所定量の有機金属化合物をアルコール溶媒中で加水分解し、加水分解物を被覆すべき鱗片状基材あるいは被覆層を形成した複合粉体上に析出させる方法等、従来の公知の方法が採用できる。
例えば、鱗片状基材を水中に分散させ、これに所定量の硫酸チタニル等の金属塩を添加し、アルカリ雰囲気で加水分解し、鱗片状基材の表面に金属塩加水分解物を析出させることにより、所定厚の二酸化チタン被覆層を得ることができる。
また、最外層としてシリカを被覆する場合には、シリカより高い屈折率の被覆層を形成した鱗片状基材の分散液に、所定量のアルカリ金属珪酸塩水溶液あるいは有機珪素化合物等を添加し、必要に応じて酸またはアルカリを加えて、上記被覆層を形成した鱗片状基材の表面に珪酸の重合物（加水分解縮重合物）を付着させる等の方法により、所定の厚みのシリカ被覆層を形成することができる。なお、シリカの被覆層を形成するには、他の従来法を採用することもできる。
【００３１】
本発明において、金属酸化物の被覆膜厚は、鱗片状基材あるいは金属酸化物を被覆した鱗片状基材の幾何学的表面積、あるいは窒素吸着法等で測定される比表面積と、被覆する金属酸化物の密度より求めることができる。また、所定の膜厚となる金属酸化物の量から、添加する所定量の金属塩、有機金属化合物を計算することができる。
【００３２】
本発明において、より透明感を出すためには、各被覆層の金属酸化物の膜厚は、計算値で５０ｎｍ以下であることが好ましい。
【００３３】
鱗片状基材上に二酸化チタン、酸化アルミニウムの順に被覆する場合は、二酸化チタンと酸化アルミニウムの被覆量がＴｉＯ2／Ａｌ2Ｏ3の重量比で０．４２以下であることが、ぎらつき感を低減する点で好ましい。また、これら金属酸化物の合計の被覆量が（Ａ）成分の１〜５０重量％（以下単に％と記載する）、特には、５〜４０％であるのが好ましい。合計の被覆量が１〜５０％だと、透明性を維持しつつ、使用感が良好で、毛穴等を目立たなくする効果を付与することができる。
一方、二酸化チタン、酸化アルミニウム、シリカの順に被覆する場合は、二酸化チタンと酸化アルミニウムの被覆量がＴｉＯ2／Ａｌ2Ｏ3の重量比で０．６２以下、特には、０．４２以下であり、合計の被覆量が１〜５０％、特には、５〜４０％であるのが好ましい。また、使用感（きしみ感を低減する）の点から該粉体に対するＳｉＯ2の被覆量が０．１〜３０％、特には、０．２〜２０％であるのが好ましい。
【００３４】
更に、（Ａ）成分は、撥水撥油性を持たせるために表面をシリコーン、フッ素化合物、レシチン、アミノ酸、ポリエチレン、金属石けん等の撥水撥油処理剤で処理することが好ましい。また、（Ａ）成分の粉体に特開平１１−４９６３４号公報記載のスフィンゴシン類縁体、ステロール類及び脂肪酸による表面処理を施し処方中に配合すると、透明性が向上する上に、滑らかでのびがよくしっとり感を有し、しかも皮膚刺激性の少ない皮膚化粧料を得ることができる。
（Ａ）成分に対する撥水撥油処理剤の処理量は、（Ａ）成分１００重量部に対して０．０５〜２０重量部、特に１〜１０重量部が、十分な撥水撥油性、良好な使用感・耐光性が得られ好ましい。
【００３５】
（Ａ）成分は、本発明の皮膚化粧料中に１〜９０％、特に１０〜８０％、更には２０〜７０％含有するのが使用感（のび、付着性等）、仕上がり（透明感、毛穴隠蔽性等）の点から好ましい。
【００３６】
本発明で用いる（Ｂ）成分の微粒子酸化亜鉛は、化粧くずれが生じないことと使用感の点から比表面積が１０〜１００ｍ2／ｇ、特に２０〜８０ｍ2／ｇにあるのが好ましい。ここで、比表面積はＢＥＴ吸着法に基づいて測定できる。
【００３７】
かかる微粒子酸化亜鉛は、特開平２−２８９５０６号公報、特開昭５７−２０５３１９号公報等に開示され、各種グレードのものが市販品として入手可能である。
（Ｂ）成分も、（Ａ）成分と同様に撥水及び／又は撥油化処理して使用することが好ましいが、フッ素化合物で表面処理を行うと皮脂になじまなくなるので好ましくない。また、（Ｂ）成分は、球状粉体等の感触向上可能な他の粉体と複合化して、本発明の皮膚化粧料中に含有することもできる。
【００３８】
（Ｂ）成分は、本発明の皮膚化粧料中に０．１〜９９％、特に２〜９０％含有するのが好ましい。
【００３９】
本発明の皮膚化粧料には、上記の必須成分である（Ａ）成分及び（Ｂ）成分以外に、化粧料用粉体、例えばケイ酸、無水ケイ酸、ケイ酸マグネシウム、タルク、セリサイト、マイカ、カオリン等の無機粉体、ポリアミド、ポリエステル、ポリプロピレン、ポリスチレン、ポリウレタン等の有機粉体や有機タール系色素等を含有してもよい。
これらの粉体は、２種以上を組み合わせて用いることもできる。
【００４０】
本発明の皮膚化粧料は、例えば化粧水、乳液、クリーム等の基礎化粧料；粉白粉、固形白粉、フェイスパウダー、パウダーファンデーション、油性ファンデーション、クリーム状ファンデーション、リキッドファンデーション、コンシーラー、口紅、リップクリーム、頬紅、アイライナー、アイシャドウ、アイブロウ等のメークアップ化粧料等とすることができる。
【００４１】
【実施例】
（Ａ）成分の製造例：
製造例１
