WO2021200149A1 - Composition pour polissage, et procédé de polissage - Google Patents
Composition pour polissage, et procédé de polissage Download PDFInfo
- Publication number
- WO2021200149A1 WO2021200149A1 PCT/JP2021/010796 JP2021010796W WO2021200149A1 WO 2021200149 A1 WO2021200149 A1 WO 2021200149A1 JP 2021010796 W JP2021010796 W JP 2021010796W WO 2021200149 A1 WO2021200149 A1 WO 2021200149A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polishing
- less
- polishing composition
- metal salt
- substrate
- Prior art date
Links
- 238000005498 polishing Methods 0.000 title claims abstract description 252
- 239000000203 mixture Substances 0.000 title claims abstract description 98
- 238000000034 method Methods 0.000 title claims description 42
- 150000003839 salts Chemical class 0.000 claims abstract description 70
- 229910052751 metal Inorganic materials 0.000 claims abstract description 66
- 239000002184 metal Substances 0.000 claims abstract description 66
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000007800 oxidant agent Substances 0.000 claims abstract description 46
- 229910021485 fumed silica Inorganic materials 0.000 claims abstract description 36
- 239000000758 substrate Substances 0.000 claims description 58
- 239000000463 material Substances 0.000 claims description 27
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 21
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 20
- 239000011575 calcium Substances 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 8
- 229910044991 metal oxide Inorganic materials 0.000 claims description 8
- 150000004706 metal oxides Chemical class 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
- 239000011591 potassium Substances 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N nitrate group Chemical group [N+](=O)([O-])[O-] NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 239000006061 abrasive grain Substances 0.000 description 29
- 239000002245 particle Substances 0.000 description 29
- 239000002253 acid Substances 0.000 description 20
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 20
- 239000007788 liquid Substances 0.000 description 19
- 150000001875 compounds Chemical class 0.000 description 13
- 229910003460 diamond Inorganic materials 0.000 description 13
- 239000010432 diamond Substances 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 11
- 150000007513 acids Chemical class 0.000 description 10
- 239000004065 semiconductor Substances 0.000 description 10
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 8
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 8
- 239000011164 primary particle Substances 0.000 description 7
- 239000011163 secondary particle Substances 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- -1 polishing methods Substances 0.000 description 6
- DHEQXMRUPNDRPG-UHFFFAOYSA-N strontium nitrate Chemical compound [Sr+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O DHEQXMRUPNDRPG-UHFFFAOYSA-N 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 5
- 239000002612 dispersion medium Substances 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000001110 calcium chloride Substances 0.000 description 4
- 229910001628 calcium chloride Inorganic materials 0.000 description 4
- 235000011148 calcium chloride Nutrition 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 229960003975 potassium Drugs 0.000 description 4
- 239000001103 potassium chloride Substances 0.000 description 4
- 235000011164 potassium chloride Nutrition 0.000 description 4
- 239000004323 potassium nitrate Substances 0.000 description 4
- 235000010333 potassium nitrate Nutrition 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229910002601 GaN Inorganic materials 0.000 description 3
- 229910005540 GaP Inorganic materials 0.000 description 3
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910052581 Si3N4 Inorganic materials 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 3
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000007865 diluting Methods 0.000 description 3
- 239000002552 dosage form Substances 0.000 description 3
- HZXMRANICFIONG-UHFFFAOYSA-N gallium phosphide Chemical compound [Ga]#P HZXMRANICFIONG-UHFFFAOYSA-N 0.000 description 3
- 150000002505 iron Chemical class 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 238000007517 polishing process Methods 0.000 description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229910001631 strontium chloride Inorganic materials 0.000 description 3
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 3
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 2
- 229910052580 B4C Inorganic materials 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 2
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical class OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 150000001844 chromium Chemical class 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 229910052701 rubidium Inorganic materials 0.000 description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- JHJLBTNAGRQEKS-UHFFFAOYSA-M sodium bromide Chemical compound [Na+].[Br-] JHJLBTNAGRQEKS-UHFFFAOYSA-M 0.000 description 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 2
- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical class CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical class OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910000530 Gallium indium arsenide Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GPXJNWSHGFTCBW-UHFFFAOYSA-N Indium phosphide Chemical compound [In]#P GPXJNWSHGFTCBW-UHFFFAOYSA-N 0.000 description 1
- VSOYJNRFGMJBAV-UHFFFAOYSA-N N.[Mo+4] Chemical compound N.[Mo+4] VSOYJNRFGMJBAV-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920005830 Polyurethane Foam Polymers 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- KXNLCSXBJCPWGL-UHFFFAOYSA-N [Ga].[As].[In] Chemical compound [Ga].[As].[In] KXNLCSXBJCPWGL-UHFFFAOYSA-N 0.000 description 1
