WO2020232767A1 - Energy circulating active convection oxygenating ecological floating island - Google Patents

Energy circulating active convection oxygenating ecological floating island Download PDF

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Publication number
WO2020232767A1
WO2020232767A1 PCT/CN2019/090601 CN2019090601W WO2020232767A1 WO 2020232767 A1 WO2020232767 A1 WO 2020232767A1 CN 2019090601 W CN2019090601 W CN 2019090601W WO 2020232767 A1 WO2020232767 A1 WO 2020232767A1
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WIPO (PCT)
Prior art keywords
water
housing
air
electrolysis
oxygen
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PCT/CN2019/090601
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French (fr)
Chinese (zh)
Inventor
吴丹丹
孙优生
彭晨
彭博
张华恒
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南京森淼环保科技有限公司
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Publication of WO2020232767A1 publication Critical patent/WO2020232767A1/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00Electrolytic production of inorganic compounds or non-metals
    • C25B1/01Products
    • C25B1/02Hydrogen or oxygen
    • C25B1/04Hydrogen or oxygen by electrolysis of water
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/06Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0656Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by electrochemical means
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/129Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Definitions

  • the invention relates to the field of environmental protection technology and aquaculture, in particular to an ecological floating island with active convection and oxygenation of energy circulation.
  • the present invention provides an energy cycle active convective oxygen-enhancing ecological floating island.
  • the floating island adopts molecular-level aerators to perform molecular-level high-efficiency oxygenation of water bodies, and at the same time cooperates with the energy recovery of hydrogen fuel cells and solar power generation devices Energy replenishment to achieve high-efficiency molecular-level oxygenation.
  • the purpose of the present invention is to provide an ecological floating island with active convection and oxygenation of energy circulation, which realizes high-efficiency and three-dimensional aeration of water bodies.
  • An energy cycle active convection and oxygen-enhancing ecological floating island comprising a floating platform, at least one aeration device, a microbial fungus bed and landscape plants; the floating platform is fixed on the water surface by a fixed anchor;
  • the aeration device and landscape plants are fixed on the floating platform, and the microbial fungus bed is located underwater and connected to the lower surface of the floating platform;
  • the oxygen increasing device includes a housing, a driving device, a hydrogen fuel cell, an electrolysis device, and a power supply device, and the housing includes an upper housing section and a lower housing section that are connected;
  • the driving device is arranged above the upper section of the housing, and the drive shaft of the driving device extends into the upper section of the housing, is connected with the water sling wheel, and drives the water sling wheel to rotate;
  • At least one water spray port is provided on the outer side wall of the upper section of the housing, and the water spray port is connected to a water spray pipe;
  • the electrolysis device includes an electrolytic positive electrode and an electrolytic negative electrode; a plurality of holes are axially provided in the side wall of the upper section of the housing, and the electrolytic negative electrode is installed in the hole; the electrolytic positive electrode is fixed to the inner cavity of the upper section of the housing; Internal cavity communication;
  • the hydrogen fuel cell is connected to the electrolysis negative electrode of the electrolysis device through a hydrogen recovery pipeline, collects the hydrogen generated by the reaction of the electrolysis device, and stores the electric energy generated by the reaction in the energy storage device;
  • the power supply device is used to supply power to the electric device.
  • the floating platform adopts a block interlocking arrangement, and the blocks are connected to form floating islands through occlusion to form a device carrier.
  • the top of the upper section of the casing is closed, the cross section is circular, and the longitudinal section is rectangular; the bottom of the casing is open, the cross section is circular, and the longitudinal section is an isosceles trapezoid.
  • the lower section of the shell can adjust the length and the diameter of the bottom opening according to the actual depth of the water area to meet the needs of the project.
  • the water body enters the aeration equipment from the bottom of the lower section of the shell.
  • the shell adopts this design method, which can ensure the sufficient water intake while keeping the water inlet flow rate very low, preventing the adsorption of debris, preventing debris from entering the equipment and blocking the pipeline, and avoiding the sludge at the bottom from stirring and changing the water body
  • the turbidity affects the normal life of farmed fish and shrimp.
  • the water spray pipe is arranged tangentially to the upper section of the housing, and the horizontal extension direction of the water spray pipe is consistent with the rotation direction of the driving device. Further, the angle between the water spray pipe and the horizontal plane is -30° to 0°; the diameter of the water spray pipe is a gradual design, and the diameter of the water outlet>the diameter of the water inlet.
  • the through holes are opened radially along the upper section of the casing, and the level of the through holes is lower than the level of the bottom of the electrolytic negative electrode.
  • the bottom of the electrolytic negative electrode is slightly higher than the position of the through hole, and the through hole is opened in the radial direction, that is, perpendicular to the side wall of the upper section of the housing, to avoid negative pressure due to the operation of high-speed water flow inside the equipment, and suck hydrogen into the equipment to achieve hydrogen and oxygen Efficient separation.
  • the electrolysis positive electrode has a ring structure and is fixed under the water spinner.
  • the longitudinal section of the hydrogen fuel cell is a gear-shaped design, which increases the contact area between hydrogen and oxygen in the air and the catalyst, and improves the reaction efficiency of the hydrogen fuel cell.
  • the hydrogen fuel cell is composed of several battery cells to form a fuel cell stack.
  • the battery cells can be arranged in parallel, series, series and parallel according to actual needs.
  • the air inlet of the hydrogen fuel cell is provided with an air filter to filter the air entering the hydrogen fuel cell to prevent dust from being adsorbed on the surface of the hydrogen fuel cell catalyst and affect the efficiency of the catalyst.
  • the upper part of the hydrogen chamber of the hydrogen fuel cell is provided with an air inlet, and the bottom is provided with an air outlet.
  • the air outlet is controlled by a one-way check valve, and only gas is allowed to exhaust from the hydrogen chamber. Allow outside air to enter the hydrogen chamber through the lower exhaust port.
  • the upper part of the hydrogen chamber is provided with an air inlet for introducing hydrogen, and the lower part is provided with an exhaust port.
  • the density of hydrogen is small. The water condensed from the original air in the hydrogen chamber and the water vapor carried by the hydrogen can be effectively discharged through the exhaust port, which is convenient for later maintenance. , Quickly exhaust air, ensure the purity of hydrogen in the hydrogen chamber, and improve reaction efficiency.
  • the air chamber of the hydrogen fuel cell is divided into an air outer chamber and an air inner chamber on both sides by two perforated separation plates; the perforated separation plate has holes diagonally upward; the air outer chamber is connected to an air filter, and the air
  • a one-way check valve is arranged at the junction of the chamber and the air filter; a number of exhaust ports are arranged at the bottom of the air inner chamber, and the exhaust ports are controlled by a one-way check valve.
  • the air chamber of the hydrogen fuel cell is divided into an outer air chamber and an air inner chamber on both sides by two perforated partition plates; the perforated partition plates open holes diagonally upward to force air from the outer chamber When entering the inner chamber, the airflow is directly blown to the positive side of the hydrogen fuel cell to improve the reaction efficiency.
  • the outer air chamber is connected to an air filter, and the connection between the outer air chamber and the air filter is provided with a one-way check valve, which only allows air to enter the outer chamber from the outside, and does not allow gas to retrograde; the bottom of the air inner chamber is provided with several
  • the exhaust port and the exhaust port are controlled by a one-way check valve, which only allows air to be discharged from the air chamber, and does not allow air to flow backwards.
  • This design scheme can ensure that the fuel cell is in a non-working state, the inner chamber is in a closed state, to ensure a certain humidity inside the cell, and to prevent the reduction of reaction efficiency caused by the low water content of the proton permeable membrane and the shrinkage of the proton permeable membrane after loss of water
  • the proton permeable membrane is broken.
  • the exhaust port at the bottom of the air chamber is connected to the heat dissipation fan of the driving device.
  • the heat dissipation fan of the driving device is used to suck air into the positive side of the hydrogen fuel cell to increase the amount of air sucked in. While ensuring the rapid and efficient response of the hydrogen fuel cell, Heat the fuel cell.
  • the electrolytic positive electrode is arranged at a position 5-10 cm from the lower part of the water slinger, and is connected to the inner surface of the side wall of the upper section of the shell through a fixed rod.
