WO2022095420A1 - 一种烟气处理系统及烟气处理方法 - Google Patents

一种烟气处理系统及烟气处理方法 Download PDF

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WO2022095420A1
WO2022095420A1 PCT/CN2021/096142 CN2021096142W WO2022095420A1 WO 2022095420 A1 WO2022095420 A1 WO 2022095420A1 CN 2021096142 W CN2021096142 W CN 2021096142W WO 2022095420 A1 WO2022095420 A1 WO 2022095420A1
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flue gas
sewage
tank
water outlet
water
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PCT/CN2021/096142
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English (en)
French (fr)
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胡维杰
朱洁
曹绎名
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上海市政工程设计研究总院（集团）有限公司
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Priority to AU2021376697A priority Critical patent/AU2021376697B2/en
Publication of WO2022095420A1 publication Critical patent/WO2022095420A1/zh

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77—Liquid phase processes
    • B01D53/78—Liquid phase processes with gas-liquid contact
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/501—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/502—Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific solution or suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/96—Regeneration, reactivation or recycling of reactants
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00—Multistage treatment of water, waste water or sewage
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281—Installations for water purification using chemical agents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F2001/007—Processes including a sedimentation step
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/18—Nature of the water, waste water, sewage or sludge to be treated from the purification of gaseous effluents
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00—Biological treatment of water, waste water, or sewage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Definitions

  • the invention belongs to the technical field of environmental engineering, and particularly relates to a flue gas treatment system and a flue gas treatment method.
  • the treatment of sludge generally includes composting, landfilling, drying, effective utilization (mostly for agricultural use) and incineration of sludge.
  • the flue gas discharged after the sludge incineration treatment in the sewage treatment plant contains a large amount of sulfur dioxide (SO 2 ), and these sulfur-containing flue gas will cause serious pollution to the atmosphere and cause great damage to the environment. Therefore, the sludge incineration process needs to take desulfurization treatment on the flue gas, and treat the flue gas to meet the emission standards before discharging.
  • Flue gas desulfurization is a common method for desulfurization treatment of flue gas.
  • the sulfur dioxide in the flue gas is removed by contacting the flue gas with the lye in the desulfurization tower.
  • the high-temperature flue gas is directly in contact with the lye, so that the flue gas is humidified and cooled, and the water in the lye is endothermic and gasified, resulting in loss of water in the lye. Therefore, it is necessary to treat the lye. Hydrate.
  • the technical problem to be solved by the present invention is to provide a flue gas treatment system and a flue gas treatment method in order to overcome the waste of industrial water or tap water in the prior art as the replenishing water source for flue gas desulfurization after sludge incineration and low cost performance.
  • Fully exploit the reuse value of sewage save the cost of water in the sewage plant, and prevent the fouling of the flue gas desulfurization tower caused by the amphoteric coagulant in the sewage, and reduce the maintenance cost of the flue gas desulfurization equipment.
  • the invention provides a flue gas treatment system, which includes a flue gas desulfurization tower, a first sewage reuse pool and a second sewage reuse pool; the upper part of the flue gas desulfurization tower is provided with a spray pipe, and the The spray pipes are respectively connected with a first water outlet pipeline and a second water outlet pipeline; the first water outlet pipeline is connected with the first sewage reuse tank, and is used for conveying amphoteric-containing water to the flue gas desulfurization tower Sewage containing material coagulant; the second water outlet pipeline is connected to the second sewage reuse tank, and is used to transport sewage that does not form precipitation with alkali to the flue gas desulfurization tower.
  • the amphoteric coagulant refers to a coagulant that can react with both acid and alkali. Such as aluminum-based coagulants or iron-based coagulants.
  • the first sewage reuse tank is provided with a first water inlet pipeline and the first water outlet pipeline
  • the second sewage reuse tank is provided with the second water outlet pipeline
  • the second The second water outlet pipeline of the sewage reuse tank includes a first branch pipe and a second branch pipe, the first branch pipe is connected with the first water inlet pipeline of the first sewage reuse tank, and the second branch pipe is connected to the sprayer shower pipe connection.
  • the first water inlet pipeline and the first water outlet pipeline are branch pipelines of the first sewage reuse tank.
  • the first sewage reuse tank and the second sewage reuse tank are included in an independent sewage treatment system;
  • the sewage treatment system includes a waste water inlet pipe, a first-level mechanical A treatment tank, a first- and second-level biological treatment tank, and a first- and third-level sedimentation treatment tank, the effluent of the second-level biological treatment tank is stored in the second sewage reuse tank, and the effluent of the third-level sedimentation treatment tank is stored in the into the first sewage reuse tank.
  • the sewage in the first sewage reuse tank is generally tertiary sedimentation tank water.
