WO2021236720A1 - Capteur de turbidité à angle solide étendu - Google Patents

Capteur de turbidité à angle solide étendu Download PDF

Info

Publication number
WO2021236720A1
WO2021236720A1 PCT/US2021/033083 US2021033083W WO2021236720A1 WO 2021236720 A1 WO2021236720 A1 WO 2021236720A1 US 2021033083 W US2021033083 W US 2021033083W WO 2021236720 A1 WO2021236720 A1 WO 2021236720A1
Authority
WO
WIPO (PCT)
Prior art keywords
sensor array
linear
array
turbidity
linear sensor
Prior art date
Application number
PCT/US2021/033083
Other languages
English (en)
Inventor
Kevin Flanagan
Ronald METZGER
Kyle LOGES
Original Assignee
Ysi, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ysi, Inc. filed Critical Ysi, Inc.
Priority to JP2022571196A priority Critical patent/JP7451767B2/ja
Priority to BR112022023418A priority patent/BR112022023418A2/pt
Priority to AU2021276375A priority patent/AU2021276375B2/en
Priority to CN202180036389.3A priority patent/CN115667886A/zh
Priority to CA3178563A priority patent/CA3178563C/fr
Priority to KR1020227040421A priority patent/KR20230011951A/ko
Priority to EP21807774.1A priority patent/EP4153970A1/fr
Publication of WO2021236720A1 publication Critical patent/WO2021236720A1/fr

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/18Water
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • G01N21/645Specially adapted constructive features of fluorimeters
    • G01N21/6456Spatial resolved fluorescence measurements; Imaging
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • G01N15/06Investigating concentration of particle suspensions
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N15/00Investigating characteristics of particles; Investigating permeability, pore-volume or surface-area of porous materials
    • G01N15/06Investigating concentration of particle suspensions
    • G01N15/075Investigating concentration of particle suspensions by optical means
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/47Scattering, i.e. diffuse reflection
    • G01N21/4785Standardising light scatter apparatus; Standards therefor
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/47Scattering, i.e. diffuse reflection
    • G01N21/49Scattering, i.e. diffuse reflection within a body or fluid
    • G01N21/53Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/47Scattering, i.e. diffuse reflection
    • G01N21/49Scattering, i.e. diffuse reflection within a body or fluid
    • G01N21/53Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke
    • G01N21/532Scattering, i.e. diffuse reflection within a body or fluid within a flowing fluid, e.g. smoke with measurement of scattering and transmission
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/75Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
    • G01N21/77Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
    • G01N21/82Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a precipitate or turbidity
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/02Food
    • G01N33/08Eggs, e.g. by candling
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04NPICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N25/00Circuitry of solid-state image sensors [SSIS]; Control thereof
    • H04N25/40Extracting pixel data from image sensors by controlling scanning circuits, e.g. by modifying the number of pixels sampled or to be sampled
    • H04N25/46Extracting pixel data from image sensors by controlling scanning circuits, e.g. by modifying the number of pixels sampled or to be sampled by combining or binning pixels
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/47Scattering, i.e. diffuse reflection
    • G01N2021/4704Angular selective
    • G01N2021/4709Backscatter
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • G01N21/6428Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
    • G01N2021/6439Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes" with indicators, stains, dyes, tags, labels, marks
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • G01N21/645Specially adapted constructive features of fluorimeters
    • G01N2021/6463Optics
    • G01N2021/6473In-line geometry
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/63Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
    • G01N21/64Fluorescence; Phosphorescence
    • G01N2021/6491Measuring fluorescence and transmission; Correcting inner filter effect
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/061Sources
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/063Illuminating optical parts
    • G01N2201/0633Directed, collimated illumination
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/063Illuminating optical parts
    • G01N2201/0636Reflectors
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/12Circuits of general importance; Signal processing
    • G01N2201/126Microprocessor processing
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/12Circuits of general importance; Signal processing
    • G01N2201/127Calibration; base line adjustment; drift compensation
    • G01N2201/12746Calibration values determination
    • G01N2201/12761Precalibration, e.g. for a given series of reagents
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/12Circuits of general importance; Signal processing
    • G01N2201/127Calibration; base line adjustment; drift compensation
    • G01N2201/12792Compensating own radiation in apparatus