  • the fixed rod is made of insulating material or the same material as the electrolytic positive electrode;
  • the electrolysis negative electrode spacing is controlled to be about 2cm, and the electrolysis voltage adopts a low voltage of 12V-24V.
  • the floating body is made of light materials such as plastic or foam.
  • the upper section of the housing is made of insulating material.
  • the bottom of the casing is provided with a dirt blocking net; the dirt blocking net is provided with square or circular holes, and the aperture is not greater than 0.5 cm. Blocking nets can prevent small fish or sundries in the water from entering the equipment and affecting the operation of the equipment.
  • a water-proof oil seal is provided at the bearing part where the transmission shaft and the water slinger are connected to prevent water from the lower part from entering the driving device.
  • the driving device is a waterproof DC speed reduction motor.
  • the power supply device is a solar power supply device; the electrical energy generated by the hydrogen fuel cell is stored in the energy storage device of the solar power supply device.
  • the microbial fungus bed is arranged on the side of the aerator to ensure sufficient oxygen supply.
  • the floating island of the present invention drives the water spinner to rotate through the driving device of the aerator to make the water form three-dimensional convection.
  • the electrolysis device is powered by the energy storage device to electrolyze the water entering the equipment, and the oxygen molecules generated by the electrolysis It is quickly taken away by the high-speed water flow inside the equipment and sprayed into the external waters to achieve molecular-level oxygen increase.
  • the electrolytic positive electrode is placed in the inner cavity of the shell. When the device is running, a high-speed water flow is generated inside the electrolysis positive electrode.
  • the oxygen generated is quickly taken away, and the density of hydrogen generated by the electrolytic negative electrode is small, and it quickly accumulates in the channel and enters the recovery pipeline; in addition, the bottom of the electrolytic negative electrode is slightly higher than the position of the through hole, and the through hole is vertical to the outer wall, avoiding the internal
  • the operation of high-speed water flow generates negative pressure, which sucks hydrogen into the equipment, thereby realizing efficient separation of hydrogen and oxygen.
  • the hydrogen produced by electrolysis enters the hydrogen fuel cell through the hydrogen recovery pipeline, generates electricity through the hydrogen fuel cell reaction, and is supplied to the energy storage device to realize energy circulation; the solar power supply device generates electricity under the action of sunlight, and is further supplied to the energy storage device to compensate Energy loss during the reaction to achieve energy balance.
  • the arrangement of the microbial bacteria bed in the lower water body of the floating body provides a good living space for microorganisms, so that the sludge rich in organic matter at the bottom of the polluted water body is digested under the action of aerobic bacteria, and the three-dimensional convection brought by the aeration device can accelerate the digestion.
  • landscape plants placed on the floating island can increase the overall aesthetics, and pollution-resistant landscape plants can also be used to promote water purification, so that the floating island of the present invention has the functions of beauty, oxygenation and purification, and can be improved in long-term operation Control the overall dissolved oxygen in the water area, activate the vitality of the water body, assist in the construction of a benign ecological balance, and realize the control of the water quality improvement of the water area and the long-term maintenance of the energy cycle.
  • Figure 1 is a cross-sectional view of the overall structure of the floating island of the present invention.
  • Aeration device 200.
  • Microbial bed 300.
  • Landscape plants 18.
  • Floating platform 19.
  • Fixed anchor 19.
  • Figure 2 is a schematic diagram of the structure of the aerator
  • Figure 3 is a cross-sectional view of the water jet wheel.
  • Figure 4 is a longitudinal sectional view of a hydrogen fuel cell
  • 20 One-way check valve, 21. Open hole isolation plate, 22. Air extraction port, 23. Hydrogen gas inlet, 24. Air exhaust port, 25. Hydrogen chamber, 26. Air inner chamber, 27. Air Outer room.
  • Figure 5 is a top view of a hydrogen fuel cell
  • Figure 6 is a sectional view of a hydrogen fuel cell unit
  • Figure 7 is a schematic cross-sectional structure diagram of the electrolysis device
  • the ecological floating island as shown in FIG. 1 includes a floating platform 18, at least one aeration device 100, a microbial fungus bed 200 and landscape plants 300; the floating platform 18 is fixed on the water surface by a fixed anchor 19; the aeration device 100 and landscape plants 300 Fixed on the floating platform 18, the microbial bacteria bed 200 is located underwater and connected to the lower surface of the floating platform.
  • the structure of the oxygen increasing device 100 is shown in Figures 2-7, including a housing, a driving device 1, a hydrogen fuel cell 5, an electrolysis device and a power supply device.
  • the housing includes an upper section 9 and a lower section 11 connected by a flange 10; The top of the upper section 9 is closed, the cross section is circular, and the longitudinal section is rectangular; the bottom of the shell lower section 11 is open, the cross section is circular, and the longitudinal section is an isosceles trapezoid.
  • the driving device 1 is a waterproof DC speed reduction motor, which is arranged above the upper section 9 of the housing.
  • the drive shaft 3 of the driving device 1 extends into the upper section 9 of the housing, and is connected to the water slinger 4 to drive the water slinger 4 to rotate.
  • a waterproof oil seal 2 is arranged at the bearing part where the transmission shaft 3 and the water thrower 4 are connected to prevent water from splashing into the transmission shaft 3.
  • the spur wheel 4 is a three-blade or four-blade spur wheel, as shown in Figure 2.
  • the outer side wall of the upper section 9 of the shell is provided with at least one water spout, and the center height of the spout is the same as the center height of the water thrower 4; the spout is connected to the sprinkler pipe 6;
  • the horizontal extension direction of the water pipe 6 is consistent with the rotation direction of the driving device 1.
  • the angle between the water spray pipe 6 and the horizontal plane is -30° ⁇ 0°; the diameter of the water spray pipe 6 is a gradual design, and the water outlet diameter>the water inlet diameter. In this embodiment, the diameter of the water outlet is 50-80mm, and the diameter of the water inlet is 40-50mm.
  • the structure of the electrolysis device is shown in Fig. 6, including the electrolysis positive electrode 7 and the electrolysis negative electrode 8.
  • the holes 32 should be designed to avoid the opening of the water spout; the hole 32 is equipped with the electrolysis negative electrode. 8;
  • the electrolysis positive electrode 7 is a ring structure, the electrolysis positive electrode 7 is set at the 5-10cm position of the lower part of the water spinner 4, and is connected to the inner surface of the side wall of the upper section 9 of the housing through a fixed rod 33.
  • the fixed rod 33 is made of insulating material or the same as the electrolytic positive electrode Material; each channel 32 is provided with a through hole 34, the through hole 34 is perpendicular to the side wall of the housing, and communicates with the inner cavity of the upper section 9 of the housing, so that the electrolytic positive electrode 7 and the electrolytic negative electrode 8 are connected, and the level of the through hole 34 is lower than the electrolytic negative electrode 8.
  • the distance between the electrolysis positive electrode and the electrolysis negative electrode is controlled to be about 2cm, and the electrolysis voltage adopts a low voltage of 12V-24V.
  • the hydrogen fuel cell 5 is connected to the electrolysis negative electrode 8 of the electrolysis device through a hydrogen recovery line 13 to collect the hydrogen generated by the reaction of the electrolysis device.
  • the structure of the hydrogen fuel cell 5 is shown in FIGS. 3 to 5, and the longitudinal section is gear-shaped.
  • the hydrogen fuel cell 5 can adopt the existing hydrogen fuel cell structure, including a hydrogen fuel cell housing 28, a hydrogen chamber 25 and an air chamber arranged in the housing, and a hydrogen fuel cell unit 15 for reaction is arranged between the hydrogen chamber and the air chamber. Its structure includes a gas diffusion layer 29, a catalyst layer 30 and a proton permeable membrane 31.
  • the air chamber of the hydrogen fuel cell is divided into an outer air chamber 27 and an inner air chamber 26 on both sides by two perforated partition plates 21; the perforated partition plate 21 has holes diagonally upward; the outer air chamber 27 is connected to the air filter
  • a one-way check valve 20 is provided at the junction of the air outer chamber 27 and the air filter 14; a number of air exhaust ports 24 are provided at the bottom of the air inner chamber 26, and the air exhaust ports 24 at the bottom of the air inner chamber are connected to the drive
  • the heat dissipation fan of the device 1 draws air into the anode side of the hydrogen fuel cell through the air suction port 22.