- DYPHJEMAXTWPFB-UHFFFAOYSA-N [K].[Fe] Chemical compound [K].[Fe] DYPHJEMAXTWPFB-UHFFFAOYSA-N 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- FTWRSWRBSVXQPI-UHFFFAOYSA-N alumanylidynearsane;gallanylidynearsane Chemical compound [As]#[Al].[As]#[Ga] FTWRSWRBSVXQPI-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 description 1
- 229910001632 barium fluoride Inorganic materials 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- QWUZMTJBRUASOW-UHFFFAOYSA-N cadmium tellanylidenezinc Chemical compound [Zn].[Cd].[Te] QWUZMTJBRUASOW-UHFFFAOYSA-N 0.000 description 1
- ZTXUIQYSNNFFDU-UHFFFAOYSA-L cadmium(2+);tellurate Chemical compound [Cd+2].[O-][Te]([O-])(=O)=O ZTXUIQYSNNFFDU-UHFFFAOYSA-L 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 239000004301 calcium benzoate Substances 0.000 description 1
- 235000010237 calcium benzoate Nutrition 0.000 description 1
- 229910001622 calcium bromide Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- WGEFECGEFUFIQW-UHFFFAOYSA-L calcium dibromide Chemical compound [Ca+2].[Br-].[Br-] WGEFECGEFUFIQW-UHFFFAOYSA-L 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- HZQXCUSDXIKLGS-UHFFFAOYSA-L calcium;dibenzoate;trihydrate Chemical compound O.O.O.[Ca+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 HZQXCUSDXIKLGS-UHFFFAOYSA-L 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 229940005991 chloric acid Drugs 0.000 description 1
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Chemical class O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical compound CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- QFWPJPIVLCBXFJ-UHFFFAOYSA-N glymidine Chemical compound N1=CC(OCCOC)=CN=C1NS(=O)(=O)C1=CC=CC=C1 QFWPJPIVLCBXFJ-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-N iodic acid Chemical class OI(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-N 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- OTCKOJUMXQWKQG-UHFFFAOYSA-L magnesium bromide Chemical compound [Mg+2].[Br-].[Br-] OTCKOJUMXQWKQG-UHFFFAOYSA-L 0.000 description 1
- 229910001623 magnesium bromide Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- CVMIVKAWUQZOBP-UHFFFAOYSA-L manganic acid Chemical class O[Mn](O)(=O)=O CVMIVKAWUQZOBP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000033116 oxidation-reduction process Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 125000005385 peroxodisulfate group Chemical group 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000011496 polyurethane foam Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- BQFYGYJPBUKISI-UHFFFAOYSA-N potassium;oxido(dioxo)vanadium Chemical compound [K+].[O-][V](=O)=O BQFYGYJPBUKISI-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- SBIBMFFZSBJNJF-UHFFFAOYSA-N selenium;zinc Chemical compound [Se]=[Zn] SBIBMFFZSBJNJF-UHFFFAOYSA-N 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
- 235000013024 sodium fluoride Nutrition 0.000 description 1
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- FVRNDBHWWSPNOM-UHFFFAOYSA-L strontium fluoride Chemical compound [F-].[F-].[Sr+2] FVRNDBHWWSPNOM-UHFFFAOYSA-L 0.000 description 1
- 229910001637 strontium fluoride Inorganic materials 0.000 description 1
- RXSHXLOMRZJCLB-UHFFFAOYSA-L strontium;diacetate Chemical compound [Sr+2].CC([O-])=O.CC([O-])=O RXSHXLOMRZJCLB-UHFFFAOYSA-L 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- 150000003657 tungsten Chemical class 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/14—Anti-slip materials; Abrasives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/302—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
- H01L21/304—Mechanical treatment, e.g. grinding, polishing, cutting
Definitions
- the present invention relates to a polishing composition and a polishing method. More specifically, the present invention relates to a polishing composition and a polishing method suitable for polishing a high-hardness material having a Vickers hardness of 1500 Hv or more.
- This application claims priority based on Japanese Patent Application No. 2020-060913 filed on March 30, 2020, the entire contents of which are incorporated herein by reference.
- the surface of materials such as metals, metalloids, non-metals, and oxides thereof is polished using a polishing composition.
- a surface made of a compound semiconductor material such as silicon carbide, boron carbide, tungsten carbide, silicon nitride, titanium nitride, and gallium nitride is wrapped by supplying diamond abrasive grains between the surface and the polishing platen.
- diamond abrasive grains can be processed by.
- polishing (polishing) using a polishing pad and a polishing composition after or instead of wrapping with diamond abrasive grains has been studied.
- Patent Document 1 is mentioned as a document that discloses the prior art of the polishing composition.
- Patent Document 1 a composition for polishing tantalum is studied.
- the polishing removal speed is sufficiently high for practical use.
- a surface made of a high-hardness material such as silicon carbide further improvement in polishing removal speed is desired.
- the polishing composition that can be expected to improve the polishing removal speed include a polishing composition containing fumed silica. Since fumed silica is more non-spherical than colloidal silica, it tends to have excellent processing power, but it is preferable because it is less likely to cause a problem of alumina residue (piercing or the like) on a polished surface such as alumina abrasive grains. Further, when the polishing composition contains an oxidizing agent, the oxidizing agent may change the surface of the substrate, and the polishing removal rate may be improved.
- the present invention has been made in view of such circumstances, and an object of the present invention is to improve the polishing removal rate of a composition containing fumed silica and an oxidizing agent.
