WO2021070756A1 - フレキシブル画像表示装置およびそれに用いる光学積層体 - Google Patents

フレキシブル画像表示装置およびそれに用いる光学積層体 Download PDF

Info

Publication number
WO2021070756A1
WO2021070756A1 PCT/JP2020/037605 JP2020037605W WO2021070756A1 WO 2021070756 A1 WO2021070756 A1 WO 2021070756A1 JP 2020037605 W JP2020037605 W JP 2020037605W WO 2021070756 A1 WO2021070756 A1 WO 2021070756A1
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive
window
layer
image display
display device
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2020/037605
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
康隆 石原
孝伸 矢野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Denko Corp
Original Assignee
Nitto Denko Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Priority to CN202080070484.0A priority Critical patent/CN114514570B/zh
Priority to KR1020227009749A priority patent/KR102458092B1/ko
Publication of WO2021070756A1 publication Critical patent/WO2021070756A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • G09F9/301—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23B—TURNING; BORING
    • B23B7/00—Automatic or semi-automatic turning-machines with a single working-spindle, e.g. controlled by cams; Equipment therefor; Features common to automatic and semi-automatic turning-machines with one or more working-spindles
    • B23B7/12—Automatic or semi-automatic machines for turning of workpieces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/022—Mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02—Physical, chemical or physicochemical properties
    • B32B7/023—Optical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J143/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Adhesives based on derivatives of such polymers
    • C09J143/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J183/00—Adhesives based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Adhesives based on derivatives of such polymers
    • C09J183/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14—Protective coatings, e.g. hard coatings
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/133305—Flexible substrates, e.g. plastics, organic film
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F3/00—Input arrangements for transferring data to be processed into a form capable of being handled by the computer; Output arrangements for transferring data from processing unit to output unit, e.g. interface arrangements
    • G06F3/01—Input arrangements or combined input and output arrangements for interaction between user and computer
    • G06F3/03—Arrangements for converting the position or the displacement of a member into a coded form
    • G06F3/041—Digitisers, e.g. for touch screens or touch pads, characterised by the transducing means
    • G06F3/0412—Digitisers structurally integrated in a display
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
    • G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/02—Details
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/0277—Bendability or stretchability details
    • H05K1/028—Bending or folding regions of flexible printed circuits
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K5/00—Casings, cabinets or drawers for electric apparatus
    • H05K5/0017—Casings, cabinets or drawers for electric apparatus with operator interface units
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
    • H10D86/40—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs
    • H10D86/411—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs characterised by materials, geometry or structure of the substrates
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
    • H10D86/40—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs
    • H10D86/481—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs integrated with passive devices, e.g. auxiliary capacitors
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10D—INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D86/00—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates
    • H10D86/40—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs
    • H10D86/60—Integrated devices formed in or on insulating or conducting substrates, e.g. formed in silicon-on-insulator [SOI] substrates or on stainless steel or glass substrates characterised by multiple TFTs wherein the TFTs are in active matrices
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/40—OLEDs integrated with touch screens
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/50—OLEDs integrated with light modulating elements, e.g. with electrochromic elements, photochromic elements or liquid crystal elements
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K77/00—Constructional details of devices covered by this subclass and not covered by groups H10K10/80, H10K30/80, H10K50/80 or H10K59/80
    • H10K77/10—Substrates, e.g. flexible substrates
    • H10K77/111—Flexible substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/548—Creep
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08—Dimensions, e.g. volume
    • B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105—Thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
    • B32B2457/206—Organic displays, e.g. OLED
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
    • B32B2457/208—Touch screens
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
    • C09K2323/05—Bonding or intermediate layer characterised by chemical composition, e.g. sealant or spacer
    • C09K2323/053—Organic silicon compound, e.g. organosilicon
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F2203/00—Indexing scheme relating to G06F3/00 - G06F3/048
    • G06F2203/041—Indexing scheme relating to G06F3/041 - G06F3/045
    • G06F2203/04102—Flexible digitiser, i.e. constructional details for allowing the whole digitising part of a device to be flexed or rolled like a sheet of paper
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/301—Details of OLEDs
    • H10K2102/311—Flexible OLED
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/8791—Arrangements for improving contrast, e.g. preventing reflection of ambient light

