WO2022095908A1 - 一种除草剂组合物及其应用 - Google Patents
一种除草剂组合物及其应用 Download PDFInfo
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- WO2022095908A1 WO2022095908A1 PCT/CN2021/128499 CN2021128499W WO2022095908A1 WO 2022095908 A1 WO2022095908 A1 WO 2022095908A1 CN 2021128499 W CN2021128499 W CN 2021128499W WO 2022095908 A1 WO2022095908 A1 WO 2022095908A1
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- WIPO (PCT)
- Prior art keywords
- methyl
- component
- butyl
- hydrogen
- ethyl
- Prior art date
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 27
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 22
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 18
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- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 8
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 8
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
- A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/06—Sulfonic acid amides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/30—Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
Definitions
- the invention belongs to the field of agricultural herbicides, and relates to a herbicide composition and application thereof.
- Patent WO2016095768 reports isoxazoline-containing uracil compounds as shown in general formula I:
- the compound of general formula I has good herbicidal activity and can effectively control barnyardgrass, foxtail, sedge, water sedge, crabgrass, sedge grass, abalone, zinnia, amaranth, purslane, sagebrush Weeds at different leaf stages such as ear, nightshade, cassia, wild watermelon seedlings, wild soybeans, etc., have excellent weed control effect.
- the object of the present invention is to provide a herbicidal composition and its application.
- a herbicide composition is composed of component A and component B, component A is a compound with the following structural formula I; component B is selected from ALS inhibitors, ACCa enzyme inhibitors , one or more of HPPD inhibitors, triazinones, PPO inhibitors, hormone inhibitors herbicides; the weight ratio between the component A and the component B is 1:100 ⁇ 100:1;
- R 1 is selected from methyl
- R 2 and R 3 can be the same or different, and are respectively selected from hydrogen, fluorine or chlorine;
- R 4 is selected from hydrogen, cyano, methyl, ethyl, n-propyl, n-butyl, isopropyl, isobutyl, tert-butyl, trifluoroethyl, trifluoromethyl or CO 2 R 6 ;
- R 5 is selected from hydrogen, methyl, ethyl, tert-butyl or trifluoromethyl
- R 6 is selected from hydrogen, methyl, ethyl, n-propyl, n-butyl, isopropyl, isobutyl, tert-butyl, trifluoroethyl, allyl, propargyl, methoxyethyl , ethoxyethyl, methylcarbonyloxyethyl, 2-tetrahydrofuranmethylene or 3-tetrahydrofuranmethylene.
- the component A is the compound represented by formula I, in formula I:
- R 1 is selected from methyl
- R 2 and R 3 can be the same or different, and are respectively selected from hydrogen, fluorine or chlorine;
- R 4 is selected from CO 2 R 6 ;
- R 5 is selected from hydrogen, methyl, ethyl, tert-butyl or trifluoromethyl
- R 6 is selected from hydrogen, methyl, ethyl, n-propyl, n-butyl, isopropyl, isobutyl, tert-butyl, trifluoroethyl, allyl, propargyl, methoxyethyl , ethoxyethyl, 2-tetrahydrofuran methylene or 3-tetrahydrofuran methylene.
- Component B is chlorsulfuron-methyl, chlorsulfuron-methyl, fluorosulfuron-methyl, cyclosulfuron-methyl, rimsulfuron-methyl, trisulfuron-methyl, flumisulfuron-methyl, iodosulfuron-methyl, foramsulfuron-methyl, One or more of nicosulfuron-methyl, diflufena-ft, clodinafop-prop, propanil, cyhalofop-prop, pinoxafen, etc.;
- Component B is metazapyr, pyrazolate, pentapyr, diflufenazone, mesotrione, oxaflutole, cyclosulfonone, sulfapyrazole, diflufenapyr, isoproturon , Methyldisulfuron, Fluoxulfuron, Dioxsulam, Diclosulfuron, Penoxsulam, Chlorpyrazosulfuron, Trisulfuron, Cyclamate One or more of fendizone, fenflufen, and oxyfluorfen;
- Component B is profenazone, acifluorfen, methyl oxafen, metazapyr, acloxyfluorfen, chlorofluorfen, flufentrazone, sulfentrazone, fenconazole, fenoxapyr
- the weight ratio between the component A and the component B is 1:50-50:1.