タルク３４０ｇを純水３１６０ｇに添加して十分に分散し、これに二酸化チタンとして濃度２０％の硫酸チタニル水溶液２００ｇを加え、攪拌しながら加熱し５時間沸騰させた。これを室温まで冷却し、濾過水洗後、１１０℃で乾燥させて、二酸化チタンの水和物が被覆されたタルクを得た。このうち３２０ｇを２６８０ｇの純水中でよく分散させ、これに酸化アルミニウムとして濃度１０％の塩化アルミニウム水溶液８００ｇ及び尿素５００ｇを水１８００ｇに溶かした溶液を加えてよく混合し、９０℃で１０時間加熱した後室温まで冷却した。これを濾過水洗し、１１０℃で乾燥後、６００℃で５時間焼成し、酸化チタン、酸化アルミニウムで順次被覆されたタルクを得た。更にこれを１００ｇ計量しエタノールと水の混合溶剤（７：３の比率）１Ｌに加えて、よく分散させた。これをシリカとして４重量％の正ケイ酸エチルエタノール溶液２７８ｇを加え、攪拌しながら５０℃に加熱し約１０時間保持した。次にこれを冷却後濾過し、エタノール及び純水で十分洗浄し１１０℃で乾燥し、二酸化チタン、酸化アルミニウム、シリカで順次被覆されたタルクを得た。
【００４２】
製造例２
セリサイト３０９ｇを純水３６９１ｇに添加して十分に分散し、これに酸化アルミニウムとして濃度１０％の塩化アルミニウム水溶液９１２ｇ及び尿素５８８ｇを水２０００ｇに溶かした溶液を加えてよく混合し、９０℃で１０時間加熱した後室温まで冷却した。これを濾過水洗し、１１０℃で乾燥後、６００℃で５時間焼成し、酸化アルミニウムで被覆されたセリサイトを得た。
【００４３】
製造例３
タルク３６８ｇを純水３１３２ｇに添加して十分に分散し、これに二酸化チタンとして濃度２０％の硫酸チタニル水溶液１５８ｇを加え攪拌しながら加熱し５時間沸騰させた。これを室温まで冷却し、濾過水洗後、１１０℃で乾燥させて、二酸化チタンの水和物が被覆されたタルクを得た。このうち３１４ｇを２６８６ｇの純水中によく分散させ、これに酸化アルミニウムとして濃度１０％の塩化アルミニウム水溶液８６０ｇ及び尿素６４０ｇを水２０００ｇに溶かした溶液を加えてよく混合し、９０℃で１０時間加熱した後室温まで冷却した。これを濾過水洗し、１１０℃で乾燥後、６００℃で５時間焼成し、二酸化チタン、酸化アルミニウムで順次被覆されたタルクを得た。
【００４４】
比較製造例１
タルク３６８ｇを純水３１３２ｇに添加して十分に分散し、これに二酸化チタンとして濃度２０％の硫酸チタニル水溶液１５８ｇを加え、攪拌しながら加熱し５時間沸騰させた。これを室温まで冷却し、濾過水洗後、１１０℃で乾燥させて、二酸化チタンの水和物が被覆されたタルクを得た。このうち３７４ｇを３１２６ｇの純水中でよく分散させ、これに酸化アルミニウムとして濃度１０％の塩化アルミニウム水溶液２６４ｇ及び尿素２３６ｇを水８００ｇに溶かした溶液を加えてよく混合し、９０℃で１０時間加熱した後室温まで冷却した。これを濾過水洗し、１１０℃で乾燥後、６００℃で５時間焼成し、二酸化チタン、酸化アルミニウムで順次被覆されたタルクを得た。
【００４５】
実施例１（パウダーファンデーション）
表１及び表２に示す組成のパウダーファンデーションを、下記製法に従って製造した。また、これらのファンデーションの使用評価を、下記方法に従って実施した結果も表１及び表２に示す。
（製法）成分（１）〜（１７）を混合し粉砕機にて粉砕した。これを高速ブレンダーに移し、成分（１８）〜（２２）を８０℃に混合溶解したものを加えて均一混合した。更にこの混合物に成分（２３）を加え混合した後、再び粉砕してふるいを通した。これを金皿に圧縮成型した。
【００４６】
（評価方法）
パネラー１０名により、顔に試料を塗布したときの使用感（肌へののび、肌上での付着性）と仕上がり（自然な仕上がり、透明感のある仕上がり、毛穴が目立たない、シミ・ソバカスが目立たない、肌が明るく見える、きめ細かい仕上がり）、及び４時間後の化粧持ち（きめ細かさ、くずれにくさ、べたつきのなさ）について官能評価し、以下の基準で判定した。
判定基準
◎：８名以上が良好と回答
○：５〜７名が良好と回答
△：２〜４名が良好と回答
×：１名以下が良好と回答
【００４７】
【表１】
【表２】
本発明品は、いずれも使用感、仕上がり、化粧持ちが優れていた。
【００５０】
実施例２（固形白粉）
（組成）
製造例１の無機複合粉体をフッ素処理したもの ５０．０％
(TiO2/A1203(重量比)0.42、被覆量合計28.4％
SiO2処理量10％、表面反射光量の差13.7
表面反射光量と粉体層反射光量の差-1.2)
酸化亜鉛（比表面積５０ｍ2／ｇ） ６．０
ステアリン酸亜鉛 ４．０
フッ素処理硫酸バリウム １０．０
フッ素処理微粒子二酸化チタン ４．０
フッ素処理マイカ ５．０
フッ素処理タルク 残量
フッ素処理二酸化チタン ０．５
フッ素処理赤酸化鉄 ０．１
フッ素処理黄酸化鉄 ０．１
フッ素処理黒酸化鉄 ０．０１
流動パラフィン ６．０
パラメトキシ桂皮酸２−エチルヘキシル ２．７
ミツロウ ２．０
防腐剤 適量
香料 微量
【００５１】
実施例３（ルースタイプフェイスパウダー）
（組成）
製造例１の無機複合粉体をレシチン素処理したもの ５５．０％
(TiO2/A1203(重量比)0.42、被覆量合計28.4％
SiO2処理量10％、表面反射光量の差13.5
表面反射光量と粉体層反射光量の差-2.7)
酸化亜鉛（比表面積７５ｍ2／ｇ） ５．０
シリコーン処理二酸化チタン ０．５
シリコーン処理赤酸化鉄 ０．１
シリコーン処理黄酸化鉄 ０．１
シリコーン処理タルク 残量
シリコーン処理硫酸バリウム ２０．０
メチルポリシロキサン（６cs） １．０
防腐剤 適量
香料 微量
【００５２】
実施例４（アイシャドー）
（組成）
製造例２の無機複合粉体をフッ素処理したもの ４５．０％