Definitions

  • This invention relates to a sensor for measuring the quality of water; and more particularly, to a turbidity sensor for measuring the quality of water.
  • turbidity sensing techniques suffer from poor sensitivity (especially field-deployable sensors) stemming from poor/inefficient capture of scattered signal (solid angle).
  • Existing turbidity sensors typically employ a single excitation light source and a single, or point-like emission receiver, utilizing a photosensitive element. Regardless of the particular photosensitive element or excitation light source used, the current turbidity sensors known in the art are not opto-mechanically configured for efficient capture of solid angle resulting in compromised limit of detection for turbidity.
  • the difficulty with measuring scattering-based signals is the spatial/directional nature of randomly scattered optical radiation.
  • the spatial distribution of scattered radiation of a single turbid particle is well approximated by a sphere, resulting in 4p [steradians] solid angle of scattered radiation (See Fig. 1).
  • To optimally capture such a turbidity signal would require a photosensitive area that closely matches the radiation pattern, i.e., a photosensitive area in the shape of a spherical shell. See Fig. 1 . In view of this, there is a need in the art for a better turbidity sensor.
  • the turbidity measurement system includes a sample assembly that contains a plurality of samples, a light source that illuminates the sample assembly, and a light detection system that includes a two-dimensional light-sensitive array.
  • the light-sensitive array is simultaneously exposed to light transmitted through each of the samples in the sample assembly.
  • the exposure is analyzed to determine a mean transmitted light intensity for each sample and to calculate a turbidity value for each sample based on its mean transmitted light intensity.
  • Multiple exposures may be taken during a measurement period so as to obtain time-resolved turbidity measurements of the samples.
  • the temperature of the samples may be varied during the measurement period so as to measure turbidity as a function of temperature.
  • the present invention aims to greatly enhance the captured solid angle thereby significantly enhancing the sensitivity of turbidity measurements.
  • the sensor under consideration incorporates (insofar that is practicable in a field-rugged sensor) many of the features exhibited in the idealized long-cylinder geometry.
  • the present invention employs a linear photodiode array (the proposed approach is not limited to photodiode technology, e.g., a linear CCD or CMOS array could be used as well).
  • the linear array allows ample room for biofouling counter measures such as motorized wiping.
  • linear sensor arrays are currently available as relatively inexpensive commercial-of-the-shelf (COTS) components.
  • COTS commercial-of-the-shelf
  • the key to this invention pertains specifically to the opto-mechanical configuration which utilizes a wide, linear array along the length of the quasi- collimated light source for enhanced signal capture. Additionally, the design allows for the capture of back scattered radiation — all in a single embodiment
  • the present design is compatible with non-intensity-based determinations of turbidity. These measurements are spatially dependent, the main idea being that an optical signal will undergo an attenuation across the linear array, following Beer’s law, thereby creating a “spatial gradient”. This spatial gradient contains information regarding the concentration of the turbidity.
  • the non-intensity-based measurement is immune to “drift” of the excitation source.
  • the spatial gradient is unaffected by moderate changes in the intensity of the excitation source, e.g., LED intensity degradation through the course of use, or a change in optical power due to thermal effects.
  • the “spatial gradient” method according to the present invention enables real time, inner filter effect (IFE) correction, which greatly enhances high-concentration sensing range. .
  • IFE inner filter effect
  • a known technique of inner filter correction involves post processing via lab analysis after a field deployment.
  • the “spatial gradient” method according to the present invention also allows for certain types of interference correction not achievable with amplitude- based techniques known in the art.
  • the above “spatial gradient” method requires that each optical element in the array be individually addressable.
  • there is a possible variant of the design that involves connecting all of the linear array elements in a parallel configuration which would preclude the possibility of individual addressability.
  • such a design variant could be modified to include a transmission photodiode (located at the end of the array, opposite of the source) which would restore the sensor’s ability to perform drift correction and IFE correction.
  • the present invention may include, or take the form of, apparatus featuring a signal processor or processing module configured to: receive signaling containing information about light reflected off suspended matter in a liquid and sensed by a linear sensor array having rows and columns of optical elements; and determine corresponding signaling containing information about a concentration of parameter of the liquid, based upon the signaling received
  • the apparatus may include one or more of the following additional features:
  • the parameter may include turbidity of the liquid.
  • the apparatus may include the linear sensor array.
  • the linear sensor array may include a linear photodiode array.
  • the linear sensor array may include a linear CCD array.
  • the linear sensor array may include a linear CMOS array.
  • the linear sensor array may include a closed cylinder sensor array having a three-dimensional cylindrical array of the rows and columns of the optical elements.
  • the apparatus may be a turbidity sensor.
  • the apparatus may include a quasi-collimated light source having a length and being configured to provide the light, including quasi-collimated light, along a corresponding length of the linear sensor array.
  • the signal processor or processing module may be configured to determine the parameter based upon an attenuation of an optical signal sensed across the linear sensor array.
  • the linear sensor array may include a two-dimensional array of optical elements that are individually addressable.
  • the signal processor or processing module may be configured to determine the turbidity based upon a spatial gradient of an optical signal sensed across the linear sensor array that contains information about the concentration of the turbidity.
  • the optical elements may be individually addressable by the signal processor or processing module.
  • Either the rows or the columns of the optical elements may be connected in parallel and addressable by the signal processor or processing module; the apparatus may include a transmission photodiode located at an end of the linear sensor array, opposite the light source, configured to respond to the light reflected off the suspended matter and provide transmission photodiode signaling containing information about the same; and the signal processor or processing module may be configured to receive the photodiode signaling and correct the corresponding signaling for drift or the inner filter effect.
  • the present invention may include a turbidity sensor featuring a quasi-collimated light source, a linear sensor array and a signal processor or processing module.
  • the quasi-collimated light source has a length and may be configured to provide quasi-collimated light to a liquid sample.
  • the linear sensor array may include rows and columns of optical elements and be configured to sense light reflected off suspended matter in the liquid sample along the length of the quasi-collimated light source and provide signaling containing information about the light reflected off the suspended matter.
  • the signal processor or processing module may be configured to: receive the signaling; and determine corresponding signaling containing information about a concentration of turbidity of the liquid, based upon the signaling received
  • the turbidity sensor may also include one or more of the features set forth above.
  • the present invention may include a method, featuring: receiving, with a signal processor or processing module, signaling containing information about light reflected off suspended matter in a liquid and sensed by a linear sensor array having rows and columns of optical elements; and determining, with the signal processor or processing module, corresponding signaling containing information about a concentration of a parameter of the liquid, based upon the signaling received
  • the method may also include one or more of the features set forth above.
  • Computer-readable Storage Medium According to some embodiments of the present invention, the present invention may also take the form of a computer-readable storage medium having computer-executable components for performing the steps of the aforementioned method.
  • the computer-readable storage medium may also include one or more of the features set forth above.
  • the present invention offers distinct advantages over the current known techniques in the prior art, as follows:
