WO2023124203A1 - Inverted a2/o-gdmbr integrated village and town sewage treatment apparatus with external electric field, and sewage treatment method thereof - Google Patents
Inverted a2/o-gdmbr integrated village and town sewage treatment apparatus with external electric field, and sewage treatment method thereof Download PDFInfo
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- WO2023124203A1 WO2023124203A1 PCT/CN2022/117406 CN2022117406W WO2023124203A1 WO 2023124203 A1 WO2023124203 A1 WO 2023124203A1 CN 2022117406 W CN2022117406 W CN 2022117406W WO 2023124203 A1 WO2023124203 A1 WO 2023124203A1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/48—Treatment of water, waste water, or sewage with magnetic or electric fields
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Definitions
- the invention belongs to the technical field of village and town sewage treatment, and relates to an inverted A 2 /O-GDMBR integrated village and town sewage treatment device and method with an external electric field.
- rural sewage treatment technology must be mobile, flexible, easy to operate, low energy consumption, low maintenance, no need for special supervision, and can realize unmanned
- the process characteristics such as long-term stable operation under on-duty conditions can effectively solve the problem of rural sewage treatment in my country.
- the existing membrane bioreactor is a new type of high-efficiency sewage treatment technology that combines sewage biological treatment with membrane separation. It has the advantages of good sewage treatment effect, small footprint, high degree of automation, and low sludge yield. And other advantages, it can be used as the preferred process for sewage treatment in villages and towns.
- MBR membrane bioreactor
- the traditional single MBR process is unsatisfactory in terms of synchronous denitrification and phosphorus removal, and the membrane fouling is serious, requiring frequent cleaning; in the process of operation, long-term high-intensity aeration, frequent hydraulic backwashing and regular Chemical cleaning, which will bring greater energy consumption and higher operating costs. Therefore, it is necessary to design a novel sewage treatment device to solve the above problems.
- the present invention aims to propose an inverted A 2 /O-GDMBR integrated village and town sewage treatment device and method with an external electric field.
- one gas and three functions are realized, namely, aeration, oxygenation, and nitrification liquid circulation. It integrates the three functions of sludge reflux and adopts the rotary microelectrode to provide low-voltage regulation to microorganisms while realizing gas-liquid-solid three-phase rapid separation function to strengthen nitrogen and phosphorus removal. It has high water purification efficiency, low energy consumption, and easy operation.
- the advantage of simplicity is a reliable process for solving rural sewage treatment in the future.
- An inverted A 2 /O-GDMBR integrated village and town sewage treatment device with an external electric field including an inverted A 2 /O box shell, cathode electrode, anode electrode, mechanical stirring and lifting mechanism, first aeration component, adjustable angle barrier plate, inclined deflector, curved deflector, GDMBR box, membrane module, second aeration module, water collection tank, air pump, return pump and solar power supply device, the inverted A 2 /O box shell
- the GDMBR box is an open top box, and the air pump, return pump and solar power supply device are all arranged outside the inverted A 2 /O box shell, and the water collection tank Set outside the GDMBR box, the air pump, anode electrode, cathode electrode, mechanical stirring lifting mechanism and return pump are all powered by solar power supply devices;
- the interior of the inverted A 2 /O box shell is divided into anoxic zone, anaerobic zone and aerobic zone sequentially by the first partition and the second partition arranged in parallel inside the inverted A 2 /O box shell, said The upper end of the first partition is arranged higher than the upper end of the second partition, the anoxic zone communicates with the bottom of the anaerobic zone, the upper part of the anaerobic zone communicates with the aerobic zone, and the upper part of the anoxic zone passes through
- the water inlet is connected with the external water inlet pipe, the cathode electrode is arranged in the anoxic zone, the anode electrode is arranged in the cathode electrode, and the mechanical stirring lifting mechanism is arranged in the anaerobic zone;
- the first aeration assembly is set in the aerobic zone, the upper end of the inclined deflector is fixedly connected to the upper end of the first partition, and the lower end of the inclined deflector extends into the aerobic zone and the adjustable angle baffle
- the upper end of the curved deflector is fixed on the top wall of the housing, and the lower end is a free end.
- the interior of the GDMBR box is divided into a conditioning area and a membrane filtration area by two partitions arranged staggered in the GDMBR box.
- the upper outlet of the aerobic area is connected to the upper part of the conditioning area through a connecting pipe, and the bottom of the conditioning area is through a return pipe.
- the second aeration module and the membrane module are arranged in the membrane filtration area, and the second aeration module is arranged under the membrane module, and the outlet pipe of the membrane module is connected to the water collection tank, and the membrane module
- An exhaust assembly and a water outlet valve are arranged on the water outlet pipe of the assembly, the air inlet pipe of the first aeration assembly and the air inlet pipe of the second aeration assembly are connected with an air pump, and an air inlet pipe is provided on the air inlet pipe. valve;
- the first aeration component When the first aeration component is aerated, part of the sludge and liquid in the aerobic zone will flow back to the anoxic zone along the return channel, and the other part of the mixed liquid will enter the adjustment area through the connecting pipe after passing through the inclined fender, and the sediment in the adjustment area Part of the sludge returns to the upper part of the anoxic zone through the return pipe and the return pump, and part of it is discharged regularly; the mixed solution pre-sedimented in the adjustment zone enters the membrane filtration zone, driven by gravity, the mixed solution is filtered through the membrane module, and the water is discharged After entering the water collection tank, the second aeration component aerates and scours the membrane components.
- the return channel is connected to the return port of the anoxic area, and the return port is arranged directly opposite to the water inlet of the inverted A 2 /O box shell; an exhaust port is provided on the top of the anoxic area, and the exhaust port is higher than the top of the pool 30-200cm.
- inclined fenders are provided at the bottom of the anoxic zone, the bottom of the anaerobic zone, the bottom of the aerobic zone, the bottom of the regulating zone and the bottom of the membrane filtration zone.
- the lower end of the inclined deflector is hinged to the upper end of the adjustable angle baffle, and the circulation and reflux ratio is controlled by adjusting the opening and closing angle of the adjustable angle baffle.
- the distance between the cathode electrode and the anode electrode is 0.3-10cm;
- the material of the cathode electrode is carbon cloth, carbon felt or graphite plate carbon-based material and stainless steel mesh, nickel foam or titanium plate non-precious metal material;
- the anode electrode The material is graphite carbon brush, graphite rod, graphite plate or carbon felt carbon-based material;
- the electrode adopts a rotary structure, and the cylindrical shape formed by the cathode electrode maintains a fixed distance from the anode electrode.
- the solar power supply device is electrically connected to a controller, and the controller is electrically connected to the cathode electrode and the anode electrode, and the applied voltage is controlled to be 0.1-5.0V.
- the mechanical agitation and lifting mechanism in the anaerobic zone strengthens the push flow, it is opened, and the first aeration component is installed at the bottom of the aerobic zone, and the aeration provides the driving force of the airflow while controlling the dissolved oxygen at 2-4mg/L;
- the bottom of the membrane filtration area is equipped with a second aeration component, which is programmed to aerate and form microbubbles to oxygenate and flush the membrane components.
- a perforated sludge discharge pipe is respectively provided at the bottom of the aerobic zone, the bottom of the adjustment zone and the bottom of the membrane filtration zone, and a vent valve is provided on each perforated sludge discharge pipe; the perforated sludge discharge pipe And the vent valve is used to discharge the sedimented mud in the device; part of the sludge in the conditioning area is periodically returned to the anoxic area.
- the GDMBR adopts a submerged membrane module, which can be a flat membrane or a hollow fiber membrane, and the material can be cellulose acetate, cellulose acetate, polyethylene, polysulfone or polyamide; the membrane module adopts Driven by low-pressure gravity flow, the working pressure is 5-100KPa, without hydraulic cleaning and chemical cleaning devices, and the water is continuously discharged.
- a sewage treatment method of an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field specifically comprising the following steps:
- the raw water to be treated enters the anoxic zone of the device from the water inlet, flows through the low-voltage electric field formed by the cathode electrode and the anode electrode, and then enters the anaerobic zone from the bottom of the first partition, and then the water is lifted by the mechanical agitation lifting mechanism.
- the raw water to be treated and the return sludge deposited in the conditioning area enter the anoxic area of the device from the water inlet, and the sludge and return liquid returned from the aerobic area through the return channel pass through the cathode stainless steel mesh and the anode carbon brush together.
- the effect of the low-voltage electric field the mixed water after the action of the low-voltage electric field enters the anaerobic zone from the bottom of the first partition, and then is lifted by the mechanical stirring lifting mechanism to lift the mixed water from the top of the second partition into the aerobic zone.
- a part of the sludge and reflux liquid is returned to the anoxic zone through the reflux channel to rejoin the raw water to be treated newly entering the device; another part of the sludge and reflux liquid is again passed through
- the large-angle inclined fender enters the GDMBR tank through the connecting pipe, and the sludge deposited in the adjustment area flows back to the upper part of the anoxic area through the return pipe and the return pump to rejoin the raw water to be treated in the newly entered device;
- the pre-sedimented mixed solution in the conditioning area is filtered through the membrane module and then enters the water collection tank from the outlet pipe; such a circulation backflow finally completes the treatment of sewage;
- the aeration of the first aeration assembly and the second aeration assembly is stopped for a period of time, and the perforated mud discharge pipe is opened to discharge the mud, and the device restarts after the mud discharge is completed.
- the inverted A 2 /O-GDMBR integrated village sewage treatment device with external electric field described in the present invention has the following advantages:
- the device applies a low-intensity electric field (0.1-5.0V) in the anoxic area to realize the mutual conversion between biological energy, chemical energy and electrical energy, and regulate the metabolic behavior, physiological function, cell morphology and surface characteristics of microorganisms.
