WO2022065088A1 - 二次電池の充電方法および充電システム - Google Patents

二次電池の充電方法および充電システム Download PDF

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WO2022065088A1
WO2022065088A1 PCT/JP2021/033393 JP2021033393W WO2022065088A1 WO 2022065088 A1 WO2022065088 A1 WO 2022065088A1 JP 2021033393 W JP2021033393 W JP 2021033393W WO 2022065088 A1 WO2022065088 A1 WO 2022065088A1
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charging
secondary battery
profile
current density
negative electrode
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English (en)
French (fr)
Japanese (ja)
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隆弘 福岡
聡 蚊野
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Panasonic Intellectual Property Management Co Ltd
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Panasonic Intellectual Property Management Co Ltd
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Priority to US18/028,360 priority Critical patent/US20230378792A1/en
Priority to JP2022551885A priority patent/JP7727942B2/ja
Priority to CN202180066275.3A priority patent/CN116235313B/zh
Priority to EP21872219.7A priority patent/EP4220770A4/en
Publication of WO2022065088A1 publication Critical patent/WO2022065088A1/ja
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    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
    • H02J7/90—Regulation of charging or discharging current or voltage
    • H02J7/933—Regulation of charging or discharging current or voltage the cycle being controlled or terminated in response to electric parameters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/44—Methods for charging or discharging
    • H01M10/446—Initial charging measures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/46—Accumulators structurally combined with charging apparatus
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/48—Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
    • H02J7/80—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries including monitoring or indicating arrangements
    • H02J7/82—Control of state of charge [SOC]
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
    • H02J7/90—Regulation of charging or discharging current or voltage
    • H02J7/92—Regulation of charging or discharging current or voltage with prioritisation of loads or sources
    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02J—ELECTRIC POWER NETWORKS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00—Circuit arrangements for charging or discharging batteries or for supplying loads from batteries
    • H02J7/90—Regulation of charging or discharging current or voltage
    • H02J7/96—Regulation of charging or discharging current or voltage in response to battery voltage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • This disclosure relates to a secondary battery charging method and a charging system.
  • Non-aqueous electrolyte secondary batteries represented by lithium-ion secondary batteries have high energy density and high output, and are power sources for mobile devices such as smartphones, power sources for vehicles such as electric vehicles, and natural energy such as sunlight. It is regarded as a promising storage device for electricity.
  • Patent Document 1 proposes a non-aqueous electrolyte secondary battery of a type in which lithium metal is deposited on a negative electrode current collector during charging and the lithium metal is dissolved during discharge for the purpose of increasing the capacity of the battery.
  • Patent Document 2 has a positive electrode current collector foil, a positive electrode active material layer, a solid electrolyte layer, and a negative electrode current collector foil in this order, and is a method for charging a secondary battery using a precipitation-dissolution reaction of metallic lithium as a reaction of the negative electrode.
  • the secondary battery By charging the secondary battery with the first current density I1 (mA / cm 2 ), metallic lithium is deposited on the surface of the solid electrolyte layer on the negative electrode collecting foil side to activate the negative electrode.
  • the secondary battery is made larger than the first current density I1.
  • the secondary battery has at least a second charging step of charging with a second current density I2 to increase the thickness of the roughness coating layer
  • the first charging step is the negative electrode current collecting foil side of the solid electrolyte layer.
  • one aspect of the present disclosure includes a positive electrode, a negative electrode provided with a negative electrode current collector, and a non-aqueous electrolyte, and lithium metal is deposited on the negative electrode during charging and the lithium metal is not present at the time of discharging.
  • a method for charging a secondary battery that dissolves in a water electrolyte wherein the charging method includes a step of charging the secondary battery according to either a first charging profile or a second charging profile.
  • the one charging profile includes at least two charging steps
  • the second charging profile includes more charging steps than the first charging profile, and at the start of the step of charging the secondary battery, the secondary battery.
  • Another aspect of the present disclosure comprises a secondary battery, a DOD detection device that detects the depth of discharge of the secondary battery, and a charge control unit that controls charging of the secondary battery.
  • a positive electrode, a negative electrode including a negative electrode current collector, and a non-aqueous electrolyte are provided. Lithium metal is deposited on the negative electrode during charging, and the lithium metal is dissolved in the non-aqueous electrolyte during discharge to detect the DOD.
  • the device measures the discharge depth of the secondary battery before the start of charging of the secondary battery, and the charge control unit of the secondary battery follows one of the first charge profile and the second charge profile.
  • the first charging profile comprises at least two charging steps
  • the second charging profile includes more charging steps than the first charging profile
  • the balance between the charging time of the secondary battery and the cycle characteristics is improved.
  • FIG. 1 is a flow chart of a method for charging a secondary battery according to an embodiment of the present disclosure.
  • FIG. 2 is a schematic configuration diagram of a secondary battery charging system according to an embodiment of the present disclosure.
