WO2022054733A1 - 有機溶剤回収システム - Google Patents
有機溶剤回収システム Download PDFInfo
- Publication number
- WO2022054733A1 WO2022054733A1 PCT/JP2021/032561 JP2021032561W WO2022054733A1 WO 2022054733 A1 WO2022054733 A1 WO 2022054733A1 JP 2021032561 W JP2021032561 W JP 2021032561W WO 2022054733 A1 WO2022054733 A1 WO 2022054733A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- treatment
- organic solvent
- gas
- flow path
- desorption
- Prior art date
Links
- 239000003960 organic solvent Substances 0.000 title claims abstract description 152
- 238000011084 recovery Methods 0.000 title claims abstract description 62
- 238000011282 treatment Methods 0.000 claims abstract description 172
- 238000001179 sorption measurement Methods 0.000 claims abstract description 62
- 238000003795 desorption Methods 0.000 claims abstract description 59
- 239000003463 adsorbent Substances 0.000 claims description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910021536 Zeolite Inorganic materials 0.000 claims description 6
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 6
- 239000010457 zeolite Substances 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 136
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 33
- 239000000779 smoke Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 11
- 238000005273 aeration Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002351 wastewater Substances 0.000 description 7
- 238000001816 cooling Methods 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- -1 triethylene glycol, organic acids Chemical class 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N Vilsmeier-Haack reagent Natural products CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- HTWIZMNMTWYQRN-UHFFFAOYSA-N 2-methyl-1,3-dioxolane Chemical compound CC1OCCO1 HTWIZMNMTWYQRN-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-M hexanoate Chemical compound CCCCCC([O-])=O FUZZWVXGSFPDMH-UHFFFAOYSA-M 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000002336 sorption--desorption measurement Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0423—Beds in columns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/72—Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/82—Solid phase processes with stationary reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/30—Active carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
- B01D2257/704—Solvents not covered by groups B01D2257/702 - B01D2257/7027
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
Definitions
- the present invention relates to an organic solvent recovery system that recovers an organic solvent from a gas containing an organic solvent.
- Patent Document 1 discloses a gas treatment apparatus provided with three treatment tanks having an adsorbent.
- the adsorption step is continuously carried out in the two treatment tanks, and the desorption step is carried out in the remaining treatment tanks during that period.
- Diluting gas is supplied to dry the adsorbent in the treatment tank after the desorption step.
- Patent Document 2 includes a first suction / desorption device having two treatment tanks and a second suction / desorption device for recovering an organic solvent contained in a gas to be treated discharged from the first suction / desorption device.
- An organic solvent recovery system is disclosed.
- the second suction / desorption device desorbs the organic solvent adsorbed on the second suction / desorption element from the second suction / desorption element and the first treatment unit that adsorbs the organic solvent contained in the gas to be treated by the second suction / desorption element. It has a second processing unit and a second processing unit.
- the removal rate of the organic solvent is increased by continuously performing the adsorption step in the two treatment tanks, and in the organic solvent recovery system described in Patent Document 2, The removal rate of the organic solvent is increased by continuously performing the adsorption step in any of the treatment tanks of the first suction / desorption device and the first treatment section of the second suction / desorption device.
- the adsorption rate of the organic solvent slows down due to the rise in the temperature of the gas to be treated and the adsorption of water on the second suction / desorption device, which is equal to or higher than the design outlet concentration of the second suction / desorption device.
- the organic solvent gas is discharged.
- the adsorption of water by white smoke also causes an increase in the heat energy required for the desorption step of the second suction / desorption device.
- the present invention has been made in view of the above problems, and an object thereof is to provide an organic solvent recovery system capable of cost control, size increase control, and energy control.
- the present invention has the following configuration. 1.
- a connecting flow path connecting three or more first treatment tanks filled with a first adsorbent capable of absorbing and desorbing an organic solvent, a water vapor supply flow path for introducing water vapor, and a plurality of the first treatment tanks in series.
- a processing gas supply flow path for supplying the processing gas containing an organic solvent.
- the organic solvent contained in the gas to be treated supplied in the plurality of first treatment tanks connected in series in multiple stages is adsorbed, the first treatment gas is discharged, and the rest.
- the desorption treatment of the organic solvent adsorbed in the first treatment tank is performed using the introduced steam, and all the first treatment tanks are continuously performed by switching between the adsorption treatment and the desorption treatment.
- Solvent recovery device and It is provided with a second treatment tank filled with a second adsorbent capable of adsorbing and desorbing an organic solvent, and a feed channel for supplying the first treatment gas to the second treatment tank, and is included in the first treatment gas. Equipped with an organic solvent concentrator that continuously switches between adsorption processing and desorption processing of organic solvent.
- An organic solvent recovery system characterized in that the desorption treatment and the adsorption treatment are simultaneously switched between the first treatment tank and the second treatment tank. 2.
- the organic solvent recovery system according to 1 above. 3. 3. A connection flow path for introducing a part of the second treatment gas discharged by the adsorption treatment in the second treatment tank for desorption treatment in the second treatment tank, and a heating means provided in the connection flow path.