  • a linear sensor array provides a much larger overall active area to capture scattered rays. More importantly, the active area is larger in the dimension that matters most, along the direction of the quasi-collimated excitation source. Additionally, a wider linear array is preferred over a thin one for reasons stated above, increased active area. However, there is a limit of diminishing return regarding the width, i.e., an array width that does not roughly match the diameter of the excitation beam appears non-ideal.
  • the present invention enables measurement of backscattered radiation (in addition to the radially emitted side scatter) - all in a single sensing embodiment.
  • Figure 1 is a diagram of a spatial distribution of scattered radiation of a single turbid particle that is approximated by a sphere, resulting in 4p [steradians] solid angle of scattered radiation that is known in the art.
  • Figure 2A is a block diagram of apparatus, including a turbidity sensor, according to some embodiments of the present invention.
  • Figure 2B is a block diagram of a linear sensor array having rows and columns of optical elements, according to some embodiments of the present invention.
  • Figure 3 is a three dimension perspective view of a quasi-collimated light source that provides a quasi-collimated light in relation to a linear sensor array, according to some embodiments of the present invention.
  • Figure 4 is a side view of that shown in Figure 3 showing captured backscatter radiation by the linear sensor array, according to some embodiments of the present invention.
  • Figure 5 is a graph of relative sensor response versus relative concentration, e.g., showing a sensitivity comparison of the assignee's contemporary EXO turbidity sensor (solid line with dots) vs. the linear array turbidity sensor (solid line). Note that the graph shows simulated data based on a physical model of the design according to the present invention.
  • Figure 6A is an isometric view showing of a three-dimensional rendering of solid angle capture for an idealized long-cylinder shell geometry, e.g., such as a 3-D cylindrical linear sensor array, according to the present invention.
  • Figure 6B is a cross-sectional view showing of the idealized long-cylinder shell geometry, e.g., such as the 3-D cylindrical linear sensor array.
  • FIG. 2 shows apparatus 10, including a turbidity sensor, according to the present invention having a quasi-collimated light source 20, a linear sensor array 30, and a signal processor or processing module 40.
  • the signal processor or processing module 40 may be configured to receive signaling containing information about light Lr reflected off suspended matter in a liquid and sensed by the linear sensor array 30 having rows and columns of optical elements (r1 , d ; r1 , c2; r1 , c3; r1 , c4; r1 , c5; r1 , c6; r1 , c7; r1 , c8; r1 , cn; r2, d ; r2, c2; r2, c3; r2, c4; r2, c5; r2, c6; r2, c7; r2, c8; r2, cn; r3, d ; r3, c2; r3, c3; r3, c4; r3, c5; r3, c6; r3, c7; r3, c8; r3, cn;
  • the parameter may include the concentration of turbidity in the liquid
  • the apparatus may be, or take the form of, a turbidity sensor.
  • the scope of the invention is not intended to be limited to any particular type or kind of parameter being sensed in a liquid either now known or later developed in the future.
  • the Linear Sensor Array 30 may include the linear sensor array 30, e.g., such as a linear photodiode array, a linear charge-coupled device (CCD) array, a linear CMOS array.
  • the linear sensor array 30 may include a two- dimensional array of rows and columns of optical elements, e.g., like that shown in Figure 2B, that are individually addressable. Linear sensor arrays are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now known or later developed in the future.
  • linear sensors arrays are disclosed in the following US Patent nos. 9,020,202; 8,022,349; 7,956,341 ; 7,040,538; 5,252,818; and 4,193,057, which are all hereby incorporated by reference.
  • the apparatus 10 may include the source 20 configured to provide the light Lc, including quasi-collimated light, along a corresponding length of the linear sensor array 30, e.g., as shown in Figures 2 and 3, e.g., through a liquid sample arranged in relation to the light source 20 and the linear sensor array 30 so as to reflect the light Lr off suspended matter in the liquid sample being monitored or tested onto the linear sensor array 30.
  • the light Lr may be reflected radially (Fig. 3) and backwards (Fig. 4), i.e., backscattered reflected light or radiation.
  • FIG. 4 shows captured backscatter radiation by the linear sensor array 30, where backscattered radiation is understood to be light reflected of the suspended matter in the liquid sample that travels backwards, consistent with that shown.
  • the Signal Processor or Processing Module 40 may be configured to determine the parameter, including turbidity, based upon an attenuation of an optical signal sensed across the linear sensor array, including its length and width.
  • Techniques for sensing the attenuation of the optical signal e.g., in relation to the concentration of turbidity in the liquid, are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now known or later developed in the future.
  • the signal processor or processing module 40 may be configured to determine the concentration of turbidity based upon a spatial gradient of the optical signal sensed across the linear sensor array.
  • concentration of turbidity based upon a spatial gradient of the optical signal sensed across the linear sensor array.
  • techniques for determining the concentration of turbidity in a liquid based upon a spatial gradient of an optical signal are known in the art, e.g., consistent with that set forth herein re PCT/US2008/059575, which is hereby incorporated by reference in its entirety, and the scope of the invention is not intended to be limited to any particular type or kind of technique either now known or later developed in the future.
  • either the rows or the columns of the optical elements may be connected in parallel and addressable by the signal processor or processing module 40; the apparatus 10 may include a transmission photodiode 30a located at an end of the linear sensor array 30, opposite the light source 20, configured to respond to the light L reflected off the suspended matter and provide transmission photodiode signaling containing information about the same; and the signal processor or processing module 40 may be configured to receive the photodiode signaling and correct the corresponding signaling for drift or the inner filter effect.
  • the functionality of the signal processor or processing module 40 may be implemented using hardware, software, firmware, or a combination thereof.
  • the signal processor 40 would include one or more microprocessor-based architectures having, e. g., at least one signal processor or microprocessor.
  • One skilled in the art would be able to program with suitable program code such a microcontroller-based, or microprocessor-based, implementation to perform the signal processing functionality disclosed herein without undue experimentation.
  • the apparatus 10 may also include, e.g., other signal processor circuits or components generally indicated 50, including random access memory or memory module (RAM) and/or read only memory (ROM), input/output devices and control, and data and address buses connecting the same, and/or at least one input processor and at least one output processor, e.g., which would be appreciate by one skilled in the art.
  • RAM random access memory or memory module
  • ROM read only memory
  • the signal processor may include, or take the form of, some combination of a signal processor and at least one memory including a computer program code, where the signal processor and at least one memory are configured to cause the system to implement the functionality of the present invention, e.g., to respond to signaling received and to determine the corresponding signaling, based upon the signaling received.
  • Figure 6A and 6B The 3D Cylindrical Linear Sensor Array 60
  • the apparatus 10 may include a closed cylinder sensor array 60 having a three-dimensional cylindrical array of the rows and columns of the optical elements and a length L, e.g., as shown in Figure 6A.
  • the 3-D cylindrical linear sensor array 32 configured to capture light reflected off the suspended matter in the liquid along its length L and 360 degrees radially about its longitudinal axis.
  • IFE Inner Filter Effect
  • the IFE is a fluorescence spectroscopy phenomenon, e.g., where there is a decrease in fluorescence emission seen in concentrated solutions due to the absorption of exciting light by the fluorophore that is close to the incident beam and which significantly diminishes light that reaches the sample further away from it.
  • techniques for correcting for the IFE are known in the art, and the scope of the invention is not intended to be limited to any particular type or kind thereof either now known or later developed in the future.
  • the present invention has applications, e.g., in the basic parameter of water quality monitoring for freshwater applications (e.g., where turbidity is one of the “big five”), as well as drinking water monitoring.

