WO2021002626A1 - 배터리 모듈, 이를 포함하는 배터리 랙 및 전력 저장 장치 - Google Patents
배터리 모듈, 이를 포함하는 배터리 랙 및 전력 저장 장치 Download PDFInfo
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- WO2021002626A1 WO2021002626A1 PCT/KR2020/008193 KR2020008193W WO2021002626A1 WO 2021002626 A1 WO2021002626 A1 WO 2021002626A1 KR 2020008193 W KR2020008193 W KR 2020008193W WO 2021002626 A1 WO2021002626 A1 WO 2021002626A1
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- battery
- flame
- cell assembly
- battery module
- gas
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/233—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions
- H01M50/24—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders characterised by physical properties of casings or racks, e.g. dimensions adapted for protecting batteries from their environment, e.g. from corrosion
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/383—Flame arresting or ignition-preventing means
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- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C3/00—Fire prevention, containment or extinguishing specially adapted for particular objects or places
- A62C3/16—Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/61—Types of temperature control
- H01M10/613—Cooling or keeping cold
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/62—Heating or cooling; Temperature control specially adapted for specific applications
- H01M10/627—Stationary installations, e.g. power plant buffering or backup power supplies
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/655—Solid structures for heat exchange or heat conduction
- H01M10/6554—Rods or plates
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/655—Solid structures for heat exchange or heat conduction
- H01M10/6554—Rods or plates
- H01M10/6555—Rods or plates arranged between the cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/658—Means for temperature control structurally associated with the cells by thermal insulation or shielding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/659—Means for temperature control structurally associated with the cells by heat storage or buffering, e.g. heat capacity or liquid-solid phase changes or transition
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/204—Racks, modules or packs for multiple batteries or multiple cells
- H01M50/207—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape
- H01M50/211—Racks, modules or packs for multiple batteries or multiple cells characterised by their shape adapted for pouch cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/20—Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
- H01M50/258—Modular batteries; Casings provided with means for assembling
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/30—Arrangements for facilitating escape of gases
- H01M50/35—Gas exhaust passages comprising elongated, tortuous or labyrinth-shaped exhaust passages
- H01M50/367—Internal gas exhaust passages forming part of the battery cover or case; Double cover vent systems
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/502—Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/502—Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing
- H01M50/507—Interconnectors for connecting terminals of adjacent batteries; Interconnectors for connecting cells outside a battery casing comprising an arrangement of two or more busbars within a container structure, e.g. busbar modules
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a battery module having a flame retardant plate, a battery rack including the same, and a power storage device, and more particularly, to a battery module reducing the risk of secondary ignition or explosion.
- a lithium secondary battery mainly use lithium-based oxides and carbon materials as a positive electrode active material and a negative electrode active material, respectively.
- a lithium secondary battery includes an electrode assembly in which a positive electrode plate and a negative electrode plate to which the positive electrode active material and the negative electrode active material are applied, respectively, are disposed with a separator therebetween, and a case material for sealing and storing the electrode assembly together with an electrolyte solution, that is, a battery pouch case material.
- secondary batteries are widely used not only in small devices such as portable electronic devices, but also in mid- to large-sized devices such as automobiles and power storage devices.
- a large number of secondary batteries are electrically connected to increase capacity and output.
- pouch-type secondary batteries are widely used in such medium-sized devices due to the advantage of easy stacking.
- such a battery rack generally includes an outer housing made of a metal material to protect or store a plurality of secondary batteries from an external impact. Meanwhile, the demand for high-capacity battery racks is increasing recently.
- the battery rack of the prior art is provided with a plurality of battery modules, and when the secondary cells of each battery module ignite or explode, there is a case where heat or flame is transferred to the adjacent secondary cells, causing a secondary explosion, etc.
- efforts to prevent secondary ignition or explosion are increasing.
- the present invention has been invented to solve the above problems, and an object of the present invention is to provide a battery module that reduces the risk of secondary ignition or explosion.
- the battery module according to the present invention for achieving the above object,
- At least two or more cell assemblies each having a plurality of secondary batteries electrically connected to each other and stacked in a front-rear direction;
- a module housing having an inner space formed to accommodate the cell assembly therein, and having a gas passage through which gas generated from the cell assembly flows on one or both sides of the cell assembly in a left-right direction;
- a flame-retardant plate having a plate shape and having a body portion interposed between the two or more cell assemblies, and a flame blocking portion protruding from one end or both ends of the body portion in the left-right direction and positioned in a portion of the gas passage.
- the battery module includes at least one bus bar in contact with an electrode terminal provided in the plurality of secondary batteries, and the at least one bus bar mounted thereon so as to electrically interconnect the plurality of secondary batteries. It may further include a bus bar assembly provided with at least two bus bar frames provided on each of both sides in the left and right direction.
- the gas passage may be a space formed between an outer surface of the busbar frame and an inner surface of the module housing.
- a plurality of gas discharge holes perforated in the front-rear direction may be formed in the flame blocking part so that the gas generated from the cell assembly flows.
- the module housing may be provided with a gas outlet to communicate with an end of the gas passage, and the gas outlet hole may be configured such that the hole of the hole is continuously narrowed in a direction in which the gas outlet is located.