(アルミナ処理22.8％、表面反射光量の差10.9
表面反射光量と粉体層反射光量の差-0.4)
酸化亜鉛（比表面積７５ｍ2／ｇ） ７．０
ステアリン酸亜鉛 ２．０
フッ素処理硫酸バリウム ５．０
フッ素処理微粒子二酸化チタン ４．０
シリコーン処理マイカ 残量
シリコーン処理タルク １０．０
シリコーン処理二酸化チタン １．５
シリコーン処理赤酸化鉄 ０．２
シリコーン処理黄酸化鉄 ０．８
シリコーン処理黒酸化鉄 ０．１
スクワラン ５．０
メチルポリシロキサン（６cs） ３．０
マイクロクリスタリンワックス ０．５
防腐剤 適量
香料 微量
【００５３】
実施例５（頬紅）
（組成）
製造例３の無機複合粉体をフッ素処理したもの ３５．０％
(TiO2/A1203(重量比)0.29、被覆量合計27.7％
表面反射光量の差9.8
表面反射光量と粉体層反射光量の差0.5)
疎水化処理酸化亜鉛（比表面積５０ｍ2／ｇ） ５．０
ステアリン酸マグネシウム ２．０
フッ素処理硫酸バリウム ５．０
フッ素処理微粒子二酸化チタン ４．０
フッ素処理マイカ 残量
フッ素処理タルク １０．０
フッ素処理二酸化チタン ２．２
赤色２２６号 ０．５
フッ素処理黄酸化鉄 ０．３
フッ素処理黒酸化鉄 ０．１
流動パラフィン ３．０
メチルポリシロキサン（６cs） ３．０
マイクロクリスタリンワックス ０．９
防腐剤 適量
香料 微量
【００５４】
実施例２〜５で得られた皮膚化粧料は、いずれも肌上でののび、付着性が良好で透明感があり、毛穴やシミ、ソバカスが目立たず、肌が明るく滑らかに見え、きめ細かい仕上がりになり、かつ経時で仕上がりが変化せず長時間塗布直後の仕上がりを持続することができる。
【００５５】
【発明の効果】
本発明の皮膚化粧料は、十分なカバー力がありながらも透明感があり、自然な仕上がりで、毛穴やシミ、ソバカスが目立たず、かつ経時で仕上がりが変化せず長時間塗布直後の仕上がりを持続できる。
【図面の簡単な説明】
【図１】表面反射光、粉体層反射光及び基底層反射光を含む、塗膜からの反射光の説明図である。[0001]
BACKGROUND OF THE INVENTION
By containing a composite inorganic powder having specific optical characteristics and fine zinc oxide, the present invention has a transparent feeling while having sufficient covering power, and pores, spots and freckles are not noticeable with a natural finish. In addition, the present invention relates to a skin cosmetic that maintains a fine finish immediately after application for a long time without any change in the finish over time.
[0002]
[Prior art]
Scale-like powders such as mica, talc and sericite are blended in makeup cosmetics such as powder foundation. These powders have the characteristics of improving the feeling of use such as spreadability, adhesion and smoothness to the skin, and enhancing the finished feeling such as covering power and moist feeling, but these powders have a refractive index of 1. Since it is 7 or less, there is a drawback that the color change (color dullness) is large when wet with sebum or sweat. Therefore, for example, pearl pigments (see Japanese Examined Patent Publication No. 43-25644) in which mica is coated with titanium oxide having a high refractive index are used. In this case, silver white, gold color, etc. due to light interference by the titanium dioxide thin film on the mica surface. The pearly luster is produced. For this reason, the surface reflection light of the powder becomes large, and when it is blended into a cosmetic, the finish is not preferable.