- the present invention by simultaneously switching between the desorption treatment and the adsorption treatment in the treatment tank between the organic solvent recovery device in the first stage and the organic solvent concentrator in the second stage, the water content due to the inflow of white smoke into the organic solvent concentrator in the latter stage. It is possible to secure the layer length of the adsorbent in which the organic solvent is not saturated against the decrease in the adsorption rate due to the adsorption of. Therefore, it is possible to prevent the organic solvent from being mixed with the processing gas (clean gas) processed and discharged by the organic solvent concentrating device.
- FIG. 1 is a diagram schematically showing the configuration of the organic solvent recovery system 1 according to the embodiment of the present invention.
- the organic solvent recovery system 1 includes an organic solvent recovery device 100 and an organic solvent concentrator 200. Further, it is provided with a feed flow path L300 and a return flow path L400.
- the organic solvent recovery system 1 removes and recovers the organic solvent from the gas to be treated containing the organic solvent in the organic solvent recovery device 100, and then collects the organic solvent with respect to the first treatment gas discharged from the organic solvent recovery device 100.
- the concentrator 200 further removes and concentrates the organic solvent, and discharges the second treatment gas (clean gas). Further, the desorbed gas desorbed from the organic solvent concentrating device 200 is returned to the organic solvent recovery device 100 through the return flow path L400.
- the organic solvent recovery system 1 simultaneously switches between the desorption treatment (desorption step) and the adsorption treatment (adsorption step) in each treatment tank of the organic solvent recovery device 100 and the organic solvent concentrator 200. Simultaneous includes almost simultaneous.
- the organic solvent recovery device 100 is a device that removes and recovers the organic solvent from the gas to be treated.
- the gas to be treated is supplied to the organic solvent recovery device 100 from a gas supply source to be treated provided outside the system of the organic solvent recovery device 100.
- the organic solvent recovery device 100 includes three first treatment tanks 101 to 103, a gas supply flow path L110 to be treated, a connection flow path L121 to L123, an extraction flow path L131 to L133, and a steam supply flow path L141 to L143.
- the organic solvent recovery channels L151 to L153, the separator 120, the resupply channel L160, and the diluted gas supply channel L170 are provided.
- Each of the first treatment tanks 101 to 103 has first adsorbents 101A to 103A capable of adsorbing an organic solvent and desorbing the organic solvent.
- the first adsorbents 101A to 103A include granular activated carbon, zeolite, honeycomb-shaped activated carbon, zeolite, activated carbon fiber and the like, and those made of activated carbon fiber are preferable.
- Each of the first treatment tanks 101 to 103 discharges / discharges the processing gas discharge port after passing through the opening / closing dampers V101 to V103 and the first adsorbents 101A to 103A for switching the supply / non-supply of the treatment gas to the treatment gas supply port. It has open / close dampers V104 to V106 that switch non-discharge.
- each of the first treatment tanks 101 to 103 the adsorption of the organic solvent by the first adsorbents 101A to 103A and the desorption of the organic solvent from the first adsorbents 101A to 103A are alternately performed. That is, in the first treatment tank of one of the three first treatment tanks 101 to 103, the organic solvent is adsorbed from the gas to be treated supplied from the gas supply source to be treated, and the gas after the first adsorption is discharged. 1
- the adsorption step (adsorption treatment) is performed, and in another first treatment tank connected in series to the first treatment tank in which the first adsorption treatment is performed, the organic solvent is adsorbed from the gas after the first adsorption.
- a second adsorption step (adsorption treatment) for discharging the treated gas is performed, and during that time, a desorption step (desorption treatment) for desorbing an organic solvent from the first adsorbent is performed in the remaining one first treatment tank.
- a desorption step desorption treatment for desorbing an organic solvent from the first adsorbent is performed in the remaining one first treatment tank.
- the gas to be treated flow path L110 is a flow path for supplying the gas to be treated to each of the first treatment tanks 101 to 103.
- the upstream end of the gas supply flow path L110 to be processed is connected to the gas supply source to be processed.
- the processed gas supply flow path L110 is provided with a cooler C1 and a heater H1 for adjusting the temperature and humidity of the processed gas flowing into each of the first processing tanks 101 to 103.
- the gas to be processed flow path L110 has branch flow paths L111 to L113 for supplying the gas to be processed to each of the first treatment tanks 101 to 103.
- the branch flow path L111 is provided with an on-off valve V111.
- the branch flow path L112 is provided with an on-off valve V112.
- the branch flow path L113 is provided with an on-off valve V113.
- the organic solvent is adsorbed in the first adsorbent of the first treatment tank (the first treatment tank used in the first adsorption step) of one of the three first treatment tanks 101 to 103.
- Each connecting flow path L121 to L123 has L120 that merges with each other.
- An on-off valve V121 is provided at a portion of the first connecting flow path L121 that branches again from the merging path L120.
- An on-off valve V122 is provided at a portion of the second connecting flow path L122 that branches again from the merging path L120.
