WO2022097357A1 - Composition lubrifiante - Google Patents

Composition lubrifiante Download PDF

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Publication number
WO2022097357A1
WO2022097357A1 PCT/JP2021/031974 JP2021031974W WO2022097357A1 WO 2022097357 A1 WO2022097357 A1 WO 2022097357A1 JP 2021031974 W JP2021031974 W JP 2021031974W WO 2022097357 A1 WO2022097357 A1 WO 2022097357A1
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WIPO (PCT)
Prior art keywords
lubricating oil
component
mass
oil composition
content
Prior art date
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PCT/JP2021/031974
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English (en)
Japanese (ja)
Inventor
耕平 増田
真夕子 松岡
紀子 菖蒲
Original Assignee
Ｅｎｅｏｓ株式会社
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Publication of WO2022097357A1 publication Critical patent/WO2022097357A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
    • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
    • C10M137/04—Phosphate esters
    • C10M137/10—Thio derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

Definitions

  • the present invention relates to a lubricating oil composition, and more particularly to a lubricating oil composition that can be suitably used for lubricating an electric motor.
  • an air cooling method As a means for cooling the electric motor, an air cooling method, a water cooling method, and an oil cooling method are known.
  • the oil cooling method has a high cooling effect by circulating oil inside the electric motor to directly contact the heat generating part (for example, coil, core, magnet, etc.) in the electric motor with the cooling medium (oil). It is a method that can be obtained.
  • the oil cooling method is adopted, the electric motor is cooled and lubricated at the same time by the oil circulated inside. Therefore, the oil used in the oil cooling system (oil distributed inside the electric motor: electric motor oil) is required to have high electrical insulation so as not to impair the function of the electric motor during cooling and lubrication.
  • automobiles that use an electric motor as a power source for traveling are usually equipped with a transmission having a gear mechanism.
  • the lubricating oil used for lubricating the gear mechanism is usually required to have wear resistance.
  • Patent Document 1 discloses a lubricating oil composition containing a base oil and a phosphorus-containing carboxylic acid compound.
  • Patent Document 2 discloses a lubricating oil composition in which ⁇ -dithiophosphorylated propionic acid or ⁇ -dithiophosphorylated propionic acid ethyl ester is combined is disclosed.
  • Japanese Patent Application Laid-Open No. 2005-307203 discloses a lubricating oil composition containing a base oil and a phosphorus-containing carboxylic acid compound.
  • Patent Document 2 discloses a lubricating oil composition in which ⁇ -dithiophosphorylated propionic acid or ⁇ -dithiophosphorylated propionic acid ethyl ester is combined.
  • Patent Document 2 discloses a composition containing a lubricant such as an oil based on mineral oil and a compound represented by a specific formula, and a column of examples thereof is disclosed.
  • a composition containing a base and ⁇ -dithiophosphorylated propionic acid, or a base and ethyl-3-[(bisisopropyloxyphosphinothioil) thio] propionate (manufactured by BASF, brand name: Irgalube 63). ) And the composition including.
  • Patent Document 3 discloses a lubricating oil composition obtained by blending a sulfur compound represented by a specific formula with a specific base oil, and examples thereof are disclosed.
  • a lubricating oil composition containing a base oil and a dithiophosphate compound as a sulfur compound (manufactured by BASF, trade name: Irgalube 63) is disclosed.
  • all of the conventional lubricating oil compositions as described in Patent Documents 1 to 3 are necessarily sufficient in terms of achieving both a sufficiently high level of electrical insulation and excellent wear resistance. It wasn't a thing.
  • the present invention has been made in view of the above-mentioned problems of the prior art, and provides a lubricating oil composition capable of achieving both a sufficiently high level of electrical insulation and excellent wear resistance. With the goal.
  • the present inventors have made the lubricating oil composition include the following component (A), the following component (B1), and the following component (B2), and the following.
  • the lubricating oil composition of the present invention is (A) Lubricating oil base oil and (B1) A dithiophosphorylated fatty acid ester having a content of 0.01% by mass or more and 0.50% by mass or less based on the total mass of the lubricating oil composition. (B2) A dithiophosphorylated fatty acid having a content of 0.005% by mass or more and 0.15% by mass or less based on the total mass of the lubricating oil composition.
  • M (B1) indicates the content of the component (B1) based on the total mass of the lubricating oil composition
  • M (B2) is based on the total mass of the lubricating oil composition ( B2) Indicates the content of the component. ] It satisfies the condition represented by.
  • the component (B1) is the following general formula (1):
  • R 1 and R 2 each independently represent a linear or branched alkyl group having 1 to 18 carbon atoms
  • R 3 is a linear or branched chain having 1 to 18 carbon atoms. It represents an alkylene group of 10
  • R4 represents a linear or branched alkyl group having 1 to 18 carbon atoms.