  • the air exhaust port 24 is controlled by a one-way check valve 20.
  • the upper part of the hydrogen chamber 25 of the hydrogen fuel cell 5 is provided with an air inlet 23, and the bottom is provided with an air outlet, and the air outlet is controlled by a one-way check valve 20.
  • the hydrogen fuel cell 5 is composed of several battery cells to form a fuel cell stack, and the battery cells are arranged in parallel, series, or series-parallel.
  • the floating platform 18 is made of light materials such as plastic or foam, and is fixed on the top of the upper section 9 of the shell so that the whole shell is under water; the floating platform 18 is fixed by a fixed anchor 19.
  • the power supply device is a solar power supply device, including a solar panel 16 and an energy storage device 17; the electrical energy generated by the hydrogen fuel cell 5 is stored in the energy storage device 17.
  • the bottom of the lower section 11 of the casing is provided with a trash net 12; the trash net 12 is provided with a square or circular hole with a diameter of not more than 0.5 cm. Water enters the aeration device 100 from the bottom of the lower section 11 of the casing.
  • the electrolysis device Start up, electrolyze the water entering the equipment, and generate oxygen molecules that are taken away by the high-speed water flow and sprayed to the external water body to achieve molecular-level oxygen increase in the water body.
  • the hydrogen produced by the electrolysis enters the hydrogen fuel cell 5 through the hydrogen recovery pipeline 13, and the hydrogen enters the hydrogen chamber 25 through the hydrogen gas inlet 23.
  • the hydrogen passes through the gas diffusion layer 29 and contacts the catalyst layer 30.
  • catalysis the hydrogen molecules lose two The electrons become two protons.
  • the electrons cannot pass through the proton permeable membrane 31 and can only enter the anode side of the fuel cell by circulating through the circuit.
  • the protons can smoothly pass through the proton permeable membrane 31 and directly reach the anode side of the fuel cell, and are under the action of the catalyst.
  • the oxygen molecules in the air, the protons that reach the positive electrode side through the proton permeable membrane 31, and the electrons that circulate to the positive electrode side through the external circuit react to generate water.
  • the chemical energy is converted into electrical energy through the reaction of the fuel cell to realize partial recovery of electrolytic energy, and the electrical energy is stored in the energy storage device 17 to cooperate with the electrical energy supplement of the solar power supply device to realize the molecular-level oxygen enrichment of possible quantity circulation.
  • the microbial bacteria bed 200 provides a good living space for microorganisms.
  • the microbial bacteria bed 200 is located on the side of the aerator 100, which can ensure sufficient oxygen supply.
  • the aerator 100 protects the water body during operation.
  • the nutrient-rich substances at the bottom are brought to the microbial fungus bed 200 through the circulating water flow, which greatly improves the efficiency of microbial water purification.
  • Landscape plants 300 are arranged on the upper part of the floating platform 18, which not only absorb pollutants in the water during the growth process of the landscape plants 300, but also play a role in beautifying the water environment.

Abstract

The present invention provides an energy circulating active convection oxygenating ecological floating island. The energy circulating active convection oxygenating ecological floating island comprises a floating table, at least one oxygenating device, microbial beds, and landscape plants, wherein the floating table is fixed to a water surface by means of a fixing anchor; the oxygenating device and the landscape plants are fixed to the floating table, and the microbial beds are located underwater and connected to the lower surface of the floating table; electrolysis and vertical convection design is adopted by the oxygenating device, hydrogen generated by electrolysed water is recycled and converted into electric energy by using a hydrogen cell, and electric energy supplementation is performed in combination with a solar power supply device; the microbial beds are arranged in water below a floating body, and provides good living space for microorganisms. According to the present invention, energy consumption can be reduced by means of energy circulation; vertical convection is formed on a controlled water area while implementing molecular-grade oxygenating; the overall oxygen dissolving of the controlled water area is effectively improved; the vigor of the water is activated; benign ecological balance is auxiliarily built; and water quality improvement of the controlled water area and long-term maintenance of energy circulation are achieved.

Description

一种能量循环主动对流增氧生态浮岛Energy cycle active convection and oxygenation ecological floating island 技术领域Technical field
本发明涉及环保技术和水产养殖领域,具体涉及一种能量循环主动对流增氧生态浮岛。The invention relates to the field of environmental protection technology and aquaculture, in particular to an ecological floating island with active convection and oxygenation of energy circulation.
背景技术Background technique
随着我国城市化进程发展,城市人口密集,原有的城市排污工程不完善,导致大量生活污水、工业废水直接排放到城市河流,造成河流严重污染,出现大量黑臭河,严重影响了城市居民的身体健康,对城市水生态造成严重破坏。黑臭河治理已成为治理环境污染的重中之重。黑臭河治理的问题,更关键的是后期长效保持,目前关于水系统生态的重建和水质保持,多采用人工增氧和生态浮岛技术。人工增氧存在长期运行能耗高,成本大的问题;常规的生态浮岛多依赖浮岛上种植水生植物吸收水体多余营养物质,达到维持水质的目的,存在效率低、对改善水体溶氧无贡献、对水体底层营养富集区无效果等问题。With the development of my country’s urbanization process, the urban population is densely populated, and the original urban sewage project is imperfect, causing a large amount of domestic sewage and industrial wastewater to be directly discharged into urban rivers, causing serious pollution of the river, and the emergence of a large number of black and smelly rivers, which seriously affects urban residents The health of the city has caused serious damage to the urban water ecology. The treatment of the Heiwu River has become the top priority in the treatment of environmental pollution. The more important issue for the treatment of the Heiwu River is the long-term maintenance in the later period. At present, artificial aeration and ecological floating island technologies are mostly used for the ecological reconstruction of the water system and the maintenance of water quality. Artificial aeration has the problems of high energy consumption and high cost for long-term operation; conventional ecological floating islands mostly rely on planting aquatic plants on floating islands to absorb excess nutrients in the water body to achieve the purpose of maintaining water quality. It has low efficiency and has no effect on improving the dissolved oxygen in the water body. Contribution, no effect on the bottom nutrient enrichment area of the water body, etc.
河流出现黑臭,最重要的原因是大量的污染物排放,严重超出了城市河流水系的纳污能力,加之城市河流的流动性、水交换能力差,本身的自净能力受到极大的抑制,进一步加剧了城市河流的污染程度。对于已经治理的黑臭河,后期的水生态系统重建和水质长效保持,是黑臭河治理的最终目的。The most important reason for the blackness and odor of rivers is the large amount of pollutants discharged, which seriously exceeds the pollution-holding capacity of the urban river system. In addition to the poor mobility and water exchange capacity of the urban rivers, their self-purification ability is greatly inhibited, and further Intensified the pollution of urban rivers. For the black and smelly river that has been treated, the reconstruction of the water ecosystem and the long-term maintenance of water quality in the later stage are the ultimate goals of the black and smelly river.
为了实现水体水质长效保持,建立良性水生态,必须保证水体有充足的溶氧,同时要建立水体的空间对流、打破水体的溶氧分层,提供充足的微生物生存空间等,同时要最大限度的降低运行成本。基于此,本发明提供了一种能量循环主动对流增氧生态浮岛,该浮岛采用分子级增氧机,对水体进行分子级高效增氧,同时配合氢燃料电池的能量回收以及太阳能发电装置的能量补充,实现高效分子级增氧。In order to achieve long-term maintenance of water quality and establish a benign aquatic ecology, it is necessary to ensure that the water body has sufficient dissolved oxygen. At the same time, it is necessary to establish spatial convection of the water body, break the dissolved oxygen stratification of the water body, and provide sufficient living space for microorganisms. To reduce operating costs. Based on this, the present invention provides an energy cycle active convective oxygen-enhancing ecological floating island. The floating island adopts molecular-level aerators to perform molecular-level high-efficiency oxygenation of water bodies, and at the same time cooperates with the energy recovery of hydrogen fuel cells and solar power generation devices Energy replenishment to achieve high-efficiency molecular-level oxygenation.
发明内容Summary of the invention
本发明的目的是提供一种能量循环主动对流增氧生态浮岛,实现水体高效立体增氧。The purpose of the present invention is to provide an ecological floating island with active convection and oxygenation of energy circulation, which realizes high-efficiency and three-dimensional aeration of water bodies.