- An on-off valve V123 is provided at a portion of the third connecting flow path L123 that branches again from the merging path L120.
- the take-out flow paths L131 to L133 are flow paths for taking out the first treatment gas, which is the treatment gas after the adsorption treatment in each of the first treatment tanks 101 to 103.
- the take-out flow paths L131 to L133 are connected to the processing gas discharge ports in the first processing tanks 101 to 103.
- An on-off valve V131 is provided in the first take-out flow path L131.
- An on-off valve V132 is provided in the second take-out flow path L132.
- An on-off valve V133 is provided in the third take-out flow path L133.
- Each take-out flow path L131 to L133 has a merging flow path L130 that joins each other.
- the steam supply channels L141 to L143 are for supplying steam for desorbing the organic solvent adsorbed on the first adsorbents 101A to 103A from the first adsorbents 101A to 103A to the first treatment tanks 101 to 103. It is a flow path.
- the first steam supply flow path L141 connects the steam supply source and the first treatment tank 101, and the first steam supply flow path is provided with an on-off valve V141.
- the second steam supply flow path L142 connects the steam supply source and the first treatment tank 102, and the second steam supply flow path is provided with an on-off valve V142.
- the third steam supply flow path L143 connects the steam supply source and the first treatment tank 103, and the third steam supply flow path is provided with an on-off valve V143.
- the organic solvent recovery flow paths L151 to L153 are flow paths for recovering water vapor (desorbed gas) containing the organic solvent desorbed from the first adsorbents 101A to 103A.
- the organic solvent recovery channels L151 to L153 are connected to the first treatment tanks 101 to 103.
- Each of the organic solvent recovery channels L151 to L153 has L150 that merges with each other.
- a condenser 122 is provided in the merging flow path L150. The condenser 122 condenses the desorbed gas by cooling the desorbed gas flowing through the confluence flow path L150, and discharges the condensed liquid (a mixed liquid of water generated by the condensation of the desorbed gas and the organic solvent of the liquid phase). Let me.
- the separator 120 is provided on the downstream side of the condenser 122, and phase-separates the inflowing condensed liquid into a liquid phase of the separated waste water and a liquid phase of the recovered solvent.
- the recovered solvent is taken out of the system of the organic solvent recovery device 100.
- a space (vent gas) in which a trace amount of organic solvent is present is formed on the upper portion of the separator 120.
- the resupply flow path L160 is a flow path connecting the separator 120 and the gas flow path L110 to be processed.
- the vent gas in the separator 120 is supplied to each of the first treatment tanks 101 to 103 again through the resupply flow path L160 and the gas to be processed flow path L110.
- the wastewater treatment facility 500 is a facility for removing the organic solvent contained in the separated wastewater. It is supplied from the liquid phase of the separated wastewater of the separator 120, the organic solvent is removed from the separated wastewater, and the treated water is discharged to the outside of the system.
- the wastewater treatment facility 500 includes an aeration facility that aerates the separated wastewater to volatilize the organic solvent contained in the separated wastewater and separates the separated wastewater into an aerated gas containing the organic solvent and the treated water.
- the aeration gas is connected to the upstream side of the cooler C1 of the gas to be treated gas supply flow path L110 via the aeration gas supply flow path L61.
- the aeration gas supply flow path L61 may be provided with a dehumidifying means for the purpose of removing water in the aeration gas.
- the diluted gas supply flow path L170 is a flow path for supplying the diluted gas for promoting the drying of the first adsorbents 101A to 103A after the desorption step to the connecting flow paths L21 to L23.
- the diluting gas is composed of a gas containing at least one of outside air, instrumentation air, nitrogen gas, and argon gas.
- the organic solvent concentrating device 200 is a device that further removes the organic solvent from the first treatment gas discharged from the organic solvent recovery device 100.
- the organic solvent concentrator 200 has at least two or more second treatment tanks, and in the case of two cases, the second treatment tanks 201 and 202 are used for the first treatment gas discharged through the confluence flow path L130. It has the second adsorbents 201A and 202A capable of adsorbing the contained organic solvent.
- the organic solvent contained in the first treatment gas is adsorbed by the second adsorbent 201A
- the organic solvent in the first treatment gas adsorbed by the second adsorbent 202A is adsorbed. Desorb the organic solvent.
- the second treatment tanks 201 and 202 are sequentially performed while exchanging the adsorption step and the desorption step.
- the second treatment gas which is a clean gas from which the organic solvent has been further removed, can be discharged, and after the adsorption is completed, the heating gas having a smaller air volume than the first treatment gas can be discharged.
- the desorbed gas in which the organic solvent is concentrated is discharged.
- the desorbed gas is returned to the organic solvent recovery device 100 from the diluted gas supply flow path L170 connected to the return flow path L400.
- Each of the second treatment tanks 201 and 202 has second adsorbents 201A and 202A capable of adsorbing an organic solvent and desorbing the organic solvent.