- a low-intensity electric field 0.1-5.0V
- the device applies a low-intensity electric field (0.1-5.0V) in the anoxic area to realize the mutual conversion between biological energy, chemical energy and electrical energy, and regulate the metabolic behavior, physiological function, cell morphology and surface characteristics of microorganisms.
- 0.1-5.0V low-intensity electric field
- the cathode and anode of the device can be made of a variety of electrode materials, and have a wide range of applications. Different from traditional common electrodes, this device adopts a rotary structure electrode, so that the anode electrode can not only transfer electrons but also have a large contact area with the mixed solution, and also It can play the function of quick separation of gas-liquid-solid three-phase, degas quickly, reduce dissolved oxygen, promote the denitrification process, and the gas is discharged from the exhaust port; the cylindrical shape formed by the cathode electrode maintains a fixed small distance from the anode , improve electron transfer efficiency.
- the device can use a mechanical stirring lifting mechanism or a push-flow device to mix and lift the mixed liquid in the anaerobic zone to promote anaerobic denitrification and phosphorus release.
- the device arranges aeration facilities in the aerobic area, and the tiny air bubbles produced oxygenate the aerobic area, providing sufficient dissolved oxygen of about 2-4 mg/L for microorganisms, and promoting microbial nitrification and phosphorus absorption;
- the gas also provides power for the nitrifying liquid and the return flow of the sludge.
- the device is equipped with an arc-shaped deflector on the upper part of the aerobic area to realize the adjustment of the movement law of water and gas, and achieve the purpose of one gas with three functions (oxygenation, sludge return, and digestive liquid circulation).
- the mixture escapes from the outlet, and the mixed liquid is smoothly returned to the anoxic zone under the push of the airflow to mix with the raw water and the return sludge.
- the device is equipped with an inclined deflector in the middle and upper part of the anaerobic zone, and the nitrifying liquid flows back to the anoxic zone through the internal return channel.
- the high flow rate and the disturbance of air bubbles make the influent quickly and evenly distributed; at the same time, the high concentration of organic matter in the influent can quickly consume the dissolved oxygen in the water and promote the rapid formation of an anaerobic environment.
- the device is equipped with an inclined fender with a slightly larger angle at the lower part of the aerobic zone.
- the large angle can effectively prevent the sludge from floating up, realize good sedimentation conditions, minimize the sludge entering the GDMBR tank with the effluent, and ensure the inverted A 2 /O
- the sludge concentration in the tank is stable and the subsequent membrane fouling is reduced.
- the device is equipped with a regulating area in the GDMBR, and the influent water is pre-sedimented first to reduce the amount of sludge entering the membrane filtration area to reduce membrane pollution.
- the device adopts submerged membrane modules, which can be used in various types such as flat membranes and hollow fiber membranes, and various materials such as cellulose acetate, cellulose acetate ester, polyethylene, polysulfone or polyamide.
- the membrane has a wide range of applications, and the device is compact and small in size; the high-efficiency interception effect of the membrane enables microbial interception in the reactor to achieve complete separation of hydraulic retention time (HRT) 6-8h and sludge age (SRT) 5-15d , so that the operation control is more flexible and stable; the concentration of microorganisms in the device is high, and the impact load resistance is strong.
- HRT hydraulic retention time
- SRT sludge age
- the membrane module of the device is driven by low-pressure gravity flow, the working pressure is 5-100KPa, the power consumption of the outlet water is low, the energy consumption is saved, and the requirements for the inlet water pressure of equipment, pipelines and accessories are reduced.
- the device adopts a filtration mode without hydraulic cleaning and chemical cleaning. Compared with the traditional MBR process, which requires regular cleaning and complicated operation and maintenance, it greatly reduces operating costs and workload; at the same time, it does not inhibit the growth of microorganisms on the surface of the membrane module. And use the action of microorganisms to strengthen the removal effect of pollutants, improve the quality of effluent water, alleviate membrane fouling, and increase water production.
- the device uses procedural aeration measures to clean the membrane modules, sustainable, intermittent or pulse aeration, which can effectively control membrane fouling while saving aeration energy consumption; and adopts a microbubble aeration device to obtain Higher cross flow velocity and lower rising resistance, good cleaning effect on the membrane components without damaging the membrane components.
- the device adopts a special exhaust device to remove the gas accumulated in the pipeline, which can be manually or automatically exhausted to ensure smooth water outlet.
- the exhaust device can directly observe and detect the gas accumulation in the pipeline, has a good exhaust effect, is more intuitive than ordinary exhaust valves, reduces the number of exhausts, and simplifies the operation process.
- the device uses a solar battery integrated power supply system to provide the electric energy required by the external electric field, aeration device, and mechanical stirring and lifting mechanism, which is green and environmentally friendly. not functioning properly.
- Fig. 1 is a schematic structural diagram of an inverted A 2 /O-GDMBR integrated village sewage treatment device with applied electric field according to an embodiment of the present invention.
- A-anoxic zone B-anaerobic zone, C-aerobic zone, D-regulation zone, E-membrane filter zone;
- an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field the device adds sewage to be treated in the device during sewage treatment, including an inverted A 2 /O box shell 17, a cathode Electrode 3, anode electrode 4, mechanical stirring lifting mechanism 7, first aeration assembly 9, adjustable angle baffle 11, inclined deflector 12, arc deflector 16, GDMBR box 34, membrane module 27, the second Two aeration components 35, water collection tank 31, air pump 21, return pump 25 and solar power supply device 20,
- the inverted A 2 /O box shell 17 is a sealed box shell, in a micro-pressure state, which can strengthen oxygen Solubility and the mass transfer efficiency of pollutants strengthen the removal efficiency of pollutants;
- the GDMBR box 34 is an open box at the top, and the air pump 21, the return pump 25 and the solar power supply device 20 are all arranged on the inverted A 2 /O outside the box shell 17, the water collection tank 31 is arranged on the outside of the GDMBR box 34, the air pump 21, the an
- the inside of the inverted A 2 /O box shell 17 is sequentially divided into anoxic zone A, anaerobic zone B and In the aerobic zone C, the upper end of the first partition 5 is arranged higher than the upper end of the second partition 8, the anoxic zone A communicates with the bottom of the anaerobic zone B, and the upper part of the anaerobic zone B is connected to the aerobic zone B.
- the oxygen zone C is connected, the upper part of the anoxic zone A is communicated with the external water inlet pipe through the water inlet 15, the cathode electrode 3 is set in the anoxic zone A, and the anode electrode 4 is set in the cathode electrode 3 , the mechanical stirring lifting mechanism 7 is set in the anaerobic zone B;
- the first aeration assembly 9 is set in the aerobic zone C, the inclined deflector 12 is arranged at an angle of 30° with the horizontal direction, and the upper end of the inclined deflector 12 is in contact with the first separator 5
- the upper end of the inclined deflector 12 is fixedly connected, the lower end of the inclined deflector 12 extends into the aerobic zone C and is connected with the upper end of the adjustable angle baffle 11, the upper end of the arc deflector is fixed on the top wall of the housing, and the lower end is a free end , the return channel 13 is formed between the inclined deflector 12, the adjustable angle baffle 11, the top wall of the housing and the arc deflector 16;
- the inside of the GDMBR box 34 is divided into a conditioning area D and a membrane filtration area E by two partitions staggered in the GDMBR box 34, and the upper water outlet of the aerobic area C communicates with the upper part of the conditioning area D through a connecting pipe 24 , the bottom of the adjustment zone D communicates with the upper part of the anoxic zone A through the return pipe, the second aeration assembly 35 and the membrane assembly 27 are all arranged in the membrane filtration area E, and the second aeration assembly 35 is arranged in the membrane assembly 27, the water outlet pipe of the membrane module 27 communicates with the water collection tank 31, and the exhaust assembly 29 and the water outlet valve 30 are arranged on the water outlet pipe of the membrane module 27.
- the air inlet pipe of the first aeration assembly 9 and the second The air inlet pipes of the aeration module 35 are all connected to the air pump 21, and an air valve 22 is arranged on the air inlet pipe;
- the membrane module 27, namely GDMBR adopts a submerged membrane module, which is a flat membrane or a hollow fiber membrane, and the material can be: acetic acid
- the working pressure of cellulose, cellulose acetate, polyethylene, polysulfone or polyamide is provided by the gravity head of water, about 5-100kPa, and the membrane module 27 is not provided with hydraulic cleaning and chemical cleaning devices, and continuous water (also It can run intermittently);
- the exhaust assembly 29 can be a manual exhaust valve or an exhaust valve for timing exhaust, and the exhaust valve can be opened manually (once every 8-12 hours) or automatically to remove the accumulated gas in the pipeline to ensure smooth water outlet;
- the first aeration component 9 aerates, part of the sludge and liquid in the aerobic zone C flows back to the anoxic zone A along the return channel 13, and the other part of the mixed liquid enters the adjustment zone D through the connecting pipe 24 after passing through the inclined fender , part of the sedimented sludge in the adjustment area D is returned to the upper part of the anoxic area A through the return pipe 26 and the return pump 25, and part of it is discharged regularly; the mixed solution pre-settled in the adjustment area D enters the membrane filtration area E, and is Driven by the driving force, the mixed liquid is filtered through the membrane module 27, and the effluent enters the water collection tank 31, and the second aeration module 35 aerates and scours the membrane module 27.
- the shell 17 of the inverted A 2 /O box is sealed and opened when the mechanical agitation lifting mechanism in the anaerobic zone B strengthens the push flow, and the first aeration component is installed at the bottom of the aerobic zone C to control the dissolved oxygen at 2-4mg/L At the same time, the aeration provides the driving force of the airflow; a second aeration component is installed at the bottom of the membrane filtration area E, and the program aerates to form microbubbles to oxygenate and flush the membrane components.