- said component A is the compound shown in formula I, in formula I:
- R 1 is selected from methyl
- R 2 and R 3 can be the same or different, and are respectively selected from fluorine or chlorine;
- R 4 is selected from CO 2 R 6 ;
- R 5 is selected from hydrogen, methyl, ethyl or tert-butyl
- R is selected from hydrogen, methyl, ethyl, n - propyl, n-butyl, isopropyl, isobutyl or tert-butyl;
- Component B is chlorsulfuron-methyl, epoxysulfuron-methyl, rimsulfuron-methyl, trifensulfuron-methyl, foramsulfuron-methyl, nicosulfuron-methyl, pyrazofen-ethyl, clodinafop-propargyl, propanil, cyhalofop One or more of esters, pinoxaden, and;
- Component B is metazatrione, pyrazolate, mesotrione, oxaflutole, cyclosulfonone, sulfapyrazole, diflufenacil, isoproturon, methyldisulfuron, and fluoxazole Sulfuron-methyl, Dioxsulam, Diclossulam, Penoxsulam, Chlorpyrazosulfuron, Trisulfuron-methyl, Cycloazinone, Sulfonamides: flavin, fenoxuron, phenazine One or more of oxflufen and oxyfluorfen;
- Component B is profenazone, chlorfenapyr, fenconazole, carfenazone, saflufenacil, fomesafen, atrazine, picloram, quinoxazone, 2 One or more of methyl 4-chloroisooctyl chloride and chloramphenicol;
- the weight ratio between component A and component B is 1:25-25:1.
- said component A is the compound shown in formula I, in formula I: R 1 is selected from methyl;
- R 2 and R 3 can be the same or different, and are respectively selected from fluorine or chlorine;
- R 4 is selected from CO 2 R 6 ;
- R 5 is selected from hydrogen, methyl, ethyl or tert-butyl
- R 6 is selected from hydrogen, methyl, ethyl, isopropyl, n-propyl or n-butyl;
- Component B is one or more of formisulfuron-methyl, nicosulfuron-methyl, clodinafop-prop, propanil, cyhalofop-butyl, pinoxaden;
- Component B is mesotrione, oxaflutole, cyclosulfonone, sulfapyrazole, diflufenapyr, isoproturon, mesulfuron-methyl, fluoxulfuron-methyl, dioxsulam or variety;
- Component B is one or more of carfenazone, saflufenacil, fomesafen, atrazine, 2 methyl 4 chloroisooctyl chloride, and chloramphenicol;
- the weight ratio between component A and component B is 1:10-10:1.
- the herbicidal composition in controlling weeds.
- the herbicides of the present invention are applied to loci where undesirable vegetation is present or expected, and may be applied selectively or non-selectively to loci where undesirable vegetation is present or expected. Specifically, it can be applied to the soil where the vegetation is not expected to survive, the stems and leaves of the unwanted vegetation, or before the crops are planted or after sowing and before emergence, and the post-emergence treatment of tolerant crops and non-tolerant crops.
- the herbicide is applied to non-arable land, orchards, rubber plantations, idle cultivated land, rubber plantations, eucalyptus forests, fir forests, forests, fire roads, lawns, railways, highways, airports and warehouses.
- the tolerant and non-tolerant crops are selected from the group consisting of rice, corn, legume crops, rape, vegetables, cotton, sugar beets, small grains, soybeans, peanuts, sugarcane, sunflowers, cultivated crops, woody plants.
- the orchards include apple orchards, peach orchards, vineyards, pear orchards, tea orchards, mulberry orchards, and citrus orchards.
- the undesired vegetation includes grasses, broadleaf weeds, sedges, algae, ferns and woody shrubs.
- the herbicide activity of component A involved in the present invention has a broad herbicidal spectrum, and has activity on grass weeds and broadleaf weeds, but has different activities on different weeds.
- Component B herbicides The activity on grass weeds is higher than the activity on broad-leaved weeds.
- the invention expands the herbicidal spectrum through the mixed use of the two components, has obvious synergistic effect on the activity of grass weeds, and reduces the herbicidal effect.