  • It is preferably a compound represented by (hereinafter, sometimes simply referred to as “compound (X)”).
  • the component (B2) is the following general formula (2) :.
  • R 5 and R 6 each independently represent a linear or branched chain-shaped alkyl group having 1 to 18 carbon atoms, and R 7 is a linear or branched chain-shaped carbon number 1 to 18 each. Shows 10 alkylene groups.
  • It is preferably a compound represented by (hereinafter, sometimes simply referred to as “compound (Y)”).
  • the component (A) is preferably a lubricating oil base oil having a kinematic viscosity of 5.0 to 20.0 mm 2 / s at 40 ° C.
  • a lubricating oil composition capable of achieving both a sufficiently high level of electrical insulation and excellent wear resistance.
  • the lubricating oil composition of the present invention is (A) Lubricating oil base oil and (B1) A dithiophosphorylated fatty acid ester having a content of 0.01% by mass or more and 0.50% by mass or less based on the total mass of the lubricating oil composition. (B2) A dithiophosphorylated fatty acid having a content of 0.005% by mass or more and 0.15% by mass or less based on the total mass of the lubricating oil composition.
  • M (B1) indicates the content of the component (B1) based on the total mass of the lubricating oil composition
  • M (B2) is based on the total mass of the lubricating oil composition ( B2) Indicates the content of the component. ] It satisfies the condition represented by.
  • the lubricating oil base oil used as the component (A) in the present invention is not particularly limited, and known base oils available in the field of lubricating oil can be appropriately used.
  • one or more mineral oil-based base oils or One or more synthetic base oils or a mixed base oil thereof can be used.
  • the lubricating oil base oils in the classification of base oils by API (American Petroleum Institute), group II base oil, group III base oil, group IV base oil, and group V base oil. , Or a mixture of two or more of these base oils (mixed base oil) can be preferably used (hereinafter, the group of base oil classification by API is simply referred to as "API group").
  • the base oil of API Group II is a mineral oil-based base oil having a sulfur content of 0.03% by mass or less, a saturation content of 90% by mass or more, and a viscosity index of 80 or more and less than 120.
  • the base oil of API Group III is a mineral oil-based base oil having a sulfur content of 0.03% by mass or less, a saturation content of 90% by mass or more, and a viscosity index of 120 or more.
  • the base oil of API group IV is a poly ⁇ -olefin base oil.
  • the base oil of API group V is a base oil other than API groups I to IV, and preferred examples thereof include ester-based base oils.
  • the mineral oil-based base oil the lubricating oil distillate obtained by atmospheric distillation and vacuum distillation of crude oil is subjected to solvent removal, solvent extraction, hydrocracking, solvent removal, contact removal, and hydrorefining.
  • mineral oil-based base oils such as paraffin-based or naphthen-based, which are obtained by appropriately combining one or more kinds of refining means such as distillation washing and white clay treatment.
  • API Group II base oils and Group III base oils are usually produced through a hydrocracking process.
  • a wax isomerized base oil, a base oil produced by a method of isomerizing GTL WAX (gas to liquid wax), or the like can also be used.
  • Examples of the base oil of API Group IV include ethylene-propylene copolymers, polybutenes, 1-octene oligomers, 1-decene oligomers, and hydrides thereof.
  • the base oil of API Group V includes, for example, monoesters (eg, butylstearate, octyllaurate, 2-ethylhexyloleate, etc.); diesters (eg, ditridecylglutarate, bis (2-ethylhexyl) adipate, diisodecyl adipate, ditri).
  • monoesters eg, butylstearate, octyllaurate, 2-ethylhexyloleate, etc.
  • diesters eg, ditridecylglutarate, bis (2-ethylhexyl) adipate, diisodecyl adipate, ditri.
  • Polyester eg, trimellitic acid ester, etc.
  • Polyester ester eg, trimethylolpropane caprilate, trimethylolpropane pelargonate, pentaerythritol-2-ethylhexanoate, penta) Ellis ritol pelargonate, etc.
  • the lubricating oil base oil may consist of one type of base oil or may be a mixed base oil containing two or more types of base oil.
  • the API classifications of the base oils may be the same or different from each other.
  • the content of the base oil of API Group V is preferably 0 to 20% by mass (more preferably 0 to 15% by mass, still more preferably 0 to 10% by mass) based on the total amount of the lubricating oil base oil.
  • the component (A) has a kinematic viscosity at 100 ° C. of 1.8 to 4.5 mm 2 / s (more preferably 2.1 to 4.5 mm 2 / s, particularly preferably 2.3 to 4.2 mm 2 / s). ) Is preferably the lubricating oil base oil.