- This application adopts the inverted A 2 /O coupled GDMBR process, and through the research and development of a new configuration, it realizes three functions of one gas and three functions, that is, integrates three functions of aeration and oxygenation, nitrification liquid circulation and sludge return, saving energy consumption; building an external source of weak electricity Field-mediated, the negative and positive poles are built in a rotary structure, the outer cylinder is the cathode, and the anode is placed in the center of the cathode.
- the cylinder placement increases the contact area between microorganisms and electrodes, and increases the utilization efficiency of electrons, thereby promoting denitrification speed, Improve denitrification efficiency; microorganisms in low-voltage electric field have metabolic behavior, physiological functions, cell morphology and surface characteristics change, increase the diversity of microbial communities, change the properties of sludge mixture, thereby reducing membrane pollution; adopt gravity flow membrane filtration System (Gravity Driven Membrane system, GDM), the filtration head is much smaller than the filtration head required by traditional membrane filtration equipment, the pressure is only provided by the gravity of the water, and no pump is needed for suction, so the energy consumption is low during operation; no hydraulic reaction is required Flushing and chemical cleaning, so the operation is simple, and the operation and maintenance management is convenient.
- GDM Gravity Driven Membrane system
- the backflow channel 13 is connected to the backflow port 14 of the anoxic zone A, and the backflow port 14 is arranged directly opposite to the water inlet 15 of the inverted A 2 /O box shell 17, and the flow rate of the backflow liquid and the disturbance of the air bubbles are used to quickly and evenly distribute the water inflow ;
- the high concentration of organic matter in the influent can quickly consume the dissolved oxygen in the water and promote the rapid formation of an anaerobic environment.
- Inclined fenders are provided at the bottom of the anoxic zone A, the bottom of the anaerobic zone B, the bottom of the aerobic zone C, the bottom of the regulating zone D and the bottom of the membrane filtration zone E.
- an inclined fender 6 is respectively provided at the bottom of the anoxic area A and the bottom of the anaerobic area B, and the inclined fenders in the two areas are arranged facing each other; at the bottom of the aerobic area C, two A slanted fender facing to each other, and the fender at the bottom of the aerobic zone C is vertically arranged with the space of the fender in the anoxic zone A, and on the side wall of the aerobic zone C, there is a Fenders, for water flow to the GDMBR box 34, two inclined fenders are symmetrically arranged at the bottom of the adjustment area D, and two inclined fenders are symmetrically arranged at the bottom of the membrane filtration area E; the adjustment area D and the membrane filter The fender space in area E is arranged
- the mud on the inclined fender slides down from the inclined plate and falls into anaerobic area B or aerobic area C , Regulating area D, and membrane filtration area E, slowly deposit and accumulate, and finally collect and discharge through the perforated mud discharge pipe.
- the lower end of the inclined deflector 12 is hinged to the upper end of the adjustable angle baffle 11, and the circulation and reflux ratio is controlled by adjusting the opening and closing angle of the adjustable angle baffle 11; the fluid flow is changed by adjusting the opening and closing angle of the baffle. State and flow field, so as to change different circulating reflux ratios.
- the reflux ratio is controlled at a circulating reflux ratio of 0.5:1-3:1; in order to cope with the impact of changes in water quality, water quantity and temperature on denitrification, and maintain optimal operation state.
- a water inlet valve 2 and a check valve 1 are respectively arranged on the external water inlet pipe, the connecting pipe 24 and the return pipe 26 , and a liquid flow meter 28 is also arranged on the water outlet pipe of the membrane module 27 .
- a gas flow meter 23 is also provided on the air intake pipe of the aeration assembly.
- An exhaust port 18 is provided on the top of the anoxic zone A, and the exhaust port is 30-200 cm higher than the pool top; an overflow pipe 32 is connected to the upper part of the GDMBR box body 34 .
- the bottom of the conditioning zone D and the bottom of the membrane filtration zone E are respectively provided with a perforated mud discharge pipe 10, and a vent valve 33 is provided on each perforated mud discharge pipe 10; the perforated The mud discharge pipe 10 and the vent valve 33 are used to discharge the settled mud in the device.
- the solar power supply device 20 is electrically connected to the controller 19, and the controller 19 is electrically connected to the cathode electrode 3 and the anode electrode 4; the electric energy is provided by the solar power supply device, and the electrode volume occupies the space of the anaerobic zone as much as possible, and the material of the cathode electrode adopts Carbon cloth, carbon felt or graphite plate carbon-based material and stainless steel mesh, nickel foam or titanium plate are non-precious metal materials; the anode electrode material is graphite carbon brush, graphite rod, graphite plate or carbon felt carbon-based material; the electrode adopts a rotary structure , the cylindrical shape formed by the cathode electrode keeps a fixed distance from the anode electrode; and the distance between the stainless steel mesh cathode and the graphite carbon brush anode is 0.3-10cm.
- a sewage treatment method of an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field specifically comprising the following steps:
- the angle of the adjustable angle baffle 11 applies a low pressure of 0.1-5.0V to the cathode stainless steel mesh and the anode carbon brush in the anoxic zone, and the raw water to be treated enters the anoxic zone A of the device from the water inlet 15, After the flow passes through the low-voltage electric field formed by the cathode electrode 3 and the anode electrode 4, it enters the anaerobic zone B from the bottom of the first separator 5, and the anode electrode also functions as a gas-liquid-solid three-phase rapid separation, degassing quickly and reducing dissolution Oxygen, to promote the denitrification process, the gas is discharged from the exhaust port; then the mechanical agitation lifting mechanism 7 lifts the water from the top of the second partition 10 into the aerobic zone C, and the tiny air bubbles generated by the first aeration component 9 Oxygenation is carried out in the aerobic zone to provide microorganisms with sufficient dissolved oxygen concentration of 2-4mg/L, which promotes microbial
- the module 27 performs oxygenation and flushing, and the water entering the membrane filtration area E is filtered by the membrane module 27 and then enters the water collection tank 31 through the outlet pipe; the sludge reflux is carried out in the adjustment area D during normal operation, and is returned to the inverted A 2 /O pool Anoxic zone A; when the mud discharge period (5-15d) is reached, the backflow is closed, the emptying pipe is opened, and the mud is discharged; the working pressure in the membrane filtration zone E is provided by the gravity head of water, which is 5-100kPa, The membrane module is not equipped with hydraulic cleaning and chemical cleaning devices, and the water is discharged continuously (intermittent operation is also possible);
- the raw water to be treated and the reflux sludge settled in the conditioning zone D enter the anoxic zone A of the device from the water inlet 15, and the sludge and reflux liquid returned from the aerobic zone C through the reflux channel 13 pass through the cathode electrode 3 together.
- the mixed water after the action of the low-voltage electric field enters the anaerobic zone B from the bottom of the first partition 5, and then is lifted by the mechanical stirring lifting mechanism 7 to lift the mixed water from the second partition
- the top of 8 is lifted into the aerobic zone C, and under the backflow force provided by the first aeration component 9, a part of the sludge and reflux liquid are returned to the anoxic zone A again through the backflow channel 13 to reconnect with the newly entered device to be treated
- the raw water of the water confluence; the other part of the mixed solution enters the GDMBR box 34 through the connecting pipe 24 through the large-angle inclined fender 6 again, and part of the sludge deposited in the adjustment area D is returned to the gap through the return pipe 26 and the return pump 25 again.
- the upper part of the oxygen zone A rejoins the raw water to be treated newly entering the device; the mixed solution pre-settled in the conditioning zone D is filtered through the membrane module 27 and then enters the water collection tank 31 through the outlet pipe; thus, the circulation backflow is finally completed.
- Sewage treatment regularly manually (every 8-12 hours, can be 10 hours) or automatically open the exhaust valve to remove the gas accumulation in the pipeline, and keep the water out of the pipeline smooth;
- the quality of treated raw water is: COD: 200mg/L; ammonia nitrogen: 30 ⁇ 5mg/L; TP: 4 ⁇ 0.5mg/L; pH 7.0-7.5.
- the quality of the effluent treated by the sewage treatment device of this application is: COD: 20.02 ⁇ 3.95mg/L; ammonia nitrogen: 4.3 ⁇ 0.5mg/L; TP: 0.32 ⁇ 0.05mg/L; the device of this application removes organic matter and denitrification
- the phosphorus removal effect is good, and the effluent water quality meets the first-class A standard in the "Pollutant Discharge Standards for Urban Sewage Treatment Plants". At the same time, it can remove pathogenic bacteria and has a good ability to resist shock loads.
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Abstract
Description
本发明属于村镇污水处理技术领域,涉及一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置及方法。 The invention belongs to the technical field of village and town sewage treatment, and relates to an inverted A 2 /O-GDMBR integrated village and town sewage treatment device and method with an external electric field.