为实现上述技术目的,本发明采用如下技术方案:In order to achieve the above technical objectives, the present invention adopts the following technical solutions:
一种能量循环主动对流增氧生态浮岛,包括浮台、至少一个增氧装置、微生物菌床和景观植物;浮台通过固定锚固定在水面;An energy cycle active convection and oxygen-enhancing ecological floating island, comprising a floating platform, at least one aeration device, a microbial fungus bed and landscape plants; the floating platform is fixed on the water surface by a fixed anchor;
所述增氧装置、景观植物固定于浮台上,微生物菌床位于水下,连接浮台下表 面;The aeration device and landscape plants are fixed on the floating platform, and the microbial fungus bed is located underwater and connected to the lower surface of the floating platform;
所述增氧装置包括外壳、驱动装置、氢燃料电池、电解装置和供电装置,所述外壳包括相连的外壳上段和外壳下段;The oxygen increasing device includes a housing, a driving device, a hydrogen fuel cell, an electrolysis device, and a power supply device, and the housing includes an upper housing section and a lower housing section that are connected;
所述驱动装置设置于外壳上段上方,驱动装置传动轴伸入外壳上段内部,连接甩水轮,驱动甩水轮转动;The driving device is arranged above the upper section of the housing, and the drive shaft of the driving device extends into the upper section of the housing, is connected with the water sling wheel, and drives the water sling wheel to rotate;
所述外壳上段外侧壁设有至少一个喷水口,所述喷水口连接喷水管;At least one water spray port is provided on the outer side wall of the upper section of the housing, and the water spray port is connected to a water spray pipe;
所述电解装置包括电解正极、电解负极;外壳上段侧壁内轴向设有若干孔道,孔道内安装电解负极;电解正极固定于外壳上段内腔;每个孔道上设有贯通孔,与外壳上段内腔连通;The electrolysis device includes an electrolytic positive electrode and an electrolytic negative electrode; a plurality of holes are axially provided in the side wall of the upper section of the housing, and the electrolytic negative electrode is installed in the hole; the electrolytic positive electrode is fixed to the inner cavity of the upper section of the housing; Internal cavity communication;
所述氢燃料电池通过氢气回收管路连接电解装置的电解负极,收集电解装置反应生成的氢气,并将反应产生的电能存储至储能装置;The hydrogen fuel cell is connected to the electrolysis negative electrode of the electrolysis device through a hydrogen recovery pipeline, collects the hydrogen generated by the reaction of the electrolysis device, and stores the electric energy generated by the reaction in the energy storage device;
所述供电装置用于给用电装置供电。The power supply device is used to supply power to the electric device.
本发明中所述浮台采用分块连锁布置,块体之间通过咬合连接成浮岛,形成设备载体。In the present invention, the floating platform adopts a block interlocking arrangement, and the blocks are connected to form floating islands through occlusion to form a device carrier.
作为本发明的进一步改进,所述外壳上段顶部封闭,横断面呈圆形,纵断面呈矩形;外壳下段底部开放,横断面呈圆形,纵断面呈等腰梯形。外壳下段可根据实际水域深度,调整长度和底部开口直径,以适应工程需求,水体从外壳下段底部进入增氧设备。外壳采用此设计方式,可在保证足够进水量的同时,使得进水口流速很低,防止对杂物吸附作用,防止杂物进入设备堵塞管路,同时避免将底部的污泥搅动,使水体变的浑浊,影响养殖鱼虾的正常生活。As a further improvement of the present invention, the top of the upper section of the casing is closed, the cross section is circular, and the longitudinal section is rectangular; the bottom of the casing is open, the cross section is circular, and the longitudinal section is an isosceles trapezoid. The lower section of the shell can adjust the length and the diameter of the bottom opening according to the actual depth of the water area to meet the needs of the project. The water body enters the aeration equipment from the bottom of the lower section of the shell. The shell adopts this design method, which can ensure the sufficient water intake while keeping the water inlet flow rate very low, preventing the adsorption of debris, preventing debris from entering the equipment and blocking the pipeline, and avoiding the sludge at the bottom from stirring and changing the water body The turbidity affects the normal life of farmed fish and shrimp.
作为本发明的进一步改进,所述喷水管与外壳上段相切布置,喷水管水平延伸方向与驱动装置转动方向一致。进一步的,所述喷水管与水平面夹角为‐30°~0°;喷水管直径为渐变设计,出水口直径>进水口直径。As a further improvement of the present invention, the water spray pipe is arranged tangentially to the upper section of the housing, and the horizontal extension direction of the water spray pipe is consistent with the rotation direction of the driving device. Further, the angle between the water spray pipe and the horizontal plane is -30° to 0°; the diameter of the water spray pipe is a gradual design, and the diameter of the water outlet>the diameter of the water inlet.
作为本发明的进一步改进,所述贯通孔沿外壳上段径向开设,贯通孔水平高度低于电解负极底部的水平高度。电解负极的底部略高于贯通孔位置,且贯通孔沿径向开设,即垂直于外壳上段侧壁,避免因设备内部高速水流的运行产生负压,将氢气吸入设备内部,从而实现氢气、氧气的高效分离。As a further improvement of the present invention, the through holes are opened radially along the upper section of the casing, and the level of the through holes is lower than the level of the bottom of the electrolytic negative electrode. The bottom of the electrolytic negative electrode is slightly higher than the position of the through hole, and the through hole is opened in the radial direction, that is, perpendicular to the side wall of the upper section of the housing, to avoid negative pressure due to the operation of high-speed water flow inside the equipment, and suck hydrogen into the equipment to achieve hydrogen and oxygen Efficient separation.
作为本发明的进一步改进,所述电解正极为环形结构,固定于甩水轮下方。As a further improvement of the present invention, the electrolysis positive electrode has a ring structure and is fixed under the water spinner.
作为本发明的进一步改进,所述氢燃料电池纵断面为齿轮形设计,增加氢气以 及空气中的氧气与催化剂的接触面积,提高氢燃料电池的反应效率。As a further improvement of the present invention, the longitudinal section of the hydrogen fuel cell is a gear-shaped design, which increases the contact area between hydrogen and oxygen in the air and the catalyst, and improves the reaction efficiency of the hydrogen fuel cell.
作为本发明的进一步改进,所述氢燃料电池由若干电池单元组成,形成燃料电池堆栈,电池单元可根据实际需求,采用并联、串联、串并联等形式布置。As a further improvement of the present invention, the hydrogen fuel cell is composed of several battery cells to form a fuel cell stack. The battery cells can be arranged in parallel, series, series and parallel according to actual needs.
作为本发明的进一步改进,所述氢燃料电池的空气进气口设置空气过滤器,对进入氢燃料电池的空气进行过滤,防止粉尘吸附到氢燃料电池催化剂表面,影响催化剂工作效率。As a further improvement of the present invention, the air inlet of the hydrogen fuel cell is provided with an air filter to filter the air entering the hydrogen fuel cell to prevent dust from being adsorbed on the surface of the hydrogen fuel cell catalyst and affect the efficiency of the catalyst.
作为本发明的进一步改进,所述氢燃料电池的氢气室上部设置进气口,底部设置排气口,排气口采用单向逆止阀控制,只允许气体从氢气室向外排气,不允许外界空气通过下部排气口进入氢气室。氢气室上部设置进气口通入氢气,下部设置排气口,氢气密度小,可以有效的将氢气室内原有的空气以及氢气携带的水汽凝结成的水通过排气口排出,便于后期检修后,快速排空气,保证氢气室内氢气的纯度,提高反应效率。As a further improvement of the present invention, the upper part of the hydrogen chamber of the hydrogen fuel cell is provided with an air inlet, and the bottom is provided with an air outlet. The air outlet is controlled by a one-way check valve, and only gas is allowed to exhaust from the hydrogen chamber. Allow outside air to enter the hydrogen chamber through the lower exhaust port. The upper part of the hydrogen chamber is provided with an air inlet for introducing hydrogen, and the lower part is provided with an exhaust port. The density of hydrogen is small. The water condensed from the original air in the hydrogen chamber and the water vapor carried by the hydrogen can be effectively discharged through the exhaust port, which is convenient for later maintenance. , Quickly exhaust air, ensure the purity of hydrogen in the hydrogen chamber, and improve reaction efficiency.