Definitions

  • the present invention relates to a flexible image display device and an optical laminate provided with a plurality of layers of adhesive members.
  • the flexible image display device includes, for example, a panel member including a display panel and an optical laminate arranged on the front surface of the panel member.
  • the optical laminate includes, for example, a window member and an optical film, and may further include a touch sensor.
  • An adhesive layer or an adhesive layer is arranged between each member included in the optical laminate and between the panel member and the optical laminate.
  • Patent Document 1 a display panel, a polarizing member provided on the display panel, a window provided on the polarizing member, a first adhesive member provided between the display panel and the polarizing member, and polarization are provided.
  • a foldable display device including a member and a second adhesive member provided between windows has been proposed.
  • Patent Document 1 describes that a foldable display device can include a touch sensing unit. Further, Patent Document 1 describes a foldable display device including a window WD, a touch sensing unit TSU, a polarizing member POL, and a display panel DP.
  • a first adhesive member AD1 is arranged between the window WD and the touch sensing unit TSU, a fourth adhesive member AD4 is arranged between the touch sensing unit TSU and the polarizing member POL, and the polarizing member POL and the display panel.
  • a second adhesive member AD2 is arranged between the DP and the DP.
  • JP-A-2017-126061 (Claim 1, [0132], [0138] and FIG. 7B)
  • the window member side is the surface (visual side), so that the surface on the window member side is required to have high pencil hardness.
  • the pencil hardness may be significantly lowered when the adhesive member is attached to another member.
  • peeling may occur between the bonded members, and high adhesiveness may not be ensured.
  • One aspect of the present invention is a window member and The first member laminated on the window member and A first laminated body or a panel member with a first touch sensor laminated on the window member via the first member.
  • a flexible image display device including a plurality of layers of adhesive members.
  • the first laminated body is a laminated body of a second member laminated via the first member and a third A member laminated via the first member and the second member on the window member. Yes, When the flexible image display device includes the first laminated body, One of the first member and the second member is an optical film, and the other is an optical film or a touch sensor.
  • the third A member includes at least a panel member.
  • the plurality of layers of the adhesive member are arranged at least between the window member and the first member, between the first member and the second member, and between the second member and the third A member. Including 3 layers to be
  • the first member is an optical film and
  • the plurality of layers of the adhesive member includes at least two layers arranged between the window member and the first member and between the first member and the panel member with the first touch sensor.
  • the elastic modulus (GPa) of the window member is E0 and the thickness (mm) of the window member is T0, E0 ⁇ T0 ⁇ 0.32.
  • the thickness of the first adhesive member arranged between the window member and the first member satisfies the condition of 10 ⁇ m or less.
  • the present invention relates to a flexible image display device in which the thickness of at least one layer other than the first adhesive member among the plurality of layers of the adhesive member satisfies a condition of 18 ⁇ m or more.
  • Another aspect of the present invention is used in the flexible image display device described above.
  • An optical laminate comprising a plurality of layers of adhesive members.
  • the second laminated body is a laminated body of a second member laminated via the first member and a third B member laminated via the first member and the second member on the window member.
  • the optical laminate includes the second laminate
  • One of the first member and the second member is an optical film
  • the other is an optical film or a touch sensor.
  • the third B member includes at least a second separator.
  • the plurality of layers of the adhesive member are arranged at least between the window member and the first member, between the first member and the second member, and between the second member and the third B member. Including 3 layers to be
  • the first member is an optical film and
  • the plurality of layers of the adhesive member includes at least two layers arranged between the window member and the first member and between the first member and the first separator.
  • the elastic modulus (GPa) of the window member is E0 and the thickness (mm) of the window member is T0, E0 ⁇ T0 ⁇ 0.32.
  • the thickness of the first adhesive member arranged between the window member and the first member satisfies the condition of 10 ⁇ m or less.
  • the present invention relates to an optical laminate in which the thickness of at least one layer other than the first adhesive member among the plurality of layers of the adhesive member satisfies the condition of 18 ⁇ m or more.
  • High pencil hardness can be ensured on the surface of the flexible image display device and the optical laminate used for the flexible image display device on the window member side. Further, when the flexible image display device is repeatedly bent in a high temperature environment, high adhesiveness between the laminated members can be ensured.
  • the flexible image display device includes a window member, a first member laminated on the window member, and a first laminated body or a panel member with a first touch sensor laminated on the window member via the first member. , With a plurality of layers of adhesive members.
  • the first laminated body is a laminated body of a second member laminated via the first member and a third A member laminated via the first member and the second member on the window member.
  • the flexible image display device includes the first laminated body, one of the first member and the second member is an optical film, and the other is an optical film or a touch sensor.
  • the third A member includes at least a panel member.
  • the plurality of layers of the adhesive member are at least three layers arranged between the window member and the first member, between the first member and the second member, and between the second member and the third B member. including.
  • the first member is an optical film.
  • the plurality of layers of the adhesive member includes at least two layers arranged between the window member and the first member and between the first member and the panel member with the first touch sensor.
  • the present invention also includes an optical laminate used in the above-mentioned flexible image display device.
  • the optical laminate includes a window member, a first member laminated on the window member, a second laminate or a first separator laminated on the window member via the first member, and a plurality of layers of adhesive members. Equipped.
  • the second laminated body is a laminated body of a second member laminated via the first member and a third B member laminated via the first member and the second member on the window member.
  • the optical laminate includes the second laminate
  • one of the first member and the second member is an optical film
  • the other is an optical film or a touch sensor.
  • the third B member includes at least a second separator.
  • the multi-layer adhesive member includes at least three layers arranged between the window member and the first member, between the first member and the second member, and between the second member and the third B member.
  • the first member is an optical film.
  • the plurality of layers of the adhesive member includes at least two layers arranged between the window member and the first member and between the first member and the first separator.
  • the optical laminate is used in a flexible image display device with the separator (specifically, the first separator or the second separator included in the third B member) peeled off.
  • the flexible image display device includes an optical laminate with the separator peeled off, with the window member arranged on the viewing side.
  • the flexible image display device is used in an exposed state with the surface on the window member side being the visual side. Therefore, the surface on the window member side is required to have high scratch resistance.
  • the scratch resistance of the surface on the window member side can be evaluated by, for example, a pencil hardness test. However, even if a high pencil hardness can be obtained only with the window member, if it is laminated with another member (for example, an optical film and a touch sensor) via an adhesive member to form a flexible image display device, a pencil on the surface of the window member side. It has become clear that the hardness can be significantly reduced.
  • the adhesive member has a high viscosity even when the members are bonded together, unlike the adhesive member that adheres the members to each other by curing.
  • the adhesive member is present in the flexible image display device, the stress is relaxed by the adhesive member when the surface on the window member side is pressed, but at that time, the adhesive member is deformed and the pressing mark is based on the pressure mark. It becomes difficult to return and the scratch resistance decreases.
  • the optical laminate includes a plurality of layers of adhesive members, such a decrease in scratch resistance becomes more remarkable.
  • stress relaxation unlike the case of an adhesive member is unlikely to occur, and a decrease in scratch resistance is hardly observed.
  • the constituent members are required to have high flexibility, it is considered that the influence of the highly viscous adhesive member on the pencil hardness is likely to become apparent.
  • the adhesive member is a hardened adhesive and does not have fluidity.
  • the adhesive member is a non-curable adhesive and has fluidity.
  • the adhesive member arranged between the window member and the first member (hereinafter referred to as the first adhesive member).
  • the thickness of is 10 ⁇ m or less.
  • the thickness of at least one layer other than the first adhesive member among the plurality of layers of the adhesive member contained in the flexible image display device or the optical laminate is set to satisfy the condition of 18 ⁇ m or more.
  • the pencil hardness on the window member side is harder than F, and a high pencil hardness can be ensured. Further, in the flexible image display device according to the present invention, it is possible to secure a pencil hardness higher than H on the window member side.
  • the pencil hardness means the scratch hardness (pencil method) specified in JIS K 5600-5-4: 1999.
  • the pencil hardness can be measured under the conditions of a load of 750 g and a weight of 25 ° C. in accordance with JIS K 5600-5-4: 1999.
  • each member in the flexible image display device or the optical laminate including the window member can be adjusted by, for example, adjusting the material, layer structure, and / or thickness of each member.
  • the optical laminate or the flexible image display device includes a plurality of layers of adhesive members. More specifically, when the flexible image display device (or optical laminate) includes the first laminate (or the second laminate), the flexible image display device (or the optical laminate) is at least the window member and the first. A three-layer adhesive member is provided between the first member, between the first member and the second member, and between the second member and the third A member (or the third B member). When the flexible image display device (or optical laminate) includes the panel member with the first touch sensor (or the first separator), the multi-layer adhesive member is at least between the window member and the first member, and the first. It includes a two-layer adhesive member arranged between the member and the panel member with the first touch sensor (or the first separator).
  • the multi-layer adhesive member may include an adhesive member other than the three-layer or two-layer adhesive member arranged between such adjacent members.
  • the adhesive member other than the three-layer or two-layer adhesive member is inside each member other than the window member (specifically, the first member, the second member, the third A member (or the third B member), and the first touch. It is arranged in at least one member selected from the group consisting of panel members with sensors).
  • Each adhesive member is usually layered.
  • the number of adhesive members in each member is not particularly limited, and may be 0 layer, 1 layer, or 2 or more layers.
