WO2021109582A1 - Magnetic memory and preparation method therefor - Google Patents

Magnetic memory and preparation method therefor Download PDF

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WO2021109582A1
WO2021109582A1 PCT/CN2020/103232 CN2020103232W WO2021109582A1 WO 2021109582 A1 WO2021109582 A1 WO 2021109582A1 CN 2020103232 W CN2020103232 W CN 2020103232W WO 2021109582 A1 WO2021109582 A1 WO 2021109582A1
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mram
array
stt
sot
magnetic tunnel
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孟皓
迟克群
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浙江驰拓科技有限公司
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B61/00Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/01Manufacture or treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/10Magnetoresistive devices
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N50/00Galvanomagnetic devices
    • H10N50/80Constructional details
    • H10N50/85Magnetic active materials
    • HELECTRICITY
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    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N59/00Integrated devices, or assemblies of multiple devices, comprising at least one galvanomagnetic or Hall-effect element covered by groups H10N50/00 - H10N52/00

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Abstract

Provided are a magnetic memory and a preparation method therefor. The magnetic memory comprises at least one hybrid storage array, the hybrid storage array comprising an STT-MRAM array and an SOT-MRAM array arranged adjacent to each other, wherein the STT-MRAM array comprises STT-MRAM storage units arranged in an array, the SOT-MRAM array comprises SOT-MRAM storage units arranged in an array, and the STT-MRAM storage units and the SOT-MRAM storage units have the same laminated structure. The magnetic memory of the present invention can not only fulfil the long-term storage requirement of a large amount of data, but also fulfil the frequent erasure and writing of the large amount of data.

Description

磁性存储器及其制备方法Magnetic memory and preparation method thereof 技术领域Technical field
本发明涉及磁性存储器技术领域,尤其涉及一种磁性存储器及其制备方法。The present invention relates to the technical field of magnetic memory, in particular to a magnetic memory and a preparation method thereof.
背景技术Background technique
随着存储器技术的发展,在传统的SRAM(Static Random Access Memory,静态随机存取存储器)、DRAM(Dynamic Random Access Memory,动态随机存取存储器)的基础上,出现了一种新型的存储器类别——MRAM(Magnetic Random Access Memory,磁性随机存取存储器),其使用寿命高于固态硬盘,数据非易失性好于SRAM、DRAM,器件密度高于SRAM,具有替代现行的存储器的应用潜力。With the development of memory technology, based on the traditional SRAM (Static Random Access Memory) and DRAM (Dynamic Random Access Memory, dynamic random access memory), a new type of memory has emerged— —MRAM (Magnetic Random Access Memory) has a longer service life than solid-state hard disks, better data non-volatility than SRAM and DRAM, and higher device density than SRAM, which has the potential to replace current memory.
但是,不论哪种类型的存储器,都无法实现既能满足大量数据长时间保存,同时还能满足大量数据的频繁擦写。因此有必要提出一种新型的存储器,去满足多场景的应用需求。However, no matter which type of memory, it can not only meet the long-term storage of large amounts of data, but also meet the frequent erasing and writing of large amounts of data. Therefore, it is necessary to propose a new type of memory to meet the application requirements of multiple scenarios.
发明内容Summary of the invention
有鉴于此,本发明提供一种磁性存储器及其制备方法,具有多种存储特性,既能满足大量数据长时间保存,同时还能满足大量数据的频繁擦写。In view of this, the present invention provides a magnetic memory and a preparation method thereof, which have multiple storage characteristics, which can not only meet the long-term storage of a large amount of data, but also meet the frequent erasing and writing of a large amount of data.
第一方面,本发明提供一种磁性存储器,包括至少一个混合存储阵列,所述混合存储阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,In a first aspect, the present invention provides a magnetic memory including at least one hybrid memory array, the hybrid memory array including an STT-MRAM array and a SOT-MRAM array arranged adjacently, wherein:
所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。The STT-MRAM array includes STT-MRAM storage units arranged in an array, the SOT-MRAM array includes SOT-MRAM storage units arranged in an array, and the STT-MRAM storage unit is connected to the SOT-MRAM storage unit. The units have the same stacked structure.
可选地,所述STT-MRAM存储单元包括第一磁性隧道结(MTJ),所述SOT-MRAM存储单元包括第二磁性隧道结(MTJ),所述第一磁性隧道结与所述第二磁性隧道结具有相同的层叠结构。Optionally, the STT-MRAM memory cell includes a first magnetic tunnel junction (MTJ), the SOT-MRAM memory cell includes a second magnetic tunnel junction (MTJ), and the first magnetic tunnel junction and the second magnetic tunnel junction The magnetic tunnel junction has the same laminated structure.
可选地,所述STT-MRAM阵列中全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。Optionally, the diameter size of the first magnetic tunnel junction of all STT-MRAM memory cells in the STT-MRAM array is the same; the diameter size of the second magnetic tunnel junction of all SOT-MRAM memory cells in the SOT-MRAM array the same.
可选地,所述STT-MRAM阵列中同一列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离所述SOT-MRAM阵列最远的一列或行至距离所述SOT-MRAM阵列最近的一列或行,各列或行的STT-MRAM存储单 元的第一磁性隧道结的直径尺寸逐渐变小;Optionally, the diameters of the first magnetic tunnel junctions of the STT-MRAM memory cells in the same column or row in the STT-MRAM array are the same, and from the farthest column or row to the SOT-MRAM array. In the nearest column or row of the SOT-MRAM array, the diameter of the first magnetic tunnel junction of the STT-MRAM memory cell in each column or row gradually becomes smaller;
所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。The diameters of the second magnetic tunnel junctions of all SOT-MRAM memory cells in the SOT-MRAM array are the same.
可选地,所述STT-MRAM阵列划分为相邻设置的STT-MRAM第一子阵列和STT-MRAM第二子阵列,其中所述STT-MRAM第二子阵列与所述SOT-MRAM阵列相邻,所述STT-MRAM第一子阵列中全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;所述STT-MRAM第二子阵列中同一列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离所述SOT-MRAM阵列最远的一列或行至距离所述SOT-MRAM阵列最近的一列或行,各列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;Optionally, the STT-MRAM array is divided into adjacently arranged STT-MRAM first sub-array and STT-MRAM second sub-array, wherein the STT-MRAM second sub-array is similar to the SOT-MRAM array Next, the diameters of the first magnetic tunnel junctions of all STT-MRAM memory cells in the first sub-array of STT-MRAM are the same; those of STT-MRAM memory cells in the same column or row in the second sub-array of STT-MRAM The diameters of the first magnetic tunnel junctions are the same, and from the column or row farthest from the SOT-MRAM array to the column or row closest to the SOT-MRAM array, the size of each column or row of STT-MRAM memory cells The diameter of the first magnetic tunnel junction gradually becomes smaller;
所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。The diameters of the second magnetic tunnel junctions of all SOT-MRAM memory cells in the SOT-MRAM array are the same.
可选地,所述STT-MRAM存储单元还包括耦合于所述第一磁性隧道结的第一顶电极,所述第一顶电极包括层叠设置的第一预制层和第一功能层,所述第一预制层与所述第一磁性隧道结接触;Optionally, the STT-MRAM memory cell further includes a first top electrode coupled to the first magnetic tunnel junction, and the first top electrode includes a first prefabricated layer and a first functional layer that are stacked, and the The first prefabricated layer is in contact with the first magnetic tunnel junction;
所述SOT-MRAM存储单元还包括耦合于所述第二磁性隧道结的第二顶电极,所述第二顶电极包括层叠设置的第二预制层和第二功能层,所述第二预制层与所述第二磁性隧道结接触。The SOT-MRAM memory cell further includes a second top electrode coupled to the second magnetic tunnel junction, and the second top electrode includes a second prefabricated layer and a second functional layer that are stacked and arranged, and the second prefabricated layer In contact with the second magnetic tunnel junction.