- a polishing composition containing fumed silica, an oxidizing agent, and a metal salt is provided.
- This polishing composition is characterized by containing more than 10 mmol / L of metal salts.
- the polishing removal rate is improved in the composition containing fumed silica and an oxidizing agent.
- the "metal salt” in the present specification is defined as a compound different from the above “oxidizing agent”, and specifically, it is produced by neutralization of a strong acid and a strong base. Can be pure salt.
- the metal forming the metal salt includes lithium, sodium, potassium, rubidium, cesium, magnesium, calcium, strontium or barium.
- the metal salt is a nitrate of an alkali metal and / or an alkaline earth metal. And / or hydrochloride.
- the polishing removal rate is preferably improved.
- the metal forming the metal salt is calcium.
- the polishing removal rate is particularly preferably improved.
- the metal forming the metal salt is potassium.
- the polishing removal rate is particularly preferably improved.
- the oxidizing agent comprises a composite metal oxide.
- the composition containing the composite metal oxide as an oxidizing agent contains a metal salt in an amount of more than 10 mmol / L, the polishing removal rate can be easily improved.
- the ratio (B / A) of the metal salt concentration B [mmol / L] to the oxidizing agent concentration A [mmol / L] is 0.01 or more and 10 or less. According to such a configuration, the effect of the technique disclosed herein is preferably exhibited.
- the pH of the polishing composition is greater than 5.0 and less than 9.0.
- the pH of the polishing composition is in the above range (a range close to the neutral range), the effects of the techniques disclosed herein are preferably exhibited.
- the polishing composition disclosed herein is preferably used for polishing a material having a Vickers hardness of 1500 Hv or more. According to the above-mentioned polishing composition, the polishing removal rate for a high-hardness material can be improved.
- a preferable example of the high hardness material is silicon carbide. When polishing silicon carbide, the effects of the techniques disclosed herein are preferably exhibited.
- a method for polishing a substrate includes a step of polishing a substrate using any of the polishing compositions disclosed herein. According to this polishing method, the polishing removal speed is improved.
- the polishing composition disclosed herein comprises fumed silica.
- fumed silica it can be appropriately selected and used from various known fumed silicas.
- the fumed silica may contain one of various known fumed silicas alone or in combination of two or more.
- the average primary particle size of fumed silica is not particularly limited as long as the effect of the present invention is exhibited, and is preferably 10 nm or more, more preferably 15 nm or more, still more preferably 20 nm or more from the viewpoint of improving the polishing removal speed and the like. For example, it may be 30 nm or more. Higher polishing removal rates can be achieved by increasing the average primary particle size. From the viewpoint of surface quality after polishing, the average primary particle size is preferably 150 nm or less, more preferably 100 nm or less, still more preferably 80 nm or less, and may be, for example, 60 nm or less.
- BET value (m 2 / g)) means the particle size (BET particle size) calculated by the formula.
- the specific surface area can be measured, for example, by using a surface area measuring device manufactured by Micromeritex Co., Ltd., trade name "Flow Sorb II 2300".
- the average secondary particle size of fumed silica is not particularly limited as long as the effect of the present invention is exhibited, for example, 15 nm or more is suitable, and from the viewpoint of improving the polishing removal speed, it is preferably 30 nm or more, more preferably. Is 60 nm or more, more preferably 80 nm or more, particularly preferably 100 nm or more (for example, 120 nm or more), and may be 150 nm or more.
- the average secondary particle size of the fumed silica can be, for example, 1000 nm or less. From the viewpoint of surface quality after polishing, the average secondary particle size is preferably 500 nm or less, and may be 300 nm or less. For example, fumed silica having an average secondary particle size of 120 nm or more and 220 nm or less can be preferably adopted.
- the average secondary particle size of fumed silica means the volume-based average particle size (50% volume average particle size) based on the dynamic light scattering method.
- the particle size measurement based on the dynamic light scattering method can be performed using, for example, "N4 Plus” manufactured by BECKMAN COULTER.
- the aspect ratio of fumed silica is not particularly limited and may be, for example, 1.5 or more. From the viewpoint of improving the polishing removal speed, the aspect ratio of the fumed silica may be 2.0 or more, 2.5 or more, or 3.0 or more. Further, the upper limit of the aspect ratio is, for example, less than 8.0, and may be less than 6.0.
- the "aspect ratio" of the fumed silica means the value of the ratio of the average secondary particle size / the average primary particle size of the fumed silica.
- the content of fumed silica in the polishing composition (when a plurality of types of fumed silica are contained, the total content thereof) is not particularly limited as long as the effects of the present invention are exhibited, and for example, 0. It is 01% by weight or more, and may be 0.05% by weight or more. From the viewpoint of improving the polishing speed, it is appropriate to be 0.1% by weight or more, preferably 0.5% by weight or more, more preferably 0.8% by weight or more, and may be 1% by weight or more, 5% by weight. The above may be sufficient. Further, from the viewpoint of dispersibility of the polishing composition, stability over time, etc., the content of fumed silica is preferably 50% by weight or less, preferably 20% by weight or less, and 15% by weight. It may be 10% by weight or less, 8% by weight or less, 3% by weight or less, 1.5% by weight or less, for example, 0.3% by weight or less.