[0003]
In Japanese Patent Laid-Open No. 58-149959, a powder in which a homogeneous mixed layer of silicon dioxide and aluminum oxide in addition to titanium dioxide is used as a metal oxide layer on mica is used. Interference colors such as blue are generated. Further, the surface reflected light of the powder becomes large, and if blended, an unnatural finish is obtained, which is not preferable.
In JP-A-63-254169, a powder in which the surface of the scaly inorganic powder is coated with titanium dioxide and further coated with aluminum oxide is used, but the weight ratio of titanium dioxide and aluminum oxide is used. Is 30:70 to 70:30, and the ratio of titanium dioxide is large, so that the reflected light becomes high.
[0004]
JP-A-6-56628 and JP-A-8-188723 propose cosmetics having a transparent skin-like makeup finish while covering spots, freckles, and the like. As these substrates, flaky extender pigments such as mica are first coated with titanium dioxide or colored pigment titanium dioxide, and a silica layer or a powder that diffuses and reflects light is coated thereon. When coated with layers, the difference in refractive index between titanium dioxide and silica is large and there is strong light reflection at the interface between the two layers, so that sufficient transparency cannot be obtained.
[0005]
Further, even in a cosmetic that can obtain a transparent finish, if the makeup is lost due to sebum or the like, the transparency cannot be maintained. Therefore, in recent years, for the purpose of preventing makeup loss due to sebum, it has been proposed to treat the powder surface with a fluorine compound to impart water and oil repellency (Japanese Patent Laid-Open No. 55-167209, Japanese Patent Laid-Open No. 55-167209). Sho 62-250074, JP-A 1-180881, US Pat. No. 3,632,744, etc.). However, when such a fluorinated powder is used frequently in makeup cosmetics, there is a problem that oil, sebum and the like that are ejected are scattered and become conspicuous.
[0006]
[Problems to be solved by the invention]
The objects of the present invention are excellent in feeling of use (such as stretch and stickiness) and finish (natural finish, transparent finish, pores, spots, buckwheat etc. are not noticeable), etc. An object of the present invention is to provide a skin cosmetic that has no stickiness and can maintain a natural and transparent finish immediately after application for a long time.
[0007]
[Means for Solving the Problems]
The inventor of the present invention uses a composite inorganic powder (A) having specific optical characteristics and fine-particle zinc oxide (B) in combination, which has sufficient covering power but is transparent and has a natural finish with pores and spots. It has been found that buckwheat becomes inconspicuous, and makeup loss due to sebum does not occur, and a very fine skin cosmetic finish is obtained, which finishes for a long time.
[0008]
The present invention relates to a sample in which (A) 10 mg of a mixture of composite inorganic powder, talc and squalane (weight ratio 47: 47: 6) is uniformly applied to a 10 cm × 5 cm portion of the surface of black artificial leather. Using a variable angle spectrocolorimeter equipped with an S-polarizing plate or a P-polarizing plate on the light receiving side, respectively, the incident light is measured when the surface reflected light amount and the powder layer reflected light amount under the 2 ° field light receiving condition with C light are measured. The difference in the amount of reflected light on each surface measured under conditions of an angle of 45 ° and a light receiving angle of 45 ° and an incident light angle of 45 ° and a light receiving angle of 0 ° is 7 to 15, and the incident light angle of 45 ° and Provided is a skin care composition containing a composite inorganic powder having a difference between the amount of reflected light on the surface and the amount of reflected light on the powder layer of −3 to 3 measured at a light receiving angle of 0 °, and (B) fine particle zinc oxide. .
[0009]
DETAILED DESCRIPTION OF THE INVENTION
In the present invention, in order to evaluate the optical properties of the composite inorganic powder of component (A), a sample obtained by applying a mixture of the composite inorganic powder, talc and squalane on artificial leather will be described in detail below. Measure the amount of reflected light.
[0010]
That is, a 10 cm × 5 cm polyurethane artificial leather (black artificial leather: OK-7 made by Okamoto, white artificial leather: OK-mat made by Okamoto), and a mixture (weight) of composite inorganic powder, talc and squalane for each artificial leather 10 mg of the ratio 47: 47: 6) is applied, and measurement is performed using a two-dimensional variable angle spectrocolorimeter GCMS-3 manufactured by Murakami Color Research Laboratory under a light receiving condition of 2 ° visual field with C light. Here, talc has an average particle size (measured by laser diffraction method) of 15 to 20 μm, for example, FK-300S (average particle size 17.8 μm, manufactured by Yamaguchi Mica Industry Co., Ltd.), and squalane is a cosmetic grade. For example, Nikkor Squalane (manufactured by Nikko Chemical Co., Ltd.) is used. As shown in FIG. 1, the reflected light from the coating film includes surface reflected light, powder layer reflected light, and base layer reflected light. Depending on the polarization mode in incident light and light reception, the reflected light component Are different. In measuring, the incident light side and the light receiving side are respectively combined with S polarizing plates or P polarizing plates, and from the measured values obtained with black artificial leather and the measured values obtained with white artificial leather, the surface reflected light amount, The body layer reflected light amount and the base layer reflected light amount can be calculated respectively.
[0011]
Using black artificial leather, the value measured with the S polarizing plate on the incident light side and the S polarizing plate on the light receiving side was measured, and the value measured with the S polarizing plate on the incident light side and the P polarizing plate on the light receiving side was measured. Is Bsp, the value measured with the P polarizing plate on the incident light side and the S polarizing plate on the light receiving side is Bps, and the value measured with the P polarizing plate on the incident light side and the P polarizing plate on the light receiving side is Bpp. . Similarly, when white artificial leather is used, Wss, Wsp, Wps and Wpp are used. Each measurement value includes tristimulus values X, Y, and Z in the XYZ color system, and can be measured as individual numerical values.
