WO2021093303A1 - 一种碳纤维复合材料及其制备方法 - Google Patents

一种碳纤维复合材料及其制备方法 Download PDF

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WO2021093303A1
WO2021093303A1 PCT/CN2020/091835 CN2020091835W WO2021093303A1 WO 2021093303 A1 WO2021093303 A1 WO 2021093303A1 CN 2020091835 W CN2020091835 W CN 2020091835W WO 2021093303 A1 WO2021093303 A1 WO 2021093303A1
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carbon fiber
composite material
fiber composite
polyphenylene sulfide
flame retardant
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PCT/CN2020/091835
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English (en)
French (fr)
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蔡福泉
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安徽旭升新材料有限公司
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
    • C08L81/02—Polythioethers; Polythioether-ethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/001—Conductive additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/04—Thermoplastic elastomer

Definitions

  • the invention relates to a material, in particular to a carbon fiber composite material and a preparation method thereof.
  • Polyphenylene sulfide is a thermoplastic resin with a phenylsulfide group in the main chain of the polymer molecule. It is a thermoplastic special engineering plastic with excellent comprehensive performance.
  • the polyphenylene sulfide material has outstanding heat resistance, excellent chemical resistance, Solvent resistance and corrosion resistance, inherent flame retardancy, excellent mechanical properties, excellent dimensional stability and good molding processing performance, relatively low price, can be processed by a variety of molding processing methods, and can be Precision molding.
  • the current plates formed with polyphenylene sulfide still have the defects of poor mechanical strength and poor electrical conductivity.
  • the present invention has made improvements.
  • the purpose of the present invention is to provide a carbon fiber composite material with high mechanical strength and good electrical conductivity molded with polyphenylene sulfide as a base material and a preparation method thereof.
  • the technical scheme adopted by the present invention is: a carbon fiber composite material, including the following components:
  • the conductive filler is carbon nanotubes.
  • the conductive filler further includes carbon black, and the weight percentage of carbon black is 0-10%.
  • the flame retardant is a halogen-free flame retardant, which is a composite melamine cyanurate.
  • the said toughening agent is hydrogenated styrene-butadiene-styrene (SEBS) grafted MAH copolymer (SEBS-g-MAH) and/or ethylene propylene diene rubber (EPDM) and / Or active toughening agent 6350 with epoxy groups, wherein the grafting rate of MAH in the copolymer is 0.5%.
  • SEBS hydrogenated styrene-butadiene-styrene
  • SEBS-g-MAH grafted MAH copolymer
  • EPDM ethylene propylene diene rubber
  • active toughening agent 6350 with epoxy groups wherein the grafting rate of MAH in the copolymer is 0.5%.
  • the elastomer is thermoplastic elastomer G155D3-5.
  • Step 1 Add 40-60% polyphenylene sulfide, 10-30% carbon fiber powder fiber, 10-15% polyphenylene sulfide-polyorganosiloxane block copolymer, 0.3-5% conductive filling The mixture, 2-5% flame retardant, 1-4% toughening agent and 2-5% elastomer are stirred and mixed and reacted in a reactor for 20-60 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.
  • the melting temperature is 270°C-300°C, and the cooling time is 30-50 minutes.
  • the beneficial effects of the present invention are: due to the above technical solution, carbon fiber powder is added to the traditional polyphenylene sulfide, so that the material has better interface bonding force, can effectively transmit load, increase the mechanical strength, and because of conductive filling
  • the increase of the material improves the conductivity of the material, and the conductivity is increased by 20-30% on the original basis, and the increase of the flame retardant makes the material have better flame retardancy, and the flame retardant is Halogen-free flame retardant is environmentally friendly and non-toxic.
  • the present invention provides a carbon fiber composite material, comprising the following components:
  • the conductive filler is carbon nanotubes.
  • the conductive filler also includes carbon black, and the weight percentage of carbon black is 0-10%.
  • the flame retardant is a halogen-free flame retardant, which is a composite melamine cyanurate.
  • the described toughening agent is hydrogenated styrene-butadiene-styrene (SEBS) grafted MAH copolymer (SEBSg-MAH) and/or ethylene propylene diene rubber (EPDM) and/or with epoxy
  • SEBS hydrogenated styrene-butadiene-styrene
  • SEBSg-MAH grafted MAH copolymer
  • EPDM ethylene propylene diene rubber
  • the elastomer is thermoplastic elastomer G155D3-5.
  • a preparation method of carbon fiber composite material includes the following steps:
  • Step 1 Add 40-60% polyphenylene sulfide, 10-30% carbon fiber powder fiber, 10-15% polyphenylene sulfide-polyorganosiloxane block copolymer, 0.3-5% conductive filling The mixture, 2-5% flame retardant, 1-4% toughening agent and 2-5% elastomer are stirred and mixed and reacted in a reactor for 20-60 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.
  • the melting temperature is 270°C-300°C, and the cooling time is 30-50 minutes.
  • a preparation method of carbon fiber composite material includes the following steps:
  • Step 1 Combine 45% polyphenylene sulfide, 30% carbon fiber powder fiber, 15% polyphenylene sulfide-polyorganosiloxane block copolymer, 1% conductive filler, 2% flame retardant , 2% of the toughening agent and 5% of the elastomer are stirred and mixed and reacted in the reactor for 30 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.
  • a preparation method of carbon fiber composite material includes the following steps:
  • Step 1 Combine 50% polyphenylene sulfide, 30% carbon fiber powder fiber, 10% polyphenylene sulfide-polyorganosiloxane block copolymer, 2% conductive filler, 3% flame retardant , 3% of the toughening agent and 2% of the elastomer are stirred and mixed and reacted in the reactor for 40 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.
  • a preparation method of carbon fiber composite material includes the following steps:
  • Step 1 Combine 55% polyphenylene sulfide, 25% carbon fiber powder fiber, 12% polyphenylene sulfide-polyorganosiloxane block copolymer, 3% conductive filler, 2% flame retardant , 1% of the toughening agent and 2% of the elastomer are stirred and mixed and reacted in the reactor for 20-60 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.
  • a preparation method of carbon fiber composite material includes the following steps:
  • Step 1 Combine 60% polyphenylene sulfide, 20% carbon fiber powder fiber, 10% polyphenylene sulfide-polyorganosiloxane block copolymer, 3% conductive filler, 3% flame retardant , 2% of the toughening agent and 2% of the elastomer are stirred and mixed and passed through the reactor for 50 minutes to obtain a mixture;
  • Step 2 Add carbon black to the mixture obtained in Step 1;
  • Step 3 Melt and continuously extrude the mixture in step 2 in an extruder, shape it, and cool it to form a carbon fiber composite material.