  • FIG. 3 is a schematic perspective view in which a part of the secondary battery used in the charging method and the charging system according to the embodiment of the present disclosure is cut out.
  • the discharge depth (DOD) is the ratio of the amount of discharged electricity to the amount of electricity possessed by the fully charged battery.
  • the charge level (SOC) is the ratio of the amount of electricity remaining in the battery to the amount of electricity possessed by the fully charged battery.
  • the amount of electricity charged that is, the amount of full charge
  • the voltage of a fully charged battery corresponds to the end-of-charge voltage.
  • the voltage of the battery in the fully discharged state corresponds to the discharge end voltage.
  • the current density (mA / cm 2 ) is the charge density per unit facing area (1 cm 2 ) between the positive electrode and the negative electrode, and is the total area of the positive electrode mixture layer (or the positive electrode active material layer) facing the negative electrode. (Hereinafter, also referred to as the effective total area of the positive electrode), it is obtained by dividing the current value applied to the battery.
  • the effective total area of the positive electrode is, for example, when the positive electrode has positive electrode mixture layers on both sides of the positive electrode current collector, the total area of the positive electrode mixture layers on both sides (that is, the positive electrode collection of each positive electrode mixture layer on both sides). The total area projected onto one and the other surface of the electric body).
  • the secondary battery charged by the charging method according to the present disclosure includes a positive electrode, a negative electrode provided with a negative electrode current collector, and a non-aqueous electrolyte, and lithium metal is deposited on the negative electrode during charging and lithium metal during discharge.
  • a secondary battery that dissolves in a non-aqueous electrolyte that is, the secondary battery mainly means, but is not limited to, a lithium (metal) secondary battery.
  • a lithium secondary battery for example, 70% or more of the rated capacity is expressed by precipitation and dissolution of lithium metal.
  • the movement of electrons in the negative electrode during charging and discharging is mainly due to the precipitation and dissolution of lithium metal in the negative electrode.
  • 70 to 100% (for example, 80 to 100% or 90 to 100%) of electron transfer (current in another aspect) in the negative electrode during charging and discharging is due to the precipitation and dissolution of the lithium metal.
  • the negative electrode according to the present embodiment is different from the negative electrode in which the movement of electrons in the negative electrode during charging and discharging is mainly due to the storage and release of lithium ions by the negative electrode active material (graphite or the like).
  • the charging method according to the present disclosure includes a step of charging the secondary battery according to either the first charging profile or the second charging profile.
  • FIG. 1 is a flow chart showing an example of a charging method according to the present disclosure.
  • the exemplified charging method includes a step (S1) of selecting one of a first charging profile and a second charging profile before starting charging. Such selection is based on the DOD prior to the start of the process of charging the secondary battery (hereinafter also referred to as time point T).
  • time point T time point
  • the charging current can be selectively reduced within a necessary range during the period of use of the secondary battery in which charging and discharging are repeated, and the time required for charging can be shortened as a whole.
  • the first charging profile includes at least two charging steps, and the second charging profile includes more charging steps than the first charging profile. That is, when the first charging profile includes n ( ⁇ 2) charging steps, the second charging profile includes (n + m) charging steps.
  • the charging profile is a recipe that defines conditions such as the charging method, voltage, and current when the secondary battery is charged.
  • the charging profile defines the schedule for each step of charging the secondary battery to a fully charged state.
  • each charging step is a step of charging the secondary battery under different charging conditions.
  • the charging conditions are regulated by the charging current and / or the charging voltage.
  • Each charging step may be a constant current charging step or a constant voltage charging step.
  • the value of the charge current is initially small and gradually increases.
  • the charging current increases in smaller increments than in the first charging profile.
  • the charging current may start to decrease after a period in which the charging current gradually increases from the start of charging. Normally, in the step of charging the secondary battery, the battery is charged according to the first profile or the second profile until the battery is fully charged (SOC 100%).
  • the first charging profile is selected, and when it is equal to or higher than the threshold value, the second charging profile is selected.
  • Selected (S2) That is, at the time point T, when the DOD is shallow (when the SOC of the battery is high), the number of charging steps is small, and when the DOD is deep (when the SOC of the battery is low), the number of charging steps is larger.
  • the charging current increases in smaller increments. That is, in the second charge profile, charging can be started from a charge current smaller than that in the first charge profile. Further, in the second charge profile, charging can be performed with a charge current larger than that in the first charge profile.
  • the second charging profile contributes to improving the cycle characteristics and / or shortening the charging time.
  • the first charging profile does not need to increase the charging current in such small steps. Therefore, simpler control (or simpler control circuit structure) can be adopted. Further, when the first profile is selected, the charging current at the start of charging may be larger than the charging current at the start of charging in the second profile.
  • the threshold value of DOD that influences the selection of the first profile and the second profile may be, for example, 50% or more and 70% or less, or 55% or more and 70% or less.