- the second adsorbents 201A and 202A include granular activated carbon, zeolite, activated carbon on a honeycomb, zeolite, and activated carbon fiber, and those made of activated carbon fiber are preferable.
- Each of the second treatment tanks 201 and 202 discharges / discharges the treated gas discharge port after passing through the open / close dampers V201 and V202, the second adsorbents 201A and 202A that switch the supply / non-supply of the processed gas to the processed gas supply port. It has open / close dampers V201 and V202 that switch non-discharge.
- the feed flow path L300 is a flow path for sending the gas to be processed from the organic solvent recovery device 100 to the organic solvent concentrator 200.
- the feed flow path L300 is provided with a cooler C2 and a heater H2 for adjusting the temperature and humidity of the first processing gas to be introduced into the organic solvent concentrator 200.
- the return flow path L400 is a flow path for returning the desorbed gas from the organic solvent concentrating device 200 to the organic solvent recovery device 100.
- the return flow path L400 is connected to the dilution gas supply flow path L170.
- the organic solvent concentrator 200 discharges the second treatment gas discharged from the second treatment tanks 201 and 202 to the outside from the clean gas discharge flow path L220. Further, the organic solvent concentrator 200 has a connection flow path L230 and a heater H3.
- connection flow path L230 connects the clean gas discharge flow path L220 and the second treatment tanks 201 and 202, and a part of the second treatment gas is used for desorption. It should be noted that the configuration may be such that the outside air is used for attachment / detachment.
- an appropriate device is appropriately arranged as necessary.
- the organic compound contained in the gas to be treated of the organic solvent recovery system 1 of the present embodiment is not particularly limited, but is not limited to aldehydes such as formaldehyde, acetaldehyde, propionaldehyde and achlorein, methylethylketone, diacetyl and methylisobutylketone.
- aldehydes such as formaldehyde, acetaldehyde, propionaldehyde and achlorein, methylethylketone, diacetyl and methylisobutylketone.
- Ketones such as acetone, esters such as 1,4-dioxane, 2-methyl-1,3-dioxolane, 1,3-dioxolane, tetrahydrofuran, methyl acetate, ethyl acetate, propyl vinegar, butyl acetate, ethanol, n- Alcohols such as propyl alcohol, isopropyl alcohol and butanol, glycols such as ethylene glycol, propylene glycol, diethylene glycol and triethylene glycol, organic acids such as acetic acid and propionic acid, and aromatic organic substances such as phenols, toluene, xylene and cyclohexane.
- esters such as 1,4-dioxane, 2-methyl-1,3-dioxolane, 1,3-dioxolane, tetrahydrofuran, methyl acetate, ethyl acetate, propyl vinegar, butyl acetate,
- ethers such as diethyl ether and allylglycidyl ether, ditrils such as acrylonitrile, chlorine organic compounds such as dichloromethane, 1,2-dichloroethane, trichloroethylene and epichlorohydrin, N-methyl-2-pyrrolidone, dimethylacetamide. , N, N-dimethylformamide organic compounds and the like can be mentioned as an example.
- the gas to be treated may contain one kind or various kinds thereof.
- Example 1 The following treatment was carried out using the organic solvent recovery system 1 shown in FIG. 1 described above. Activated carbon fibers were used for the first adsorbents 101A, 102A, 103A and the second adsorbents 201A, 202A of the organic solvent concentrator 200.
- the active stage fiber used for the first adsorbents 101A, 102A, 103A was 3.8 kg / tank, and the active stage fiber used for the second adsorbents 201A, 202A was 3.7 kg / tank.
- the gas to be treated a gas to be treated at 25 ° C. containing 26000 ppm of dichloromethane as an organic solvent was used. At an air volume of 5.3 Nm 3 / min, the design concentration of dichloromethane discharged to the outside of the organic solvent recovery system was set to 5 ppm or less.
- the treatment gas was blown into the first treatment tank 101, which is the first adsorption step, at an air volume of 5.3 Nm 3 / min by the organic solvent recovery device 100.
- the first adsorption step outlet gas discharged from the first treatment tank 101 was blown to the first treatment tank 102, which is the second adsorption step, as the second adsorption inlet gas.
- the second adsorption inlet gas was adjusted to 9.5 Nm 3 / min, 45 ° C. with a diluting gas and a desorbing gas.
- the gas treated in the first treatment tank 102 was discharged as the first treatment gas, and was blown to the organic solvent concentrator 200 through the feed flow path L300.
- the first treatment tank 101 was performing the first adsorption step and the first treatment tank 102 was performing the second adsorption step, water vapor was introduced into the first treatment tank 103 to perform the desorption step.
- white smoke was contained for 1 minute immediately after switching the adsorption tank, the temperature of the first treatment gas was 60 ° C., the humidity was 100%, the dichloromethane concentration in the first treatment gas after 1 minute had passed, and the gas temperature was 100 ppm. 45 ° C, humidity 55% Met.