可选地,所述第一预制层的横截面形状和尺寸与所述第一磁性隧道结相同,所述第二预制层的横截面形状和尺寸与所述第二磁性隧道结相同;Optionally, the cross-sectional shape and size of the first prefabricated layer are the same as the first magnetic tunnel junction, and the cross-sectional shape and size of the second prefabricated layer are the same as the second magnetic tunnel junction;
所述第一功能层的横截面形状为圆形,且所述第一功能层的直径尺寸大于或者等于所述第一磁性隧道结的直径尺寸;所述第二功能层的横截面形状为矩形,且所述第二功能层的宽度大于或者等于所述第二磁性隧道结的直径尺寸。The cross-sectional shape of the first functional layer is circular, and the diameter of the first functional layer is greater than or equal to the diameter of the first magnetic tunnel junction; the cross-sectional shape of the second functional layer is rectangular And the width of the second functional layer is greater than or equal to the diameter of the second magnetic tunnel junction.
可选地,所述第一预制层和所述第二预制层的材料相同,选自Pt、Ta、W、Au和Cu中的一种;Optionally, the materials of the first prefabricated layer and the second prefabricated layer are the same, and are selected from one of Pt, Ta, W, Au, and Cu;
所述第一功能层与所述第二功能层的材料相同,选自Pt、Ta、W、Au和Cu中的一种。The first functional layer and the second functional layer are made of the same material, and are selected from one of Pt, Ta, W, Au, and Cu.
可选地,当所述磁性存储器包括多个混合存储阵列时,所述多个混合存储阵列依次排列,每个混合存储阵列的阵列排布方式相同,不同混合存储阵列中的STT-MRAM阵列和SOT-MRAM阵列的大小各不相同。Optionally, when the magnetic memory includes a plurality of hybrid storage arrays, the plurality of hybrid storage arrays are arranged in sequence, and the array arrangement of each hybrid storage array is the same, and the STT-MRAM arrays in different hybrid storage arrays are The size of the SOT-MRAM array varies.
第二方面,本发明提供一种磁性存储器的制备方法,所述方法包括:In a second aspect, the present invention provides a method for manufacturing a magnetic memory, the method including:
在基底上沉积磁性隧道结多层薄膜并在所述磁性隧道结多层薄膜上沉积顶电极预制层材料薄膜;Depositing a magnetic tunnel junction multilayer film on the substrate and depositing a top electrode prefabricated layer material film on the magnetic tunnel junction multilayer film;
通过光刻和刻蚀,在基底上形成至少一个预制结构阵列,所述预制结构阵列包括相邻设置的第一预制结构阵列和第二预制结构阵列,所述第一预制结构阵列用于形成STT-MRAM阵列,所述第二预制结构阵列用于形成SOT-MRAM阵列,其中所述第一预制结构阵列包括按阵列排布的第一预制单元,所述第一预制单元包括第一磁性隧道结和第一磁性隧道结上的第一预制层,所述第二预制结构阵列包括按阵列排布的第二预制单元,所述第二预制单元包括第二磁性隧道结和第二磁性隧道结上的第二预制层;At least one array of prefabricated structures is formed on the substrate by photolithography and etching, the array of prefabricated structures includes a first array of prefabricated structures and a second array of prefabricated structures that are arranged adjacently, and the first array of prefabricated structures is used to form STT -MRAM array, the second prefabricated structure array is used to form a SOT-MRAM array, wherein the first prefabricated structure array includes first prefabricated units arranged in an array, and the first prefabricated units include first magnetic tunnel junctions And a first prefabricated layer on the first magnetic tunnel junction, the second prefabricated structure array includes second prefabricated units arranged in an array, the second prefabricated unit includes a second magnetic tunnel junction and a second magnetic tunnel junction The second prefabricated layer;
采用绝缘介质填充满所述预制结构阵列中的空隙,并进行表面平坦化处理,形成一平坦表面,所述平坦表面位于所述第一预制层和所述第二预制层上方;Filling the voids in the prefabricated structure array with an insulating medium, and performing surface planarization treatment to form a flat surface, the flat surface being located above the first prefabricated layer and the second prefabricated layer;
通过光刻和刻蚀,在所述第一预制层和所述第二预制层上方形成孔槽;Forming holes and grooves above the first prefabricated layer and the second prefabricated layer by photolithography and etching;
沉积顶电极功能层材料薄膜,以填充所述孔槽,并对所述顶电极功能层材料薄膜进行化学机械抛光或者刻蚀,以在所述第一预制层上方形成第一功能层,并在所述第二预制层上方形成第二功能层。A material film of the top electrode functional layer is deposited to fill the holes, and the material film of the top electrode functional layer is chemically mechanically polished or etched to form a first functional layer above the first prefabricated layer. A second functional layer is formed on the second prefabricated layer.
本发明提供的磁性存储器,利用STT-MRAM阵列和SOT-MRAM阵列所具有的不同存储特性,既能满足大量数据长时间保存,同时还能满足大量数据的频繁擦写。同时,由于STT-MRAM存储单元和SOT-MRAM存储单元采用相同的层叠结构,具有很好的工艺兼容性,因此本发明实施例提供的磁性存储器便于制造。The magnetic memory provided by the present invention utilizes the different storage characteristics of the STT-MRAM array and the SOT-MRAM array, which can not only meet the long-term storage of a large amount of data, but also meet the frequent erasing and writing of a large amount of data. At the same time, since the STT-MRAM memory cell and the SOT-MRAM memory cell adopt the same layered structure and have good process compatibility, the magnetic memory provided by the embodiment of the present invention is easy to manufacture.
附图说明Description of the drawings
图1为本发明一实施例的磁性存储器的存储单元的结构示意图;FIG. 1 is a schematic structural diagram of a storage unit of a magnetic memory according to an embodiment of the present invention;
图2为本发明一实施例的磁性存储器的阵列分布(只显示磁性隧道结)的俯视图;2 is a top view of the array distribution of the magnetic memory (only the magnetic tunnel junction is shown) according to an embodiment of the present invention;
图3为本发明一实施例的磁性存储器的阵列分布(显示磁性隧道结上方顶电极)的俯视图;FIG. 3 is a top view of the array distribution of the magnetic memory (showing the top electrode above the magnetic tunnel junction) according to an embodiment of the present invention;
图4为本发明一实施例的磁性存储器的存储区域功能视图;4 is a functional view of a storage area of a magnetic memory according to an embodiment of the present invention;
图5为本发明一实施例的磁性存储器的阵列分布(只显示磁性隧道结)的俯视图;5 is a top view of an array distribution of a magnetic memory (only the magnetic tunnel junction is shown) according to an embodiment of the present invention;
图6为本发明一实施例的磁性存储器的阵列分布(显示磁性隧道结上方顶电极)的俯视图;6 is a top view of an array distribution of a magnetic memory (showing the top electrode above the magnetic tunnel junction) according to an embodiment of the present invention;
图7为本发明一实施例的磁性存储器的存储区域功能视图;Fig. 7 is a functional view of a storage area of a magnetic memory according to an embodiment of the present invention;
图8为本发明一实施例的磁性存储器的阵列分布(只显示磁性隧道结)的俯视图;FIG. 8 is a top view of an array distribution of a magnetic memory (only the magnetic tunnel junction is shown) according to an embodiment of the present invention;
图9为本发明一实施例的磁性存储器的阵列分布(显示磁性隧道结上方顶电极)的俯视图;9 is a top view of an array distribution of a magnetic memory (showing the top electrode above the magnetic tunnel junction) according to an embodiment of the present invention;
图10为本发明一实施例的磁性存储器的存储区域功能视图;10 is a functional view of a storage area of a magnetic memory according to an embodiment of the present invention;
图11为本发明又一实施例的磁性存储器的存储区域功能视图;11 is a functional view of a storage area of a magnetic memory according to another embodiment of the present invention;
图12A至图12E为本发明一实施例的磁性存储器的制备方法各步骤的结构示意图。12A to 12E are structural schematic diagrams of each step of a method for manufacturing a magnetic memory according to an embodiment of the present invention.