From each measured value, the surface reflected light S B is
[0012]
[Expression 1]
It is represented by The powder layer reflected light D f is
[0014]
[Expression 2]
It is represented by The base layer reflected light Db is
[0016]
[Equation 3]
It is represented by From these, the surface reflected light amount Y (S B ) is
[0018]
[Expression 4]
The powder layer reflected light amount Y (D f ) is
[0020]
[Equation 5]
The base layer reflected light amount Y (D b ) is
[0022]
[Formula 6]
It is represented by Here, Y (Bsp), Y (Bps), etc. indicate the Y values of Bsp and Bps, respectively.
[0024]
As a light source to be used, C light which is a daylight source is used, and a light receiving field is set to 2 °.
Measurement is performed with the incident angle constant at 45 °, the light receiving angle in increments of 5 ° from 0 ° to 90 °, and the incident angle is 45 ° / light receiving angle is 45 ° with the largest difference in the amount of reflected light. Attention is paid to the measured value under the condition of angle 45 ° / light receiving angle 0 °.
[0025]
The first requirement for the component (A) of the present invention is that the difference in the amount of reflected light on each surface under these conditions is 7 to 15. If the “difference in the amount of reflected light from the surface” is greater than 15, the face appears too glossy, while if it is less than 7, the face appears to be dark and dull with less gloss.
[0026]
Furthermore, the difference between the surface reflected light amount and the powder layer reflected light amount is -3 to 3 based on the measured value under the condition of 45 ° incident angle / 0 ° light receiving angle, in which the difference between the surface reflected light amount and the powder layer reflected light amount is easily understood. That is the second requirement. If the “difference between the reflected light amount on the surface and the reflected light amount on the powder layer” is greater than 3, the face appears too glossy, and if it is smaller than −3, the face becomes whitish.
[0027]
The composite inorganic powder of the component (A) used in the present invention is designed so as to have other optical oxides on a scaly substrate and to have the above optical characteristics. The scaly substrate preferably has an average particle diameter of 2 to 20 μm and a thickness of 0.05 to 1 μm. Such scale-like substrates include mica, sericite, talc, kaolin, smectite clay minerals, synthetic mica, synthetic sericite, plate-like titanium dioxide, plate-like silica, plate-like aluminum oxide, boron nitride, barium sulfate, Examples thereof include plate-like titania / silica composite oxide, and talc is particularly preferable from the viewpoint of usability.
[0028]
As metal oxides to be compounded with these scaly substrates, titanium dioxide (TiO 2 ), iron oxide (Fe 2 O 3 ), cerium oxide (CeO 2 ), zinc oxide (ZnO), silica (SiO 2 ), Examples include magnesium oxide (MgO), aluminum oxide (Al 2 O 3 ), calcium oxide (CaO), and zirconium oxide (ZrO 2 ). In particular, titanium dioxide, aluminum oxide, and silica are preferable in terms of refractive index.
[0029]
The component (A) is prepared by coating the scale-like substrate with one to three kinds of metal oxides having different refractive indexes selected from the metal oxides in order from the higher refractive index. What is necessary is just to select the said metal oxide by the cover force requested | required of (A) component. In order to obtain a powder having a high covering power, it is preferable to coat the first layer with a metal oxide having a high refractive index, such as titanium dioxide. On the other hand, in order to obtain a powder with low covering power, it is preferable to coat the first layer with a metal oxide having a medium refractive index, such as aluminum oxide.
Next, if necessary, the second layer or more is formed, but the second layer or more is a metal oxide having a refractive index smaller than that of the first layer in order to suppress the reflection of light and to give a transparent feeling. Is desirable.
[0030]
The metal oxide coating method includes hydrolyzing a predetermined amount of a metal salt which is a precursor of the metal oxide selected as described above, or similarly hydrolyzing a predetermined amount of an organometallic compound in an alcohol solvent. Conventionally known methods such as a method of depositing on a scale-like substrate to be coated with a hydrolyzate or a composite powder on which a coating layer is formed can be employed.
For example, dispersing a scaly base material in water, adding a predetermined amount of a metal salt such as titanyl sulfate, hydrolyzing in an alkaline atmosphere, and depositing a metal salt hydrolyzate on the surface of the scaly base material Thus, a titanium dioxide coating layer having a predetermined thickness can be obtained.
In addition, when silica is coated as the outermost layer, a predetermined amount of an alkali metal silicate aqueous solution or an organic silicon compound is added to a dispersion of a scaly substrate having a coating layer having a higher refractive index than silica, A silica coating layer having a predetermined thickness is added by a method such as adding an acid or alkali to the surface of the scaly substrate on which the coating layer is formed, if necessary, and attaching a silicic acid polymer (hydrolyzed condensation polymer). Can be formed. In order to form a silica coating layer, other conventional methods may be employed.
[0031]
In the present invention, the coating thickness of the metal oxide covers the geometric surface area of the flaky substrate or the flaky substrate coated with the metal oxide, or the specific surface area measured by a nitrogen adsorption method or the like. It can obtain | require from the density of a metal oxide. Further, a predetermined amount of metal salt or organometallic compound to be added can be calculated from the amount of metal oxide having a predetermined film thickness.
[0032]
In the present invention, in order to obtain a more transparent feeling, the thickness of the metal oxide of each coating layer is preferably 50 nm or less as a calculated value.