  • a shallow discharge depth with a DOD of less than 50% that is, an SOC of 50% or more
  • the lithium metal is less likely to be isolated because there is a sufficient underlayer in which the lithium metal is deposited during charging.
  • priority is given to selecting the first profile and completing charging with simple control or as quickly as possible.
  • the DOD is shallow, the merit of further increasing the number of charging steps and charging with a large current at the end of charging is not seen from the viewpoint of the capacity retention rate.
  • the presence of the underlying layer on which the lithium metal precipitates during charging is insufficient, and the lithium metal may grow like a dendrite. high.
  • it is prioritized to select the second profile and proceed with charging carefully.
  • it is prioritized to select a second profile that includes more charging steps and charge with a larger current closer to the end of charging to shorten the charging time.
  • the first charging profile includes, for example, a charging step S11 at a first current density I1 followed by a charging step S12 at a second current density I2 that is greater than the first current density I1 (I1 ⁇ I2).
  • the second charging profile includes, for example, a charging step S21 at a third current density I3 and a subsequent charging step S22 at a fourth current density I4 that is larger than the third current density I3 (I3 ⁇ I4).
  • the second charging profile has a larger number of charging steps than the first charging profile, and has at least a charging step S23 at a fifth current density I5 following the charging step S22. It is desirable that the fifth current density I5 of the charging step S23 following the charging step S22 is larger than the fourth current density I4 (I4 ⁇ I5).
  • the charging step S11 is set as, for example, the first charging step in the first profile. Further, the charging step S21 is set as, for example, the first charging step in the second profile. Both the charging step S11 and the charging step S12 in the first profile may be a constant current charging step. The charging step S21, the charging step S22, and the charging step S23 in the second profile may all be constant current charging steps.
  • the third current density I3 may be smaller than the first current density I1 (I3 ⁇ I1).
  • I3 / I1 is not particularly limited, but may be, for example, 0.2 to 1 or 0.5 to 1.
  • I1 is to I2 (the closer I1 / I2 is to 1), the shorter the charging time when charging the secondary battery with the first profile.
  • I4 is relative to I3 (the smaller I3 / I4), the more difficult it is for the lithium metal to grow like a dendrite. Therefore, it is desirable to satisfy I1 / I2> I3 / I4.
  • I1 / I2 may be, for example, 0.6 or more, 0.7 or more, 0.75 or more (further 0.8 or more). However, if I1 / I2 approaches 1 too much, the possibility that the lithium metal is isolated during charging in the charging step S11 gradually increases, so that I1 / I2 is preferably 0.9 or less.
  • the charging electricity amount Q1 in the charging step S11, the charging electricity amount Q2 in the charging step S12, the charging electricity amount Q3 in the charging step S21, and the charging electricity amount Q4 in the charging step S22 may satisfy Q1 / Q2 ⁇ Q3 / Q4.
  • the larger Q2 is relative to Q1 (the smaller Q1 / Q2), the shorter the charging time when charging the secondary battery with the first profile.
  • Q4 is larger than Q3 (Q3 / Q4 is smaller), the charging time when charging the secondary battery with the second profile becomes shorter.
  • it is desirable that Q2 ⁇ Q4 it is desirable that Q1 / Q2 ⁇ Q3 / Q4.
  • the first current density I1 may be, for example, 3.0 mA / cm 2 or less, and the second current density I2 may be 4.0 mA / cm 2 or more.
  • the first current density I1 is preferably 1.0 mA / cm 2 or more, and may be 2.0 mA / cm 2 or more in consideration of the balance between the charging time and the cycle characteristics.
  • the second current density I2 is preferably 4.0 mA / cm 2 or more, and may be 6.0 mA / cm 2 or more. However, if the second current density I2 is too high, the possibility that the lithium metal is isolated during charging gradually increases, so that I2 is preferably 8.0 mA / cm 2 or less.
  • I1 / I2 may be, for example, 0.1 or more and 0.8 or less, and may be 0.4 or more and 0.7 or less.
  • the charging electricity amount (Q1) in the charging step S11 may be 5% or more and 15% or less of the total charging electricity amount charged in the process of charging the secondary battery.
  • the “total charge electricity amount charged in the process of charging the secondary battery” is the charge electricity amount from the start of charging until the secondary battery is fully charged, and is the secondary charge at the start of charging. It changes depending on the DOD or SOC of the battery.
  • the “total charge electricity amount” charged according to the first profile is also referred to as a total charge electricity amount P1.
  • Q1 is 5% or more of the total charge electricity amount P1
  • the effect of suppressing the growth of the dendrite-like lithium metal becomes large.
  • Q1 is 15% or less of the total charge electricity amount, a sufficient effect of suppressing the growth of the dendrite-like lithium metal can be obtained while shortening the charge time.