具体实施方式Detailed ways
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。In order to make the objectives, technical solutions, and advantages of the embodiments of the present invention clearer, the following will clearly and completely describe the technical solutions in the embodiments of the present invention with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments It is only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
实施例一Example one
本发明一实施例提供一种磁性存储器,包括一个混合存储阵列,该混合存储阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,An embodiment of the present invention provides a magnetic memory including a hybrid memory array, the hybrid memory array includes an STT-MRAM array and a SOT-MRAM array that are arranged adjacently, wherein,
所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。The STT-MRAM array includes STT-MRAM storage units arranged in an array, the SOT-MRAM array includes SOT-MRAM storage units arranged in an array, and the STT-MRAM storage unit is connected to the SOT-MRAM storage unit. The units have the same stacked structure.
从STT-MRAM阵列和SOT-MRAM阵列中分别选取一个存储单元进行图示,如图1所示,本实施例中,所述STT-MRAM存储单元包括第一磁性隧道结(MTJ)10以及耦合于第一磁性隧道结的第一顶电极11,第一磁性隧道结10包括第一参考层101、第一势垒层102和第一自由层103,第一顶电极11包括第一预制层111和第一功能层112,第一预制层111与第一自由层103接触,第一预制层111用于防止第一自由层103在制备过程中发生氧化。A memory cell is selected from the STT-MRAM array and the SOT-MRAM array for illustration. As shown in FIG. 1, in this embodiment, the STT-MRAM memory cell includes a first magnetic tunnel junction (MTJ) 10 and a coupling On the first top electrode 11 of the first magnetic tunnel junction, the first magnetic tunnel junction 10 includes a first reference layer 101, a first barrier layer 102 and a first free layer 103, and the first top electrode 11 includes a first prefab layer 111 And the first functional layer 112, the first prefabricated layer 111 is in contact with the first free layer 103, and the first prefabricated layer 111 is used to prevent the first free layer 103 from being oxidized during the preparation process.
所述SOT-MRAM存储单元包括第二磁性隧道结(MTJ)20以及耦合于第二磁性隧道结的第二顶电极21,第二磁性隧道结20包括第二参考层201、第二势垒层202和第二自由层203,第二顶电极21包括第二预制层211和第二功能层212,第二预制层211与第二自由层203接触,第二预制层211用于防止第二 自由层203在制备过程中发生氧化。The SOT-MRAM memory cell includes a second magnetic tunnel junction (MTJ) 20 and a second top electrode 21 coupled to the second magnetic tunnel junction. The second magnetic tunnel junction 20 includes a second reference layer 201 and a second barrier layer. 202 and a second free layer 203. The second top electrode 21 includes a second prefabricated layer 211 and a second functional layer 212. The second prefabricated layer 211 is in contact with the second free layer 203. The second prefabricated layer 211 is used to prevent the second free The layer 203 is oxidized during the preparation process.
进一步地,所述第一预制层111的横截面形状和尺寸与所述第一磁性隧道结10相同,所述第二预制层211的横截面形状和尺寸与所述第二磁性隧道结20相同。所述第一功能层112的横截面形状为圆形,且所述第一功能层112的直径尺寸大于或者等于所述第一磁性隧道结10的直径尺寸;所述第二功能层212的横截面形状为矩形,且所述第二功能层212的宽度大于或者等于所述第二磁性隧道结20的直径尺寸。所述第一预制层111和所述第二预制层211的材料相同,选自Pt、Ta、W、Au和Cu中的一种;所述第一功能层112与所述第二功能层212的材料相同,选自Pt、Ta、W、Au和Cu中的一种。Further, the cross-sectional shape and size of the first prefabricated layer 111 are the same as those of the first magnetic tunnel junction 10, and the cross-sectional shape and size of the second prefabricated layer 211 are the same as those of the second magnetic tunnel junction 20 . The cross-sectional shape of the first functional layer 112 is circular, and the diameter of the first functional layer 112 is greater than or equal to the diameter of the first magnetic tunnel junction 10; the cross-sectional shape of the second functional layer 212 The cross-sectional shape is rectangular, and the width of the second functional layer 212 is greater than or equal to the diameter of the second magnetic tunnel junction 20. The first prefabricated layer 111 and the second prefabricated layer 211 are made of the same material, and are selected from one of Pt, Ta, W, Au and Cu; the first functional layer 112 and the second functional layer 212 The material is the same, selected from one of Pt, Ta, W, Au and Cu.
本发明实施例提供的磁性存储器,利用STT-MRAM阵列和SOT-MRAM阵列所具有的不同存储特性,既能满足大量数据长时间保存,同时还能满足大量数据的频繁擦写。同时,由于STT-MRAM存储单元和SOT-MRAM存储单元采用相同的层叠结构,具有很好的工艺兼容性,因此本发明实施例提供的磁性存储器便于制造。The magnetic memory provided by the embodiment of the present invention utilizes the different storage characteristics of the STT-MRAM array and the SOT-MRAM array, which can not only meet the long-term storage of a large amount of data, but also meet the frequent erasing and writing of a large amount of data. At the same time, since the STT-MRAM memory cell and the SOT-MRAM memory cell adopt the same layered structure and have good process compatibility, the magnetic memory provided by the embodiment of the present invention is easy to manufacture.
进一步地,由于存储单元中磁性隧道结的直径尺寸直接影响存储单元的存储特性,在本发明实施例中,参阅图2和图3,图2示出了本实施例的磁性存储器(只显示磁性隧道结)的俯视图,图3示出了本实施例的磁性存储器(显示磁性隧道结上方的顶电极)的俯视图。STT-MRAM阵列中的全部STT-MRAM存储单元的第一磁性隧道结刻蚀成圆柱形,且全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;SOT-MRAM阵列中的全部SOT-MRAM存储单元的第二磁性隧道结刻蚀成圆柱形,且全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。一般地,STT-MRAM存储单元的第一磁性隧道结的直径尺寸会大于SOT-MRAM存储单元的第二磁性隧道结的直径尺寸。Further, since the diameter of the magnetic tunnel junction in the memory cell directly affects the storage characteristics of the memory cell, in the embodiment of the present invention, referring to FIGS. 2 and 3, FIG. 2 shows the magnetic memory of the present embodiment (only showing magnetic A top view of the tunnel junction), and FIG. 3 shows a top view of the magnetic memory (showing the top electrode above the magnetic tunnel junction) of this embodiment. The first magnetic tunnel junctions of all STT-MRAM memory cells in the STT-MRAM array are etched into a cylindrical shape, and the diameters of the first magnetic tunnel junctions of all STT-MRAM memory cells are the same; all SOTs in the SOT-MRAM array -The second magnetic tunnel junction of the MRAM memory cell is etched into a cylindrical shape, and the diameter of the second magnetic tunnel junction of all the SOT-MRAM memory cells is the same. Generally, the diameter of the first magnetic tunnel junction of the STT-MRAM memory cell is larger than the diameter of the second magnetic tunnel junction of the SOT-MRAM memory cell.
上述实施例一提供的磁性存储器,由于STT-MRAM阵列具有高密度、非易失性的特点,因此STT-MRAM阵列形成一个“数据保存区”,用于需要大量读操作、少量写操作的存储情景,例如存储“程序”或“模型”,而SOT-MRAM阵列具有较高的使用寿命和非易失性的特点,可以形成一个“高频擦写区”,用于需要大量写操作的存储情景,例如存储“计算数据”。将磁性存储器以存储区域的视图形式进行展示,如图4所示,磁性存储器包括数据保存区和高频擦写区。The magnetic memory provided by the first embodiment above, because the STT-MRAM array has the characteristics of high density and non-volatility, the STT-MRAM array forms a "data storage area" for storage that requires a large number of read operations and a small amount of write operations. Scenarios, such as storing "programs" or "models", and the SOT-MRAM array has a high service life and non-volatile characteristics, which can form a "high-frequency erasing area" for storage that requires a large number of write operations Scenarios such as storing "calculation data". The magnetic memory is shown in the view of the storage area. As shown in Figure 4, the magnetic memory includes a data storage area and a high-frequency erasing area.