- the first treatment gas discharged from the organic solvent recovery device 100 was aerated from the feed flow path L300 to the second treatment tank 201 to perform an adsorption step, and the second treatment gas (clean gas) was discharged. Further, a part of the second treatment gas was heated from L230 to 130 ° C. by the heater H3 and supplied to the second treatment tank 202 to discharge the desorbed gas. The entire amount of the desorbed gas was supplied to the diluted gas supply channel L170 of the organic solvent recovery device 100 through the return channel L400.
- the process switching of each first treatment tank of the organic solvent concentrating device 200 was performed at the same time as the process switching of each second treatment tank of the organic solvent recovery device 100.
- Switching from the second adsorption step to the desorption step in 103, switching from the adsorption step to the desorption step in the second treatment tank 201, and switching from the desorption step to the adsorption step in the second treatment tank 202 are performed at the same time. rice field. It was done at the same time every time it was switched.
- Example 1 the dichloromethane removal rate was 99%, the amount of cooling water utility used was 0, and the amount of steam used was 4 kg / hr.
- Comparative Example 1 The same gas to be treated as in Example 1 was treated by the organic solvent recovery device 100 and the organic solvent concentrator 200 in the same manner as in Example 1.
- the process switching of each first treatment tank of the organic solvent recovery device 100 is performed 7 minutes after the start of the adsorption process of the organic solvent concentrator 200, and the dichloromethane concentration of the adsorption process outlet gas of the organic solvent concentrator 200 is set. When it reached 5 ppm, it was operated so as to switch each step.
- the white smoke is cooled and dehumidified to 50 ° C. in order to suppress the influence of the white smoke so that the performance is equivalent to that of the first embodiment, that is, the concentration of the outlet gas discharged at the removal rate of 99% is 5 ppm or less. I needed it.
- FIG. 2 shows the dichloromethane concentration and removal rate in the gas to be treated and the amount of the cold water utility used in Example 1 and Comparative Example 1.
- Example 1 the layer of the adsorbent in which the organic solvent is not saturated against the decrease in the adsorption rate due to the adsorption of water due to the inflow of white smoke by simultaneously switching the process in each treatment tank as compared with Comparative Example 1. Since the length can be secured, it is possible to suppress the discharge of the organic solvent in the gas to be treated to the treatment gas due to the influence of the white smoke without cooling the white smoke. In addition, since white smoke enters at the initial stage of the adsorption process of the organic solvent concentrator 200, the time required for the adsorbent to be dried by aeration of the gas to be treated after the white smoke has subsided is maximized, which is necessary for desorption. It shows that it is possible to reduce the amount of energy more than the conventional technology.