  • the water quality of the tertiary sedimentation tank in the sewage plant is good, and the SS concentration is low.
  • the specific parameters are pH 6 ⁇ 9, SS 10mg/L, COD 50mg/L, but because the sewage contains amphoteric coagulants, such as aluminum salts, etc.
  • the lye in the flue gas desulfurization tower and the amphoteric coagulant form precipitation, which causes scaling in the flue gas desulfurization tower and affects the desulfurization efficiency.
  • the sewage in the second sewage reuse tank is generally the water in the secondary sedimentation tank.
  • the water in the secondary sedimentation tank in the sewage plant does not form precipitation with alkali, and the SS concentration is low.
  • the specific parameters are pH 6-9, SS 20mg/L , COD 55mg/L.
  • the flue gas treatment system further includes a regeneration water tank, the first water outlet pipeline and the second water outlet pipeline are connected in parallel at one end of the regeneration water tank, and the other end of the regeneration water tank is connected to the regenerated water tank. Connect the sprinkler pipe.
  • the regenerated water tank is used to further precipitate the effluent of the first sewage reuse tank and the second sewage reuse tank, and store incoming water as a storage tank to avoid problems such as flow fluctuation or insufficient water source.
  • the first water outlet pipe of the first sewage reuse tank and the second water outlet pipe of the second sewage reuse tank are used to transport the effluent in the first sewage reuse tank and the second sewage reuse tank
  • the effluent water from the water tank is sent to the regeneration water tank, and the regeneration water tank is used to transport different water sources to the flue gas desulfurization tower for reuse and descaling.
  • valve groups are respectively provided on the first water outlet pipeline and the second water outlet pipeline.
  • the valve group is used to control whether to transmit the effluent of the first sewage reuse tank and the effluent of the second sewage reuse tank to the regeneration water tank.
  • the structure of the flue gas desulfurization tower is conventional in the field, and the upper part is provided with the spray pipe; Alkali external circulation loop.
  • the flue gas desulfurization tower is used for removing sulfur from the flue gas generated after sludge incineration.
  • the flue gas enters the flue gas desulfurization tower from the flue gas inlet, and is transported to the flue gas discharge system from the upper flue gas outlet, and different water sources enter the flue gas desulfurization tower through the spray pipe.
  • a water pump is provided on the pipeline connecting the regeneration water tank and the spray pipe.
  • the water pump is used to transport different water sources to the flue gas desulfurization tower.
  • a valve group is arranged on the pipeline connecting the regenerated water tank and the spray pipe.
  • the valve group is used to control the transportation of sewage.
  • a flow meter is installed on the pipeline connecting the regenerated water tank and the spray pipe.
  • the flow meter is used to monitor the flow of different water sources to the flue gas desulfurization tower.
  • the present invention also provides a flue gas treatment method, which adopts the above-mentioned flue gas treatment system, and includes the following steps: alternately feeding the sewage of the first water outlet pipeline and the second water outlet pipeline into the sprayer shower pipe, you can.
  • the flue gas treatment method includes the following steps: step (1) opening the valve group arranged on the first water outlet pipeline, and closing the valve group on the second water outlet pipeline; step (2) 80 After ⁇ 100 days, close the valve group arranged on the first water outlet pipeline, and open the valve group of the second water outlet pipeline.
  • Step (1) use the effluent of the first sewage reuse pool to make up water for the flue gas desulfurization tower, and step (2) switch the water source of the flue gas desulfurization tower make-up water to the effluent of the second sewage reuse pool for the flue gas desulfurization tower. Remove the dirt inside.
  • the ratio of the effluent time period between the amphoteric coagulant-containing sewage entering the flue gas desulfurization tower and the sewage that does not form precipitation with alkali is 2 to 4, more preferably 3.
  • the ratio of the effluent flow rate of the sewage containing amphoteric coagulant and the sewage that does not form precipitation with alkali entering the flue gas desulfurization tower is 0.8-1.2, more preferably 1.
  • FIG. 1 is a flow chart of the flue gas treatment system in Embodiment 1 of the present invention.
  • the second sewage reuse tank; 2- The first sewage reuse tank; 3- The second branch pipe; 4- The first water outlet pipeline; 5- Valve group; 6- Regeneration water tank; Desulfurization tower; 9-flow meter; 801-spray pipe; 802-flue gas inlet; 803-flue gas outlet; 804-lye inlet; 805-lye external circulation loop.
  • a flue gas treatment system provided in Embodiment 1 of the present invention includes a second sewage reuse tank 1 , a first sewage reuse tank 2 , a flue gas desulfurization tower 8 and a regeneration water tank 6 .