- the dosage of the agent improves the overall control effect of the mixture on weeds;
- the herbicide of the present invention expands the suitable period of application, especially for the older weeds, the continuous inhibition and control effects are enhanced;
- the herbicide stem and leaf spraying treatment of the present invention can be used to prevent most weeds in places such as non-arable land, orchards, idle farmland, rubber plantations, eucalyptus forests, forests, fire roads, lawns, railways, highways, airports and warehouses.
- the synergistic effect of the herbicide of the present invention on grass weeds and broadleaf weeds can be further illustrated by the following examples, but the present invention is by no means limited thereto.
- the active components of the herbicide of the present invention are component A and component B, the component A is compound A, and component B is selected from ALS inhibitors, ACCa enzyme inhibitors, HPPD inhibitors, triazine One or more of ketones, PPO inhibitors, hormone inhibitor herbicides, etc.
- the percentages in all formulations are weight percentages, and the active components are calculated on the basis of effective content.
- Example The herbicide active component of the present invention is used to determine the indoor combined action of compound A and B on weeds, where A is a compound with the structure of general formula I, wherein R 1 is selected from methyl, R 2 is F, R 3 is Cl, R 4 is CO 2 C 2 H 5 , R 5 is CH 3 ; the active component B is: foramsulfuron-methyl, nicosulfuron, clodinafop-propargyl, propanil, cyhalofop-butyl, azoles Lineafen, carfenazone, saflufenacil, fomesafen, atrazine, 2-methyl-4-chloroisooctyl, chloramphenicol, mesotrione, oxaflutole, cyclosulfonone, Sulflufenazone, Diflufenapyr, Isoproturon, Methosulfuron-methyl, Fluoxasuulfuron, Dioxsulam