实施例二Example two
在本发明另一实施例中,磁性存储器包括一个混合存储阵列,该混合存储 阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,In another embodiment of the present invention, the magnetic memory includes a hybrid memory array, and the hybrid memory array includes an STT-MRAM array and a SOT-MRAM array arranged adjacently, wherein,
所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。The STT-MRAM array includes STT-MRAM storage units arranged in an array, the SOT-MRAM array includes SOT-MRAM storage units arranged in an array, and the STT-MRAM storage unit is connected to the SOT-MRAM storage unit. The units have the same stacked structure.
本发明实施例中,STT-MRAM存储单元与SOT-MRAM存储单元的层叠结构与实施例一相同,在此不再赘述。请参阅图5和图6,图5示出了本实施例的磁性存储器(只显示磁性隧道结)的俯视图,图6示出了本实施例的磁性存储器(显示磁性隧道结上方的顶电极)的俯视图。STT-MRAM阵列中同一列的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离SOT-MRAM阵列最远的一列至距离SOT-MRAM阵列最近的一列,各列的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。一般地,STT-MRAM阵列中最靠近SOT-MRAM阵列的一列STT-MRAM存储单元的直径尺寸依然要大于SOT-MRAM存储单元的直径尺寸。In the embodiment of the present invention, the stacked structure of the STT-MRAM memory cell and the SOT-MRAM memory cell is the same as that of the first embodiment, and will not be repeated here. Please refer to FIGS. 5 and 6. FIG. 5 shows a top view of the magnetic memory of this embodiment (showing only the magnetic tunnel junction), and FIG. 6 shows the magnetic memory of this embodiment (showing the top electrode above the magnetic tunnel junction) Top view. The diameter of the first magnetic tunnel junction of the STT-MRAM memory cells in the same column in the STT-MRAM array is the same, and from the column farthest from the SOT-MRAM array to the column closest to the SOT-MRAM array, the STT- The diameter size of the first magnetic tunnel junction of the MRAM memory cell gradually becomes smaller; the diameter size of the second magnetic tunnel junction of all SOT-MRAM memory cells in the SOT-MRAM array is the same. Generally, the diameter size of the column of STT-MRAM memory cells closest to the SOT-MRAM array in the STT-MRAM array is still larger than the diameter size of the SOT-MRAM memory cells.
图5和图6中,STT-MRAM阵列和SOT-MRAM阵列横向排列,可以理解的是,当STT-MRAM阵列和SOT-MRAM阵列竖向排列时,STT-MRAM阵列中同一行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离SOT-MRAM阵列最远的一行至距离SOT-MRAM阵列最近的一行,各行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。In Figures 5 and 6, the STT-MRAM array and the SOT-MRAM array are arranged horizontally. It can be understood that when the STT-MRAM array and the SOT-MRAM array are arranged vertically, the STT-MRAM in the same row in the STT-MRAM array The diameter size of the first magnetic tunnel junction of the memory cell is the same, and from the row farthest from the SOT-MRAM array to the row closest to the SOT-MRAM array, the diameter size of the first magnetic tunnel junction of each row of the STT-MRAM memory cell Gradually become smaller; the diameter of the second magnetic tunnel junction of all SOT-MRAM memory cells in the SOT-MRAM array is the same.
上述实施例二提供的磁性存储器,SOT-MRAM阵列可以形成一个“高频擦写区”,用于存储频繁擦写的数据,STT-MRAM阵列的存储单元从左至右直径尺寸逐渐变小,因此从左至右非易失性减弱,擦写速度加快,使用寿命增长。即最左侧非易失性最强,擦写速度最慢,使用寿命最短,最右侧非易失性最差,擦写速度最快,使用寿命最短。因此该STT-MRAM阵列形成一个自左至右性能逐渐变化的“复用区”,当数据擦写不频繁时,数据保存在“复用区”的最左侧;当需要存储频繁擦写的数据时,先存储在“高频擦写区”,然后再存储在“复用区”的右侧。将磁性存储器以存储区域的视图形式进行展示,如图7所示,磁性存储器包括复用区和高频擦写区。In the magnetic memory provided by the second embodiment above, the SOT-MRAM array can form a "high-frequency erasing area" for storing frequently erased data. The memory cells of the STT-MRAM array gradually become smaller in diameter from left to right. Therefore, the non-volatility is weakened from left to right, the erasing speed is accelerated, and the service life is increased. That is, the leftmost side has the strongest non-volatility, the slowest erasing speed and the shortest service life, and the rightmost side has the worst non-volatility, the fastest erasing speed and the shortest service life. Therefore, the STT-MRAM array forms a "multiplex area" whose performance gradually changes from left to right. When the data is not frequently erased and written, the data is stored on the leftmost side of the "multiplex area"; when it is necessary to store frequently erased and written data When the data is stored, it is first stored in the "high frequency erasing area", and then stored on the right side of the "multiplexing area". The magnetic memory is shown in the view of the storage area. As shown in FIG. 7, the magnetic memory includes a multiplexing area and a high-frequency erasing area.
实施例三Example three
在本发明另一实施例中,磁性存储器包括一个混合存储阵列,该混合存储 阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,In another embodiment of the present invention, the magnetic memory includes a hybrid memory array, and the hybrid memory array includes an STT-MRAM array and a SOT-MRAM array arranged adjacently, wherein,
所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。The STT-MRAM array includes STT-MRAM storage units arranged in an array, the SOT-MRAM array includes SOT-MRAM storage units arranged in an array, and the STT-MRAM storage unit is connected to the SOT-MRAM storage unit. The units have the same stacked structure.
本发明实施例中,STT-MRAM存储单元与SOT-MRAM存储单元的层叠结构与实施例一相同,在此不再赘述。请参阅图8和图9,图8示出了本实施例的磁性存储器(只显示磁性隧道结)的俯视图,图9示出了本实施例的磁性存储器(显示磁性隧道结上方的顶电极)的俯视图。STT-MRAM阵列划分为相邻设置的STT-MRAM第一子阵列和STT-MRAM第二子阵列,其中所述STT-MRAM第二子阵列与所述SOT-MRAM阵列相邻,所述STT-MRAM第一子阵列中全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;所述STT-MRAM第二子阵列中同一列的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离所述SOT-MRAM阵列最远的一列至距离所述SOT-MRAM阵列最近的一列,各列的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。一般地,STT-MRAM阵列中最靠近SOT-MRAM阵列的一列STT-MRAM存储单元的直径尺寸依然要大于SOT-MRAM存储单元的直径尺寸。In the embodiment of the present invention, the stacked structure of the STT-MRAM memory cell and the SOT-MRAM memory cell is the same as that of the first embodiment, and will not be repeated here. Please refer to FIGS. 8 and 9. FIG. 8 shows a top view of the magnetic memory of this embodiment (showing only the magnetic tunnel junction), and FIG. 9 shows the magnetic memory of this embodiment (showing the top electrode above the magnetic tunnel junction) Top view. The STT-MRAM array is divided into adjacently arranged STT-MRAM first sub-array and STT-MRAM second sub-array, wherein the STT-MRAM second sub-array is adjacent to the SOT-MRAM array, and the STT-MRAM second sub-array is adjacent to the SOT-MRAM array. The diameter size of the first magnetic tunnel junction of all STT-MRAM memory cells in the first sub-array of MRAM is the same; the diameter size of the first magnetic tunnel junction of the STT-MRAM memory cells in the same column in the second sub-array of STT-MRAM The same, and from the column farthest from the SOT-MRAM array to the column closest to the SOT-MRAM array, the diameter size of the first magnetic tunnel junction of the STT-MRAM memory cell in each column gradually becomes smaller; The diameter size of the second magnetic tunnel junction of all SOT-MRAM memory cells in the SOT-MRAM array is the same. Generally, the diameter size of the column of STT-MRAM memory cells closest to the SOT-MRAM array in the STT-MRAM array is still larger than the diameter size of the SOT-MRAM memory cells.