  • the first sewage reuse tank 2 is provided with a first water inlet pipeline and a first water outlet pipeline 4
  • the second sewage reuse tank 1 is provided with a second water outlet pipeline
  • the second water outlet pipeline includes a first branch pipe and a second branch pipe , wherein the first branch pipe is connected with the first water inlet pipeline, and is used to input the pool water of the second sewage reuse tank 1 into the first sewage reuse tank 2, and the second branch pipe 3 and the first water outlet pipeline 4 are connected in parallel to the regeneration water tank 6
  • the first water inlet pipeline and the first water outlet pipeline 4 are also the branch pipes of the first sewage reuse tank 2, and the other end of the regenerated water tank 6 is connected to the spray pipe 801 of the flue gas desulfurization tower 8 through the pipeline, and is It is used to transport different water sources to the flue gas desulfurization tower 8.
  • the second branch pipe 3 and the first outlet pipe 4 of the first sewage reuse tank 2 are respectively used to transport the effluent from the second sewage reuse tank 1 and the effluent from the first sewage reuse tank 2 to the regenerated water tank 6
  • the regeneration water tank 6 is used to transport different water sources to the flue gas desulfurization tower 8 for reuse and descaling
  • the regeneration water tank 6 can also be used to further precipitate the effluent of the second sewage reuse tank 1 and the first sewage reuse tank 2
  • a storage tank to store incoming water to avoid problems such as flow fluctuations or insufficient water sources.
  • the first sewage reuse tank 2 and the second sewage reuse tank 1 are included in a set of independent sewage treatment system;
  • the sewage treatment system includes a wastewater inlet pipe, a primary mechanical treatment tank, and a secondary biological treatment system connected in sequence.
  • the effluent of the secondary biological treatment tank is stored in the second sewage reuse tank 1, and the effluent of the tertiary sedimentation treatment tank is stored in the first sewage reuse tank 2.
  • the sewage in the first sewage reuse tank 2 is generally the water of the three-stage sedimentation tank.
  • the water quality of the tertiary sedimentation tank in the sewage plant is good, and the SS concentration is low.
  • the specific parameters are pH 6 ⁇ 9, SS 10mg/L, COD 50mg/L, but because the sewage contains amphoteric coagulants, such as polychlorinated Aluminum, etc., after being reused for a period of time, the lye in the flue gas desulfurization tower will form aluminum hydroxide precipitation with aluminum salts, resulting in scaling phenomenon in the flue gas desulfurization tower 8, which affects the desulfurization efficiency.
  • the sewage in the second sewage reuse tank 1 is generally the secondary sedimentation tank water.
  • the secondary sedimentation tank water in the sewage plant does not precipitate with alkali, and the SS concentration is low.
  • the specific parameters are pH 6-9, SS 20mg/L, COD 55mg/L.
  • the lye in the flue gas desulfurization tower 8 will react with aluminum hydroxide precipitation, reduce the occurrence of scaling, and realize the purpose of treating waste with waste. Therefore, the first outlet pipe 4 is used to transport sewage containing amphoteric coagulants; the second branch pipe 3 is used to transport sewage that does not precipitate with alkali.
  • the second branch pipe 3 and the first water outlet pipe 4 are respectively provided with valve groups 5, and the valve groups are used to control whether the effluent of the first sewage reuse tank 2 and the effluent of the second sewage reuse tank 1 are transported to the Regeneration tank 6.
  • the structure of the flue gas desulfurization tower 8 is conventional in the field.
  • the upper part is provided with a spray pipe 801, the middle part and the top part are respectively provided with a flue gas inlet 802 and a flue gas outlet 803, and the lower part is provided with a lye inlet 804 and an lye solution.
  • the flue gas desulfurization tower 8 is used to remove sulfur from the flue gas generated after sludge incineration.
  • the flue gas When in use, the flue gas enters the flue gas desulfurization tower 8 from the flue gas inlet 802 , and is transported to the flue gas discharge system from the upper flue gas outlet 803 , and different water sources enter the flue gas desulfurization tower 8 through the spray pipe 801 .
  • the water pump 7 is provided on the pipeline connecting the regeneration water tank 6 and the spray pipe 801 .
  • the water pump is used to transport different water sources to the flue gas desulfurization tower 8 .
  • a valve group 5 is arranged on the pipeline connecting the regeneration water tank 6 and the spray pipe 801 . This valve group is used to control the conveyance of sewage.
  • a flow meter 9 is provided on the pipe connecting the regeneration water tank 6 and the spray pipe 801 . The flow meter is used to monitor the flow of different water sources to the flue gas desulfurization tower 8 .
  • Embodiment 2 of the present invention also provides a flue gas treatment method, which adopts the above-mentioned flue gas treatment system and includes the following steps: Step (1) Open the valve group 5 on the first water outlet pipeline 4, and close the second branch pipe 3 After about 90 days in step (2), close the valve group 5 on the first water outlet pipeline 4, and open the valve group 5 on the second branch pipe 3.