[0033]
When coating on a scaly substrate in the order of titanium dioxide and aluminum oxide, the amount of coating of titanium dioxide and aluminum oxide is 0.42 or less in terms of the weight ratio of TiO 2 / Al 2 O 3 . It is preferable at the point which reduces. Further, the total coating amount of these metal oxides is preferably 1 to 50% by weight (hereinafter simply referred to as%) of the component (A), and particularly preferably 5 to 40%. When the total coating amount is 1 to 50%, it is possible to impart an effect of making the feeling of use good and making pores inconspicuous while maintaining transparency.
On the other hand, when coating is performed in the order of titanium dioxide, aluminum oxide, and silica, the coating amount of titanium dioxide and aluminum oxide is 0.62 or less in weight ratio of TiO 2 / Al 2 O 3 , especially 0.42 or less. The total coating amount is preferably 1 to 50%, particularly 5 to 40%. From the viewpoint of feeling of use (reducing squeaky feeling), the coating amount of SiO 2 on the powder is preferably 0.1 to 30%, particularly preferably 0.2 to 20%.
[0034]
Furthermore, the component (A) is preferably treated with a water / oil repellent treatment agent such as silicone, fluorine compound, lecithin, amino acid, polyethylene, or metal soap in order to impart water / oil repellency. Moreover, when the powder of component (A) is subjected to surface treatment with sphingosine analogs, sterols and fatty acids described in JP-A No. 11-49634, and blended in the formulation, the transparency is improved, and smooth spreading It is possible to obtain a skin cosmetic that has a moist feeling and little skin irritation.
The processing amount of the water / oil repellent treatment agent with respect to the component (A) is 0.05 to 20 parts by weight, particularly 1 to 10 parts by weight with respect to 100 parts by weight of the component (A). A good feeling of use and light resistance are obtained, which is preferable.
[0035]
Component (A) is contained in the skin cosmetic of the present invention in an amount of 1 to 90%, particularly 10 to 80%, and more preferably 20 to 70%. From the viewpoint of pore concealing properties and the like.
[0036]
(B) used in the present invention fine particles of zinc oxide component, it a specific surface area in terms of usability is 10 to 100 m 2 / g which makeup does not occur, preferably in the particular 20 to 80 m 2 / g. Here, the specific surface area can be measured based on the BET adsorption method.
[0037]
Such fine particle zinc oxide is disclosed in JP-A-2-289506, JP-A-57-205319, and the like, and those of various grades are commercially available.
The component (B) is also preferably used after being subjected to water and / or oil repellency treatment in the same manner as the component (A), but it is not preferable because surface treatment with a fluorine compound will not be compatible with sebum. Moreover, (B) component can also be compounded with other powders which can improve touch, such as spherical powder, and can also be contained in the skin cosmetics of this invention.
[0038]
Component (B) is preferably contained in the skin cosmetic of the present invention in an amount of 0.1 to 99%, particularly 2 to 90%.
[0039]
In addition to the above essential components (A) and (B), the skin cosmetics of the present invention include cosmetic powders such as silicic acid, anhydrous silicic acid, magnesium silicate, talc, sericite, Inorganic powders such as mica and kaolin, organic powders such as polyamide, polyester, polypropylene, polystyrene, and polyurethane, and organic tar dyes may be contained.
These powders can be used in combination of two or more.
[0040]
Skin cosmetics of the present invention are, for example, basic cosmetics such as lotion, milky lotion, cream; powdered white powder, solid white powder, face powder, powder foundation, oily foundation, creamy foundation, liquid foundation, concealer, lipstick, lip balm, Make-up cosmetics such as blusher, eyeliner, eyeshadow, eyebrow can be used.
[0041]
【Example】
Example of production of component (A):
Production Example 1
340 g of talc was added to 3160 g of pure water and sufficiently dispersed. To this was added 200 g of a 20% strength titanyl sulfate aqueous solution as titanium dioxide, heated with stirring and boiled for 5 hours. This was cooled to room temperature, washed with filtered water, and dried at 110 ° C. to obtain talc coated with a hydrate of titanium dioxide. Of these, 320 g was well dispersed in 2680 g of pure water, and 800 g of 10% strength aluminum chloride aqueous solution and 500 g of urea dissolved in 1800 g of water as aluminum oxide were added and mixed well, followed by heating at 90 ° C. for 10 hours. And then cooled to room temperature. This was washed with filtered water, dried at 110 ° C., and then calcined at 600 ° C. for 5 hours to obtain talc coated with titanium oxide and aluminum oxide sequentially. Further, 100 g of this was weighed and added to 1 L of a mixed solvent of ethanol and water (ratio of 7: 3) and well dispersed. To this was added 278 g of a 4 wt% ethyl silicate solution as silica, heated to 50 ° C. with stirring and held for about 10 hours. Next, this was cooled and filtered, washed thoroughly with ethanol and pure water and dried at 110 ° C. to obtain talc coated with titanium dioxide, aluminum oxide and silica in this order.
[0042]
Production Example 2
309 g of sericite was added to 3691 g of pure water and sufficiently dispersed, and a solution prepared by dissolving 912 g of a 10% aluminum chloride aqueous solution and 588 g of urea in 2000 g of water as aluminum oxide was added and mixed well. After heating for hours, it was cooled to room temperature. This was washed with filtered water, dried at 110 ° C., and then calcined at 600 ° C. for 5 hours to obtain sericite coated with aluminum oxide.