图8和图9中,STT-MRAM阵列和SOT-MRAM阵列横向排列,可以理解的是,当STT-MRAM阵列和SOT-MRAM阵列竖向排列时,STT-MRAM第二子阵列中同一行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离SOT-MRAM阵列最远的一行至距离SOT-MRAM阵列最近的一行,各行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。In Figures 8 and 9, the STT-MRAM array and the SOT-MRAM array are arranged horizontally. It can be understood that when the STT-MRAM array and the SOT-MRAM array are arranged vertically, the second sub-array of STT-MRAM in the same row The diameters of the first magnetic tunnel junctions of STT-MRAM memory cells are the same, and from the row farthest from the SOT-MRAM array to the row closest to the SOT-MRAM array, the first magnetic tunnel junction of each row of STT-MRAM memory cells The diameter size of SOT-MRAM gradually becomes smaller; the diameter size of the second magnetic tunnel junction of all SOT-MRAM memory cells in the SOT-MRAM array is the same.
上述实施例三提供的磁性存储器,SOT-MRAM阵列可以形成一个“高频擦写区”,用于存储频繁擦写的数据,具有高使用寿命、高擦写速度,非易失性与数据密度中等的特点;STT-MRAM第一子阵列形成一个“数据保存区”,用于长时间保存数据,具有强非易失性、高数据密度,使用寿命长、擦写速度中等的特点;STT-MRAM第二子阵列形成一个“复用区”,“复用区”功能介于“高频擦写区”和“数据保存区”之间,可以灵活复用,当数据保存量增大时,可以充当“数据保存区”;当频繁擦写的需求增加时,可以充当“高频擦写区”。将磁性存储器以存储区域的视图形式进行展示,如图10所示,磁性存储器包括 数据保存区、复用区和高频擦写区。In the magnetic memory provided by the third embodiment, the SOT-MRAM array can form a "high-frequency erasing area" for storing frequently erasable data, with high service life, high erasing speed, non-volatility, and data density. Moderate characteristics; the first sub-array of STT-MRAM forms a "data storage area" for storing data for a long time. It has the characteristics of strong non-volatility, high data density, long service life, and medium erasing speed; STT- The second sub-array of MRAM forms a "multiplexing area". The function of the "multiplexing area" is between the "high-frequency erasing area" and the "data storage area", which can be flexibly multiplexed. When the amount of data storage increases, It can serve as a "data storage area"; when the demand for frequent erasing and writing increases, it can serve as a "high-frequency erasing area." The magnetic memory is shown as a view of the storage area. As shown in Figure 10, the magnetic memory includes a data storage area, a multiplexing area, and a high-frequency erasing area.
另外,如果假定磁性存储器的整个存储区域由一个混合存储阵列来实现,可以想到,混合存储阵列中的STT-MRAM阵列和SOT-MRAM阵列的阵列规模肯定会非常大,因此,磁性存储器采用分布式设计,磁性存储器包括多个混合存储阵列,每个混合存储阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。有关每个混合存储阵列的结构描述,可以参考上述三个实施例,不再赘述。In addition, if it is assumed that the entire storage area of the magnetic memory is realized by a hybrid memory array, it is conceivable that the array scale of the STT-MRAM array and SOT-MRAM array in the hybrid memory array will definitely be very large. Therefore, the magnetic memory adopts distributed Design, the magnetic memory includes multiple hybrid memory arrays, each hybrid memory array includes adjacently arranged STT-MRAM array and SOT-MRAM array, wherein the STT-MRAM array includes STT-MRAM memory cells arranged in an array The SOT-MRAM array includes SOT-MRAM memory cells arranged in an array, and the STT-MRAM memory cells and the SOT-MRAM memory cells have the same layered structure. For the description of the structure of each hybrid storage array, reference may be made to the above three embodiments, which will not be repeated here.
基于实施三的磁性存储器,当磁性存储器包括多个混合存储阵列时,而每个混合存储阵列又可以形成图10所示的存储区域,最终磁性存储器的存储区域视图如图11所示。Based on the magnetic memory of the third embodiment, when the magnetic memory includes multiple hybrid storage arrays, and each hybrid storage array can form the storage area shown in FIG. 10, the final view of the storage area of the magnetic storage is shown in FIG. 11.
可以理解的是,当磁性存储器包括多个混合存储阵列时,通过多个混合存储阵列形成磁性存储器的整个存储区域,则在磁性存储器存储区域相同的前提下,能够使得每个混合存储阵列自身的规模变小。因此,这种分布式设计的优点在于,“高频擦写区”与“数据保存区”、“复用区”的距离较近,当存储的数据从“频繁擦写”转为“长时间保存”类型时,可以更方便的将数据转移;同时,分布式设计具有更多布局的灵活性,可以更方便的针对设计功能进行优化,例如:不同的混合存储阵列的三个功能区的占比与性能可以不同,增加“复用区”,更适用于数据存储时间短、保存的数据会被经常更改的应用场景,增加“数据保存区”,更适用于数据存储时间长、保存的数据长时间不会被更改的应用场景。It is understandable that when the magnetic storage includes multiple hybrid storage arrays, the entire storage area of the magnetic storage is formed by the multiple hybrid storage arrays. Under the premise that the storage area of the magnetic storage is the same, each hybrid storage array can make its own The scale becomes smaller. Therefore, the advantage of this distributed design is that the "high-frequency erasing area" is closer to the "data storage area" and the "multiplexing area". When the stored data changes from "frequent erasing" to "long-term erasing" In the “Save” type, the data can be transferred more conveniently; at the same time, the distributed design has more layout flexibility and can be more convenient to optimize design functions, for example: the three functional areas of different hybrid storage arrays occupy The ratio and performance can be different. The addition of "reuse area" is more suitable for application scenarios where the data storage time is short and the saved data will be frequently changed. The addition of "data storage area" is more suitable for long data storage time and saved data. Application scenarios that will not be changed for a long time.
本发明另一实施例提供一种磁性存储器的制备方法,所述方法包括:Another embodiment of the present invention provides a method for manufacturing a magnetic memory, the method including:
步骤S1、在基底上沉积磁性隧道结多层薄膜并在所述磁性隧道结多层薄膜上沉积顶电极预制层材料薄膜;Step S1, depositing a magnetic tunnel junction multilayer film on a substrate and depositing a top electrode prefabricated layer material film on the magnetic tunnel junction multilayer film;
本实施例中,如图12A所示,提供一基底300,基底300中可以预埋必须的底电极,在基底300上依次沉积用于形成参考层的第一磁性材料层301、用于形成势垒层的绝缘氧化物材料层302、用于形成自由层的第二磁性材料层303以及用于形成顶电极预制层的第一重金属材料层304,这里沉积一层重金属材料层304可以防止第二磁性材料层303发生氧化,同时起到连接顶电极功能层和自由层的作用,其中,第一磁性材料层301可以是单层铁磁材料,也可以由多层铁 磁材料、合成铁磁材料组成,绝缘氧化物材料层302包括MgO、AlO等氧化物,第二磁性材料层303可以由单层铁磁层或多层铁磁材料组成,也可以在上方再生长一层MgO等材料构成双势垒结构,第一重金属材料层304可以由Pt、Ta、W、Au、Cu等材料组成。In this embodiment, as shown in FIG. 12A, a substrate 300 is provided. In the substrate 300, necessary bottom electrodes can be pre-embedded, and a first magnetic material layer 301 for forming a reference layer is sequentially deposited on the substrate 300 to form a potential The insulating oxide material layer 302 of the barrier layer, the second magnetic material layer 303 used to form the free layer, and the first heavy metal material layer 304 used to form the top electrode prefabricated layer, where a heavy metal material layer 304 can be deposited to prevent the second The magnetic material layer 303 is oxidized and serves as a connection between the top electrode functional layer and the free layer. The first magnetic material layer 301 may be a single layer of ferromagnetic material, or it may be composed of multiple layers of ferromagnetic materials or synthetic ferromagnetic materials. The insulating oxide material layer 302 includes MgO, AlO and other oxides. The second magnetic material layer 303 can be composed of a single layer of ferromagnetic layer or multiple layers of ferromagnetic material, or a layer of MgO and other materials can be grown on top to form a double layer. In the barrier structure, the first heavy metal material layer 304 may be composed of materials such as Pt, Ta, W, Au, and Cu.