- the cooling cost for preventing white smoke and the amount of water vapor required for desorption are conventionally reduced. It can be reduced more than the system. Therefore, it can greatly contribute to the industrial world.
- Organic solvent recovery system 100 Organic solvent recovery device 101 to 103: First treatment tank 101A to 103A: First adsorbent 110: Supply flow path 120: Separator 200: Organic solvent concentrator 201, 202: Second treatment tank 201A, 202A: Second adsorbent 500: Wastewater treatment equipment H1 to H3: Heaters C1, C2: Cooler L110: Gas supply flow path L121 to L123: Connection flow path L130: Confluence flow path L131 to L133: Extraction flow path L140: Water vapor supply flow path L151 to L153: Organic solvent recovery flow path L160: Resupply flow path L170: Diluted gas supply flow path L230: Connection flow path L300: Feed flow path L400: Return flow path V111 to V113, V121 to V123 , V131 to V133, V141 to V143: On-off valve V101 to V106, V201 to V203: On-off damper
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Separation Of Gases By Adsorption (AREA)
- Treating Waste Gases (AREA)
Abstract
Description
槽において連続的に吸着工程を実施した後、特許文献2に記載される第2吸脱着装置によってさらに吸着工程を実施し、第2吸脱着装置から脱着された有機溶剤を含むガスを、処理槽の被処理ガス(原ガス)に戻すシステムを検討した。
吸着した状態(すなわち、第2吸脱着装置の吸着工程がある程度行われた状態)で、白煙が含まれる高温・高湿度の被処理ガスが第2吸脱着装置に供給されると、被処理ガス温度の上昇と第2吸脱着装置への水分の吸着により、有機溶剤の吸着速度が遅くなって、第2吸脱着装置の設計出口濃度以上の有機溶剤ガスが排出されてしまうという問題が起こる。また白煙による水分の吸着は、第2吸脱着装置の脱着工程に要する必要な熱エネルギーの増加をも引き起こす。
1.有機溶剤を吸脱着可能な第1吸着材が充填された第1処理槽を3つ以上と、水蒸気を導入する水蒸気供給流路と、複数の前記第1処理槽を直列多段接続する連結流路と、有機溶剤を含有した被処理ガスを供給する被処理ガス供給流路とを備え、
全ての前記第1処理槽のうち、直列多段接続した複数の前記第1処理槽にて供給された前記被処理ガスに含有された有機溶剤の吸着処理を行い第1処理ガスを排出し、残りの第1処理槽にて吸着された有機溶剤の脱着処理を導入された前記水蒸気を用いて行い、全ての前記第1処理槽は前記吸着処理と前記脱着処理とを切り替えて連続して行う有機溶剤回収装置と、
有機溶剤の吸脱着可能な第2吸着材が充填された第2処理槽と、当該第2処理槽に前記第1処理ガスを供給する送り流路とを備え、当該第1処理ガスに含まれる有機溶剤の吸着処理と脱着処理とを切り替えて連続して行う有機溶剤濃縮装置と、を備え、
前記第1処理槽と前記第2処理槽とにおける脱着処理と吸着処理との切り替えを同時に行うことを特徴とする有機溶剤回収システム。
2.前記連結流路に希釈ガスを供給する希釈ガス供給流路と、前記第2処理槽での脱着処理により排出された脱着ガスを前記希釈ガス供給流路に戻す戻し流路と、を備えたことを特徴とする上記1に記載の有機溶剤回収システム。
3.前記第2理槽での吸着処理により排出された第2処理ガスの一部を前記第2処理槽での脱着処理用に導入する接続流路と、当該接続流路に設けられた加熱手段と、を備える上記1または2に記載の有機溶剤回収システム。
4.前記第2吸着材は、粒状活性炭、活性炭素繊維、またはゼオライトのうち少なくとも1つを含む材料から成ることを特徴とする上記1から3のいずれか1つに記載の有機溶剤回収システム。
5.前記第2吸着材の脱着処理に加熱空気を用いることを特徴とする請求項1から4のいずれか1項に記載の有機溶剤回収システム。
図1は、本発明の一実施形態の有機溶剤回収システム1の構成を概略的に示す図である。有機溶剤回収システム1は、有機溶剤回収装置100と有機溶剤濃縮装置200とを備えている。また、送り流路L300と戻し流路L400とを備えている。
処理ガスである第1処理ガスを取り出すための流路である。取出し流路L131~L133は、各第1処理槽101~103における処理ガス排出口に接続されている。第1取出し流路L131には、開閉弁V131が設けられている。第2取出し流路L132には開閉弁V132が設けられている。第3取出し流路L133には、開閉弁V133が設けられている。各取出し流路L131~L133は互いに合流する合流流路L130を有している。
上記説明した図1に示す有機溶剤回収システム1を用いて以下の処理を実施した。第1吸着材101A,102A,103Aと、有機溶剤濃縮装置200の第2吸着材201A,202Aには、活性炭素繊維を使用した。第1吸着材101A,102A,103Aに使用した活性段素繊維は3.8Kg/槽、第2吸着材201A,202Aに使用した活性段素繊維は3.7Kg/槽であった。被処理ガスの一例として、有機溶剤としてジクロロメタンを26000ppm含有する25℃の被処理ガスを用いた。風量5.3Nm3/minにて、有機溶剤回収システム系外へ排出するジクロロメタンの設計濃度は5ppm以下とした。
であった。
ここで、有機溶剤濃縮装置200の各第1処理槽の工程切替は、有機溶剤回収装置100の各第2処理槽の工程切替と同時に行った。具体例を用いて説明すると、第1処理槽101での脱着工程から第1吸着工程への切替、第1処理槽102での第1吸着工程から第2吸着工程への切替、第1処理槽103での第2吸着工程からの脱着工程への切替、第2処理槽201での吸着工程から脱着工程への切替、第2処理槽202での脱着工程から吸着工程への切替、を同時に行った。切替の度に同時に行った。
実施例1と同じ被処理ガスを、実施例1と同様に有機溶剤回収装置100及び有機溶剤濃縮装置200にて処理した。比較例1では、有機溶剤回収装置100の各第1処理槽の工程切替は、有機溶剤濃縮装置200の吸着工程開始から7分後とし、有機溶剤濃縮装置200は吸着工程出口ガスのジクロロメタン濃度が5ppmに達した時点で、各工程を切り替えるように運転した。比較例1では、実施例1と同等の性能、すなわち除去率99%で排出される出口ガス濃度5ppm以下となるように白煙の影響を抑えるために、白煙を50℃まで冷却・除湿する必要があった。
100:有機溶剤回収装置
101~103:第1処理槽
101A~103A:第1吸着材
110:供給流路
120:セパレータ
200:有機溶剤濃縮装置
201、202:第2処理槽