随着经济发展,新农村建设的持续推进,农村生活水平得到了极大提高,生活污水产生量也在不断加大,农村生活污水已成为影响地表水环境安全的重要因素。与城市相比,农村地区的污水处理具有显著的地域差异性和水质水量差异性,且污水处理设施建设严重滞后,治理缓慢,大部分地区没有建设污水处理设施,部分已建处理设施也存在设计不合理、运行效能低下、能耗药耗高、缺乏专业运维人员等共性问题。因此,目前农村污水的收集处理率极低,大部分生活污水未经任何处理直接排放,造成河流、水塘大面积污染,对当地生态环境造成巨大影响,给农村居民的生活生产造成不便,严重制约了当地的经济发展和生活品质提升。针对农村污水处理现状、常规集中式处理技术在农村应用过程中存在的问题以及农村的地域和污水水质水量特性,农村污水处理必须从污染源头进行收集和处理,不能像城市那样集中处理-尾端解决。农村污水分布具有点多、量小、高度分散、水质复杂、变化系数大等特点,因此农村污水处理技术必须具有机动、灵活、操作简单、低能耗、低维护、无需专人看管、可实现无人值守条件下长期稳定运行等工艺特点,才能有效解决我国的农村污水处理问题。With economic development and the continuous advancement of new rural construction, rural living standards have been greatly improved, and the production of domestic sewage is also increasing. Rural domestic sewage has become an important factor affecting the safety of surface water environments. Compared with cities, sewage treatment in rural areas has significant regional differences and differences in water quality and quantity, and the construction of sewage treatment facilities is seriously lagging behind, and treatment is slow. Most areas have no sewage treatment facilities, and some of the built treatment facilities also have design problems. Unreasonable, low operating efficiency, high energy consumption, lack of professional operation and maintenance personnel and other common problems. Therefore, the current collection and treatment rate of rural sewage is extremely low, and most domestic sewage is directly discharged without any treatment, causing large-scale pollution of rivers and ponds, causing huge impact on the local ecological environment, causing inconvenience to the life and production of rural residents, and seriously Restricted the local economic development and the improvement of the quality of life. In view of the status quo of rural sewage treatment, the problems existing in the application of conventional centralized treatment technologies in rural areas, and the characteristics of rural areas and sewage water quality and water volume, rural sewage treatment must be collected and treated from the source of pollution, and cannot be treated in a centralized manner like cities. solve. The distribution of rural sewage has the characteristics of many points, small volume, high dispersion, complex water quality, and large coefficient of variation. Therefore, rural sewage treatment technology must be mobile, flexible, easy to operate, low energy consumption, low maintenance, no need for special supervision, and can realize unmanned The process characteristics such as long-term stable operation under on-duty conditions can effectively solve the problem of rural sewage treatment in my country.
现有的膜生物反应器(MBR)是一种将污水生物处理与膜分离相结合的新型的高效污水处理技术,具有污水处理效果好、占地面积小、自动化程度高、污泥产率低等优点,可作为村镇污水处理的优选工艺。然而,传统的单一MBR工艺在同步脱氮除磷方面的处理效果不理想,且膜污染严重,需要频繁的清洗;在运行过程中需要长时间大强度的曝气、频繁进行水力反冲洗和定期的化学清洗,这都会带来较大的能耗、较高的运营成本。因此,有必要设计一种新型的污水处理装置来解决上述问题。The existing membrane bioreactor (MBR) is a new type of high-efficiency sewage treatment technology that combines sewage biological treatment with membrane separation. It has the advantages of good sewage treatment effect, small footprint, high degree of automation, and low sludge yield. And other advantages, it can be used as the preferred process for sewage treatment in villages and towns. However, the traditional single MBR process is unsatisfactory in terms of synchronous denitrification and phosphorus removal, and the membrane fouling is serious, requiring frequent cleaning; in the process of operation, long-term high-intensity aeration, frequent hydraulic backwashing and regular Chemical cleaning, which will bring greater energy consumption and higher operating costs. Therefore, it is necessary to design a novel sewage treatment device to solve the above problems.
发明内容Contents of the invention
有鉴于此,本发明旨在提出一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装 置及方法,通过新构型研发实现了一气三用即集曝气充氧、硝化液循环和污泥回流三种功能于一体,采用回转式微电极在对微生物提供低电压调控的同时实现气-液-固三相速分功能强化脱氮除磷,具有净水效能高、低能耗、操作简便优势,是未来解决农村污水处理的一种可靠工艺。 In view of this, the present invention aims to propose an inverted A 2 /O-GDMBR integrated village and town sewage treatment device and method with an external electric field. Through the research and development of a new configuration, one gas and three functions are realized, namely, aeration, oxygenation, and nitrification liquid circulation. It integrates the three functions of sludge reflux and adopts the rotary microelectrode to provide low-voltage regulation to microorganisms while realizing gas-liquid-solid three-phase rapid separation function to strengthen nitrogen and phosphorus removal. It has high water purification efficiency, low energy consumption, and easy operation. The advantage of simplicity is a reliable process for solving rural sewage treatment in the future.
为达到上述目的,本发明的技术方案是这样实现的:In order to achieve the above object, technical solution of the present invention is achieved in that way:
一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置,包括倒置A 2/O箱体外壳、阴极电极、阳极电极、机械搅拌提升机构、第一曝气组件、可调节角度挡板、倾斜导流板、弧形导流板、GDMBR箱体、膜组件、第二曝气组件、集水箱、空气泵、回流泵和太阳能供电装置,所述的倒置A 2/O箱体外壳为密封箱体外壳,所述的GDMBR箱体为上部敞开的箱体,所述的空气泵、回流泵和太阳能供电装置均设置在倒置A 2/O箱体外壳的外部,所述的集水箱设置在GDMBR箱体的外部,所述空气泵、阳极电极、阴极电极、机械搅拌提升机构和回流泵均由太阳能供电装置供电; An inverted A 2 /O-GDMBR integrated village and town sewage treatment device with an external electric field, including an inverted A 2 /O box shell, cathode electrode, anode electrode, mechanical stirring and lifting mechanism, first aeration component, adjustable angle barrier plate, inclined deflector, curved deflector, GDMBR box, membrane module, second aeration module, water collection tank, air pump, return pump and solar power supply device, the inverted A 2 /O box shell In order to seal the box shell, the GDMBR box is an open top box, and the air pump, return pump and solar power supply device are all arranged outside the inverted A 2 /O box shell, and the water collection tank Set outside the GDMBR box, the air pump, anode electrode, cathode electrode, mechanical stirring lifting mechanism and return pump are all powered by solar power supply devices;
通过在倒置A 2/O箱体外壳内部平行布置的第一隔板和第二隔板将倒置A 2/O箱体外壳内部依次分隔成缺氧区、厌氧区和好氧区,所述第一隔板的上端高于第二隔板的上端布置,所述的缺氧区和厌氧区底部连通,所述的厌氧区上部与好氧区连通,所述的缺氧区上部通过进水口与外部进水管道连通,所述的阴极电极设置在缺氧区内,所述的阳极电极设置在阴极电极内,所述的机械搅拌提升机构设置在厌氧区内; The interior of the inverted A 2 /O box shell is divided into anoxic zone, anaerobic zone and aerobic zone sequentially by the first partition and the second partition arranged in parallel inside the inverted A 2 /O box shell, said The upper end of the first partition is arranged higher than the upper end of the second partition, the anoxic zone communicates with the bottom of the anaerobic zone, the upper part of the anaerobic zone communicates with the aerobic zone, and the upper part of the anoxic zone passes through The water inlet is connected with the external water inlet pipe, the cathode electrode is arranged in the anoxic zone, the anode electrode is arranged in the cathode electrode, and the mechanical stirring lifting mechanism is arranged in the anaerobic zone;
所述第一曝气组件设置在好氧区内,所述的倾斜导流板的上端与第一隔板的上端固定连接,倾斜导流板的下端伸入好氧区与可调节角度挡板的上端连接,所述的弧形导流板的上端固定在外壳顶壁上,下端为自由端,所述倾斜导流板、可调节角度挡板与外壳顶壁及弧形导流板之间形成回流通道;The first aeration assembly is set in the aerobic zone, the upper end of the inclined deflector is fixedly connected to the upper end of the first partition, and the lower end of the inclined deflector extends into the aerobic zone and the adjustable angle baffle The upper end of the curved deflector is fixed on the top wall of the housing, and the lower end is a free end. Form a return channel;
通过在GDMBR箱体内交错设置的两个隔板将GDMBR箱体内部分隔成调节区和膜滤区,好氧区的上部出水口通过连接管与调节区的上部连通,调节区的底部通过回流管与缺氧区的上部连通,所述第二曝气组件和膜组件均设置在膜滤区内,且第二曝气组件设置在膜组件的下方,膜组件的出水管道连通集水箱,在膜组件的出水管道上设有排气组件和出水阀,所述的第一曝气组件的进气管道和第二曝气组件的进气管道均与空气泵连接,在进气管道上设有空气阀;The interior of the GDMBR box is divided into a conditioning area and a membrane filtration area by two partitions arranged staggered in the GDMBR box. The upper outlet of the aerobic area is connected to the upper part of the conditioning area through a connecting pipe, and the bottom of the conditioning area is through a return pipe. It communicates with the upper part of the anoxic zone, the second aeration module and the membrane module are arranged in the membrane filtration area, and the second aeration module is arranged under the membrane module, and the outlet pipe of the membrane module is connected to the water collection tank, and the membrane module An exhaust assembly and a water outlet valve are arranged on the water outlet pipe of the assembly, the air inlet pipe of the first aeration assembly and the air inlet pipe of the second aeration assembly are connected with an air pump, and an air inlet pipe is provided on the air inlet pipe. valve;
第一曝气组件曝气时使好氧区的一部分污泥及液体沿回流通道回流至缺氧区,另一 部分混合液经倾斜挡泥板后由连接管进入到调节区,调节区内的沉淀的污泥部分经回流管和回流泵回流到缺氧区的上部,部分定期排出;经调节区预沉后的混合液进入膜滤区,在重力的驱动下,混合液经膜组件过滤,出水进入集水箱,第二曝气组件曝气冲刷膜组件。When the first aeration component is aerated, part of the sludge and liquid in the aerobic zone will flow back to the anoxic zone along the return channel, and the other part of the mixed liquid will enter the adjustment area through the connecting pipe after passing through the inclined fender, and the sediment in the adjustment area Part of the sludge returns to the upper part of the anoxic zone through the return pipe and the return pump, and part of it is discharged regularly; the mixed solution pre-sedimented in the adjustment zone enters the membrane filtration zone, driven by gravity, the mixed solution is filtered through the membrane module, and the water is discharged After entering the water collection tank, the second aeration component aerates and scours the membrane components.