Abstract

一种碳纤维复合材料包含以下组分：聚苯硫醚40-60％；碳纤维粉末纤维10-30％；聚苯硫醚-聚有机硅氧烷嵌段共聚物10-15％；导电填充物0.3-5％；阻燃剂2-5％；增韧剂1-4％；弹性体2-5％；所述的导电填充物为碳纳米管；所述的导电填充物还包括有碳黑，碳黑的重量百化比为0-10％；所述的阻燃剂为无卤阻燃剂，具本为复合三聚氰胺氰尿酸盐；所述的增韧剂为氢化苯乙烯-丁二烯-苯乙烯(SEBS)接枝MAH共聚物(SEBS-g-MAH)和/或三元乙丙橡胶(EPDM)和/或带环氧基团的活性增韧剂6350，其中共聚物中MAH的接枝率为0.5。所述碳纤维复合材料以聚苯硫醚为基料，机械强度高、导电性能好。

Description

一种碳纤维复合材料及其制备方法 技术领域
本发明涉及一种材料，特别涉及一种碳纤维复合材料及其制备方法。
背景技术
聚苯硫醚是聚合物分子主链中带有苯硫基的热塑性树脂，是一种综合性能优异的热塑性特种工程塑料，聚苯硫醚材料具有突出的耐热性，优异的耐化学药品、耐溶剂性和耐腐蚀性，本身固有的阻燃性、优良的力学性能、出色的尺寸稳定性和良好的成型加工性能、相对较低的价格，可用多种成型加工方法进行成型加工，并且可以精密成型。
但目前用聚苯硫醚成型的板材还是具有机械强度差、导电性能差的缺陷，针对该缺陷，本发明作出了改进。
发明概述
技术问题
问题的解决方案
技术解决方案
为了克服背景技术的不足，本发明的目的在于提供了一种以聚苯硫醚为基料成型的机械强度高、导电性能好的碳纤维复合材料及其制备方法。
本发明所采用的技术方案是：一种碳纤维复合材料，包含以下组分：
聚苯硫醚40-60％；
碳纤维粉末纤维10-30％；
聚苯硫醚-聚有机硅氧烷嵌段共聚物10-15％；
导电填充物0.3-5％；
阻燃剂2-5％；
增韧剂1-4％；
弹性体2-5％。
优选的，所述的导电填充物为碳纳米管。
优选的，所述的导电填充物还包括有碳黑，碳黑的重量百化比为0-10％。
优选的，所述的阻燃剂为无卤阻燃剂，具本为复合三聚氰胺氰尿酸盐。
优选的，所述的所述的增韧剂为氢化苯乙烯-丁二烯-苯乙烯(SEBS)接枝MAH共聚物(SEBS-g-MAH)和/或三元乙丙橡胶(EPDM)和/或带环氧基团的活性增韧剂6350，其中共聚物中MAH的接枝率为0.5％。
优选的，所述的弹性体为热塑性弹性体G155D3-5。
一种碳纤维复合材料的制备方法，其特征在于，包括如下步骤：
步骤1：将40-60％的聚苯硫醚、10-30％的碳纤维粉末纤维、10-15％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、0.3-5％的导电填充物、2-5％的阻燃剂、1-4％的增韧剂及2-5％的弹性体搅拌混合并通过反应釜反应20-60分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
优选的，熔融温度为270℃-300℃，冷却时间为30-50分钟。
发明的有益效果
有益效果
本发明的有益效果是：由于采用上述技术方案，在传统的聚苯硫醚中加入了碳纤维粉，使材料具有更好的界面结合力，能有效传递载荷，增加了机械强度，且由于导电填充物的增加，提高了材料的导电能力，在原有的基础之上导电性能提高了20-30％，且阻燃剂的增加，使该材料具有更好的阻燃性，且该阻燃剂为无卤阻燃剂，具有环保无毒的特点。
发明实施例
本发明的实施方式
本发明提供一种碳纤维复合材料，包含以下组分：
聚苯硫醚40-60％；
碳纤维粉末纤维10-30％；
聚苯硫醚-聚有机硅氧烷嵌段共聚物10-15％；
导电填充物0.3-5％；
阻燃剂2-5％；
增韧剂1-4％；
弹性体2-5％。
所述的导电填充物为碳纳米管。
所述的导电填充物还包括有碳黑，碳黑的重量百化比为0-10％。