- the module housing may be provided with a gas outlet to communicate with the end of the gas passage, and the flame blocking portion has a guide structure for guiding the gas generated from the cell assembly to move in the direction in which the gas discharge hole is located. It can be provided.
- an insertion protrusion having a slit into which at least a portion of the flame blocking portion is inserted may be provided on an inner surface of the module housing.
- the flame-retardant plate includes at least one of a flame retardant layer that does not burn easily, a heat insulating layer configured to prevent heat transfer, an expansion layer whose volume expands at a predetermined temperature, and a heat absorbing layer that absorbs heat at a predetermined temperature. It can have a multi-layered structure.
- the multilayer structure may be a structure in which the expansion layer is interposed between two flame retardant layers, or a structure in which the heat insulating layer is interposed between two flame retardant layers.
- the cell assembly may include at least one of a heat absorbing pad configured to absorb heat through an endothermic reaction at a predetermined temperature and an insulating pad configured to prevent heat transfer between the plurality of secondary batteries.
- the battery rack according to the present invention for achieving the above object includes a rack case for accommodating the plurality of battery modules and the plurality of battery modules in a vertically stacked form.
- it may include a flameproof cover interposed between the plurality of battery modules and configured to cover the upper or lower portion of the battery module.
- At least a portion of the outer periphery of the flame-retardant cover may protrude to be exposed to the outside from between the plurality of battery modules, and the outer periphery of the flame-retardant cover may be bent upward.
- the flameproof cover may have an uneven structure bent at predetermined intervals.
- the power storage device according to the present invention for achieving the above object includes a battery rack.
- the battery module of the present invention includes a body portion interposed between two or more cell assemblies and a flame-retardant plate having a flame blocking portion protruding from the body portion in a left and right direction and positioned in a portion of the gas passage.
- the battery module of the present invention is provided with a plurality of gas discharge holes provided in the flame blocking portion of the flame-retardant plate, the gas generated from the cell assembly through the plurality of gas discharge holes. Can be allowed to go through.
- the flame blocking unit can stably prevent the flame generated from the cell assembly from propagating around.
- the flame retardant plate includes a flame retardant layer that does not burn easily, a heat insulating layer configured to prevent heat transfer, an expansion layer that expands in volume at a predetermined temperature, and absorbs heat at a predetermined temperature.
- the battery rack protrudes so that at least a portion of the outer peripheral portion of the flame retardant cover is exposed to the outside from between a plurality of battery modules, and the outer peripheral portion protruding and extended of the flame retardant cover is bent upward.
- FIG. 1 is a perspective view schematically showing a battery module according to an embodiment of the present invention.
- FIG. 2 is an exploded perspective view schematically showing a state in which components of a battery module according to an embodiment of the present invention are separated.
- FIG 3 is a perspective view schematically showing some components of a battery module according to an embodiment of the present invention.
- FIG. 4 is an exploded perspective view schematically showing a separated state of a flame retardant plate, which is a part of a battery module according to an embodiment of the present invention.
- FIG. 5 is a partial cross-sectional view schematically showing a portion of the battery module cut along the line A-A' of FIG. 1.
- FIG. 6 is a partial cross-sectional view schematically showing a portion of the flame retardant plate cut along the line B-B' of FIG. 4.
- FIG. 7 is a partial cross-sectional view schematically showing a portion of the flame retardant plate cut along the line C-C' of FIG. 4.
- FIG. 8 is a plan view schematically showing some configurations of a battery module according to another embodiment of the present invention.
- FIG. 9 is a perspective view schematically showing some configurations of a battery rack according to an embodiment of the present invention.
- FIG. 10 is a perspective view schematically showing some configurations of a battery rack according to another embodiment of the present invention.
- FIG. 1 is a perspective view schematically showing a battery module 200 according to an embodiment of the present invention.
- FIG. 2 is an exploded perspective view schematically showing the configurations of the battery module 200 according to an embodiment of the present invention separated.
- the battery module 200 may include at least two cell assemblies 100, a module housing 210, and a flameproof plate 230. .
- the at least two or more cell assemblies 100 may include a connection bus bar 272 so that each is electrically connected to each other.
- the connection bus bar 272 may be an alloy containing a metal such as copper, nickel, or aluminum having excellent electrical conductivity.
- Each of the at least two or more cell assemblies 100 may include a plurality of secondary batteries 110 stacked in a front-rear direction.
- the secondary battery 110 may be a pouch-type secondary battery 110.
- each of the two cell assemblies 100 may be configured in a form in which 21 pouch-type secondary batteries 110 are stacked side by side in the front-rear direction (y direction).
- the pouch-type secondary battery 110 may include an electrode assembly (not shown), an electrolyte (not shown), and a pouch 116.
- each of the secondary batteries 110 When viewed in the F direction (shown in FIG. 1), each of the secondary batteries 110 is roughly ground so that the two wide surfaces are located in the front and rear directions, and the sealing parts are located in the up, down, left and right directions. It can be arranged in a form that stands perpendicular to (z direction). In other words, each secondary battery 110 may be configured to be erected in the vertical direction. In the meantime, in the present specification, unless otherwise specified, it is based on the case of looking in the F direction with respect to the up, down, front, back, left, and right directions.