- the polishing composition disclosed herein may contain silica abrasive grains other than fumed silica (hereinafter, also referred to as non-fumed silica abrasive grains) as long as the effects of the present invention are not impaired.
- silica abrasive grains other than fumed silica hereinafter, also referred to as non-fumed silica abrasive grains
- Abrasive grains made of a material other than the above hereinafter, also referred to as non-silica abrasive grains
- non-fumed silica abrasive grains include colloidal silica and precipitated silica.
- non-silica abrasive grains include oxide particles such as aluminum oxide particles, cerium oxide particles, chromium oxide particles, titanium dioxide particles, zirconium oxide particles, magnesium oxide particles, manganese oxide particles, zinc oxide particles, and iron oxide particles; Nitride particles such as silicon nitride particles and boron nitride particles; carbide particles such as silicon carbide particles and boron carbide particles; diamond particles; inorganic particles such as carbonates such as calcium carbonate and barium carbonate, and crosslinked or non-crosslinked polymethacryl Examples thereof include abrasive grains substantially composed of any of organic particles such as methyl acid, polyacrylonitrile, polystyrene, nylon and silicone.
- the ratio of fumed silica to the total abrasive grains used is high.
- the proportion of fumed silica in the entire abrasive grains is preferably more than 50% by weight, preferably 70% by weight or more, more preferably 90% by weight or more, still more preferably 95% by weight or more, and is substantially. It may be 100% by weight.
- the polishing composition may be substantially free of diamond particles as abrasive grains. Since diamond particles have high hardness, they can be a limiting factor for improving smoothness. Moreover, since diamond particles are generally expensive, they cannot be said to be advantageous materials in terms of cost effectiveness, and from a practical point of view, the dependence on high-priced materials such as diamond particles may be low.
- the fact that the abrasive grains do not substantially contain diamond particles means that the ratio of the diamond particles to the total abrasive grains is 1% by weight or less, more preferably 0.5% by weight or less, typically 0.1% by weight. % Or less, including the case where the ratio of diamond particles is 0% by weight. In such an embodiment, the effects of the techniques disclosed herein can be suitably exerted.
- the polishing composition disclosed herein comprises an oxidizing agent.
- the oxidant can cause an oxidation reaction with the surface of the substrate during the polishing process to reduce the hardness of the surface and make the surface fragile.
- the oxidizing agent is not particularly limited as long as it is a substance having a sufficient redox potential to exert an action of oxidizing the surface of the substrate.
- the oxidizing agent can be a substance having a redox potential higher than the redox potential of the substrate material at the pH at which polishing is performed.
- the pH at which the polishing is carried out is usually the same as the pH of the polishing composition.
- the redox potential of the substrate material is determined by dispersing the powder of the material in water to make a slurry, adjusting the slurry to the same pH as the polishing composition, and then using a commercially available redox potential meter to prepare the slurry.
- the value obtained by measuring the redox potential (oxidation-reduction potential with respect to the standard hydrogen electrode at a liquid temperature of 25 ° C.) is adopted.
- the oxidizing agent in the present specification does not include the metal salt described later.
- the oxidizing agent include peroxides such as hydrogen peroxide; nitrates such as iron nitrate, silver nitrate and aluminum nitrate; persulfates such as persulfates such as peroxomonosulfate and peroxodisulfate; persulfates such as chloric acid and the like.
- peroxides such as hydrogen peroxide
- nitrates such as iron nitrate, silver nitrate and aluminum nitrate
- persulfates such as persulfates such as peroxomonosulfate and peroxodisulfate
- persulfates such as chloric acid and the like.
- the polishing composition comprises a composite metal oxide as an oxidizing agent.
- the composite metal oxide include nitric acids, iron acids, permanganic acids, chromium acids, vanadic acids, ruthenic acids, molybdic acids, renic acids and tungsten acids. Among them, iron acids, permanganates and chromium acids are more preferable, and permanganates are even more preferable.
- One type of composite metal oxide may be used alone, or two or more types may be used in combination as appropriate.
- the polishing composition disclosed here may or may not further contain an oxidizing agent other than the above-mentioned composite metal oxide.
- the technique disclosed herein can be preferably carried out in a manner in which an oxidizing agent (for example, hydrogen peroxide) other than the above-mentioned composite metal oxide is substantially not contained as an oxidizing agent.
- the concentration (content) of the oxidizing agent in the polishing composition is 0.001 mol / L or more.
- the concentration of the oxidizing agent is preferably 0.005 mol / L or more, more preferably 0.01 mol / L or more, and 0.05 mol / L or more. The above is more preferable.
- the concentration of oxidant is 0.10 mol / L or higher, may be 0.15 mol / L or higher, may be 0.20 mol / L or higher, eg, 0.25 mol / L or higher. Molar / L or more.