  • the kinematic viscosity of the lubricating oil base oil at 100 ° C. is not more than the upper limit value, it is possible to further improve the fuel efficiency as compared with the case where the upper limit value is exceeded.
  • kinematic viscosity at 100 ° C. is measured using an automatic viscometer (trade name "CAV-2100", manufactured by Canon Instrument) as a measuring device in accordance with JIS K 2283-2000. It means the kinematic viscosity at 100 ° C.
  • the component (A) has a kinematic viscosity of 5.0 to 20.0 mm 2 / s (more preferably 7.0 to 20.0 mm 2 / s, particularly preferably 7.7 to 19.5 mm 2 / s) at 40 ° C. s)
  • the lubricating oil base oil is preferable.
  • the kinematic viscosity of the lubricating oil base oil at 40 ° C. is not more than the upper limit value, it is possible to further improve the fuel efficiency as compared with the case where the upper limit value is exceeded.
  • kinematic viscosity at 40 ° C. is measured using an automatic viscometer (trade name "CAV-2100", manufactured by Canon Instrument) as a measuring device in accordance with JIS K 2283-2000. It means the kinematic viscosity at 40 ° C.
  • the component (A) is preferably a lubricating oil base oil having a viscosity index of 100 or more (more preferably 105 or more, further preferably 110 or more, particularly preferably 120 or more, most preferably 125 or more).
  • a viscosity index of the lubricating oil base oil is at least the above lower limit value, the viscosity-temperature characteristics of the lubricating oil composition are further improved and the friction coefficient is further reduced as compared with the case where the viscosity index is less than the lower limit value.
  • the "viscosity index” means a viscosity index measured in accordance with JIS K 2283-1993.
  • the content of sulfur in the lubricating oil base oil, which is the component (A), is preferably 0.03% by mass (300% by mass) or less, more preferably 50% by mass or less, from the viewpoint of oxidation stability. It is particularly preferably 10 mass ppm or less, and most preferably 1 mass ppm or less.
  • the component (A) occupies the main part (main component) of the lubricating oil composition of the present invention.
  • the content of component (A) in the lubricating oil composition is based on the total amount of the lubricating oil composition. It is preferably 80% by mass or more (more preferably 90% by mass or more, still more preferably 92% by mass or more).
  • the content of the component (A) may be 75.0 to 99.5% by mass based on the total amount of the lubricating oil composition, depending on the case (for example, depending on its use, relationship with other components, etc.). good.
  • dithiophosphorylated fatty acid ester used as the component (B1) in the present invention is not particularly limited, and is described in known dithiophosphorylated fatty acid ester compounds (for example, JP-A-2010-150562 and JP-A-2010-138416). Of the described phosphorylated carboxylic acids, those that serve as esters, etc.) can be appropriately used.
  • R 1 and R 2 each independently represent a hydrocarbon group having 1 to 30 carbon atoms
  • R 3 represents an alkylene group having 1 to 20 carbon atoms
  • R 4 has 1 carbon atom. Shows up to 30 hydrocarbon groups.
  • It is preferably a compound represented by.
  • R 1 and R 2 in the general formula (1) independently represent hydrocarbon groups having 1 to 30 carbon atoms.
  • the hydrocarbon group having 1 to 30 carbon atoms include a linear or branched alkyl group, a cycloalkyl group, a linear or branched alkenyl group, an alkyl substituted cycloalkyl group, an aryl group, and an alkyl.
  • Substituted aryl groups or arylalkyl groups can be mentioned, and among them, linear or branched alkyl groups are more preferable.
  • the linear or branched alkyl groups that can be suitably selected as R 1 and R 2 include, for example, a methyl group, an ethyl group, a propyl group, an isopropyl group, an n-butyl group, an isobutyl group, and a tertiary butyl.
  • pentyl group isopentyl group, hexyl group, heptyl group, 3-heptyl group, octyl group, 2-ethylhexyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group, pentadecyl group, hexadecyl group , Heptadecyl group, octadecyl group, 2-ethylbutyl group, 1-methylphenyl group, 1,3-dimethylbutyl group, 1,1,3,3-tetramethylbutyl group, 1-methylhexyl group, isoheptyl group, 1- Examples thereof include a methylheptyl group, a 1,1,3-trimethylhexyl group and a 1-methylundecyl group.
  • the number of carbon atoms of the linear or branched alkyl group that can be selected as R 1 and R 2 in the general formula (1) is preferably 1 to 18, and is preferably 3 to 18 alkyl groups. More preferably, it is more preferably 3 to 8.