  • Step (1) use the first sewage reuse tank 2 containing the amphoteric coagulant to make up water for the flue gas desulfurization tower 8, and in this step, the sewage and the lye in the flue gas desulfurization tower 8 generate precipitation; step (2) ) switch the water source of the water replenishment of the flue gas desulfurization tower 8, and use the effluent of the second sewage reuse pool 1 that does not generate precipitation with alkali as the replenishment water source, and the lye in the flue gas desulfurization tower 8 will be dissolved with the generated amphoteric precipitation, Thereby, the fouling in the flue gas desulfurization tower 8 is removed.
  • the effluent time period of the sewage containing amphoteric coagulant entering the flue gas desulfurization tower is 3 months, and the effluent time period of the sewage that does not form precipitation with alkali entering the flue gas desulfurization tower is 1 month, and enters the flue gas desulfurization tower.
  • the ratio of the effluent time period between the sewage containing amphoteric coagulant and the sewage that does not form precipitation with alkali is 3.
  • the effluent flow of the sewage containing amphoteric coagulant and the sewage that does not form precipitation with alkali that enter the flue gas desulfurization tower is consistent with the set value of the flue gas desulfurization tower, and the ratio is 1.
  • Step (1) is repeated after the fouling phenomenon of the flue gas desulfurization tower 8 is eliminated, and the cycle is repeated.
  • the flue gas entering the flue gas desulfurization tower is 48000Nm 3 /d, and the water replenishment amount is 4500 tons per day.
  • the effluent of the tertiary sedimentation tank of the sewage treatment plant and the effluent of the secondary sedimentation tank are reused for the supplementary water of the flue gas desulfurization tower.
  • the daily water cost can be saved 9,000 yuan/day, and further, after the influent of the secondary sedimentation tank is continuously fed for 1 month, the amount of scaling caused by the continuous feeding of the effluent of the tertiary sedimentation tank for 3 months can be eliminated by more than 90%.

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Abstract