  • the third current density I3 is, for example, 1 mA / cm 2 or less
  • the fourth current density I4 is larger than the third current density and 4 mA / cm 2 or less
  • the current density I5 may be larger than the second current density and may be 4 mA / cm 2 or more.
  • the third current density I3 is preferably 0.1 mA / cm 2 or more, and may be 0.5 mA / cm 2 or more in consideration of the balance between the charging time and the cycle characteristics.
  • the fourth current density I4 is preferably 1.0 mA / cm 2 or more, and may be 2.0 mA / cm 2 or more. However, if the fourth current density I4 is too high, the possibility that the lithium metal is isolated during charging gradually increases, so that I4 is preferably 4.0 mA / cm 2 or less.
  • the fifth current density I5 is preferably 6.0 mA / cm 2 or more, and may be 8.0 mA / cm 2 or more. However, if the fifth current density I5 is too high, the possibility that the lithium metal is isolated during charging gradually increases, so that I5 is preferably 10.0 mA / cm 2 or less.
  • I3 / I4 may be, for example, 0.1 or more and 0.5 or less, and may be 0.2 or more and 0.4 or less.
  • I4 / I5 may be, for example, 0.2 or more and 0.9 or less, and may be 0.3 or more and 0.7 or less.
  • the charging step S21 (initial stage of charging) with a small third current density I3, lithium metal is deposited in a lump (granular form) on the negative electrode current collector, and a good lithium metal underlayer is likely to be formed. Therefore, even if the fourth current density I4 in the subsequent charging step S22 is made larger than the third current density I3, the dendrite-like lithium metal is unlikely to grow. Further, since the lithium metal underlayer grows further in the charging step S22, even if the current density I5 in the subsequent charging step S23 is made larger than I4 (I4 ⁇ I5), the growth of the dendrite-like lithium metal is suppressed. To. This makes it possible to significantly reduce the charging time.
  • the charging electricity amount (Q3) in the charging step S21 may be 5% or more and 15% or less of the total charging electricity amount charged in the process of charging the secondary battery.
  • the "total charge electricity amount" charged according to the second profile is also referred to as a total charge electricity amount P2.
  • Q3 is 5% or more of the total charge electricity amount P2
  • the effect of suppressing the growth of the dendrite-like lithium metal becomes large.
  • Q3 is 15% or less of the total charge electricity amount P2 a sufficient effect of suppressing the growth of the dendrite-like lithium metal can be obtained while shortening the charge time.
  • the total charge electricity amount in the charge step S21 and the charge step S22 may be 50% or less of the total charge electricity amount P2, or may be 40% or less. In this case, it is possible to significantly shorten the charging time while sufficiently suppressing the growth of the dendrite-like lithium metal. More than 50% of the rest of the total charge electricity amount P2 is charged in the charging step S23 at the higher current density I5.
  • the timing of ending each charging step may be controlled by, for example, charging time, charging electricity amount, voltage, etc., and is controlled by the ratio of the charged electricity amount to the total charging electricity amount P1 and P2 of each charging step. It may be controlled by SOC or charge rate. SOC may be estimated by voltage. For example, the SOC may be estimated from the voltage, and the charge stop voltage at each charge step may be set.
  • the charging at the first current density I1 is terminated and the second current density I2 is used.
  • Charging step S12 is started.
  • the charging at the second current density I2 is completed.
  • the first voltage is, for example, the voltage when the charging electricity amount corresponding to 15% or less of the total charging electricity amount P1 is charged
  • the second voltage is, for example, 90% or more of the total charging electricity amount P1. It is the voltage when the total amount of charging electricity to be charged is charged.
  • the charging step S21 at the third current density I3 is completed and the fourth.
  • the charging step S22 at the current density I4 is started.
  • the charging step S22 at the fourth current density I4 is terminated and the charging step S23 at the fifth current density I5 is started.
  • the charging at the fifth current density I5 is terminated.
  • the third voltage is, for example, the voltage when the charging electricity amount corresponding to 15% or less of the total charging electricity amount P2 is charged, and the fourth voltage is, for example, 50% or less of the total charging electricity amount P1.
  • the charging electricity amount to be charged is the voltage when the total charge is performed, and the fifth voltage is, for example, the voltage when the charging electricity amount corresponding to 90% or more of the total charging electricity amount P1 is totally charged.
  • the charging step S3 at a constant voltage may be performed following the charging step at a constant current. Such a charging step is performed, for example, until the current reaches a predetermined value. For example, after performing the final charging step at a constant current to a predetermined charge termination voltage, the charging step at a constant voltage may be performed at the voltage. After that, the discharge is performed with the discharge up to a predetermined end-of-discharge voltage as a limit.
  • the charging system includes a secondary battery, a DOD detection device that detects the discharge depth of the secondary battery, and a charge control unit that controls charging of the secondary battery.
  • the secondary battery is a battery including a positive electrode, a negative electrode provided with a negative electrode current collector, and a non-aqueous electrolyte, in which lithium metal is deposited on the negative electrode during charging and the lithium metal is dissolved in the non-aqueous electrolyte during discharge.