  • R 3 in the general formula (1) represents an alkylene group having 1 to 20 carbon atoms.
  • the carbon number of the alkylene group is preferably 1 to 10, more preferably 2 to 6, and even more preferably 2 to 4.
  • the alkylene group that can be selected as R 3 includes the following general formula (3):
  • R 8 , R 9 , R 10 and R 11 each independently represent a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms. However, R 8 , R 9 , R 10 and R 11 satisfy the condition that the total number of carbon atoms is 6 or less.
  • the alkylene group represented by is preferable.
  • R 8 , R 9 , R 10 and R 11 in the general formula (3) are independently hydrogen atoms or hydrocarbon groups having 1 to 3 carbon atoms (more preferably 1 to 2), respectively. In this case, it is more preferable that the total number of carbon atoms of R 8 , R 9 , R 10 and R 11 satisfies the condition of 5 or less (more preferably 4 or less, particularly preferably 3 or less). Further, in R 8 , R 9 , R 10 and R 11 in the general formula (3), all of them are hydrogen atoms, or both R 8 and R 9 are hydrogen atoms and R 10 and R are R. It is preferable that one of 11 is a hydrogen atom and the other is a methyl group.
  • R4 of the general formula (1) represents a hydrogen atom or a hydrocarbon group having 1 to 30 carbon atoms.
  • the hydrocarbon group has the same meaning as the hydrocarbon group having 1 to 30 carbon atoms described in R 1 and R 2 (basically, a suitable one is also synonymous).
  • R4 of the general formula (1) a linear alkyl group having 1 to 8 carbon atoms (most preferably 1 to 4) is particularly preferable, and an ethyl group is most preferable.
  • the compound represented by the general formula (1) is more preferably the compound (X). That is, as the compound represented by the general formula (1), R 1 and R 2 in the general formula (1) are independently linear or branched and have 1 to 18 carbon atoms (more preferably 3). ⁇ 18, particularly preferably 3 to 8), and R3 is a linear or branched alkylene group having 1 to 10 carbon atoms (particularly preferably an alkylene represented by the above general formula (3)). Group), where R4 is a linear or branched alkyl group having 1 to 18 carbon atoms (particularly preferably a linear alkyl group having 1 to 8 carbon atoms, most preferably 1 to 4 carbon atoms). It is more preferable that the compound exhibits a linear alkyl group ().
  • the method for producing the component (B1) is not particularly limited, and a known method can be appropriately used. Further, as the component (B1), a commercially available product may be used.
  • dithiophosphorylated fatty acid used as the component (B2) in the present invention is not particularly limited, and is described in known dithiophosphorylated fatty acid compounds (for example, JP-A-2010-150562 and JP-A-2010-138416). Phosphorylated carboxylic acid, etc.) can be appropriately used.
  • R 5 and R 6 each independently represent a hydrocarbon group having 1 to 30 carbon atoms, and R 7 represents an alkylene group having 1 to 20 carbon atoms.
  • It is preferably a compound represented by.
  • the hydrocarbon groups having 1 to 30 carbon atoms that can be selected as R 5 and R 6 in the general formula (2) have 1 to 30 carbon atoms that can be selected as R 1 and R 2 in the general formula (1), respectively.
  • the alkylene group having 1 to 20 carbon atoms which can be selected as R7 in the general formula (2) is synonymous with the hydrocarbon group of (1). It is synonymous with an alkylene group having 1 to 20 carbon atoms that can be selected as R 3 in the medium (the preferred one is also synonymous).
  • the compound represented by the general formula (2) is more preferably the compound (Y). That is, as the compound represented by the general formula (2), R 5 and R 6 in the general formula (2) are independently linear or branched chains having 1 to 18 carbon atoms (more preferably 3). ⁇ 18, particularly preferably 3 to 8), and R7 is a linear or branched alkylene group having 1 to 10 carbon atoms (particularly preferably an alkylene represented by the above general formula (3)). It is more preferable that it is a compound showing a group).
  • the method for producing the component (B2) is not particularly limited, and a known method can be appropriately used. Further, as the component (B2), a commercially available product may be used.
  • the content of the component (B1) is 0.01% by mass or more and 0.50% by mass or less (more preferably 0.10% by mass or more and 0.40% by mass or less) based on the total mass of the lubricating oil composition. ..
  • the wear resistance can be further improved as compared with the case where the content is less than the lower limit value.
  • the content of the component (B1) is not more than the upper limit value, it is possible to further improve the wear resistance and the electrical insulation property as compared with the case where the upper limit value is exceeded.
  • the content of the component (B2) is 0.005% by mass or more and 0.15% by mass or less (more preferably 0.01% by mass or more and 0.10% by mass or less) based on the total mass of the lubricating oil composition. Is.