所述氢燃料电池的空气室通过两个开孔隔离板划分为空气外室和两边的空气内室;所述开孔隔离板斜向上开孔;所述空气外室连接空气过滤器,空气外室和空气过滤器连接处设有单向逆止阀;所述空气内室底部设有若干排气口,排气口采用单向逆止阀控制。The air chamber of the hydrogen fuel cell is divided into an air outer chamber and an air inner chamber on both sides by two perforated separation plates; the perforated separation plate has holes diagonally upward; the air outer chamber is connected to an air filter, and the air A one-way check valve is arranged at the junction of the chamber and the air filter; a number of exhaust ports are arranged at the bottom of the air inner chamber, and the exhaust ports are controlled by a one-way check valve.
作为本发明的进一步改进,所述氢燃料电池的空气室通过两个开孔隔离板划分为空气外室和两边的空气内室;所述开孔隔离板斜向上开孔,迫使空气从外室进入内室时,气流直接吹向氢燃料电池正极侧,提高反应效率。所述空气外室连接空气过滤器,空气外室和空气过滤器连接处设有单向逆止阀,只允许空气自外界进入外室,不允许气体逆行;所述空气内室底部设有若干排气口,排气口采用单向逆止阀控制,只允许空气自空气内室排出,不允许空气逆行。此设计方案可保证燃料电池在非工作状态下,内室处于封闭状态,保证电池内部一定的湿度,防止质子渗透膜含水率过低而导致的反应效率下降以及质子渗透膜失水后收缩引起的质子渗透膜破损。空气内室底部的排气口连接驱动装置的散热风扇,利用驱动装置的散热风扇,将空气吸入氢燃料电池的正极侧,增加空气的吸入量,在保障氢燃料电池的快速高效反应的同时,对燃料电池进行散热。As a further improvement of the present invention, the air chamber of the hydrogen fuel cell is divided into an outer air chamber and an air inner chamber on both sides by two perforated partition plates; the perforated partition plates open holes diagonally upward to force air from the outer chamber When entering the inner chamber, the airflow is directly blown to the positive side of the hydrogen fuel cell to improve the reaction efficiency. The outer air chamber is connected to an air filter, and the connection between the outer air chamber and the air filter is provided with a one-way check valve, which only allows air to enter the outer chamber from the outside, and does not allow gas to retrograde; the bottom of the air inner chamber is provided with several The exhaust port and the exhaust port are controlled by a one-way check valve, which only allows air to be discharged from the air chamber, and does not allow air to flow backwards. This design scheme can ensure that the fuel cell is in a non-working state, the inner chamber is in a closed state, to ensure a certain humidity inside the cell, and to prevent the reduction of reaction efficiency caused by the low water content of the proton permeable membrane and the shrinkage of the proton permeable membrane after loss of water The proton permeable membrane is broken. The exhaust port at the bottom of the air chamber is connected to the heat dissipation fan of the driving device. The heat dissipation fan of the driving device is used to suck air into the positive side of the hydrogen fuel cell to increase the amount of air sucked in. While ensuring the rapid and efficient response of the hydrogen fuel cell, Heat the fuel cell.
作为本发明的进一步改进,所述电解正极设置于甩水轮下部5‐10cm位置,通过固定杆连接外壳上段侧壁内表面,所述固定杆为绝缘材质或和电解正极同材质;电 解正极和电解负极间距控制为2cm左右,电解电压采用12V‐24V的低电压。As a further improvement of the present invention, the electrolytic positive electrode is arranged at a position 5-10 cm from the lower part of the water slinger, and is connected to the inner surface of the side wall of the upper section of the shell through a fixed rod. The fixed rod is made of insulating material or the same material as the electrolytic positive electrode; The electrolysis negative electrode spacing is controlled to be about 2cm, and the electrolysis voltage adopts a low voltage of 12V-24V.
作为本发明的进一步改进,所述浮体选用塑料或泡沫之类轻材质。As a further improvement of the present invention, the floating body is made of light materials such as plastic or foam.
作为本发明的进一步改进,所述外壳上段为绝缘材质。As a further improvement of the present invention, the upper section of the housing is made of insulating material.
作为本发明的进一步改进,所述外壳底部设有拦污网;所述拦污网上开设方形或圆形孔,孔径不大于0.5cm。拦网可防止小鱼或水中杂物进入设备内部,影响设备运行。As a further improvement of the present invention, the bottom of the casing is provided with a dirt blocking net; the dirt blocking net is provided with square or circular holes, and the aperture is not greater than 0.5 cm. Blocking nets can prevent small fish or sundries in the water from entering the equipment and affecting the operation of the equipment.
作为本发明的进一步改进,所述传动轴和甩水轮连接的轴承部位设有防水油封,防止下部的水进入驱动装置。As a further improvement of the present invention, a water-proof oil seal is provided at the bearing part where the transmission shaft and the water slinger are connected to prevent water from the lower part from entering the driving device.
作为本发明的进一步改进,所述驱动装置为防水的直流降速电机。As a further improvement of the present invention, the driving device is a waterproof DC speed reduction motor.
作为本发明的进一步改进,所述供电装置为太阳能供电装置;所述氢燃料电池产生的电能存储于太阳能供电装置的储能装置。As a further improvement of the present invention, the power supply device is a solar power supply device; the electrical energy generated by the hydrogen fuel cell is stored in the energy storage device of the solar power supply device.
作为本发明的进一步改进,所述微生物菌床布置于增氧装置的侧面,保证得到充足的氧气补给。As a further improvement of the present invention, the microbial fungus bed is arranged on the side of the aerator to ensure sufficient oxygen supply.
本发明的浮岛通过增氧装置的驱动装置驱动甩水轮旋转,使得水体形成立体对流,电机启动同时,电解装置通过储能装置供电,对进入设备内部的水进行电解,电解产生的氧气分子被设备内部的高速水流迅速带走并喷射到外部水域,实现分子级增氧,本发明的电解装置中,电解正极放置于外壳内腔中,装置运行时,内部会产生高速水流,将电解正极产生的氧气快速带走,电解负极产生的氢气密度小,在孔道内快速向上聚集,进入回收管路;此外,电解负极的底部略高于贯通孔位置,且贯通孔垂直外壁,避免因设备内部高速水流的运行产生负压,将氢气吸入设备内部,从而实现氢气、氧气的高效分离。电解产生的氢气通过氢气回收管路进入氢燃料电池,经氢燃料电池反应产生电能,补给到储能装置,实现能量循环;太阳能供电装置在阳光作用下产生电能,进一步补给到储能装置以弥补反应过程中的能量损失,以达到能量平衡。微生物菌床布设与浮体下部水体内,为微生物提供良好的生存空间,使污染水体底部富含有机物的污泥在好氧菌的作用下消解,而增氧装置带来的立体对流可加速消解,促进水质修复;浮岛上布设的景观植物则可增加整体美观性,也可采用耐污景观植物促进水质净化,从而使得本发明的浮岛兼具美观、增氧、净化功能,长期运行可提升控制水域整体溶氧,激活水体的活力,辅助构建良性生态平衡,实现控制水域水质提升和能量循环长效保持。The floating island of the present invention drives the water spinner to rotate through the driving device of the aerator to make the water form three-dimensional convection. At the same time as the motor is started, the electrolysis device is powered by the energy storage device to electrolyze the water entering the equipment, and the oxygen molecules generated by the electrolysis It is quickly taken away by the high-speed water flow inside the equipment and sprayed into the external waters to achieve molecular-level oxygen increase. In the electrolysis device of the present invention, the electrolytic positive electrode is placed in the inner cavity of the shell. When the device is running, a high-speed water flow is generated inside the electrolysis positive electrode. The oxygen generated is quickly taken away, and the density of hydrogen generated by the electrolytic negative electrode is small, and it quickly accumulates in the channel and enters the recovery pipeline; in addition, the bottom of the electrolytic negative electrode is slightly higher than the position of the through hole, and the through hole is vertical to the outer wall, avoiding the internal The operation of high-speed water flow generates negative pressure, which sucks hydrogen into the equipment, thereby realizing efficient separation of hydrogen and oxygen. The hydrogen produced by electrolysis enters the hydrogen fuel cell through the hydrogen recovery pipeline, generates electricity through the hydrogen fuel cell reaction, and is supplied to the energy storage device to realize energy circulation; the solar power supply device generates electricity under the action of sunlight, and is further supplied to the energy storage device to compensate Energy loss during the reaction to achieve energy balance. The arrangement of the microbial bacteria bed in the lower water body of the floating body provides a good living space for microorganisms, so that the sludge rich in organic matter at the bottom of the polluted water body is digested under the action of aerobic bacteria, and the three-dimensional convection brought by the aeration device can accelerate the digestion. Promote water quality restoration; landscape plants placed on the floating island can increase the overall aesthetics, and pollution-resistant landscape plants can also be used to promote water purification, so that the floating island of the present invention has the functions of beauty, oxygenation and purification, and can be improved in long-term operation Control the overall dissolved oxygen in the water area, activate the vitality of the water body, assist in the construction of a benign ecological balance, and realize the control of the water quality improvement of the water area and the long-term maintenance of the energy cycle.