Landscapes

  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Analytical Chemistry (AREA)
  • Pathology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plasma & Fusion (AREA)
  • Signal Processing (AREA)
  • Multimedia (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Centrifugal Separators (AREA)
  • Geophysics And Detection Of Objects (AREA)
  • Vehicle Body Suspensions (AREA)
  • Investigating Or Analysing Biological Materials (AREA)
  • Molecular Biology (AREA)
  • Optics & Photonics (AREA)

Abstract

La présente invention concerne un capteur de turbidité qui comprend un processeur de signal ou un module de traitement configuré : pour recevoir une signalisation contenant des informations concernant la lumière réfléchie par la matière en suspension dans un liquide et détectée par un réseau linéaire de capteurs ayant des rangées et des colonnes d'éléments optiques ; et pour déterminer une signalisation correspondante contenant des informations concernant une concentration de turbidité du liquide, sur la base de la signalisation reçue.
PCT/US2021/033083 2020-05-20 2021-05-19 Capteur de turbidité à angle solide étendu WO2021236720A1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP2022571196A JP7451767B2 (ja) 2020-05-20 2021-05-19 拡張した立体角の濁度センサ
BR112022023418A BR112022023418A2 (pt) 2020-05-20 2021-05-19 Sensor de turbidez de ângulo sólido estendido
AU2021276375A AU2021276375B2 (en) 2020-05-20 2021-05-19 Extended solid angle turbidity sensor
CN202180036389.3A CN115667886A (zh) 2020-05-20 2021-05-19 扩展式立体角浊度传感器
CA3178563A CA3178563C (fr) 2020-05-20 2021-05-19 Capteur de turbidite a angle solide etendu
KR1020227040421A KR20230011951A (ko) 2020-05-20 2021-05-19 확장된 입체각 탁도 센서
EP21807774.1A EP4153970A1 (fr) 2020-05-20 2021-05-19 Capteur de turbidité à angle solide étendu

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US202063027587P 2020-05-20 2020-05-20
US63/027,587 2020-05-20
US202063028013P 2020-05-21 2020-05-21
US63/028,013 2020-05-21
US202063028723P 2020-05-22 2020-05-22
US63/028,723 2020-05-22

Publications (1)

Publication Number Publication Date
WO2021236720A1 true WO2021236720A1 (fr) 2021-11-25

Family

ID=78608840

Family Applications (3)

Application Number Title Priority Date Filing Date
PCT/US2021/033090 WO2021236726A1 (fr) 2020-05-20 2021-05-19 Fluorimètre à balayage en fréquence
PCT/US2021/033100 WO2021236735A1 (fr) 2020-05-20 2021-05-19 Fluorimètre à gradient spatial
PCT/US2021/033083 WO2021236720A1 (fr) 2020-05-20 2021-05-19 Capteur de turbidité à angle solide étendu

Family Applications Before (2)

Application Number Title Priority Date Filing Date
PCT/US2021/033090 WO2021236726A1 (fr) 2020-05-20 2021-05-19 Fluorimètre à balayage en fréquence
PCT/US2021/033100 WO2021236735A1 (fr) 2020-05-20 2021-05-19 Fluorimètre à gradient spatial

Country Status (9)