  • the discharge depth detection device measures the discharge depth of the secondary battery before starting charging of the secondary battery.
  • the charge control unit controls the charge of the secondary battery according to any of the first charge profile and the second charge profile already described.
  • the first charge profile is selected, and when the DOD is equal to or higher than the threshold value, the first charge profile is selected. A second charge profile is selected.
  • FIG. 2 shows an example of a charging system according to an embodiment.
  • the charging system includes a secondary battery 11 and a charging device 12.
  • An external power source 13 that supplies electric power to the charging device 12 is connected to the charging device 12.
  • the charging device 12 includes a charging control unit 14 including a charging circuit.
  • the charge control unit 14 controls charging of the secondary battery according to the selected charge profile.
  • the charging device 12 includes a voltage detecting unit 15 that detects the voltage of the secondary battery 11 as a DOD detecting device that detects the DOD of the secondary battery.
  • the voltage detection unit 15 includes a calculation unit that detects the voltage of the secondary battery 11 before the start of charging of the secondary battery and calculates the DOD based on the detected voltage.
  • the charge control unit 14 selects either the first profile or the second profile based on the DOD obtained by the calculation unit. Then, the charging of the secondary battery is controlled according to the selected charging profile.
  • the charging device 12 includes a current detecting unit 16 that detects the current output from the secondary battery.
  • the charge control unit 14 controls the charge current so that the current value detected by the current detection unit 16 does not deviate significantly from a predetermined value.
  • the timing of switching or ending the charging step is controlled by the voltage (or DOD (or SOC)) detected by the voltage detection unit 15, but the control method is not limited. For example, at least a part of the control may be performed based on the charging time, the amount of charging electricity, and the like.
  • the negative electrode includes a negative electrode current collector.
  • lithium metal is deposited on the surface of the negative electrode by charging. More specifically, lithium ions contained in the non-aqueous electrolyte receive electrons on the negative electrode by charging to become lithium metal, which are deposited on the surface of the negative electrode.
  • the lithium metal deposited on the surface of the negative electrode is dissolved as lithium ions in the non-aqueous electrolyte by electric discharge.
  • the lithium ion contained in the non-aqueous electrolyte may be derived from the lithium salt added to the non-aqueous electrolyte, or may be supplied from the positive electrode active material by charging, and both of them may be used. There may be.
  • the negative electrode may include a negative electrode current collector and a sheet-shaped lithium metal that is in close contact with the surface of the negative electrode current collector, and further, a lithium ion storage layer (negative electrode activity) supported on the negative electrode current collector. It may contain a layer that develops capacity by the storage and release of lithium ions by a substance (such as graphite).
  • the open circuit potential of the negative electrode at the time of full charge may be 70 mV or less with respect to the lithium metal (dissolution and precipitation potential of lithium).
  • the open circuit potential of the negative electrode at the time of full charge is 70 mV or less with respect to the lithium metal, the lithium metal is present on the surface of the lithium ion storage layer at the time of full charge. That is, the negative electrode develops the capacity due to the precipitation and dissolution of lithium metal.
  • the open circuit potential of the negative electrode at the time of full charge may be measured by disassembling the fully charged battery in an argon atmosphere, taking out the negative electrode, and assembling the cell with lithium metal as the counter electrode.
  • the non-aqueous electrolyte of the cell may have the same composition as the non-aqueous electrolyte in the decomposed battery.
  • the lithium ion occlusion layer is a layered negative electrode mixture containing a negative electrode active material.
  • the negative electrode mixture may contain a binder, a thickener, a conductive agent and the like in addition to the negative electrode active material.
  • Examples of the negative electrode active material include carbonaceous materials, Si-containing materials, Sn-containing materials, and the like.
  • the negative electrode may contain one kind of negative electrode active material, or may contain two or more kinds in combination.
  • Examples of the carbonaceous material include graphite, graphitized carbon (soft carbon), and graphitized carbon (hard carbon).
  • the conductive material is, for example, a carbon material.
  • the carbon material include carbon black, acetylene black, ketjen black, carbon nanotubes, graphite and the like.
  • binder examples include fluororesin, polyacrylonitrile, polyimide resin, acrylic resin, polyolefin resin, rubber-like polymer and the like.
  • fluororesin examples include polytetrafluoroethylene and polyvinylidene fluoride.
  • the negative electrode current collector may be a conductive sheet.
  • a conductive sheet a foil, a film or the like is used.
  • the thickness of the negative electrode current collector is not particularly limited, and is, for example, 5 ⁇ m or more and 300 ⁇ m or less.
  • the material of the negative electrode current collector may be any conductive material other than lithium metal and lithium alloy.
  • the conductive material may be a metal material such as a metal or an alloy.