附图说明Description of the drawings
图1为本发明浮岛整体结构断面图;Figure 1 is a cross-sectional view of the overall structure of the floating island of the present invention;
其中,100.增氧装置,200.微生物菌床,300.景观植物,18.浮台,19.固定锚。Among them, 100. Aeration device, 200. Microbial bed, 300. Landscape plants, 18. Floating platform, 19. Fixed anchor.
图2为增氧装置结构示意图;Figure 2 is a schematic diagram of the structure of the aerator;
其中,1.驱动装置,2.防水油封,3.传动轴,4.甩水轮,5.氢燃料电池,6.喷水管,7.电解正极,8.电解负极,9.外壳上段,10.法兰,11.外壳下段,12.拦污网,13.氢气回收管路,14.空气过滤器,15.氢燃料电池单元,16.太阳能板,17.储能装置。Among them, 1. Drive device, 2. Waterproof oil seal, 3. Drive shaft, 4. Water spinner, 5. Hydrogen fuel cell, 6. Water spray pipe, 7. Electrolysis positive electrode, 8. Electrolysis negative electrode, 9. Upper section of the housing, 10. Flange, 11. Lower section of the housing, 12. Trash net, 13. Hydrogen recovery pipeline, 14. Air filter, 15. Hydrogen fuel cell unit, 16. Solar panel, 17. Energy storage device.
图3为甩水轮断面图。Figure 3 is a cross-sectional view of the water jet wheel.
图4为氢燃料电池纵断面图;Figure 4 is a longitudinal sectional view of a hydrogen fuel cell;
其中,20.单向逆止阀,21.开孔隔离板,22.抽气口,23.氢气进气口,24.空气排气口,25.氢气室,26.空气内室,27.空气外室。Among them, 20. One-way check valve, 21. Open hole isolation plate, 22. Air extraction port, 23. Hydrogen gas inlet, 24. Air exhaust port, 25. Hydrogen chamber, 26. Air inner chamber, 27. Air Outer room.
图5为氢燃料电池俯视图;Figure 5 is a top view of a hydrogen fuel cell;
其中,28.氢燃料电池外壳。Among them, 28. Hydrogen fuel cell housing.
图6为氢燃料电池单元剖面图;Figure 6 is a sectional view of a hydrogen fuel cell unit;
其中,29.气体扩散层,30.催化剂层,31.质子渗透膜。Among them, 29. Gas diffusion layer, 30. Catalyst layer, 31. Proton permeable membrane.
图7为电解装置剖面结构示意图;Figure 7 is a schematic cross-sectional structure diagram of the electrolysis device;
其中,32.孔道;33.固定杆;34.贯通孔。Among them, 32. Hole; 33. Fixed rod; 34. Through hole.
具体实施方式Detailed ways
下面结合实施例和附图说明对本发明的技术方案做进一步说明。The technical solution of the present invention will be further described below in conjunction with the description of the embodiments and the drawings.
实施例1Example 1
如图1所示的生态浮岛,包括浮台18、至少一个增氧装置100、微生物菌床200和景观植物300;浮台18通过固定锚19固定在水面;增氧装置100、景观植物300固定于浮台18上,微生物菌床200位于水下,连接浮台下表面。The ecological floating island as shown in FIG. 1 includes a floating platform 18, at least one aeration device 100, a microbial fungus bed 200 and landscape plants 300; the floating platform 18 is fixed on the water surface by a fixed anchor 19; the aeration device 100 and landscape plants 300 Fixed on the floating platform 18, the microbial bacteria bed 200 is located underwater and connected to the lower surface of the floating platform.
所述增氧装置100结构如图2~7所示,包括外壳、驱动装置1、氢燃料电池5、电解装置和供电装置,外壳包括通过法兰10相连的外壳上段9和外壳下段11;外壳上段9顶部封闭,横断面呈圆形,纵断面呈矩形;外壳下段11底部开放,横断面呈圆形,纵断面呈等腰梯形。The structure of the oxygen increasing device 100 is shown in Figures 2-7, including a housing, a driving device 1, a hydrogen fuel cell 5, an electrolysis device and a power supply device. The housing includes an upper section 9 and a lower section 11 connected by a flange 10; The top of the upper section 9 is closed, the cross section is circular, and the longitudinal section is rectangular; the bottom of the shell lower section 11 is open, the cross section is circular, and the longitudinal section is an isosceles trapezoid.
驱动装置1为防水的直流降速电机,设置于外壳上段9上方,驱动装置1传动轴3伸入外壳上段9内部,连接甩水轮4,驱动甩水轮4转动。传动轴3和甩水轮4连接的轴承部位设置防水油封2密封,防止水花溅入传动轴3内。甩水轮4为3叶或4叶甩水轮,如图2所示。The driving device 1 is a waterproof DC speed reduction motor, which is arranged above the upper section 9 of the housing. The drive shaft 3 of the driving device 1 extends into the upper section 9 of the housing, and is connected to the water slinger 4 to drive the water slinger 4 to rotate. A waterproof oil seal 2 is arranged at the bearing part where the transmission shaft 3 and the water thrower 4 are connected to prevent water from splashing into the transmission shaft 3. The spur wheel 4 is a three-blade or four-blade spur wheel, as shown in Figure 2.
外壳上段9外侧壁设有至少一个喷水口,喷水口的中心高度与甩水轮4中心高度一致;喷水口连接喷水管6;喷水管6与外壳上段9相切布置,喷水管6水平延伸方向与驱动装置1转动方向一致。喷水管6与水平面夹角为‐30°~0°;喷水管6直径为渐变设计,出水口直径>进水口直径。本实施例中出水口直径为50‐80mm,进水口直径为40‐50mm。The outer side wall of the upper section 9 of the shell is provided with at least one water spout, and the center height of the spout is the same as the center height of the water thrower 4; the spout is connected to the sprinkler pipe 6; The horizontal extension direction of the water pipe 6 is consistent with the rotation direction of the driving device 1. The angle between the water spray pipe 6 and the horizontal plane is -30°~0°; the diameter of the water spray pipe 6 is a gradual design, and the water outlet diameter>the water inlet diameter. In this embodiment, the diameter of the water outlet is 50-80mm, and the diameter of the water inlet is 40-50mm.
电解装置结构如图6所示,包括电解正极7、电解负极8;外壳上段9侧壁内轴向设有若干孔道32,孔道32设计应避开喷水口开口位置;孔道32内安装电解负极8;电解正极7为环形结构,电解正极7设置于甩水轮4下部5‐10cm位置,通过固定杆33连接外壳上段9侧壁内表面,所述固定杆33为绝缘材质或和电解正极同材质;每个孔道32上设有贯通孔34,贯通孔34垂直于外壳侧壁,与外壳上段9内腔连通,使得电解正极7、电解负极8连通,贯通孔34水平高度低于电解负极8底部的水平高度。电解正极和电解负极间距控制为2cm左右,电解电压采用12V‐24V的低电压。The structure of the electrolysis device is shown in Fig. 6, including the electrolysis positive electrode 7 and the electrolysis negative electrode 8. There are a number of holes 32 in the axial direction of the side wall of the upper section 9 of the housing. The holes 32 should be designed to avoid the opening of the water spout; the hole 32 is equipped with the electrolysis negative electrode. 8; The electrolysis positive electrode 7 is a ring structure, the electrolysis positive electrode 7 is set at the 5-10cm position of the lower part of the water spinner 4, and is connected to the inner surface of the side wall of the upper section 9 of the housing through a fixed rod 33. The fixed rod 33 is made of insulating material or the same as the electrolytic positive electrode Material; each channel 32 is provided with a through hole 34, the through hole 34 is perpendicular to the side wall of the housing, and communicates with the inner cavity of the upper section 9 of the housing, so that the electrolytic positive electrode 7 and the electrolytic negative electrode 8 are connected, and the level of the through hole 34 is lower than the electrolytic negative electrode 8. The horizontal height of the bottom. The distance between the electrolysis positive electrode and the electrolysis negative electrode is controlled to be about 2cm, and the electrolysis voltage adopts a low voltage of 12V-24V.