- the pouch may be configured as a pouch in which a concave-shaped receiving portion is formed.
- an electrode assembly and an electrolyte may be accommodated in the receiving portion.
- each pouch includes an outer insulating layer, a metal layer, and an inner adhesive layer, and the inner adhesive layer adheres to each other at an edge portion of the pouch, thereby forming a sealing portion.
- a terrace portion may be formed at each end of the secondary battery 110 in the left and right directions (x direction) on which the positive lead 111 and the negative lead 112 are formed.
- the electrode assembly is an assembly of an electrode plate and a separator coated with an electrode active material, and may be configured in a form in which at least one positive electrode plate and at least one negative electrode plate are disposed with the separator interposed therebetween.
- a positive electrode tab may be provided on the positive electrode plate of the electrode assembly, and one or more positive electrode tabs may be connected to the positive electrode lead 111.
- the positive lead 111 has one end connected to the positive electrode tab and the other end exposed to the outside of the pouch 116, and the exposed part is an electrode terminal of the secondary battery 110, for example, a secondary It can function as a positive terminal of the battery 110.
- a negative electrode tab may be provided on the negative electrode plate of the electrode assembly, and one or more negative electrode tabs may be connected to the negative electrode lead 112.
- the negative lead 112 has one end connected to the negative electrode tab and the other end exposed to the outside of the pouch, and the exposed part is an electrode terminal of the secondary battery 110, for example, the secondary battery 110 Can function as the negative terminal of.
- the positive lead 111 and the negative lead 112 are left and right in opposite directions (x direction) with respect to the center of the secondary battery 110. Can be formed at the end of. That is, the positive lead 111 may be provided at one end (left end) based on the center of the secondary battery 110. In addition, the negative lead 112 may be provided at the other end (right end) of the secondary battery 110 based on the center of the secondary battery 110.
- each secondary battery 110 of the cell assembly 100 may be configured such that the positive lead 111 and the negative lead 112 protrude in the left and right directions.
- directions such as before, after, left, right, up, and down may vary depending on the position of the observer or the shape of the object.
- directions such as front, rear, left, right, up, and down are indicated separately based on when viewed in the F direction.
- the positive lead 111 and the negative lead 112 may be formed in a plate shape.
- the positive electrode lead 111 and the negative electrode lead 112 may protrude in a horizontal direction (X direction) with a wide surface erected toward the front-rear direction.
- the horizontal direction may be said to mean a direction parallel to the ground when the secondary battery 110 is placed on the ground, and may also be referred to as at least one direction on a plane perpendicular to the vertical direction.
- the battery module 200 according to the present invention is not limited to the pouch-type secondary battery 110 described above, and various secondary batteries 110 known at the time of filing of the present invention may be employed.
- the at least two or more cell assemblies 100 may be arranged in a front-rear direction.
- two cell assemblies 100 are arranged in the front-rear direction.
- the two cell assemblies 100 may have a predetermined distance apart.
- the module housing 210 may have an inner space to accommodate the cell assembly 100 therein.
- the module housing 210 may include an upper cover 220, a base plate 240, a front cover 250, and a rear cover 260.
- the base plate 240 may have an area larger than a size of a bottom surface of the at least two cell assemblies 100 so as to mount the at least two cell assemblies 100 on the top.
- the base plate 240 may have a plate shape extending in a horizontal direction.
- the upper cover 220 may include a top portion 224 and a side portion 226.
- the top part 224 may have a plate shape extending in a horizontal direction to cover an upper portion of the cell assembly 100.
- the side portion 226 may have a plate shape extending downward from both ends of the top portion 224 in the left-right direction to cover both sides of the cell assembly 100 in the left-right direction.
- the side portion 226 may be coupled to a portion of the base plate 240.
- the upper cover 220 may include a top portion 224 having a plate shape that extends in the front and rear directions.
- the upper cover 220 may be provided with two side portions 226 extending downward from each of both ends of the top portion 224 in the left and right direction.
- the lower ends of each of the two side parts 226 may be configured to be coupled to both ends of the base plate 240 in the left and right directions.
- the coupling method may be a male and female coupling method or a welding coupling method.
- the side part 226 may be provided with a beading part B1 protruding in an inward direction on which the secondary battery 110 is located.
- a beading part B1 protruding in an inward direction on which the secondary battery 110 is located.
- seven beading portions B1 protruding in an inward direction may be formed on one side portion 226.
- the front cover 250 may be configured to cover the front of the plurality of secondary batteries 110.
- the front cover 250 may have a plate shape having a size larger than that of the front surfaces of the plurality of secondary batteries 110.
- the plate shape may be erected in a vertical direction.
- a portion of the outer peripheral portion of the front cover 250 may be coupled to the base plate 240.
- a lower portion of the outer peripheral portion of the front cover 250 may be coupled to a front end portion of the base plate 240.
- the upper portion of the outer peripheral portion of the front cover 250 may be coupled to the front end portion of the upper cover 220.
- bolt coupling may be applied as the coupling method.
- the rear cover 260 may be configured to cover the rear of the cell assembly 100.