Country Link
US (3) US11860096B2 (fr)
EP (3) EP4153970A1 (fr)
JP (3) JP2023527783A (fr)
KR (3) KR20230011951A (fr)
CN (3) CN115667886A (fr)
AU (2) AU2021276375B2 (fr)
BR (2) BR112022023420A2 (fr)
CA (2) CA3178563C (fr)
WO (3) WO2021236726A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2021276375B2 (en) * 2020-05-20 2023-11-02 Ysi, Inc. Extended solid angle turbidity sensor

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050219526A1 (en) * 2003-01-17 2005-10-06 Hong Peng Method and apparatus for monitoring biological substance
US20090230288A1 (en) * 2006-11-04 2009-09-17 Leopold Kostal Gmbh & Co. Kg Method for the operation of a photoelectric sensor array
US20170241893A1 (en) * 2016-02-19 2017-08-24 Research Triangle Institute Devices, systems and methods for detecting particles
US20180251713A1 (en) * 2017-03-01 2018-09-06 Fluidion Sas Field-deployable Multiplexed Sampling and Monitoring Device and Bacterial Contamination Measurement Method

Family Cites Families (106)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4160914A (en) * 1977-12-16 1979-07-10 Monitek, Inc. Apparatus for measuring of particulate scattering in fluids
US4193057A (en) 1978-03-20 1980-03-11 Bunker Ramo Corporation Automatic deployment of horizontal linear sensor array
WO1990009637A1 (fr) * 1989-02-13 1990-08-23 Research Corporation Technologies, Inc. Procede et dispositif de saisie en parallele de frequences en fluorimetrie frequentielle
US5059811A (en) * 1990-08-30 1991-10-22 Great Lakes Instruments, Inc. Turbidimeter having a baffle assembly for removing entrained gas
US5252818A (en) 1991-08-22 1993-10-12 Vision Ten, Inc. Method and apparatus for improved scanner accuracy using a linear sensor array
US5436476A (en) * 1993-04-14 1995-07-25 Texas Instruments Incorporated CCD image sensor with active transistor pixel
PT101290B (pt) 1993-06-18 2000-10-31 Fernandes Jose Guilherme Da Cu Fluorometro para medicao da concentracao de fluoroforos de localizacao ocular
US5486693A (en) 1994-02-17 1996-01-23 Thermedics Detection Inc. Detection of turbid contaminants in containers by detecting scattered radiant energy
US6710879B1 (en) * 1997-05-05 2004-03-23 Chemometec A/S Method and a system for determination of particles in a liquid sample
ZA984976B (en) 1997-06-11 1999-04-19 Nalco Chemical Co Solid-state fluorometer and methods of use therefore
US6070093A (en) * 1997-12-02 2000-05-30 Abbott Laboratories Multiplex sensor and method of use
KR20010040510A (ko) * 1998-02-02 2001-05-15 유니액스 코포레이션 전환가능한 감광성을 가진 유기 다이오드
WO1999058953A1 (fr) 1998-05-08 1999-11-18 Sequoia Scientific, Inc. Dispositif de mesure du volume et de la granulometrie moyenne de particules dans l'eau
AU1429401A (en) 1999-07-02 2001-02-05 Conceptual Mindworks, Inc. Organic semiconductor recognition complex and system
US6852986B1 (en) 1999-11-12 2005-02-08 E. I. Du Pont De Nemours And Company Fluorometer with low heat-generating light source
US7875442B2 (en) * 2000-03-24 2011-01-25 Eppendorf Array Technologies Identification and quantification of a plurality of biological (micro)organisms or their components
US6573991B1 (en) * 2000-04-26 2003-06-03 Martin Paul Debreczeny Self-compensating radiation sensor with wide dynamic range
US6369894B1 (en) 2000-05-01 2002-04-09 Nalco Chemical Company Modular fluorometer
WO2002068932A2 (fr) 2001-02-23 2002-09-06 Genicon Sciences Corporation Procedes permettant d'etendre l'echelle dynamique dans des dosages d'analytes
US7046347B1 (en) * 2001-03-30 2006-05-16 Amend John R Instrument with colorimeter and sensor inputs for interfacing with a computer
US7183050B2 (en) 2001-04-18 2007-02-27 Krull Ulrich J Gradient resolved information platform
FR2824139B1 (fr) * 2001-04-27 2003-05-30 Commissariat Energie Atomique Dispositif de mesure de luminescence a elimintation d'effet de prefiltre
US6929730B2 (en) 2001-05-01 2005-08-16 Cheng Sheng Lee Two dimensional microfluidic gene scanner
KR20040018378A (ko) * 2001-05-23 2004-03-03 하크 컴퍼니 렌즈 튜브를 구비한 광학 탁도계
WO2003002959A1 (fr) 2001-06-15 2003-01-09 Mj Research, Inc. Dispositif de commande d'un fluorometre
US6670617B2 (en) 2001-06-28 2003-12-30 Ondeo Nalco Company Mirror fluorometer
DK2423673T3 (da) * 2001-06-29 2020-09-07 Meso Scale Technologies Llc Indretning til måling af luminescens fra en flerbrønds-assayplade med en flerhed af brønde, fremgangsmåde til måling af luminescens med anvendelse af indretningen og system omfattende indretningen
US6811085B2 (en) 2001-10-26 2004-11-02 Symbol Technologies, Inc. Miniature imager
US6842243B2 (en) * 2001-12-10 2005-01-11 Apprise Technologies, Inc. Turbidity sensor
US6894778B2 (en) 2002-04-23 2005-05-17 Hach Company Low detection limit turbidimeter