  • the content of the component (B2) is at least the lower limit value, the wear resistance can be further improved as compared with the case where the content is less than the lower limit value.
  • the content of the component (B2) is not more than the upper limit value, it is possible to further improve the electrical insulation property as compared with the case where the upper limit value is exceeded.
  • M (B1) indicates the content (mass ratio) of the component (B1) based on the total mass of the lubricating oil composition
  • M (B2) indicates the total mass of the lubricating oil composition.
  • the content (mass ratio) of the component (B2) as a reference is shown. ] It is necessary to satisfy the condition represented by.
  • the value of [M (B1) / (M (B1) + M (B2) )) in the above formula (I) is 0.40 or more and 0.90 or less. It is more preferable that there is, and it is particularly preferable that it is 0.50 or more and 0.85 or less.
  • the lubricating oil composition of the present invention is generally used in a lubricating oil composition depending on the purpose in order to further improve its performance.
  • the known additives mentioned above may be appropriately contained.
  • the additives contained in the lubricating oil composition of the present invention among them, (C) a metal-based detergent, (D) an ashless dispersant, from the viewpoint of further improving the oxidation stability of the lubricating oil composition.
  • (E) Antioxidants are preferred.
  • the component (C), the component (D) and the component (E) are contained in combination. Is particularly preferred.
  • the lubricating oil composition of the present invention can further improve wear resistance and oxidation stability, it is preferable that the lubricating oil composition further contains (C) a metal-based detergent.
  • the component (C) is not particularly limited, and a known metal-based cleaning agent can be appropriately used. Can be mentioned. Further, among the components (C), a sulfonate cleaning agent and a salicylate cleaning agent are preferable because a higher effect can be obtained in terms of wear resistance and oxidation stability.
  • a sulfonate detergent suitable as the component (C) for example, an alkali of an alkyl aromatic sulfonic acid obtained by sulfonated an alkyl aromatic compound having a molecular weight of 300 to 1500 (more preferably 400 to 1300).
  • Metallic salts or alkaline earth metal salts can be mentioned as suitable.
  • the alkyl aromatic sulfonic acid include petroleum sulfonic acid and synthetic sulfonic acid. Further, known petroleum sulfonic acids and synthetic sulfonic acids can be appropriately used.
  • (C1) calcium sulfonate cleaning agent is more preferable.
  • the component (C1) include calcium sulfonate, which is a calcium salt of an alkyl aromatic sulfonic acid, a basic salt of the calcium sulfonate, and a hyperbasic salt of the calcium sulfonate.
  • the method for preparing the basic salt or the hyperbasic salt is not particularly limited, and a known method can be appropriately used.
  • the sulfonate cleaning agent known ones that can be used for the lubricating oil composition (for example, those described in JP-A-2016-020454) can be appropriately used.
  • the salicylate detergent suitable as the component (C) is not particularly limited, but for example, an alkylsalicylic acid having 1 to 2 alkyl groups or alkenyl groups having 4 to 36 carbon atoms (more preferably 14 to 30) as a substituent. Alkali metal salts or alkaline earth metal salts and mixtures thereof and the like can be mentioned.
  • As the salicylate cleaning agent (C2) calcium salicylating cleaning agent is more preferable.
  • the component (C2) for example, calcium salicylate, a basic salt of calcium salicylate, or a hyperbasic salt of calcium salicylate can be used.
  • the method for preparing the basic salt or the hyperbasic salt is not particularly limited, and a known method can be appropriately used.
  • known components that can be used in the lubricating oil composition for example, those described in JP-A-2020-076004, International Publication No. 2020/095970, etc.
  • the component (C) the component (C1) and the component (C2) are more preferable, and the component (C1) is particularly preferable, because a higher effect can be obtained in terms of wear resistance and oxidation stability.
  • a calcium sulfonate detergent is particularly preferable.
  • the component (C) may be used alone or in combination of two or more.
  • the base value of the metal-based detergent as the component (C) is not particularly limited, but is preferably 50 to 500 mgKOH / g, more preferably 100 to 500 mgKOH / g, and particularly preferably 150 to 500 mgKOH / g. g.
  • the base value of the component (C) is at least the above lower limit value, it becomes possible to further enhance the electrical insulating property of the composition after oxidative deterioration.
  • the method for producing the component (C) is not particularly limited, and a known production method can be appropriately used.
  • a commercially available product may be used as the component (C).
  • the content of the component (C) is not particularly limited, but is 0.01 to 0.50% by mass (more preferably) based on the total amount of the lubricating oil composition. Is preferably 0.05 to 0.30% by mass).