进一步的,回流通道连通缺氧区的回流口,回流口与倒置A 2/O箱体外壳的进水口正对布置;在缺氧区的顶部设有排气口,排气口高出池顶30-200cm。 Further, the return channel is connected to the return port of the anoxic area, and the return port is arranged directly opposite to the water inlet of the inverted A 2 /O box shell; an exhaust port is provided on the top of the anoxic area, and the exhaust port is higher than the top of the pool 30-200cm.
进一步的,在缺氧区的底部、厌氧区的底部、好氧区的底部、调节区的底部和膜滤区的底部均设有倾斜挡泥板。Further, inclined fenders are provided at the bottom of the anoxic zone, the bottom of the anaerobic zone, the bottom of the aerobic zone, the bottom of the regulating zone and the bottom of the membrane filtration zone.
进一步的,所述倾斜导流板的下端与可调节角度挡板的上端铰接,通过调整可调节角度挡板的开合角度控制循环回流比。Further, the lower end of the inclined deflector is hinged to the upper end of the adjustable angle baffle, and the circulation and reflux ratio is controlled by adjusting the opening and closing angle of the adjustable angle baffle.
进一步的,所述阴极电极和阳极电极之间的距离为0.3-10cm;阴极电极材质采用碳布、碳毡或石墨板碳基材料及不锈钢网、泡沫镍或钛板非贵重金属材料;阳极电极材质采用石墨碳刷、石墨棒、石墨板或碳毡碳基材料;电极采用回转式结构,阴极电极所形成的筒状与阳极电极保持固定的间距。Further, the distance between the cathode electrode and the anode electrode is 0.3-10cm; the material of the cathode electrode is carbon cloth, carbon felt or graphite plate carbon-based material and stainless steel mesh, nickel foam or titanium plate non-precious metal material; the anode electrode The material is graphite carbon brush, graphite rod, graphite plate or carbon felt carbon-based material; the electrode adopts a rotary structure, and the cylindrical shape formed by the cathode electrode maintains a fixed distance from the anode electrode.
进一步的,所述太阳能供电装置与控制器电连接,所述控制器与阴极电极和阳极电极电连接,控制外加电压在0.1-5.0V。Further, the solar power supply device is electrically connected to a controller, and the controller is electrically connected to the cathode electrode and the anode electrode, and the applied voltage is controlled to be 0.1-5.0V.
进一步的,在厌氧区的机械搅拌提升机构强化推流时打开,在好氧区底部设有第一曝气组件,控制溶解氧在2-4mg/L的同时曝气提供气流推动力;在膜滤区底部设有第二曝气组件,程序性曝气,形成微气泡对膜组件进行充氧和冲刷。Further, when the mechanical agitation and lifting mechanism in the anaerobic zone strengthens the push flow, it is opened, and the first aeration component is installed at the bottom of the aerobic zone, and the aeration provides the driving force of the airflow while controlling the dissolved oxygen at 2-4mg/L; The bottom of the membrane filtration area is equipped with a second aeration component, which is programmed to aerate and form microbubbles to oxygenate and flush the membrane components.
进一步的,在好氧区的底部、调节区的底部和膜滤区的底部分别设有一个穿孔排泥管,在每个穿孔排泥管上均设有一个放空阀;所述穿孔排泥管和放空阀用于排出装置内的沉淀的泥;调节区的部分污泥定期回流至缺氧区。Further, a perforated sludge discharge pipe is respectively provided at the bottom of the aerobic zone, the bottom of the adjustment zone and the bottom of the membrane filtration zone, and a vent valve is provided on each perforated sludge discharge pipe; the perforated sludge discharge pipe And the vent valve is used to discharge the sedimented mud in the device; part of the sludge in the conditioning area is periodically returned to the anoxic area.
进一步的,所述GDMBR采用浸没式膜组件,可为平板膜或中空纤维膜,材质可采用醋酸纤维素类、醋酸纤维素酯类、聚乙烯类、聚砜类或聚酰胺类;膜组件采用低压重力流驱动,工作压力为5-100KPa,不设置水力清洗和化学清洗装置,连续出水。Further, the GDMBR adopts a submerged membrane module, which can be a flat membrane or a hollow fiber membrane, and the material can be cellulose acetate, cellulose acetate, polyethylene, polysulfone or polyamide; the membrane module adopts Driven by low-pressure gravity flow, the working pressure is 5-100KPa, without hydraulic cleaning and chemical cleaning devices, and the water is continuously discharged.
一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置的污水处理方法,具体包括以下步骤: A sewage treatment method of an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field, specifically comprising the following steps:
初始时,待处理的原水从进水口进入装置的缺氧区,流经由阴极电极和阳极电极构成的低压电场作用后由第一隔板底部进入厌氧区,然后经机械搅拌提升机构提升将水从第二隔板的上方提升进入好氧区,在好氧区内的第一曝气组件提供的回流动力下,使得一部分污泥和回流液经弧形导流板导流由回流通道回流至缺氧区;另一部分混合液经大角度的倾斜挡泥板后由连接管进入GDMBR箱体内,调节区沉淀的污泥部分经回流管和回流泵回流到缺氧区的上部,另一部分定期排出;经调节区预沉后的混合液进入膜滤区,第二曝气组件对膜组件进行充氧和冲刷,进入膜滤区的水通过膜组件过滤后由出水管道进入到集水箱中;Initially, the raw water to be treated enters the anoxic zone of the device from the water inlet, flows through the low-voltage electric field formed by the cathode electrode and the anode electrode, and then enters the anaerobic zone from the bottom of the first partition, and then the water is lifted by the mechanical agitation lifting mechanism. Lifting from the top of the second partition into the aerobic zone, under the return flow force provided by the first aeration component in the aerobic zone, a part of the sludge and return liquid are guided by the arc-shaped deflector and returned from the return channel to the Anoxic zone; the other part of the mixed liquid enters the GDMBR tank through the connecting pipe after passing through the large-angle inclined fender, and part of the sludge settled in the adjustment zone returns to the upper part of the anoxic zone through the return pipe and the return pump, and the other part is discharged regularly The mixed solution pre-sedimented in the conditioning area enters the membrane filtration area, the second aeration component oxygenates and flushes the membrane module, and the water entering the membrane filtration area is filtered by the membrane module and then enters the water collection tank through the outlet pipe;
运行时,待处理的原水和经调节区沉淀的回流污泥从进水口进入装置的缺氧区与从好氧区通过回流通道回流的污泥和回流液共同经过阴极不锈钢网和阳极碳刷构成的低压电场的作用,经低压电场作用后的混合水再由第一隔板底部进入厌氧区,然后再经机械搅拌提升机构提升将混合水从第二隔板的上方提升进入好氧区,在第一曝气组件提供的回流动力下,使得一部分污泥和回流液再次经回流通道回流至缺氧区重新与新进入装置内的待处理的原水汇合;另一部分污泥和回流液再次经大角度的倾斜挡泥板后由连接管进入GDMBR箱体内,调节区沉淀的污泥再次经回流管和回流泵回流到缺氧区的上部重新与新进入装置内的待处理的原水汇合;经调节区预沉后的混合液通过膜组件过滤后由出水管道进入到集水箱中;如此循环回流最终完成对污水的处理;During operation, the raw water to be treated and the return sludge deposited in the conditioning area enter the anoxic area of the device from the water inlet, and the sludge and return liquid returned from the aerobic area through the return channel pass through the cathode stainless steel mesh and the anode carbon brush together. The effect of the low-voltage electric field, the mixed water after the action of the low-voltage electric field enters the anaerobic zone from the bottom of the first partition, and then is lifted by the mechanical stirring lifting mechanism to lift the mixed water from the top of the second partition into the aerobic zone. Under the reflux power provided by the first aeration component, a part of the sludge and reflux liquid is returned to the anoxic zone through the reflux channel to rejoin the raw water to be treated newly entering the device; another part of the sludge and reflux liquid is again passed through The large-angle inclined fender enters the GDMBR tank through the connecting pipe, and the sludge deposited in the adjustment area flows back to the upper part of the anoxic area through the return pipe and the return pump to rejoin the raw water to be treated in the newly entered device; The pre-sedimented mixed solution in the conditioning area is filtered through the membrane module and then enters the water collection tank from the outlet pipe; such a circulation backflow finally completes the treatment of sewage;
在正常运行过程中,待达到排泥周期时,停止第一曝气组件和第二曝气组件曝气一段时间,打开穿孔排泥管进行排泥,排泥完成后所述装置重新运行。During normal operation, when the mud discharge period is reached, the aeration of the first aeration assembly and the second aeration assembly is stopped for a period of time, and the perforated mud discharge pipe is opened to discharge the mud, and the device restarts after the mud discharge is completed.