  • the adhesive member (that is, the adhesive member having a plurality of layers) included in the flexible image display device or the optical laminate includes both the adhesive member included between the adjacent members and the adhesive member contained in each member. Is included.
  • the adhesive member included in the flexible image display device or the optical laminate may be, for example, 8 layers or less, 7 layers or 6 layers or less, or 5 layers or 4 layers or less.
  • the thickness of the first adhesive member is 10 ⁇ m or less, and may be 8 ⁇ m or less or 6 ⁇ m or less.
  • the thickness of the first adhesive member is set to such a range.
  • the thickness of each layer of the adhesive member is preferably 3 ⁇ m or more, more preferably 5 ⁇ m or more, and 8 ⁇ m or more or 10 ⁇ m or more, respectively. It may be 13 ⁇ m or more.
  • the thickness of at least one layer of the adhesive member other than the first adhesive member is 18 ⁇ m or more, and may be 20 ⁇ m or more.
  • the product of the elastic modulus E0 (GPa) of the window member and the thickness T0 (mm) of the window member is E0 ⁇ T0 ⁇ 0.32
  • at least one layer of the adhesive member other than the first adhesive member By setting the thickness in such a range, high adhesiveness between the laminated members can be ensured even when the flexible image display device is repeatedly bent in a high temperature environment.
  • the thickness of at least one adhesive member other than the first adhesive member may be 50 ⁇ m or less, 40 ⁇ m or less, or 40 ⁇ m or less. It may be 30 ⁇ m or less.
  • the thickness of at least one layer of the adhesive member may be 18 ⁇ m or more (or 20 ⁇ m or more).
  • the thickness of at least two layers of the pressure-sensitive adhesive member may be 18 ⁇ m or more or 20 ⁇ m or more.
  • the thickness of the pressure-sensitive adhesive member having such a thickness may be 50 ⁇ m or less, 40 ⁇ m or less, or 30 ⁇ m or less from the viewpoint of easily ensuring higher scratch resistance.
  • the thickness of the adhesive member located on the outer side of the adhesive member located on the inner side in the bent state of the flexible image display device may be 18 ⁇ m or more (or 20 ⁇ m or more). It is advantageous.
  • the thickness of the remaining adhesive member is not particularly limited. As described above, from the viewpoint of flexibility, the thickness of the remaining adhesive member may be, for example, 3 ⁇ m or more, 5 ⁇ m or more, 8 ⁇ m or more, 10 ⁇ m or more, or 13 ⁇ m or more. The thickness of the remaining adhesive member may be 50 ⁇ m or less, 40 ⁇ m or less, or 30 ⁇ m or less.
  • the surface of the window member on the first member side and the touch sensor or the panel member with a touch sensor are used.
  • a decorative layer may be provided so as to come into contact with the one-layer adhesive member. If the thickness of the adhesive member at the portion where the decorative layer is provided is small, it becomes difficult for the adhesive member to absorb the step formed by the decorative layer. Therefore, from the viewpoint of easily absorbing the step caused by the decorative layer, the thickness of the adhesive member with which the decorative layer comes into contact may be 10 ⁇ m or more. In the present invention, since the thickness of the first adhesive member is relatively small, the decorative layer is provided on the surface of the first member on the second member side or in the first member from the viewpoint of easily absorbing the step caused by the decorative layer. It is more advantageous to provide it.
  • the thickness of the adhesive member with which the decorative layer contacts may be 1.5 times or more the thickness of the decorative layer, or more than twice or 2.5 times, and further. May be tripled or more.
  • the upper limit value and the lower limit value of the layer thickness of the adhesive member described above can be arbitrarily combined.
  • the thickness of the adhesive member is measured by cutting out a cross section of a flexible image display device or an optical laminate and measuring the cross section based on an image obtained by a scanning electron microscope (SEM).
  • the thickness of the adhesive member is obtained by measuring and averaging the thicknesses of the portions where the decorative layer is not formed at an arbitrary plurality of locations (for example, 5 locations) in the SEM image of the cross section.
  • the storage elastic modulus of each adhesive member at 25 ° C. is usually 10 MPa or less, may be 3 MPa or less, 2 MPa or less, or 1.5 MPa or less.
  • the storage elastic modulus of each adhesive member at 25 ° C. is preferably 1 MPa or less, 0.3 MPa or less or 0.2 MPa or less, and 0.15 MPa or less or 0.1 MPa or less.
  • the flexible image display device includes a plurality of layers of adhesive members that can easily relieve stress due to pressing, high pencil hardness can be ensured by controlling the thickness of the first adhesive member. it can.
  • the storage elastic modulus of each adhesive member at 25 ° C. may be 0.001 MPa or more, or 0.005 MPa or more.
  • the upper limit and lower limit of the storage elastic modulus of the adhesive member described above can be arbitrarily combined.
  • the storage elastic modulus of the adhesive member at 25 ° C. is larger than 10 MPa, may be 100 MPa or more, and is usually about 1 GPa.
  • the adhesive member means a member having such a storage elastic modulus. In this way, the adhesive member is distinguished from the adhesive member by the storage elastic modulus.
  • the storage elastic modulus of the adhesive member can be measured in accordance with JIS K 7244-1: 1998. Specifically, first, a molded product having a thickness of about 1.5 mm is produced using an adhesive member. This molded product is punched into a disk shape having a diameter of 7.9 mm to prepare a test piece. This test piece is sandwiched between parallel plates, and the viscoelasticity is measured under the following conditions using a dynamic viscoelasticity measuring device (for example, "Advanced Rheometric Expansion System (ARES)" manufactured by Rheometric Scientific), and the viscoelasticity is measured at 25 ° C.
  • ADS Advanced Rheometric Expansion System
  • the storage elastic modulus in.
  • the storage elastic modulus of the adhesive member is also obtained in the same manner as in the case of the adhesive member.
  • the total light transmittance of each adhesive member is preferably 85% or more, more preferably 90% or more.
  • the total light transmittance of the adhesive member can be measured in accordance with JIS K 7136K: 2000.
  • a test piece in which an adhesive member is arranged on non-alkali glass is used.
  • Each adhesive member is composed of an adhesive.
  • the type of adhesive is not particularly limited, and for example, acrylic adhesive, rubber adhesive, silicone adhesive, urethane adhesive, vinyl alkyl ether adhesive, polyvinylpyrrolidone adhesive, polyacrylamide adhesive. , And a cellulose-based pressure-sensitive adhesive.
  • Adhesives include, for example, base polymers, cross-linking agents, additives (eg, tackifiers, coupling agents, polymerization inhibitors, cross-linking retarders, catalysts, plasticizers, softeners, fillers, colorants, metal powders.
  • Ultraviolet absorbers Ultraviolet absorbers, light stabilizers, antioxidants, deterioration inhibitors, surfactants, antistatic agents, surface lubricants, leveling agents, corrosion inhibitors, particles of inorganic or organic materials (metal compound particles (metal oxidation) (Object particles, etc.), resin particles, etc.)) are included, but are not limited thereto.
  • the pressure-sensitive adhesive that can obtain the above-mentioned storage elastic modulus as the pressure-sensitive adhesive because the effect of controlling the thickness of the pressure-sensitive adhesive member tends to be remarkable.
  • the pressure-sensitive adhesives constituting at least two layers of the pressure-sensitive adhesive members may be the same, and the pressure-sensitive adhesives constituting each pressure-sensitive adhesive member may be different.
  • the adhesive member can be formed, for example, by applying the adhesive constituting each adhesive member to one of the members that sandwich each adhesive member, or by transferring the adhesive formed into a sheet shape. Then, by laminating the other of the members that sandwich each adhesive member on the adhesive member, each adhesive member is arranged between the members. Even when the adhesive member is included in each member, the adhesive member is arranged in each member in the same manner as when the adhesive member is arranged between the members. For example, the adhesive member is arranged on one of the layers (or laminates) constituting each member and sandwiching the adhesive member by utilizing the application or transfer of the adhesive as described above, and the other layer (or laminate) is arranged. The adhesive member is arranged in each member by attaching the body) to the adhesive member.
  • the window member is arranged on the outermost surface of the flexible image display device or the optical laminate on the visual side in order to prevent damage to the optical film, the touch sensor, the panel member with the touch sensor, and the panel member.
  • the properties of the adhesive member (particularly, the first adhesive member) included in the flexible image display device or the optical laminate are the window. It affects the pencil hardness on the surface on the member side.
  • the thickness of at least one layer of the adhesive member other than the first adhesive member is the adhesiveness between the laminated members (or the layers constituting each member) when the flexible image display device is repeatedly bent in a high temperature environment. Affects.
  • the thickness of the first adhesive member as described above, a high pencil hardness can be ensured on the surface on the window member side.
  • the thickness of at least one layer other than the first adhesive member as described above high adhesiveness can be ensured even in a high temperature environment.
  • the window member usually includes a window film.
  • Flexible image display devices or optical laminates applied thereto are required to have high flexibility (high commutativity, etc.), high transparency (high total light transmittance, low haze, etc.), and high hardness.
  • the material of the window film is not particularly limited as long as it satisfies these physical characteristics.
  • the window film examples include a transparent resin film.
  • the resin constituting the transparent resin film include polyimide resin, polyamide resin, polyester resin, cellulose resin, acetate resin, styrene resin, sulfone resin, epoxy resin, polyolefin resin, and polyether. At least one selected from ether ketone resin, sulfide resin, vinyl alcohol resin, urethane resin, acrylic resin, and polycarbonate resin can be mentioned. However, the resin constituting the transparent resin film is not limited to these.
  • the thickness of the window film is, for example, 20 ⁇ m or more and 500 ⁇ m or less, and may be 30 ⁇ m or more and 200 ⁇ m or less. When the window film has such a thickness, it is easy to achieve both high strength and high flexibility.
  • the transparent material means that the total light transmittance of the test piece is 80% or more.
  • a test piece having a thickness of about 1.5 mm and made of a transparent material or member is used for measuring the total light transmittance. The total light transmittance can be measured according to the case of the adhesive member.
  • the window member may include a hard coat layer. From the viewpoint that a high damage prevention effect of the window film can be easily obtained, it is preferable that the hard coat layer is provided at least on the side opposite to the first member side of the window member. More specifically, it is preferable that the hard coat layer is provided on the surface at least on the side opposite to the first member side of the window film (that is, the visible side of the window film).
  • the thickness of the hard coat layer is, for example, 1 ⁇ m or more and 100 ⁇ m or less, and may be 1 ⁇ m or more and 50 ⁇ m or less.
  • the thickness of each hard coat layer may be within such a range.
  • the hard coat layer is formed by applying a curable coating agent to the surface of a underlying layer (for example, a window film) and curing it.
  • a curable coating agent for example, a window film
  • the coating agent for example, one for optical film can be used.
  • the coating agent include, but are not limited to, an acrylic coating agent, a melamine coating agent, a urethane coating agent, an epoxy coating agent, a silicone coating agent, and an inorganic coating agent.
  • the coating agent may contain an additive.