所述的阻燃剂为无卤阻燃剂，具本为复合三聚氰胺氰尿酸盐。
所述的所述的增韧剂为氢化苯乙烯-丁二烯-苯乙烯(SEBS)接枝MAH共聚物(SEBSg-MAH)和/或三元乙丙橡胶(EPDM)和/或带环氧基团的活性增韧剂6350，其中共聚物中MAH的接枝率为0.5％。
所述的弹性体为热塑性弹性体G155D3-5。
一种碳纤维复合材料的制备方法，包括如下步骤：
步骤1：将40-60％的聚苯硫醚、10-30％的碳纤维粉末纤维、10-15％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、0.3-5％的导电填充物、2-5％的阻燃剂、1-4％的增韧剂及2-5％的弹性体搅拌混合并通过反应釜反应20-60分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
熔融温度为270℃-300℃，冷却时间为30-50分钟。
下面通过四组实施例进行进一步说明：
实施例一：
一种碳纤维复合材料的制备方法，包括如下步骤：
步骤1：将45％的聚苯硫醚、30％的碳纤维粉末纤维、15％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、1％的导电填充物、2％的阻燃剂、2％的增韧剂及5％的弹性体搅拌混合并通过反应釜反应30分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
实施例二：
一种碳纤维复合材料的制备方法，包括如下步骤：
步骤1：将50％的聚苯硫醚、30％的碳纤维粉末纤维、10％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、2％的导电填充物、3％的阻燃剂、3％的增韧剂及2％的弹性体搅拌混合并通过反应釜反应40分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
实施例三：
一种碳纤维复合材料的制备方法，包括如下步骤：
步骤1：将55％的聚苯硫醚、25％的碳纤维粉末纤维、12％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、3％的导电填充物、2％的阻燃剂、1％的增韧剂及2％的弹性体搅拌混合并通过反应釜反应20-60分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
实施例四：
一种碳纤维复合材料的制备方法，包括如下步骤：
步骤1：将60％的聚苯硫醚、20％的碳纤维粉末纤维、10％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、3％的导电填充物、3％的阻燃剂、2％的增韧剂及2％的弹性体搅拌混合并通过反应釜反50分钟，得到混合物；
步骤2：向步骤1得到的混合物中进一步加入碳黑；
步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
为论证本发明的实际效果和性能，特对本发明进行了拉伸实验并对数据进行了测量，其主要数据统计如下：
[Table 1]
Figure PCTCN2020091835-appb-000001
经过对比，碳纤维含量较多时力学性能上具有明显的优势，能更有效的传递载荷，充分发挥碳纤维的特性，提高整体的力学性能，机械强度更高，而导电性能的电阻率都能达1.5×10m 2ohm.cm，对阻燃性能进行了测试，阻燃等级达到5VB。
各位技术人员须知：虽然本发明已按照上述具体实施方式做了描述，但是本发明的发明思想并不仅限于此发明，任何运用本发明思想的改装，都将纳入本专利专利权保护范围内。