201A、202A:第2吸着材
500:排水処理設備
H1~H3:ヒータ
C1、C2:クーラ
L110:被処理ガス供給流路
L121~L123:連結流路
L130:合流流路
L131~L133:取出し流路
L140:水蒸気供給流路
L151~L153:有機溶剤回収流路
L160:再供給流路
L170:希釈ガス供給流路
L230:接続流路
L300:送り流路
L400:戻し流路
V111~V113、V121~V123、V131~V133、V141~V143:開閉弁
V101~V106,V201~V203:開閉ダンパー
Claims (5)
- 有機溶剤を吸脱着可能な第1吸着材が充填された第1処理槽を3つ以上と、水蒸気を導入する水蒸気供給流路と、複数の前記第1処理槽を直列多段接続する連結流路と、有機溶剤を含有した被処理ガスを供給する被処理ガス供給流路とを備え、
全ての前記第1処理槽のうち、直列多段接続した複数の前記第1処理槽にて供給された前記被処理ガスに含有された有機溶剤の吸着処理を行い第1処理ガスを排出し、残りの第1処理槽にて吸着された有機溶剤の脱着処理を導入された前記水蒸気を用いて行い、全ての前記第1処理槽は前記吸着処理と前記脱着処理とを切り替えて連続して行う有機溶剤回収装置と、
有機溶剤の吸脱着可能な第2吸着材が充填された第2処理槽と、当該第2処理槽に前記第1処理ガスを供給する送り流路とを備え、当該第1処理ガスに含まれる有機溶剤の吸着処理と脱着処理とを切り替えて連続して行う有機溶剤濃縮装置と、を備え、
前記第1処理槽と前記第2処理槽とにおける脱着処理と吸着処理との切り替えを同時に行うことを特徴とする有機溶剤回収システム。 - 前記連結流路に希釈ガスを供給する希釈ガス供給流路と、
前記第2処理槽での脱着処理により排出された脱着ガスを前記希釈ガス供給流路に戻す戻し流路と、を備えたことを特徴とする請求項1に記載の有機溶剤回収システム。 - 前記第2理槽での吸着処理により排出された第2処理ガスの一部を前記第2処理槽での脱着処理用に導入する接続流路と、当該接続流路に設けられた加熱手段と、を備える請求項1または2に記載の有機溶剤回収システム。
- 前記第2吸着材は、粒状活性炭、活性炭素繊維、またはゼオライトのうち少なくとも1つを含む材料から成ることを特徴とする請求項1から3のいずれか1項に記載の有機溶剤
回収システム。 - 前記第2吸着材の脱着に加熱空気を用いることを特徴とする請求項1から4のいずれか1項に記載の有機溶剤回収システム。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202180061932.5A CN116322942A (zh) | 2020-09-11 | 2021-09-03 | 有机溶剂回收系统 |
US18/025,068 US20230330587A1 (en) | 2020-09-11 | 2021-09-03 | Organic solvent recovery system |
KR1020237011453A KR20230066385A (ko) | 2020-09-11 | 2021-09-03 | 유기 용제 회수 시스템 |
JP2022519840A JPWO2022054733A1 (ja) | 2020-09-11 | 2021-09-03 | |
EP21866692.3A EP4212231A1 (en) | 2020-09-11 | 2021-09-03 | Organic solvent recovery system |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2020-152927 | 2020-09-11 | ||
JP2020152927 | 2020-09-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2022054733A1 true WO2022054733A1 (ja) | 2022-03-17 |
Family
ID=80631850
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2021/032561 WO2022054733A1 (ja) | 2020-09-11 | 2021-09-03 | 有機溶剤回収システム |
Country Status (7)
Country | Link |
---|---|
US (1) | US20230330587A1 (ja) |
EP (1) | EP4212231A1 (ja) |
JP (1) | JPWO2022054733A1 (ja) |
KR (1) | KR20230066385A (ja) |
CN (1) | CN116322942A (ja) |
TW (1) | TW202216273A (ja) |
WO (1) | WO2022054733A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023190214A1 (ja) * | 2022-03-31 | 2023-10-05 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
WO2024019007A1 (ja) * | 2022-07-20 | 2024-01-25 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
WO2024019008A1 (ja) * | 2022-07-20 | 2024-01-25 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58168877A (ja) * | 1982-03-31 | 1983-10-05 | 日本酸素株式会社 | ガス精製方法 |
JP2006083311A (ja) * | 2004-09-17 | 2006-03-30 | Ebara Corp | 消化ガスの精製装置及びその方法 |
JP2008133327A (ja) * | 2006-11-27 | 2008-06-12 | Nippon Steel Engineering Co Ltd | ガス化ガスの浄化装置及び浄化方法 |
JP2012183462A (ja) * | 2011-03-04 | 2012-09-27 | Toho Kako Kensetsu Kk | 有機溶剤の除去方法及び除去装置 |
JP2014147863A (ja) | 2013-01-31 | 2014-08-21 | Toyobo Co Ltd | ガス処理装置およびガス処理方法 |
JP2014240052A (ja) | 2013-06-12 | 2014-12-25 | 東洋紡株式会社 | 有機溶剤含有ガス処理システム |
JP2015000381A (ja) * | 2013-06-17 | 2015-01-05 | 東洋紡株式会社 | 有機溶剤回収システム |
WO2018101255A1 (ja) * | 2016-12-01 | 2018-06-07 | 東洋紡株式会社 | 有機溶剤回収システム及び有機溶剤回収方法 |
WO2020158442A1 (ja) * | 2019-01-31 | 2020-08-06 | 東洋紡株式会社 | 有機溶剤回収システム |
-
2021
- 2021-09-03 EP EP21866692.3A patent/EP4212231A1/en active Pending
- 2021-09-03 KR KR1020237011453A patent/KR20230066385A/ko active Search and Examination