- the concentration of the oxidizing agent is preferably 10 mol / L or less, preferably 5 mol / L or less, and 3 mol / L or less (for example, 1). It is more preferably mol / L or less, or 0.5 mol / L or less). In some embodiments, the concentration of oxidant may be 0.30 mol / L or less, 0.20 mol / L or less, 0.12 mol / L or less, 0.09 mol / L or less. It may be L or less.
- the content of the oxidant can also be specified by the relative relationship with the abrasive grains (typically fumed silica).
- the content of the oxidizing agent with respect to 100 parts by weight of the abrasive grains can be, for example, 0.01 mol or more, and the effect of using the oxidizing agent is effectively exhibited. From the viewpoint, it is appropriate to set it to 0.05 mol or more, and it may be 0.10 mol or more, 0.5 mol or more, 1 mol or more, 2.5 mol or more, and 5 mol. The above may be sufficient.
- the content of the oxidizing agent with respect to 100 parts by weight of the abrasive grains can be, for example, 50 mol or less (for example, 30 mol or less), and 10 mol or less from the viewpoint of effectively exerting the mechanical polishing force of the abrasive grains. It may be 6 mol or less, 3 mol or less, 1 mol or less, 0.3 mol or less (for example, 0.1 mol or less).
- the polishing composition disclosed herein comprises a metal salt.
- the polishing removal rate is improved.
- the oxidizing agent contained in the polishing composition disclosed herein alters the surface of the substrate (particularly the surface of the substrate of a high-hardness material such as silicon carbide), and the altered layer is removed by polishing. ..
- the metal salt exhibits an action of promoting or assisting its alteration and removal, and is considered to contribute to the improvement of the polishing removal rate. It should be noted that the improvement in polishing removal speed by the technique disclosed herein is not limited to the above mechanism.
- the “metal salt” disclosed herein is a compound different from the above-mentioned “oxidizing agent”, and specifically, it may be a positive salt produced by neutralization of a strong acid and a strong base.
- the metal salt preferably contains an element belonging to an alkali metal and / or an alkaline earth metal, and is preferably lithium (Li), sodium (Na), potassium (K), rubidium (Rb), cesium (Cs), or magnesium. More preferably, it contains any one or more of (Mg), calcium (Ca), cesium (Sr), and barium (Ba).
- a metal salt containing any one of Na, K, Ca and Sr is preferable, and a metal salt containing any one of K and Ca is particularly preferable.
- the type of salt in the above metal salt is not particularly limited, and may be an inorganic acid salt or an organic acid salt.
- the inorganic acid salt include salts of hydrohalic acid (for example, hydrochloric acid, hydrobromic acid, hydrofluoric acid), nitric acid, sulfuric acid, carbonic acid, silicic acid, boric acid, phosphoric acid and the like.
- the organic acid salt include carboxylic acids (for example, formic acid, acetic acid, propionic acid, benzoic acid, glycic acid, butyric acid, citric acid, tartaric acid, and trifluoroacetic acid) and organic sulfonic acids (for example, methanesulfonic acid and trifluoromethane).
- Examples thereof include salts of sulfonic acid, benzenesulfonic acid, toluenesulfonic acid), organic phosphonic acid (eg, methylphosphonic acid, benzenephosphonic acid, toluenephosphonic acid), organic phosphoric acid (eg, ethylphosphoric acid) and the like.
- organic phosphonic acid eg, methylphosphonic acid, benzenephosphonic acid, toluenephosphonic acid
- organic phosphoric acid eg, ethylphosphoric acid
- metal salt examples include chlorides such as lithium chloride, sodium chloride, potassium chloride, magnesium chloride, calcium chloride, strontium chloride and barium chloride; sodium bromide, potassium bromide, magnesium bromide, calcium bromide and the like.
- fluorides such as lithium fluoride, sodium fluoride, potassium fluoride, magnesium fluoride, calcium fluoride, strontium fluoride, barium fluoride; lithium nitrate, sodium nitrate, potassium nitrate, magnesium nitrate, calcium nitrate, strontium nitrate , Nitrate such as barium nitrate; sulfates such as lithium sulfate, sodium sulfate, potassium sulfate, magnesium sulfate, calcium sulfate, strontium sulfate, barium sulfate; potassium carbonate, potassium hydrogencarbonate, sodium carbonate, sodium hydrogencarbonate, magnesium carbonate, carbonic acid Substantial from any of carbonates such as calcium, strontium carbonate, barium carbonate; carboxylates such as potassium acetate, sodium acetate, calcium acetate, strontium acetate, sodium benzoate, calcium benzoate, sodium citrate, calcium citrate; A metal salt composed
- the metal salt may be dissolved in the polishing composition or may be dispersed as a solid. That is, the metal salt may be water-soluble or water-insoluble. Further, a part of the metal salt may be dissolved in the polishing composition, and the rest may be dispersed as a solid.
- the metal salt is a water-soluble salt. By using a water-soluble metal salt, a good surface with few defects such as scratches can be efficiently formed.
- the metal salt is a salt that dissolves in water and exhibits a neutral range, and can be specifically a normal salt produced by neutralization of a strong acid and a strong base.