- the rear cover 260 may have a plate shape having a size larger than that of the rear surfaces of the plurality of secondary batteries 110.
- a portion of the outer peripheral portion of the rear cover 260 may be coupled to the base plate 240.
- a lower portion of the outer peripheral portion of the rear cover 260 may be coupled to a front end portion of the base plate 240.
- the upper portion of the outer circumferential portion of the rear cover 260 may be coupled to the rear end of the upper cover 220.
- bolt coupling may be applied as the coupling method.
- the module housing 210 has a structure that can stably protect the plurality of secondary batteries 110 from external shocks, It can increase safety.
- FIG 3 is a perspective view schematically showing some components of a battery module according to an embodiment of the present invention.
- the module housing 210 may be provided with a gas passage 211 so that gas generated from the cell assembly 100 flows.
- the gas passage 211 may be a space elongated in the front-rear direction so as to communicate with the outside.
- the gas passage 211 may be provided on one or both sides of the cell assembly 100 in the left and right direction. More specifically, the gas passage 211 may be formed in a portion of a space between one surface of the cell assembly 100 in the left-right direction and an inner surface of the module housing 210.
- two gas passages 211 are provided between the two side portions 226 of the upper cover 220 and both sides of the cell assembly 100 in the left-right direction. It can be provided.
- the flame retardant plate 230 may be provided with a flame retardant material that does not burn easily.
- the flame-retardant material may be mica, vinyl chloride resin containing chlorine, paraffin chloride, decabromodiphenyl oxide, antimony trioxide, or the like.
- the flame retardant plate 230 may include a body portion 231 and a flame blocking portion 236.
- the main body 231 may have a plate shape that is erected in a vertical direction. That is, the main body 231 may have a side surface in a front-rear direction wider than a side surface in an up-down, left-right direction.
- the main body 231 may be configured to be interposed between the two or more cell assemblies 100.
- the flame blocking part 236 may have a shape extending in a left-right direction from one end or both ends of the body part 231 in the left-right direction.
- the flame blocking portion 236 may be configured to protrude further in the left-right direction than the cell assembly 100 from both ends of the body portion 231 in the left-right direction.
- the flame blocking part 236 may have a shape protruding and extending so as to be positioned in a part of the gas passage 211.
- the flame-retardant plate 230 may be positioned such that the main body 231 is interposed between the two cell assemblies 100.
- the flame blocking portion 236 may protrude from both ends of the body portion 231 in the left-right direction and may be positioned in a portion of the gas passage 211.
- the present invention protrudes in the left and right direction (X direction) from the main body 231 and the main body 231 interposed between the two or more cell assemblies 100 to provide the gas passage
- a flame blocking part 236 located in a part of 211, even if a fire occurs in any one of at least two or more cell assemblies 100, it prevents the fire from spreading to the adjacent cell assembly 100 can do.
- the battery module 200 may further include a bus bar assembly 270.
- the bus bar assembly 270 is configured to mount at least one bus bar 272 configured to electrically interconnect the plurality of secondary batteries 110 and the at least one bus bar 272 outside.
- At least two or more busbar frames 276 may be provided.
- the at least two busbar frames 276 may be provided on each side of the cell assembly 100 in the left and right directions.
- the bus bar 272 may include a conductive metal, for example, copper, aluminum, nickel, or the like.
- the busbar frame 276 may include an electrically insulating material.
- the busbar frame 276 may be made of a plastic material. More specifically, the plastic material may be polyvinyl chloride.
- the battery module 200 may include four busbar assemblies 270.
- Each of the four busbar assemblies 270 may include four busbars 272 and a busbar frame 276 having the four busbars 272 mounted thereon.
- the gas passage 211 may be a space formed by an outer surface of the busbar frame 276 and an inner surface of the module housing 210.
- the gas passage 211 has an outer surface in the left and right direction of the bus bar frame 276 and a top portion 224 and a side portion 226 of the upper cover 220 It may be a space formed by the inner surface of.
- a plurality of gas discharge holes 236h may be formed in the flame blocking part 236 so that the gas generated from the cell assembly 100 flows.
- the gas discharge hole 236h may be an opening drilled in the front-rear direction.
- gas passages 211 may be provided on both sides of the two cell assemblies 100 in the front-rear direction.
- a plurality of gas discharge holes 236h perforated in the front and rear directions so that the gas generated from the cell assembly 100 flows may be formed in the flame blocking portion 236 of the flame retardant plate 230.
- the flame-retardant plate 230 is provided with a plurality of gas discharge holes 236h provided in the flame blocking unit 236, the plurality of gas generated from the cell assembly 100 It can be allowed to move through the gas discharge hole (236h).
- the flame blocking unit 236 may stably prevent the flame generated from the cell assembly 100 from spreading to the surroundings.
- the module housing 210 may be provided with a gas outlet 264h.
- the gas outlet 264h may be provided in the rear cover 260 of the module housing 210.
- two gas outlets 264h may be provided on both sides of the rear cover 260 in the left-right direction.
- the gas outlet 264h may be configured to communicate with an end of the gas passage 211. That is, the gas moving through the gas passage 211 may be discharged to the outside through the gas outlet 264h.