- the weed cultivation method is as follows: Quantitative weed seeds barnyardgrass, crabgrass, quinoa and amaranthus are sown in paper cups with a diameter of 7 cm and filled with nutrient soil. . The grass weeds grew to the 5-7 leaf stage, and the broad-leaved weeds were at the 6-8 leaf stage. The stems and leaves were sprayed, and the experiment was repeated 3 times. The treated liquid was naturally air-dried and placed in a greenhouse for management according to conventional methods. According to the inhibition or death of weeds, a visual control effect was investigated 30 days after treatment.
- the present invention uses the Gowing method to evaluate the combined effect of the proposed compositions.
- test results show that when component A is mixed with different components B, it has obvious synergistic effect on the grass weed barnyardgrass in different proportions.
- test results show that when component A is mixed with different components B, it has obvious synergistic effect on broadleaf weeds quinoa, amaranth and grass weeds barnyardgrass and crabgrass in different proportions.
- test results showed that when component A was mixed with different components B, it exhibited obvious synergistic effects on broad-leaved weed abalone and grass weed barnyardgrass in different proportions.
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- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
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Abstract
本发明涉及一种除草剂组合物及其应用方法，组分A为具有如结构式I所示的化合物。组分B选自ALS抑制剂类、ACCa酶抑制剂类、HPPD抑制剂类、三嗪酮类、PPO类抑制剂类、激素抑制剂类除草剂中的一种或多种。本发明的除草剂组合物施用于存在或预期存在的不希望植被的场所，特别适用于非耕地杂草的防除。
Description
本发明属于农用除草剂领域，涉及一种除草剂组合物及其应用。
专利WO2016095768报道了如通式I所示的含异恶唑啉脲嘧啶类化合物：
通式I化合物具有很好的除草活性，可以有效地控制稗草、狗尾草、异型莎草、水莎草、马唐、荩草、苘麻、百日草、反枝苋、马齿苋、苍耳、龙葵、决明、野西瓜苗、野大豆等不同叶期的杂草，除草效果优异。
不同的除草剂具有不同的杀草谱，虽然除草剂的混用是扩大杀草谱、降低使用量、防治抗性产生的一个有效途径；但，选择怎样的除草剂混用实现广谱性并非显而易见。
发明内容
本发明的目的在于提供一种除草剂组合物及其应用。
为实现上述目的，本发明的技术方案如下：
一种除草剂组合物，除草剂活性组分由组分A和组分B组成，组分A为具有如下结构式I所示的化合物；组分B选自ALS抑制剂类、ACCa酶抑制剂类、HPPD抑制剂类、三嗪酮类、PPO类抑制剂类、激素抑制剂类除草剂中的一种或多种；所述组分A和组分B之间的重量比为1:100～100:1；
式I中：
R
1选自甲基；
R
2、R
3可相同或不同，分别选自氢、氟或氯；
R
4选自氢、氰基、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、三氟甲基或CO
2R
6；
R
5选自氢、甲基、乙基、叔丁基或三氟甲基；
R
6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、烯丙基、炔丙基、甲氧基乙基、乙氧基乙基、甲基羰基氧基乙基、2-四氢呋喃亚甲基或3-四氢呋喃亚甲基。
优选所述的组合物，所述组分A为式Ⅰ所示的化合物，式I中：
R
1选自甲基；
R
2、R
3可相同或不同，分别选自氢、氟或氯；
R
4选自CO
2R
6；
R
5选自氢、甲基、乙基、叔丁基或三氟甲基；
R
