WO2020254869A1 - Mélange d'extinction d'incendie amélioré - Google Patents
Mélange d'extinction d'incendie amélioré Download PDFInfo
- Publication number
- WO2020254869A1 WO2020254869A1 PCT/IB2019/057902 IB2019057902W WO2020254869A1 WO 2020254869 A1 WO2020254869 A1 WO 2020254869A1 IB 2019057902 W IB2019057902 W IB 2019057902W WO 2020254869 A1 WO2020254869 A1 WO 2020254869A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fire
- solution
- extinguishing
- extinguishing mixture
- until
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 39
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000006260 foam Substances 0.000 claims abstract description 16
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 15
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims abstract description 15
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims abstract description 14
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims abstract description 14
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 14
- 229910000027 potassium carbonate Inorganic materials 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 11
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 10
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 239000004033 plastic Substances 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims 1
- 210000002700 urine Anatomy 0.000 abstract description 6
- 239000010754 BS 2869 Class F Substances 0.000 abstract description 5
- 235000015165 citric acid Nutrition 0.000 abstract description 2
- 235000011181 potassium carbonates Nutrition 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000010411 cooking Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- -1 silk Substances 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62C—FIRE-FIGHTING
- A62C19/00—Hand fire-extinguishers in which the extinguishing substance is expelled by an explosion; Exploding containers thrown into the fire
Definitions
- the utility solution relates to an improved fire-extinguishing mixture for throwable fire extinguishers, as well as to a fire extinguisher containing thereof.
- the fire-extinguishing mixture can extinguish fires of various classes by throwing directly the fire extinguisher containing fire-extinguishing mixture into the fire.
- fire extinguishers there is a variety of products referred to as fire extinguishers.
- C02 powder fire extinguishers are difficult to use and heavy. Therefore, it is not convenient to use them in case of a fire.
- conventional aerosol fire extinguishers can be easily used by anyone, but it is very difficult to use them for dealing with the expanded fire situation.
- throwable fire extinguishers are those that are too easy to use, which contain inorganic foaming fire-extinguishing mixtures with a good extinguishing ability for high temperature fires (175°C and higher).
- the shell of a fire extinguisher is easy to shatter and distribute the fire extinguishing mixture, which facilitates the extinguishment of expanded fires.
- the composition of a fire extinguisher used in the fire extinguisher comprises various agents.
- throwable fire extinguishers available on the market, which have been developed and sold for many years.
- these comprise: BONEX fire extinguishers, the throwable fire extinguishers from JAPAN FIRE PROTECT CO.LTD, the fire extinguishers from QINGDAO HUOSHEN EQUIPMENT. CO, the fire extinguishers from FRUNE ZONE CO.LTD, and some other throwable fire extinguishers: FIRE FIGHTER THROWING, TG FIREFIGHTER etc.
- An advantage of the prior-art throwable fire extinguishers is their environmental and user friendliness.
- the pH of the fire extinguishing solution is about 8, that is, slightly alkaline, thus not causing harm to one's health if swallowed.
- the prior-art throwable fire extinguishers have a not-so-large volume, about 500-650 mL, which have limitation for extinguishment of larger fires.
- the prior-art throwable fire extinguishers on the market contain a fire extinguishing solution that usually has a plurality of ammonium radicals. These ammonium radicals will cause urine odor (smell of urine) for accidental leakage, and breakage into environment during the transport and storage. Such smell is very unpleasant to the users, which makes the deodorization highly time-consuming.
- the prior-art throwable fire extinguishers may be able to extinguish Class A, Class B, and Class C fires only.
- an objective of the utility solution is to develop a safe improved fire-extinguishing mixture that does not have affect to human body and that is an effective fire-extinguishing mixture with extinguishing ability for maximizing the effects of the fire-extinguishing agents, increasing the extinguishing ability, improving user experience during the transport and storage of throwable fire extinguishers.
- the utility solution provides an improved fire-extinguishing mixture for throwable fire extinguishers as well as a fire extinguisher containing the same.