- the module housing 210 of the present invention includes a gas outlet 264h for discharging the gas to the outside, so that the gas generated from the cell assembly 100 is passed through the gas passage 211 ) And through the gas outlet 264h communicating with the end of the gas passage 211, it can be effectively discharged to the outside.
- FIG. 5 is a partial cross-sectional view schematically showing a portion of the battery module cut along the line A-A' of FIG. 1.
- an insertion protrusion 226p configured to insert a portion of the flame blocking portion 236 may be provided on the inner surface of the module housing 210.
- the insertion protrusion 226p may have a slit (not shown) through which a portion of the flame blocking portion 236 is inserted.
- the upper end of the flame blocking portion 236 of the flame retardant plate 230 may be inserted into and fixed to the insertion protrusion 226p provided on the inner surface of the module housing 210. have.
- the insertion protrusion 226p may have a shape in which two square plates are overlapped and a portion of the insertion protrusion 226p is combined.
- the slit may be an empty gap between the two plates.
- an insertion protrusion 226p having a slit into which a portion of the flame blocking unit 236 is inserted is provided on the inner surface of the module housing 210, so that the flame blocking unit 236 ) Can be guided so that the module housing 210 can be mounted in the correct position, and the gas passage can be divided into a larger area. Accordingly, the manufacturing process of the battery module 200 can be improved and the flame can be prevented from affecting the adjacent cell assembly 100.
- the flame retardant plate 230 may have a multilayer structure.
- the multilayer structure may include at least one of a flame retardant layer, a heat insulating layer, an expansion layer, and a heat absorbing layer.
- the flame retardant layer is a layer that does not burn easily, and may include, for example, a flame retardant material.
- the flame-retardant material may be mica, vinyl chloride resin containing chlorine, paraffin chloride, decabromodiphenyl oxide, antimony trioxide, or the like.
- the heat insulating layer may be configured to prevent heat transfer.
- the insulating layer may be provided with a glass fiber or foamed plastic material. That is, the heat insulating layer may prevent heat from the ignited cell assembly 100 from being transferred to the adjacent cell assembly 100. Accordingly, it is possible to prevent the occurrence of a secondary fire.
- the expansion layer may include a material in which volume expansion occurs around 200 degrees Celsius.
- the volume expandable material is sodium hydrogen carbonate, potassium hydrogen carbonate, lithium carbonate, ammonium carbonate, benzenesulfonyl hydrazide, semicarbazide, carbazide, azobisformamide, azobisisobutyronitrile, and diazo It may be one or more selected from the group consisting of aminobenzene. That is, the expansion layer may be configured to expand so that there is no gap between two or more cell assemblies 100 when the temperature of the cell assembly 100 rises around 200 degrees Celsius. Accordingly, it is possible to block a path through which flames may propagate between the plurality of cell assemblies 100 by the expansion layer, or to prevent the high-temperature secondary battery 110 from contacting air, which is an ignition condition.
- the heat absorbing layer may include a heat absorbing material to absorb heat at a predetermined temperature.
- the endothermic material may be a material (Phase Change Material: PCM) having high latent heat upon phase change at a predetermined temperature.
- the material with high latent heat is paraffin, polyethylene glycol, inorganic hydrate (eg, Na 2 HPO 4 ⁇ 12H 2 O, Na 2 SO 4 ⁇ 10H 2 O, Zn(NO 3 ) 2 ⁇ 6H 2 O), etc.
- the heat absorbing material may absorb heat and prevent the cell assembly 100 from being ignited when the temperature of the cell assembly 100 rises above 100 degrees Celsius due to an abnormal operation.
- the flame retardant plate 230 includes a flame retardant layer that does not burn easily, a heat insulating layer configured to prevent heat transfer, an expansion layer whose volume expands at a predetermined temperature, and heat at a predetermined temperature.
- the multilayer structure may be a structure in which an expansion layer 225 is interposed between two flame retardant layers 223 and 227. That is, in the multilayer structure of this structure, when the cell assembly 100 is in an ignited state, flame retardant layers located on both sides of the expansion layer 225 as the expansion layer 225 of the flameproof plate 230 swells. 223 and 227 may be configured to press the ignited cell assembly 100. Accordingly, the cell assembly 100 may be compressed so that the fire of the cell assembly 100 ignited by the flame retardant plate 230 does not increase.
- the multilayered structure of the flame retardant plate 230 may be a structure in which an insulating layer is interposed instead of the expansion layer 225 between the two flame retardant layers 223 and 227. That is, the flame-retardant plate 230 having a structure in which an insulating layer is interposed between the two flame-retardant layers has an insulating layer (foaming plastic) that is relatively easy to burn or deform in an inner layer, and a flame-retardant layer that does not burn easily is an outer layer.
- insulating layer foaming plastic
- FIG. 6 is a partial cross-sectional view schematically showing a portion of the flame retardant plate cut along the line B-B' of FIG. 4.
- the gas discharge hole 236h guides the gas generated from the cell assembly 100 to move in the direction F1 in which the gas discharge port 264h is located. It can have a structure.
- the gas discharge hole 236h may be configured such that the hole of the hole is continuously narrowed in the direction F1 in which the gas discharge port 264h is located.