  • the content of the component (C) is preferably an amount such that the mass of the metal element is 10 to 500 mass ppm (more preferably 50 to 300 mass ppm) based on the total amount of the lubricating oil composition.
  • the content of the component (C) is not more than or equal to the upper limit value, the electrical insulating property of the lubricating oil composition can be further enhanced as compared with the case where the upper limit value is exceeded.
  • the content of the component (C) is at least the above lower limit value, the fatigue resistance can be further improved as compared with the case where the content is less than the front lower limit value.
  • the lubricating oil composition of the present invention can disperse metal powder generated by wear during use to a higher degree, can further improve wear resistance, and further improve oxidation stability. Therefore, it is preferable to further contain (D) an ashless dispersant.
  • the component (D) known compounds used as ash-free dispersants in the field of lubricating oil compositions (for example, JP-A-2003-155492, JP-A-2020-76004, International Publication No. 2013/147162). Etc.) can be used as appropriate.
  • the ashless dispersant include mono or biscosuccinateimide having at least one linear or branched alkyl group or alkenyl group in the molecule, and benzylamine having at least one alkyl group or alkenyl group in the molecule. , Polyamine having at least one alkyl group or alkenyl group in the molecule, or a modified product of these boron compounds, carboxylic acid, phosphoric acid and the like.
  • the linear or branched alkyl group or alkenyl group has a linear or branched alkyl group or alkenyl group having 40 to 400 carbon atoms (more preferably 60 to 350). Is preferable.
  • (D1) borohydride succinimide (the above-mentioned mono or a boron-modified compound of bisuccinimide, etc.), (D2).
  • Non-boronized succinimide (such as the above-mentioned mono or bisuccinimide) and mixtures thereof can be preferably used.
  • component (D1) and the component (D2) known boronized succinimide compounds and non-borated succinimide compounds used as ashless dispersants can be appropriately used. Further, as the component (D1) and the component (D2), those having a nitrogen atom content of 0.5 to 3.0% by mass based on the total amount of the component (D1) or the component (D2) are preferable. Further, as the component (D1), a component having a boron atom content of 0.1 to 5.0% by mass is preferable based on the total amount of the component (D1).
  • the components (D1) and (D2) preferably have a weight average molecular weight of 1000 to 20000 (more preferably 2000 to 20000, still more preferably 4000 to 15000), respectively.
  • the component (D) may be used alone or in combination of two or more.
  • the content of the component (D) is not particularly limited, but is 0.1 to 5.0% by mass (based on the total amount of the lubricating oil composition). More preferably 0.1 to 2.5% by mass). By setting the content of the component (D) within the above range, it is possible to further improve the electrical insulation.
  • the lubricating oil composition of the present invention can further improve the oxidative stability, it is preferable to further contain (E) an antioxidant.
  • the component (E) is not particularly limited, and a known one used as an antioxidant in the field of lubricating oil compositions can be appropriately used.
  • (E1) a phenolic antioxidant (hereinafter, simply in some cases)
  • examples thereof include “(E1) component"), (E2) amine-based antioxidant (hereinafter, in some cases, simply referred to as "(E2) component”), and the like.
  • component (E1) examples include 4,4'-methylenebis (2,6-di-t-butylphenol); 4,4'-bis (2,6-di-tert-butylphenol); 4,4'-. Bis (2-methyl-6-tert-butylphenol); 2,2'-methylenebis (4-ethyl-6-tert-butylphenol); 2,2'-methylenebis (4-methyl-6-tert-butylphenol); 4 , 4'-butylidenebis (3-methyl-6-tert-butylphenol); 4,4'-isopropyridenebis (2,6-di-tert-butylphenol); 2,2'-methylenebis (4-methyl-6- Nonylphenol); 2,2'-isobutylidenebis (4,6-dimethylphenol); 2,2'-methylenebis (4-methyl-6-cyclohexylphenol); 2,6-di-tert-butyl-4- Methylphenol; 2,6-di-tert-butyl-4- Me
  • 3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid esters include octyl-3- (3,5-di-tert-butyl-4-hydroxyphenyl) propionate; decyl.
  • Examples of the component (E2) are exemplified by compounds known as amine-based antioxidants such as aromatic amine-based antioxidants and hindered amine-based antioxidants (for example, International Publication No. 2020/095970). Compounds, etc.) can be used as appropriate.
  • amine-based antioxidant alkylated diphenylamine and alkylated phenyl- ⁇ -naphthylamine can be preferably used.
  • the hindered amine-based antioxidant for example, a compound having a 2,2,6,6-tetraalkylpiperidine skeleton (2,2,6,6-tetraalkylpiperidine derivative) or the like can be preferably used.