  • the conductive material is preferably a material that does not react with lithium. More specifically, a material that does not form any of lithium and an alloy or an intermetallic compound is preferable. Examples of such conductive materials include copper (Cu), nickel (Ni), iron (Fe), and alloys containing these metal elements, or graphite whose basal surface is preferentially exposed. ..
  • Examples of the alloy include copper alloys and stainless steel (SUS). Of these, copper and / or copper alloys having high conductivity are preferable.
  • the negative electrode current collector may be a copper foil or a copper alloy foil.
  • the positive electrode includes, for example, a positive electrode current collector and a positive electrode mixture layer supported by the positive electrode current collector.
  • the positive electrode mixture layer contains, for example, a positive electrode active material, a conductive material, and a binder.
  • the positive electrode mixture layer may be formed on only one side of the positive electrode current collector, or may be formed on both sides.
  • the positive electrode can be obtained, for example, by applying a positive electrode mixture slurry containing a positive electrode active material, a conductive material, and a binder on both sides of a positive electrode current collector, drying the coating film, and then rolling.
  • the positive electrode active material is a material that occludes and releases lithium ions.
  • the positive electrode active material include a composite oxide containing lithium and a metal Me other than lithium (for example, a lithium-containing transition metal oxide containing at least a transition metal as the metal Me), a transition metal fluoride, a polyanion, and a fluorinated polyanion. , Transition metal sulfide and the like.
  • lithium-containing transition metal oxides are preferable in that the manufacturing cost is low and the average discharge voltage is high.
  • those having a layered rock salt type crystal structure are preferable.
  • Lithium contained in the lithium-containing transition metal oxide is released from the positive electrode as lithium ions during charging, and precipitates as a lithium metal on the negative electrode or the negative electrode current collector. At the time of discharge, lithium metal is dissolved from the negative electrode and lithium ions are released, which are stored in the composite oxide of the positive electrode. That is, the lithium ions involved in charging and discharging are generally derived from the solute in the non-aqueous electrolyte and the positive electrode active material.
  • the molar ratio of the total amount of Li contained in the positive electrode and the negative electrode mLi: mLi / mMe to the amount mMe of the metal Me contained in the lithium-containing transition metal oxide is, for example, 1.2 or less.
  • transition metal element contained in the lithium-containing transition metal oxide examples include Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Y, Zr, W and the like.
  • the lithium-containing transition metal oxide may contain one kind of transition metal element, or may contain two or more kinds of transition metal elements.
  • the transition metal element may be Co, Ni and / or Mn.
  • Lithium-containing transition metal oxides may contain one or more main group elements, if desired. Typical elements include Mg, Al, Ca, Zn, Ga, Ge, Sn, Sb, Pb, Bi and the like.
  • the main group element may be Al or the like.
  • a composite oxide having a rock salt-type crystal structure having a layered structure which may contain Co, Ni and / or Mn as a transition metal element and Al as an optional component, is high. It is preferable in terms of obtaining capacity. Further, a lithium-containing transition metal oxide containing at least Ni as a transition metal is particularly preferable in that it has a high capacity.
  • the molar ratio of the total amount of lithium possessed by the positive electrode and the negative electrode mLi to the amount mM of the metal M other than lithium possessed by the positive electrode: mLi / mM is set to, for example, 1.1 or less. May be done.
  • the lithium-containing transition metal oxide is represented by, for example, the general formula (1): Li a Ni b M 1-b O 2 .
  • the general formula (1) satisfies, for example, m0.9 ⁇ a ⁇ 1.2 and 0.65 ⁇ b ⁇ 1.
  • M may be, for example, at least one element selected from the group consisting of Co, Mn, Al, Ti, Fe, Nb, B, Mg, Ca, Sr, Zr and W.
  • the binder As the binder, the conductive agent, etc., for example, those exemplified for the negative electrode can be used.
  • the shape and thickness of the positive electrode current collector can be selected from the shape and range of the positive electrode current collector.
  • Examples of the material of the positive electrode current collector (conductive sheet) include metal materials containing Al, Ti, Fe and the like.
  • the metal material may be Al, Al alloy, Ti, Ti alloy, Fe alloy or the like.
  • the Fe alloy may be stainless steel (SUS).
  • a porous sheet having ion permeability and insulating property is used as the separator.
  • the porous sheet include a thin film having microporous, a woven fabric, a non-woven fabric and the like.
  • the material of the separator is not particularly limited, but may be a polymer material.
  • the polymer material include olefin resin, polyamide resin, cellulose and the like.
  • the olefin resin include polyethylene, polypropylene and a copolymer of ethylene and propylene.
  • the separator may contain additives, if desired. Examples of the additive include an inorganic filler and the like.
  • the thickness of the separator is not particularly limited, but is, for example, 5 ⁇ m or more and 20 ⁇ m or less, and more preferably 10 ⁇ m or more and 20 ⁇ m or less.