US7095500B2 (en) 2004-01-30 2006-08-22 Nalco Company Interchangeable tip-open cell fluorometer
JP2008522160A (ja) 2004-11-24 2008-06-26 アイデックス ラボラトリーズ インコーポレイテッド 化学分析装置において使用する反射率計および関連の光源
US20070128658A1 (en) * 2005-11-14 2007-06-07 Blackwell Helen E Fluorescent dyes, methods and uses thereof
US20160121009A1 (en) * 2006-02-06 2016-05-05 Woods Hole Oceanographic Institution Optical Communication Systems and Methods
US7505132B2 (en) * 2006-03-23 2009-03-17 Hach Company Self calibrating measurement system
US7528951B2 (en) * 2006-03-23 2009-05-05 Hach Company Optical design of a measurement system having multiple sensor or multiple light source paths
US7786457B2 (en) 2006-06-28 2010-08-31 Alcon, Inc. Systems and methods of non-invasive level sensing for a surgical cassette
US7580128B2 (en) * 2006-11-01 2009-08-25 Finesse Solutions, Llc. Linear optical loss probe
JP5286599B2 (ja) 2007-02-23 2013-09-11 サーモ ニトン アナライザーズ リミテッド ライアビリティ カンパニー 線形センサアレイによる高速かつ正確な時間分解分光法
US7599055B2 (en) * 2007-02-27 2009-10-06 Corning Incorporated Swept wavelength imaging optical interrogation system and method for using same
EP2171396B1 (fr) * 2007-07-12 2020-05-13 Volcano Corporation Appareil et procédés permettant la synchronisation d'échantillons de fréquence uniforme
WO2009017721A2 (fr) 2007-07-28 2009-02-05 Buglab Llc Capteur de particules avec large plage linéaire
US7920252B2 (en) 2007-10-19 2011-04-05 Xin Hua Hu Method and apparatus for spectrophotometric characterization of turbid materials
KR100903133B1 (ko) 2007-12-17 2009-06-16 한국전자통신연구원 광공동을 이용한 고감도 혼탁도 센서 및 센싱 방법
US8119998B2 (en) * 2008-01-04 2012-02-21 Pion, Inc. Methods and systems for in situ physicochemical property testing
US7738101B2 (en) * 2008-07-08 2010-06-15 Rashid Mavliev Systems and methods for in-line monitoring of particles in opaque flows
EP2194381B1 (fr) * 2008-12-03 2015-12-02 Roche Diagnostics GmbH Elément de test doté d'une zone de contrôle et de calibrage combinée
US8654319B2 (en) 2009-01-23 2014-02-18 University Of Maryland, Baltimore County Chlorophyll and turbidity sensor system
US8463083B2 (en) * 2009-01-30 2013-06-11 Claudio Oliveira Egalon Side illuminated multi point multi parameter optical fiber sensor
US8211708B2 (en) * 2009-03-13 2012-07-03 Furukawa Electric Co., Ltd. Optical measuring device and method therefor
GB0906986D0 (en) * 2009-04-23 2009-06-03 Avacta Ltd Apparatus and method
CN101581668B (zh) * 2009-06-04 2010-11-17 山东大学 消除荧光测定中内滤效应的新装置及测试新方法
US20100321046A1 (en) * 2009-06-17 2010-12-23 Ysi Incorporated Wipeable conductivity probe and method of making same
DE102009027929B4 (de) * 2009-07-22 2021-05-12 Endress+Hauser Conducta Gmbh+Co. Kg Trübungsmessgerät und ein Verfahren zur Bestimmung einer Konzentration eines Trübstoffs
US8486709B2 (en) * 2009-08-21 2013-07-16 Massachusetts Institute Oftechnology Optical nanosensors comprising photoluminescent nanostructures
US8526472B2 (en) * 2009-09-03 2013-09-03 Axsun Technologies, Inc. ASE swept source with self-tracking filter for OCT medical imaging
US8625104B2 (en) * 2009-10-23 2014-01-07 Bioptigen, Inc. Systems for comprehensive fourier domain optical coherence tomography (FDOCT) and related methods
US8420996B2 (en) * 2009-12-23 2013-04-16 Nokia Corporation Intensity estimation using binary sensor array with spatially varying thresholds
WO2011103562A1 (fr) * 2010-02-22 2011-08-25 University Of Houston Formation de nanomotifs de particules neutres pour sondes neurales multimode non planes
US8721858B2 (en) 2010-03-12 2014-05-13 The Board Of Trustees Of The Leland Stanford Junior University Non-focusing tracers for indirect detection in electrophoretic displacement techniques
US8488122B2 (en) * 2010-05-05 2013-07-16 Ysi Incorporated Turbidity sensors and probes
US8717562B2 (en) * 2010-08-23 2014-05-06 Scattering Solutions, Inc. Dynamic and depolarized dynamic light scattering colloid analyzer
JP2012060912A (ja) * 2010-09-15 2012-03-29 Sony Corp 核酸増幅反応装置、核酸増幅反応装置に用いる基板、及び核酸増幅反応方法
WO2012054783A2 (fr) * 2010-10-21 2012-04-26 Nexcelom Bioscience Llc Billes de référence et de focalisation internes utilisées dans la cytométrie en image
JP2012118055A (ja) * 2010-11-12 2012-06-21 Sony Corp 反応処理装置及び反応処理方法
CA2823703C (fr) 2011-01-17 2019-04-02 Biosynergetics, Inc. Debitmetre en ligne
US20120287435A1 (en) * 2011-05-12 2012-11-15 Jmar Llc Automatic dilution for multiple angle light scattering (mals) instrument
TWI708052B (zh) * 2011-08-29 2020-10-21 美商安美基公司 用於非破壞性檢測-流體中未溶解粒子之方法及裝置
FI20115999A0 (fi) * 2011-10-11 2011-10-11 Teknologian Tutkimuskeskus Vtt Oy Optinen mittaus
US9020202B2 (en) 2012-12-08 2015-04-28 Masco Canada Limited Method for finding distance information from a linear sensor array