- a metal salt in which the aqueous solution exhibits a neutral range for example, pH 6 to 8, preferably pH 6.5 to 7.5
- the metal salt in which the aqueous solution is neutral include chlorides such as sodium chloride, potassium chloride, calcium chloride and strontium chloride, and nitrates such as sodium nitrate, potassium nitrate, calcium nitrate and strontium nitrate.
- chlorides such as sodium chloride, potassium chloride, calcium chloride, strontium chloride, potassium nitrate, calcium nitrate and strontium nitrate.
- potassium chloride, sodium chloride, calcium chloride, strontium chloride, potassium nitrate, calcium nitrate and strontium nitrate are preferable because they can efficiently form a good surface.
- potassium chloride, calcium chloride, potassium nitrate and calcium nitrate are particularly preferable.
- the concentration (content) of the metal salt is more than 10 mmol / L. This improves the polishing removal rate in the composition containing the fumed silica and the oxidizing agent.
- the concentration of the metal salt is preferably 12 mmol / L or higher, more preferably 20 mmol / L or higher, 30 mmol / L or higher, or 50 mmol / L or higher.
- the concentration of the metal salt is preferably 80 mmol / L or higher, preferably 150 mmol / L or higher, 250 mmol / L or higher, 500 mmol / L or higher. But it may be.
- the upper limit of the concentration of the metal salt is not particularly limited, and it is appropriate to set it to 10 mol / L or less.
- the concentration of the metal salt is in a predetermined range, the polishing removal rate on the surface of the substrate material (particularly the high hardness material) can be improved at a higher level.
- the above concentration is preferably 5 mol / L or less, more preferably 3 mol / L or less, further preferably 1000 mmol / L or less, and even if it is 600 mmol / L or less. It may be 400 mmol / L or less, or 200 mmol / L or less.
- the concentration of the metal salt may be 100 mmol / L or less, 70 mmol / L or less, or 25 mmol / L or less (eg, 20 mmol / L or less).
- the concentration ratio of the oxidizing agent and the metal salt is not particularly limited as long as the effect of the present invention is exhibited. Estimating the effect of the present invention, it is considered preferable to set the amount of the metal salt in a predetermined range with respect to the amount of the oxidizing agent. From this point of view, the ratio (B / A) of the metal salt concentration B [mmol / L] to the oxidizing agent concentration A [mmol / L] is, for example, 0.01 or more from the viewpoint of improving the polishing removal speed. Yes, 0.05 or more is appropriate, 0.07 or more, or 0.10 or more (for example, 0.15 or more).
- the ratio (B / A) may be 0.30 or higher, 1.0 or higher, or 3.0 or higher (eg 6.0 or higher).
- the upper limit of the ratio (B / A) is not particularly limited, and may be, for example, 15 or less. From the viewpoint of polishing removal speed, 10 or less is appropriate, preferably 5.0 or less, and more preferably. It is 1.0 or less, more preferably 0.50 or less (for example, 0.20 or less), and may be 0.12 or less.
- the dispersion medium used in the polishing composition is not particularly limited as long as it can disperse fumed silica, an oxidizing agent and a metal salt.
- the dispersion medium in the present specification is a liquid (a liquid medium at 23 ° C.) generally referred to as a dispersion medium or a solvent, and includes those which can be a solvent for an oxidizing agent or a metal salt.
- Water is preferably used as the dispersion medium.
- the water for example, ion-exchanged water (deionized water), pure water, ultrapure water, distilled water and the like can be preferably used.
- the polishing composition disclosed herein may further contain an organic solvent (lower alcohol, lower ketone, etc.) that can be uniformly mixed with water, if necessary. It is preferable that 90% by volume or more of the solvent contained in the polishing composition is water, and more preferably 95% by volume or more (typically 99 to 100% by volume) of water.
- an organic solvent lower alcohol, lower ketone, etc.
- the pH of the polishing composition is about 2 to 12.
- the pH may be 2.5 or higher, 3.0 or higher, 4.0 or higher, 5.0 or higher, or 5.5 or higher.
- the upper limit of the pH is not particularly limited, and in some embodiments, the pH may be 12.0 or less, 10.0 or less, 9.0 or less, 8.0 or less, 7.5 or less. It may be less than or equal to, 7.0 or less, or 6.5 or less. In some preferred embodiments, the pH of the polishing composition is greater than 5.0 and less than 9.0, for example less than 8.0 or less than 7.0.
- the polishing composition disclosed herein is a chelating agent, a thickener, a dispersant, a surface protectant, a wetting agent, and a pH adjuster (organic acid, inorganic acid, basic) as long as the effects of the present invention are not impaired.
- a pH adjuster organic acid, inorganic acid, basic
- Known that can be used in polishing compositions for example, compositions for polishing high-hardness materials, preferably compositions for polishing silicon carbide substrates) such as compounds
- surfactants for polishing high-hardness materials, preferably compositions for polishing silicon carbide substrates
- rust preventives rust preventives
- preservatives preservatives
- antifungal agents additive may be further included as needed.
- the content of the additive may be appropriately set according to the purpose of the addition and does not characterize the present invention, and thus detailed description thereof will be omitted.