步骤S2、通过光刻和刻蚀,在基底上形成至少一个预制结构阵列,所述预制结构阵列包括相邻设置的第一预制结构阵列和第二预制结构阵列,所述第一预制结构阵列用于形成STT-MRAM阵列,所述第二预制结构阵列用于形成SOT-MRAM阵列,其中所述第一预制结构阵列包括按阵列排布的第一预制单元,所述第一预制单元包括第一磁性隧道结和第一磁性隧道结上的第一预制层,所述第二预制结构阵列包括按阵列排布的第二预制单元,所述第二预制单元包括第二磁性隧道结和第二磁性隧道结上的第二预制层;Step S2, forming at least one prefabricated structure array on the substrate by photolithography and etching. The prefabricated structure array includes a first prefabricated structure array and a second prefabricated structure array arranged adjacently. The first prefabricated structure array is used for To form an STT-MRAM array, the second prefabricated structure array is used to form a SOT-MRAM array, wherein the first prefabricated structure array includes first prefabricated units arranged in an array, and the first prefabricated units include first A magnetic tunnel junction and a first prefabricated layer on the first magnetic tunnel junction, the second prefabricated structure array includes second prefabricated units arranged in an array, and the second prefabricated unit includes a second magnetic tunnel junction and a second magnetic The second prefabricated layer on the tunnel junction;
如图12B所示,利用光刻和刻蚀工艺,对第一磁性材料层、绝缘氧化物材料层、第二磁性材料层、第一重金属材料层进行刻蚀,一般都是刻蚀成圆柱状,从而得到了圆柱状的磁性隧道结及其上方的顶电极预制层,分别从第一预制结构阵列和第二预制结构阵列中各自选取一个磁性隧道结40和50进行图示,磁性隧道结40包括从下至上堆叠设置的第一参考层401、第一势垒层402、第一自由层403,其上方的第一预制层为411,磁性隧道结50包括从下至上堆叠设置的第二参考层501、第二势垒层502、第二自由层503,其上方的第二预制层为511,实际工艺都是批量生成,同时得到多个磁性隧道结,磁性隧道结之间都是间隔设置的,其中磁性隧道结40用于进一步形成STT-MRAM存储单元,磁性隧道结50用于进一步形成SOT-MRAM存储单元。本实施例中,磁性隧道结40和50采用了相同的形状和尺寸,均为圆柱形,实际可根据需要调整具体形状和尺寸,二者可以采用不同的形状和尺寸。As shown in FIG. 12B, the first magnetic material layer, the insulating oxide material layer, the second magnetic material layer, and the first heavy metal material layer are etched using photolithography and etching processes, which are generally etched into a cylindrical shape. , The cylindrical magnetic tunnel junction and the top electrode prefabricated layer above are obtained. A magnetic tunnel junction 40 and 50 are respectively selected from the first prefabricated structure array and the second prefabricated structure array for illustration. The magnetic tunnel junction 40 It includes a first reference layer 401, a first barrier layer 402, and a first free layer 403 stacked from bottom to top. The first prefabricated layer above is 411. The magnetic tunnel junction 50 includes a second reference layer stacked from bottom to top. Layer 501, second barrier layer 502, second free layer 503, the second prefabricated layer above it is 511, the actual process is batch production, and multiple magnetic tunnel junctions are obtained at the same time, and the magnetic tunnel junctions are arranged at intervals Yes, the magnetic tunnel junction 40 is used to further form the STT-MRAM memory cell, and the magnetic tunnel junction 50 is used to further form the SOT-MRAM memory cell. In this embodiment, the magnetic tunnel junctions 40 and 50 adopt the same shape and size, and both are cylindrical. Actually, the specific shape and size can be adjusted as needed, and the two can adopt different shapes and sizes.
另外需要注意的是,由于STT-MRAM存储单元不需要条状重金属电极,因而集成密度比SOT-MRAM存储单元高,所以在薄膜刻蚀成为MTJ圆柱的过程中,用于制作STT-MRAM的MTJ圆柱的间距可以比用于制作SOT-MRAM的MTJ圆柱的间距要小。In addition, it should be noted that since the STT-MRAM memory cell does not require strip-shaped heavy metal electrodes, the integration density is higher than that of the SOT-MRAM memory cell, so in the process of film etching to become an MTJ cylinder, it is used to make the MTJ of STT-MRAM. The pitch of the cylinders can be smaller than the pitch of the MTJ cylinders used to make SOT-MRAM.
步骤S3、采用绝缘介质填充满所述预制结构阵列中的空隙,并进行表面平坦化处理,形成一平坦表面,所述平坦表面位于所述第一预制层和所述第二预制层上方;Step S3: Fill the voids in the prefabricated structure array with an insulating medium, and perform a surface planarization treatment to form a flat surface, the flat surface being located above the first prefabricated layer and the second prefabricated layer;
如图12C所示,采用绝缘介质200填充满磁性隧道结之间的空隙,绝缘介 质一般包括SiN、SiO、SiON等材料,并采用化学机械抛光的方法将第一预制层411和第二预制层511上方的绝缘介质平坦化,平坦化处理之后第一预制层411和第二预制层511上方仍保留有绝缘介质200,因此需要保证绝缘介质200有足够的填充高度。As shown in FIG. 12C, an insulating medium 200 is used to fill the gaps between the magnetic tunnel junctions. The insulating medium generally includes materials such as SiN, SiO, SiON, etc., and the first prefabricated layer 411 and the second prefabricated layer are combined by a chemical mechanical polishing method. The insulating medium above 511 is planarized. After the planarization process, the insulating medium 200 still remains above the first prefabricated layer 411 and the second prefabricated layer 511. Therefore, it is necessary to ensure that the insulating medium 200 has a sufficient filling height.
步骤S4、通过光刻和刻蚀,在所述第一预制层和所述第二预制层上方形成孔槽;Step S4, forming holes and grooves above the first prefabricated layer and the second prefabricated layer by photolithography and etching;
如图12D所示,利用光刻和刻蚀工艺,在第一预制层411上方保留的绝缘介质中形成开孔,以及,在第二预制层511上方保留的绝缘介质中形成开槽,刻蚀停止在第一预制层411和第二预制层511的表面,也可以适当过刻蚀,使得第一预制层411和第二预制层511能够充分暴露出来。其中,开孔采用与用于制备STT-MRAM存储单元的磁性隧道结40相同的形状,因此刻蚀成圆孔,所述开孔的尺寸大于或者等于用于制备STT-MRAM存储单元的磁性隧道结40的尺寸,本实施例中开孔尺寸等于磁性隧道结尺寸;开槽刻蚀成矩形槽,所述开槽的宽度大于或者等于用于制备SOT-MRAM存储单元的磁性隧道结50的尺寸,本实施例中开槽尺寸等于磁性隧道结尺寸。具体刻蚀时,刻蚀出圆孔、矩形槽的工艺流程可以不在同一步进行,对所需的电极进行分别制作。As shown in FIG. 12D, using photolithography and etching processes, openings are formed in the insulating medium retained above the first prefabricated layer 411, and grooves are formed in the insulating medium retained above the second prefabricated layer 511, and the etching Stop on the surfaces of the first prefabricated layer 411 and the second prefabricated layer 511, and may also be appropriately over-etched so that the first prefabricated layer 411 and the second prefabricated layer 511 can be fully exposed. Wherein, the opening adopts the same shape as the magnetic tunnel junction 40 used to prepare the STT-MRAM memory cell, so it is etched into a circular hole, and the size of the opening is greater than or equal to the magnetic tunnel used to prepare the STT-MRAM memory cell. The size of the junction 40, in this embodiment, the size of the opening is equal to the size of the magnetic tunnel junction; the slot is etched into a rectangular slot, and the width of the slot is greater than or equal to the size of the magnetic tunnel junction 50 used to prepare the SOT-MRAM memory cell In this embodiment, the slot size is equal to the size of the magnetic tunnel junction. During specific etching, the process flow of etching round holes and rectangular grooves may not be performed at the same step, and the required electrodes may be fabricated separately.