  • Additives include, for example, silane coupling agents, colorants, dyes, powders or particles (pigments, inorganic or organic fillers, particles of inorganic or organic materials, etc.), surfactants, plasticizers, antistatic agents. Examples thereof include, but are not limited to, agents, surface lubricants, leveling agents, antioxidants, light stabilizers, ultraviolet absorbers, polymerization inhibitors, antifouling materials, and the like.
  • the window member may be provided with another layer (hereinafter, referred to as layer A), if necessary.
  • layer A includes an antireflection layer, an antiglare layer, an antifouling layer, a sticking prevention layer, a hue adjustment layer, an antistatic layer, an easy-adhesion layer, a precipitation prevention layer such as ions or oligomers, a shock absorption layer, and a shatterproof layer.
  • the window member may include one layer A or a plurality of layers.
  • the layer A is provided, for example, on the surface side or the first member side of another layer or laminate (for example, a window film) constituting the window member.
  • the layer A may be directly formed by a coating or the like on another layer or a laminated body constituting the window film, or may be laminated via an adhesive member.
  • the window member does not include an adhesive member.
  • the adhesive member refers to an adhesive member having a storage elastic modulus at 25 ° C. as described above.
  • the thickness T0 of the window member is, for example, 0.02 mm or more and 0.6 mm or less, and may be 0.03 mm or more and 0.3 mm or less.
  • the thickness T0 of the window member is measured based on a cross section of the flexible image display device or the optical laminate and an SEM image of the cross section.
  • the thickness T0 is obtained by measuring the thickness at an arbitrary plurality of points (for example, 5 points) and averaging the thickness in the SEM image of the cross section.
  • the thickness of the member constituting the optical laminate or the flexible image display device is obtained according to the case of the thickness T0 of the window member.
  • the elastic modulus E0 of the window member is, for example, 0.53 GPa or less and 16 GPa or less, and may be 1 GPa or more and 15 GPa or less, 1 GPa or more and 10 GPa or less, or 3 GPa or more and 8 GPa or less.
  • the elastic modulus E0 (GPa) of the window member is an average value (arithmetic mean value) obtained by preparing three samples for measuring the window member, measuring the elastic modulus of each sample by a tensile test, and averaging them. is there.
  • the tensile test can be performed under the following conditions using the following device.
  • Tensile tester Shimadzu Corporation, Autograph AG-1S Control: Stroke Station distance: 100 mm
  • Elastic modulus calculation range 10N / mm 2 to 20N / mm 2
  • the sample for measuring the elastic modulus is prepared as follows. First, the elastic modulus of the window member in the vertical and horizontal directions is measured. Next, a sample is prepared by cutting the window member into strips with a length in the direction of high elastic modulus of 150 mm and a length of 10 mm in the direction of low elastic modulus. For cutting the window member, for example, a multipurpose test piece cutting machine manufactured by Dumbbell Co., Ltd. is used.
  • E0 ⁇ T0 (kN / mm) may be 0.32 or less, and may be 0.3 or less. Further, E0 ⁇ T0 is, for example, 0.01 or more, and may be 0.02 or more, 0.05 or more, 0.1 or more, or 0.2 or more. These upper limit values and lower limit values can be arbitrarily combined.
  • the first member is laminated on the window member.
  • the flexible image display device or optical laminated body
  • the second member is laminated on the window member via the first member.
  • An adhesive member is interposed between the window member and the first member, and between the first member and the second member, respectively.
  • the flexible image display device or optical laminate
  • one of the first member and the second member is an optical film
  • the other is an optical film or a touch sensor. ..
  • the flexible image display device (or optical laminate) includes a third A member (or a third B member), one of the first member and the second member may be an optical film, and the other may be a touch sensor.
  • the flexible image display device includes the panel member with the first touch sensor and the optical laminate includes the first separator, the first member may be an optical film.
  • the third A member includes a panel member with a second touch sensor, each of the first member and the second member may be an optical film.
  • the elastic moduli (GPa) of the first member and the second member are E1 and E2, respectively, and the thicknesses (mm) of the first member and the second member are T1 and T2, respectively.
  • the first member and the second member each satisfy the following.
  • the product of the elastic modulus and the thickness of each member is in such a range, the effect of controlling the thickness of each layer of the adhesive member as described above can be further easily obtained. 0.01 ⁇ E1 x T1 ⁇ 0.35 (first member) 0.01 ⁇ E2 x T2 ⁇ 0.35 (second member)
  • the unit of each of E1 ⁇ T1 and E2 ⁇ T2 is kN / mm.
  • the optical film is a film that imparts an optical function.
  • An optical film is usually a laminate containing at least one layer having an optical function. Examples of the optical film include those used in the field of image display devices and the like.
  • Each of the first member and the second member may be an optical film, or may be one layer or a laminate of two or more layers constituting the optical film.
  • the layer having an optical function examples include a layer having an optically anisotropic substance (for example, an optically anisotropic film).
  • the layer having optical anisotropy include, but are limited to, a polarizer, a retardation layer, a viewing angle expanding film, a viewing angle limiting (peeping prevention) film, a brightness improving film, and an optical compensation film. It's not something.
  • the laminate of two or more layers may have two or more selected from these layers having optical anisotropy. In a laminate of two or more layers, all of the layers having optical anisotropy may have different functions, or at least two layers may have the same function.
  • the laminate may include a polarizer and a retardation layer, or may include two retardation layers having different compositions.
  • the optical film may include a layer having at least one optical function and a base material layer (or a protective layer that protects the layer).
  • the polarizing plate includes at least a film-shaped polarizing element, and may be composed of a polarizing element and a protective film that protects the polarizing element.
  • the polarizer is not particularly limited, and those used in the field of image display devices can be used.
  • the polarizer include a film in which a dichroic substance is adsorbed on a hydrophilic polymer film and uniaxially stretched, and a polyene-based oriented film.
  • the hydrophilic polymer constituting the hydrophilic polymer film include polyvinyl alcohol-based resins (including partially formalized polyvinyl alcohol-based resins) and partially saponified ethylene-vinyl acetate copolymers.
  • the dichroic substance include iodine and a dichroic dye.
  • the material constituting the polyene-based alignment film include a dehydrated product of a polyvinyl alcohol-based resin and a dehydrochlorinated product of a polyvinyl chloride-based resin.
  • polarizer a thin polarizer having a thickness of 10 ⁇ m or less may be used.
  • the thin polarizing element are described in JP-A-51-069644, JP-A-2000-338329, International Publication No. 2010/100917 Pamphlet, Patent No. 46910205, and Japanese Patent No. 4751481. Polarizers can be mentioned.
  • the thin polarizing element is obtained by, for example, a manufacturing method including a step of stretching a polyvinyl alcohol-based resin layer and a resin base material layer in a laminated state and a step of dyeing with a dichroic material.
  • the protective film for example, a polymer film having excellent transparency, mechanical strength, thermal stability, moisture blocking property, and optical isotropic property is used.
  • the polymer material having such properties the protective film includes, for example, cellulose-based resin, polyolefin-based resin (including cyclic polyolefin-based resin), acrylic-based resin, imide-based resin (including phenylmaleimide-based resin), and polyamide.
  • Based resin polycarbonate resin, polyester resin (including polyarylate resin), acetate resin, polyether sulfone resin, polyvinyl chloride resin, polyvinylidene chloride resin, polystyrene resin, polyvinyl alcohol resin , At least one selected from the group consisting of sulfide-based resins (for example, polyphenylene sulfide-based resins), polyether ether ketone-based resins, epoxy-based resins, and urethane-based resins.
  • the resin constituting the protective film is not limited to these polymer materials.
  • the optical film may include one layer of protective film or may include two or more layers of protective film.
  • the protective film may be arranged on one surface of a layer having an optical function (for example, a polarizer), or may be arranged on both surfaces. Further, the optical film may include two or more layers having an optical function in which a protective film is arranged on one surface. If the optical film contains more than one layer of protective film (eg, if the protective film is placed on both surfaces of the polarizer), the composition of all protective films may be different and at least two layers of protection The composition may be the same in the film.
  • the optical film may include, in addition to the polarizer or the polarizing plate, another film (hereinafter, referred to as layer B) that further imparts an optical function other than the polarizer or the polarizing plate.
  • layer B include those used in the field of image display devices.
  • the layer B may be, for example, an optically anisotropic film.
  • examples of the layer B include layers other than the polarizer or the polarizing plate among the above-mentioned layers having optical anisotropy.
  • examples of the layer B include a retardation layer, a viewing angle expanding film, a viewing angle limiting (peeping prevention) film, a brightness improving film, and an optical compensation film.
  • the optical film may contain one such layer B, or may contain two or more such layers B. However, layer B is not limited to these.
  • the thickness of the optical film is, for example, 5 ⁇ m or more and 500 ⁇ m or less, and may be 10 ⁇ m or more and 100 ⁇ m or less.
  • the thickness of the polarizing plate is, for example, 200 ⁇ m or less. From the viewpoint of easily ensuring high flexibility, the thickness of the polarizing plate is preferably 100 ⁇ m or less, more preferably 80 ⁇ m or less or 70 ⁇ m or less. The thickness of the polarizing plate is, for example, 10 ⁇ m or more.
  • the thickness of layer B is, for example, 0.1 ⁇ m or more and 100 ⁇ m or less.
  • the thickness of the laminate of the layer B and the polarizing plate is within the range described for the thickness of the polarizing plate. It is preferable to adjust the thickness of the layer B so as to be.
  • the layers constituting the optical film may be directly laminated on the adjacent layers by using a coating or the like. Further, the layers constituting the optical film may be laminated on adjacent layers via an adhesive member or an adhesive member.
  • the layer B may be laminated on the polarizing plate via an adhesive member, or may be laminated via an adhesive member. When two or more adjacent layers B are provided, the adjacent layers B may be laminated via either an adhesive member or an adhesive member.
  • touch sensor for example, a touch sensor used in the field of an image display device or the like is used.
  • the touch sensor include, but are not limited to, a resistive film type, a capacitance type, an optical type, and an ultrasonic type.
  • a capacitance type for example, a resistive film type, a capacitance type, an optical type, and an ultrasonic type.
  • an optical film is present between the touch sensor and the window member, it is easy to obtain high sensitivity by using a capacitive touch sensor.
  • Capacitive touch sensors usually have a transparent conductive layer.
  • Examples of such a touch sensor include a laminate of a transparent conductive layer and a transparent base material.
  • Examples of the transparent base material include a transparent film.
  • the transparent conductive layer is not particularly limited, but conductive metal oxides, metal nanowires, etc. are used.
  • the metal oxide include indium oxide (ITO: Indium Tin Oxide) containing tin oxide and tin oxide containing antimony.
  • the transparent conductive layer may be a conductive pattern composed of a metal oxide or a metal. Examples of the shape of the conductive pattern include, but are not limited to, a striped shape, a square shape, and a grid shape.