6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、烯丙基、炔丙基、甲氧基乙基、乙氧基乙基、2-四氢呋喃亚甲基或3-四氢呋喃亚甲基。
组分B为氯嘧磺隆、氯磺隆、氟啶嘧磺隆、环氧嘧磺隆、玉嘧磺隆、醚苯磺隆、氟胺磺隆、碘甲磺隆、甲酰胺磺隆、烟嘧磺隆、吡唑草酯、炔草酯、敌稗、氰氟草酯、唑啉草酯、中的一种或多种；
组分B为吡草酮、吡唑特、苄草唑、氟吡草酮、硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、啶黄草胺、嗪草酮、苯嗪草酮、乙氧氟草醚中的一种或多种；
组分B为丙炔氟草胺、乙羧氟草醚、嗪草酸甲酯、吡草醚、苯草醚、氯氟草醚、氟胺草酯、甲磺草胺、苯酮唑、唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、毒莠定、绿草定、喹草酸、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种。
所述组分A和组分B之间的重量比为1:50～50:1。
进一步优选所述的组合物，所述组分A为式Ⅰ所示的化合物，式I中：
R
1选自甲基；
R
2、R
3可相同或不同，分别选自氟或氯；
R
4选自CO
2R
6；
R
5选自氢、甲基、乙基或叔丁基；
R
6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基或叔丁基；
组分B为氯嘧磺隆、环氧嘧磺隆、玉嘧磺隆、醚苯磺隆、甲酰胺磺隆、烟嘧磺隆、吡唑草酯、炔草酯、敌稗、氰氟草酯、唑啉草酯、中的一种或多种；
组分B为吡草酮、吡唑特、硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、磺酰胺类：啶黄草胺、嗪草酮、苯嗪草酮、乙氧氟草醚中的一种或多种；
组分B为丙炔氟草胺、嗪草酸甲酯、氯氟草醚、苯酮唑、唑草酮、苯嘧磺草胺、氟磺胺 草醚、莠去津、毒莠定、喹草酸、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种；
其中，组分A和组分B之间的重量比为1:25～25:1。
再进一步优选所述的组合物，所述组分A为式Ⅰ所示的化合物，式I中：R
1选自甲基；
R
2、R
3可相同或不同，分别选自氟或氯；
R
4选自CO
2R
6；
R
5选自氢、甲基、乙基或叔丁基；
R
6选自氢、甲基、乙基、异丙基、正丙基或正丁基；
组分B为甲酰胺磺隆、烟嘧磺隆、炔草酯、敌稗、氰氟草酯、唑啉草酯中的一种或多种；
组分B为硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、磺酰胺类：啶黄草胺、嗪草酮、乙氧氟草醚中的一种或多种；
组分B为唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种；
其中，组分A和组分B之间的重量比为1:10～10:1。
一种所述的除草组合物在防除杂草中的应用。本发明除草剂施用于存在或预期存在的不希望植被的场所，及可以选择性或非选择性地用于存在或预期存在的不希望植被的场所。具体是可以施用于不希望植被生存的土壤中、不希望植被的茎叶，或作物种植前或播种后出苗前的烧荒及耐受作物及非耐受作物的苗后处理。
所述的除草剂施用于非耕地、果园、橡胶园、闲置耕地、橡胶园、桉树林、杉树林、森林、防火道、草坪、铁路、公路、机场及仓库场所。
所述耐受和非耐受作物选自水稻、玉米、豆类作物、油菜、蔬菜、棉花、甜菜、小粒谷物、大豆、花生、甘蔗、向日葵、栽培作物、木本植物。所述的果园包括苹果园、桃园、葡萄园、梨园、茶园、桑园、柑橘园。所述不希望的植被包括禾本科杂草、阔叶杂草、莎草科杂草、藻类、蕨类和木本灌木。
本发明提出的组合物具有以下优点：
1、本发明所涉及的组分A除草剂活性具有较广的杀草谱，对禾本科杂草和阔叶杂草具有活性，但对不同的杂草具有不同的活性，组分B除草剂对禾本科杂草的活性高于对阔叶杂草的活性，本发明通过两种组分的混用，扩大了杀草谱，对禾本科杂草的活性有明显的增效作用，降低了除草剂的用量，提高了混合物对杂草的整体防除效果；
2、本发明除草剂扩大了施药适期，特别对较大叶龄杂草，持续抑制和防除作用增强；
3、本发明除草剂茎叶喷雾处理，可用于防除非耕地、果园、闲置耕地、橡胶园、桉树林、森林、防火道、草坪、铁路、公路、机场及仓库等场所的大多数杂草。
本发明除草剂对禾本科杂草和阔叶杂草的协同增效作用可通过下列实施例作进一步说明，但本发明绝非仅限于此。其中，本发明除草剂活性组分为组分A和组分B，所述组分A为化合物A，组分B选自ALS抑制剂类、ACCa酶抑制剂类、HPPD抑制剂类、三嗪酮类、PPO类抑制剂类、激素抑制剂类除草剂等中的一种或多种。所有配比中的百分比均为重量百分比，活性组分以有效含量计算。
生物活性测定实施例
实施例 采用本发明除草剂活性组分为化合物A分别与B复配对杂草的室内联合作用测定，A为具有通式I结构的化合物，其中，R
1选自甲基，R
2为F，R
3为Cl，R
4为CO