- the method for producing the polishing composition disclosed herein is not particularly limited.
- the mode in which these components are mixed is not particularly limited, and for example, all the components may be mixed at once, or may be mixed in an appropriately set order.
- the polishing composition disclosed here may be a one-dosage form or a multi-dosage form including a two-dosage form.
- the liquid A containing a part of the constituent components of the polishing composition and the liquid B containing the remaining components are stored separately, and the liquid A and the liquid B are mixed when polishing the substrate. It may be configured to be used.
- the polishing composition disclosed herein may be in a concentrated form (ie, in the form of a concentrated solution of a polishing solution) before being used for polishing.
- the polishing composition in such a concentrated form is advantageous from the viewpoint of convenience and cost reduction in production, distribution, storage and the like.
- the substrate to be polished using the polishing composition disclosed herein is not particularly limited.
- the polishing composition disclosed herein can be applied to polish a substrate having a surface made of a compound semiconductor material, that is, a compound semiconductor substrate.
- the constituent materials of the compound semiconductor substrate are not particularly limited, and are, for example, II-VI group compound semiconductors such as cadmium tellurate, zinc selenium, cadmium sulfide, cadmium telluride mercury, and cadmium zinc telluride; gallium phosphide and gallium arsenide.
- Group III-V compound semiconductors such as gallium phosphide, indium phosphide, aluminum gallium arsenide, gallium arsenide, indium gallium arsenide, and gallium phosphide indium; IV-IV such as silicon carbide and germanium silicate. Group compound semiconductor; etc.
- a substrate having a surface made of a plurality of materials may be used.
- the polishing compositions disclosed herein can be applied to polish a substrate having a surface composed of a non-oxide (ie, non-oxide) compound semiconductor material.
- the polishing promoting effect of the oxidizing agent contained in the polishing composition disclosed herein is likely to be suitably exhibited.
- the polishing composition disclosed herein can be preferably used, for example, for polishing the surface of a substrate having a Vickers hardness of 500 Hv or more.
- the Vickers hardness is preferably 700 Hv or higher, for example 1000 Hv or higher, and in some preferred embodiments 1500 Hv or higher.
- the Vickers hardness of the substrate material may be 1800 Hv or more, 2000 Hv or more, or 2200 Hv or more.
- the upper limit of the Vickers hardness of the substrate surface is not particularly limited, and may be, for example, approximately 7,000 Hv or less, 5000 Hv or less, or 3000 Hv or less. In this specification, the Vickers hardness can be measured based on JIS R 1610: 2003.
- the international standard corresponding to the above JIS standard is ISO 14705: 2000.
- Examples of the material having a Vickers hardness of 1500 Hv or more include silicon carbide, silicon nitride, titanium nitride, gallium nitride and the like.
- the substrate in the techniques disclosed herein may have a single crystal surface of the above material that is mechanically and chemically stable.
- the surface of the substrate is preferably composed of either silicon carbide or gallium nitride, and more preferably composed of silicon carbide.
- Silicon carbide is expected as a compound semiconductor substrate material with low power loss and excellent heat resistance, and the practical advantage of efficiently smoothing and flattening the surface thereof is particularly great.
- the techniques disclosed herein may be particularly preferably applied to polishing the single crystal surface of silicon carbide.
- the polishing composition disclosed herein can be used when polishing a substrate, for example, in an embodiment including the following operations. That is, a polishing liquid (slurry) containing any of the polishing compositions disclosed herein is prepared. To prepare the above polishing liquid, the polishing liquid is prepared by adjusting the concentration of the polishing composition (for example, diluting the polishing composition), adjusting the pH of the polishing composition, or the like. Can be included. Alternatively, the above-mentioned polishing composition may be used as it is as a polishing liquid.
- the above-mentioned polishing liquid is prepared by mixing the agents, diluting one or more agents before the mixing, and after the mixing. Diluting the mixture, etc. may be included.
- the polishing liquid is then supplied to the polishing surface and polished by a conventional method performed by those skilled in the art. For example, it is a method in which a substrate is set in a general polishing apparatus and the polishing liquid is supplied to a polishing surface of the substrate through a polishing pad of the polishing apparatus. Typically, while continuously supplying the polishing liquid, the polishing pad is pressed against the polishing surface of the substrate to move the two relative to each other (for example, rotational movement). Polishing of the substrate is completed through such a polishing step.
- a polishing method for polishing a substrate and a method for manufacturing a substrate using the polishing method are provided.
- the polishing method is characterized by including the step of polishing the substrate with the polishing composition disclosed herein.
- the polishing method includes a step of performing preliminary polishing (preliminary polishing step) and a step of performing finish polishing (finish polishing step).
- the pre-polishing step is a polishing step that is placed immediately prior to the finishing polishing step.
- the preliminary polishing step may be a one-step polishing step, or may be a plurality of two or more steps of polishing steps.
- the finish polishing step referred to here is a step of performing finish polishing on a substrate on which preliminary polishing has been performed, and is the last of the polishing steps performed using a polishing slurry containing abrasive grains (that is, that is). It refers to the polishing process that is arranged (on the most downstream side).