步骤S5、沉积顶电极功能层材料薄膜,以填充所述孔槽,并对所述顶电极功能层材料薄膜进行化学机械抛光或者刻蚀,以在所述第一预制层上方形成第一功能层,并在所述第二预制层上方形成第二功能层。Step S5, deposit a top electrode functional layer material film to fill the holes, and perform chemical mechanical polishing or etching on the top electrode functional layer material film to form a first functional layer above the first prefabricated layer , And forming a second functional layer above the second prefabricated layer.
如图12E所示,沉积顶电极功能层材料薄膜,顶电极功能层与顶电极预制层材料可以相同,为Pt、Ta、W等重金属,充满开孔和开槽,并对所述顶电极功能层材料薄膜进行化学机械抛光或者刻蚀,需要保证相邻存储单元之间的隔离,在所述开孔内形成STT-MRAM存储单元的顶电极功能层412并在所述开槽内形成SOT-MRAM存储单元的顶电极功能层512,顶电极功能层512作为自旋轨道矩提供层。当然,也可根据实际电极制备需要,保留一部分磁性隧道结顶部电极有一定的连续性。As shown in FIG. 12E, the top electrode functional layer material film is deposited. The top electrode functional layer and the top electrode prefabricated layer can be made of the same material, which is heavy metals such as Pt, Ta, W, and is filled with openings and grooves. The layer material film is chemically mechanically polished or etched. It is necessary to ensure the isolation between adjacent memory cells. The top electrode functional layer 412 of the STT-MRAM memory cell is formed in the opening and the SOT- is formed in the groove. The top electrode functional layer 512 of the MRAM memory cell, and the top electrode functional layer 512 serves as a spin orbit moment providing layer. Of course, according to actual electrode preparation requirements, a certain continuity of the top electrode of a part of the magnetic tunnel junction can also be retained.
本发明实施例提供的磁性存储器的制备方法,利用了STT-MRAM与SOT-MRAM的工艺相近的特点,参考层、势垒层、自由层以及顶电极可以使用同一套材料体系,可以通过一次薄膜沉积制成,降低了工艺复杂度。The preparation method of the magnetic memory provided by the embodiment of the present invention utilizes the characteristics of the similar processes of STT-MRAM and SOT-MRAM. The reference layer, barrier layer, free layer and top electrode can use the same set of material systems, and can pass through a single film It is made by deposition, which reduces the complexity of the process.
另外说明的是,根据需要可以调整用于制备STT-MRAM的隧道结的尺寸和用于制备SOT-MRAM的隧道结的尺寸,用于制备STT-MRAM的隧道结尺寸较 大时,具有较高的热稳定性;用于制备SOT-MRAM的隧道结尺寸较小时,热稳定性较小但是翻转速率较快、翻转电流密度较低。结合不同尺寸的隧道结,可以增加磁性存储器中用于长时间保存数据的存储部分的保存时间,同时加快频繁写入数据部分的写入速率,降低写入电流密度。改变尺寸不会影响具体的制备方法,在此不再赘述。It is also noted that the size of the tunnel junction used to prepare STT-MRAM and the size of the tunnel junction used to prepare SOT-MRAM can be adjusted according to needs. When the size of the tunnel junction used to prepare STT-MRAM is larger, the size of the tunnel junction is higher. The thermal stability of the tunnel junction used to prepare SOT-MRAM is small, the thermal stability is small, but the flip rate is faster and the flip current density is low. Combining tunnel junctions of different sizes can increase the storage time of the storage part for storing data for a long time in the magnetic memory, speed up the writing rate of the frequently written data part, and reduce the writing current density. Changing the size will not affect the specific preparation method, so I will not repeat it here.
以上所述,仅为本发明的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,可轻易想到的变化或替换,都应涵盖在本发明的保护范围之内。因此,本发明的保护范围应该以权利要求的保护范围为准。The above are only specific embodiments of the present invention, but the protection scope of the present invention is not limited to this. Any person skilled in the art can easily think of changes or substitutions within the technical scope disclosed in the present invention. All should be covered within the protection scope of the present invention. Therefore, the protection scope of the present invention should be subject to the protection scope of the claims.

Claims (10)

  1. 一种磁性存储器,其特征在于,包括至少一个混合存储阵列,所述混合存储阵列包括相邻设置的STT-MRAM阵列和SOT-MRAM阵列,其中,A magnetic memory, which is characterized by comprising at least one hybrid storage array, the hybrid storage array comprising adjacently arranged STT-MRAM array and SOT-MRAM array, wherein,
    所述STT-MRAM阵列包括按阵列排布的STT-MRAM存储单元,所述SOT-MRAM阵列包括按阵列排布的SOT-MRAM存储单元,所述STT-MRAM存储单元与所述SOT-MRAM存储单元具有相同的层叠结构。The STT-MRAM array includes STT-MRAM storage units arranged in an array, the SOT-MRAM array includes SOT-MRAM storage units arranged in an array, and the STT-MRAM storage unit is connected to the SOT-MRAM storage unit. The units have the same stacked structure.
  2. 根据权利要求1所述的磁性存储器,其特征在于,所述STT-MRAM存储单元包括第一磁性隧道结(MTJ),所述SOT-MRAM存储单元包括第二磁性隧道结(MTJ),所述第一磁性隧道结与所述第二磁性隧道结具有相同的层叠结构。The magnetic memory of claim 1, wherein the STT-MRAM memory cell includes a first magnetic tunnel junction (MTJ), the SOT-MRAM memory cell includes a second magnetic tunnel junction (MTJ), and the The first magnetic tunnel junction and the second magnetic tunnel junction have the same laminated structure.
  3. 根据权利要求2所述的磁性存储器,其特征在于,所述STT-MRAM阵列中全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。The magnetic memory according to claim 2, wherein the diameter of the first magnetic tunnel junction of all STT-MRAM memory cells in the STT-MRAM array is the same; all SOT-MRAM memory cells in the SOT-MRAM array The diameter of the second magnetic tunnel junction of the unit is the same.
  4. 根据权利要求2所述的磁性存储器,其特征在于,The magnetic memory according to claim 2, wherein:
    所述STT-MRAM阵列中同一列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离所述SOT-MRAM阵列最远的一列或行至距离所述SOT-MRAM阵列最近的一列或行,各列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;The diameters of the first magnetic tunnel junctions of the STT-MRAM memory cells in the same column or row in the STT-MRAM array are the same, and from the column or row farthest from the SOT-MRAM array to the SOT-MRAM The diameter size of the first magnetic tunnel junction of the STT-MRAM memory cell in the nearest column or row of the array becomes gradually smaller;
    所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直径尺寸相同。The diameters of the second magnetic tunnel junctions of all SOT-MRAM memory cells in the SOT-MRAM array are the same.
  5. 根据权利要求2所述的磁性存储器,其特征在于,所述STT-MRAM阵列划分为相邻设置的STT-MRAM第一子阵列和STT-MRAM第二子阵列,其中所述STT-MRAM第二子阵列与所述SOT-MRAM阵列相邻,所述STT-MRAM第一子阵列中全部STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同;所述STT-MRAM第二子阵列中同一列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸相同,且从距离所述SOT-MRAM阵列最远的一列或行至距离所述SOT-MRAM阵列最近的一列或行,各列或行的STT-MRAM存储单元的第一磁性隧道结的直径尺寸逐渐变小;The magnetic memory according to claim 2, wherein the STT-MRAM array is divided into adjacently arranged STT-MRAM first sub-array and STT-MRAM second sub-array, wherein the second STT-MRAM The sub-array is adjacent to the SOT-MRAM array, and the diameters of the first magnetic tunnel junctions of all STT-MRAM memory cells in the first sub-array of STT-MRAM are the same; and the same in the second sub-array of STT-MRAM The diameters of the first magnetic tunnel junctions of the STT-MRAM memory cells in the columns or rows are the same, and from the column or row farthest from the SOT-MRAM array to the column or row closest to the SOT-MRAM array, each The diameter of the first magnetic tunnel junction of the column or row of STT-MRAM memory cells gradually becomes smaller;
    所述SOT-MRAM阵列中全部SOT-MRAM存储单元的第二磁性隧道结的直 径尺寸相同。The diameter and size of the second magnetic tunnel junctions of all SOT-MRAM memory cells in the SOT-MRAM array are the same.