氢燃料电池5通过氢气回收管路13连接电解装置的电解负极8,收集电解装置反应生成的氢气。氢燃料电池5结构如图3~5所示,纵断面为齿轮形。氢燃料电池5可采用现有的氢燃料电池结构,包括氢燃料电池外壳28、设置于外壳内的氢气室25和空气室,氢气室和空气室间设置用于反应的氢燃料电池单元15,其结构包括气体扩散层29、催化剂层30和质子渗透膜31。本实施例中,氢燃料电池的空气室通过两个开孔隔离板21划分为空气外室27和两边的空气内室26;开孔隔离板21斜向上开孔;空气外室27连接空气过滤器14,空气外室27和空气过滤器14连接处设有单向逆止阀20;空气内室26底部设有若干空气排气口24,空气内室底部的空气排气口24连接至驱动装置1的散热风扇,通过抽气口22将空气吸入氢燃料电池的正极侧。空气排气口24采用单向逆止阀20控制。氢燃料电池5的氢气室25上部设置进气口23,底部设置排气口,排气口采用单向逆止阀20控制。The hydrogen fuel cell 5 is connected to the electrolysis negative electrode 8 of the electrolysis device through a hydrogen recovery line 13 to collect the hydrogen generated by the reaction of the electrolysis device. The structure of the hydrogen fuel cell 5 is shown in FIGS. 3 to 5, and the longitudinal section is gear-shaped. The hydrogen fuel cell 5 can adopt the existing hydrogen fuel cell structure, including a hydrogen fuel cell housing 28, a hydrogen chamber 25 and an air chamber arranged in the housing, and a hydrogen fuel cell unit 15 for reaction is arranged between the hydrogen chamber and the air chamber. Its structure includes a gas diffusion layer 29, a catalyst layer 30 and a proton permeable membrane 31. In this embodiment, the air chamber of the hydrogen fuel cell is divided into an outer air chamber 27 and an inner air chamber 26 on both sides by two perforated partition plates 21; the perforated partition plate 21 has holes diagonally upward; the outer air chamber 27 is connected to the air filter A one-way check valve 20 is provided at the junction of the air outer chamber 27 and the air filter 14; a number of air exhaust ports 24 are provided at the bottom of the air inner chamber 26, and the air exhaust ports 24 at the bottom of the air inner chamber are connected to the drive The heat dissipation fan of the device 1 draws air into the anode side of the hydrogen fuel cell through the air suction port 22. The air exhaust port 24 is controlled by a one-way check valve 20. The upper part of the hydrogen chamber 25 of the hydrogen fuel cell 5 is provided with an air inlet 23, and the bottom is provided with an air outlet, and the air outlet is controlled by a one-way check valve 20.
本实施例中,氢燃料电池5由若干电池单元组成,形成燃料电池堆栈,电池单 元间采用并联、串联或串并联形式布置。In this embodiment, the hydrogen fuel cell 5 is composed of several battery cells to form a fuel cell stack, and the battery cells are arranged in parallel, series, or series-parallel.
浮台18选用塑料或泡沫之类轻材质,固定在外壳上段9顶部,使外壳整体位于水下;浮台18通过固定锚19固定。The floating platform 18 is made of light materials such as plastic or foam, and is fixed on the top of the upper section 9 of the shell so that the whole shell is under water; the floating platform 18 is fixed by a fixed anchor 19.
供电装置为太阳能供电装置,包括太阳能板16、储能装置17;氢燃料电池5产生的电能存储于储能装置17。The power supply device is a solar power supply device, including a solar panel 16 and an energy storage device 17; the electrical energy generated by the hydrogen fuel cell 5 is stored in the energy storage device 17.
本实施例中,外壳下段11底部设有拦污网12;拦污网12上开设方形或圆形孔,孔径不大于0.5cm,水体从外壳下段11底部进入增氧装置100。In this embodiment, the bottom of the lower section 11 of the casing is provided with a trash net 12; the trash net 12 is provided with a square or circular hole with a diameter of not more than 0.5 cm. Water enters the aeration device 100 from the bottom of the lower section 11 of the casing.
将浮岛放入水体,接通增氧装置100的电源,在防水直流电机1作用下,带动传动轴3以及甩水轮4旋转,使得下部水体通过拦污网12进入设备内部,同时电解装置启动,对进入设备内部的水进行电解,产生氧气分子被高速水流带走,并喷射到外部水体,实现对水体的分子级增氧。同时电解产生的氢气通过氢气回收管路13进入氢燃料电池5,氢气通过氢气进气口23进入氢气室25,氢气通过气体扩散层29与催化剂层30接触,通过催化,使得氢气分子失去两个电子,变成两个质子,电子无法通过质子渗透膜31,只能由通过电路循环进入燃料电池的正极侧,质子可以顺利通过质子渗透膜31直接达到燃料电池的正极侧,并在催化剂作用下,使空气中的氧分子、通过质子渗透膜31到达正极侧的质子以及外电路循环到达正极侧的电子发生反应,生成水。通过燃料电池反应将化学能转化为电能,实现电解能量的部分回收,并将电能存储于储能装置17,配合太阳能供电装置的电能补充,实现可能量循环的分子级增氧。Put the floating island into the water body, turn on the power supply of the aerator 100, drive the drive shaft 3 and the water thrower 4 to rotate under the action of the waterproof DC motor 1, so that the lower body of water enters the equipment through the trash net 12, and the electrolysis device Start up, electrolyze the water entering the equipment, and generate oxygen molecules that are taken away by the high-speed water flow and sprayed to the external water body to achieve molecular-level oxygen increase in the water body. At the same time, the hydrogen produced by the electrolysis enters the hydrogen fuel cell 5 through the hydrogen recovery pipeline 13, and the hydrogen enters the hydrogen chamber 25 through the hydrogen gas inlet 23. The hydrogen passes through the gas diffusion layer 29 and contacts the catalyst layer 30. Through catalysis, the hydrogen molecules lose two The electrons become two protons. The electrons cannot pass through the proton permeable membrane 31 and can only enter the anode side of the fuel cell by circulating through the circuit. The protons can smoothly pass through the proton permeable membrane 31 and directly reach the anode side of the fuel cell, and are under the action of the catalyst. , The oxygen molecules in the air, the protons that reach the positive electrode side through the proton permeable membrane 31, and the electrons that circulate to the positive electrode side through the external circuit react to generate water. The chemical energy is converted into electrical energy through the reaction of the fuel cell to realize partial recovery of electrolytic energy, and the electrical energy is stored in the energy storage device 17 to cooperate with the electrical energy supplement of the solar power supply device to realize the molecular-level oxygen enrichment of possible quantity circulation.
浮岛运行过程中,微生物菌床200为微生物提供了良好的生存空间,同时微生物菌床200位于增氧装置100侧面,可保证得到充足的氧气补给,增氧装置100在运行过程中,把水体底部富营养物质通过循环水流带向微生物菌床200,大大提高了微生物净化水质的效率。During the operation of the floating island, the microbial bacteria bed 200 provides a good living space for microorganisms. At the same time, the microbial bacteria bed 200 is located on the side of the aerator 100, which can ensure sufficient oxygen supply. The aerator 100 protects the water body during operation. The nutrient-rich substances at the bottom are brought to the microbial fungus bed 200 through the circulating water flow, which greatly improves the efficiency of microbial water purification.