- the fire-extinguishing mixture is able to extinguish Class A, Class B, and Class C (or class F) fires, by throwing directly the fire extinguisher containing fire extinguishing mixture into to the fire.
- a fire extinguishing mixture comprising: a. 40% to 55% by weight of potassium carbonate (K 2 C0 ), b. 5 to 10% by weight of sodium bicarbonate (NaHC0 3 ),
- ammonium bicarbonate (NH 4 HC0 3 )
- citric acid C 6 H 8 0 7
- a fire extinguisher containing the aforementioned fire-extinguishing mixture.
- the utility solution provides a fire extinguisher, having a brittle and fragile plastic shell, that contains the aforementioned fire-extinguishing mixture.
- the previous fire extinguisher contains the aforementioned fire-extinguishing mixture of a 710 mL volume.
- a method of producing a fire-extinguishing mixture comprises:
- numeric ranges with endpoints will include all values and fractions within the corresponding ranges, as well as the said endpoints.
- the term“approximately” when used for the numeric values indicates that an approximation to certain degree in calculation and measurement thereof (which is precisely, adjacently, approximately or substantially the same numeric value). If for any reason the inaccuracy resulted from the term“approximately” is not understood by common knowledge in the art, the term“approximately” used herein indicates at least variations from conventional methods of measurement or using of these parameters. For example, the term“generally”,“approximately” and“substantially” can be used herein as being within the manufacturing errors.
- the term “approximately” used herein when changing the amount of a component or a reactant of the utility solution, or when used will indicate variation of the shown amount, is presented by a number that can occur during the common operational and measuring processes used, e.g., when producing concentrates or solutions in practice due to neglection in these processes, or differences in the production, the sources or the purity of the agents used in producing the composition or in implementing the methods, and the like.
- the term“approximately” also includes the varying amounts due to the balancing of different compositions derived from a particular original mixture. Whether there is change caused by the term“approximately”, the claims still include the equivalents to these amounts.
- a reference to “embodiments” or “an embodiment” means that the particular features, structures or properties are described together with the embodiment will be included at least in one embodiment of the utility solution. As such, the presence of the terms “according to the embodiment” or “according to an embodiment” in various parts of the present specification is not necessary to refer to the same embodiment, but it may be. Furthermore, such features, structures or properties can be combined in any appropriate manner in one or more embodiments, as will be appreciated by a person of ordinary skill in the art when reading the present specification.
- Class A fires refer to the fires related to combustible materials such as wood, paper, silk, plastic, textile, waste, and the like.
- Class B fires refer to the fires related to flammable liquids, gases, or materials, also referred to as Group B flames.
- Class C fires refer to the electrical fires and fires related to electronic devices.
- Class K fires also referred to as kitchen fires (previously referred to as Class F fires, renamed "K” by NFPA 10 in 1998, in The United States of America), are the fires related to flammable liquids such as lards, oils, fats occurring during cooking.
- the fire extinguishing solution usually includes ammonium radicals for cooling during the extinguishment.
- the fire extinguishing solution in high temperature will produce ammonia NH .
- Ammonia usually is unpleasant due to its urine odor, which normally occurs if the extinguisher containing the solution is dropped or broken during transport and storage (in vehicle, building, workshop, etc.).
- the ammonium radicals in the ammonium bicarbonate have been reduced to a proper amount as to alleviate the urine odor of the solution (product) upon breakage during transport and storage of the solution in normal environments (non-extinguishment), but it still maintains the extinguishing efficiency .
- the fire-extinguishing mixture of the utility solution produces a large amount of C0 2 for extinguishment.
- potassium carbonate, sodium bicarbonate, ammonium bicarbonate, citric acid thermally react with the fire and create a large amount of C0 2 .
- the fire-extinguishing mixture of the utility solution has a very large ratio of K 2 C0 3 , greatly facilitating the extinguishment of Class F fires (named class "K” by NFPA 10 in 1998, in The United States of America), particularly the fires related to the cooking materials (oils and fats) in cookware.
- the fire-extinguishing mixture of the utility solution contains an associated combination of sodium lauryl sulfate and aqueous film forming foam for increasing its extinguishing efficiency .