  • an aromatic amine-based antioxidant can be more preferably used.
  • component (E) one type may be used alone, or two or more types may be used in combination. Further, as the component (E), it is preferable to use the component (E1) and the component (E2) in combination from the viewpoint that the oxidative deterioration of the lubricating oil composition can be suppressed for a long period of time.
  • the content of the component (E) is 0.1 to 1.5% by mass (more preferably 0.1 to 1) based on the total amount of the lubricating oil composition. 1.0% by mass) is preferable.
  • the content of the component (E) is more than 0% by mass and 1.5% by mass or less (more preferably 0) based on the total amount of the lubricating oil composition.
  • the lubricating oil composition of the present invention contains the component (E2), the content of the component (E2) is more than 0% by mass and 1.5% by mass or less (more preferably 0) based on the total amount of the lubricating oil composition. It is preferably more than mass% and 1.0% by mass or less (note that the lower limit of the content is more preferably 0.005% by mass or more).
  • the content of the component (E2) is such that the mass of nitrogen is more than 0% by mass and 0.15% by mass or less (more preferably more than 0% by mass 0) based on the total amount of the lubricating oil composition.
  • the amount is preferably 10.10% by mass or less) (the lower limit of the mass of nitrogen is more preferably 0.0005% by mass or more).
  • the (C) metal-based detergent, (D) ashless dispersant, and (E) antioxidant which are additives that can be suitably used for the lubricating oil composition of the present invention, have been described above.
  • the additives that can be used in the lubricating oil composition of the present invention are not limited to the above components (C) to (E), and as described above, they are known to be used in the field of lubricating oil compositions. Other additives can be used as appropriate.
  • the additives other than the above components (C) to (E) are not particularly limited, but for example, a pour point lowering agent, a friction modifier, a metal defoaming agent, a rubber swelling agent, and the like.
  • Examples thereof include defoaming agents, diluting oils, viscosity index improvers, rust preventives, antiemulsifiers, colorants, corrosion inhibitors and the like.
  • the other additives are not particularly limited and are known (for example, JP-A-2003-155492, JP-A-2017 / 073748, JP-A-2020-76004, JP-A-2020 / 09957). Etc.) can be used as appropriate.
  • the lubricating oil composition of the present invention more preferably has a kinematic viscosity of 2.0 to 5.0 mm 2 / s at 100 ° C. Further, the lubricating oil composition of the present invention preferably has a kinematic viscosity of 7.0 to 20.5 mm 2 / s at 40 ° C. When these kinematic viscosities are not more than the upper limit value, it is possible to further improve fuel efficiency as compared with the case where the upper limit value is exceeded.
  • the method for producing the lubricating oil composition of the present invention is not particularly limited, and the content of the component (B1) based on the total mass of the lubricating oil composition is 0.01% by mass or more and 0.50% by mass. % Or less, and the content of the component (B2) based on the total mass of the lubricating oil composition is 0.005% by mass or more and 0.15% by mass or less, and further, the content of the components (B1) and (B2) is
  • the lubricating oil composition of the present invention can be obtained by containing the component (A), the component (B1) and the component (B2) so that the above-mentioned condition (I) is satisfied. A method such as that can be appropriately adopted.
  • the lubricating oil composition of the present invention can achieve both wear resistance and electrical insulation at a sufficiently high level, for example, electric motor oil, transmission oil, electric motor and transmission (gear mechanism).
  • Electric motor oil, transmission oil, electric motor and transmission (gear mechanism)
  • Lubricating oil for an electric drive module provided with an electric motor and a transmission (gear mechanism) (lubricating oil for lubricating both the electric motor and the transmission) and the like.
  • A-1 Hydrorefined mineral oil (API base oil classification: Group II, kinematic viscosity (40 ° C): 7.7 mm 2 / s, kinematic viscosity (100 ° C): 2.3 mm 2 / s, viscosity index: 118, Sulfur content: less than 1 mass ppm)
  • A-2 Hydrorefined mineral oil (API base oil classification: Group III, kinematic viscosity (40 ° C): 19.5 mm 2 / s, kinematic viscosity (100 ° C): 4.2 mm 2 / s, viscosity index: 125, Sulfur content: less than 1 mass ppm)
  • A-3 Wax isomerized base oil (API base oil classification: Group III, kinematic viscosity (40 ° C): 9.3 mm 2 / s, kinematic viscosity (100 ° C)
  • B-2 Dithiophosphorylated fatty acid: Compound represented by the following formula (Y1) (manufactured by BASF, trade name "Irgalube 353", bis (2-methylpropoxy) phospinothiolthio-2-methyl)
  • C-1 Calcium sulfonate detergent (base value 300 mgKOH / g, calcium atom content: 11.6% by mass)
  • C-2 Calcium salicylate detergent (base value 325 mgKOH / g, calcium atom content: 11.4% by mass).