  • the surface resistance value of the transparent conductive layer may be, for example, 0.1 ⁇ / ⁇ or more and 1000 ⁇ / ⁇ or less, and 0.5 ⁇ / ⁇ or more and 500 ⁇ / ⁇ or less.
  • the thickness of the transparent conductive layer is, for example, 0.005 ⁇ m or more and 10 ⁇ m or less, and may be 0.01 ⁇ m or more and 3 ⁇ m or less.
  • the transparent film for example, a transparent resin film is used.
  • the resins constituting the transparent resin film include polyester resins (including polyarylate resins), acetate resins, polyether sulfone resins, polycarbonate resins, polyamide resins, polyimide resins, polyolefin resins, and acrylics.
  • Based resin polyvinyl chloride resin, vinylidene chloride resin, polystyrene resin, polyvinyl alcohol resin, sulfide resin (for example, polyphenylene sulfide resin), polyether ether ketone resin, cellulose resin, epoxy resin , Urethane-based resin and the like.
  • the transparent resin film may contain one kind of these resins, or may contain two or more kinds of these resins. Of these resins, polyester-based resins, polyimide-based resins and polyether sulfone-based resins are preferable. However, the resin constituting the transparent resin film is not limited to these resins.
  • a surface-treated transparent base material may be used.
  • the surface treatment a known one can be adopted.
  • the transparent base material may be subjected to, for example, a dust removal or cleaning treatment (cleaning treatment using a solvent, ultrasonic waves, or the like) prior to laminating the transparent conductive layer.
  • the touch sensor may be provided with a layer other than the transparent conductive layer and the transparent base material (hereinafter referred to as layer C).
  • layer C a layer other than the transparent conductive layer and the transparent base material
  • an undercoat layer or an oligomer precipitation prevention layer may be provided as the layer C between the transparent conductive layer and the transparent base material.
  • the layer C may be laminated on at least one surface of the transparent conductive layer and the transparent base material.
  • the layer C includes a functional layer having a desired function (for example, a film imparting the above optical function (optically anisotropic film or the like), a layer having the above optical function), a decorative base film, or the like. Can be mentioned.
  • the decorative base film is laminated on the surface of the transparent conductive layer, for example.
  • layer C is not limited to these layers.
  • the layer C may be laminated on the transparent conductive layer or the transparent base material via the adhesive member or the adhesive member, if necessary.
  • the thickness of the entire touch sensor is, for example, 5 ⁇ m or more and 250 ⁇ m or less, and may be 10 ⁇ m or more and 200 ⁇ m or less.
  • the third member is laminated on the window member via the first member and the second member.
  • An adhesive member is interposed between the second member and the third member.
  • the third member of the flexible image display device is referred to as a third A member.
  • the third A member includes at least a panel member.
  • the third member of the optical laminate is referred to as a third B member.
  • the third B member includes at least a separator (second separator).
  • the optical laminate is included in the flexible image display device with the separator peeled off.
  • the third B member does not include either a panel member or a panel member with a touch sensor.
  • Each of the third A member and the third B member may be a laminated body.
  • Each of the third A member and the third B member may include an adhesive member or an adhesive member.
  • the third A member may include at least a panel member.
  • the third A member may be, for example, a laminated body of a panel member and a protective member that protects the panel member.
  • the protective member is usually laminated on the side opposite to the second member side of the panel member. That is, the protective member is provided on the side opposite to the visible side of the panel member.
  • the third A member is not limited thereto.
  • adjacent layers (or members, for example, a panel member and a protective member) constituting the laminated body may be laminated via an adhesive member or an adhesive member.
  • the elastic modulus (GPa) of the third A member is E3, and the thickness (mm) of the third A member is T3.
  • the third A member preferably satisfies the following equation. 0.01 ⁇ E3 x T3 ⁇ 0.35
  • the unit of E3 ⁇ T3 is kN / mm.
  • the third B member in the optical laminate may include at least a separator.
  • the third B member may be composed of only a separator.
  • the third B member is laminated with the second member so that the separator comes into contact with the adhesive member arranged on the side opposite to the first member side of the second member. Then, the flexible image display device is formed by peeling the separator from the optical laminate and attaching the exposed adhesive member to the third A member (specifically, the panel member or the laminate including the panel member). ..
  • the panel member includes, for example, at least an image display panel.
  • a sealing member (thin film sealing layer or the like) may be arranged on the visual side of the image display panel.
  • the sealing member is usually arranged directly on the visible surface of the image display panel.
  • a known image display panel is used.
  • Examples of the image display panel include an organic electroluminescence (EL) panel.
  • EL organic electroluminescence
  • the protective member examples include a sheet or film (or substrate) that holds or protects the panel member.
  • the protective member may be one that holds the panel member, has an appropriate strength for protecting the panel member, and has an appropriate flexibility that does not hinder the flexibility of the flexible image display device.
  • a resin sheet or the like is used as the protective member.
  • the material of the resin sheet is not particularly limited and can be appropriately selected depending on the type of the image display panel, for example.
  • the panel member with a touch sensor (specifically, each of the panel member with a first touch sensor and the panel member with a second touch sensor included in the third A member) is an integral body of the touch sensor and the panel member. ..
  • a panel member with a touch sensor includes, for example, a structure in which an antistatic capacity type touch sensor of a metal mesh electrode is formed on a thin film sealing layer of an organic light emitting diode (OLED). LED.
  • OLED organic light emitting diode
  • the panel member includes, for example, at least an image display panel.
  • a sealing member (thin film sealing layer or the like) may be arranged on the visual side of the image display panel.
  • the sealing member is usually arranged directly on the visible surface of the image display panel.
  • a known image display panel is used.
  • Examples of the image display panel include an organic electroluminescence (EL) panel.
  • EL organic electroluminescence
  • the panel member with a touch sensor may be provided with a protective member.
  • the protective member include a sheet or film (or substrate) that holds or protects the panel member.
  • the protective member may be one that holds the panel member, has an appropriate strength for protecting the panel member, and has an appropriate flexibility that does not hinder the flexibility of the flexible image display device.
  • a resin sheet or the like is used as the protective member. The material of the resin sheet is not particularly limited and can be appropriately selected depending on the type of the image display panel, for example.
  • the elastic modulus (GPa) of the panel member with a touch sensor is Ep
  • the thickness (mm) of the panel member with a touch sensor is Tp.
  • the panel member with the touch sensor preferably satisfies the following formula. 0.01 ⁇ Ep x Tp ⁇ 0.35
  • the unit of Ep ⁇ Tp is kN / mm.
  • the separator (specifically, each of the first separator and the second separator included in the third B member) includes, for example, a base sheet and a release agent arranged on at least one surface of the base sheet. Sheets are used.
  • the separator is arranged with the release agent in contact with the adhesive member. More specifically, the first separator is arranged in contact with the adhesive member arranged on the side opposite to the window member of the first member.
  • the second separator is arranged in contact with the adhesive member arranged on the side opposite to the first member side of the second member.
  • the base sheet may have a structure other than the first separator or the third B member of the optical laminate, have appropriate strength and flexibility, and can easily form a release agent layer.
  • a resin film, paper, a laminate thereof, or the like is used as the base sheet.
  • the material of the base sheet is determined according to the type of release agent, the composition of the optical laminate, and the like.
  • the resin film for example, a polyester film (polyethylene terephthalate film or the like) or a polyolefin film (polypropylene film or the like) may be used.
  • the thickness of the base sheet is not particularly limited, and can be selected in consideration of desired peelability.
  • the release agent a known one can be used, and it is preferable to select one having a small residual amount of the adhesive member on the separator.
  • a silicone-based release agent or a fluorine-based release agent may be used.
  • the decorative layer is, for example, any one layer between the window member and the touch sensor or the panel member with a touch sensor (more specifically, the panel member with the first touch sensor or the panel member with the second touch sensor). It is arranged so as to come into contact with the adhesive member of.
  • the decorative layer may be arranged so as to come into contact with the adhesive member.
  • the decorative layer is usually provided in a frame-like pattern on the outer periphery of the display unit on which the image is displayed so that the lead wiring of the drive element or the touch sensor is not visible from the outside.
  • the shape of the decorative layer is not limited to the frame shape, and may be any shape that can hide the lead-out wiring and the like.
  • the decorative layer is required to block the light from the side opposite to the viewing side.
  • a decorative layer is composed of, for example, an ink layer, a metal thin film, and a thin film containing metal fine particles.
  • the thin film containing the metal fine particles includes, for example, the metal fine particles and the binder resin.
  • the decorative layer may have a single-layer structure or a laminated structure.
  • the decorative layer of the laminated structure may be, for example, at least two laminated bodies selected from an ink layer, a metal thin film, and a thin film containing metal fine particles.
  • the laminate also includes a laminate of two or more ink layers having different compositions, two or more metal thin films having different compositions, or a thin film containing two or more metal fine particles having different compositions.
  • the thickness of the decorative layer is, for example, 20 ⁇ m or less, and may be 15 ⁇ m or less. From the viewpoint that the step due to the decorative layer can be easily eliminated by the adhesive member, the thickness of the decorative layer is preferably 10 ⁇ m or less, and may be 8 ⁇ m or less or 5 ⁇ m or less. Further, when the thickness of the decorative layer is in such a range, it is easy to secure high bending resistance of the flexible image display device and the optical laminate. From the viewpoint of ensuring a higher concealing effect of the lead wiring, the thickness of the decorative layer is preferably 10 nm or more, more preferably 30 nm or more or 50 nm or more. These upper limit values and lower limit values can be arbitrarily combined.
  • the decorative layer may be formed, for example, by applying a coating agent containing a component of the decorative layer to the surface of a member or layer (excluding the adhesive member) that comes into contact with the decorative layer.
  • a coating agent containing a component of the decorative layer For example, the surface of the window member on the first member side, the surface of the first member on the first laminated body side or the surface of the panel member with the first touch sensor (or the first separator side), and when the second member is an optical film, the first The decorative layer may be formed by applying a coating agent containing a component of the decorative layer to any of the surfaces of the two members on the third A member side (or the third B member side).
  • the decorative layer may be formed by depositing constituent components on the surface of a member or layer (excluding the adhesive member) in contact with the decorative layer by a vapor phase method.