CN103630522A (zh) * 2013-12-11 2014-03-12 中国科学院南京地理与湖泊研究所 一种有色可溶性有机物三维荧光数据的校正和定标方法
CA2934576A1 (fr) 2013-12-20 2015-06-25 Trojan Technologies Methode d'epreuve de photoreparation fluorescente pour determiner la viabilite d'organismes dans un liquide aqueux
US9863881B2 (en) 2014-01-15 2018-01-09 Purdue Research Foundation Methods for measuring concentrations of analytes in turbid solutions by applying turbidity corrections to raman observations
US20150276594A1 (en) 2014-03-26 2015-10-01 Intellectual Property Transfer, LLC Method and apparatus for measuring turbidity
WO2015164274A1 (fr) 2014-04-21 2015-10-29 Buglab Llc Capteur de particules avec discrimination d'agents perturbateurs
WO2016023010A1 (fr) 2014-08-08 2016-02-11 Quantum-Si Incorporated Système optique et puce d'analyse pour sonder, détecter, et analyser des molécules
EP3149453A1 (fr) * 2014-09-19 2017-04-05 Hach Company Turbidimètre néphélométrique à éclairage axial et photodétecteur circonférentiel
US10184892B2 (en) * 2014-10-29 2019-01-22 Horiba Instruments Incorporated Determination of water treatment parameters based on absorbance and fluorescence
WO2016095008A1 (fr) 2014-12-17 2016-06-23 Total E&P Canada Ltd. Appareil, systèmes et procédés pour des mesures de teneur en matières solides en temps réel
US20160178618A1 (en) * 2014-12-17 2016-06-23 Stc.Unm 3d tissue model for spatially correlated analysis of biochemical, physiological and metabolic micro-environments
US10150680B1 (en) * 2015-01-05 2018-12-11 Sutro Connect Inc. Water monitoring device and method
US10088571B2 (en) 2015-02-17 2018-10-02 Florida Atlantic University Board Of Trustees Underwater sensing system
CA2993815C (fr) 2015-08-03 2023-11-21 Ysi, Inc. Fluorimetre a excitations multiples et a emissions multiples permettant de surveiller la qualite de l'eau a parametres multiples
WO2017048846A1 (fr) * 2015-09-14 2017-03-23 OptikTechnik LLC Dispositif de détection optique et procédé dans un système de traitement de liquides
LU92827B1 (en) 2015-09-14 2017-03-20 Luxembourg Inst Science & Tech List Method for determining in-situ suspended sediment properties
CN105318898B (zh) * 2015-10-21 2018-02-09 武汉理工大学 基于扫频光源的全同弱反射光栅传感网络解调系统及方法
KR102273852B1 (ko) * 2016-03-07 2021-07-06 와이에스아이 인코포레이티드 다변수 수질 측정을 위한 광학 질산염 센서
EP3427021B1 (fr) * 2016-03-09 2023-11-22 YSI Incorporated Algorithmes de compensation de capteur de nitrate optique pour surveillance de qualité d'eau à paramètres multiples
AU2017234815B2 (en) * 2016-03-17 2022-11-03 Becton, Dickinson And Company Cell sorting using a high throughput fluorescence flow cytometer
US10365198B2 (en) * 2016-04-21 2019-07-30 Malvern Panalytical Limited Particle characterization
GB2551993B (en) 2016-07-04 2019-09-11 Process Instruments Uk Ltd Sensor and measurement method
CA3037225A1 (fr) * 2016-09-13 2018-03-22 Basf Coatings Gmbh Capteur destine a la mesure humide des proprietes de couleur de revetements, pates et pigments
US10393660B2 (en) * 2016-11-06 2019-08-27 JianFeng Zhang Apparatus and method for measuring concentration of materials in liquid or gas
WO2018089935A1 (fr) 2016-11-14 2018-05-17 Siemens Healthcare Diagnostics Inc. Procédés et appareil de caractérisation d'un spécimen utilisant un éclairage de motif
US10823673B2 (en) * 2016-11-23 2020-11-03 Ysi, Inc. Dual function fluorometer-absorbance sensor
US10036703B1 (en) * 2017-01-27 2018-07-31 The United States Of America, As Represented By The Secretary Of The Navy Portable laser biosensor
EP3370486A1 (fr) * 2017-03-02 2018-09-05 ASML Netherlands B.V. Source de radiation
CN107144506B (zh) 2017-06-21 2023-08-22 华南理工大学 一种基于环状交织阵列的悬浮物动态监测方法与装置
CN110914001B (zh) * 2017-07-07 2022-06-24 Ysi公司 用于现场部署的传感器和仪器的防污配件
WO2019033028A1 (fr) * 2017-08-10 2019-02-14 Advanced Polymer Monitoring Technologies, Inc., Dba/ Fluence Analytics Dispositifs et procédés de caractérisation et de régulation de biopolymères et de polymères synthétiques pendant la fabrication
US20190162662A1 (en) 2017-11-27 2019-05-30 The Government Of The United States Of America, As Represented By The Secretary Of The Navy Substrates with independently tunable topographies and chemistries for quantifiable surface-induced cell behavior
US11612768B2 (en) * 2018-07-26 2023-03-28 Carnegie Mellon University In-medium sculpted tunable graded index lenses
WO2020073016A1 (fr) * 2018-10-04 2020-04-09 First Light Diagnostics, Inc. Analyse microbienne sans purification cellulaire
KR20210075648A (ko) * 2019-12-13 2021-06-23 삼성전자주식회사 소형 라만 센서 및 생체성분 추정 장치
AU2021276375B2 (en) * 2020-05-20 2023-11-02 Ysi, Inc. Extended solid angle turbidity sensor
US20220413166A1 (en) * 2021-05-18 2022-12-29 Luminated Glazings, Llc Scattering fields in a medium to redirect wave energy onto surfaces in shadow