一种烟气处理系统及烟气处理方法。处理系统包括一烟气脱硫塔（8）、一第一污水回用池（2）和一第二污水回用池（1）；烟气脱硫塔（8）的上部设有喷淋管（801），喷淋管（801）分别与一第一出水管路（4）和一第二出水管路连接；第一出水管路（4）与第一污水回用池（2）连接，用于向烟气脱硫塔（8）输送含两性物质混凝剂的污水；第二出水管路与第二污水回用池（1）连接，用于向烟气脱硫塔（8）输送不与碱生成沉淀的污水。烟气处理方法采用烟气处理系统进行，包括如下步骤：交替将第一出水管路（4）和第二出水管路的污水输入喷淋管（801）。

Description

一种烟气处理系统及烟气处理方法 技术领域
本发明属于环境工程技术领域，具体涉及一种烟气处理系统及烟气处理方法。
背景技术
近年来，随着污水处理设施的普及、处理率的提高和处理程度的深化，污水厂的污泥产生量有较大增长，由此污泥引起的二次污染问题已不容忽视。污泥的处理一般包括污泥的堆肥、填埋、干化、有效利用(多为农用)及焚烧等。其中，污水厂污泥焚烧处理后排出的烟气中含有大量的二氧化硫(SO 2)，这些含硫烟气会对大气造成严重污染，给环境带来很大破坏。因此污泥焚烧工艺需要对烟气采取脱硫处理，将烟气处理至满足排放标准后进行排放。
烟气脱硫是对烟气进行脱硫处理的常用手段，通过使烟气与碱液在脱硫塔内接触去除烟气中的二氧化硫。烟气脱硫塔在运行过程中高温烟气直接和碱液接触，使烟气被增湿冷却，碱液中的水分则吸热气化，导致碱液中的水产生损耗，因此需要对碱液进行补水。
目前的补水水源多为工业用水或自来水，脱硫系统中工业用水或自来水的用量较大，使用工业用水或自来水为水源的工艺性价比低，并且对水资源造成了极大的浪费。优化脱硫系统补水的水源，实现高性价比，对水资源的利用具有重大意义。
发明内容
本发明要解决的技术问题是为了克服现有技术中污泥焚烧后烟气脱硫的补水水源为工业用水或自来水的浪费，性价比低的问题，提供一种烟气处理系统及烟气处理方法，充分挖掘污水回用价值，节省污水厂用水成本，并且防止污水中的两性物质混凝剂导致烟气脱硫塔结垢，减少烟气脱硫设备的 维护成本。
本发明是通过下述技术方案来解决上述技术问题：
本发明提供一种烟气处理系统，其包括一烟气脱硫塔、一第一污水回用池和一第二污水回用池；所述烟气脱硫塔的上部设有喷淋管，所述喷淋管分别与一第一出水管路和一第二出水管路连接；所述第一出水管路与所述第一污水回用池连接，用于向所述烟气脱硫塔输送含两性物质混凝剂的污水；所述第二出水管路与所述第二污水回用池连接，用于向所述烟气脱硫塔输送不与碱生成沉淀的污水。
所述两性物质混凝剂是指既能和酸发生反应，又能和碱发生反应的混凝剂。如铝系混凝剂或铁系混凝剂。
较佳地，所述第一污水回用池设有第一进水管路和所述第一出水管路，所述第二污水回用池设有所述第二出水管路，所述第二污水回用池的第二出水管路包括第一支管和第二支管，所述第一支管与所述第一污水回用池的第一进水管路连接，所述第二支管与所述喷淋管连接。
较佳地，所述第一进水管路和所述第一出水管路为所述第一污水回用池的支路管路。
较佳地，所述第一污水回用池、所述第二污水回用池包含在一套独立的污水处理系统中；所述污水处理系统包括依次连接的一废水进水管、一一级机械处理池、一二级生物处理池和一三级沉淀处理池，所述二级生物处理池的出水存放在所述第二污水回用池中，所述三级沉淀处理池的出水存放在所述第一污水回用池中。
所述第一污水回用池中的污水一般为三级沉淀池池水。污水厂中三级沉淀池池水的水质较好，SS浓度低，具体参数为pH 6～9、SS 10mg/L、COD 50mg/L，但是由于污水中含有两性物质混凝剂，如铝盐等，在回用一段时间后，所述烟气脱硫塔内的碱液与两性物质混凝剂生成沉淀，导致所述烟气脱硫塔内会发生结垢现象，影响脱硫效率。所述第二污水回用池中的污水一般为二级沉淀池池水，污水厂中二级沉淀池池水不与碱生成沉淀，并且SS浓 度低，具体参数为pH 6～9、SS 20mg/L、COD 55mg/L。通入所述烟气脱硫塔后，所述烟气脱硫塔中的碱液会与沉淀反应，减少结垢的发生，实现以废治废的目的。
较佳地，所述烟气处理系统还包括一再生水箱，所述第一出水管路和所述第二出水管路在所述再生水箱的一端并联连接，所述再生水箱的另一端与所述喷淋管连接。所述再生水箱用于进一步沉淀所述第一污水回用池和所述第二污水回用池的出水，并作为储罐储存来水，避免流量波动或水源不足等问题。
所述第一污水回用池的第一出水管和所述第二污水回用池的第二出水管用于输送所述第一污水回用池中的出水和所述第二污水回用池中的出水至所述再生水箱，所述再生水箱用于将不同的水源输送至所述烟气脱硫塔进行回用和除垢。
较佳地，所述第一出水管路和所述第二出水管路上分别设有阀门组。所述阀门组用于控制是否将所述第一污水回用池的出水与所述第二污水回用池的出水输送至所述再生水箱。
较佳地，所述烟气脱硫塔的结构为本领域常规，其上部设有所述喷淋管，中部、顶部分别设有烟气进口、烟气出口，下部设有一碱液进口，以及一碱液外循环回路。所述烟气脱硫塔用于脱除污泥焚烧后产生的烟气中的硫。使用时，烟气从所述烟气进口进入所述烟气脱硫塔，从上部的所述烟气出口输送至烟气排放系统，不同水源通过所述喷淋管进入所述烟气脱硫塔。
较佳地，所述再生水箱与所述喷淋管连接的管道上设置水泵。所述水泵用于将不同水源输送至所述烟气脱硫塔。