  • the non-aqueous electrolyte having lithium ion conductivity includes, for example, a non-aqueous solvent and lithium ions and anions dissolved in the non-aqueous solvent.
  • the non-aqueous electrolyte may be liquid or gel.
  • the liquid non-aqueous electrolyte is prepared by dissolving the lithium salt in a non-aqueous solvent.
  • the dissolution of the lithium salt in a non-aqueous solvent produces lithium ions and anions.
  • the gel-like non-aqueous electrolyte contains a lithium salt and a matrix polymer, or a lithium salt and a non-aqueous solvent and a matrix polymer.
  • a matrix polymer for example, a polymer material that absorbs a non-aqueous solvent and gels is used. Examples of the polymer material include fluororesin, acrylic resin, and polyether resin.
  • a known one used for a non-aqueous electrolyte of a lithium secondary battery can be used.
  • Specific examples thereof include BF 4- , ClO 4- , PF 6- , CF 3 SO 3- , CF 3 CO 2- , imide anions, and oxalate complex anions.
  • imides N (SO 2 CF 3 ) 2- , N (C m F 2 m + 1 SO 2 ) x (C n F 2n + 1 SO 2 ) y- ( m and n are 0 or 1 independently, respectively.
  • the anion of the oxalate complex may contain boron and / or phosphorus.
  • the anions of the oxalate complex include bisoxalate borate anion, difluorooxalate borate anion (BF 2 (C 2 O 4 ) - ), PF 4 (C 2 O 4 ) - , and PF 2 (C 2 O 4 ) 2- . And so on.
  • the non-aqueous electrolyte may contain these anions alone or may contain two or more of these anions.
  • the non-aqueous electrolyte preferably contains at least an anion of an oxalate complex, and among them, an oxalate complex anion having fluorine (particularly a difluorooxalate borate anion) may be contained. desirable.
  • an oxalate complex anion having fluorine particularly a difluorooxalate borate anion
  • the interaction between the fluorine-containing oxalate complex anion and lithium facilitates the uniform precipitation of lithium metal in the form of fine particles. Therefore, it becomes easy to suppress the local precipitation of the lithium metal.
  • An oxalate complex anion having fluorine may be combined with another anion.
  • Other anions may be PF 6 - and / or imides anions.
  • non-aqueous solvent examples include esters, ethers, nitriles, amides, and halogen substituents thereof.
  • the non-aqueous electrolyte may contain these non-aqueous solvents alone or may contain two or more of them.
  • halogen substituent examples include fluoride and the like.
  • the concentration of the lithium salt in the non-aqueous electrolyte is, for example, 0.5 mol / L or more and 3.5 mol / L or less.
  • the concentration of anions in the non-aqueous electrolyte may be 0.5 mol / L or more and 3.5 mol / L or less.
  • the concentration of the anion of the oxalate complex in the non-aqueous electrolyte may be 0.05 mol / L or more and 1 mol / L or less.
  • An example of the structure of a lithium secondary battery is a structure in which an electrode group in which a positive electrode and a negative electrode are wound via a separator is housed in an exterior body together with an electrolytic solution.
  • the present invention is not limited to this, and other forms of electrodes may be applied.
  • a laminated electrode group in which a positive electrode and a negative electrode are laminated via a separator may be used.
  • the form of the lithium secondary battery is not limited, and may be, for example, a cylindrical type, a square type, a coin type, a button type, a laminated type, or the like.
  • FIG. 3 is a schematic perspective view in which a part of the rectangular lithium secondary battery according to the embodiment of the present disclosure is cut out.
  • the battery includes a bottomed square battery case 4, an electrode group 1 housed in the battery case 4, and an electrolytic solution.
  • the electrode group 1 has a long strip-shaped negative electrode, a long strip-shaped positive electrode, and a separator interposed between them.
  • the negative electrode current collector of the negative electrode is electrically connected to the negative electrode terminal 6 provided on the sealing plate 5 via the negative electrode lead 3.
  • the negative electrode terminal 6 is insulated from the sealing plate 5 by a resin gasket 7.
  • the positive electrode current collector of the positive electrode is electrically connected to the back surface of the sealing plate 5 via the positive electrode lead 2.
  • the positive electrode is electrically connected to the battery case 4 that also serves as the positive electrode terminal.
  • the peripheral edge of the sealing plate 5 is fitted to the open end portion of the battery case 4, and the fitting portion is laser welded.
  • the sealing plate 5 has an injection hole for the electrolytic solution, and is closed by the sealing 8 after the injection.
  • Example 1 [Preparation of positive electrode] Lithium-nickel composite oxide (LiNi 0.9 Co 0.05 Al 0.05 O 2 ), acetylene black, and polyvinylidene fluoride (PVdF) are mixed in a mass ratio of 95: 2.5: 2.5. After adding N-methyl-2-pyrrolidone (NMP), the mixture was stirred to prepare a positive electrode slurry. Next, the positive electrode slurry is applied to the surface of the Al foil which is the positive electrode current collector, the coating film is dried, and then rolled, and the positive electrode mixture layer (density 3.6 g / cm 3 ) is applied to both sides of the Al foil. Was formed into a positive electrode.