2C
2H
5，R
5为CH
3；活性组分B为：甲酰胺磺隆、烟嘧磺隆、炔草酯、敌稗、氰氟草酯、唑啉草酯、唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、2甲4氯异辛酯、氯氨吡啶酸、硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、磺酰胺类：啶黄草胺、嗪草酮、乙氧氟草醚中的一种。
通过室内盆栽试验，明确组合物对杂草的联合作用。
杂草培养方法为：将定量的杂草种子稗草、马唐、藜和反枝苋分别播于直径为7cm的装有营养土的纸杯中，播后覆土、镇压、淋水后在温室培养。禾本科杂草长至5～7叶期、阔叶杂草6～8叶期，茎叶喷雾处理，试验设3次重复。处理待药液自然风干，放于温室内按常规方法管理，根据杂草受抑制或死亡的情况，于处理后30天，进行目测防效调查。
药剂配制方法：供试药剂药剂样品均为原药，先用丙酮：二甲基甲酰(1：2，V/V)混合溶剂溶解，用1‰吐温80水配制成一定浓度的母液，然后按照试验方案配制不同剂量的处理液。
本发明采用Gowing法对提出的组合物的联合作用进行评价。
理论值
式中：
X—除草剂组分A用量为P时的杂草防效；
Y—除草剂组分B用量为Q时的杂草防效；
E
0—除草剂组分A用量为P时的理论防效+除草剂组分B用量为Q时的理论防效；
E—除草剂组分A与除草剂组分B按上述比例混用后的实测防效。
当E-E
0>10％时，为增效作用；当E-E
0<-10％时，为拮抗作用；当E-E
0值介于±10％时，为加成作用。
表1 组分A与甲酰胺磺隆混用对禾本科杂草的联合作用
表2 组分A与甲酰胺磺隆混用对阔叶杂草的联合作用
表3 组分A与烟嘧磺隆混用对禾本科杂草的联合作用
表4 组分A与烟嘧磺隆混用对阔叶杂草的联合作用
表5 组分A与炔草酯混用对禾本科杂草的联合作用
表6 组分A与敌稗混用对禾本科杂草的联合作用
表7 组分A与敌稗混用对阔叶杂草的联合作用
表8 组分A与氰氟草酯混用对禾本科杂草的联合作用
表9 组分A与唑啉草酯混用对禾本科杂草的联合作用
试验结果(表1～表9)表明，组分A分别与不同的组分B混用，在不同比例下对禾本科杂草稗草均表现出明显的增效作用。
表10 组分A与硝磺草酮混用对禾本科杂草的联合作用
表11 组分A与硝磺草酮混用对阔叶杂草的联合作用
表12 组分A与苯唑草酮混用对禾本科杂草的联合作用
表13 组分A与苯唑草酮混用对阔叶杂草的联合作用
表14 组分A与环磺酮混用对禾本科杂草的联合作用
表15 组分A与环磺酮混用对阔叶杂草的联合作用
表16 组分A与磺酰草吡唑混用对禾本科杂草的联合作用
表17 组分A与磺酰草吡唑混用对阔叶杂草的联合作用
表18 组分A与吡氟酰草胺混用对禾本科杂草的联合作用
表19 组分A与吡氟酰草胺混用对阔叶杂草的联合作用
表20 组分A与异丙隆混用对禾本科杂草的联合作用
表21 组分A与异丙隆混用对阔叶杂草的联合作用
表22 组分A与甲基二磺隆混用对禾本科杂草的联合作用
表23 组分A与甲基二磺隆混用对阔叶杂草的联合作用
表24 组分A与氟唑磺隆混用对禾本科杂草的联合作用
表25 组分A与氟唑磺隆混用对阔叶杂草的联合作用
表26 组分A与双氟磺草胺混用对禾本科杂草的联合作用
表27 组分A与双氟磺草胺混用对阔叶杂草的联合作用
表28 组分A与双氯磺草胺混用对禾本科杂草的联合作用
表29 组分A与双氯磺草胺混用对阔叶杂草的联合作用
表30 组分A与五氟磺草胺混用对禾本科杂草的联合作用
表31 组分A与五氟磺草胺混用对阔叶杂草的联合作用
表32 组分A与氯吡嘧磺隆混用对禾本科杂草的联合作用
表33 组分A与氯吡嘧磺隆混用对阔叶杂草的联合作用
表34 组分A与苯磺隆混用对禾本科杂草的联合作用
表35 组分A与苯磺隆混用对阔叶杂草的联合作用
表36 组分A与环嗪酮混用对禾本科杂草的联合作用
表37 组分A与环嗪酮混用对阔叶杂草的联合作用
表38 组分A与啶黄草胺混用对禾本科杂草的联合作用
表39 组分A与啶黄草胺混用对阔叶杂草的联合作用
表40 组分A与嗪草酮混用对禾本科杂草的联合作用
表41 组分A与嗪草酮混用对阔叶杂草的联合作用
表42 组分A与乙氧氟草醚混用对禾本科杂草的联合作用
表43 组分A与乙氧氟草醚混用对阔叶杂草的联合作用
试验结果表明，组分A分别与不同的组分B混用，在不同比例下对阔叶杂草藜、反枝苋和禾本科杂草稗草、马唐均表现出明显的增效作用。
表44 组分A与唑草酮混用对禾本科杂草的联合作用
表45 组分A与唑草酮混用对阔叶杂草的联合作用
表46 组分A与苯嘧磺草胺混用对禾本科杂草的联合作用
表47 组分A与苯嘧磺草胺混用对阔叶杂草的联合作用
表48 组分A与氟磺胺草醚混用对禾本科杂草的联合作用
表49 组分A与氟磺胺草醚混用对阔叶杂草的联合作用
表50 组分A与苯达松混用对禾本科杂草的联合作用
表51 组分A与苯达松混用对阔叶杂草的联合作用
表52 组分A与莠去津混用对禾本科杂草的联合作用
表53 组分A与莠去津混用对阔叶杂草的联合作用