- sodium lauryl sulfate and the aqueous film forming foam are combined together, thereby creating foams and water films, and thus rapidly quenching the oxygen source and extinguishing the fire.
- one or more components of ammonium bicarbonate, sodium lauryl sulfate and the aqueous film forming foam can be absent.
- the extinguishing efficiency of the mixture will be significantly reduced.
- the fire extinguisher containing the fire-extinguishing mixture is manufactured with a volume of 710 mL, which is much larger than many other products on the market, in order to increase the extinguishing ability of the fire-extinguishing mixture, thus facilitating the extinguishment of larger fires.
- the method of producing the fire-extinguishing mixture comprises:
- a fire-extinguishing mixture is produced by a method comprising:
- the fire-extinguishing mixture which contains: a. approximately 55% by weight of potassium carbonate (K 2 C0 ),
- the fire-extinguishing mixture of the utility solution helps to alleviate the urine odor of the fire-extinguishing mixture, increase the extinguishing ability and the re ignition prevention ability of the fire-extinguishing mixture, and specifically make the fire-extinguishing mixture to be able to extinguish the Class K (Class F) fires.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Fire-Extinguishing Compositions (AREA)
Abstract
La présente invention concerne une solution d'utilité concernant un mélange d'extinction d'incendie amélioré, comprenant les composants comprenant du carbonate de potassium, du bicarbonate de sodium, du bicarbonate d'ammonium, de l'acide citrique, du laurylsulfate de sodium, du film aqueux formant de la mousse et de l'eau dans des quantités telles que décrites ici. La solution utilitaire aide à atténuer l'odeur d'urine du mélange d'extinction d'incendie, à augmenter la capacité d'extinction et la capacité de prévention de l'inflammation du mélange d'extinction d'incendie, et à rendre plus spécifique le mélange d'extinction d'incendie pour pouvoir éteindre les incendies de classe K (classe F). De plus, la solution utilitaire concerne en outre un extincteur contenant ledit mélange d'extinction d'incendie et un procédé de production du mélange d'extinction d'incendie.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19933338.6A EP3986574A4 (fr) | 2019-06-21 | 2019-09-19 | Mélange d'extinction d'incendie amélioré |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
VN2201900236 | 2019-06-21 | ||
VN2-2019-00236 | 2019-06-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2020254869A1 true WO2020254869A1 (fr) | 2020-12-24 |
Family
ID=80786099
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2019/057902 WO2020254869A1 (fr) | 2019-06-21 | 2019-09-19 | Mélange d'extinction d'incendie amélioré |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP3986574A4 (fr) |
WO (1) | WO2020254869A1 (fr) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2595589A (en) * | 2020-05-27 | 2021-12-01 | Firexo Group Ltd | Fire extinguishing composition for large fires |
US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11865392B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103007479A (zh) * | 2012-12-31 | 2013-04-03 | 西安科技大学 | 一种灭火剂 |
WO2013145207A1 (fr) * | 2012-03-29 | 2013-10-03 | 株式会社メディプラン | Agent d'extinction d'incendie pour un extincteur d'incendie de lancement |
CN103706062A (zh) * | 2013-12-31 | 2014-04-09 | 青岛火神消防设备有限公司 | 便携投掷式灭火器 |
WO2015020388A1 (fr) * | 2013-08-06 | 2015-02-12 | Han Seungwoo | Composition pour agent extincteur d'incendie renforcé neutre et écologique |
CN104474659A (zh) * | 2014-12-17 | 2015-04-01 | 刘树民 | 液体灭火剂及水基型投掷式灭火器 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104258529B (zh) * | 2014-09-16 | 2017-02-22 | 温州安顺消防设备有限公司 | 便携式灭火消防瓶 |