- the gas discharge hole 236h may be configured such that the hole of the hole is continuously narrowed in the direction in which the gas discharge port 264h is formed.
- the flame retardant plate 230 can effectively induce the gas to move rapidly in the direction F1 in which the gas outlet 264h is located.
- the gas discharge hole 236h is configured such that the hole of the hole continuously narrows in the direction in which the gas discharge port 264h is located, so that some secondary batteries 110 of the cell assembly 100 It is possible to prevent fire from spreading to the adjacent cell assembly 100 by burning).
- FIG. 7 is a partial cross-sectional view schematically showing a portion of the flame retardant plate cut along the line C-C' of FIG. 4.
- the gas generated from the cell assembly 100 is supplied to the flame blocking part 236.
- a guide structure 236g for guiding the movement in the direction F1 in which the 264h is located may be provided.
- the guide structure 236g may protrude from the surface of the flame blocking portion 236 in a front-rear direction (Y direction in FIG. 2) and a left-right direction (Z direction in FIG. 2 ).
- a plurality of gas discharge holes 236h1 are provided in the flame blocking part 236, and a guide structure (236g) is provided at the periphery of each of the plurality of gas discharge holes 236h1. May be provided.
- the guide structure 236g may have a shape extending in a diagonal direction. Accordingly, when the gas generated from the cell assembly 100 moves from the cell assembly 100 in the left or right direction (F2), the guide structure 236g is relatively close to the gas outlet 264h. It is possible to induce gas to move to the gas discharge hole 236h1 provided in the flame blocking part 236.
- the flame blocking unit 236 moves the gas generated from the cell assembly 100 in the direction in which the gas discharge hole 236h1 is located.
- the guiding guide structure 236g may prevent gas from flowing in a direction opposite to the direction in which the gas outlet 264h is located.
- FIG. 8 is a plan view schematically showing some configurations of a battery module according to another embodiment of the present invention.
- the cell assembly 100 is configured to prevent heat transfer and a heat absorbing pad 130 that absorbs heat through an endothermic reaction at a predetermined temperature between the plurality of secondary batteries 110.
- the heat absorbing pad 130 may include a heat absorbing material.
- the endothermic material may be a material (Phase Change Material: PCM) having high latent heat upon phase change at a predetermined temperature.
- the material with high latent heat is paraffin, polyethylene glycol, inorganic hydrate (eg, Na 2 HPO 4 ⁇ 12H 2 O, Na 2 SO 4 ⁇ 10H 2 O, Zn(NO 3 ) 2 ⁇ 6H 2 O), etc. Although can be mentioned, it is not limited only to these.
- the heat absorbing pad 130 effectively reduces the temperature of the secondary battery 110 ignited by a material that undergoes a phase change when the secondary battery 110 is ignited in a state interposed between the plurality of secondary batteries 110. Since it can be lowered, it is possible to prevent fire or fire from propagating to the adjacent secondary battery 110.
- the insulating pad 140 may be formed of, for example, a glass fiber or foamed plastic material. That is, the heat insulating pad 140 may prevent heat from the ignited secondary battery 110 from being transferred to the adjacent secondary battery 110. Accordingly, it is possible to prevent the fire from spreading between the plurality of secondary batteries 110.
- FIG. 9 is a perspective view schematically showing some configurations of a battery rack according to an embodiment of the present invention.
- the battery rack 300 may include a plurality of battery modules 200.
- the battery rack 300 may include a rack case 310 accommodating the plurality of battery modules 200 in a vertically stacked form. Inside the rack case 310, the lower surface of the battery module 200 may be mounted in a form parallel to a horizontal surface.
- the rack case 310 is configured to have at least one side openable, and the battery module 200 may be introduced into the inner space through the open side.
- the rack case 310 may be configured such that such an open side can be closed.
- the rack case 310 has a rear side, a left side, a right side, an upper side and/or a lower side in a plate shape, so that the internal battery module 200 is external It can be configured so that it is not easily exposed.
- It may include a flame-retardant cover 320 interposed between the plurality of battery modules 200 and configured to cover an upper portion or a lower portion of the battery module 200.
- the flame retardant cover 320 may be provided with a flame retardant material that does not burn easily.
- the flame-retardant material may be mica, vinyl chloride resin containing chlorine, paraffin chloride, decabromodiphenyl oxide, antimony trioxide, or the like.
- At least a portion of the outer peripheral portion 320w of the flameproof cover 320 may protrude and extend so as to be exposed to the outside from between the plurality of battery modules 200.
- a plurality of flameproof covers 320 may be interposed between a plurality of battery modules.
- Both outer peripheral portions 320w in the left and right directions of the outer peripheral portion 320w of the flameproof cover 320 may protrude and extend to be exposed to the outside from between the plurality of battery modules 200.
- the outer circumferential portion 320w may be entirely bent upward.
- the structure of the outer peripheral portion (320w) is, when a fire occurs in any one of the plurality of battery modules 200, the flame is located at the top by the outer peripheral portion (320w) of the flameproof cover 320 and flameproof cover 320 It can be prevented from affecting the other battery module 200.