[0043]
Production Example 3
368 g of talc was added to 3132 g of pure water and sufficiently dispersed. To this, 158 g of a 20% titanyl sulfate aqueous solution as titanium dioxide was added and heated with stirring to boil for 5 hours. This was cooled to room temperature, washed with filtered water, and dried at 110 ° C. to obtain talc coated with a hydrate of titanium dioxide. Of these, 314 g was well dispersed in 2686 g of pure water, and a solution prepared by dissolving 860 g of 10% aluminum chloride aqueous solution and 640 g of urea in 2000 g of water as aluminum oxide was added and mixed well, and heated at 90 ° C. for 10 hours. And then cooled to room temperature. This was washed with filtered water, dried at 110 ° C., and calcined at 600 ° C. for 5 hours to obtain talc coated with titanium dioxide and aluminum oxide in this order.
[0044]
Comparative production example 1
368 g of talc was added to 3132 g of pure water and sufficiently dispersed. To this, 158 g of a 20% titanyl sulfate aqueous solution as titanium dioxide was added, heated with stirring and boiled for 5 hours. This was cooled to room temperature, washed with filtered water, and dried at 110 ° C. to obtain talc coated with a hydrate of titanium dioxide. Of these, 374 g was well dispersed in 3126 g of pure water, and a solution prepared by dissolving 264 g of 10% aluminum chloride aqueous solution and 236 g of urea in 800 g of water as aluminum oxide was added and mixed well, and heated at 90 ° C. for 10 hours. And then cooled to room temperature. This was washed with filtered water, dried at 110 ° C., and calcined at 600 ° C. for 5 hours to obtain talc coated with titanium dioxide and aluminum oxide in this order.
[0045]
Example 1 (powder foundation)
Powder foundations having the compositions shown in Table 1 and Table 2 were produced according to the following production method. In addition, Table 1 and Table 2 also show the results of evaluating the use of these foundations according to the following method.
(Production Method) Components (1) to (17) were mixed and pulverized with a pulverizer. This was transferred to a high-speed blender, and components (18) to (22) mixed and dissolved at 80 ° C. were added and mixed uniformly. Further, the component (23) was added to the mixture and mixed, and then pulverized again and passed through a sieve. This was compression molded into a metal pan.
[0046]
(Evaluation methods)
10 panelists feel that when applying a sample to the face (spread on the skin, adhesion on the skin) and finish (natural finish, transparent finish, pores are not noticeable, spots and freckles Sensory evaluation was performed on the following criteria: inconspicuous, bright skin, fine finish), and after 4 hours of makeup (fineness, difficulty in breaking, non-stickiness).
Judgment criteria ◎: 8 or more responded good ○: 5-7 answered good △: 2-4 answered good ×: 1 or less answered good
[Table 1]
[Table 2]
All of the products of the present invention were excellent in feeling of use, finish and longevity.
[0050]
Example 2 (solid white powder)
(composition)
Fluorine-treated inorganic composite powder of Production Example 1 50.0%
(TiO 2 / A1 2 0 3 (weight ratio) 0.42, total coverage 28.4%
SiO 2 treatment amount 10%, surface reflected light difference 13.7
(Difference between surface reflected light amount and powder layer reflected light amount -1.2)
Zinc oxide (specific surface area 50 m 2 / g) 6.0
Zinc stearate 4.0
Fluorine-treated barium sulfate 10.0
Fluorine-treated fine particle titanium dioxide 4.0
Fluorine-treated mica 5.0
Fluorine-treated talc Remaining fluorine-treated titanium dioxide 0.5
Fluorine-treated red iron oxide 0.1
Fluorine-treated yellow iron oxide 0.1
Fluorine-treated black iron oxide 0.01
Liquid paraffin 6.0
2-Ethylhexyl paramethoxycinnamate 2.7
Beeswax 2.0
Preservative, proper amount of fragrance, trace amount [0051]
Example 3 (Loose type face powder)
(composition)
55.0% of lecithin-treated inorganic composite powder of Production Example 1
(TiO 2 / A1 2 0 3 (weight ratio) 0.42, total coverage 28.4%
SiO 2 treatment amount 10%, surface reflected light difference 13.5
(Difference between surface reflected light amount and powder layer reflected light amount -2.7)
Zinc oxide (specific surface area 75 m 2 / g) 5.0
Silicone-treated titanium dioxide 0.5
Silicone-treated red iron oxide 0.1
Silicone-treated yellow iron oxide 0.1
Silicone-treated talc Remaining silicone-treated barium sulfate 20.0
Methyl polysiloxane (6cs) 1.0
Preservative, proper amount of fragrance, trace amount [0052]
Example 4 (Eye Shadow)
(composition)
Fluorine-treated inorganic composite powder of Production Example 2 45.0%
(Alumina treatment 22.8%, surface reflected light difference 10.9
(Difference between surface reflected light amount and powder layer reflected light amount -0.4)
Zinc oxide (specific surface area 75 m 2 / g) 7.0
Zinc stearate 2.0
Fluorine-treated barium sulfate 5.0
Fluorine-treated fine particle titanium dioxide 4.0
Silicone-treated mica Remaining silicone-treated talc 10.0
Silicone-treated titanium dioxide 1.5
Silicone-treated red iron oxide 0.2
Silicone-treated yellow iron oxide 0.8
Silicone-treated black iron oxide 0.1
Squalane 5.0
Methyl polysiloxane (6cs) 3.0
Microcrystalline wax 0.5
Preservative appropriate amount perfume trace amount [0053]
Example 5 (blusher)
(composition)
Fluorine-treated inorganic composite powder of Production Example 3 35.0%
(TiO 2 / A1 2 0 3 (weight ratio) 0.29, total coating amount 27.7%
Difference in surface reflected light 9.8
(Difference between surface reflected light amount and powder layer reflected light amount 0.5)
Hydrophobized zinc oxide (specific surface area 50 m 2 / g) 5.0
Magnesium stearate 2.0
Fluorine-treated barium sulfate 5.0
Fluorine-treated fine particle titanium dioxide 4.0
Fluorine treatment mica Remaining fluorine treatment talc 10.0
Fluorine-treated titanium dioxide 2.2
Red 226 0.5
Fluorine-treated yellow iron oxide 0.3
Fluorine-treated black iron oxide 0.1
Liquid paraffin 3.0
Methyl polysiloxane (6cs) 3.0
Microcrystalline wax 0.9
Preservative appropriate amount perfume trace amount [0054]
The skin cosmetics obtained in Examples 2 to 5 all spread on the skin, have good adhesion and have a transparent feeling, pores, spots and freckles do not stand out, the skin looks bright and smooth, and has a fine finish In addition, the finish does not change with time, and the finish immediately after application for a long time can be maintained.