较佳地，所述再生水箱与所述喷淋管连接的管道上设置阀门组。所述阀门组用于控制污水的输送。
较佳地，所述再生水箱与所述喷淋管连接的管道上设置流量计。所述流量计用于监测不同水源输送至所述烟气脱硫塔的流量。
本发明还提供一种烟气处理方法，其采用如上所述的烟气处理系统进行， 包括如下步骤：交替将所述第一出水管路和所述第二出水管路的污水输入所述喷淋管，即可。
较佳地，所述的烟气处理方法包括如下步骤：步骤(1)打开设置在所述第一出水管路上的阀门组，关闭所述第二出水管路上的阀门组；步骤(2)80～100天后，关闭设置在第一出水管路上的阀门组，打开所述第二出水管路的阀门组，即可。
步骤(1)使用所述第一污水回用池的出水为烟气脱硫塔补水，步骤(2)将烟气脱硫塔补水水源切换为所述第二污水回用池的出水对烟气脱硫塔内的污垢进行清除。
较佳地，进入所述烟气脱硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水时间段之比为2～4，更佳地为3。
较佳地，进入所述烟气脱硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水流量的比例为0.8～1.2，更佳地为1。
本发明的积极进步效果在于：
(1)在不影响污水厂正常运行的情况下，以污水厂污水作为烟气脱硫塔的补水水源，不仅减少了污水的排放，还节约了宝贵的水资源。
(2)通过切换烟气脱硫塔的进水水源，有效防止了因污水内成分引起的结垢现象的发生，系统简单，操作方便，同时也降低了污水厂的运维成本。
附图说明
图1为本发明实施例1中烟气处理系统的流程图。
附图标记：
1-第二污水回用池；2-第一污水回用池；3-第二支管；4-第一出水管路；5-阀门组；6-再生水箱；7-水泵；8-烟气脱硫塔；9-流量计；801-喷淋管；802-烟气进口；803-烟气出口；804-碱液进口；805-碱液外循环回路。
具体实施方式
下面通过实施例的方式进一步说明本发明，但并不因此将本发明限制在所述的实施例范围之中。
如图1所示，本发明实施例1提供的一种烟气处理系统，该系统包括第二污水回用池1、第一污水回用池2、烟气脱硫塔8和再生水箱6。第一污水回用池2设有第一进水管路和第一出水管路4，第二污水回用池1设有第二出水管路，第二出水管路包括第一支管和第二支管，其中第一支管与第一进水管路连接，用于将第二污水回用池1的池水输入第一污水回用池2，第二支管3与第一出水管路4并联连接在再生水箱6一侧，第一进水管路和第一出水管路4也为第一污水回用池2的支管，再生水箱6的另一端通过管道与烟气脱硫塔8的喷淋管801连接，用于将不同水源输送至烟气脱硫塔8中。
其中，第二支管3和第一污水回用池2的第一出水管路4分别用于输送第二污水回用池1中的出水和第一污水回用池2中的出水至再生水箱6，再生水箱6用于将不同的水源输送至烟气脱硫塔8进行回用和除垢，再生水箱6也可用于进一步沉淀第二污水回用池1和第一污水回用池2的出水，并作为储罐储存来水，避免流量波动或水源不足等问题。
其中，第一污水回用池2、第二污水回用池1包含在一套独立的污水处理系统中；该污水处理系统包括依次连接的废水进水管、一级机械处理池、二级生物处理池和三级沉淀处理池，二级生物处理池的出水存放在第二污水回用池1中，三级沉淀处理池的出水存放在第一污水回用池2中。
第一污水回用池2中的污水一般为三级沉淀池池水。污水厂中三级沉淀池池水的水质较好，SS浓度低，具体参数为pH 6～9、SS 10mg/L、COD 50mg/L，但是由于污水中含有两性物质混凝剂，如聚合氯化铝等，在回用一段时间后，烟气脱硫塔内的碱液会与铝盐生成氢氧化铝沉淀，导致烟气脱硫塔8内会发生结垢现象，影响脱硫效率。第二污水回用池1中的污水一般为二级沉淀池池水，污水厂中二级沉淀池池水不与碱生成沉淀，并且SS浓度低，具体参数为pH 6～9、SS 20mg/L、COD 55mg/L。通入烟气脱硫塔8后，烟气脱硫塔8中的碱液会与氢氧化铝沉淀反应，减少结垢的发生，实现以废治废的目 的。因此，第一出水管路4用于运输含有两性物质混凝剂的污水；第二支管3用于运输不与碱生成沉淀的污水。
其中，第二支管3和第一出水管路4上分别设有阀门组5，上述阀门组用于控制是否将第一污水回用池2的出水与第二污水回用池1的出水输送至再生水箱6。
其中，烟气脱硫塔8的结构为本领域常规，其上部设有喷淋管801，中部、顶部分别设有烟气进口802、烟气出口803，下部设有碱液进口804，以及碱液外循环回路805。烟气脱硫塔8用于脱除污泥焚烧后产生的烟气中的硫。使用时，烟气从烟气进口802进入烟气脱硫塔8，从上部的烟气出口803输送至烟气排放系统，不同水源通过喷淋管801进入烟气脱硫塔8。
其中，再生水箱6与喷淋管801连接的管道上设置水泵7。该水泵用于将不同水源输送至烟气脱硫塔8。再生水箱6与喷淋管801连接的管道上设置阀门组5。该阀门组用于控制污水的输送。再生水箱6与喷淋管801连接的管道上设置流量计9。该流量计用于监测不同水源输送至烟气脱硫塔8的流量。
实施例2
本发明实施例2还提供一种烟气处理方法，其采用上述的烟气处理系统进行，包括如下步骤：步骤(1)打开第一出水管路4上的阀门组5，关闭第二支管3上的阀门组5；步骤(2)约90天后，关闭第一出水管路4上的阀门组5，打开第二支管上3的阀门组5，即可。