- the outer peripheral portion 320w of the flameproof cover 320 protrudes and extends so as to be exposed to the outside from between the plurality of battery modules 200, and the flameproof cover 320 Since the protruding and extending outer circumferential portion 320w is configured to be bent upward, it is possible to effectively prevent fire from propagating in the vertical direction to the plurality of battery modules 200 stacked in the vertical direction. Accordingly, it is possible to increase the safety of the battery rack.
- FIG. 10 is a perspective view schematically showing some configurations of a battery rack according to another embodiment of the present invention.
- the flameproof cover 320 may have an uneven structure 320k bent at predetermined intervals.
- the uneven structure 320k may include a concave portion and a convex portion extending linearly in a left and right direction.
- the flame-retardant cover 320 by configuring the flame-retardant cover 320 to have an uneven structure (320k) bent at predetermined intervals, it is possible to prevent the propagation of the flame, as well as high temperature to the outside when a fire occurs. It is possible to secure a discharge passage for discharging the gas. Accordingly, it is possible to increase the safety of the battery rack 300.
- the battery rack 300 may further include other components such as a battery management system (BMS, 330 in FIG. 1) inside or outside the rack case 310 I can.
- BMS battery management system
- the power storage device according to the present invention may include one or more battery racks 300 according to the present invention described above.
- the power storage device may include a plurality of battery racks 300 according to the present invention.
- such a plurality of battery racks 300 may be electrically connected to each other.
- the power storage device according to the present invention may be implemented in various forms, such as a smart grid system or an electric charging station.
- gas passage 230 flameproof plate
- main body 236 flame blocking portion
- 226p insertion protrusion 130, 140: heat absorbing pad, heat insulating pad
- busbar assembly 272 busbar assembly 272
- the present invention relates to a battery module comprising a flame retardant plate.
- the present invention can be used in an industry related to a battery rack including a plurality of battery modules and a power storage device including the battery rack.
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- General Chemical & Material Sciences (AREA)
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- Health & Medical Sciences (AREA)
- Public Health (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Battery Mounting, Suspending (AREA)
- Gas Exhaust Devices For Batteries (AREA)
- Secondary Cells (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
Description
Claims (13)
- 각각이 상호 전기적으로 연결되고 전후 방향으로 적층된 복수의 이차전지를 가진 적어도 둘 이상의 셀 어셈블리;상기 셀 어셈블리를 내부에 수납하도록 내부 공간이 형성되고 상기 셀 어셈블리의 좌우 방향의 일측 또는 양측에 상기 셀 어셈블리로부터 발생된 가스가 유통되도록 가스 통로가 구비된 모듈 하우징; 및플레이트 형상을 가지고 상기 둘 이상의 셀 어셈블리 사이에 개재되는 본체부, 및 상기 본체부의 좌우 방향의 일 단부 또는 양 단부로부터 좌우 방향으로 돌출되어 상기 가스 통로 중 일부분에 위치된 화염 차단부를 구비한 방염 플레이트를 포함하는 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 배터리 모듈은,상기 복수의 이차전지를 전기적으로 상호 연결하도록 상기 복수의 이차전지에 구비된 전극 단자와 접촉한 적어도 하나 이상의 버스바, 및 상기 적어도 하나 이상의 버스바가 탑재되고 상기 셀 어셈블리의 좌우 방향의 양측 각각에 구비된 적어도 둘 이상의 버스바 프레임이 구비된 버스바 어셈블리를 더 포함하고,상기 가스 통로는 상기 버스바 프레임의 외측면과 상기 모듈 하우징의 내면 사이에 형성된 공간이며,상기 화염 차단부에는 상기 셀 어셈블리로부터 발생된 가스가 유통되도록 전후 방향으로 천공된 복수의 가스 배출홀이 형성된 것을 특징으로 하는 배터리 모듈.
- 제2항에 있어서,상기 모듈 하우징은 상기 가스 통로의 말단과 연통되도록 가스 배출구가 구비되고,상기 가스 배출홀은 상기 가스 배출구가 위치한 방향으로 홀의 구멍이 연속적으로 좁아지도록 구성된 것을 특징으로 하는 배터리 모듈.
- 제2항에 있어서,상기 모듈 하우징은 상기 가스 통로의 말단과 연통되도록 가스 배출구가 구비되고,상기 화염 차단부에는 상기 셀 어셈블리로부터 발생된 가스가 상기 가스 배출홀이 위치한 방향으로 이동하도록 유도하는 가이드 구조가 구비된 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 모듈 하우징의 내면에는 상기 화염 차단부의 적어도 일부위가 삽입되는 슬릿이 형성된 삽입 돌출부가 구비된 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 방염 플레이트는, 불에 잘 타지 않는 난연층, 열 전달을 막도록 구성된 단열층, 소정 온도에서 부피가 팽창하는 팽창층, 및 소정 온도에서 열을 흡수하는 흡열층 중 어느 하나 이상을 구비하는 다층 구조를 가진 것을 특징으로 하는 배터리 모듈.
- 제6항에 있어서,상기 다층 구조는 2개의 상기 난연층 사이에 상기 팽창층이 개재된 구조이거나, 또는 2개의 상기 난연층 사이에 상기 단열층이 개재된 구조인 것을 특징으로 하는 배터리 모듈.