表54 组分A与2甲4氯异辛酯混用对禾本科杂草的联合作用
表55 组分A与2甲4氯异辛酯混用对阔叶杂草的联合作用
表56 组分A与氯氨吡啶酸混用对禾本科杂草的联合作用
表57 组分A与氯氨吡啶酸混用对阔叶杂草的联合作用
试验结果表明，组分A分别与不同的组分B混用，在不同比例下对阔叶杂草苘麻和禾本科杂草稗草均表现出明显的增效作用。
Claims (6)
- 一种除草剂组合物，其特征在于：除草剂活性组分由组分A和组分B组成，组分A为具有如下结构式I所示的化合物；组分B选自ALS抑制剂类、ACCa酶抑制剂类、HPPD抑制剂类、三嗪酮类、PPO类抑制剂类、激素抑制剂类除草剂中的一种或多种；所述组分A和组分B之间的重量比为1:100～100:1；
式I中：R 1选自甲基；R 2、R 3可相同或不同，分别选自氢、氟或氯；R 4选自氢、氰基、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、三氟甲基或CO 2R 6；R 5选自氢、甲基、乙基、叔丁基或三氟甲基；R 6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、烯丙基、炔丙基、甲氧基乙基、乙氧基乙基、甲基羰基氧基乙基、2-四氢呋喃亚甲基或3-四氢呋喃亚甲基。 - 根据权利要求1所述的组合物，其特征在于：所述组分A为式Ⅰ所示的化合物，式I中：R 1选自甲基；R 2、R 3可相同或不同，分别选自氢、氟或氯；R 4选自CO 2R 6；R 5选自氢、甲基、乙基、叔丁基或三氟甲基；R 6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基、叔丁基、三氟乙基、烯丙基、炔丙基、甲氧基乙基、乙氧基乙基、2-四氢呋喃亚甲基或3-四氢呋喃亚甲基。组分B为氯嘧磺隆、氯磺隆、氟啶嘧磺隆、环氧嘧磺隆、玉嘧磺隆、醚苯磺隆、氟胺磺隆、碘甲磺隆、甲酰胺磺隆、烟嘧磺隆、吡唑草酯、炔草酯、敌稗、氰氟草酯、唑啉草酯、中的一种或多种；组分B为吡草酮、吡唑特、苄草唑、氟吡草酮、硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、啶黄草胺、嗪草酮、苯嗪草酮、乙氧氟草醚中的一种或多种；组分B为丙炔氟草胺、乙羧氟草醚、嗪草酸甲酯、吡草醚、苯草醚、氯氟草醚、氟胺草酯、甲磺草胺、苯酮唑、唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、毒莠定、绿草定、喹草酸、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种。
- 根据权利要求2所述的组合物，其特征在于：所述组分A和组分B之间的重量比为1:50～50:1。
- 根据权利要求1-3任意一项所述的组合物，其特征在于：所述组分A为式Ⅰ所示的化合物，式I中：R 1选自甲基；R 2、R 3可相同或不同，分别选自氟或氯；R 4选自CO 2R 6；R 5选自氢、甲基、乙基或叔丁基；R 6选自氢、甲基、乙基、正丙基、正丁基、异丙基、异丁基或叔丁基；组分B为氯嘧磺隆、环氧嘧磺隆、玉嘧磺隆、醚苯磺隆、甲酰胺磺隆、烟嘧磺隆、吡唑草酯、炔草酯、敌稗、氰氟草酯、唑啉草酯、中的一种或多种；组分B为吡草酮、吡唑特、硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、磺酰胺类：啶黄草胺、嗪草酮、苯嗪草酮、乙氧氟草醚中的一种或多种；组分B为丙炔氟草胺、嗪草酸甲酯、氯氟草醚、苯酮唑、唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、毒莠定、喹草酸、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种；其中，组分A和组分B之间的重量比为1:25～25:1。
- 根据权利要求4所述的组合物，其特征在于：所述组分A为式Ⅰ所示的化合物，式I中：R 1选自甲基；R 2、R 3可相同或不同，分别选自氟或氯；R 4选自CO 2R 6；R 5选自氢、甲基、乙基或叔丁基；R 6选自氢、甲基、乙基、异丙基、正丙基或正丁基；组分B为甲酰胺磺隆、烟嘧磺隆、炔草酯、敌稗、氰氟草酯、唑啉草酯中的一种或多种；组分B为硝磺草酮、苯唑草酮、环磺酮、磺酰草吡唑、吡氟酰草胺、异丙隆、甲基二磺隆、氟唑磺隆、双氟磺草胺、双氯磺草胺、五氟磺草胺、氯吡嘧磺隆、苯磺隆、环嗪酮、磺酰胺类：啶黄草胺、嗪草酮、乙氧氟草醚中的一种或多种；组分B为唑草酮、苯嘧磺草胺、氟磺胺草醚、莠去津、2甲4氯异辛酯氯、氯氨吡啶酸中的一种或多种；其中，组分A和组分B之间的重量比为1:10～10:1。
- 一种权利要求1所述的组合物的应用，其特征在于：所述组合物在防除杂草中的应用。
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Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016095768A1 (zh) * | 2014-12-16 | 2016-06-23 | 沈阳中化农药化工研发有限公司 | 一种含异恶唑啉的脲嘧啶类化合物及其用途 |