  • a vapor phase method For example, the surface of the window member on the first member side, the surface of the first member on the first laminated body side or the surface of the panel member with the first touch sensor (or the first separator side), and when the second member is an optical film, the first The decorative layer may be formed by depositing the constituent components by the vapor phase method on any of the tables on the third A member side (or the third B member side) of the two members.
  • a decorative layer having a small thickness can be easily formed by using the vapor phase method.
  • the vapor phase method examples include a sputtering method, a vacuum vapor deposition method, a chemical vapor deposition (CVD) method, and an electron beam vapor deposition method. According to these cases, when the decorative layer is formed on the surface of the layer or the laminated body constituting the first member or the second member, the decorative layer can be formed in each member.
  • a primer layer may be arranged on the surface of a member or layer (excluding the adhesive member) to which the coating agent is applied prior to application.
  • a member or layer excluding the adhesive member
  • the decorative layer is provided on the surface of the window member on the first member side, even if the primer layer is arranged between the decorative layer and the surface of the window member on the first member side. Good.
  • the decorative layer is provided on the surface of the first laminated body side of the first member or the panel member side with the first touch sensor (or the first separator side), the decorative layer and the first laminated body side of the first member
  • a primer layer may be arranged between the surface of the panel member with the first touch sensor (or the side of the first separator).
  • the primer layer contains, for example, at least one selected from the group consisting of metal compounds (metal oxides, metal nitrides, metal carbides, metal sulfides, etc.) and resin materials.
  • the primer layer is preferably transparent.
  • the thickness of the primer layer is preferably small from the viewpoint that the adhesive member easily absorbs the step of the decorative layer and the optical influence of the primer layer can be easily suppressed.
  • the thickness of the primer layer is, for example, 500 nm or less, preferably 100 nm or less or 30 nm or less.
  • the flexible image display device and the optical laminate are manufactured, for example, by laminating the constituent members while arranging the adhesive members between the respective members (and, if necessary, between the layers constituting the respective members).
  • the stacking order is not particularly limited.
  • the window member and the first member were laminated with the first adhesive member interposed therebetween, and then the first member and the second member were interposed between the members. It may be laminated in a state. Further, after the first member and the second member are laminated with the adhesive member interposed therebetween, the first member and the window member are interposed between the members with the first adhesive member. May be laminated with. It is preferable that each adhesive member is previously attached to one of the members that sandwich each adhesive member.
  • the adhesive member may be arranged on the surface of the second member opposite to the first member side before laminating the second member with the first member. Further, the adhesive member may be arranged on the surface of the second member opposite to the first member side at an appropriate stage after the second member is laminated with the first member.
  • the separator is laminated on the adhesive member arranged on the surface of the second member opposite to the first member side before or after the adhesive member is arranged on the surface of the second member.
  • the flexible image display device is manufactured by preparing an optical laminate in advance, peeling the third B member (more specifically, a separator) from the optical laminate, and attaching the exposed adhesive member to the third A member. You may. Further, the third A member and the second member are laminated so that the adhesive member is interposed between them, and then the first member is laminated on the second member so that the adhesive member is interposed between them, and then.
  • An image display device may be manufactured by laminating a window member on the first member so that an adhesive member is interposed between them. Further, a laminated body of the third A member and the second member and a laminated body of the window member and the first member are prepared in advance, and these laminated bodies are placed between the first member and the second member. May be laminated in a state of interposing.
  • the flexible image display device or the optical laminate includes a panel member with a touch sensor, it can be manufactured by laminating each member according to these manufacturing methods.
  • FIG. 1 is a schematic cross-sectional view of the flexible image display device of the first embodiment according to the above aspect of the present invention.
  • the flexible image display device 1 includes a laminated body of a window member 11, an optical film 12 as a first member, a touch sensor 13 as a second member, and a panel member 14 as a third A member.
  • the laminated body of the touch sensor 13 which is the second member and the panel member 14 which is the third A member corresponds to the first laminated body L.
  • the optical film 12 and the window member 11 are laminated with an adhesive member (first adhesive member) 21 interposed between the optical film 12 and the window member 11.
  • the touch sensor 13 is laminated on the window member 11 via the optical film 12.
  • An adhesive member 22 is interposed between the optical film 12 and the touch sensor 13.
  • the panel member 14 is laminated on the window member 11 via the optical film 12 and the touch sensor 13.
  • An adhesive member 23 is interposed between the touch sensor 13 and the panel member 14.
  • the laminated body of the structure excluding the panel member 14 and the separator (not shown) in FIG. 1 corresponds to an optical laminated body.
  • the window member 11 includes, for example, a window film 111 and a hard coat layer 112 laminated on the window film 111.
  • the hard coat layer 112 is provided on the side of the window member 11 opposite to the first member (optical film 12) side (more specifically, the surface of the window film 111 opposite to the first member side). .. Then, the product of the elastic modulus E0 of the window member 11 and the thickness T0 satisfies E0 ⁇ T0 ⁇ 0.32.
  • the optical film 12 includes a polarizing plate composed of a polarizing element 121 and a protective film 122, and a retardation layer 123.
  • the retardation layer 123 is arranged on the touch sensor 13 side, which is the second member, and is laminated on the polarizer 121 side of the polarizing plate.
  • the touch sensor 13 includes a transparent conductive layer 131 and a transparent film (touch sensor film) 132 as a transparent base material.
  • the touch sensor 13 is arranged so that the transparent conductive layer 131 comes into contact with the adhesive member 22 arranged between the optical film 12 and the touch sensor 13.
  • the panel member 14 includes an organic EL panel (organic EL display) 141 and a thin film sealing layer 142.
  • the panel member 14 is arranged so that the thin film sealing layer 142 comes into contact with the adhesive member 23 arranged between the touch sensor 13 and the panel member 14.
  • E0 ⁇ T0 ⁇ 0.32, and the thickness of the first adhesive member 21 is controlled to be within the above range. Further, the thickness of at least one layer of the adhesive member other than the first adhesive member 21 is controlled to be within the above range.
  • high pencil hardness is ensured on the surfaces of the flexible image display device 1 and the optical laminated body on the window member 11 side, and even if the flexible image display device is repeatedly bent in a high temperature environment, the laminated members are separated from each other. High adhesiveness can be ensured.
  • a frame-shaped decorative layer 30 is provided on the surface of the first member (optical film 12) on the second member (touch sensor 13) side.
  • the thickness of the adhesive member specifically, the adhesive member 22
  • the decorative layer 30 comes into contact
  • FIG. 1 shows a case where the decorative layer 30 is formed on the surface of the optical film 12 on the touch sensor 13 side, but the case is not limited to this case.
  • the decorative layer 30 may be provided on the surface of the window member 11 on the first member (optical film 12) side.
  • FIG. 1 shows a case where the first member is an optical film 12, the second member is a touch sensor 13, and the third A member is a panel member.
  • the touch sensor may be laminated on the window member 11 as the first member, and the optical film as the second member may be laminated on the window member 11 via the touch sensor.
  • the third A member a laminated body including the panel member as described above may be used.
  • FIG. 2 is a schematic cross-sectional view of the flexible image display device of the second embodiment.
  • the flexible image display device 101 includes a window member 11, an optical film 12A as the first member, and a laminate of the first laminate L.
  • the first laminated body L has a structure in which an optical film 12B, which is a second member, and a panel member 15B with a second touch sensor, which is a third A member, are laminated.
  • An adhesive member 21 is interposed between the window member 11 and the optical film 12A.
  • An adhesive member 22 is interposed between the optical film 12A and the first laminated body L, and an adhesive member 23 is interposed between the optical film 12B and the panel member 15B with a second touch sensor. Except for the configuration of the optical film 12A and the first laminated body L, which are the first members, the same as the first embodiment, and the description of the first embodiment can be referred to.
  • the optical film 12A is a polarizing plate composed of a polarizing element 121 and a protective film 122.
  • the polarizing element 121 is arranged on the adhesive member 22 side (in other words, the side opposite to the window member 11).
  • the optical film 12B is a laminate of two retardation layers 123 and 124.
  • a laminate of a configuration excluding the panel member 15B with a second touch sensor and a separator (second separator) (not shown) corresponds to an optical laminate.
  • FIG. 3 is a schematic cross-sectional view of the flexible image display device according to the third embodiment.
  • the flexible image display device 201 includes a laminated body of a window member 11, an optical film 12 as a first member, and a panel member 15A with a first touch sensor.
  • An adhesive member 21 is interposed between the window member 11 and the optical film 12.
  • An adhesive member 22 is interposed between the optical film 12 and the panel member 15A with the first touch sensor. It is the same as the first embodiment except that the panel member 15A with the first touch sensor is arranged in place of the first laminated body L.
  • the description of the first embodiment can be referred to.
  • the laminated body of the configuration excluding the panel member 15A with the first touch sensor and the separator (first separator) (not shown) corresponds to the optical laminated body.
  • E0 ⁇ T0 ⁇ 0.32, and the thickness of the first adhesive member 21 is controlled to be within the above range. Further, the thickness of at least one layer of the adhesive member other than the first adhesive member 21 is controlled to be within the above range.
  • Examples 1 to 4 and Comparative Examples 1 to 6 >> (1) Preparation of Evaluation Sample An evaluation sample of the flexible image display device 1 as shown in FIG. 1 was prepared by the following procedure.
  • the hard coat layer 112 was formed by using a coating agent for the hard coat layer.
  • a coating agent was applied to one side of the transparent polyimide film to form a coating layer, and the coating layer was heated together with the transparent polyimide film at 90 ° C. for 2 minutes.
  • the hard coat layer 112 was formed by irradiating the coating layer with ultraviolet rays using a high-pressure mercury lamp at an integrated light intensity of 300 mJ / cm 2.
  • the window member 11 was manufactured in this way.
  • the coating agent for the hard coat layer is 100 parts by mass of a polyfunctional acrylate (manufactured by Aika Kogyo Co., Ltd., product name "Z-850-16") as a base resin, and a leveling agent (manufactured by DIC Co., Ltd., product name: GRANDIC PC). -4100) Mix 5 parts by mass and 3 parts by mass of the photopolymerization initiator (trade name: Irgacure 907, manufactured by Ciba Japan) and dilute with methyl isobutyl ketone so that the solid content concentration becomes 50% by mass. Prepared by