  • D-1 Boronized succinimide (nitrogen atom content: 0.73% by mass, boron atom content: 0.19% by mass, weight average molecular weight: 9300)
  • D-2 Non-borated succiimide (nitrogen atom content: 1.5% by mass, weight average molecular weight: 4600).
  • E-1 Phenolic antioxidant: 3- (3,5-di-tert-butyl-4-hydroxyphenyl) octyl propionate
  • E-2 amine-based antioxidant: monobutylphenyl monooctylphenylamine (nitrogen) Atomic content: 4.5% by mass).
  • Lubricating oil compositions were prepared using the above-mentioned components so as to have the compositions shown in Tables 1 to 4.
  • "-" indicates that the component is not used.
  • “inmass%”, which is a unit of the content of the component (A) represents the content (mass%) of each base oil component with respect to the total amount of the lubricating oil base oil, and (B) to.
  • Tables 1 to 4 show the kinematic viscosities of the component (A) used in each example and the like (in the case of a mixture of two kinds of base oils, the mixture thereof) at 40 ° C. and the kinematic viscosities at 100 ° C. show. Further, in Tables 1 to 4, for each lubricating oil composition, "M" is used when the content of B-1 is M (B-1) and the content of B-2 is M (B-2) . The values of (B-1) / (M (B-1) + M (B-2) )) are also shown.
  • the content of the lubricating oil base oil and the total amount of the lubricating oil composition is 0.01% by mass or more and 0.50% by mass or less of B-1 (dithiophosphorylation).
  • Fatty acid ester) and B-2 (dithiophosphorylated fatty acid) having a content of 0.005% by mass or more and 0.15% by mass or less based on the total amount of the lubricating oil composition, and M (B-1) /.
  • the lubricating oil composition obtained in Examples 1 to 22 (the lubricating oil of the present invention) having a value of (M (B-1) + M (B-2) ) in the range of 0.30 or more and 0.95 or less.
  • the volumetric resistance was 1.0 ⁇ 10 10 ⁇ ⁇ cm or more, and it was confirmed that the electrical insulation was at a sufficiently high level. Further, all of the lubricating oil compositions obtained in Examples 1 to 22 (corresponding to the lubricating oil composition of the present invention) have a wear mark diameter of 0.80 mm or less (0.79 mm) when used in a high-speed walk test. It was also confirmed that it has excellent wear resistance.
  • M (B-1) / (M (B-1) + M (B-2) ) in the range of 0.30 or more and 0.95 or less.
  • the lubricating oil composition of the present invention makes it possible to improve both electrical insulation and wear resistance, and has a sufficiently high level of electrical insulation. It was found that it is possible to achieve both excellent wear resistance and excellent wear resistance.
  • the lubricating oil composition of the present invention is particularly useful as a lubricating oil or the like used for lubricating both the electric motor and the transmission.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne une composition lubrifiante comprenant (A) une huile de base lubrifiante, (B1) 0,01 à 0,50 % en masse d'un ester d'acide gras dithiophosphorylé, masse rapportée à la masse totale de la composition lubrifiante, et (B2) 0,005 à 0,15 % en masse d'un acide gras dithiophosphorylé, masse rapportée à la masse totale de la composition lubrifiante ; et satisfaisant des conditions représentées par une formule spécifique.
PCT/JP2021/031974 2020-11-04 2021-08-31 Composition lubrifiante WO2022097357A1 (fr)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010018780A (ja) * 2008-07-14 2010-01-28 Afton Chemical Corp 熱に安定な無亜鉛摩耗防止剤
JP2012207083A (ja) * 2011-03-29 2012-10-25 Jx Nippon Oil & Energy Corp 潤滑油組成物
JP2017088651A (ja) * 2015-11-04 2017-05-25 昭和シェル石油株式会社 潤滑油組成物
JP2020172642A (ja) * 2019-04-10 2020-10-22 Ｅｎｅｏｓ株式会社 潤滑油組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010018780A (ja) * 2008-07-14 2010-01-28 Afton Chemical Corp 熱に安定な無亜鉛摩耗防止剤
JP2012207083A (ja) * 2011-03-29 2012-10-25 Jx Nippon Oil & Energy Corp 潤滑油組成物
JP2017088651A (ja) * 2015-11-04 2017-05-25 昭和シェル石油株式会社 潤滑油組成物
JP2020172642A (ja) * 2019-04-10 2020-10-22 Ｅｎｅｏｓ株式会社 潤滑油組成物

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