  • NMP N-methyl-2-pyrrolidone
  • a non-aqueous electrolyte was prepared by dissolving a lithium salt in a mixed solvent.
  • FEC fluoroethylene carbonate
  • EMC ethyl methyl carbonate
  • DMC dimethyl carbonate
  • LiPF 6 , LiN (FSO 2 ) 2 hereinafter referred to as LiFSI
  • LiBF 2 (C 2 O 4 ) hereinafter referred to as LiFOB
  • the concentration of LiPF 6 in the non-aqueous electrolyte was 0.5 mol / L, and the concentration of LiFSI was 0.5 mol / L.
  • the content of LiFOB in the non-aqueous electrolyte was 1% by mass.
  • a positive electrode lead made of Al was attached to the positive electrode obtained above, and a negative electrode lead made of Ni was attached to the negative electrode obtained above.
  • the positive electrode and the negative electrode were spirally wound via a polyethylene thin film (separator) to prepare a wound electrode group.
  • the electrode group was housed in a bag-shaped exterior body formed of a laminated sheet provided with an Al layer, the non-aqueous electrolyte was injected, and then the exterior body was sealed to prepare a non-aqueous electrolyte secondary battery.
  • the electrode group was housed in the exterior body, a part of the positive electrode lead and the negative electrode lead were exposed to the outside from the exterior body, respectively.
  • the molar ratio of the total amount of lithium possessed by the positive electrode and the negative electrode mLi to the amount mMe of the metal Me (here, Ni, Co and Al) possessed by the positive electrode is: mLi / mMe. It was 1.0.
  • the voltage at 100% SOC is 4.1V, and the voltage at 100% DOD is 3.0V.
  • the current value (1 / X) C represents the current value when the amount of electricity corresponding to the rated capacity C is constantly charged or discharged in X hours.
  • 0.1C is a current value when a constant current charge or a constant current discharge is performed in 10 hours for an amount of electricity corresponding to the rated capacity C.
  • Table 1 shows the time required for full charge by charging according to the first profile and the second profile.
  • Table 2 shows the capacity retention rate after 60 cycles.
  • ⁇ 1st profile> (1) DOD at the start of charging: 80% (voltage 3.55V) (2) First charging step S21 First current density I1: 1 mA / cm 2 Charging electricity Q1: 15% of total charging electricity P1 (3) Charging step S12 following S11 2nd current density I2: 4mA / cm 2 Charging electricity Q2: The balance of the total charging electricity P1 (85%) End of charge voltage: 4.1V (4) Constant voltage charging following S12 Constant voltage charging at 4.1V until the current reaches 0.02C (current density 0.2mA / cm 2 ) (5) Discharging After 10 minutes of rest, the voltage becomes 3.75V.
  • the capacity retention rate tends to decrease slightly (96.0% ⁇ 93.8%). It is considered that this is because metallic lithium is likely to be slightly deposited in the form of dendrites when the fifth current density I5 is charged. That is, when the DOD is shallow, the charging time does not change significantly regardless of which of the first and second profiles is selected. Therefore, it is desirable to select the first profile, which is more advantageous in the capacity retention rate.
  • the charging time is significantly shortened by adopting the second profile. That is, when the second profile is adopted, the charging time is shortened from 3.04 hours to 2.72 hours by 0.32 hours as compared with the case where the first profile is adopted.
  • the threshold value of the DOD that is the boundary between the first charging profile and the second charging profile should be set to at least 50% or more. Can be said to be desirable. Further, when the DOD is 80%, the merit of shortening the charging time is remarkable, so it can be said that it is desirable to set the threshold value of the DOD to, for example, 70% or less.
  • the charging method and charging system according to the present disclosure are suitably used for charging a lithium secondary battery of a type in which lithium metal is deposited on a negative electrode current collector during charging and the lithium metal is dissolved during discharging.
  • Electrode group 2 Positive electrode lead 3 Negative electrode lead 4 Battery case 5 Seal plate 6 Negative terminal 7 Gasket 8 Sealing 11 Non-aqueous electrolyte secondary battery 12 Charging device 13 External power supply 14 Charging control unit 15 Voltage detection unit 16 Current detection unit

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EP4645646A4 (en) * 2022-12-26 2026-04-01 Panasonic Ip Man Co Ltd METHOD FOR CHARGE CONTROL FOR A SECONDARY BATTERY WITH NON-AQUEOUS ELECTROLYTE, CHARGE CONTROL SYSTEM FOR A SECONDARY BATTERY WITH NON-AQUEOUS ELECTROLYTE, AND POWER SUPPLY DEVICE USING IT

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