相对于现有技术,本发明所述的一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置具有以下优势: Compared with the prior art, the inverted A 2 /O-GDMBR integrated village sewage treatment device with external electric field described in the present invention has the following advantages:
(1)该装置在缺氧区施加低强度电场(0.1-5.0V),实现生物能、化学能及电能之间的相互转化,调控微生物的代谢行为、生理机能,细胞的形态及表面特征,从而提高微生物种群的多样性,改变污泥混合液性质,加速了酶的活化反应强度,从宏观方面表现为微生物对有机养分的吸收增强,促进污染物的降解,提高反硝化的效果和强化微生物对污染物的去除。相较于一般的电生物反应器,电能消耗小。(1) The device applies a low-intensity electric field (0.1-5.0V) in the anoxic area to realize the mutual conversion between biological energy, chemical energy and electrical energy, and regulate the metabolic behavior, physiological function, cell morphology and surface characteristics of microorganisms. Thereby increasing the diversity of microbial populations, changing the properties of the sludge mixture, and accelerating the activation reaction intensity of enzymes. From a macro perspective, it is manifested in the enhancement of the absorption of organic nutrients by microorganisms, promoting the degradation of pollutants, improving the effect of denitrification and strengthening microorganisms. removal of pollutants. Compared with general electric bioreactors, the power consumption is small.
(2)该装置的阴极和阳极可分别多种电极材料,适用范围广,与传统普通电极不同,本装置采用回转式结构电极,使得阳极电极不仅能传递电子且与混合液接触面积大,还 可起到气-液-固三相速分功能,快速脱气,降低溶解氧,促进反硝化过程,气体从排气口排出;阴极电极所形成的筒状,与阳极保持固定的较小间距,提高电子传递效率。(2) The cathode and anode of the device can be made of a variety of electrode materials, and have a wide range of applications. Different from traditional common electrodes, this device adopts a rotary structure electrode, so that the anode electrode can not only transfer electrons but also have a large contact area with the mixed solution, and also It can play the function of quick separation of gas-liquid-solid three-phase, degas quickly, reduce dissolved oxygen, promote the denitrification process, and the gas is discharged from the exhaust port; the cylindrical shape formed by the cathode electrode maintains a fixed small distance from the anode , improve electron transfer efficiency.
(3)该装置在厌氧区可采用机械搅拌提升机构或推流装置,对厌氧区混合液进行混合并且提升,促进厌氧脱氮与释磷。(3) In the anaerobic zone, the device can use a mechanical stirring lifting mechanism or a push-flow device to mix and lift the mixed liquid in the anaerobic zone to promote anaerobic denitrification and phosphorus release.
(4)该装置在好氧区布置曝气设施,产生的微小气泡对好氧区进行充氧,为微生物提供充分的溶解氧约2-4mg/L,促进微生物硝化反应和吸磷;同时曝气也为硝化液和污泥内回流提供动力。(4) The device arranges aeration facilities in the aerobic area, and the tiny air bubbles produced oxygenate the aerobic area, providing sufficient dissolved oxygen of about 2-4 mg/L for microorganisms, and promoting microbial nitrification and phosphorus absorption; The gas also provides power for the nitrifying liquid and the return flow of the sludge.
(5)该装置硝化液和污泥回流依靠装置底部曝气,仅仅在厌氧区设置机械搅拌提升机构或推流装置(需要强化回流时打开),节约能耗,同时通过调整挡板的开合角度来改变流体的流态和流场,从而改变不同的循环回流比,以应对水质、水量、温度的变化对反硝化作用的影响,保持最佳运行状态。(5) The reflux of nitrification liquid and sludge in this device relies on aeration at the bottom of the device, and only a mechanical stirring lifting mechanism or a push-flow device is installed in the anaerobic area (open when it needs to strengthen reflux) to save energy consumption, and at the same time adjust the opening of the baffle The flow state and flow field of the fluid can be changed by combining angles, so as to change the different cycle-reflux ratios, so as to cope with the impact of changes in water quality, water quantity, and temperature on denitrification, and maintain the best operating state.
(6)该装置在好氧区上部设置有弧形导流板,实现对水气运动规律的调整,达到一气三用(充氧、污泥回流、消化液循环)的目的,气体从排气口逸出,混合液在气流的推动下顺利回流至缺氧区与原水、回流污泥混合。(6) The device is equipped with an arc-shaped deflector on the upper part of the aerobic area to realize the adjustment of the movement law of water and gas, and achieve the purpose of one gas with three functions (oxygenation, sludge return, and digestive liquid circulation). The mixture escapes from the outlet, and the mixed liquid is smoothly returned to the anoxic zone under the push of the airflow to mix with the raw water and the return sludge.
(7)该装置在厌氧区中上部设置倾斜导流板,硝化液经内回流通道回流至缺氧区,进水口、外部污泥混合液回流口和装置内回流口正对,利用回流液的流速以及气泡的扰动,使进水快速均匀分布;同时进水中高浓度的有机质可快速消耗掉水中的溶解氧,促进厌氧环境的快速形成。(7) The device is equipped with an inclined deflector in the middle and upper part of the anaerobic zone, and the nitrifying liquid flows back to the anoxic zone through the internal return channel. The high flow rate and the disturbance of air bubbles make the influent quickly and evenly distributed; at the same time, the high concentration of organic matter in the influent can quickly consume the dissolved oxygen in the water and promote the rapid formation of an anaerobic environment.
(8)该装置在好氧区下部设置角度稍大的倾斜挡泥板,大角度可有效阻挡污泥上浮,实现良好沉淀条件,尽量减少污泥随出水进入GDMBR池,保证倒置A 2/O池内污泥浓度稳定并且减少后续的膜污染。 (8) The device is equipped with an inclined fender with a slightly larger angle at the lower part of the aerobic zone. The large angle can effectively prevent the sludge from floating up, realize good sedimentation conditions, minimize the sludge entering the GDMBR tank with the effluent, and ensure the inverted A 2 /O The sludge concentration in the tank is stable and the subsequent membrane fouling is reduced.
(9)该装置在GDMBR设有调节区,将进水先进行预沉调节,减少进入膜滤区的污泥量,以减轻膜污染。(9) The device is equipped with a regulating area in the GDMBR, and the influent water is pre-sedimented first to reduce the amount of sludge entering the membrane filtration area to reduce membrane pollution.
(10)该装置采用浸没式膜组件,可采用平板膜、中空纤维膜等多种类型、醋酸纤维素类、醋酸纤维素酯类、聚乙烯类、聚砜类或聚酰胺类等多种材质的膜,适用范围大,且装置紧凑,体积小;膜的高效截流作用使微生物截流在反应器内实现了水力停留时间(HRT)6-8h和污泥龄(SRT)5-15d的完全分离,使运行控制更加灵活稳定;装置内的 微生物浓度高,耐冲击负荷能力强。(10) The device adopts submerged membrane modules, which can be used in various types such as flat membranes and hollow fiber membranes, and various materials such as cellulose acetate, cellulose acetate ester, polyethylene, polysulfone or polyamide. The membrane has a wide range of applications, and the device is compact and small in size; the high-efficiency interception effect of the membrane enables microbial interception in the reactor to achieve complete separation of hydraulic retention time (HRT) 6-8h and sludge age (SRT) 5-15d , so that the operation control is more flexible and stable; the concentration of microorganisms in the device is high, and the impact load resistance is strong.
(11)该装置的膜组件采用低压重力流驱动,工作压力为5-100KPa,出水动力消耗费用低,节省能耗,降低设备、管道及附件对进水压力的要求。(11) The membrane module of the device is driven by low-pressure gravity flow, the working pressure is 5-100KPa, the power consumption of the outlet water is low, the energy consumption is saved, and the requirements for the inlet water pressure of equipment, pipelines and accessories are reduced.
(12)该装置采用无水力清洗和化学清洗的过滤模式,相对于传统的MBR工艺需要定期清洗,操作维护复杂的缺点,大幅降低了运营费用和工作量;同时不抑制膜组件表面微生物生长,并利用微生物作用强化污染物的去除效果,改善出水水质,缓解膜污染,提高产水量。(12) The device adopts a filtration mode without hydraulic cleaning and chemical cleaning. Compared with the traditional MBR process, which requires regular cleaning and complicated operation and maintenance, it greatly reduces operating costs and workload; at the same time, it does not inhibit the growth of microorganisms on the surface of the membrane module. And use the action of microorganisms to strengthen the removal effect of pollutants, improve the quality of effluent water, alleviate membrane fouling, and increase water production.
(13)该装置采用程序性曝气的措施来清洗膜组件,可持续、间歇或脉冲式曝气,在有效控制膜污染的同时节约曝气能耗;且采用微气泡曝气装置,以获得更高的横流速度和较低的上升阻力,对膜组件的清洗效果好但又不会损坏膜组件。(13) The device uses procedural aeration measures to clean the membrane modules, sustainable, intermittent or pulse aeration, which can effectively control membrane fouling while saving aeration energy consumption; and adopts a microbubble aeration device to obtain Higher cross flow velocity and lower rising resistance, good cleaning effect on the membrane components without damaging the membrane components.
(14)该装置采用特制排气装置排除管道内积气,可手动或自动排气,保障出水通畅。该排气装置可以直接观察检测管道内积气情况,排气效果好,较普通排气阀直观,减少排气次数,简化操作流程。(14) The device adopts a special exhaust device to remove the gas accumulated in the pipeline, which can be manually or automatically exhausted to ensure smooth water outlet. The exhaust device can directly observe and detect the gas accumulation in the pipeline, has a good exhaust effect, is more intuitive than ordinary exhaust valves, reduces the number of exhausts, and simplifies the operation process.
(15)该装置采用太阳能电池一体化供电系统,提供外加电场、曝气装置、机械搅拌提升机构所需电能,绿色环保,同时增设市政供电线路作为应急,避免因阴雨天气太阳能电池供电不足导致设备不能正常运行。(15) The device uses a solar battery integrated power supply system to provide the electric energy required by the external electric field, aeration device, and mechanical stirring and lifting mechanism, which is green and environmentally friendly. not functioning properly.