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050219526A1 (en) * 2003-01-17 2005-10-06 Hong Peng Method and apparatus for monitoring biological substance
US20090230288A1 (en) * 2006-11-04 2009-09-17 Leopold Kostal Gmbh & Co. Kg Method for the operation of a photoelectric sensor array
US20170241893A1 (en) * 2016-02-19 2017-08-24 Research Triangle Institute Devices, systems and methods for detecting particles
US20180251713A1 (en) * 2017-03-01 2018-09-06 Fluidion Sas Field-deployable Multiplexed Sampling and Monitoring Device and Bacterial Contamination Measurement Method

Also Published As

Publication number Publication date
BR112022023420A2 (pt) 2023-03-21
JP7451767B2 (ja) 2024-03-18
US11604143B2 (en) 2023-03-14
KR20230011952A (ko) 2023-01-25
JP2023518125A (ja) 2023-04-27
WO2021236735A1 (fr) 2021-11-25
AU2021276375A1 (en) 2022-12-15
KR20230007404A (ko) 2023-01-12
US20210364438A1 (en) 2021-11-25
EP4153970A1 (fr) 2023-03-29
EP4153972A1 (fr) 2023-03-29
JP2023527783A (ja) 2023-06-30
AU2021275061B2 (en) 2023-01-19
CA3178563A1 (fr) 2021-11-25
AU2021275061A1 (en) 2022-12-15
JP2023526508A (ja) 2023-06-21
US20210364430A1 (en) 2021-11-25
JP7303397B2 (ja) 2023-07-04
US20210364433A1 (en) 2021-11-25
CN115667890B (zh) 2024-02-02
US11860096B2 (en) 2024-01-02
BR112022023424A2 (pt) 2023-04-11
CN115667889A (zh) 2023-01-31
KR102604781B1 (ko) 2023-11-22
EP4153971A1 (fr) 2023-03-29
CA3178563C (fr) 2024-02-27
WO2021236726A1 (fr) 2021-11-25
AU2021273797A1 (en) 2022-12-15
CN115667890A (zh) 2023-01-31
CA3178570A1 (fr) 2021-11-25
CN115667886A (zh) 2023-01-31
KR20230011951A (ko) 2023-01-25
AU2021276375B2 (en) 2023-11-02
BR112022023418A2 (pt) 2023-03-21

Similar Documents

Publication Publication Date Title
US8049179B2 (en) Ultraviolet radiation detector and apparatus for evaluating ultraviolet radiation protection effect
JP2020531825A5 (fr)
US7423756B2 (en) Internally-calibrated, two-detector gas filter correlation radiometry (GFCR) system
JP2021043209A5 (fr)
AU2021276375B2 (en) Extended solid angle turbidity sensor
JP6804445B2 (ja) 吸光度測定装置への蛍光検出機能の統合
US11906629B2 (en) Method and device for distance measurement
CA2228499C (fr) Appareil de mesure optique des conditions marines
WO2016055683A1 (fr) Spectrophotomètre
CN109253991A (zh) 光学传感器
US20080180678A1 (en) Two-detector gas filter correlation radiometry (GFCR) system using two-dimensional array detection of defocused image and detected-signal summation
US9188528B2 (en) Sensor for monitoring a medium
WO2003027645A9 (fr) Appareil et procede pour mesurer des matieres optiquement actives
WO2018098260A1 (fr) Fluorimètre-capteur d'absorbance bifonctionnel
CA3178549A1 (fr) Fluorimetre a gradient spatial
JP2003315243A (ja) 粒子径分布測定装置
US9897524B1 (en) Method and apparatus for measurement of particle characteristics using light scattering and optical imaging
CARACCI et al. Arrayed sensor measurement system and method
JPH1047928A (ja) 光学式外形計測装置
Jumaaha et al. Study of the Effect of Brightness After Penetration of Light from a Lens
JPWO2021236720A5 (fr)

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 21807774

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 3178563

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2022571196

Country of ref document: JP

Kind code of ref document: A

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112022023418

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 2021276375

Country of ref document: AU

Date of ref document: 20210519

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2021807774

Country of ref document: EP

Effective date: 20221220

REG Reference to national code

Ref country code: BR

Ref legal event code: B01E

Ref document number: 112022023418

Country of ref document: BR

Free format text: APRESENTAR, EM ATE 60 (SESSENTA) DIAS, TRADUCAO COMPLETA DO PEDIDO, ADAPTADA A NORMA VIGENTE, CONFORME CONSTA NO DEPOSITO INTERNACIONAL INICIAL, POIS A MESMA NAO FOI APRESENTADA ATE O MOMENTO.

ENP Entry into the national phase

Ref document number: 112022023418

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20221117