CN106267635A (zh) * | 2016-08-08 | 2017-01-04 | 刘树民 | 一种水基型多功能阻燃灭火器 |
-
2019
- 2019-09-19 WO PCT/IB2019/057902 patent/WO2020254869A1/fr active Application Filing
- 2019-09-19 EP EP19933338.6A patent/EP3986574A4/fr active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013145207A1 (fr) * | 2012-03-29 | 2013-10-03 | 株式会社メディプラン | Agent d'extinction d'incendie pour un extincteur d'incendie de lancement |
CN103007479A (zh) * | 2012-12-31 | 2013-04-03 | 西安科技大学 | 一种灭火剂 |
WO2015020388A1 (fr) * | 2013-08-06 | 2015-02-12 | Han Seungwoo | Composition pour agent extincteur d'incendie renforcé neutre et écologique |
CN103706062A (zh) * | 2013-12-31 | 2014-04-09 | 青岛火神消防设备有限公司 | 便携投掷式灭火器 |
CN104474659A (zh) * | 2014-12-17 | 2015-04-01 | 刘树民 | 液体灭火剂及水基型投掷式灭火器 |
Non-Patent Citations (1)
Title |
---|
See also references of EP3986574A4 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11819722B1 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11819723B2 (en) | 2019-06-07 | 2023-11-21 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
GB2595589A (en) * | 2020-05-27 | 2021-12-01 | Firexo Group Ltd | Fire extinguishing composition for large fires |
GB2595589B (en) * | 2020-05-27 | 2022-12-21 | Firexo Cotm Ltd | Fire extinguishing composition for large fires |
US11865392B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11865391B2 (en) | 2020-12-15 | 2024-01-09 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US11883703B2 (en) | 2020-12-15 | 2024-01-30 | Frs Group, Llc | Long-term fire retardant with magnesium sulfate and corrosion inhibitors and methods for making and using same |
US11975231B2 (en) | 2022-03-31 | 2024-05-07 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US12053658B2 (en) | 2022-03-31 | 2024-08-06 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
US12109446B2 (en) | 2022-03-31 | 2024-10-08 | Frs Group, Llc | Long-term fire retardant with corrosion inhibitors and methods for making and using same |
Also Published As
Publication number | Publication date |
---|---|
EP3986574A1 (fr) | 2022-04-27 |
EP3986574A4 (fr) | 2024-06-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2020254869A1 (fr) | Mélange d'extinction d'incendie amélioré | |
WO2011158340A1 (fr) | Procédé de fabrication d'un agent d'extinction des incendies et équipement d'extinction des incendies lancé à la main | |
JP5261751B2 (ja) | 消火剤の製造方法 | |
MX2015003639A (es) | Composicion de extincion de incendios de fosfato. | |
US20110266486A1 (en) | Orr Formular | |
MX2015003907A (es) | Composicion de extincion de incendios de oxisal metalica. | |
JPWO2013145207A1 (ja) | 投てき消火具用消火剤 | |
CN113710332A (zh) | 渗透型灭火药剂组合物 | |
CN110124245A (zh) | 发泡海藻酸钠水凝胶及其制备方法、灭火装置 | |
CN103706062A (zh) | 便携投掷式灭火器 | |
JP6362537B2 (ja) | 銅塩系消火組成物 | |
CN105641850A (zh) | 一种灭火剂 | |
US20070251707A1 (en) | Method, apparatus and compositions for firefighting | |
GB2497820A (en) | Fire extinguishing composition and delivery apparatus | |
GB2299020A (en) | Fire extinguishing agent for use in a throwable container | |
US9533181B2 (en) | Multi-class fire extinguishing agent | |
JP6644280B2 (ja) | 消火剤 | |
CN105944274B (zh) | 一种动植物油脂专用灭火剂及其制备方法 | |
AU2017296963B2 (en) | Composition, container, system and methods | |
JP5725285B2 (ja) | 消火ボトル | |
JPH029828B2 (fr) | ||
JPH11414A (ja) | 粉末消火剤組成物、及び消火方法 | |
JPS61206468A (ja) | エアゾ−ル式消火具 | |
Alexandrovich | DEVELOPMENT OF TECHNICAL ASPECTS OF THE CONTAINER METHOD OF FIRE EXTINGUISHING | |
Ковальов | Development of technical aspects of the container method of fire extinguishing |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 19933338 Country of ref document: EP Kind code of ref document: A1 |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2019933338 Country of ref document: EP |