步骤(1)使用含有两性物质混凝剂的第一污水回用池2出水为烟气脱硫塔8补水，该步骤中，污水会与烟气脱硫塔8中的碱液生成沉淀；步骤(2)切换烟气脱硫塔8补水的水源，使用不与碱生成沉淀的第二污水回用池1的出水作为补水水源，烟气脱硫塔8内的碱液会与已生成的两性沉淀进行溶解，从而清除烟气脱硫塔8内的污垢。
进入烟气脱硫塔的含两性物质混凝剂的污水的出水时间段为3个月，进入烟气脱硫塔的不与碱生成沉淀的污水的出水时间段为1个月，进入烟气脱 硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水时间段之比为3。
进入烟气脱硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水流量均保持与烟气脱硫塔的设定值一致，比例为1。
待烟气脱硫塔8结垢现象消除后重复步骤(1)，循环往复。
某污水处理厂污泥焚烧后进入烟气脱硫塔的烟气为48000Nm 3/d，补水量为4500吨/天。采用本发明实施例2的方法，利用污水厂三级沉淀池的出水和二级沉淀池的出水回用于烟气脱硫塔补水，按自来水价格2.0元/吨计算，则每日可节约用水成本9000元/天，进一步地，将二级沉淀池的进水连续通入1个月后，由三级沉淀池的出水连续通入3个月所导致的结垢量可被消除90％以上。

Claims (10)

  1. 一种烟气处理系统，其特征在于，其包括：
    一烟气脱硫塔、一第一污水回用池和一第二污水回用池；
    所述烟气脱硫塔的上部设有喷淋管，所述喷淋管分别与一第一出水管路和一第二出水管路连接；
    所述第一出水管路与所述第一污水回用池连接，用于向所述烟气脱硫塔输送含两性物质混凝剂的污水；
    所述第二出水管路与所述第二污水回用池连接，用于向所述烟气脱硫塔输送不与碱生成沉淀的污水。
  2. 如权利要求1所述的烟气处理系统，其特征在于，所述第一污水回用池设有第一进水管路和所述第一出水管路，所述第二污水回用池设有所述第二出水管路，所述第二污水回用池的第二出水管路包括第一支管和第二支管，所述第一支管与所述第一污水回用池的所述第一进水管路连接，所述第二支管与所述喷淋管连接。
  3. 如权利要求2所述的烟气处理系统，其特征在于，所述第一进水管路和所述第一出水管路为所述第一污水回用池的支路管路；
    所述第一污水回用池、所述第二污水回用池包含在一套独立的污水处理系统中；
    所述污水处理系统包括依次连接的一废水进水管、一一级机械处理池、一二级生物处理池和一三级沉淀处理池，所述二级生物处理池的出水存放在所述第二污水回用池中，所述三级沉淀处理池的出水存放在所述第一污水回用池中。
  4. 如权利要求1所述的烟气处理系统，其特征在于，所述的烟气处理系统还包括一再生水箱，所述第一出水管路和所述第二出水管路在所述再生水箱的一端并联连接，所述再生水箱的另一端与所述喷淋管连接。
  5. 如权利要求2所述的烟气处理系统，其特征在于，所述第一出水管路和所述第二出水管路上分别设有阀门组；
    所述烟气脱硫塔的上部设有所述喷淋管，中部、顶部分别设有烟气进口、 烟气出口，下部设有一碱液进口，以及一碱液外循环回路。
  6. 如权利要求4所述的烟气处理系统，其特征在于，所述再生水箱与所述喷淋管连接的管道上设置水泵；
    和/或，所述再生水箱与所述喷淋管连接的管道上设置阀门组；
    和/或，所述再生水箱与所述喷淋管连接的管道上设置流量计。
  7. 一种烟气处理方法，其特征在于，其采用如权利要求1～6任意一项所述的烟气处理系统，包括如下步骤：交替将所述第一出水管路和所述第二出水管路的污水输入所述喷淋管，即可。
  8. 如权利要求7所述的烟气处理方法，其特征在于，其包括如下步骤：步骤(1)打开设置在所述第一出水管路上的阀门组，关闭所述第二出水管路上的阀门组；步骤(2)80～100天后，关闭设置在第一出水管路上的阀门组，打开所述第二出水管路的阀门组，即可。
  9. 如权利要求7所述的烟气处理方法，其特征在于，进入所述烟气脱硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水时间段之比为2～4，较佳地为3；
    和/或，含两性物质混凝剂的污水的参数为pH 6～9、SS 10mg/L、COD 50mg/L；
    不与碱生成沉淀的污水的参数为pH 6～9、SS 20mg/L、COD 55mg/L。
  10. 如权利要求7所述的烟气处理方法，其特征在于，进入所述烟气脱硫塔的含两性物质混凝剂的污水和不与碱生成沉淀的污水的出水流量的比例为0.8～1.2，较佳地为1。
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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1597062A (zh) * 2004-08-24 2005-03-23 北京中科通用能源环保有限责任公司 利用废碱渣进行烟气脱硫的方法
CN102923905A (zh) * 2012-10-19 2013-02-13 佛山市新泰隆环保设备制造有限公司 一种稀土冶炼废水的处理方法及装置
US20130108535A1 (en) * 2011-10-31 2013-05-02 Mitsubishi Heavy Industries, Ltd. Flue gas desulfurization