构成本发明的一部分的附图用来提供对本发明的进一步理解,本发明的示意性实施例及其说明用于解释本发明,并不构成对本发明的不当限定。在附图中:The drawings constituting a part of the present invention are used to provide a further understanding of the present invention, and the schematic embodiments and descriptions of the present invention are used to explain the present invention, and do not constitute an improper limitation of the present invention. In the attached picture:
图1为本发明实施例所述的一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置的结构示意图。 Fig. 1 is a schematic structural diagram of an inverted A 2 /O-GDMBR integrated village sewage treatment device with applied electric field according to an embodiment of the present invention.
附图标记说明:Explanation of reference signs:
A-缺氧区,B-厌氧区,C-好氧区,D-调节区,E-膜滤区;A-anoxic zone, B-anaerobic zone, C-aerobic zone, D-regulation zone, E-membrane filter zone;
1-止回阀,2-进水阀,3-阴极电极,4-阳极电极,5-第一隔板,6-挡泥板,7-机械搅拌提升机构,8-第二隔板,9-第一曝气组件,10-穿孔排泥管,11-可调节角度挡板,12-倾斜导流板,13-回流通道,14-回流口,15-进水口,16-弧形导流板,17-倒置A 2/O箱体外壳,18-排气口,19-控制器,20-太阳能供电装置,21-空气泵,22-空气阀,23- 气体流量计,24-连接管,25-回流泵,26-回流管,27-膜组件,28-液体流量计,29-排气组件,30-出水阀,31-集水箱,32-溢流管,33-放空阀,34-GDMBR箱体,35-第二曝气组件。 1- check valve, 2- water inlet valve, 3- cathode electrode, 4- anode electrode, 5- first partition, 6- fender, 7- mechanical stirring lifting mechanism, 8- second partition, 9 -The first aeration component, 10-perforated mud discharge pipe, 11-adjustable angle baffle, 12-inclined deflector, 13-return channel, 14-return port, 15-water inlet, 16-arc guide Board, 17-inverted A 2 /O box shell, 18-exhaust port, 19-controller, 20-solar power supply device, 21-air pump, 22-air valve, 23-gas flow meter, 24-connecting pipe , 25-return pump, 26-return pipe, 27-membrane assembly, 28-liquid flow meter, 29-exhaust assembly, 30-water outlet valve, 31-water collection tank, 32-overflow pipe, 33-vent valve, 34 - GDMBR box, 35 - second aeration assembly.
需要说明的是,在不冲突的情况下,本发明中的实施例及实施例中的特征可以相互组合。It should be noted that, in the case of no conflict, the embodiments of the present invention and the features in the embodiments can be combined with each other.
下面将参考附图并结合实施例来详细说明本发明。The present invention will be described in detail below with reference to the accompanying drawings and examples.
如图1所示,一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置,装置在污水处理时在装置内加入待处理污水,包括倒置A 2/O箱体外壳17、阴极电极3、阳极电极4、机械搅拌提升机构7、第一曝气组件9、可调节角度挡板11、倾斜导流板12、弧形导流板16、GDMBR箱体34、膜组件27、第二曝气组件35、集水箱31、空气泵21、回流泵25和太阳能供电装置20,所述的倒置A 2/O箱体外壳17为密封箱体外壳,处于微压状态,可强化氧的溶解度和污染物的传质效率,强化污染物去除效能;所述的GDMBR箱体34为上部敞开的箱体,所述的空气泵21、回流泵25和太阳能供电装置20均设置在倒置A 2/O箱体外壳17的外部,所述的集水箱31设置在GDMBR箱体34的外部,所述空气泵21、阳极电极4、阴极电极3、机械搅拌提升机构7和回流泵25均由太阳能供电装置20供电; As shown in Figure 1, an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field, the device adds sewage to be treated in the device during sewage treatment, including an inverted A 2 /O box shell 17, a cathode Electrode 3, anode electrode 4, mechanical stirring lifting mechanism 7, first aeration assembly 9, adjustable angle baffle 11, inclined deflector 12, arc deflector 16, GDMBR box 34, membrane module 27, the second Two aeration components 35, water collection tank 31, air pump 21, return pump 25 and solar power supply device 20, the inverted A 2 /O box shell 17 is a sealed box shell, in a micro-pressure state, which can strengthen oxygen Solubility and the mass transfer efficiency of pollutants strengthen the removal efficiency of pollutants; the GDMBR box 34 is an open box at the top, and the air pump 21, the return pump 25 and the solar power supply device 20 are all arranged on the inverted A 2 /O outside the box shell 17, the water collection tank 31 is arranged on the outside of the GDMBR box 34, the air pump 21, the anode electrode 4, the cathode electrode 3, the mechanical stirring lifting mechanism 7 and the return pump 25 are all powered by solar energy The power supply device 20 supplies power;
通过在倒置A
2/O箱体外壳17内部平行布置的第一隔板5和第二隔板8将倒置A
2/O箱体外壳17内部依次分隔成缺氧区A、厌氧区B和好氧区C,所述第一隔板5的上端高于第二隔板8的上端布置,所述的缺氧区A和厌氧区B底部连通,所述的厌氧区B上部与好氧区C连通,所述的缺氧区A上部通过进水口15与外部进水管道连通,所述的阴极电极3设置在缺氧区A内,所述的阳极电极4设置在阴极电极3内,所述的机械搅拌提升机构7设置在厌氧区B内;
The inside of the inverted A 2 /O box shell 17 is sequentially divided into anoxic zone A, anaerobic zone B and In the aerobic zone C, the upper end of the first partition 5 is arranged higher than the upper end of the
所述第一曝气组件9设置在好氧区C内,所述的倾斜导流板12与水平方向呈30°夹角布置,所述的倾斜导流板12的上端与第一隔板5的上端固定连接,倾斜导流板12的下端伸入好氧区C与可调节角度挡板11的上端连接,所述的弧形导流板的上端固定在外壳顶壁上,下端为自由端,所述倾斜导流板12、可调节角度挡板11与外壳顶壁及弧形导流板16之间形成回流通道13;The first aeration assembly 9 is set in the aerobic zone C, the
通过在GDMBR箱体34内交错设置的两个隔板将GDMBR箱体34内部分隔成调节区D 和膜滤区E,好氧区C的上部出水口通过连接管24与调节区D的上部连通,调节区D的底部通过回流管与缺氧区A的上部连通,所述第二曝气组件35和膜组件27均设置在膜滤区E内,且第二曝气组件35设置在膜组件27的下方,膜组件27的出水管道连通集水箱31,在膜组件27的出水管道上设有排气组件29和出水阀30,所述的第一曝气组件9的进气管道和第二曝气组件35的进气管道均与空气泵21连接,在进气管道上设有空气阀22;膜组件27即GDMBR采用浸没式膜组件,为平板膜或中空纤维膜,材质可采用:醋酸纤维素类、醋酸纤维素酯类、聚乙烯类、聚砜类或聚酰胺工作压力由水的重力水头提供,约5-100kPa,膜组件27不设置水力清洗和化学清洗装置,连续出水(亦可间歇运行);排气组件29可以是手动排气阀或定时排气的排气阀,定期手动(每8-12h一次)或自动打开排气阀排除管道积气,保障出水通畅;The inside of the
第一曝气组件9曝气时使好氧区C的一部分污泥及液体沿回流通道13回流至缺氧区A,另一部分混合液经倾斜挡泥板后由连接管24进入到调节区D,调节区D内的沉淀的污泥部分经回流管26和回流泵25回流到缺氧区A的上部,部分定期排出;经调节区D预沉后的混合液进入膜滤区E,在重力的驱动下,混合液经膜组件27过滤,出水进入集水箱31,第二曝气组件35曝气冲刷膜组件27。When the first aeration component 9 aerates, part of the sludge and liquid in the aerobic zone C flows back to the anoxic zone A along the
倒置A
2/O箱体外壳17密封,在厌氧区B的机械搅拌提升机构强化推流时打开,在好氧区C底部设有第一曝气组件,控制溶解氧在2-4mg/L的同时曝气提供气流推动力;在膜滤区E底部设有第二曝气组件,程序性曝气,形成微气泡对膜组件进行充氧和冲刷。
The
本申请采用倒置A 2/O耦合GDMBR工艺,通过新构型研发实现了一气三用即集曝气充氧、硝化液循环和污泥回流三种功能于一体,节约能耗;构建外源弱电场介导,阴阳两极均以回转式结构建立,外筒为阴极,阳极置于阴极中心,筒式放置提高了微生物和电极的接触面积,使电子的利用效率增大,从而促进反硝化速度、提高脱氮效率;微生物处于低压电场中代谢行为、生理机能,细胞的形态及表面特征发生变化,微生物群落的多样性提高,改变污泥混合液性质,从而降低膜污染;采用重力流式膜过滤系统(Gravity Driven Membrane system,GDM),过滤水头远小于传统膜滤设备所需过滤水头,仅由水的重力提供压力,不需要泵进行抽吸,故运行过程中能耗低;不需要水力反冲洗和化学清洗,故操作简单,运维管理方便。 This application adopts the inverted A 2 /O coupled GDMBR process, and through the research and development of a new configuration, it realizes three functions of one gas and three functions, that is, integrates three functions of aeration and oxygenation, nitrification liquid circulation and sludge return, saving energy consumption; building an external source of weak electricity Field-mediated, the negative and positive poles are built in a rotary structure, the outer cylinder is the cathode, and the anode is placed in the center of the cathode. The cylinder placement increases the contact area between microorganisms and electrodes, and increases the utilization efficiency of electrons, thereby promoting denitrification speed, Improve denitrification efficiency; microorganisms in low-voltage electric field have metabolic behavior, physiological functions, cell morphology and surface characteristics change, increase the diversity of microbial communities, change the properties of sludge mixture, thereby reducing membrane pollution; adopt gravity flow membrane filtration System (Gravity Driven Membrane system, GDM), the filtration head is much smaller than the filtration head required by traditional membrane filtration equipment, the pressure is only provided by the gravity of the water, and no pump is needed for suction, so the energy consumption is low during operation; no hydraulic reaction is required Flushing and chemical cleaning, so the operation is simple, and the operation and maintenance management is convenient.