  • amorphous polyethylene terephthalate film (thickness 100 ⁇ m) containing 7 mol% of isophthalic acid unit was prepared as a base material made of a thermoplastic resin, and the surface was subjected to corona discharge treatment at an output discharge amount of 58 W / m 2 ⁇ min. ..
  • a coating liquid is applied to the surface of the base material so that the film thickness after drying is 12 ⁇ m, and the PVA-based resin layer is formed on the base material by drying in an atmosphere of 60 ° C. for 10 minutes by hot air drying.
  • the provided laminate was produced.
  • the obtained laminate was first stretched 1.8 times at a free end (auxiliary stretching in the air) at 130 ° C. in the air to produce a stretched laminate.
  • a step of insolubilizing the PVA layer in which the PVA molecules contained in the stretched laminate were oriented was performed by immersing the stretched laminate in a boric acid insoluble aqueous solution having a liquid temperature of 30 ° C. for 30 seconds.
  • the boric acid insoluble aqueous solution in this step is a boric acid aqueous solution having a boric acid content of 3 parts by mass with respect to 100 parts by mass of water.
  • a colored laminate was produced by dyeing the obtained stretched laminate.
  • the stretched laminate is mixed with a dyeing solution containing iodine and potassium iodide at a liquid temperature of 30 ° C., and the single transmittance of the PVA layer constituting the polarizer finally produced is 40 to 44%.
  • the PVA layer contained in the stretched laminate was stained with iodine by immersing the PVA layer in the stretched laminate for a predetermined time.
  • the staining solution is an aqueous solution containing iodine and potassium iodide (iodine concentration: 0.1 to 0.4% by mass, potassium iodide concentration: 0.7 to 2.8% by mass, iodine and potassium iodide). Concentration ratio: 1: 7).
  • a step of cross-linking the PVA molecules of the PVA layer on which iodine was adsorbed was performed by immersing the colored laminate in a boric acid cross-linked aqueous solution at 30 ° C. for 60 seconds.
  • the boric acid cross-linked aqueous solution in this step is an aqueous solution containing boric acid and potassium iodide (boric acid content: 3 parts by mass with respect to 100 parts by mass of water, potassium iodide content: 3 parts by mass with respect to 100 parts by mass of water). Department).
  • the obtained colored laminate is finally stretched 3.05 times in the boric acid aqueous solution at a stretching temperature of 70 ° C. in the same direction as the above stretching in air (stretching in boric acid water).
  • a laminate having a draw ratio of 5.50 times was obtained.
  • the obtained laminate was taken out from the boric acid aqueous solution, and the boric acid adhering to the surface of the PVA layer was washed with a potassium iodide aqueous solution (potassium iodide content: 4 parts by mass with respect to 100 parts by mass of water).
  • the washed laminate was dried by a drying step with warm air at 60 ° C.
  • the thickness of the polarizer 121 contained in the dried laminate was 5 ⁇ m.
  • protective film 122 As the protective film 122, an acrylic film obtained by molding a methacrylic resin pellet having a glutarimide ring unit into a film by extrusion molding and then stretching the film was used. The thickness of the protective film was 40 ⁇ m.
  • a polarizing plate was produced by bonding the protective film 122 and the polarizer 121 together using an adhesive (active energy ray-curable adhesive) and irradiating the adhesive with ultraviolet rays under the following conditions to cure the adhesive.
  • Gallium-filled metal halide lamp Fusion UV Systems.
  • Bulb V bulb Peak illuminance: 1600 mW / cm 2
  • Integrated irradiation dose 1000 mJ / cm 2 (wavelength 380 to 440 nm)
  • the adhesive was prepared by mixing the following components at a ratio such that the content in 100% by mass of the adhesive had the following value, and stirring at 50 ° C. for 1 hour.
  • Hydroxyethyl acrylamide ... 11.4% by mass Tripropylene glycol diacrylate ... 57.1% by mass Acryloyl morpholine ... 11.4% by mass 2-Acetacetoxyethyl methacrylate ... 4.6% by mass Acrylic polymer (ARUFON UP-1190, manufactured by Toagosei Co., Ltd.) ... 11.4% by mass 2-Methyl-1- (4-methylthiophenyl) -2-morpholinopropane-1-one ... 2.8% by mass Diethylthioxanthone ... 1.3% by mass
  • retardation layer 123 a retardation film including two layers, a retardation layer for a 1/4 wave plate in which a liquid crystal material is oriented and immobilized, and a retardation layer for a 1/2 wavelength plate was used.
  • a material for forming the retardation layer for the 1/2 wave plate and the retardation layer for the 1/4 wave plate a polymerizable liquid crystal material (manufactured by BASF, trade name Palocolor LC242) showing a nematic liquid crystal phase was used.
  • the retardation layer 123 was prepared with reference to the description in paragraphs [0118] to [0120] of JP-A-2018-288573.
  • (C) Formation of Decorative Layer A frame-shaped black ink layer (width 15 mm, thickness 5 ⁇ m) was provided as a decorative layer 30 on the surface of the optical film 12 on the touch sensor 13 side by screen printing.
  • As the black ink INQ-HF979 manufactured by Teikoku Printing Co., Ltd. was used.
  • Adhesives (a1) to (a3) for producing the adhesive members 21 to 23 were prepared by the following procedure.
  • Acrylic adhesive 1 Acrylic adhesive composition obtained by the following procedure (preparation of acrylic polymer solution) A four-necked flask equipped with a stirring blade, a thermometer, a nitrogen gas introduction tube, and a cooler was charged with a monomer mixture containing 99 parts by mass of butyl acrylate and 1 part by mass of 4-hydroxybutyl acrylate. To 100 parts by mass of this monomer mixture, 2,2'-azobisisobutyronitrile was added as a polymerization initiator, and 0.1 part by mass was added together with ethyl acetate. Nitrogen gas was introduced while gently stirring the obtained mixture to carry out nitrogen substitution.
  • acrylic adhesive 1 0.1 part by mass of isocyanate-based cross-linking agent (trade name: Takenate D110N, trimethylolpropane xylylene diisocyanate, manufactured by Mitsui Chemicals, Inc.), peroxide with respect to 100 parts by mass of the polymer component of the solution of acrylic polymer A1. 0.3 parts by mass of a cross-linking agent (benzoyl peroxide (trade name: Niper BMT, manufactured by Nippon Yushi Co., Ltd.)) and a silane coupling agent (trade name: KBM403, manufactured by Shin-Etsu Chemical Industry Co., Ltd.) 0.08
  • the acrylic pressure-sensitive adhesive 1 was prepared by mixing with parts by mass.
  • Acrylic adhesive 2 Acrylic adhesive composition obtained by the following procedure (preparation of acrylic polymer solution) A four-necked flask equipped with a stirring blade, a thermometer, a nitrogen gas introduction tube, and a cooler contains 94.9 parts by mass of butyl acrylate, 5 parts by mass of acrylic acid, and 0.1 parts by mass of 2-hydroxyethyl acrylate. A mixture of monomers was charged. To 100 parts by mass of the solid content of this monomer mixture, 0.1 parts by mass of 2,2'-azobisisobutyronitrile as a polymerization initiator was added together with ethyl acetate. Nitrogen gas was introduced while gently stirring the obtained mixture to carry out nitrogen substitution.
  • acrylic adhesive 2 With respect to 100 parts by mass of the polymer component of the acrylic polymer A2 solution, 0.6 parts by mass of an isocyanate-based cross-linking agent (trade name: Coronate L, trimethylolpropane tolylene diisocyanate, manufactured by Nippon Polyurethane Industry Co., Ltd.) and silane coupling An acrylic pressure-sensitive adhesive 2 was prepared by mixing 0.08 parts by mass of an agent (trade name: KBM403, manufactured by Shin-Etsu Chemical Industry Co., Ltd.).
  • an agent trade name: KBM403, manufactured by Shin-Etsu Chemical Industry Co., Ltd.
  • Acrylic adhesive 3 Acrylic adhesive composition obtained by the following procedure (preparation of acrylic oligomer) 60 parts by mass of dicyclopentanyl methacrylate and 40 parts by mass of methyl methacrylate as a monomer component, 3.5 parts by mass of ⁇ -thioglycerol as a chain transfer agent, and 100 parts by mass of toluene as a polymerization solvent are mixed under a nitrogen atmosphere. The mixture was stirred at 70 ° C. for 1 hour. Next, 0.2 parts by mass of 2,2'-azobisisobutyronitrile was added as a thermal polymerization initiator, and the mixture was reacted at 70 ° C. for 2 hours, then heated to 80 ° C. and reacted for 2 hours. ..
  • reaction solution was heated to 130 ° C., and toluene, the chain transfer agent and the unreacted monomer were dried and removed to obtain a solid acrylic oligomer.
  • the weight average molecular weight of the acrylic oligomer was 5100, and the glass transition temperature (Tg) was 130 ° C.
  • prepolymer composition 43 parts by mass of lauryl acrylate, 44 parts by mass of 2-ethylhexyl acrylate, 6 parts by mass of 4-hydroxybutyl acrylate, and 7 parts by mass of N-vinyl-2-pyrrolidone, and BASF's "Irgacure 184" as a photopolymerization initiator.
  • a prepolymer composition (polymerization rate: about 10%) was obtained by mixing 015 parts by mass and irradiating with ultraviolet rays to carry out polymerization.
  • Table 1 shows the results of Examples 1 to 4 and Comparative Examples 1 to 6.
  • Examples 1 to 4 are E1 to E4, and Comparative Examples 1 to 6 are R1 to R6.
  • a pencil hardness as high as 4H can be obtained on the surface on the hard coat layer side (R6).
  • the pencil hardness on the surface on the window member side (specifically, the surface on the hard coat layer side) may be significantly reduced to B (R2 and R3).
  • the thickness of the first adhesive member is 10 ⁇ m or less, a decrease in pencil hardness can be suppressed on the surface on the window member side, and high pencil hardness can be ensured (E1 to E4, R4 and R5).
  • the thickness of the first adhesive member is 10 ⁇ m or less, when all the thicknesses of the adhesive members other than the first adhesive member are less than 18 ⁇ m, peeling occurs between the laminated members in a high temperature environment (60 ° C.), resulting in high adhesion. Sex cannot be ensured (R4 and R5).
  • the thickness of the first adhesive member is 10 ⁇ m or less and the thickness of at least one layer other than the first adhesive member is 18 ⁇ m or more, both high pencil hardness and adhesiveness in a high temperature environment can be achieved. In the bending test at 25 ° C., peeling did not occur in any of Examples 1 to 4 and Comparative Examples 1 to 5, and high adhesiveness was ensured.
  • Examples 5 to 6 and Comparative Examples 7 to 10 An evaluation sample of the flexible image display device 201 as shown in FIG. 3 was prepared according to Examples 1 to 4. Instead of the dummy of the touch sensor 13 and the panel member 14 of the first embodiment, a transparent polyimide film (manufactured by KOLON, product name "A_50_O", thickness 50 ⁇ m) is used as a dummy of the panel member 15A with the first touch sensor. There was.
  • a pressure-sensitive adhesive (the pressure-sensitive adhesive shown in Table 2) prepared in the same manner as in Examples 1 to 4 was used.
  • the thickness of the pressure-sensitive adhesive layer was adjusted by the amount of the pressure-sensitive adhesive applied so that the thickness of each pressure-sensitive adhesive member in the sample had the values shown in Table 2.
  • Examples 5 to 6 and Comparative Examples 7 to 10 are shown in Table 2.
  • Examples 5 to 6 are E5 to E6, and Comparative Examples 7 to 10 are R7 to R10.
  • Table 2 also shows the results of Comparative Example 6 (R6).
  • the pencil hardness on the surface on the hard coat layer side is as high as 4H (R6).
  • the pencil hardness may be significantly reduced to B (R8).
  • the thickness of the first adhesive member is 10 ⁇ m or less, a decrease in pencil hardness can be suppressed on the surface on the window member side, and high pencil hardness can be ensured (E5 to E6).
  • the thickness of the first adhesive member is 10 ⁇ m or less, when all the thicknesses of the adhesive members other than the first adhesive member are less than 18 ⁇ m, peeling occurs between the laminated members in a high temperature environment (60 ° C.), resulting in high adhesion. Sex cannot be ensured (R9 and R10).
  • the thickness of the first adhesive member is 10 ⁇ m or less and the thickness of at least one layer other than the first adhesive member is 18 ⁇ m or more, both high pencil hardness and adhesiveness in a high temperature environment can be achieved (E5 and). E6). In Examples 5 to 6 and Comparative Examples 7 to 10, peeling of the bent portion was not confirmed in the bending test, and good adhesiveness could be ensured.