| CN108207997A (zh) * | 2016-12-21 | 2018-06-29 | 沈阳中化农药化工研发有限公司 | 一种除草剂组合物及其应用 |
| CN109864068A (zh) * | 2017-12-02 | 2019-06-11 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及其应用 |
| CN109864067A (zh) * | 2017-12-02 | 2019-06-11 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及应用 |
| CN110150302A (zh) * | 2018-02-12 | 2019-08-23 | 沈阳中化农药化工研发有限公司 | 一种除草剂组合物及其应用 |
| CN110692643A (zh) * | 2018-07-09 | 2020-01-17 | 沈阳中化农药化工研发有限公司 | 一种除草剂及其应用 |
| CN110818699A (zh) * | 2018-08-08 | 2020-02-21 | 沈阳中化农药化工研发有限公司 | 一种异恶唑啉类化合物及其用途 |
| CN110818644A (zh) * | 2018-08-08 | 2020-02-21 | 沈阳中化农药化工研发有限公司 | 一种异恶唑啉羧酸酯类化合物和应用 |
| CN111316994A (zh) * | 2018-12-14 | 2020-06-23 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及其应用 |
-
2021
- 2021-11-03 WO PCT/CN2021/128499 patent/WO2022095908A1/zh active Application Filing
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016095768A1 (zh) * | 2014-12-16 | 2016-06-23 | 沈阳中化农药化工研发有限公司 | 一种含异恶唑啉的脲嘧啶类化合物及其用途 |
| CN105753853A (zh) * | 2014-12-16 | 2016-07-13 | 沈阳中化农药化工研发有限公司 | 一种含异恶唑啉的脲嘧啶类化合物及其用途 |
| CN108207997A (zh) * | 2016-12-21 | 2018-06-29 | 沈阳中化农药化工研发有限公司 | 一种除草剂组合物及其应用 |
| CN109864068A (zh) * | 2017-12-02 | 2019-06-11 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及其应用 |
| CN109864067A (zh) * | 2017-12-02 | 2019-06-11 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及应用 |
| CN110150302A (zh) * | 2018-02-12 | 2019-08-23 | 沈阳中化农药化工研发有限公司 | 一种除草剂组合物及其应用 |
| CN110692643A (zh) * | 2018-07-09 | 2020-01-17 | 沈阳中化农药化工研发有限公司 | 一种除草剂及其应用 |
| CN110818699A (zh) * | 2018-08-08 | 2020-02-21 | 沈阳中化农药化工研发有限公司 | 一种异恶唑啉类化合物及其用途 |
| CN110818644A (zh) * | 2018-08-08 | 2020-02-21 | 沈阳中化农药化工研发有限公司 | 一种异恶唑啉羧酸酯类化合物和应用 |
| CN111316994A (zh) * | 2018-12-14 | 2020-06-23 | 沈阳中化农药化工研发有限公司 | 一种除草组合物及其应用 |
Non-Patent Citations (1)
| Title |
|---|
| YE GUIBIAO: "Classification Methold of Herbididels According to Mode of Action ant Its Application ", PESTICIDE SCIENCE AND ADMINISTRATION, vol. 20, no. 1, 15 February 1999 (1999-02-15), XP055927592 * |
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