回流通道13连通缺氧区A的回流口14,回流口14与倒置A
2/O箱体外壳17的进水 口15正对布置,利用回流液的流速以及气泡的扰动,使进水快速均匀分布;同时进水中高浓度的有机质可快速消耗掉水中的溶解氧,促进厌氧环境的快速形成。
The
在缺氧区A的底部、厌氧区B的底部、好氧区C的底部、调节区D的底部和膜滤区E的底部均设有倾斜挡泥板。具体为:在缺氧区A的底部和厌氧区B的底部分别设有一个倾斜挡泥板6,两个区内的倾斜挡泥板正对布置;在好氧区C的底部设有两个正对布置的倾斜挡泥板,且好氧区C底部的挡泥板与缺氧区A内的挡泥板空间垂直布置,在好氧区C的侧壁上设有一个大倾斜角度的挡泥板,用于水流向GDMBR箱体34,在调节区D的底部对称布置两个倾斜挡泥板,在膜滤区E的底部对称布置两个倾斜挡泥板;调节区D和膜滤区E内的挡泥板空间垂直布置;如此设置防止在装置的死角处积压泥,装置在运行时,倾斜挡泥板上的泥由斜板滑落,掉入厌氧区B或好氧区C、调节区D、膜滤区E,慢慢沉淀堆积,最终由穿孔排泥管收集后排除。Inclined fenders are provided at the bottom of the anoxic zone A, the bottom of the anaerobic zone B, the bottom of the aerobic zone C, the bottom of the regulating zone D and the bottom of the membrane filtration zone E. Specifically: an inclined fender 6 is respectively provided at the bottom of the anoxic area A and the bottom of the anaerobic area B, and the inclined fenders in the two areas are arranged facing each other; at the bottom of the aerobic area C, two A slanted fender facing to each other, and the fender at the bottom of the aerobic zone C is vertically arranged with the space of the fender in the anoxic zone A, and on the side wall of the aerobic zone C, there is a Fenders, for water flow to the
所述倾斜导流板12的下端与可调节角度挡板11的上端铰接,通过调整可调节角度挡板11的开合角度控制循环回流比;通过调整挡板的开合角度来改变流体的流态和流场,从而改变不同的循环回流比,一般回流比控制在循环回流比为0.5:1-3:1;以应对水质、水量、温度的变化对反硝化作用的影响,保持最佳运行状态。The lower end of the
在外部进水管道上、在连接管24上和在回流管26上分别设有一个进水阀2和一个止回阀1,在膜组件27的出水管道上还设有液体流量计28。在曝气组件的进气管道上还设有气体流量计23。在缺氧区A的顶部设有排气口18,排气口高出池顶30-200cm;在GDMBR箱体34上部连通有溢流管32。在好氧区C的底部、调节区D的底部和膜滤区E的底部分别设有一个穿孔排泥管10,在每个穿孔排泥管10上均设有一个放空阀33;所述穿孔排泥管10和放空阀33用于排出装置内的沉淀的泥。A
所述太阳能供电装置20与控制器19电连接,所述控制器19与阴极电极3和阳极电极4电连接;电能由太阳能供电装置提供,电极体积尽量占满厌氧区空间,阴极电极材质采用碳布、碳毡或石墨板碳基材料及不锈钢网、泡沫镍或钛板非贵重金属材料;阳极电极材质采用石墨碳刷、石墨棒、石墨板或碳毡碳基材料;电极采用回转式结构,阴极电极所形成的筒状,与阳极电极保持固定的间距;且不锈钢网阴极和石墨碳刷阳极之间的距离为0.3-10cm。The solar
一种外加电场的倒置A 2/O-GDMBR一体化村镇污水处理装置的污水处理方法,具体包 括以下步骤: A sewage treatment method of an inverted A 2 /O-GDMBR integrated village sewage treatment device with an external electric field, specifically comprising the following steps:
初始时,调节好可调节角度挡板11的角度,在缺氧区给阴极不锈钢网和阳极碳刷施加0.1-5.0V的低压,待处理的原水从进水口15进入装置的缺氧区A,流经由阴极电极3和阳极电极4构成的低压电场作用后由第一隔板5底部进入厌氧区B,阳极电极还起到了气-液-固三相速分功能,快速脱气,降低溶解氧,促进反硝化过程,气体从排气口排出;然后经机械搅拌提升机构7提升将水从第二隔板10的上方提升进入好氧区C,第一曝气组件9产生的微小气泡对好氧区进行充氧,为微生物提供充分的溶解氧浓度为2-4mg/L,促进微生物硝化反应和吸磷,同时也为硝化液和污泥内回流提供动力;气体经弧形导流板迅速由排气口排出,为硝化液内回流提供有力水力条件,在好氧区C内的第一曝气组件9提供的回流动力下,使得一部分污泥和回流液经弧形导流板16导流由回流通道13回流至缺氧区A,;另一部分混合液经大角度的倾斜挡泥板6后由连接管24进入GDMBR箱体34内,设置大角度的倾斜挡泥板(与水平线夹角为70°)可有效阻挡污泥上浮,实现良好沉淀条件,尽量减少污泥随出水进入GDMBR池,保证倒置A
2/O池内污泥浓度稳定并且减少后续的膜污染;调节区D沉淀的部分污泥经回流管26和回流泵25回流到缺氧区A的上部,另一部分定期排出;经调节区D预沉后的混合液进入膜滤区E,第二曝气组件35对膜组件27进行充氧和冲刷,进入膜滤区E的水通过膜组件27过滤后由出水管道进入到集水箱31中;调节区D平常运行时进行污泥回流,回流至倒置A
2/O池的缺氧区A;当达到排泥周期(5-15d)时,关闭回流,打开排空管,进行排泥;膜滤区E内的工作压力由水的重力水头提供,为5-100kPa,膜组件不设置水力清洗和化学清洗装置,连续出水(亦可间歇运行);
Initially, adjust the angle of the adjustable angle baffle 11, apply a low pressure of 0.1-5.0V to the cathode stainless steel mesh and the anode carbon brush in the anoxic zone, and the raw water to be treated enters the anoxic zone A of the device from the
运行时,待处理的原水和经调节区D沉淀的回流污泥从进水口15进入装置的缺氧区A与从好氧区C通过回流通道13回流的污泥和回流液共同经过阴极电极3和阳极电极4构成的低压电场的作用,经低压电场作用后的混合水再由第一隔板5底部进入厌氧区B,然后再经机械搅拌提升机构7提升将混合水从第二隔板8的上方提升进入好氧区C,在第一曝气组件9提供的回流动力下,使得一部分污泥和回流液再次经回流通道13回流至缺氧区A重新与新进入装置内的待处理的原水汇合;另一部分混合液再次经大角度的倾斜挡泥板6后由连接管24进入GDMBR箱体34内,调节区D沉淀的部分污泥再次经回流管26和回流泵25回流到缺氧区A的上部重新与新进入装置内的待处理的原水汇合;经调节区D预沉后的混合液通过膜组件27过滤后由出水管道进入到集水箱31中;如此循环回 流最终完成对污水的处理;定期手动(每8-12h一次,可以为10小时)或自动打开排气阀排除管道积气,保持管道出水顺畅;During operation, the raw water to be treated and the reflux sludge settled in the conditioning zone D enter the anoxic zone A of the device from the
在正常运行过程中,待达到排泥周期(每5-15d一次,可以为10天一次)时,停止第一曝气组件9和第二曝气组件35曝气5-60min,打开穿孔排泥管10进行排泥,排泥完成后所述装置重新运行。During normal operation, when the mud discharge cycle is reached (once every 5-15 days, which can be once every 10 days), stop the aeration of the first aeration component 9 and the
处理原水水质为:COD:200mg/L;氨氮:30±5mg/L;TP:4±0.5mg/L;pH 7.0-7.5。The quality of treated raw water is: COD: 200mg/L; ammonia nitrogen: 30±5mg/L; TP: 4±0.5mg/L; pH 7.0-7.5.
采用本申请的污水处理装置处理后的出水水质为:COD:20.02±3.95mg/L;氨氮:4.3±0.5mg/L;TP:0.32±0.05mg/L;本申请的装置去除有机物、脱氮除磷的效果好,出水水质满足《城镇污水处理厂污染物排放标准》中一级A的标准,同时能够去除致病细菌,具有很好的抗冲击负荷能力。The quality of the effluent treated by the sewage treatment device of this application is: COD: 20.02±3.95mg/L; ammonia nitrogen: 4.3±0.5mg/L; TP: 0.32±0.05mg/L; the device of this application removes organic matter and denitrification The phosphorus removal effect is good, and the effluent water quality meets the first-class A standard in the "Pollutant Discharge Standards for Urban Sewage Treatment Plants". At the same time, it can remove pathogenic bacteria and has a good ability to resist shock loads.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内,所作的任何修改、等同替换、改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements, improvements, etc. made within the spirit and principles of the present invention shall be included in the scope of the present invention. within the scope of protection.
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| CN114933394A (en) * | 2022-05-24 | 2022-08-23 | 广州先进技术研究所 | Self-refluxing MBR device and system capable of adjusting reflux ratio |
| GB2619123A (en) * | 2022-09-07 | 2023-11-29 | Harbin Inst Technology | Integrated inverted A2/O-GDMBR based on external electric field for village sewage treatment device and method |
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