  6. 根据权利要求2所述的磁性存储器,其特征在于,The magnetic memory according to claim 2, wherein:
    所述STT-MRAM存储单元还包括耦合于所述第一磁性隧道结的第一顶电极,所述第一顶电极包括层叠设置的第一预制层和第一功能层,所述第一预制层与所述第一磁性隧道结接触;The STT-MRAM memory cell further includes a first top electrode coupled to the first magnetic tunnel junction, the first top electrode includes a first prefabricated layer and a first functional layer that are stacked and arranged, and the first prefabricated layer In contact with the first magnetic tunnel junction;
    所述SOT-MRAM存储单元还包括耦合于所述第二磁性隧道结的第二顶电极,所述第二顶电极包括层叠设置的第二预制层和第二功能层,所述第二预制层与所述第二磁性隧道结接触。The SOT-MRAM memory cell further includes a second top electrode coupled to the second magnetic tunnel junction. The second top electrode includes a second prefabricated layer and a second functional layer that are stacked and arranged. The second prefabricated layer In contact with the second magnetic tunnel junction.
  7. 根据权利要求6所述的磁性存储器,其特征在于,所述第一预制层的横截面形状和尺寸与所述第一磁性隧道结相同,所述第二预制层的横截面形状和尺寸与所述第二磁性隧道结相同;The magnetic memory according to claim 6, wherein the cross-sectional shape and size of the first prefabricated layer are the same as those of the first magnetic tunnel junction, and the cross-sectional shape and size of the second prefabricated layer are the same as those of the first magnetic tunnel junction. The second magnetic tunnel junction is the same;
    所述第一功能层的横截面形状为圆形,且所述第一功能层的直径尺寸大于或者等于所述第一磁性隧道结的直径尺寸;所述第二功能层的横截面形状为矩形,且所述第二功能层的宽度大于或者等于所述第二磁性隧道结的直径尺寸。The cross-sectional shape of the first functional layer is circular, and the diameter of the first functional layer is greater than or equal to the diameter of the first magnetic tunnel junction; the cross-sectional shape of the second functional layer is rectangular And the width of the second functional layer is greater than or equal to the diameter of the second magnetic tunnel junction.
  8. 根据权利要求6所述的磁性存储器,其特征在于,所述第一预制层和所述第二预制层的材料相同,选自Pt、Ta、W、Au和Cu中的一种;7. The magnetic memory according to claim 6, wherein the first prefabricated layer and the second prefabricated layer are made of the same material, and are selected from one of Pt, Ta, W, Au, and Cu;
    所述第一功能层与所述第二功能层的材料相同,选自Pt、Ta、W、Au和Cu中的一种。The first functional layer and the second functional layer are made of the same material, and are selected from one of Pt, Ta, W, Au, and Cu.
  9. 根据权利要求1所述的磁性存储器,其特征在于,当所述磁性存储器包括多个混合存储阵列时,所述多个混合存储阵列依次排列,每个混合存储阵列的阵列排布方式相同,不同混合存储阵列中的STT-MRAM阵列和SOT-MRAM阵列的大小各不相同。The magnetic memory according to claim 1, wherein when the magnetic memory includes a plurality of hybrid memory arrays, the plurality of hybrid memory arrays are arranged in sequence, and the array arrangement of each hybrid memory array is the same but different The size of the STT-MRAM array and the SOT-MRAM array in the hybrid storage array are different.
  10. 一种磁性存储器的制备方法,其特征在于,所述方法包括:A preparation method of a magnetic memory, characterized in that the method comprises:
    在基底上沉积磁性隧道结多层薄膜并在所述磁性隧道结多层薄膜上沉积顶电极预制层材料薄膜;Depositing a magnetic tunnel junction multilayer film on the substrate and depositing a top electrode prefabricated layer material film on the magnetic tunnel junction multilayer film;
    通过光刻和刻蚀,在基底上形成至少一个预制结构阵列,所述预制结构阵列包括相邻设置的第一预制结构阵列和第二预制结构阵列,所述第一预制结构阵列用于形成STT-MRAM阵列,所述第二预制结构阵列用于形成SOT-MRAM阵列,其中所述第一预制结构阵列包括按阵列排布的第一预制单元,所述第一预制单元包括第一磁性隧道结和第一磁性隧道结上的第一预制层,所述第二预制结构阵列包括按阵列排布的第二预制单元,所述第二预制单元包括第二磁性 隧道结和第二磁性隧道结上的第二预制层;At least one array of prefabricated structures is formed on the substrate by photolithography and etching, the array of prefabricated structures includes a first array of prefabricated structures and a second array of prefabricated structures that are arranged adjacently, and the first prefabricated structure array is used to form STT -MRAM array, the second prefabricated structure array is used to form a SOT-MRAM array, wherein the first prefabricated structure array includes first prefabricated units arranged in an array, and the first prefabricated units include first magnetic tunnel junctions And a first prefabricated layer on the first magnetic tunnel junction, the second prefabricated structure array includes second prefabricated units arranged in an array, the second prefabricated unit includes a second magnetic tunnel junction and a second magnetic tunnel junction The second prefabricated layer;
    采用绝缘介质填充满所述预制结构阵列中的空隙,并进行表面平坦化处理,形成一平坦表面,所述平坦表面位于所述第一预制层和所述第二预制层上方;Filling the voids in the prefabricated structure array with an insulating medium, and performing a surface flattening treatment to form a flat surface, the flat surface being located above the first prefabricated layer and the second prefabricated layer;
    通过光刻和刻蚀,在所述第一预制层和所述第二预制层上方形成孔槽;Forming holes and grooves above the first prefabricated layer and the second prefabricated layer by photolithography and etching;
    沉积顶电极功能层材料薄膜,以填充所述孔槽,并对所述顶电极功能层材料薄膜进行化学机械抛光或者刻蚀,以在所述第一预制层上方形成第一功能层,并在所述第二预制层上方形成第二功能层。A material film of the top electrode functional layer is deposited to fill the holes, and the material film of the top electrode functional layer is chemically mechanically polished or etched to form a first functional layer above the first prefabricated layer. A second functional layer is formed on the second prefabricated layer.
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107611255A (en) * 2017-09-11 2018-01-19 北京航空航天大学 A kind of high density magnetic memory device
CN108538328A (en) * 2018-03-07 2018-09-14 北京航空航天大学 A kind of method for writing data of magnetic storage
CN109166962A (en) * 2018-08-09 2019-01-08 北京航空航天大学 A kind of complementary type magnetic memory cell
US20190287591A1 (en) * 2018-02-23 2019-09-19 Commissariat A L'energie Atomique Et Aux Energies Alternatives Magnetic tunnel junction with perpendicular shape anisotropy and minimised variation of temperature memory point and logic element including the magnetic tunnel junction, method of manufacturing the magnetic tunnel junction

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* Cited by examiner, † Cited by third party
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US20180151210A1 (en) * 2016-11-30 2018-05-31 Western Digital Technologies, Inc. Shared source line architectures of perpendicular hybrid spin-torque transfer (stt) and spin-orbit torque (sot) magnetic random access memory
WO2018136003A1 (en) * 2017-01-17 2018-07-26 Agency For Science, Technology And Research Memory cell, memory array, method of forming and operating memory cell

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107611255A (en) * 2017-09-11 2018-01-19 北京航空航天大学 A kind of high density magnetic memory device
US20190287591A1 (en) * 2018-02-23 2019-09-19 Commissariat A L'energie Atomique Et Aux Energies Alternatives Magnetic tunnel junction with perpendicular shape anisotropy and minimised variation of temperature memory point and logic element including the magnetic tunnel junction, method of manufacturing the magnetic tunnel junction
CN108538328A (en) * 2018-03-07 2018-09-14 北京航空航天大学 A kind of method for writing data of magnetic storage
CN109166962A (en) * 2018-08-09 2019-01-08 北京航空航天大学 A kind of complementary type magnetic memory cell

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