- 2021-09-03 US US18/025,068 patent/US20230330587A1/en active Pending
- 2021-09-03 CN CN202180061932.5A patent/CN116322942A/zh active Pending
- 2021-09-03 WO PCT/JP2021/032561 patent/WO2022054733A1/ja unknown
- 2021-09-03 JP JP2022519840A patent/JPWO2022054733A1/ja active Pending
- 2021-09-10 TW TW110133676A patent/TW202216273A/zh unknown
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS58168877A (ja) * | 1982-03-31 | 1983-10-05 | 日本酸素株式会社 | ガス精製方法 |
JP2006083311A (ja) * | 2004-09-17 | 2006-03-30 | Ebara Corp | 消化ガスの精製装置及びその方法 |
JP2008133327A (ja) * | 2006-11-27 | 2008-06-12 | Nippon Steel Engineering Co Ltd | ガス化ガスの浄化装置及び浄化方法 |
JP2012183462A (ja) * | 2011-03-04 | 2012-09-27 | Toho Kako Kensetsu Kk | 有機溶剤の除去方法及び除去装置 |
JP2014147863A (ja) | 2013-01-31 | 2014-08-21 | Toyobo Co Ltd | ガス処理装置およびガス処理方法 |
JP2014240052A (ja) | 2013-06-12 | 2014-12-25 | 東洋紡株式会社 | 有機溶剤含有ガス処理システム |
JP2015000381A (ja) * | 2013-06-17 | 2015-01-05 | 東洋紡株式会社 | 有機溶剤回収システム |
WO2018101255A1 (ja) * | 2016-12-01 | 2018-06-07 | 東洋紡株式会社 | 有機溶剤回収システム及び有機溶剤回収方法 |
WO2020158442A1 (ja) * | 2019-01-31 | 2020-08-06 | 東洋紡株式会社 | 有機溶剤回収システム |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2023190214A1 (ja) * | 2022-03-31 | 2023-10-05 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
WO2024019007A1 (ja) * | 2022-07-20 | 2024-01-25 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
WO2024019008A1 (ja) * | 2022-07-20 | 2024-01-25 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
JP7435933B1 (ja) | 2022-07-20 | 2024-02-21 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
JP7435934B1 (ja) | 2022-07-20 | 2024-02-21 | 東洋紡エムシー株式会社 | 有機溶剤回収システム |
Also Published As
Publication number | Publication date |
---|---|
KR20230066385A (ko) | 2023-05-15 |
JPWO2022054733A1 (ja) | 2022-03-17 |
TW202216273A (zh) | 2022-05-01 |
US20230330587A1 (en) | 2023-10-19 |
CN116322942A (zh) | 2023-06-23 |
EP4212231A1 (en) | 2023-07-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2022054733A1 (ja) | 有機溶剤回収システム | |
JP7380571B2 (ja) | 有機溶剤回収システム | |
CN102489106B (zh) | 一种采用二次吸附对废气进行循环回收的方法 | |
CN103480233B (zh) | 多级吸附回收有机废气装置及方法 | |
JP5588163B2 (ja) | 溶剤回収装置 | |
JP2005000862A (ja) | 吸着装置及び吸着方法 | |
JP6946730B2 (ja) | 有機溶剤回収システム | |
CN206911061U (zh) | 低浓度有机废气回收处理系统 | |
JP6229267B2 (ja) | ガス処理装置およびガス処理方法 | |
JP6880602B2 (ja) | 有機溶剤回収システム | |
WO2024203539A1 (ja) | 有機溶剤回収システム | |
WO2024070943A1 (ja) | 有機溶剤回収システム | |
JP2013132582A (ja) | 有機溶剤含有ガス処理システム | |
JP2012139670A (ja) | 有機溶剤回収システム | |
CN211098274U (zh) | 一种有机废气两级吸附回收处理系统 | |
TW202432225A (zh) | 有機溶劑回收系統 | |
CN112588075A (zh) | 一种具有深度脱附功能有机废气净化回收装置及其方法 | |
JP7544308B1 (ja) | 有機溶剤回収システム、および有機溶剤処理システム | |
JP2011092870A (ja) | 有機溶剤回収システム | |
JP2011092871A (ja) | 有機溶剤回収システム | |
TW202432227A (zh) | 有機溶劑回收系統及有機溶劑處理系統 | |
WO2023190214A1 (ja) | 有機溶剤回収システム | |
JP2971127B2 (ja) | ドライクリーニング方法 | |
CN109012024A (zh) | 一种高效节能的高沸点有机废气处理系统 | |
JP7435934B1 (ja) | 有機溶剤回収システム |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
ENP | Entry into the national phase |
Ref document number: 2022519840 Country of ref document: JP Kind code of ref document: A |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 21866692 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 20237011453 Country of ref document: KR Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2021866692 Country of ref document: EP Effective date: 20230411 |