Landscapes

  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • General Engineering & Computer Science (AREA)
  • Nonlinear Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mathematical Physics (AREA)
  • Human Computer Interaction (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Laminated Bodies (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)
  • Liquid Crystal (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Polarising Elements (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Electroluminescent Light Sources (AREA)
  • Transforming Electric Information Into Light Information (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
PCT/JP2020/037605 2019-10-09 2020-10-02 フレキシブル画像表示装置およびそれに用いる光学積層体 Ceased WO2021070756A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN202080070484.0A CN114514570B (zh) 2019-10-09 2020-10-02 柔性图像显示装置以及用于其的光学层叠体
KR1020227009749A KR102458092B1 (ko) 2019-10-09 2020-10-02 플렉서블 화상 표시 장치 및 이에 이용하는 광학 적층체

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2019186257 2019-10-09
JP2019-186257 2019-10-09
JP2020159580A JP6934996B2 (ja) 2019-10-09 2020-09-24 フレキシブル画像表示装置およびそれに用いる光学積層体
JP2020-159580 2020-09-24

Publications (1)

Publication Number Publication Date
WO2021070756A1 true WO2021070756A1 (ja) 2021-04-15

Family

ID=75380199

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2020/037605 Ceased WO2021070756A1 (ja) 2019-10-09 2020-10-02 フレキシブル画像表示装置およびそれに用いる光学積層体

Country Status (5)

Country Link
JP (1) JP6934996B2 (https=)
KR (1) KR102458092B1 (https=)
CN (1) CN114514570B (https=)
TW (1) TWI772916B (https=)
WO (1) WO2021070756A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7388389B2 (ja) 2021-03-31 2023-11-29 トヨタ自動車株式会社 蓄電装置の製造方法
JP7348928B2 (ja) * 2021-06-02 2023-09-21 住友化学株式会社 積層体
JPWO2024225385A1 (https=) 2023-04-27 2024-10-31

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017014287A1 (ja) * 2015-07-22 2017-01-26 住友化学株式会社 樹脂フィルム、積層体、光学部材、ガスバリア材及びタッチセンサー基材
JP2017165941A (ja) * 2015-12-25 2017-09-21 日東電工株式会社 有機ｅｌ表示装置用粘着剤組成物、有機ｅｌ表示装置用粘着剤層、有機ｅｌ表示装置用粘着剤層付き偏光フィルム、及び有機ｅｌ表示装置
JP2018027995A (ja) * 2016-08-15 2018-02-22 日東電工株式会社 フレキシブル画像表示装置用粘着剤組成物、フレキシブル画像表示装置用粘着剤層、フレキシブル画像表示装置用積層体、及び、フレキシブル画像表示装置
US20180059300A1 (en) * 2016-08-23 2018-03-01 Dongwoo Fine-Chem Co., Ltd. Polarizing plate and image display device comprising the same
JP2018529987A (ja) * 2015-06-24 2018-10-11 サムスン エレクトロニクス カンパニー リミテッド 表示装置用ハードコートフィルムおよびこれを含む表示装置
JP2018200463A (ja) * 2017-05-09 2018-12-20 日東電工株式会社 光学部材用組成物、光学部材及び画像表示装置
JP2019095506A (ja) * 2017-11-20 2019-06-20 株式会社ジャパンディスプレイ 表示装置及びその製造方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100844164B1 (ko) * 2006-12-05 2008-07-04 (주)매트릭스 칼라 필터층이 형성된 키패드용 이엘 시트 및 그 제조 방법
JP6018397B2 (ja) * 2012-04-09 2016-11-02 共同技研化学株式会社 情報表示面用の両面粘着シート，情報表示面の保護シート，及び前記両面粘着シート及び保護シートの製造方法
JP2013218188A (ja) * 2012-04-11 2013-10-24 Nec Casio Mobile Communications Ltd 表示パネル保護フィルム
KR102494986B1 (ko) 2016-01-11 2023-02-03 삼성디스플레이 주식회사 폴더블 표시장치
KR102318145B1 (ko) * 2017-09-15 2021-10-26 동우 화인켐 주식회사 플렉시블 디스플레이 장치
KR102370422B1 (ko) * 2018-03-05 2022-03-07 삼성디스플레이 주식회사 전자 장치

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018529987A (ja) * 2015-06-24 2018-10-11 サムスン エレクトロニクス カンパニー リミテッド 表示装置用ハードコートフィルムおよびこれを含む表示装置
WO2017014287A1 (ja) * 2015-07-22 2017-01-26 住友化学株式会社 樹脂フィルム、積層体、光学部材、ガスバリア材及びタッチセンサー基材
JP2017165941A (ja) * 2015-12-25 2017-09-21 日東電工株式会社 有機ｅｌ表示装置用粘着剤組成物、有機ｅｌ表示装置用粘着剤層、有機ｅｌ表示装置用粘着剤層付き偏光フィルム、及び有機ｅｌ表示装置
JP2018027995A (ja) * 2016-08-15 2018-02-22 日東電工株式会社 フレキシブル画像表示装置用粘着剤組成物、フレキシブル画像表示装置用粘着剤層、フレキシブル画像表示装置用積層体、及び、フレキシブル画像表示装置
US20180059300A1 (en) * 2016-08-23 2018-03-01 Dongwoo Fine-Chem Co., Ltd. Polarizing plate and image display device comprising the same
JP2018200463A (ja) * 2017-05-09 2018-12-20 日東電工株式会社 光学部材用組成物、光学部材及び画像表示装置
JP2019095506A (ja) * 2017-11-20 2019-06-20 株式会社ジャパンディスプレイ 表示装置及びその製造方法

Also Published As

Publication number Publication date
JP2021060576A (ja) 2021-04-15
CN114514570A (zh) 2022-05-17
JP6934996B2 (ja) 2021-09-15
KR20220044853A (ko) 2022-04-11
KR102458092B1 (ko) 2022-10-25
TWI772916B (zh) 2022-08-01
CN114514570B (zh) 2023-04-04
TW202114860A (zh) 2021-04-16

Similar Documents

Publication Publication Date Title
JP6858912B2 (ja) フレキシブル画像表示装置およびそれに用いる光学積層体
CN115312672B (zh) 挠性图像显示装置用层叠体及挠性图像显示装置
JP6850601B2 (ja) 画像表示装置
TW202325815A (zh) 可撓性圖像顯示裝置用黏著劑組合物、可撓性圖像顯示裝置用黏著劑層、可撓性圖像顯示裝置用積層體及可撓性圖像顯示裝置
JP6970850B2 (ja) 表示装置及び基材積層体
JP6934996B2 (ja) フレキシブル画像表示装置およびそれに用いる光学積層体
WO2021066191A1 (ja) 表示装置及び基材積層体
JP6877525B1 (ja) 加飾付積層体、光学積層体、およびフレキシブル画像表示装置
JP6903830B1 (ja) フレキシブル画像表示装置およびそれに用いる光学積層体
JP6903804B1 (ja) フレキシブル画像表示装置およびそれに用いる光学積層体
WO2021066190A1 (ja) 表示装置及び基材積層体

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 20875529

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 20227009749

Country of ref document: KR

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 20875529

Country of ref document: EP

Kind code of ref document: A1