Claims (8)

  1. 一种碳纤维复合材料，其特征在于，包含以下组分：聚苯硫醚40-60％；碳纤维粉末纤维10-30％；聚苯硫醚-聚有机硅氧烷嵌段共聚物10-15％；导电填充物0.3-5％；阻燃剂2-5％；增韧剂1-4％；弹性体2-5％。
  2. 根据权利要求1所述的一种碳纤维复合材料，其特征在于，所述的导电填充物为碳纳米管。
  3. 根据权利要求2所述的一种碳纤维复合材料，其特征在于，所述的导电填充物还包括有碳黑，碳黑的重量百化比为0-10％。
  4. 根据权利要求1所述的一种碳纤维复合材料，其特征在于：所述的阻燃剂为无卤阻燃剂，具本为复合三聚氰胺氰尿酸盐。
  5. 根据权利要求1所述的一种碳纤维复合材料，其特征在于：所述的所述的增韧剂为氢化苯乙烯-丁二烯-苯乙烯(SEBS)接枝MAH共聚物(SEBS-g-MAH)和/或三元乙丙橡胶(EPDM)和/或带环氧基团的活性增韧剂6350，其中共聚物中MAH的接枝率为0.5％。
  6. 根据权利要求2或3或4所述的一种碳纤维组合物，其特征在于：所述的弹性体为热塑性弹性体G155D3-5。
  7. 根据权利要求1-6任一项所述的一种碳纤维复合材料的制备方法，其特征在于，包括如下步骤：
    步骤1：将40-60％的聚苯硫醚、10-30％的碳纤维粉末纤维、10-15％的聚苯硫醚-聚有机硅氧烷嵌段共聚物、0.3-5％的导电填充物、2-5％的阻燃剂、1-4％的增韧剂及2-5％的弹性体搅拌混合并通过反应釜反应20-60分钟，得到混合物；
    步骤2：向步骤1得到的混合物中进一步加入碳黑；
    步骤3：将步骤2中的混合物轩于挤出机中熔融连续挤出、定型并冷却成型，得到碳纤维复合材料。
  8. 根据权利要求7所述的一种碳纤维复合材料的制备方法，其特征在于：熔融温度为270℃-300℃，冷却时间为30-50分。
PCT/CN2020/091835 2019-11-14 2020-05-22 一种碳纤维复合材料及其制备方法 WO2021093303A1 (zh)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101161726A (zh) * 2007-09-28 2008-04-16 深圳市科聚新材料有限公司 高导电聚苯硫醚复合材料及其制备方法
US20130168894A1 (en) * 2012-01-04 2013-07-04 Baker Hughes Incorporated Shape memory polyphenylene sulfide manufacturing, process, and composition
CN105348796A (zh) * 2015-12-17 2016-02-24 重庆可益荧新材料有限公司 碳纤维增强聚苯硫醚复合材料及其制备方法
CN108424648A (zh) * 2018-04-20 2018-08-21 江苏澳盛复合材料科技有限公司 一种注塑用碳纤维复合材料
CN110845848A (zh) * 2019-11-14 2020-02-28 安徽旭升新材料有限公司 一种碳纤维复合材料及其制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101343415A (zh) * 2007-07-12 2009-01-14 四川得阳化学有限公司 含导电材料的聚苯硫醚复合材料的制造方法
CN108192315A (zh) * 2018-02-09 2018-06-22 重庆邮电大学 一种车辆仪器仪表壳体用电磁屏蔽复合材料及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101161726A (zh) * 2007-09-28 2008-04-16 深圳市科聚新材料有限公司 高导电聚苯硫醚复合材料及其制备方法
US20130168894A1 (en) * 2012-01-04 2013-07-04 Baker Hughes Incorporated Shape memory polyphenylene sulfide manufacturing, process, and composition
CN105348796A (zh) * 2015-12-17 2016-02-24 重庆可益荧新材料有限公司 碳纤维增强聚苯硫醚复合材料及其制备方法
CN108424648A (zh) * 2018-04-20 2018-08-21 江苏澳盛复合材料科技有限公司 一种注塑用碳纤维复合材料
CN110845848A (zh) * 2019-11-14 2020-02-28 安徽旭升新材料有限公司 一种碳纤维复合材料及其制备方法

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