- 제1항에 있어서,상기 셀 어셈블리는, 상기 복수의 이차전지 사이에 소정 온도에서 흡열 반응을 통해 열을 흡수하는 흡열 패드 및 열 전달을 막도록 구성된 단열 패드 중 어느 하나 이상이 구비된 것을 특징으로 하는 배터리 모듈.
- 제1항 내지 제8항 중 어느 한 항에 따른 복수의 배터리 모듈, 및 상기 복수의 배터리 모듈을 상하 방향으로 적층된 형태로 수용하는 랙 케이스를 포함한 것을 특징으로 하는 배터리 랙.
- 제9항에 있어서,상기 복수의 배터리 모듈 사이에 개재되고 상기 배터리 모듈의 상부 또는 하부를 커버하도록 구성된 방염 커버를 포함한 것을 특징으로 하는 배터리 랙.
- 제10항에 있어서,상기 방염 커버 외주부의 적어도 일부는 상기 복수의 배터리 모듈 사이로부터 외부로 노출되도록 돌출 연장되고,상기 방염 커버의 돌출 연장된 외주부는 상부 방향으로 굽어져 있는 것을 특징으로 하는 배터리 랙.
- 제10항에 있어서,상기 방염 커버는 소정 간격으로 굴곡진 요철 구조를 가진 것을 특징으로 하는 배터리 랙.
- 제9항에 따른 배터리 랙을 포함하는 전력 저장 장치.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US17/431,388 US11870094B2 (en) | 2019-07-03 | 2020-06-23 | Battery module, battery rack comprising same, and power storage device |
EP20834689.0A EP3965220B1 (en) | 2019-07-03 | 2020-06-23 | Battery module, battery rack comprising same, and power storage device |
JP2021557060A JP7268188B2 (ja) | 2019-07-03 | 2020-06-23 | バッテリーモジュール、これを含むバッテリーラック及び電力貯蔵装置 |
CN202080038388.8A CN113939944B (zh) | 2019-07-03 | 2020-06-23 | 电池模块、包括该电池模块的电池架和能量存储系统 |
AU2020300283A AU2020300283A1 (en) | 2019-07-03 | 2020-06-23 | Battery module, battery rack comprising same, and power storage device |
PL20834689.0T PL3965220T3 (pl) | 2019-07-03 | 2020-06-23 | Moduł akumulatorowy, stojak akumulatorowy zawierający moduł akumulatorowy i urządzenie magazynujące energię |
US18/505,866 US20240079721A1 (en) | 2019-07-03 | 2023-11-09 | Battery module, battery rack comprising same, and power storage device |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2019-0080195 | 2019-07-03 | ||
KR1020190080195A KR20210004189A (ko) | 2019-07-03 | 2019-07-03 | 방염 플레이트를 구비한 배터리 모듈, 이를 포함하는 배터리 랙 및 전력 저장 장치 |
Related Child Applications (2)
Application Number | Title | Priority Date | Filing Date |
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US17/431,388 A-371-Of-International US11870094B2 (en) | 2019-07-03 | 2020-06-23 | Battery module, battery rack comprising same, and power storage device |
US18/505,866 Continuation US20240079721A1 (en) | 2019-07-03 | 2023-11-09 | Battery module, battery rack comprising same, and power storage device |
Publications (1)
Publication Number | Publication Date |
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WO2021002626A1 true WO2021002626A1 (ko) | 2021-01-07 |
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ID=74100898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/KR2020/008193 WO2021002626A1 (ko) | 2019-07-03 | 2020-06-23 | 배터리 모듈, 이를 포함하는 배터리 랙 및 전력 저장 장치 |
Country Status (9)
Country | Link |
---|---|
US (2) | US11870094B2 (ko) |
EP (1) | EP3965220B1 (ko) |
JP (1) | JP7268188B2 (ko) |
KR (1) | KR20210004189A (ko) |
CN (1) | CN113939944B (ko) |
AU (1) | AU2020300283A1 (ko) |
HU (1) | HUE067073T2 (ko) |
PL (1) | PL3965220T3 (ko) |
WO (1) | WO2021002626A1 (ko) |
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EP4310995A4 (en) * | 2021-11-15 | 2024-10-16 | Lg Energy Solution Ltd | HEAT RADIATION ELEMENT AND BATTERY PACK |
Also Published As
Publication number | Publication date |
---|---|
US11870094B2 (en) | 2024-01-09 |
JP7268188B2 (ja) | 2023-05-02 |
EP3965220A4 (en) | 2022-06-29 |
AU2020300283A1 (en) | 2021-12-23 |
CN113939944B (zh) | 2023-12-12 |
JP2022528227A (ja) | 2022-06-09 |
CN113939944A (zh) | 2022-01-14 |
EP3965220B1 (en) | 2024-04-24 |
EP3965220A1 (en) | 2022-03-09 |
US20240079721A1 (en) | 2024-03-07 |
PL3965220T3 (pl) | 2024-07-01 |
US20220115737A1 (en) | 2022-04-14 |
KR20210004189A (ko) | 2021-01-13 |
HUE067073T2 (hu) | 2024-09-28 |
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