CN103691296A (zh) * 2013-12-12 2014-04-02 上海龙净环保科技工程有限公司 一种pm2.5烟气治理塔水循环系统及方法
EP3238810A1 (en) * 2016-04-29 2017-11-01 General Electric Technology GmbH Wet flue gas desulfurization system with zero waste water liquid discharge
CN108310951A (zh) * 2018-04-20 2018-07-24 大连航化能源装备有限公司 一体化烟气微雾脱硫除尘超净排放系统
CN108793523A (zh) * 2018-07-14 2018-11-13 浙江大维高新技术股份有限公司 一种脱硫废水浓缩减量装置
CN110156178A (zh) * 2018-03-27 2019-08-23 新疆环境工程技术有限责任公司 一种用于脱硫系统的软化除垢剂
CN110510780A (zh) * 2019-09-23 2019-11-29 上海双昊环保科技有限公司 一种采用stro装置的洗烟废水回用处理装置及方法
CN112473348A (zh) * 2020-11-06 2021-03-12 上海市政工程设计研究总院（集团）有限公司 一种烟气处理系统及烟气处理方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3837760B2 (ja) * 1995-07-31 2006-10-25 栗田工業株式会社 排煙脱硫排水の処理方法
JP4841065B2 (ja) * 2001-06-21 2011-12-21 三菱重工メカトロシステムズ株式会社 排煙のｓｏ３分除去装置
JP2011005448A (ja) * 2009-06-26 2011-01-13 Mitsubishi Heavy Ind Ltd 河川水利用排煙脱硫システム及び腐植物質除去方法
CN104163543B (zh) * 2014-07-28 2015-12-02 漳州职业技术学院 一种污水处理装置及其污水处理方法
CN105712384B (zh) * 2014-12-05 2017-10-27 中国石油化工股份有限公司 一种利用含硫烟气制备纳米氧化铝的方法及装置
CN106319218B (zh) * 2015-06-16 2019-12-24 有研稀土新材料股份有限公司 从含稀土的铝硅废料中回收稀土、铝和硅的方法
CN106241972A (zh) * 2016-08-23 2016-12-21 盛发环保科技（厦门）有限公司 基于电渗析的脱硫废水零排放处理方法及系统
CN206867995U (zh) * 2017-04-21 2018-01-12 北京国电龙源环保工程有限公司 吸收塔补水系统
CN107456850A (zh) * 2017-08-16 2017-12-12 重庆高成环保技术开发有限公司 一种水泥厂烟气超声波脱硫除尘方法

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1597062A (zh) * 2004-08-24 2005-03-23 北京中科通用能源环保有限责任公司 利用废碱渣进行烟气脱硫的方法
US20130108535A1 (en) * 2011-10-31 2013-05-02 Mitsubishi Heavy Industries, Ltd. Flue gas desulfurization
CN102923905A (zh) * 2012-10-19 2013-02-13 佛山市新泰隆环保设备制造有限公司 一种稀土冶炼废水的处理方法及装置
CN103691296A (zh) * 2013-12-12 2014-04-02 上海龙净环保科技工程有限公司 一种pm2.5烟气治理塔水循环系统及方法
EP3238810A1 (en) * 2016-04-29 2017-11-01 General Electric Technology GmbH Wet flue gas desulfurization system with zero waste water liquid discharge
CN110156178A (zh) * 2018-03-27 2019-08-23 新疆环境工程技术有限责任公司 一种用于脱硫系统的软化除垢剂
CN108310951A (zh) * 2018-04-20 2018-07-24 大连航化能源装备有限公司 一体化烟气微雾脱硫除尘超净排放系统
CN108793523A (zh) * 2018-07-14 2018-11-13 浙江大维高新技术股份有限公司 一种脱硫废水浓缩减量装置
CN110510780A (zh) * 2019-09-23 2019-11-29 上海双昊环保科技有限公司 一种采用stro装置的洗烟废水回用处理装置及方法
CN112473348A (zh) * 2020-11-06 2021-03-12 上海市政工程设计研究总院（集团）有限公司 一种烟气处理系统及烟气处理方法

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