- the polishing composition disclosed herein may be used in one step of the preliminary polishing step or may be used in the finishing polishing step. , May be used in both the pre-polishing step and the finishing polishing step.
- Preliminary polishing and finish polishing can be performed by either a single-sided polishing device or a double-sided polishing device.
- a single-sided polishing device a substrate is attached to a ceramic plate with wax, the substrate is held by a holder called a carrier, and a polishing pad is pressed against one side of the substrate while supplying a polishing composition to make the two relative to each other.
- One side of the object to be polished is polished by moving it. The movement is, for example, a rotational movement.
- the substrate is held by a holder called a carrier, and while the polishing composition is supplied from above, the polishing pads are pressed against the facing surfaces of the substrate and rotated in the relative direction of the substrate. Polish both sides at the same time.
- the polishing pad used in each polishing process disclosed here is not particularly limited.
- any of non-woven fabric type, suede type, rigid polyurethane foam type, those containing abrasive grains, those containing no abrasive grains and the like may be used.
- a non-woven fabric type or a rigid foamed polyurethane type polishing pad containing no abrasive grains can be preferably adopted.
- Substrates polished by the methods disclosed herein are typically cleaned after polishing. This cleaning can be performed using a suitable cleaning solution.
- the cleaning solution to be used is not particularly limited, and known and commonly used cleaning solutions can be appropriately selected and used.
- the polishing method disclosed herein may include any other steps in addition to the preliminary polishing step and the finishing polishing step.
- Examples of such a step include a mechanical polishing step and a wrapping step performed before the preliminary polishing step.
- the mechanical polishing step the substrate is polished using a liquid in which diamond abrasive grains are dispersed in a solvent.
- the dispersion is oxidant-free.
- the lapping step is a step of pressing the surface of a polishing surface plate, for example, a cast iron surface plate, against a substrate to polish it. Therefore, the polishing pad is not used in the wrapping process.
- the wrapping step is typically performed by supplying abrasive grains between the polishing surface plate and the substrate.
- the abrasive grains are typically diamond abrasive grains.
- the polishing method disclosed herein may include an additional step before the preliminary polishing step or between the preliminary polishing step and the finishing polishing step.
- the additional steps are, for example, a cleaning step and a polishing step.
- the techniques disclosed herein may include a method of making a substrate that includes a polishing step by any of the polishing methods described above and the provision of a substrate made by that method.
- the method for manufacturing the substrate is, for example, a method for manufacturing a silicon carbide substrate. That is, according to the techniques disclosed herein, a method of manufacturing a substrate, including polishing any of the substrates disclosed herein by any of the methods disclosed herein, and a substrate produced by that method. Is provided. According to the above manufacturing method, a substrate having improved surface quality, for example, a silicon carbide substrate can be efficiently provided.
- Example 1 Fumed silica, potassium permanganate (KMnO 4 ) as an oxidizing agent, calcium nitrate as a metal salt, and deionized water were mixed to prepare the polishing composition of this example.
- the concentration of fumed silica was 1%
- the concentration of potassium permanganate was 260 mmol / L
- the concentration of calcium nitrate was 15 mmol / L.
- the pH of the polishing composition is as shown in Table 1.
- the fumed silica one having an average primary particle size of 30 nm and an average secondary particle size of 150 nm was used.
- Example 2 The polishing composition of each example was prepared in the same manner as in Example 1 except that the concentration of calcium nitrate was set to the concentration shown in Table 1.
- Example 4 The polishing composition of each example was prepared in the same manner as in Example 1 except that the concentration of the oxidizing agent was 80 mmol / L and the concentration of calcium nitrate was the concentration shown in Table 1.
- Example 7 The polishing compositions of each example were prepared in the same manner as in Example 4 except that the types and concentrations of the metal salts were shown in Table 1.
- Example 9 The polishing compositions of each example were prepared in the same manner as in Example 4 except that the concentration of calcium nitrate was 15 mmol / L and the concentration of fumed silica was the concentration shown in Table 1.
- Example 12 to 13 The polishing compositions of each example were prepared in the same manner as in Example 4 except that the types and concentrations of the metal salts were shown in Table 1.
- the metal salt content was 10.
- the polishing rate was improved as compared with Comparative Examples 1 to 4 having a millimole / L or less.
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Abstract
L'invention fournit une composition pour polissage qui contient une silice sublimée, un oxydant et un sel métallique. Cette composition pour polissage contient plus de 10millimoles/L dudit sel métallique.
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JP2001189296A (ja) * | 1999-12-28 | 2001-07-10 | Nec Corp | 金属配線形成方法 |
JP2007520050A (ja) * | 2003-09-11 | 2007-07-19 | キャボット マイクロエレクトロニクス コーポレイション | 化学的機械的研磨組成物およびその使用方法 |
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JP2001189296A (ja) * | 1999-12-28 | 2001-07-10 | Nec Corp | 金属配線形成方法 |
JP2007520050A (ja) * | 2003-09-11 | 2007-07-19 | キャボット マイクロエレクトロニクス コーポレイション | 化学的機械的研磨組成物およびその使用方法 |
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