[0055]
【The invention's effect】
The skin cosmetic of the present invention has a clear feeling while having sufficient covering power, has a natural finish, pores, stains and freckles are not noticeable, and the finish does not change over time, and the finish immediately after application for a long time It can last.
[Brief description of the drawings]
FIG. 1 is an explanatory diagram of reflected light from a coating film including surface reflected light, powder layer reflected light, and base layer reflected light.
Claims (2)
（Ａ）(a1)鱗片状基材上に二酸化チタン、酸化アルミニウムの順に被覆してなり、それらの重量比（ＴｉＯ2／Ａｌ2Ｏ3）が０．４２以下の複合無機粉体、又は
(a2)鱗片状基材上に二酸化チタン、酸化アルミニウム、シリカの順に被覆してなり、二酸化チタンと酸化アルミニウムの重量比（ＴｉＯ2／Ａｌ2Ｏ3）が０．６２以下であり、かつＳｉＯ2の被覆量が０．１〜３０重量％の複合無機粉体であって、
複合無機粉体とタルク及びスクワランの混合物（重量比 ４７：４７：６）１０ｍｇを黒色人工皮革表面の１０ｃｍ×５ｃｍの部分に均一に塗布した試料について、入射光側と受光側にそれぞれＳ偏光板又はＰ偏光板を装着した変角分光測色計を用いて、Ｃ光による２°視野の受光条件における表面反射光量及び粉体層反射光量を測定したとき、入射光角４５°及び受光角４５°の条件下と、入射光角４５°及び受光角０°の条件下で測定されたそれぞれの表面反射光量の差が７〜１５で、かつ入射光角４５°及び受光角０°で測定された表面反射光量と粉体層反射光量の差が−３〜３であり、
金属酸化物の合計の被覆量が（Ａ）成分の１〜５０重量％である複合無機粉体、
（Ｂ）比表面積が５０〜１００ｍ2／ｇである微粒子酸化亜鉛
を含有する皮膚化粧料。Next (A) component and (B) component:
(A) (a1) A composite inorganic powder having a scaly substrate coated with titanium dioxide and aluminum oxide in this order, and having a weight ratio (TiO 2 / Al 2 O 3 ) of 0.42 or less, or
(a2) A scaly substrate is coated with titanium dioxide, aluminum oxide, and silica in that order, and the weight ratio of titanium dioxide to aluminum oxide (TiO 2 / Al 2 O 3 ) is 0.62 or less, and SiO 2 is a composite inorganic powder having a coating amount of 0.1 to 30% by weight,
For a sample in which 10 mg of a mixture of composite inorganic powder and talc and squalane (weight ratio 47: 47: 6) is uniformly applied to a 10 cm × 5 cm portion of the surface of black artificial leather, S polarizing plates are respectively provided on the incident light side and the light receiving side. Alternatively, using a variable angle spectrocolorimeter equipped with a P-polarizing plate, when the surface reflected light amount and the powder layer reflected light amount under the light receiving condition of 2 ° field of view with C light are measured, the incident light angle is 45 ° and the light receiving angle is 45. The difference in the amount of reflected light on each surface measured under the condition of ° and the incident light angle of 45 ° and the light receiving angle of 0 ° is 7 to 15, and the difference is measured at the incident light angle of 45 ° and the light receiving angle of 0 ° The difference between the reflected light amount on the surface and the reflected light amount on the powder layer is −3 to 3 ,
A composite inorganic powder in which the total coating amount of the metal oxide is 1 to 50% by weight of the component (A) ;
(B) A skin cosmetic containing fine-particle zinc oxide having a specific surface area of 50 to 100 m 2 / g.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000290598A JP4205844B2 (en) | 2000-09-25 | 2000-09-25 | Skin cosmetics |
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| Application Number | Priority Date | Filing Date | Title |
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| JP2000290598A JP4205844B2 (en) | 2000-09-25 | 2000-09-25 | Skin cosmetics |
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| JP2002104930A JP2002104930A (en) | 2002-04-10 |
| JP4205844B2 true JP4205844B2 (en) | 2009-01-07 |
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| JP4684480B2 (en) * | 2001-07-18 | 2011-05-18 | 株式会社ナリス化粧品 | Inorganic powder composition and cosmetics using the same |
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