浮台18上部布设景观植物300,在景观植物300生长过程中吸收水中污染物的同时,也起到了美化水环境的作用。 Landscape plants 300 are arranged on the upper part of the floating platform 18, which not only absorb pollutants in the water during the growth process of the landscape plants 300, but also play a role in beautifying the water environment.
以上所述为本发明的优选实施实例,并不用于限制不发明,对于本领域技术人员,可以参照本发明详细说明,对前述各功能部件的技术方案进行修改,或者对其中部分技术特征进行等同替换,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above are the preferred implementation examples of the present invention and are not intended to limit the invention. For those skilled in the art, referring to the detailed description of the present invention, the technical solutions of the aforementioned functional components can be modified, or some of the technical features can be equivalent. Replacement, any modification, equivalent replacement, improvement, etc., made within the spirit and principle of the present invention shall be included in the protection scope of the present invention.

Claims (10)

  1. 一种能量循环主动对流增氧生态浮岛,其特征在于,包括浮台(18)、至少一个增氧装置(100)、微生物菌床(200)和景观植物(300);浮台(18)通过固定锚(19)固定在水面;An energy cycle active convection and oxygen-enhancing ecological floating island, which is characterized by comprising a floating platform (18), at least one aeration device (100), a microbial fungus bed (200) and landscape plants (300); the floating platform (18) Fixed on the water surface by a fixed anchor (19);
    所述增氧装置(100)、景观植物(300)固定于浮台(18)上,微生物菌床(200)位于水下,连接浮台下表面;The aeration device (100) and landscape plants (300) are fixed on the floating platform (18), and the microbial fungus bed (200) is located underwater and connected to the lower surface of the floating platform;
    所述增氧装置(100)包括外壳、驱动装置(1)、氢燃料电池(5)、电解装置、供电装置和储能装置(17),所述外壳包括相连的外壳上段(9)和外壳下段(11),外壳整体位于水下;The oxygen increasing device (100) includes a housing, a driving device (1), a hydrogen fuel cell (5), an electrolysis device, a power supply device, and an energy storage device (17), and the housing includes a connected housing upper section (9) and a housing In the lower section (11), the whole shell is located underwater;
    所述驱动装置(1)设置于外壳上段(9)上方,驱动装置(1)传动轴(3)伸入外壳上段(9)内部,连接甩水轮(4),驱动甩水轮(4)转动;The driving device (1) is arranged above the upper section (9) of the housing, and the drive shaft (3) of the driving device (1) extends into the upper section (9) of the housing, is connected to the water slinger (4), and drives the water slinger (4) Rotate
    所述外壳上段(9)外侧壁设有至少一个喷水口,所述喷水口连接喷水管(6);The outer side wall of the upper section (9) of the housing is provided with at least one water spray port, and the water spray port is connected with a water spray pipe (6);
    所述电解装置包括电解正极(7)、电解负极(8);外壳上段(9)侧壁内轴向设有若干孔道(32),孔道(32)内安装电解负极(8);电解正极(7)固定于外壳上段(9)内腔;每个孔道(32)上设有贯通孔(34),与外壳上段(9)内腔连通;The electrolysis device includes an electrolysis positive electrode (7) and an electrolysis negative electrode (8); a number of holes (32) are axially provided in the side wall of the upper section (9) of the housing, and the electrolysis negative electrode (8) is installed in the hole (32); 7) It is fixed to the inner cavity of the upper section (9) of the housing; each channel (32) is provided with a through hole (34) which communicates with the inner cavity of the upper section (9) of the housing;
    所述氢燃料电池(5)通过氢气回收管路(13)连接电解装置的电解负极(8),收集电解装置反应生成的氢气,并将反应产生的电能存储至储能装置(17);The hydrogen fuel cell (5) is connected to the electrolysis negative electrode (8) of the electrolysis device through a hydrogen recovery pipeline (13), collects the hydrogen generated by the reaction of the electrolysis device, and stores the electric energy generated by the reaction to the energy storage device (17);
    所述供电装置用于给用电装置供电。The power supply device is used to supply power to the electric device.
  2. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述外壳上段(9)顶部封闭,横断面呈圆形,纵断面呈矩形;外壳下段(11)底部开放,横断面呈圆形,纵断面呈等腰梯形。The active convection and oxygen-enhancing ecological floating island for energy circulation according to claim 1, characterized in that the top of the upper shell (9) is closed, the cross section is circular, and the vertical section is rectangular; the bottom of the shell lower section (11) It is open with a circular cross section and an isosceles trapezoid in vertical section.
  3. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述喷水管(6)与外壳上段(9)相切布置,喷水管(6)水平延伸方向与驱动装置(1)转动方向一致。The energy cycle active convection and oxygen-enhancing ecological floating island according to claim 1, wherein the water spray pipe (6) is arranged tangentially to the upper section (9) of the housing, and the water spray pipe (6) extends horizontally. It is consistent with the rotation direction of the driving device (1).
  4. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述喷水管(6)与水平面夹角为‐30°~0°;喷水管(6)直径为渐变设计,出水口直径>进水口直径。The energy cycle active convection and oxygen-enhancing ecological floating island according to claim 1, wherein the angle between the water spray pipe (6) and the horizontal plane is -30°~0°; the diameter of the water spray pipe (6) For a gradual design, the outlet diameter>the inlet diameter.
  5. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在 于,所述贯通孔(34)沿外壳上段(9)径向开设,贯通孔(34)水平高度低于电解负极(8)底部的水平高度。The energy cycle active convection and oxygen-enhancing ecological floating island according to claim 1, wherein the through holes (34) are radially opened along the upper section (9) of the housing, and the level of the through holes (34) is lower than that of the electrolysis The level of the bottom of the negative electrode (8).
  6. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述电解正极(7)为环形结构,固定于甩水轮(4)下方。The energy cycle active convection and oxygen-enhancing ecological floating island according to claim 1, wherein the electrolysis anode (7) has a ring structure and is fixed under the water slinger (4).
  7. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述氢燃料电池(5)纵断面为齿轮形。The energy cycle active convection and oxygen-enhancing ecological floating island according to claim 1, wherein the longitudinal section of the hydrogen fuel cell (5) is gear-shaped.
  8. 根据权利要求1或7所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述氢燃料电池(5)由若干电池单元组成,形成燃料电池堆栈,电池单元间采用并联、串联或串并联形式布置。An energy cycle active convection oxygen-enhancing ecological floating island according to claim 1 or 7, characterized in that the hydrogen fuel cell (5) is composed of several battery cells to form a fuel cell stack, and the battery cells are connected in parallel, Arranged in series or series-parallel.
  9. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述氢燃料电池(5)的氢气室(25)上部设置进气口(23),底部设置排气口,排气口采用单向逆止阀(20)控制。An energy cycle active convection oxygen-enhancing ecological floating island according to claim 1, wherein the upper part of the hydrogen chamber (25) of the hydrogen fuel cell (5) is provided with an air inlet (23) and an exhaust port (23) is provided at the bottom. The exhaust port is controlled by a one-way check valve (20).
  10. 根据权利要求1所述的一种能量循环主动对流增氧生态浮岛,其特征在于,所述氢燃料电池的空气室通过两个开孔隔离板(21)划分为空气外室(27)和两边的空气内室(26);所述开孔隔离板(21)斜向上开孔;所述空气外室(27)连接空气过滤器(14),空气外室(27)和空气过滤器(14)连接处设有单向逆止阀(20);所述空气内室(26)底部设有若干排气口(24),空气内室底部的排气口(24)连接至驱动装置(1)的散热风扇,排气口(24)采用单向逆止阀(20)控制。An energy cycle active convection oxygen-enhancing ecological floating island according to claim 1, wherein the air chamber of the hydrogen fuel cell is divided into an air outer chamber (27) and an air chamber (27) by two perforated isolation plates (21). The air inner chambers (26) on both sides; the perforated isolation plate (21) is opened obliquely upward; the air outer chamber (27) is connected to the air filter (14), the air outer chamber (27) and the air filter ( 14) A one-way check valve (20) is provided at the connection; a number of exhaust ports (24) are provided at the bottom of the air inner chamber (26), and the exhaust port (24) at the bottom of the air inner chamber is connected to the driving device ( 1) For the cooling fan, the exhaust port (24) is controlled by a one-way check valve (20).
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